Appendix I: Leachability - Laboratory Test Certificates and CoC
Documentation
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 562180-S
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Sep 07, 2017
Client Sample ID 0990_SS168_170821
0990_SS169_170821
0990_SS170_170821
0990_SS171_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Se07424 M17-Se07425 M17-Se07426 M17-Se07427
Date Sampled Aug 31, 2017 Aug 31, 2017 Aug 31, 2017 Aug 31, 2017
Test/Reference LOR Unit
Conductivity (1:5 aqueous extract at 25°C) 10 uS/cm 97 - 13 -
pH (1:5 Aqueous extract) 0.1 pH Units 8.8 7.5 7.6 8.0
Total Organic Carbon 0.1 % 1.8 < 0.1 < 0.1 0.1
% Moisture 1 % 47 24 16 12
Cation Exchange Capacity
Cation Exchange Capacity 0.05 meq/100g 66 - 1.5 -
Client Sample ID 0990_SS172_170821
0990_SS173_170821
0990_SS174_170821
0990_SS175_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Se07428 M17-Se07429 M17-Se07430 M17-Se07431
Date Sampled Aug 31, 2017 Aug 31, 2017 Aug 31, 2017 Aug 31, 2017
Test/Reference LOR Unit
Conductivity (1:5 aqueous extract at 25°C) 10 uS/cm 25 - 150 -
pH (1:5 Aqueous extract) 0.1 pH Units 7.6 7.8 8.2 8.7
Total Organic Carbon 0.1 % 1.3 3.1 1.6 0.4
% Moisture 1 % 26 26 2.4 35
Cation Exchange Capacity
Cation Exchange Capacity 0.05 meq/100g 7.4 - 52 -
Client Sample ID 0990_SS176_170821
0990_SS177_170821
0990_SS178_170821
0990_SS179_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Se07432 M17-Se07433 M17-Se07434 M17-Se07435
Date Sampled Aug 31, 2017 Aug 31, 2017 Aug 31, 2017 Aug 31, 2017
Test/Reference LOR Unit
Conductivity (1:5 aqueous extract at 25°C) 10 uS/cm 16 - 24 -
pH (1:5 Aqueous extract) 0.1 pH Units 8.2 7.8 7.6 7.4
Total Organic Carbon 0.1 % 0.5 0.2 0.1 0.8
% Moisture 1 % 27 29 23 17
Cation Exchange Capacity
Cation Exchange Capacity 0.05 meq/100g 6.4 - 2.1 -
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 562180-S
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_SS180_170821
0990_SS181_170821
0990_SS182_170821
0990_SS183_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Se07436 M17-Se07437 M17-Se07438 M17-Se07439
Date Sampled Aug 31, 2017 Aug 31, 2017 Aug 31, 2017 Aug 31, 2017
Test/Reference LOR Unit
Conductivity (1:5 aqueous extract at 25°C) 10 uS/cm 46 - 130 -
pH (1:5 Aqueous extract) 0.1 pH Units 7.2 8.3 8.4 8.4
Total Organic Carbon 0.1 % 0.1 0.7 0.8 0.9
% Moisture 1 % 22 23 7.7 26
Cation Exchange Capacity
Cation Exchange Capacity 0.05 meq/100g 2.4 - 40 -
Client Sample ID 0990_SS184_170821
0990_SS185_170821
0990_SS186_170821
0990_SS187_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Se07440 M17-Se07441 M17-Se07442 M17-Se07443
Date Sampled Aug 31, 2017 Aug 31, 2017 Aug 31, 2017 Aug 31, 2017
Test/Reference LOR Unit
Conductivity (1:5 aqueous extract at 25°C) 10 uS/cm 76 - 80 -
pH (1:5 Aqueous extract) 0.1 pH Units 8.1 8.8 6.5 8.7
Total Organic Carbon 0.1 % 1.1 0.4 2.6 0.9
% Moisture 1 % 15 19 19 17
Cation Exchange Capacity
Cation Exchange Capacity 0.05 meq/100g 16 - 27 -
Client Sample ID 0990_SS188_170821
0990_SS189_170821
0990_SS190_170821
0990_SS191_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Se07444 M17-Se07445 M17-Se07446 M17-Se07447
Date Sampled Aug 31, 2017 Aug 31, 2017 Aug 31, 2017 Aug 31, 2017
Test/Reference LOR Unit
Conductivity (1:5 aqueous extract at 25°C) 10 uS/cm 77 - 93 -
pH (1:5 Aqueous extract) 0.1 pH Units 8.1 8.0 7.9 8.2
Total Organic Carbon 0.1 % 1.2 0.7 < 0.1 0.4
% Moisture 1 % 23 1.4 15 < 1
Cation Exchange Capacity
Cation Exchange Capacity 0.05 meq/100g 31 - 16 -
Client Sample ID 0990_SS192_170821
Sample Matrix Soil
Eurofins | mgt Sample No. M17-Se07448
Date Sampled Aug 31, 2017
Test/Reference LOR Unit
pH (1:5 Aqueous extract) 0.1 pH Units 5.6
Total Organic Carbon 0.1 % 0.1
% Moisture 1 % 5.3
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 562180-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Conductivity (1:5 aqueous extract at 25°C) Melbourne Sep 09, 2017 7 Day
- Method: LTM-INO-4030
Cation Exchange Capacity Melbourne Sep 12, 2017 180 Days
- Method: LTM-MET-3060 - Cation Exchange Capacity (CEC) & Exchangeable Sodium Percentage (ESP)
pH (1:5 Aqueous extract) Melbourne Sep 11, 2017 7 Day
- Method: LTM-GEN-7090 pH in soil by ISE
Total Organic Carbon Melbourne Sep 12, 2017 28 Day
- Method: APHA 5310B Total Organic Carbon
% Moisture Melbourne Sep 07, 2017 14 Day
- Method: LTM-GEN-7080 Moisture
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 562180-S
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Sep 7, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 562180 Due: Sep 14, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Cation E
xchange Capacity
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_SS168_170821
Aug 31, 2017 Soil M17-Se07424 X X X X
2 0990_SS169_170821
Aug 31, 2017 Soil M17-Se07425 X X X
3 0990_SS170_170821
Aug 31, 2017 Soil M17-Se07426 X X X X
4 0990_SS171_170821
Aug 31, 2017 Soil M17-Se07427 X X X
5 0990_SS172_170821
Aug 31, 2017 Soil M17-Se07428 X X X X
6 0990_SS173_ Aug 31, 2017 Soil M17-Se07429 X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 562180-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Sep 7, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 562180 Due: Sep 14, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Cation E
xchange Capacity
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170821
7 0990_SS174_170821
Aug 31, 2017 Soil M17-Se07430 X X X X
8 0990_SS175_170821
Aug 31, 2017 Soil M17-Se07431 X X X
9 0990_SS176_170821
Aug 31, 2017 Soil M17-Se07432 X X X X
10 0990_SS177_170821
Aug 31, 2017 Soil M17-Se07433 X X X
11 0990_SS178_170821
Aug 31, 2017 Soil M17-Se07434 X X X X
12 0990_SS179_170821
Aug 31, 2017 Soil M17-Se07435 X X X
13 0990_SS180_ Aug 31, 2017 Soil M17-Se07436 X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 562180-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Sep 7, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 562180 Due: Sep 14, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Cation E
xchange Capacity
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170821
14 0990_SS181_170821
Aug 31, 2017 Soil M17-Se07437 X X X
15 0990_SS182_170821
Aug 31, 2017 Soil M17-Se07438 X X X X
16 0990_SS183_170821
Aug 31, 2017 Soil M17-Se07439 X X X
17 0990_SS184_170821
Aug 31, 2017 Soil M17-Se07440 X X X X
18 0990_SS185_170821
Aug 31, 2017 Soil M17-Se07441 X X X
19 0990_SS186_170821
Aug 31, 2017 Soil M17-Se07442 X X X X
20 0990_SS187_ Aug 31, 2017 Soil M17-Se07443 X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 562180-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Sep 7, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 562180 Due: Sep 14, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Cation E
xchange Capacity
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170821
21 0990_SS188_170821
Aug 31, 2017 Soil M17-Se07444 X X X X
22 0990_SS189_170821
Aug 31, 2017 Soil M17-Se07445 X X X
23 0990_SS190_170821
Aug 31, 2017 Soil M17-Se07446 X X X X
24 0990_SS191_170821
Aug 31, 2017 Soil M17-Se07447 X X X
25 0990_SS192_170821
Aug 31, 2017 Soil M17-Se07448 X X X
26 0990_SS175_170821
Aug 31, 2017 AUS Leachate M17-Se07449 X X
27 0990_SS176_ Aug 31, 2017 AUS Leachate M17-Se07450 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 562180-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Sep 7, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 562180 Due: Sep 14, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Cation E
xchange Capacity
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170821
28 0990_SS186_170821
Aug 31, 2017 AUS Leachate M17-Se07451 X X
29 0990_SS188_170821
Aug 31, 2017 AUS Leachate M17-Se07452 X X
Test Counts 25 25 4 25 12 4
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 562180-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 562180-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Conductivity (1:5 aqueous extract at 25°C) uS/cm < 10 10 Pass
Total Organic Carbon % < 0.1 0.1 Pass
Method Blank
Cation Exchange Capacity
Cation Exchange Capacity meq/100g < 0.05 0.05 Pass
LCS - % Recovery
Total Organic Carbon % 89 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Result 1 Result 2 RPD
Total Organic Carbon M17-Se07424 CP % 1.8 1.6 11 30% Pass
% Moisture M17-Se10377 NCP % 9.3 9.3 <1 30% Pass
Duplicate
Cation Exchange Capacity Result 1 Result 2 RPD
Cation Exchange Capacity M17-Se08631 NCP meq/100g 10 10 4.0 30% Pass
Duplicate
Result 1 Result 2 RPD
Conductivity (1:5 aqueous extractat 25°C) M17-Se07426 CP uS/cm 13 11 20 30% Pass
pH (1:5 Aqueous extract) M17-Se07426 CP pH Units 7.6 7.6 pass 30% Pass
Duplicate
Result 1 Result 2 RPD
Conductivity (1:5 aqueous extractat 25°C) M17-Se07428 CP uS/cm 25 25 <1 30% Pass
pH (1:5 Aqueous extract) M17-Se07428 CP pH Units 7.6 7.5 pass 30% Pass
Duplicate
Result 1 Result 2 RPD
Total Organic Carbon M17-Se07432 CP % 0.5 0.7 30 30% Pass
Duplicate
Result 1 Result 2 RPD
Conductivity (1:5 aqueous extractat 25°C) M17-Se07434 CP uS/cm 24 27 13 30% Pass
pH (1:5 Aqueous extract) M17-Se07434 CP pH Units 7.6 7.6 pass 30% Pass
Duplicate
Result 1 Result 2 RPD
Total Organic Carbon M17-Se07440 CP % 1.1 0.7 46 30% Fail Q15
Duplicate
Result 1 Result 2 RPD
Conductivity (1:5 aqueous extractat 25°C) M17-Se07444 CP uS/cm 77 71 8.0 30% Pass
pH (1:5 Aqueous extract) M17-Se07444 CP pH Units 8.1 8.0 pass 30% Pass
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 562180-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionQ15 The RPD reported passes Eurofins | mgt's QC - Acceptance Criteria as defined in the Internal Quality Control Review and Glossary page of this report.
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 562180-S
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 568586-L
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Oct 19, 2017
Client Sample ID 0990_SS151_170729
0990_SS129_170712
0990_SS162_170731
0990_SS101_0.0_170706
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23370 B17-Oc23372 B17-Oc23374 B17-Oc23376
Date Sampled Jul 29, 2017 Jul 12, 2017 Jul 31, 2017 Jul 06, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 0.28 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 0.25 < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.02 N090.73 < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 N090.14 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.02 N090.54 < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 0.16 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 0.24 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 0.13 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 N090.03 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 137 122 139 123
13C5-PFPeA (surr.) 1 % 107 87 101 105
13C5-PFHxA (surr.) 1 % 76 64 74 83
13C4-PFHpA (surr.) 1 % 100 90 101 105
13C8-PFOA (surr.) 1 % 135 120 142 143
13C5-PFNA (surr.) 1 % 119 101 122 121
13C6-PFDA (surr.) 1 % 87 68 104 106
13C2-PFUnDA (surr.) 1 % 58 48 79 69
13C2-PFDoDA (surr.) 1 % 47 37 76 77
13C2-PFTeDA (surr.) 1 % 24 10 37 24
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 0.59 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 57 36 73 69
D3-N-MeFOSA (surr.) 1 % 28 32 43 31
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 16
Report Number: 568586-L
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_SS151_170729
0990_SS129_170712
0990_SS162_170731
0990_SS101_0.0_170706
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23370 B17-Oc23372 B17-Oc23374 B17-Oc23376
Date Sampled Jul 29, 2017 Jul 12, 2017 Jul 31, 2017 Jul 06, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 19 27 38 25
D7-N-MeFOSE (surr.) 1 % 29 32 48 35
D9-N-EtFOSE (surr.) 1 % 25 26 38 27
D5-N-EtFOSAA (surr.) 1 % 46 38 67 62
D3-N-MeFOSAA (surr.) 1 % 50 43 76 71
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L N090.02 N090.32 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.04 N090.34 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.24 N092.2 N090.02 N090.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.02 N090.59 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.63 16 < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 88 78 83 86
18O2-PFHxS (surr.) 1 % 136 103 138 135
13C8-PFOS (surr.) 1 % 84 78 93 75
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 0.41 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 84 81 79 109
13C2-6:2 FTS (surr.) 1 % 118 112 120 136
13C2-8:2 FTS (surr.) 1 % 67 63 86 94
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.87 18.2 0.02 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.65 16.54 < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.89 18.74 0.02 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.93 20.87 < 0.05 < 0.05
Sum of PFASs (n=28) 0.1 ug/L 0.99 22.96 < 0.1 < 0.1
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 8.9 8.7 8.3 8.4
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 8.0 7.7 7.7 7.9
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 16
Report Number: 568586-L
Client Sample ID 0990_SS126_170712
0990_SS134_170713
0990_SS135_170713
0990_SS202_170929
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23378 B17-Oc23380 B17-Oc23382 B17-Oc23384
Date Sampled Jul 12, 2017 Jul 13, 2017 Jul 13, 2017 Sep 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L 0.42 < 0.05 < 0.05 0.07
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.37 < 0.01 0.02 N090.04
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.57 < 0.01 N090.03 N090.14
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.2 < 0.01 0.02 N090.02
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.52 N090.02 N090.06 N090.04
Perfluorononanoic acid (PFNA)N11 0.01 ug/L N090.22 < 0.01 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L N090.43 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.2 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.2 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.2 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.2 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 156 120 127 112
13C5-PFPeA (surr.) 1 % 165 93 94 102
13C5-PFHxA (surr.) 1 % 134 65 67 78
13C4-PFHpA (surr.) 1 % 143 92 92 108
13C8-PFOA (surr.) 1 % 155 131 135 152
13C5-PFNA (surr.) 1 % 146 130 127 130
13C6-PFDA (surr.) 1 % 138 112 113 96
13C2-PFUnDA (surr.) 1 % 105 80 82 58
13C2-PFDoDA (surr.) 1 % 78 84 81 62
13C2-PFTeDA (surr.) 1 % 16 30 28 28
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.2 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.2 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.2 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.2 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.2 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.2 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.2 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 101 70 65 66
D3-N-MeFOSA (surr.) 1 % 46 60 49 38
D5-N-EtFOSA (surr.) 1 % 36 54 41 34
D7-N-MeFOSE (surr.) 1 % 52 63 59 40
D9-N-EtFOSE (surr.) 1 % 32 48 46 31
D5-N-EtFOSAA (surr.) 1 % 108 63 62 58
D3-N-MeFOSAA (surr.) 1 % 112 67 69 63
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.32 < 0.01 < 0.01 N090.12
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L 0.22 < 0.01 < 0.01 N090.16
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N092.1 N090.02 N090.06 N090.47
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L 0.30 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L 9.8 < 0.01 N090.07 N090.02
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.2 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 135 78 81 83
18O2-PFHxS (surr.) 1 % 164 136 137 137
13C8-PFOS (surr.) 1 % 140 108 104 88
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 16
Report Number: 568586-L
Client Sample ID 0990_SS126_170712
0990_SS134_170713
0990_SS135_170713
0990_SS202_170929
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23378 B17-Oc23380 B17-Oc23382 B17-Oc23384
Date Sampled Jul 12, 2017 Jul 13, 2017 Jul 13, 2017 Sep 29, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.2 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.2 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L 1.3 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.2 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 113 70 77 144
13C2-6:2 FTS (surr.) 1 % 118 107 115 144
13C2-8:2 FTS (surr.) 1 % 113 95 85 91
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 11.9 0.02 0.13 0.49
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 10.32 0.02 0.13 0.06
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 12.42 0.04 0.19 0.53
Sum of WA DER PFAS (n=10) 0.05 ug/L 15.4 < 0.05 0.26 0.92
Sum of PFASs (n=28) 0.1 ug/L 16.57 < 0.1 0.27 1.08
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 8.4 8.1 8.1 8.4
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 7.8 8.1 7.9 7.3
Client Sample ID 0990_SS192_170822
0990_SS154_170729
0990_SS122_170712
0990_SS133_170713
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23386 B17-Oc23388 B17-Oc23390 B17-Oc23392
Date Sampled Aug 22, 2017 Jul 29, 2017 Jul 12, 2017 Jul 13, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.06 < 0.01 0.03 N090.03
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.12 N090.03 0.07 N090.05
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.02 < 0.01 N090.01 0.02
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.02 N090.02 N090.03 N090.04
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 0.02
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 92 129 121 127
13C5-PFPeA (surr.) 1 % 104 100 96 100
13C5-PFHxA (surr.) 1 % 125 68 107 71
13C4-PFHpA (surr.) 1 % 113 96 97 95
13C8-PFOA (surr.) 1 % 112 131 146 138
13C5-PFNA (surr.) 1 % 103 121 131 123
13C6-PFDA (surr.) 1 % 80 103 117 103
13C2-PFUnDA (surr.) 1 % 69 75 86 77
13C2-PFDoDA (surr.) 1 % 62 72 83 76
13C2-PFTeDA (surr.) 1 % 15 33 33 30
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 16
Report Number: 568586-L
Client Sample ID 0990_SS192_170822
0990_SS154_170729
0990_SS122_170712
0990_SS133_170713
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23386 B17-Oc23388 B17-Oc23390 B17-Oc23392
Date Sampled Aug 22, 2017 Jul 29, 2017 Jul 12, 2017 Jul 13, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 59 70 55 65
D3-N-MeFOSA (surr.) 1 % 18 36 22 41
D5-N-EtFOSA (surr.) 1 % 14 30 19 35
D7-N-MeFOSE (surr.) 1 % 24 45 29 56
D9-N-EtFOSE (surr.) 1 % 17 37 22 44
D5-N-EtFOSAA (surr.) 1 % 61 62 68 58
D3-N-MeFOSAA (surr.) 1 % 62 67 79 63
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.01 < 0.01 0.03 0.02
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 N090.02 N090.05 N090.02
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.02 N090.03 N090.14 N090.06
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.01 < 0.01 N090.10 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 120 81 81 83
18O2-PFHxS (surr.) 1 % 112 137 138 135
13C8-PFOS (surr.) 1 % 83 97 103 101
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 114 74 INT 87
13C2-6:2 FTS (surr.) 1 % 113 106 134 125
13C2-8:2 FTS (surr.) 1 % 88 87 103 91
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.03 0.03 0.24 0.06
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.03 0.02 0.13 0.04
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.05 0.05 0.27 0.1
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.26 0.08 0.41 0.22
Sum of PFASs (n=28) 0.1 ug/L 0.26 0.1 0.46 0.26
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 9.5 9.1 8.7 8.6
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 8.3 8.4 8.3 8.5
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 16
Report Number: 568586-L
Client Sample ID 0990_SS158_170729
Sample Matrix AUS Leachate
Eurofins | mgt Sample No. B17-Oc23394
Date Sampled Jul 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.07
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.13
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.05
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.11
Perfluorononanoic acid (PFNA)N11 0.01 ug/L 0.03
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L N090.02
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 133
13C5-PFPeA (surr.) 1 % 103
13C5-PFHxA (surr.) 1 % 70
13C4-PFHpA (surr.) 1 % 97
13C8-PFOA (surr.) 1 % 135
13C5-PFNA (surr.) 1 % 128
13C6-PFDA (surr.) 1 % 120
13C2-PFUnDA (surr.) 1 % 84
13C2-PFDoDA (surr.) 1 % 81
13C2-PFTeDA (surr.) 1 % 28
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 81
D3-N-MeFOSA (surr.) 1 % 48
D5-N-EtFOSA (surr.) 1 % 44
D7-N-MeFOSE (surr.) 1 % 50
D9-N-EtFOSE (surr.) 1 % 40
D5-N-EtFOSAA (surr.) 1 % 74
D3-N-MeFOSAA (surr.) 1 % 86
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L N090.03
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.05
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.21
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.03
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 81
18O2-PFHxS (surr.) 1 % 134
13C8-PFOS (surr.) 1 % 114
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 16
Report Number: 568586-L
Client Sample ID 0990_SS158_170729
Sample Matrix AUS Leachate
Eurofins | mgt Sample No. B17-Oc23394
Date Sampled Jul 29, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L 0.02
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 76
13C2-6:2 FTS (surr.) 1 % 123
13C2-8:2 FTS (surr.) 1 % 106
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.24
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.14
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.35
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.65
Sum of PFASs (n=28) 0.1 ug/L 0.75
AUS Leaching Procedure
Leachate FluidC01 comment 4.0
pH (initial) 0.1 pH Units 8.9
pH (Leachate fluid) 0.1 pH Units 7.0
pH (off) 0.1 pH Units 8.7
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 16
Report Number: 568586-L
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Oct 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Oct 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Oct 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Oct 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
AUS Leaching Procedure Brisbane Oct 23, 2017 7 Days
- Method: LTM-GEN-7010 Leaching Procedure for Soils & Solid Wastes
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 16
Report Number: 568586-L
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 568586 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_SS151_170729
Jul 29, 2017 Soil B17-Oc23369 X X X
2 0990_SS151_170729
Jul 29, 2017 AUS Leachate B17-Oc23370 X X
3 0990_SS129_170712
Jul 12, 2017 Soil B17-Oc23371 X X X
4 0990_SS129_170712
Jul 12, 2017 AUS Leachate B17-Oc23372 X X
5 0990_SS162_170731
Jul 31, 2017 Soil B17-Oc23373 X X X
6 0990_SS162_ Jul 31, 2017 AUS Leachate B17-Oc23374 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 16
Report Number: 568586-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 568586 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170731
7 0990_SS101_0.0_170706
Jul 06, 2017 Soil B17-Oc23375 X X X
8 0990_SS101_0.0_170706
Jul 06, 2017 AUS Leachate B17-Oc23376 X X
9 0990_SS126_170712
Jul 12, 2017 Soil B17-Oc23377 X X X
10 0990_SS126_170712
Jul 12, 2017 AUS Leachate B17-Oc23378 X X
11 0990_SS134_170713
Jul 13, 2017 Soil B17-Oc23379 X X X
12 0990_SS134_170713
Jul 13, 2017 AUS Leachate B17-Oc23380 X X
13 0990_SS135_ Jul 13, 2017 Soil B17-Oc23381 X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 16
Report Number: 568586-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 568586 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170713
14 0990_SS135_170713
Jul 13, 2017 AUS Leachate B17-Oc23382 X X
15 0990_SS202_170929
Sep 29, 2017 Soil B17-Oc23383 X X X
16 0990_SS202_170929
Sep 29, 2017 AUS Leachate B17-Oc23384 X X
17 0990_SS192_170822
Aug 22, 2017 Soil B17-Oc23385 X X X
18 0990_SS192_170822
Aug 22, 2017 AUS Leachate B17-Oc23386 X X
19 0990_SS154_170729
Jul 29, 2017 Soil B17-Oc23387 X X X
20 0990_SS154_ Jul 29, 2017 AUS Leachate B17-Oc23388 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 11 of 16
Report Number: 568586-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 568586 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170729
21 0990_SS122_170712
Jul 12, 2017 Soil B17-Oc23389 X X X
22 0990_SS122_170712
Jul 12, 2017 AUS Leachate B17-Oc23390 X X
23 0990_SS133_170713
Jul 13, 2017 Soil B17-Oc23391 X X X
24 0990_SS133_170713
Jul 13, 2017 AUS Leachate B17-Oc23392 X X
25 0990_SS158_170729
Jul 29, 2017 Soil B17-Oc23393 X X X
26 0990_SS158_170729
Jul 29, 2017 AUS Leachate B17-Oc23394 X X
Test Counts 13 13 13 13 13
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 12 of 16
Report Number: 568586-L
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 13 of 16
Report Number: 568586-L
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Oc23380 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Oc23380 CP ug/L 0.02 0.02 5.0 30% Pass
Perfluorononanoic acid (PFNA) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 14 of 16
Report Number: 568586-L
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Oc23380 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Oc23380 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Oc23380 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Oc23380 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Oc23380 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Oc23380 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Oc23380 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Oc23380 CP ug/L 0.02 0.02 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Oc23380 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Oc23380 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 15 of 16
Report Number: 568586-L
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved No
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionC01 Leachate Fluid Key: 1 - pH 5.0; 2 - pH 2.9; 3 - pH 9.2; 4 - Reagent (DI) water; 5 - Client sample, 6 - other
N09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 16 of 16
Report Number: 568586-L
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 568586-S
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Oct 19, 2017
Client Sample ID 0990_SS151_170729
0990_SS129_170712
0990_SS162_170731
0990_SS101_0.0_170706
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. B17-Oc23369 B17-Oc23371 B17-Oc23373 B17-Oc23375
Date Sampled Jul 29, 2017 Jul 12, 2017 Jul 31, 2017 Jul 06, 2017
Test/Reference LOR Unit
pH (1:5 Aqueous extract) 0.1 pH Units 6.8 7.0 7.3 7.6
Total Organic Carbon 0.1 % 0.3 1.0 1.3 0.9
% Moisture 1 % 2.5 1.7 5.3 28
Client Sample ID 0990_SS126_170712
0990_SS134_170713
0990_SS135_170713
0990_SS202_170929
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. B17-Oc23377 B17-Oc23379 B17-Oc23381 B17-Oc23383
Date Sampled Jul 12, 2017 Jul 13, 2017 Jul 13, 2017 Sep 29, 2017
Test/Reference LOR Unit
pH (1:5 Aqueous extract) 0.1 pH Units 7.4 7.0 6.7 7.7
Total Organic Carbon 0.1 % 1.3 2.4 1.1 3.9
% Moisture 1 % 1.5 19 11 2.5
Client Sample ID 0990_SS192_170822
0990_SS154_170729
0990_SS122_170712
0990_SS133_170713
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. B17-Oc23385 B17-Oc23387 B17-Oc23389 B17-Oc23391
Date Sampled Aug 22, 2017 Jul 29, 2017 Jul 12, 2017 Jul 13, 2017
Test/Reference LOR Unit
pH (1:5 Aqueous extract) 0.1 pH Units 6.9 8.1 7.8 7.8
Total Organic Carbon 0.1 % 8.9 0.2 0.8 0.5
% Moisture 1 % 6.0 3.3 20 3.1
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 10
Report Number: 568586-S
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_SS158_170729
Sample Matrix Soil
Eurofins | mgt Sample No. B17-Oc23393
Date Sampled Jul 29, 2017
Test/Reference LOR Unit
pH (1:5 Aqueous extract) 0.1 pH Units 7.9
Total Organic Carbon 0.1 % 0.7
% Moisture 1 % 12
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 10
Report Number: 568586-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
pH (1:5 Aqueous extract) Melbourne Oct 25, 2017 7 Day
- Method: LTM-GEN-7090 pH in soil by ISE
Total Organic Carbon Melbourne Oct 26, 2017 28 Day
- Method: APHA 5310B Total Organic Carbon
% Moisture Melbourne Oct 20, 2017 14 Day
- Method: LTM-GEN-7080 Moisture
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 10
Report Number: 568586-S
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 568586 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_SS151_170729
Jul 29, 2017 Soil B17-Oc23369 X X X
2 0990_SS151_170729
Jul 29, 2017 AUS Leachate B17-Oc23370 X X
3 0990_SS129_170712
Jul 12, 2017 Soil B17-Oc23371 X X X
4 0990_SS129_170712
Jul 12, 2017 AUS Leachate B17-Oc23372 X X
5 0990_SS162_170731
Jul 31, 2017 Soil B17-Oc23373 X X X
6 0990_SS162_ Jul 31, 2017 AUS Leachate B17-Oc23374 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 10
Report Number: 568586-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 568586 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170731
7 0990_SS101_0.0_170706
Jul 06, 2017 Soil B17-Oc23375 X X X
8 0990_SS101_0.0_170706
Jul 06, 2017 AUS Leachate B17-Oc23376 X X
9 0990_SS126_170712
Jul 12, 2017 Soil B17-Oc23377 X X X
10 0990_SS126_170712
Jul 12, 2017 AUS Leachate B17-Oc23378 X X
11 0990_SS134_170713
Jul 13, 2017 Soil B17-Oc23379 X X X
12 0990_SS134_170713
Jul 13, 2017 AUS Leachate B17-Oc23380 X X
13 0990_SS135_ Jul 13, 2017 Soil B17-Oc23381 X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 10
Report Number: 568586-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 568586 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170713
14 0990_SS135_170713
Jul 13, 2017 AUS Leachate B17-Oc23382 X X
15 0990_SS202_170929
Sep 29, 2017 Soil B17-Oc23383 X X X
16 0990_SS202_170929
Sep 29, 2017 AUS Leachate B17-Oc23384 X X
17 0990_SS192_170822
Aug 22, 2017 Soil B17-Oc23385 X X X
18 0990_SS192_170822
Aug 22, 2017 AUS Leachate B17-Oc23386 X X
19 0990_SS154_170729
Jul 29, 2017 Soil B17-Oc23387 X X X
20 0990_SS154_ Jul 29, 2017 AUS Leachate B17-Oc23388 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 10
Report Number: 568586-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 568586 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170729
21 0990_SS122_170712
Jul 12, 2017 Soil B17-Oc23389 X X X
22 0990_SS122_170712
Jul 12, 2017 AUS Leachate B17-Oc23390 X X
23 0990_SS133_170713
Jul 13, 2017 Soil B17-Oc23391 X X X
24 0990_SS133_170713
Jul 13, 2017 AUS Leachate B17-Oc23392 X X
25 0990_SS158_170729
Jul 29, 2017 Soil B17-Oc23393 X X X
26 0990_SS158_170729
Jul 29, 2017 AUS Leachate B17-Oc23394 X X
Test Counts 13 13 13 13 13
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 10
Report Number: 568586-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 10
Report Number: 568586-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Total Organic Carbon % < 0.1 0.1 Pass
LCS - % Recovery
Total Organic Carbon % 104 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Result 1 Result 2 RPD
pH (1:5 Aqueous extract) M17-Oc22933 NCP pH Units 7.1 7.0 pass 30% Pass
Duplicate
Result 1 Result 2 RPD
% Moisture B17-Oc23371 CP % 1.7 1.7 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Total Organic Carbon B17-Oc23377 CP % 1.3 1.6 19 30% Pass
Duplicate
Result 1 Result 2 RPD
Total Organic Carbon B17-Oc23393 CP % 0.7 0.6 7.5 30% Pass
% Moisture B17-Oc23393 CP % 12 11 10 30% Pass
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 10
Report Number: 568586-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved No
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 10
Report Number: 568586-S
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 568621-L
Project name DOD TINDAL
Project ID ADDITIONAL ANALYSIS
Received Date Oct 19, 2017
Client Sample ID 0990_BH119_0.4_170712
0990_QCB114_170712
0990_QCBH116_170712
0990_BH148_0.0_170804
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23841 B17-Oc23843 B17-Oc23845 B17-Oc23847
Date Sampled Jul 12, 2017 Jul 12, 2017 Jul 12, 2017 Aug 04, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L 0.06 0.16 < 0.05 0.12
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.03 N090.16 N090.06 N090.06
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.06 N090.36 N090.12 N090.13
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.02 N090.09 N090.03 N090.02
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.02 N090.30 N090.06 N090.04
Perfluorononanoic acid (PFNA)N11 0.01 ug/L 0.02 N090.03 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L 0.01 N090.04 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 N090.02 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 126 119 121 122
13C5-PFPeA (surr.) 1 % 93 90 101 96
13C5-PFHxA (surr.) 1 % 68 63 72 64
13C4-PFHpA (surr.) 1 % 94 91 102 88
13C8-PFOA (surr.) 1 % 147 129 162 145
13C5-PFNA (surr.) 1 % 133 120 143 134
13C6-PFDA (surr.) 1 % 121 109 130 116
13C2-PFUnDA (surr.) 1 % 84 80 88 94
13C2-PFDoDA (surr.) 1 % 70 79 89 91
13C2-PFTeDA (surr.) 1 % 24 30 40 30
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 0.16 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 59 64 64 76
D3-N-MeFOSA (surr.) 1 % 39 47 27 44
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 25
Report Number: 568621-L
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_BH119_0.4_170712
0990_QCB114_170712
0990_QCBH116_170712
0990_BH148_0.0_170804
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23841 B17-Oc23843 B17-Oc23845 B17-Oc23847
Date Sampled Jul 12, 2017 Jul 12, 2017 Jul 12, 2017 Aug 04, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 32 39 25 38
D7-N-MeFOSE (surr.) 1 % 44 58 36 49
D9-N-EtFOSE (surr.) 1 % 35 47 29 40
D5-N-EtFOSAA (surr.) 1 % 64 63 78 71
D3-N-MeFOSAA (surr.) 1 % 75 66 87 91
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L N090.02 N090.07 N090.08 N090.20
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L 0.01 N090.10 N090.11 N090.12
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.04 N090.60 N090.50 N090.24
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 N090.03 N090.03 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.12 N091.9 N090.27 N090.11
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 83 78 82 78
18O2-PFHxS (surr.) 1 % 141 123 136 140
13C8-PFOS (surr.) 1 % 112 80 114 114
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 77 70 104 98
13C2-6:2 FTS (surr.) 1 % 124 101 154 135
13C2-8:2 FTS (surr.) 1 % 92 88 122 93
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.16 2.5 0.77 0.35
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.14 2.2 0.33 0.15
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.18 2.8 0.83 0.39
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.37 3.64 1.13 0.92
Sum of PFASs (n=28) 0.1 ug/L 0.41 4.02 1.28 1.04
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 8.6 8.4 8.4 9.1
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 6.9 7.1 6.5 7.5
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 25
Report Number: 568621-L
Client Sample ID 0990_BH148_0.4_170804
0990_BH149_0.5_170808
0990_BH150_0.0_170808
0990_BH175_0.0_170811
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23849 B17-Oc23851 B17-Oc23853 B17-Oc23855
Date Sampled Aug 04, 2017 Aug 08, 2017 Aug 08, 2017 Aug 11, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L 0.10 < 0.2 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.10 < 0.2 N090.04 N090.05
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.42 < 0.2 N090.25 N090.09
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.04 < 0.2 N090.04 N090.02
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.05 N09< 0.2 N090.17 N090.07
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 N09< 0.2 < 0.01 0.03
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.2 N090.01 N090.15
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.2 N090.02 N090.07
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 N09< 0.2 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.2 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.2 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 132 131 135 134
13C5-PFPeA (surr.) 1 % 97 133 100 97
13C5-PFHxA (surr.) 1 % 64 106 65 67
13C4-PFHpA (surr.) 1 % 90 121 94 93
13C8-PFOA (surr.) 1 % 124 134 135 135
13C5-PFNA (surr.) 1 % 112 127 129 127
13C6-PFDA (surr.) 1 % 96 126 117 112
13C2-PFUnDA (surr.) 1 % 75 103 96 73
13C2-PFDoDA (surr.) 1 % 67 85 92 70
13C2-PFTeDA (surr.) 1 % 26 15 32 27
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.2 0.63 0.06
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.2 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.2 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.2 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.2 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.2 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.2 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 52 107 70 73
D3-N-MeFOSA (surr.) 1 % 26 49 43 36
D5-N-EtFOSA (surr.) 1 % 22 37 38 32
D7-N-MeFOSE (surr.) 1 % 36 53 51 47
D9-N-EtFOSE (surr.) 1 % 27 32 41 36
D5-N-EtFOSAA (surr.) 1 % 63 106 75 65
D3-N-MeFOSAA (surr.) 1 % 73 110 99 77
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L N090.43 < 0.2 N090.03 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.30 < 0.2 N090.07 N090.02
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.33 N090.98 N090.41 N090.07
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 N09< 0.2 N090.02 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.02 N092.7 N090.59 N090.04
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.2 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 75 110 80 80
18O2-PFHxS (surr.) 1 % 125 142 128 134
13C8-PFOS (surr.) 1 % 86 124 96 107
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 25
Report Number: 568621-L
Client Sample ID 0990_BH148_0.4_170804
0990_BH149_0.5_170808
0990_BH150_0.0_170808
0990_BH175_0.0_170811
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23849 B17-Oc23851 B17-Oc23853 B17-Oc23855
Date Sampled Aug 04, 2017 Aug 08, 2017 Aug 08, 2017 Aug 11, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.2 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.2 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.2 < 0.01 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.2 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 75 90 75 77
13C2-6:2 FTS (surr.) 1 % 110 100 113 127
13C2-8:2 FTS (surr.) 1 % 81 102 98 84
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.35 3.68 1 0.11
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.07 2.7 0.76 0.11
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.4 3.68 1.17 0.18
Sum of WA DER PFAS (n=10) 0.05 ug/L 1.49 3.68 1.53 0.36
Sum of PFASs (n=28) 0.1 ug/L 1.79 3.68 2.28 0.69
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 9.3 9.2 8.9 9.1
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 8.1 8.5 8.8 8.9
Client Sample ID 0990_BH175_0.2_170811
0990_BH164_2.0_170810
0990_BH165_0.0_170810
0990_BH165_1.0_170810
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23857 B17-Oc23859 B17-Oc23861 B17-Oc23863
Date Sampled Aug 11, 2017 Aug 10, 2017 Aug 10, 2017 Aug 10, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 0.16 0.54
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.03 N090.02 N090.22 N090.89
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.06 N090.03 N090.86 N094.0
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.02 < 0.01 N090.13 N090.32
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.05 N090.02 N090.27 N090.61
Perfluorononanoic acid (PFNA)N11 0.01 ug/L 0.03 < 0.01 N090.03 N090.02
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L 0.06 < 0.01 0.02 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L N090.02 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 130 135 128 117
13C5-PFPeA (surr.) 1 % 99 97 93 89
13C5-PFHxA (surr.) 1 % 66 69 62 53
13C4-PFHpA (surr.) 1 % 94 94 91 91
13C8-PFOA (surr.) 1 % 139 141 140 109
13C5-PFNA (surr.) 1 % 124 131 137 129
13C6-PFDA (surr.) 1 % 105 118 123 111
13C2-PFUnDA (surr.) 1 % 72 75 88 81
13C2-PFDoDA (surr.) 1 % 59 71 81 77
13C2-PFTeDA (surr.) 1 % 20 28 26 26
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 25
Report Number: 568621-L
Client Sample ID 0990_BH175_0.2_170811
0990_BH164_2.0_170810
0990_BH165_0.0_170810
0990_BH165_1.0_170810
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23857 B17-Oc23859 B17-Oc23861 B17-Oc23863
Date Sampled Aug 11, 2017 Aug 10, 2017 Aug 10, 2017 Aug 10, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L N090.76 < 0.05 N090.21 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 58 66 70 58
D3-N-MeFOSA (surr.) 1 % 27 51 54 47
D5-N-EtFOSA (surr.) 1 % 21 44 41 39
D7-N-MeFOSE (surr.) 1 % 37 64 59 50
D9-N-EtFOSE (surr.) 1 % 27 49 46 40
D5-N-EtFOSAA (surr.) 1 % 46 47 53 49
D3-N-MeFOSAA (surr.) 1 % 54 54 58 62
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 N090.23 N091.3
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01 0.25 N091.3
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.07 0.03 N090.96 N095.2
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 N090.02 N090.10
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.57 N090.30 N091.1 N090.18
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 81 84 81 66
18O2-PFHxS (surr.) 1 % 139 140 124 90
13C8-PFOS (surr.) 1 % 91 109 101 102
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 0.02 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 76 80 84 66
13C2-6:2 FTS (surr.) 1 % 131 111 118 96
13C2-8:2 FTS (surr.) 1 % 94 99 110 102
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.64 0.33 2.06 5.38
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.62 0.32 1.37 0.79
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.69 0.35 2.33 5.99
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.8 0.4 3.95 13.04
Sum of PFASs (n=28) 0.1 ug/L 1.67 0.4 4.48 14.46
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 9.4 9.1 8.9 8.8
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 9.3 9.1 8.7 8.5
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 25
Report Number: 568621-L
Client Sample ID 0990_BH165_2.0_170810
0990_BH167_0.0_170810
0990_BH167_1.0_170810
0990_BH167_2.0_170810
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23865 B17-Oc23867 B17-Oc23869 B17-Oc23871
Date Sampled Aug 10, 2017 Aug 10, 2017 Aug 10, 2017 Aug 10, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L 1.4 0.40 3.9 7.7
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N091.8 N090.75 N095.2 N097.4
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N098.2 N092.8 N0929 N0928
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.61 N090.97 N094.8 N092.7
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N091.7 N092.3 N0913 N095.9
Perfluorononanoic acid (PFNA)N11 0.01 ug/L N09< 0.2 N090.51 N090.26 N09< 0.2
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.2 0.13 < 0.2 < 0.2
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.2
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.2
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.2
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.2
13C4-PFBA (surr.) 1 % 116 132 129 134
13C5-PFPeA (surr.) 1 % 113 140 130 142
13C5-PFHxA (surr.) 1 % 84 106 105 111
13C4-PFHpA (surr.) 1 % 100 120 120 129
13C8-PFOA (surr.) 1 % 111 127 120 135
13C5-PFNA (surr.) 1 % 112 123 123 131
13C6-PFDA (surr.) 1 % 97 117 106 128
13C2-PFUnDA (surr.) 1 % 65 86 86 95
13C2-PFDoDA (surr.) 1 % 45 58 56 65
13C2-PFTeDA (surr.) 1 % 28 12 INT INT
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.2 N091.2 N091.1 < 0.2
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.2
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.2
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.2
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.2
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.2
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.2
13C8-FOSA (surr.) 1 % 78 104 109 110
D3-N-MeFOSA (surr.) 1 % 28 42 38 35
D5-N-EtFOSA (surr.) 1 % 25 33 26 24
D7-N-MeFOSE (surr.) 1 % 46 46 42 45
D9-N-EtFOSE (surr.) 1 % 36 29 25 25
D5-N-EtFOSAA (surr.) 1 % 71 87 85 95
D3-N-MeFOSAA (surr.) 1 % 77 94 97 105
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 2.7 N090.83 5.7 7.6
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N093.5 N091.5 N099.3 N097.6
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N0923 N097.4 N0975 N0941
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N091.2 N09< 0.2 N096.4 N091.6
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N096.9 N092.0 N09210 N095.7
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.2
13C3-PFBS (surr.) 1 % 90 113 112 116
18O2-PFHxS (surr.) 1 % 115 134 112 129
13C8-PFOS (surr.) 1 % 101 119 145 126
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 25
Report Number: 568621-L
Client Sample ID 0990_BH165_2.0_170810
0990_BH167_0.0_170810
0990_BH167_1.0_170810
0990_BH167_2.0_170810
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23865 B17-Oc23867 B17-Oc23869 B17-Oc23871
Date Sampled Aug 10, 2017 Aug 10, 2017 Aug 10, 2017 Aug 10, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.2
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L 0.22 0.44 0.75 0.25
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.2 1.8 0.37 < 0.2
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.2
13C2-4:2 FTS (surr.) 1 % 86 91 87 95
13C2-6:2 FTS (surr.) 1 % 94 98 92 100
13C2-8:2 FTS (surr.) 1 % 84 101 101 102
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 29.9 9.4 285 46.7
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 8.6 4.3 223 11.6
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 31.6 11.7 298 52.6
Sum of WA DER PFAS (n=10) 0.05 ug/L 46.53 19.69 347.72 106.25
Sum of PFASs (n=28) 0.1 ug/L 51.23 23.03 364.78 115.45
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 9.1 9.0 8.3 8.4
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 8.4 8.5 8.4 8.6
Client Sample ID 0990_BH169_1.0_170810
0990_BH171_0.5_170811
0990_BH173_0.5_170811
0990_BH193_0.5_170815
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23873 B17-Oc23875 B17-Oc23877 B17-Oc23879
Date Sampled Aug 10, 2017 Aug 11, 2017 Aug 11, 2017 Aug 15, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L 0.03 N090.01 < 0.01 N090.03
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.02 N090.02 N090.02 N090.05
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.01 N090.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.04 N090.04 N090.03 N090.02
Perfluorononanoic acid (PFNA)N11 0.01 ug/L N090.02 < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 130 134 130 129
13C5-PFPeA (surr.) 1 % 92 96 90 93
13C5-PFHxA (surr.) 1 % 65 69 65 64
13C4-PFHpA (surr.) 1 % 94 100 96 94
13C8-PFOA (surr.) 1 % 143 142 142 144
13C5-PFNA (surr.) 1 % 141 129 129 140
13C6-PFDA (surr.) 1 % 118 104 108 121
13C2-PFUnDA (surr.) 1 % 82 79 70 83
13C2-PFDoDA (surr.) 1 % 79 73 62 79
13C2-PFTeDA (surr.) 1 % 29 29 20 25
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 25
Report Number: 568621-L
Client Sample ID 0990_BH169_1.0_170810
0990_BH171_0.5_170811
0990_BH173_0.5_170811
0990_BH193_0.5_170815
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23873 B17-Oc23875 B17-Oc23877 B17-Oc23879
Date Sampled Aug 10, 2017 Aug 11, 2017 Aug 11, 2017 Aug 15, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L N090.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 70 61 54 75
D3-N-MeFOSA (surr.) 1 % 45 38 26 48
D5-N-EtFOSA (surr.) 1 % 39 31 19 39
D7-N-MeFOSE (surr.) 1 % 59 52 36 58
D9-N-EtFOSE (surr.) 1 % 46 40 28 44
D5-N-EtFOSAA (surr.) 1 % 54 54 44 49
D3-N-MeFOSAA (surr.) 1 % 63 68 54 59
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L 0.03 0.01 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.21 < 0.01 N090.04 N090.02
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 83 85 83 81
18O2-PFHxS (surr.) 1 % 141 141 142 143
13C8-PFOS (surr.) 1 % 113 97 101 112
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 73 73 71 67
13C2-6:2 FTS (surr.) 1 % 114 116 112 121
13C2-8:2 FTS (surr.) 1 % 97 97 90 99
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.24 0.01 0.05 0.02
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.25 0.04 0.07 0.04
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.28 0.05 0.08 0.04
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.34 0.09 0.1 0.12
Sum of PFASs (n=28) 0.1 ug/L 0.41 < 0.1 0.1 0.12
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 8.2 8.0 8.1 8.2
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 8.8 8.4 9.1 8.9
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 25
Report Number: 568621-L
Client Sample ID 0990_BH194_0.5_170824
0990_BH195_1.0_170824
Sample Matrix AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23881 B17-Oc23883
Date Sampled Aug 24, 2017 Aug 24, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.03 N090.03
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.04 N090.05
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 N090.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.02 N090.05
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 126 146
13C5-PFPeA (surr.) 1 % 95 102
13C5-PFHxA (surr.) 1 % 67 73
13C4-PFHpA (surr.) 1 % 95 103
13C8-PFOA (surr.) 1 % 145 146
13C5-PFNA (surr.) 1 % 134 132
13C6-PFDA (surr.) 1 % 119 117
13C2-PFUnDA (surr.) 1 % 88 74
13C2-PFDoDA (surr.) 1 % 79 71
13C2-PFTeDA (surr.) 1 % 27 29
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 68 60
D3-N-MeFOSA (surr.) 1 % 43 47
D5-N-EtFOSA (surr.) 1 % 33 40
D7-N-MeFOSE (surr.) 1 % 62 54
D9-N-EtFOSE (surr.) 1 % 47 42
D5-N-EtFOSAA (surr.) 1 % 47 52
D3-N-MeFOSAA (surr.) 1 % 56 61
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L 0.01 0.10
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.05 N090.03
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 83 91
18O2-PFHxS (surr.) 1 % 142 142
13C8-PFOS (surr.) 1 % 118 98
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 25
Report Number: 568621-L
Client Sample ID 0990_BH194_0.5_170824
0990_BH195_1.0_170824
Sample Matrix AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Oc23881 B17-Oc23883
Date Sampled Aug 24, 2017 Aug 24, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 77 82
13C2-6:2 FTS (surr.) 1 % 118 140
13C2-8:2 FTS (surr.) 1 % 105 106
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.06 0.13
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.07 0.08
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.08 0.18
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.15 0.28
Sum of PFASs (n=28) 0.1 ug/L 0.15 0.29
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0
pH (initial) 0.1 pH Units 7.8 7.8
pH (Leachate fluid) 0.1 pH Units 7.0 7.0
pH (off) 0.1 pH Units 8.7 8.6
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 25
Report Number: 568621-L
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Oct 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Oct 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Oct 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Oct 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
AUS Leaching Procedure Brisbane Oct 23, 2017 7 Days
- Method: LTM-GEN-7010 Leaching Procedure for Soils & Solid Wastes
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 11 of 25
Report Number: 568621-L
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_BH119_0.4_170712
Jul 12, 2017 Soil B17-Oc23840 X X X X
2 0990_BH119_0.4_170712
Jul 12, 2017 AUS Leachate B17-Oc23841 X X
3 0990_QCBH114_170712
Jul 12, 2017 Soil B17-Oc23842 X X X X
4 0990_QCB114_170712
Jul 12, 2017 AUS Leachate B17-Oc23843 X X
5 0990_QCBH116_170712
Jul 12, 2017 Soil B17-Oc23844 X X X X
6 0990_QCBH1 Jul 12, 2017 AUS Leachate B17-Oc23845 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 12 of 25
Report Number: 568621-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
16_170712
7 0990_BH148_0.0_170804
Aug 04, 2017 Soil B17-Oc23846 X X X X
8 0990_BH148_0.0_170804
Aug 04, 2017 AUS Leachate B17-Oc23847 X X
9 0990_BH148_0.4_170804
Aug 04, 2017 Soil B17-Oc23848 X X X X
10 0990_BH148_0.4_170804
Aug 04, 2017 AUS Leachate B17-Oc23849 X X
11 0990_BH149_0.5_170808
Aug 04, 2017 Soil B17-Oc23850 X X X X
12 0990_BH149_0.5_170808
Aug 08, 2017 AUS Leachate B17-Oc23851 X X
13 0990_BH150_ Aug 08, 2017 Soil B17-Oc23852 X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 13 of 25
Report Number: 568621-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
0.0_170808
14 0990_BH150_0.0_170808
Aug 08, 2017 AUS Leachate B17-Oc23853 X X
15 0990_BH175_0.0_170811
Aug 11, 2017 Soil B17-Oc23854 X X X X
16 0990_BH175_0.0_170811
Aug 11, 2017 AUS Leachate B17-Oc23855 X X
17 0990_BH175_0.2_170811
Aug 11, 2017 Soil B17-Oc23856 X X X X
18 0990_BH175_0.2_170811
Aug 11, 2017 AUS Leachate B17-Oc23857 X X
19 0990_BH164_2.0_170810
Aug 10, 2017 Soil B17-Oc23858 X X X X
20 0990_BH164_ Aug 10, 2017 AUS Leachate B17-Oc23859 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 14 of 25
Report Number: 568621-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
2.0_170810
21 0990_BH165_0.0_170810
Aug 10, 2017 Soil B17-Oc23860 X X X X
22 0990_BH165_0.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23861 X X
23 0990_BH165_1.0_170810
Aug 10, 2017 Soil B17-Oc23862 X X X X
24 0990_BH165_1.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23863 X X
25 0990_BH165_2.0_170810
Aug 10, 2017 Soil B17-Oc23864 X X X X
26 0990_BH165_2.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23865 X X
27 0990_BH167_ Aug 10, 2017 Soil B17-Oc23866 X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 15 of 25
Report Number: 568621-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
0.0_170810
28 0990_BH167_0.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23867 X X
29 0990_BH167_1.0_170810
Aug 10, 2017 Soil B17-Oc23868 X X X X
30 0990_BH167_1.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23869 X X
31 0990_BH167_2.0_170810
Aug 10, 2017 Soil B17-Oc23870 X X X X
32 0990_BH167_2.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23871 X X
33 0990_BH169_1.0_170810
Aug 10, 2017 Soil B17-Oc23872 X X X X
34 0990_BH169_ Aug 10, 2017 AUS Leachate B17-Oc23873 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 16 of 25
Report Number: 568621-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
1.0_170810
35 0990_BH171_0.5_170811
Aug 11, 2017 Soil B17-Oc23874 X X X X
36 0990_BH171_0.5_170811
Aug 11, 2017 AUS Leachate B17-Oc23875 X X
37 0990_BH173_0.5_170811
Aug 11, 2017 Soil B17-Oc23876 X X X X
38 0990_BH173_0.5_170811
Aug 11, 2017 AUS Leachate B17-Oc23877 X X
39 0990_BH193_0.5_170815
Aug 15, 2017 Soil B17-Oc23878 X X X X
40 0990_BH193_0.5_170815
Aug 15, 2017 AUS Leachate B17-Oc23879 X X
41 0990_BH194_ Aug 24, 2017 Soil B17-Oc23880 X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 17 of 25
Report Number: 568621-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
0.5_170824
42 0990_BH194_0.5_170824
Aug 24, 2017 AUS Leachate B17-Oc23881 X X
43 0990_BH195_1.0_170824
Aug 24, 2017 Soil B17-Oc23882 X X X X
44 0990_BH195_1.0_170824
Aug 24, 2017 AUS Leachate B17-Oc23883 X X
Test Counts 22 22 22 22 22 22
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 18 of 25
Report Number: 568621-L
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 19 of 25
Report Number: 568621-L
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Oc23843 CP ug/L 0.16 0.17 1.0 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Oc23843 CP ug/L 0.16 0.16 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Oc23843 CP ug/L 0.36 0.36 1.0 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Oc23843 CP ug/L 0.09 0.09 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Oc23843 CP ug/L 0.30 0.29 2.0 30% Pass
Perfluorononanoic acid (PFNA) B17-Oc23843 CP ug/L 0.03 0.03 13 30% Pass
Perfluorodecanoic acid (PFDA) B17-Oc23843 CP ug/L 0.04 0.04 7.0 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Oc23843 CP ug/L 0.02 0.02 6.0 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Oc23843 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Oc23843 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Oc23843 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 20 of 25
Report Number: 568621-L
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Oc23843 CP ug/L 0.16 0.13 23 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Oc23843 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Oc23843 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Oc23843 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Oc23843 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Oc23843 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Oc23843 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Oc23843 CP ug/L 0.07 0.07 4.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Oc23843 CP ug/L 0.10 0.10 1.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Oc23843 CP ug/L 0.60 0.52 14 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Oc23843 CP ug/L 0.03 0.02 18 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Oc23843 CP ug/L 1.9 1.5 22 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Oc23843 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Oc23843 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Oc23843 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Oc23843 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Oc23843 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Oc23855 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Oc23855 CP ug/L 0.05 0.05 7.0 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Oc23855 CP ug/L 0.09 0.08 5.0 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Oc23855 CP ug/L 0.02 0.02 7.0 30% Pass
Perfluorooctanoic acid (PFOA) B17-Oc23855 CP ug/L 0.07 0.06 4.0 30% Pass
Perfluorononanoic acid (PFNA) B17-Oc23855 CP ug/L 0.03 0.02 5.0 30% Pass
Perfluorodecanoic acid (PFDA) B17-Oc23855 CP ug/L 0.15 0.14 11 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Oc23855 CP ug/L 0.07 0.06 13 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Oc23855 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Oc23855 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Oc23855 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 21 of 25
Report Number: 568621-L
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Oc23855 CP ug/L 0.06 0.06 1.0 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Oc23855 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Oc23855 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Oc23855 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Oc23855 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Oc23855 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Oc23855 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Oc23855 CP ug/L 0.01 0.01 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Oc23855 CP ug/L 0.02 0.02 3.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Oc23855 CP ug/L 0.07 0.08 12 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Oc23855 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Oc23855 CP ug/L 0.04 0.03 26 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Oc23855 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Oc23855 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Oc23855 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Oc23855 CP ug/L 0.01 0.01 3.0 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Oc23855 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Oc23857 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Oc23857 CP ug/L 0.03 0.03 3.0 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Oc23857 CP ug/L 0.06 0.06 4.0 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Oc23857 CP ug/L 0.02 0.02 4.0 30% Pass
Perfluorooctanoic acid (PFOA) B17-Oc23857 CP ug/L 0.05 0.05 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Oc23857 CP ug/L 0.03 0.02 6.0 30% Pass
Perfluorodecanoic acid (PFDA) B17-Oc23857 CP ug/L 0.06 0.07 2.0 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Oc23857 CP ug/L 0.02 0.02 1.0 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Oc23857 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Oc23857 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Oc23857 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 22 of 25
Report Number: 568621-L
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Oc23857 CP ug/L 0.76 0.71 7.0 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Oc23857 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Oc23857 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Oc23857 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Oc23857 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Oc23857 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Oc23857 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Oc23857 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Oc23857 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Oc23857 CP ug/L 0.07 0.08 8.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Oc23857 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Oc23857 CP ug/L 0.57 0.56 2.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Oc23857 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Oc23857 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Oc23857 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Oc23857 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Oc23857 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Oc23875 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Oc23875 CP ug/L 0.01 0.02 10 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Oc23875 CP ug/L 0.02 0.02 3.0 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Oc23875 CP ug/L 0.01 0.01 4.0 30% Pass
Perfluorooctanoic acid (PFOA) B17-Oc23875 CP ug/L 0.04 0.05 6.0 30% Pass
Perfluorononanoic acid (PFNA) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 23 of 25
Report Number: 568621-L
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Oc23875 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Oc23875 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Oc23875 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Oc23875 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Oc23875 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Oc23875 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Oc23875 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Oc23875 CP ug/L 0.01 0.02 18 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Oc23875 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Oc23875 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 24 of 25
Report Number: 568621-L
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionC01 Leachate Fluid Key: 1 - pH 5.0; 2 - pH 2.9; 3 - pH 9.2; 4 - Reagent (DI) water; 5 - Client sample, 6 - other
N09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 25 of 25
Report Number: 568621-L
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 568621-S
Project name DOD TINDAL
Project ID ADDITIONAL ANALYSIS
Received Date Oct 19, 2017
Client Sample ID 0990_BH119_0.4_170712
0990_QCBH114_170712
0990_QCBH116_170712
0990_BH148_0.0_170804
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. B17-Oc23840 B17-Oc23842 B17-Oc23844 B17-Oc23846
Date Sampled Jul 12, 2017 Jul 12, 2017 Jul 12, 2017 Aug 04, 2017
Test/Reference LOR Unit
% Clay 1 % 5.0 21 5.3 20
pH (1:5 Aqueous extract) 0.1 pH Units 7.0 6.8 6.9 7.7
Total Organic Carbon 0.1 % 0.9 1.0 1.9 0.7
% Moisture 1 % < 1 10 19 5.1
Client Sample ID 0990_BH148_0.4_170804
0990_BH149_0.5_170808
0990_BH150_0.0_170808
0990_BH175_0.0_170811
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. B17-Oc23848 B17-Oc23850 B17-Oc23852 B17-Oc23854
Date Sampled Aug 04, 2017 Aug 04, 2017 Aug 08, 2017 Aug 11, 2017
Test/Reference LOR Unit
% Clay 1 % 24 < 1 6.8 6.2
pH (1:5 Aqueous extract) 0.1 pH Units 7.9 8.4 8.3 8.4
Total Organic Carbon 0.1 % 0.4 < 0.1 0.4 1.5
% Moisture 1 % 8.8 6.6 1.3 1.3
Client Sample ID 0990_BH175_0.2_170811
0990_BH164_2.0_170810
0990_BH165_0.0_170810
0990_BH165_1.0_170810
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. B17-Oc23856 B17-Oc23858 B17-Oc23860 B17-Oc23862
Date Sampled Aug 11, 2017 Aug 10, 2017 Aug 10, 2017 Aug 10, 2017
Test/Reference LOR Unit
% Clay 1 % 14 11 13 14
pH (1:5 Aqueous extract) 0.1 pH Units 9.1 8.0 7.9 7.7
Total Organic Carbon 0.1 % 1.8 < 0.1 0.1 < 0.1
% Moisture 1 % 2.6 12 5.1 8.4
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 13
Report Number: 568621-S
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_BH165_2.0_170810
0990_BH167_0.0_170810
0990_BH167_1.0_170810
0990_BH167_2.0_170810
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. B17-Oc23864 B17-Oc23866 B17-Oc23868 B17-Oc23870
Date Sampled Aug 10, 2017 Aug 10, 2017 Aug 10, 2017 Aug 10, 2017
Test/Reference LOR Unit
% Clay 1 % 53 14 55 41
pH (1:5 Aqueous extract) 0.1 pH Units 8.2 8.0 8.1 8.5
Total Organic Carbon 0.1 % 0.4 1.4 < 0.1 < 0.1
% Moisture 1 % 18 2.8 11 14
Client Sample ID 0990_BH169_1.0_170810
0990_BH171_0.5_170811
0990_BH173_0.5_170811
0990_BH193_0.5_170815
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. B17-Oc23872 B17-Oc23874 B17-Oc23876 B17-Oc23878
Date Sampled Aug 10, 2017 Aug 11, 2017 Aug 11, 2017 Aug 15, 2017
Test/Reference LOR Unit
% Clay 1 % 14 29 < 1 9.9
pH (1:5 Aqueous extract) 0.1 pH Units 8.3 8.1 8.9 8.4
Total Organic Carbon 0.1 % < 0.1 < 0.1 < 0.1 0.3
% Moisture 1 % 7.6 9.6 1.6 7.5
Client Sample ID 0990_BH194_0.5_170824
0990_BH195_1.0_170824
Sample Matrix Soil Soil
Eurofins | mgt Sample No. B17-Oc23880 B17-Oc23882
Date Sampled Aug 24, 2017 Aug 24, 2017
Test/Reference LOR Unit
% Clay 1 % 21 28
pH (1:5 Aqueous extract) 0.1 pH Units 8.1 8.0
Total Organic Carbon 0.1 % 0.3 < 0.1
% Moisture 1 % 7.0 9.2
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 13
Report Number: 568621-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
% Clay Brisbane Oct 23, 2017 6 Day
- Method: LTM-GEN-7040
pH (1:5 Aqueous extract) Melbourne Oct 23, 2017 7 Day
- Method: LTM-GEN-7090 pH in soil by ISE
Total Organic Carbon Melbourne Oct 23, 2017 28 Day
- Method: APHA 5310B Total Organic Carbon
% Moisture Melbourne Oct 20, 2017 14 Day
- Method: LTM-GEN-7080 Moisture
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 13
Report Number: 568621-S
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_BH119_0.4_170712
Jul 12, 2017 Soil B17-Oc23840 X X X X
2 0990_BH119_0.4_170712
Jul 12, 2017 AUS Leachate B17-Oc23841 X X
3 0990_QCBH114_170712
Jul 12, 2017 Soil B17-Oc23842 X X X X
4 0990_QCB114_170712
Jul 12, 2017 AUS Leachate B17-Oc23843 X X
5 0990_QCBH116_170712
Jul 12, 2017 Soil B17-Oc23844 X X X X
6 0990_QCBH1 Jul 12, 2017 AUS Leachate B17-Oc23845 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 13
Report Number: 568621-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
16_170712
7 0990_BH148_0.0_170804
Aug 04, 2017 Soil B17-Oc23846 X X X X
8 0990_BH148_0.0_170804
Aug 04, 2017 AUS Leachate B17-Oc23847 X X
9 0990_BH148_0.4_170804
Aug 04, 2017 Soil B17-Oc23848 X X X X
10 0990_BH148_0.4_170804
Aug 04, 2017 AUS Leachate B17-Oc23849 X X
11 0990_BH149_0.5_170808
Aug 04, 2017 Soil B17-Oc23850 X X X X
12 0990_BH149_0.5_170808
Aug 08, 2017 AUS Leachate B17-Oc23851 X X
13 0990_BH150_ Aug 08, 2017 Soil B17-Oc23852 X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 13
Report Number: 568621-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
0.0_170808
14 0990_BH150_0.0_170808
Aug 08, 2017 AUS Leachate B17-Oc23853 X X
15 0990_BH175_0.0_170811
Aug 11, 2017 Soil B17-Oc23854 X X X X
16 0990_BH175_0.0_170811
Aug 11, 2017 AUS Leachate B17-Oc23855 X X
17 0990_BH175_0.2_170811
Aug 11, 2017 Soil B17-Oc23856 X X X X
18 0990_BH175_0.2_170811
Aug 11, 2017 AUS Leachate B17-Oc23857 X X
19 0990_BH164_2.0_170810
Aug 10, 2017 Soil B17-Oc23858 X X X X
20 0990_BH164_ Aug 10, 2017 AUS Leachate B17-Oc23859 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 13
Report Number: 568621-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
2.0_170810
21 0990_BH165_0.0_170810
Aug 10, 2017 Soil B17-Oc23860 X X X X
22 0990_BH165_0.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23861 X X
23 0990_BH165_1.0_170810
Aug 10, 2017 Soil B17-Oc23862 X X X X
24 0990_BH165_1.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23863 X X
25 0990_BH165_2.0_170810
Aug 10, 2017 Soil B17-Oc23864 X X X X
26 0990_BH165_2.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23865 X X
27 0990_BH167_ Aug 10, 2017 Soil B17-Oc23866 X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 13
Report Number: 568621-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
0.0_170810
28 0990_BH167_0.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23867 X X
29 0990_BH167_1.0_170810
Aug 10, 2017 Soil B17-Oc23868 X X X X
30 0990_BH167_1.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23869 X X
31 0990_BH167_2.0_170810
Aug 10, 2017 Soil B17-Oc23870 X X X X
32 0990_BH167_2.0_170810
Aug 10, 2017 AUS Leachate B17-Oc23871 X X
33 0990_BH169_1.0_170810
Aug 10, 2017 Soil B17-Oc23872 X X X X
34 0990_BH169_ Aug 10, 2017 AUS Leachate B17-Oc23873 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 13
Report Number: 568621-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
1.0_170810
35 0990_BH171_0.5_170811
Aug 11, 2017 Soil B17-Oc23874 X X X X
36 0990_BH171_0.5_170811
Aug 11, 2017 AUS Leachate B17-Oc23875 X X
37 0990_BH173_0.5_170811
Aug 11, 2017 Soil B17-Oc23876 X X X X
38 0990_BH173_0.5_170811
Aug 11, 2017 AUS Leachate B17-Oc23877 X X
39 0990_BH193_0.5_170815
Aug 15, 2017 Soil B17-Oc23878 X X X X
40 0990_BH193_0.5_170815
Aug 15, 2017 AUS Leachate B17-Oc23879 X X
41 0990_BH194_ Aug 24, 2017 Soil B17-Oc23880 X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 13
Report Number: 568621-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 19, 2017 8:53 AMAddress: Level 1, 436 Johnston Street Report #: 568621 Due: Oct 26, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: ADDITIONAL ANALYSIS
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
% C
lay
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
0.5_170824
42 0990_BH194_0.5_170824
Aug 24, 2017 AUS Leachate B17-Oc23881 X X
43 0990_BH195_1.0_170824
Aug 24, 2017 Soil B17-Oc23882 X X X X
44 0990_BH195_1.0_170824
Aug 24, 2017 AUS Leachate B17-Oc23883 X X
Test Counts 22 22 22 22 22 22
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 13
Report Number: 568621-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 11 of 13
Report Number: 568621-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
% Clay % < 1 1 Pass
Total Organic Carbon % < 0.1 0.1 Pass
LCS - % Recovery
% Clay % 89 70-130 Pass
Total Organic Carbon % 105 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Result 1 Result 2 RPD
Total Organic Carbon B17-Oc23876 CP % < 0.1 < 0.1 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
pH (1:5 Aqueous extract) B17-Oc23878 CP pH Units 8.4 8.3 pass 30% Pass
Duplicate
Result 1 Result 2 RPD
% Clay B17-Oc23880 CP % 21 23 6.0 30% Pass
Duplicate
Result 1 Result 2 RPD
% Clay B17-Oc23882 CP % 28 26 5.0 30% Pass
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 12 of 13
Report Number: 568621-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Inorganic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Oct 30, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 13 of 13
Report Number: 568621-S
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 557977-L
Project name ADDITIONAL ANALYSIS: DOD TINDAL
Project ID 754_MELEN199420
Received Date Aug 10, 2017
Client Sample ID0990_BH115_0.0_170712(JL20193)
0990_BH115_0.5_170712(JL20194)
0990_BH117_1.5_170713(JL20200)
0990_SS127_170712(JL20201)
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Au12519 B17-Au12520 B17-Au12521 B17-Au12522
Date Sampled Jul 12, 2017 Jul 12, 2017 Jul 13, 2017 Jul 12, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L 95 3.6 0.22 0.30
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N09390 N0914 N090.58 0.48
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N092800 N09100 N092.2 N091.1
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N09160 N0923 N090.33 N090.41
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N09130 N0942 N091.00 N091.4
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.2 < 0.2 N090.05 N091.1
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.2 < 0.2 0.02 2.2
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.2 < 0.2 < 0.01 0.21
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.2 < 0.2 < 0.01 < 0.2
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.2 < 0.2 < 0.01 < 0.2
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.2 < 0.2 < 0.01 < 0.2
13C4-PFBA (surr.) 1 % 42 71 141 73
13C5-PFPeA (surr.) 1 % 50 62 118 65
13C5-PFHxA (surr.) 1 % 55 68 104 82
13C4-PFHpA (surr.) 1 % 32 65 96 73
13C8-PFOA (surr.) 1 % 37 65 130 76
13C5-PFNA (surr.) 1 % 34 55 125 58
13C6-PFDA (surr.) 1 % 37 54 57 66
13C2-PFUnDA (surr.) 1 % 42 70 79 72
13C2-PFDoDA (surr.) 1 % 44 64 105 80
13C2-PFTeDA (surr.) 1 % 11 15 70 24
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.2 < 0.2 < 0.05 0.25
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.2 < 0.2 < 0.05 < 0.2
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.2 < 0.2 < 0.05 < 0.2
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.2 < 0.2 < 0.05 < 0.2
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.2 < 0.2 < 0.05 < 0.2
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.2 < 0.2 < 0.05 < 0.2
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.2 < 0.2 < 0.05 < 0.2
13C8-FOSA (surr.) 1 % 47 79 107 80
D3-N-MeFOSA (surr.) 1 % 32 47 71 51
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 15
Report Number: 557977-L
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID0990_BH115_0.0_170712(JL20193)
0990_BH115_0.5_170712(JL20194)
0990_BH117_1.5_170713(JL20200)
0990_SS127_170712(JL20201)
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Au12519 B17-Au12520 B17-Au12521 B17-Au12522
Date Sampled Jul 12, 2017 Jul 12, 2017 Jul 13, 2017 Jul 12, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 18 26 42 28
D7-N-MeFOSE (surr.) 1 % 34 50 60 54
D9-N-EtFOSE (surr.) 1 % 28 42 66 49
D5-N-EtFOSAA (surr.) 1 % 40 66 77 68
D3-N-MeFOSAA (surr.) 1 % 40 68 88 74
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L N091400 N0948 0.63 < 0.2
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N09920 N0969 N090.67 < 0.2
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N09610 N09450 N093.4 N091.4
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N0939 N0953 N090.28 N091.2
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N0949 N09100 N0996 N09110
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.2 < 0.2 N090.05 N090.58
13C3-PFBS (surr.) 1 % 46 59 90 69
18O2-PFHxS (surr.) 1 % 62 98 92 88
13C8-PFOS (surr.) 1 % 48 75 73 89
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.2 < 0.2 < 0.01 < 0.2
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L 1.5 0.86 < 0.05 < 0.2
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.2 < 0.2 0.07 16
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.2 < 0.2 < 0.01 < 0.2
13C2-4:2 FTS (surr.) 1 % 27 47 198 52
13C2-6:2 FTS (surr.) 1 % 28 44 113 50
13C2-8:2 FTS (surr.) 1 % 27 41 73 48
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 659 550 99.4 111.4
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 179 142 97 111.4
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 789 592 100.4 112.8
Sum of WA DER PFAS (n=10) 0.05 ug/L 5635.5 781.46 104.43 131.09
Sum of PFASs (n=28) 0.1 ug/L 6594.5 903.46 105.5 136.63
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 8.3 8.1 8.0 7.7
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 8.9 8.8 9.1 8.5
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 15
Report Number: 557977-L
Client Sample ID0990_BH121_0.2_170713(JL20205)
0990_BH123_0.2_170713(JL20209)
0990_SS130_170712(JL20216)
0990_SS131_170712(JL20217)
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Au12523 B17-Au12524 B17-Au12525 B17-Au12526
Date Sampled Jul 13, 2017 Jul 13, 2017 Jul 12, 2017 Jul 12, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 0.08 < 0.05 0.06
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L 0.01 N090.08 N090.01 N090.09
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L 0.03 N090.13 N090.02 N090.20
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 N090.02 < 0.01 N090.04
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.04 N090.07 N090.02 N090.14
Perfluorononanoic acid (PFNA)N11 0.01 ug/L N090.01 < 0.01 0.03 0.10
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 0.05
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 141 141 146 133
13C5-PFPeA (surr.) 1 % 122 121 127 119
13C5-PFHxA (surr.) 1 % 136 131 135 129
13C4-PFHpA (surr.) 1 % 93 108 101 97
13C8-PFOA (surr.) 1 % 137 125 126 134
13C5-PFNA (surr.) 1 % 117 106 108 110
13C6-PFDA (surr.) 1 % 91 81 85 78
13C2-PFUnDA (surr.) 1 % 81 76 73 81
13C2-PFDoDA (surr.) 1 % 83 84 71 96
13C2-PFTeDA (surr.) 1 % 58 50 54 58
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 0.06
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 102 89 97 105
D3-N-MeFOSA (surr.) 1 % 47 51 49 52
D5-N-EtFOSA (surr.) 1 % 27 32 30 31
D7-N-MeFOSE (surr.) 1 % 49 43 36 53
D9-N-EtFOSE (surr.) 1 % 51 55 49 58
D5-N-EtFOSAA (surr.) 1 % 72 62 63 67
D3-N-MeFOSAA (surr.) 1 % 75 73 66 77
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 0.01 0.01 0.08
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 N090.01 < 0.01 N090.07
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.03 N090.08 N090.03 N090.55
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 N090.03 < 0.01 N090.09
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N091.1 N090.92 N090.64 N0914
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 N090.17
13C3-PFBS (surr.) 1 % 97 103 101 99
18O2-PFHxS (surr.) 1 % 153 143 143 134
13C8-PFOS (surr.) 1 % 83 81 83 106
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 15
Report Number: 557977-L
Client Sample ID0990_BH121_0.2_170713(JL20205)
0990_BH123_0.2_170713(JL20209)
0990_SS130_170712(JL20216)
0990_SS131_170712(JL20217)
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Au12523 B17-Au12524 B17-Au12525 B17-Au12526
Date Sampled Jul 13, 2017 Jul 13, 2017 Jul 12, 2017 Jul 12, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L 0.01 < 0.01 < 0.01 0.07
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 194 168 186 199
13C2-6:2 FTS (surr.) 1 % 116 109 105 120
13C2-8:2 FTS (surr.) 1 % 75 62 61 77
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 1.13 1 0.67 14.55
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 1.14 0.99 0.66 14.14
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 1.17 1.07 0.69 14.69
Sum of WA DER PFAS (n=10) 0.05 ug/L 1.22 1.39 0.73 15.23
Sum of PFASs (n=28) 0.1 ug/L 1.23 1.43 0.76 15.78
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 7.7 7.5 7.5 7.2
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 7.6 7.2 7.0 5.6
Client Sample ID0990_MW104_1.0_170719(JL27865)
0990_MW105_0.4_170719(JL27867)
0990_SS125_170711(JL16783)
Sample Matrix AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Au12527 B17-Au12528 B17-Au12529
Date Sampled Jul 19, 2017 Jul 19, 2017 Jul 12, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L 0.08 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L 0.05 0.04 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.12 N090.11 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.02 N090.02 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.13 N090.09 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L N090.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 144 139 145
13C5-PFPeA (surr.) 1 % 127 129 119
13C5-PFHxA (surr.) 1 % 133 108 132
13C4-PFHpA (surr.) 1 % 100 113 98
13C8-PFOA (surr.) 1 % 132 114 119
13C5-PFNA (surr.) 1 % 117 119 100
13C6-PFDA (surr.) 1 % 81 99 82
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 15
Report Number: 557977-L
Client Sample ID0990_MW104_1.0_170719(JL27865)
0990_MW105_0.4_170719(JL27867)
0990_SS125_170711(JL16783)
Sample Matrix AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Au12527 B17-Au12528 B17-Au12529
Date Sampled Jul 19, 2017 Jul 19, 2017 Jul 12, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C2-PFUnDA (surr.) 1 % 82 100 76
13C2-PFDoDA (surr.) 1 % 86 93 79
13C2-PFTeDA (surr.) 1 % 69 64 54
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 107 106 88
D3-N-MeFOSA (surr.) 1 % 56 66 46
D5-N-EtFOSA (surr.) 1 % 32 37 26
D7-N-MeFOSE (surr.) 1 % 40 50 47
D9-N-EtFOSE (surr.) 1 % 57 60 49
D5-N-EtFOSAA (surr.) 1 % 68 77 65
D3-N-MeFOSAA (surr.) 1 % 71 80 70
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.05 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.05 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.49 N090.07 N090.04
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.04 0.03 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N0925 N093.7 N090.40
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 101 103 98
18O2-PFHxS (surr.) 1 % 135 149 139
13C8-PFOS (surr.) 1 % 86 79 86
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 186 201 184
13C2-6:2 FTS (surr.) 1 % 114 144 99
13C2-8:2 FTS (surr.) 1 % 72 125 65
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 25.49 3.77 0.44
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 25.13 3.79 0.4
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 25.62 3.86 0.44
Sum of WA DER PFAS (n=10) 0.05 ug/L 25.94 4.03 0.44
Sum of PFASs (n=28) 0.1 ug/L 26.04 4.06 0.44
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 15
Report Number: 557977-L
Client Sample ID0990_MW104_1.0_170719(JL27865)
0990_MW105_0.4_170719(JL27867)
0990_SS125_170711(JL16783)
Sample Matrix AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Au12527 B17-Au12528 B17-Au12529
Date Sampled Jul 19, 2017 Jul 19, 2017 Jul 12, 2017
Test/Reference LOR Unit
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0
pH (initial) 0.1 pH Units 7.3 7.2 7.5
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0
pH (off) 0.1 pH Units 6.5 6.4 8.3
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 15
Report Number: 557977-L
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
AUS Leaching Procedure Brisbane Aug 17, 2017 7 Days
- Method: LTM-GEN-7010 Leaching Procedure for Soils & Solid Wastes
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 15
Report Number: 557977-L
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 10, 2017 9:00 AMAddress: 3G Marine Pde Report #: 557977 Due: Aug 17, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: ADDITIONAL ANALYSIS: DOD TINDALProject ID: 754_MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
AU
S Leaching P
rocedure
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_BH115_0.0_170712(JL20193)
Jul 12, 2017 AUS Leachate B17-Au12519X X
2 0990_BH115_0.5_170712(JL20194)
Jul 12, 2017 AUS Leachate B17-Au12520X X
3 0990_BH117_1.5_170713(JL20200)
Jul 13, 2017 AUS Leachate B17-Au12521X X
4 0990_SS127_170712(JL20201)
Jul 12, 2017 AUS Leachate B17-Au12522X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 15
Report Number: 557977-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 10, 2017 9:00 AMAddress: 3G Marine Pde Report #: 557977 Due: Aug 17, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: ADDITIONAL ANALYSIS: DOD TINDALProject ID: 754_MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
AU
S Leaching P
rocedure
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
5 0990_BH121_0.2_170713(JL20205)
Jul 13, 2017 AUS Leachate B17-Au12523X X
6 0990_BH123_0.2_170713(JL20209)
Jul 13, 2017 AUS Leachate B17-Au12524X X
7 0990_SS130_170712(JL20216)
Jul 12, 2017 AUS Leachate B17-Au12525X X
8 0990_SS131_170712(JL20217)
Jul 12, 2017 AUS Leachate B17-Au12526X X
9 0990_MW104_1.0_170719(JL27865)
Jul 19, 2017 AUS Leachate B17-Au12527X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 15
Report Number: 557977-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 10, 2017 9:00 AMAddress: 3G Marine Pde Report #: 557977 Due: Aug 17, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: ADDITIONAL ANALYSIS: DOD TINDALProject ID: 754_MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
AU
S Leaching P
rocedure
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
10 0990_MW105_0.4_170719(JL27867)
Jul 19, 2017 AUS Leachate B17-Au12528X X
11 0990_SS125_170711(JL16783)
Jul 12, 2017 AUS Leachate B17-Au12529X X
Test Counts 11 11
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 15
Report Number: 557977-L
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 11 of 15
Report Number: 557977-L
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Au12523 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Au12523 CP ug/L 0.01 0.01 8.0 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Au12523 CP ug/L 0.03 0.03 11 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Au12523 CP ug/L < 0.01 0.01 3.0 30% Pass
Perfluorooctanoic acid (PFOA) B17-Au12523 CP ug/L 0.04 0.04 11 30% Pass
Perfluorononanoic acid (PFNA) B17-Au12523 CP ug/L 0.01 0.01 14 30% Pass
Perfluorodecanoic acid (PFDA) B17-Au12523 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Au12523 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Au12523 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Au12523 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Au12523 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 12 of 15
Report Number: 557977-L
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Au12523 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Au12523 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Au12523 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Au12523 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Au12523 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Au12523 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Au12523 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Au12523 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Au12523 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Au12523 CP ug/L 0.03 0.03 7.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Au12523 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Au12523 CP ug/L 1.1 1.3 15 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Au12523 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Au12523 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Au12523 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Au12523 CP ug/L 0.01 0.02 35 30% Fail Q15
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Au12523 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Au12529 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 13 of 15
Report Number: 557977-L
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Au12529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Au12529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Au12529 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Au12529 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Au12529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Au12529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Au12529 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Au12529 CP ug/L 0.04 0.04 2.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Au12529 CP ug/L 0.40 0.41 2.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Au12529 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Au12529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 14 of 15
Report Number: 557977-L
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionC01 Leachate Fluid Key: 1 - pH 5.0; 2 - pH 2.9; 3 - pH 9.2; 4 - Reagent (DI) water; 5 - Client sample, 6 - other
N09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q15 The RPD reported passes Eurofins | mgt's QC - Acceptance Criteria as defined in the Internal Quality Control Review and Glossary page of this report.
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 15 of 15
Report Number: 557977-L
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 558047-L
Project name ADDITIONAL ANALYSIS: DOD TINDAL
Project ID 754_MELEN199420
Received Date Aug 10, 2017
Client Sample ID0990_SS113_170711(JL16771)
0990_SS114_170711(JL16772)
0990_SS116_170711(JL16780)
Sample Matrix AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Au12877 B17-Au12878 B17-Au12879
Date Sampled Jul 11, 2017 Jul 11, 2017 Jul 11, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L 5.4 4.9 7.2
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N0918 N0915 N0911
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N0981 N0948 N0918
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N09370 N0934 N0917
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N091100 N09140 N0928
Perfluorononanoic acid (PFNA)N11 0.01 ug/L 490 100 36
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L 71 4.3 7.9
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L 21 < 2 0.56
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L 5.5 < 2 0.45
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 2 < 2 0.22
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 2 < 2 0.60
13C4-PFBA (surr.) 1 % 78 85 91
13C5-PFPeA (surr.) 1 % 70 76 82
13C5-PFHxA (surr.) 1 % 88 97 107
13C4-PFHpA (surr.) 1 % 63 79 92
13C8-PFOA (surr.) 1 % 64 84 97
13C5-PFNA (surr.) 1 % 55 70 78
13C6-PFDA (surr.) 1 % 50 70 92
13C2-PFUnDA (surr.) 1 % 75 88 96
13C2-PFDoDA (surr.) 1 % 83 96 92
13C2-PFTeDA (surr.) 1 % 75 84 21
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L 16 < 2 0.46
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 2 < 2 < 0.2
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 2 < 2 < 0.2
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 2 < 2 < 0.2
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 2 < 2 < 0.2
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 2 < 2 < 0.2
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 2 < 2 < 0.2
13C8-FOSA (surr.) 1 % 86 93 119
D3-N-MeFOSA (surr.) 1 % 62 75 68
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 8
Report Number: 558047-L
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID0990_SS113_170711(JL16771)
0990_SS114_170711(JL16772)
0990_SS116_170711(JL16780)
Sample Matrix AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. B17-Au12877 B17-Au12878 B17-Au12879
Date Sampled Jul 11, 2017 Jul 11, 2017 Jul 11, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 40 51 36
D7-N-MeFOSE (surr.) 1 % 69 77 66
D9-N-EtFOSE (surr.) 1 % 70 85 55
D5-N-EtFOSAA (surr.) 1 % 76 84 90
D3-N-MeFOSAA (surr.) 1 % 74 86 96
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 2.5 < 2 4.1
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N0945 N094.5 N093.1
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N09690 N09150 N0915
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N09200 N0954 N092.6
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N093100 N091100 N0970
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L 26 N0910 < 0.2
13C3-PFBS (surr.) 1 % 74 82 90
18O2-PFHxS (surr.) 1 % 74 98 115
13C8-PFOS (surr.) 1 % 103 82 92
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 2 < 2 < 0.2
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L 1100 28 2.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L 730 110 20
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L 3.9 < 2 < 0.2
13C2-4:2 FTS (surr.) 1 % 66 63 78
13C2-6:2 FTS (surr.) 1 % 61 58 72
13C2-8:2 FTS (surr.) 1 % 51 58 70
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 3790 1250 85
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 4200 1240 98
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 4890 1390 113
Sum of WA DER PFAS (n=10) 0.05 ug/L 7196.9 1629.9 192.8
Sum of PFASs (n=28) 0.1 ug/L 8075.3 1802.7 244.69
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0
pH (initial) 0.1 pH Units 8.3 7.2 6.7
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0
pH (off) 0.1 pH Units 6.1 6.3 7.4
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 8
Report Number: 558047-L
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
AUS Leaching Procedure Brisbane Aug 17, 2017 7 Days
- Method: LTM-GEN-7010 Leaching Procedure for Soils & Solid Wastes
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 8
Report Number: 558047-L
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 10, 2017 9:00 AMAddress: 3G Marine Pde Report #: 558047 Due: Aug 17, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: ADDITIONAL ANALYSIS: DOD TINDALProject ID: 754_MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
AU
S Leaching P
rocedure
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_SS113_170711(JL16771)
Jul 11, 2017 AUS Leachate B17-Au12877X X
2 0990_SS114_170711(JL16772)
Jul 11, 2017 AUS Leachate B17-Au12878X X
3 0990_SS116_170711(JL16780)
Jul 11, 2017 AUS Leachate B17-Au12879X X
Test Counts 3 3
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 8
Report Number: 558047-L
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 8
Report Number: 558047-L
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Au12523 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Au12523 NCP ug/L 0.01 0.01 8.0 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Au12523 NCP ug/L 0.03 0.03 11 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Au12523 NCP ug/L 0.01 0.01 3.0 30% Pass
Perfluorooctanoic acid (PFOA) B17-Au12523 NCP ug/L 0.04 0.04 11 30% Pass
Perfluorononanoic acid (PFNA) B17-Au12523 NCP ug/L 0.01 0.01 14 30% Pass
Perfluorodecanoic acid (PFDA) B17-Au12523 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Au12523 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Au12523 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Au12523 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Au12523 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 8
Report Number: 558047-L
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Au12523 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Au12523 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Au12523 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Au12523 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Au12523 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Au12523 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Au12523 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Au12523 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Au12523 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Au12523 NCP ug/L 0.03 0.03 7.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Au12523 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Au12523 NCP ug/L 1.1 1.3 15 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Au12523 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Au12523 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Au12523 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Au12523 NCP ug/L 0.01 0.02 35 30% Fail Q15
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Au12523 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 8
Report Number: 558047-L
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionC01 Leachate Fluid Key: 1 - pH 5.0; 2 - pH 2.9; 3 - pH 9.2; 4 - Reagent (DI) water; 5 - Client sample, 6 - other
N09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q15 The RPD reported passes Eurofins | mgt's QC - Acceptance Criteria as defined in the Internal Quality Control Review and Glossary page of this report.
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 21, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 8
Report Number: 558047-L
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 560144-L
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 24, 2017
Client Sample ID 0990_CONC01_170822
0990_CONC02_170822
0990_CONC03_170822
0990_CONC04_170822
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. M17-Au29753 M17-Au29754 M17-Au29755 M17-Au29756
Date Sampled Aug 22, 2017 Aug 22, 2017 Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L 0.42 13 2.5 0.22
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.94 N098.7 N094.3 N090.21
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N095.6 N0933 N0939 N090.91
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N092.2 N0911 N095.6 N090.12
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N097.4 N0917 N094.2 N090.31
Perfluorononanoic acid (PFNA)N11 0.01 ug/L 0.94 3.8 0.38 0.03
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L 0.46 1.6 0.40 0.02
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.2 0.31 < 0.2 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.01
13C4-PFBA (surr.) 1 % 131 104 117 80
13C5-PFPeA (surr.) 1 % 142 115 131 89
13C5-PFHxA (surr.) 1 % 143 109 122 79
13C4-PFHpA (surr.) 1 % 127 102 113 80
13C8-PFOA (surr.) 1 % 119 98 111 80
13C5-PFNA (surr.) 1 % 124 100 113 74
13C6-PFDA (surr.) 1 % 84 85 96 55
13C2-PFUnDA (surr.) 1 % 100 86 95 43
13C2-PFDoDA (surr.) 1 % 108 92 98 41
13C2-PFTeDA (surr.) 1 % 125 104 114 43
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L N095.4 N090.83 N091.4 N090.18
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.2 < 0.2 < 0.2 < 0.05
13C8-FOSA (surr.) 1 % 108 90 99 19
D3-N-MeFOSA (surr.) 1 % 109 97 105 10
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 15
Report Number: 560144-L
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_CONC01_170822
0990_CONC02_170822
0990_CONC03_170822
0990_CONC04_170822
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. M17-Au29753 M17-Au29754 M17-Au29755 M17-Au29756
Date Sampled Aug 22, 2017 Aug 22, 2017 Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 66 59 64 INT
D7-N-MeFOSE (surr.) 1 % 129 112 132 16
D9-N-EtFOSE (surr.) 1 % 108 95 104 12
D5-N-EtFOSAA (surr.) 1 % 126 105 115 18
D3-N-MeFOSAA (surr.) 1 % 108 88 96 16
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.88 24 5.1 0.21
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N091.7 N0925 N099.6 N090.15
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N0926 N09210 N0950 N091.0
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N097.0 N0916 N093.7 N090.02
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N09920 N09130 N09100 N090.63
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L 4.5 < 0.2 0.34 < 0.01
13C3-PFBS (surr.) 1 % 118 91 104 90
18O2-PFHxS (surr.) 1 % 110 73 93 80
13C8-PFOS (surr.) 1 % 81 99 107 70
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.2 1.0 0.26 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L 7.8 3.0 3.4 0.05
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.2 < 0.2 < 0.2 < 0.01
13C2-4:2 FTS (surr.) 1 % 142 131 138 141
13C2-6:2 FTS (surr.) 1 % 126 109 114 128
13C2-8:2 FTS (surr.) 1 % 113 102 105 77
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 946 340 150 1.63
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 927.4 147 104.2 0.94
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 953.4 357 154.2 1.94
Sum of WA DER PFAS (n=10) 0.05 ug/L 971.24 450.7 214.36 3.66
Sum of PFASs (n=28) 0.1 ug/L 991.24 498.24 230.18 4.07
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 9.0 11 11 11
pH (Leachate fluid) 0.1 pH Units 7.1 7.1 7.1 7.1
pH (off) 0.1 pH Units 9.3 12 12 12
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 15
Report Number: 560144-L
Client Sample ID 0990_CONC05_170822
0990_CONC06_170822
Sample Matrix AUS Leachate AUS Leachate
Eurofins | mgt Sample No. M17-Au29757 M17-Au29758
Date Sampled Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L 22 1.2
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N0931 N091.0
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N09220 N093.7
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N0950 N090.72
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N09110 N091.7
Perfluorononanoic acid (PFNA)N11 0.01 ug/L 0.21 0.07
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.2 0.04
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.2 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.2 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.2 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.2 < 0.01
13C4-PFBA (surr.) 1 % 108 98
13C5-PFPeA (surr.) 1 % 109 110
13C5-PFHxA (surr.) 1 % 83 82
13C4-PFHpA (surr.) 1 % 92 96
13C8-PFOA (surr.) 1 % 74 71
13C5-PFNA (surr.) 1 % 99 87
13C6-PFDA (surr.) 1 % 53 46
13C2-PFUnDA (surr.) 1 % 86 53
13C2-PFDoDA (surr.) 1 % 91 54
13C2-PFTeDA (surr.) 1 % 106 55
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L N093.6 N090.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.2 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.2 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.2 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.2 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.2 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.2 < 0.05
13C8-FOSA (surr.) 1 % 87 36
D3-N-MeFOSA (surr.) 1 % 94 41
D5-N-EtFOSA (surr.) 1 % 58 23
D7-N-MeFOSE (surr.) 1 % 106 52
D9-N-EtFOSE (surr.) 1 % 90 41
D5-N-EtFOSAA (surr.) 1 % 100 33
D3-N-MeFOSAA (surr.) 1 % 88 30
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 76 3.1
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N0990 N092.2
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N09520 N0914
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N0974 N091.7
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N091800 N0928
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L 0.37 < 0.01
13C3-PFBS (surr.) 1 % 76 71
18O2-PFHxS (surr.) 1 % 50 69
13C8-PFOS (surr.) 1 % 58 57
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 15
Report Number: 560144-L
Client Sample ID 0990_CONC05_170822
0990_CONC06_170822
Sample Matrix AUS Leachate AUS Leachate
Eurofins | mgt Sample No. M17-Au29757 M17-Au29758
Date Sampled Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.2 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L 0.24 0.64
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L 0.23 3.1
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.2 < 0.01
13C2-4:2 FTS (surr.) 1 % 131 147
13C2-6:2 FTS (surr.) 1 % 109 136
13C2-8:2 FTS (surr.) 1 % 91 87
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 2320 42
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 1910 29.7
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 2430 43.7
Sum of WA DER PFAS (n=10) 0.05 ug/L 2829.47 57.16
Sum of PFASs (n=28) 0.1 ug/L 2997.65 61.22
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0
pH (initial) 0.1 pH Units 11 12
pH (Leachate fluid) 0.1 pH Units 7.1 7.1
pH (off) 0.1 pH Units 11 11
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 15
Report Number: 560144-L
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 28, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 28, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 28, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 28, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
AUS Leaching Procedure Brisbane Aug 28, 2017 7 Days
- Method: LTM-GEN-7010 Leaching Procedure for Soils & Solid Wastes
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 15
Report Number: 560144-L
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_SS168_170821
Aug 21, 2017 Soil M17-Au29720 X X
2 0990_SS169_170821
Aug 21, 2017 Soil M17-Au29721 X X
3 0990_SS170_170821
Aug 21, 2017 Soil M17-Au29722 X X
4 0990_SS171_170821
Aug 21, 2017 Soil M17-Au29723 X X
5 0990_SS172_170821
Aug 21, 2017 Soil M17-Au29724 X X
6 0990_SS173_ Aug 21, 2017 Soil M17-Au29725 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 15
Report Number: 560144-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
170821
7 0990_SS174_170821
Aug 21, 2017 Soil M17-Au29726 X X
8 0990_SS175_170821
Aug 21, 2017 Soil M17-Au29727 X X
9 0990_SS176_170821
Aug 21, 2017 Soil M17-Au29728 X X
10 0990_SS177_170821
Aug 21, 2017 Soil M17-Au29729 X X
11 0990_SS178_170821
Aug 21, 2017 Soil M17-Au29730 X X
12 0990_SS179_170821
Aug 21, 2017 Soil M17-Au29731 X X
13 0990_SS180_ Aug 21, 2017 Soil M17-Au29732 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 15
Report Number: 560144-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
170821
14 0990_SS181_170821
Aug 21, 2017 Soil M17-Au29733 X X
15 0990_SS182_170821
Aug 21, 2017 Soil M17-Au29734 X X
16 0990_SS183_170821
Aug 21, 2017 Soil M17-Au29735 X X
17 0990_SS184_170821
Aug 21, 2017 Soil M17-Au29736 X X
18 0990_QCSS193_170821
Aug 21, 2017 Soil M17-Au29737 X X
19 0990_QCSS193A_170821
Aug 21, 2017 Soil M17-Au29738 X X
20 0990_SS185_ Aug 22, 2017 Soil M17-Au29739 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 15
Report Number: 560144-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
170822
21 0990_SS186_170822
Aug 22, 2017 Soil M17-Au29740 X X
22 0990_SS187_170822
Aug 22, 2017 Soil M17-Au29741 X X
23 0990_SS188_170822
Aug 22, 2017 Soil M17-Au29742 X X
24 0990_SS189_170822
Aug 22, 2017 Soil M17-Au29743 X X
25 0990_SS190_170822
Aug 22, 2017 Soil M17-Au29744 X X
26 0990_SS191_170822
Aug 22, 2017 Soil M17-Au29745 X X X X X X X X X X X X X X
27 0990_CONC0 Aug 22, 2017 Soil M17-Au29746 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 15
Report Number: 560144-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
1_170822
28 0990_CONC02_170822
Aug 22, 2017 Solid M17-Au29747 X X
29 0990_CONC03_170822
Aug 22, 2017 Solid M17-Au29748 X X
30 0990_CONC04_170822
Aug 22, 2017 Solid M17-Au29749 X X
31 0990_CONC05_170822
Aug 22, 2017 Solid M17-Au29750 X X
32 0990_CONC06_170822
Aug 22, 2017 Solid M17-Au29751 X X
33 0990_SS192_170822
Aug 22, 2017 Soil M17-Au29752 X X
34 0990_CONC0 Aug 22, 2017 AUS Leachate M17-Au29753 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 15
Report Number: 560144-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
1_170822
35 0990_CONC02_170822
Aug 22, 2017 AUS Leachate M17-Au29754 X X
36 0990_CONC03_170822
Aug 22, 2017 AUS Leachate M17-Au29755 X X
37 0990_CONC04_170822
Aug 22, 2017 AUS Leachate M17-Au29756 X X
38 0990_CONC05_170822
Aug 22, 2017 AUS Leachate M17-Au29757 X X
39 0990_CONC06_170822
Aug 22, 2017 AUS Leachate M17-Au29758 X X
Test Counts 1 1 1 1 1 1 1 1 1 1 1 1 6 33 33 39
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 15
Report Number: 560144-L
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 15
Report Number: 560144-L
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au29756 CP ug/L 0.22 0.22 1.0 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au29756 CP ug/L 0.21 0.21 1.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au29756 CP ug/L 0.91 0.90 2.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au29756 CP ug/L 0.12 0.11 1.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au29756 CP ug/L 0.31 0.31 1.0 30% Pass
Perfluorononanoic acid (PFNA) M17-Au29756 CP ug/L 0.03 0.03 8.0 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au29756 CP ug/L 0.02 0.02 5.0 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au29756 CP ug/L 0.01 < 0.01 5.0 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au29756 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au29756 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au29756 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 15
Report Number: 560144-L
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au29756 CP ug/L 0.18 0.18 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au29756 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au29756 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au29756 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au29756 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au29756 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au29756 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au29756 CP ug/L 0.21 0.21 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au29756 CP ug/L 0.15 0.15 1.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au29756 CP ug/L 1.0 1.0 1.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au29756 CP ug/L 0.02 0.02 7.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au29756 CP ug/L 0.63 0.65 5.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au29756 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au29756 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au29756 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au29756 CP ug/L 0.05 0.06 7.0 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au29756 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 14 of 15
Report Number: 560144-L
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionC01 Leachate Fluid Key: 1 - pH 5.0; 2 - pH 2.9; 3 - pH 9.2; 4 - Reagent (DI) water; 5 - Client sample, 6 - other
N09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 15 of 15
Report Number: 560144-L
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 560144-S
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 24, 2017
Client Sample ID 0990_SS168_170821
0990_SS169_170821
0990_SS170_170821
0990_SS171_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29720 M17-Au29721 M17-Au29722 M17-Au29723
Date Sampled Aug 21, 2017 Aug 21, 2017 Aug 21, 2017 Aug 21, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 108 109 126 129
13C5-PFPeA (surr.) 1 % 96 111 99 112
13C5-PFHxA (surr.) 1 % 123 129 128 132
13C4-PFHpA (surr.) 1 % 127 132 130 133
13C8-PFOA (surr.) 1 % 116 122 119 118
13C5-PFNA (surr.) 1 % 119 123 126 125
13C6-PFDA (surr.) 1 % 125 131 135 130
13C2-PFUnDA (surr.) 1 % 170 181 161 180
13C2-PFDoDA (surr.) 1 % 162 170 165 163
13C2-PFTeDA (surr.) 1 % 151 164 151 165
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 107 112 119 101
D3-N-MeFOSA (surr.) 1 % 114 127 123 132
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 34
Report Number: 560144-S
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_SS168_170821
0990_SS169_170821
0990_SS170_170821
0990_SS171_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29720 M17-Au29721 M17-Au29722 M17-Au29723
Date Sampled Aug 21, 2017 Aug 21, 2017 Aug 21, 2017 Aug 21, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 66 70 70 77
D7-N-MeFOSE (surr.) 1 % 70 79 79 75
D9-N-EtFOSE (surr.) 1 % 95 106 108 95
D5-N-EtFOSAA (surr.) 1 % 136 142 144 153
D3-N-MeFOSAA (surr.) 1 % 159 163 152 166
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanesulfonic acid (PFDS) 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 113 121 120 123
18O2-PFHxS (surr.) 1 % 119 138 134 137
13C8-PFOS (surr.) 1 % 140 139 131 140
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTS (surr.) 1 % 79 89 98 112
13C2-6:2 FTS (surr.) 1 % 101 107 95 114
13C2-8:2 FTS (surr.) 1 % 109 100 107 114
PFASs Summations
Sum (PFHxS + PFOS) 5 ug/kg < 5 < 5 < 5 < 5
Sum of US EPA PFAS (PFOS + PFOA) 5 ug/kg < 5 < 5 < 5 < 5
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 5 ug/kg < 5 < 5 < 5 < 5
Sum of WA DER PFAS (n=10) 10 ug/kg < 10 < 10 < 10 < 10
Sum of PFASs (n=28) 50 ug/kg < 50 < 50 < 50 < 50
% Moisture 1 % 50 27 20 14
Client Sample ID 0990_SS172_170821
0990_SS173_170821
0990_SS174_170821
0990_SS175_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29724 M17-Au29725 M17-Au29726 M17-Au29727
Date Sampled Aug 21, 2017 Aug 21, 2017 Aug 21, 2017 Aug 21, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 34
Report Number: 560144-S
Client Sample ID 0990_SS172_170821
0990_SS173_170821
0990_SS174_170821
0990_SS175_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29724 M17-Au29725 M17-Au29726 M17-Au29727
Date Sampled Aug 21, 2017 Aug 21, 2017 Aug 21, 2017 Aug 21, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 120 122 117 126
13C5-PFPeA (surr.) 1 % 103 102 102 116
13C5-PFHxA (surr.) 1 % 126 127 128 135
13C4-PFHpA (surr.) 1 % 129 130 133 140
13C8-PFOA (surr.) 1 % 115 121 124 132
13C5-PFNA (surr.) 1 % 114 117 119 134
13C6-PFDA (surr.) 1 % 132 118 129 131
13C2-PFUnDA (surr.) 1 % 165 168 169 181
13C2-PFDoDA (surr.) 1 % 141 133 159 170
13C2-PFTeDA (surr.) 1 % 124 136 156 171
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 93 98 103 112
D3-N-MeFOSA (surr.) 1 % 111 109 128 132
D5-N-EtFOSA (surr.) 1 % 64 66 76 75
D7-N-MeFOSE (surr.) 1 % 68 59 80 71
D9-N-EtFOSE (surr.) 1 % 74 83 100 97
D5-N-EtFOSAA (surr.) 1 % 119 106 147 152
D3-N-MeFOSAA (surr.) 1 % 148 141 165 168
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg 5.5 < 5 < 5 N0910
Perfluorodecanesulfonic acid (PFDS) 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 118 120 122 129
18O2-PFHxS (surr.) 1 % 135 133 135 142
13C8-PFOS (surr.) 1 % 141 135 142 143
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 34
Report Number: 560144-S
Client Sample ID 0990_SS172_170821
0990_SS173_170821
0990_SS174_170821
0990_SS175_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29724 M17-Au29725 M17-Au29726 M17-Au29727
Date Sampled Aug 21, 2017 Aug 21, 2017 Aug 21, 2017 Aug 21, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTS (surr.) 1 % 97 102 105 116
13C2-6:2 FTS (surr.) 1 % 108 118 96 117
13C2-8:2 FTS (surr.) 1 % 112 106 113 113
PFASs Summations
Sum (PFHxS + PFOS) 5 ug/kg 5.5 < 5 < 5 10
Sum of US EPA PFAS (PFOS + PFOA) 5 ug/kg 5.5 < 5 < 5 10
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 5 ug/kg 5.5 < 5 < 5 10
Sum of WA DER PFAS (n=10) 10 ug/kg < 10 < 10 < 10 10
Sum of PFASs (n=28) 50 ug/kg < 50 < 50 < 50 < 50
% Moisture 1 % 30 36 2.9 4.1
Client Sample ID 0990_SS176_170821
0990_SS177_170821
0990_SS178_170821
0990_SS179_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29728 M17-Au29729 M17-Au29730 M17-Au29731
Date Sampled Aug 21, 2017 Aug 21, 2017 Aug 21, 2017 Aug 21, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 125 125 121 127
13C5-PFPeA (surr.) 1 % 114 102 111 104
13C5-PFHxA (surr.) 1 % 130 130 125 132
13C4-PFHpA (surr.) 1 % 133 131 128 134
13C8-PFOA (surr.) 1 % 106 122 120 123
13C5-PFNA (surr.) 1 % 119 126 122 136
13C6-PFDA (surr.) 1 % 129 130 127 141
13C2-PFUnDA (surr.) 1 % 168 165 155 165
13C2-PFDoDA (surr.) 1 % 150 167 151 148
13C2-PFTeDA (surr.) 1 % 120 152 131 147
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 34
Report Number: 560144-S
Client Sample ID 0990_SS176_170821
0990_SS177_170821
0990_SS178_170821
0990_SS179_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29728 M17-Au29729 M17-Au29730 M17-Au29731
Date Sampled Aug 21, 2017 Aug 21, 2017 Aug 21, 2017 Aug 21, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 93 111 117 113
D3-N-MeFOSA (surr.) 1 % 111 132 125 127
D5-N-EtFOSA (surr.) 1 % 66 71 70 67
D7-N-MeFOSE (surr.) 1 % 71 71 78 61
D9-N-EtFOSE (surr.) 1 % 90 104 108 92
D5-N-EtFOSAA (surr.) 1 % 131 140 139 128
D3-N-MeFOSAA (surr.) 1 % 152 154 146 148
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg N0912 < 5 < 5 < 5
Perfluorodecanesulfonic acid (PFDS) 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 124 122 119 126
18O2-PFHxS (surr.) 1 % 136 136 128 139
13C8-PFOS (surr.) 1 % 140 139 138 138
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTS (surr.) 1 % 105 106 103 102
13C2-6:2 FTS (surr.) 1 % 113 107 113 113
13C2-8:2 FTS (surr.) 1 % 104 109 102 116
PFASs Summations
Sum (PFHxS + PFOS) 5 ug/kg 12 < 5 < 5 < 5
Sum of US EPA PFAS (PFOS + PFOA) 5 ug/kg 12 < 5 < 5 < 5
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 5 ug/kg 12 < 5 < 5 < 5
Sum of WA DER PFAS (n=10) 10 ug/kg 12 < 10 < 10 < 10
Sum of PFASs (n=28) 50 ug/kg < 50 < 50 < 50 < 50
% Moisture 1 % 20 27 26 14
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 34
Report Number: 560144-S
Client Sample ID 0990_SS180_170821
0990_SS181_170821
0990_SS182_170821
0990_SS183_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29732 M17-Au29733 M17-Au29734 M17-Au29735
Date Sampled Aug 21, 2017 Aug 21, 2017 Aug 21, 2017 Aug 21, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 123 61 134 105
13C5-PFPeA (surr.) 1 % 114 50 111 90
13C5-PFHxA (surr.) 1 % 127 65 141 113
13C4-PFHpA (surr.) 1 % 129 65 141 117
13C8-PFOA (surr.) 1 % 119 61 139 110
13C5-PFNA (surr.) 1 % 122 61 135 112
13C6-PFDA (surr.) 1 % 143 63 135 121
13C2-PFUnDA (surr.) 1 % 165 75 186 147
13C2-PFDoDA (surr.) 1 % 152 73 167 125
13C2-PFTeDA (surr.) 1 % 139 69 164 116
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 105 59 115 84
D3-N-MeFOSA (surr.) 1 % 122 64 139 110
D5-N-EtFOSA (surr.) 1 % 68 37 79 64
D7-N-MeFOSE (surr.) 1 % 71 37 71 63
D9-N-EtFOSE (surr.) 1 % 90 51 99 80
D5-N-EtFOSAA (surr.) 1 % 140 65 145 85
D3-N-MeFOSAA (surr.) 1 % 155 68 169 134
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg N097.2 < 5 < 5 N097.6
Perfluorodecanesulfonic acid (PFDS) 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 123 60 133 109
18O2-PFHxS (surr.) 1 % 130 67 151 122
13C8-PFOS (surr.) 1 % 133 69 150 115
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 34
Report Number: 560144-S
Client Sample ID 0990_SS180_170821
0990_SS181_170821
0990_SS182_170821
0990_SS183_170821
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29732 M17-Au29733 M17-Au29734 M17-Au29735
Date Sampled Aug 21, 2017 Aug 21, 2017 Aug 21, 2017 Aug 21, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTS (surr.) 1 % 95 46 115 96
13C2-6:2 FTS (surr.) 1 % 99 51 123 115
13C2-8:2 FTS (surr.) 1 % 125 44 127 108
PFASs Summations
Sum (PFHxS + PFOS) 5 ug/kg 7.2 < 5 < 5 7.6
Sum of US EPA PFAS (PFOS + PFOA) 5 ug/kg 7.2 < 5 < 5 7.6
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 5 ug/kg 7.2 < 5 < 5 7.6
Sum of WA DER PFAS (n=10) 10 ug/kg < 10 < 10 < 10 < 10
Sum of PFASs (n=28) 50 ug/kg < 50 < 50 < 50 < 50
% Moisture 1 % 25 1.7 1.8 9.1
Client Sample ID 0990_SS184_170821
0990_QCSS193_170821
0990_QCSS193A_170821
0990_SS185_170822
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29736 M17-Au29737 M17-Au29738 M17-Au29739
Date Sampled Aug 21, 2017 Aug 21, 2017 Aug 21, 2017 Aug 22, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 125 118 123 116
13C5-PFPeA (surr.) 1 % 107 112 104 102
13C5-PFHxA (surr.) 1 % 139 136 135 127
13C4-PFHpA (surr.) 1 % 139 138 138 129
13C8-PFOA (surr.) 1 % 131 131 130 119
13C5-PFNA (surr.) 1 % 136 129 128 123
13C6-PFDA (surr.) 1 % 140 133 140 133
13C2-PFUnDA (surr.) 1 % 164 157 175 162
13C2-PFDoDA (surr.) 1 % 164 149 168 146
13C2-PFTeDA (surr.) 1 % 153 134 164 118
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 34
Report Number: 560144-S
Client Sample ID 0990_SS184_170821
0990_QCSS193_170821
0990_QCSS193A_170821
0990_SS185_170822
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29736 M17-Au29737 M17-Au29738 M17-Au29739
Date Sampled Aug 21, 2017 Aug 21, 2017 Aug 21, 2017 Aug 22, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 109 114 111 108
D3-N-MeFOSA (surr.) 1 % 133 125 131 117
D5-N-EtFOSA (surr.) 1 % 73 66 73 66
D7-N-MeFOSE (surr.) 1 % 73 74 64 67
D9-N-EtFOSE (surr.) 1 % 93 78 95 88
D5-N-EtFOSAA (surr.) 1 % 174 139 158 148
D3-N-MeFOSAA (surr.) 1 % 158 147 163 140
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg < 5 < 5 < 5 5.0
Perfluorodecanesulfonic acid (PFDS) 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 129 129 131 120
18O2-PFHxS (surr.) 1 % 141 145 142 133
13C8-PFOS (surr.) 1 % 143 153 140 139
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTS (surr.) 1 % 110 118 130 105
13C2-6:2 FTS (surr.) 1 % 122 150 127 109
13C2-8:2 FTS (surr.) 1 % 138 132 123 102
PFASs Summations
Sum (PFHxS + PFOS) 5 ug/kg < 5 < 5 < 5 5
Sum of US EPA PFAS (PFOS + PFOA) 5 ug/kg < 5 < 5 < 5 5
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 5 ug/kg < 5 < 5 < 5 5
Sum of WA DER PFAS (n=10) 10 ug/kg < 10 < 10 < 10 < 10
Sum of PFASs (n=28) 50 ug/kg < 50 < 50 < 50 < 50
% Moisture 1 % < 1 1.7 < 1 31
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 34
Report Number: 560144-S
Client Sample ID 0990_SS186_170822
0990_SS187_170822
0990_SS188_170822
0990_SS189_170822
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29740 M17-Au29741 M17-Au29742 M17-Au29743
Date Sampled Aug 22, 2017 Aug 22, 2017 Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 119 124 122 131
13C5-PFPeA (surr.) 1 % 109 108 112 112
13C5-PFHxA (surr.) 1 % 127 133 130 139
13C4-PFHpA (surr.) 1 % 130 135 132 139
13C8-PFOA (surr.) 1 % 102 125 124 134
13C5-PFNA (surr.) 1 % 119 129 123 134
13C6-PFDA (surr.) 1 % 111 136 130 143
13C2-PFUnDA (surr.) 1 % 120 174 158 173
13C2-PFDoDA (surr.) 1 % 80 160 140 178
13C2-PFTeDA (surr.) 1 % 90 158 132 167
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 54 107 108 112
D3-N-MeFOSA (surr.) 1 % 108 136 120 139
D5-N-EtFOSA (surr.) 1 % 68 74 67 75
D7-N-MeFOSE (surr.) 1 % 47 73 64 72
D9-N-EtFOSE (surr.) 1 % 76 110 86 106
D5-N-EtFOSAA (surr.) 1 % 64 152 140 162
D3-N-MeFOSAA (surr.) 1 % 144 167 143 180
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg N0911 N097.1 N0945 < 5
Perfluorodecanesulfonic acid (PFDS) 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 122 127 125 131
18O2-PFHxS (surr.) 1 % 137 139 140 148
13C8-PFOS (surr.) 1 % 91 138 138 137
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 34
Report Number: 560144-S
Client Sample ID 0990_SS186_170822
0990_SS187_170822
0990_SS188_170822
0990_SS189_170822
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au29740 M17-Au29741 M17-Au29742 M17-Au29743
Date Sampled Aug 22, 2017 Aug 22, 2017 Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTS (surr.) 1 % 105 124 113 109
13C2-6:2 FTS (surr.) 1 % 103 119 119 125
13C2-8:2 FTS (surr.) 1 % 102 115 109 111
PFASs Summations
Sum (PFHxS + PFOS) 5 ug/kg 11 7.1 45 < 5
Sum of US EPA PFAS (PFOS + PFOA) 5 ug/kg 11 7.1 45 < 5
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 5 ug/kg 11 7.1 45 < 5
Sum of WA DER PFAS (n=10) 10 ug/kg 11 < 10 45 < 10
Sum of PFASs (n=28) 50 ug/kg < 50 < 50 < 50 < 50
% Moisture 1 % 26 14 27 1.7
Client Sample ID 0990_SS190_170822
0990_SS191_170822
0990_CONC01_170822
0990_CONC02_170822
Sample Matrix Soil Soil Soil Solid
Eurofins | mgt Sample No. M17-Au29744 M17-Au29745 M17-Au29746 M17-Au29747
Date Sampled Aug 22, 2017 Aug 22, 2017 Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
Polycyclic Aromatic Hydrocarbons
Benzo(a)pyrene TEQ (lower bound) * 0.5 mg/kg - < 0.5 - -
Benzo(a)pyrene TEQ (medium bound) * 0.5 mg/kg - 0.6 - -
Benzo(a)pyrene TEQ (upper bound) * 0.5 mg/kg - 1.2 - -
Acenaphthene 0.5 mg/kg - < 0.5 - -
Acenaphthylene 0.5 mg/kg - < 0.5 - -
Anthracene 0.5 mg/kg - < 0.5 - -
Benz(a)anthracene 0.5 mg/kg - < 0.5 - -
Benzo(a)pyrene 0.5 mg/kg - < 0.5 - -
Benzo(b&j)fluorantheneN07 0.5 mg/kg - < 0.5 - -
Benzo(g.h.i)perylene 0.5 mg/kg - < 0.5 - -
Benzo(k)fluoranthene 0.5 mg/kg - < 0.5 - -
Chrysene 0.5 mg/kg - < 0.5 - -
Dibenz(a.h)anthracene 0.5 mg/kg - < 0.5 - -
Fluoranthene 0.5 mg/kg - < 0.5 - -
Fluorene 0.5 mg/kg - < 0.5 - -
Indeno(1.2.3-cd)pyrene 0.5 mg/kg - < 0.5 - -
Naphthalene 0.5 mg/kg - < 0.5 - -
Phenanthrene 0.5 mg/kg - < 0.5 - -
Pyrene 0.5 mg/kg - < 0.5 - -
Total PAH* 0.5 mg/kg - < 0.5 - -
2-Fluorobiphenyl (surr.) 1 % - 84 - -
p-Terphenyl-d14 (surr.) 1 % - 133 - -
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 34
Report Number: 560144-S
Client Sample ID 0990_SS190_170822
0990_SS191_170822
0990_CONC01_170822
0990_CONC02_170822
Sample Matrix Soil Soil Soil Solid
Eurofins | mgt Sample No. M17-Au29744 M17-Au29745 M17-Au29746 M17-Au29747
Date Sampled Aug 22, 2017 Aug 22, 2017 Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 7.6 N09540
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 19 410
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 N09100 N091300
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 N0929 N09320
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 N0994 N09720
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 26 300
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 19 390
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5 < 5 9.0 600
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5 < 5 9.3 650
Perfluorotridecanoic acid (PFTrDA) 5 ug/kg < 5 < 5 < 5 300
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 220
13C4-PFBA (surr.) 1 % 124 126 128 88
13C5-PFPeA (surr.) 1 % 109 110 106 76
13C5-PFHxA (surr.) 1 % 131 139 120 108
13C4-PFHpA (surr.) 1 % 135 140 85 85
13C8-PFOA (surr.) 1 % 126 134 97 82
13C5-PFNA (surr.) 1 % 126 137 102 59
13C6-PFDA (surr.) 1 % 133 147 56 52
13C2-PFUnDA (surr.) 1 % 168 170 121 93
13C2-PFDoDA (surr.) 1 % 162 180 133 106
13C2-PFTeDA (surr.) 1 % 155 148 111 75
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 N09160 N0988
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 105 125 91 85
D3-N-MeFOSA (surr.) 1 % 139 130 136 118
D5-N-EtFOSA (surr.) 1 % 72 75 72 54
D7-N-MeFOSE (surr.) 1 % 73 77 70 45
D9-N-EtFOSE (surr.) 1 % 107 95 103 89
D5-N-EtFOSAA (surr.) 1 % 151 166 128 118
D3-N-MeFOSAA (surr.) 1 % 159 167 137 105
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 N0915 N09690
Perfluoropentanesulfonic acid (PFPeS) 5 ug/kg < 5 < 5 N0924 N09530
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 N09310 N097300
Perfluoroheptanesulfonic acid (PFHpS) 5 ug/kg < 5 < 5 N09150 N09820
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg < 5 < 5 N0935000 N0927000
Perfluorodecanesulfonic acid (PFDS) 5 ug/kg < 5 < 5 N09310 N09320
13C3-PFBS (surr.) 1 % 128 132 124 81
18O2-PFHxS (surr.) 1 % 138 148 80 85
13C8-PFOS (surr.) 1 % 136 144 91 51
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 34
Report Number: 560144-S
Client Sample ID 0990_SS190_170822
0990_SS191_170822
0990_CONC01_170822
0990_CONC02_170822
Sample Matrix Soil Soil Soil Solid
Eurofins | mgt Sample No. M17-Au29744 M17-Au29745 M17-Au29746 M17-Au29747
Date Sampled Aug 22, 2017 Aug 22, 2017 Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10 < 10 < 10 52
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg < 5 < 5 190 410
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 5 ug/kg < 5 < 5 < 5 43
13C2-4:2 FTS (surr.) 1 % 114 117 111 157
13C2-6:2 FTS (surr.) 1 % 112 133 130 165
13C2-8:2 FTS (surr.) 1 % 104 144 139 INT
PFASs Summations
Sum (PFHxS + PFOS) 5 ug/kg < 5 < 5 35310 34300
Sum of US EPA PFAS (PFOS + PFOA) 5 ug/kg < 5 < 5 35094 27720
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 5 ug/kg < 5 < 5 35404 35020
Sum of WA DER PFAS (n=10) 10 ug/kg < 10 < 10 35764.6 38742
Sum of PFASs (n=28) 50 ug/kg < 50 < 50 36471.9 43003
Heavy Metals
Aluminium 10 mg/kg - 37000 - -
Arsenic 2 mg/kg - 4.5 - -
Cadmium 0.4 mg/kg - < 0.4 - -
Chromium 5 mg/kg - 52 - -
Copper 5 mg/kg - < 5 - -
Iron 20 mg/kg - 43000 - -
Lead 5 mg/kg - 12 - -
Manganese 5 mg/kg - 12 - -
Mercury 0.1 mg/kg - < 0.1 - -
Nickel 5 mg/kg - 7.2 - -
Zinc 5 mg/kg - 6.1 - -
% Moisture 1 % 21 < 1 < 1 11
Client Sample ID 0990_CONC03_170822
0990_CONC04_170822
0990_CONC05_170822
0990_CONC06_170822
Sample Matrix Solid Solid Solid Solid
Eurofins | mgt Sample No. M17-Au29748 M17-Au29749 M17-Au29750 M17-Au29751
Date Sampled Aug 22, 2017 Aug 22, 2017 Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg 92 N095.8 N09600 28
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg 150 5.8 N09980 N0930
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg N091200 N0924 N095400 N0981
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg N09240 < 5 N091800 N0915
Perfluorooctanoic acid (PFOA)N11 5 ug/kg N09420 N099.2 N094400 N0932
Perfluorononanoic acid (PFNA)N11 5 ug/kg 47 < 5 N0915 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg 110 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg 95 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg 100 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA) 5 ug/kg 31 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg 25 < 5 < 5 < 5
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 34
Report Number: 560144-S
Client Sample ID 0990_CONC03_170822
0990_CONC04_170822
0990_CONC05_170822
0990_CONC06_170822
Sample Matrix Solid Solid Solid Solid
Eurofins | mgt Sample No. M17-Au29748 M17-Au29749 M17-Au29750 M17-Au29751
Date Sampled Aug 22, 2017 Aug 22, 2017 Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C4-PFBA (surr.) 1 % 80 124 113 124
13C5-PFPeA (surr.) 1 % 73 108 125 111
13C5-PFHxA (surr.) 1 % 108 121 116 122
13C4-PFHpA (surr.) 1 % 72 131 100 107
13C8-PFOA (surr.) 1 % 66 130 88 127
13C5-PFNA (surr.) 1 % 68 134 78 117
13C6-PFDA (surr.) 1 % 38 145 24 110
13C2-PFUnDA (surr.) 1 % 82 154 101 157
13C2-PFDoDA (surr.) 1 % 74 150 157 182
13C2-PFTeDA (surr.) 1 % 38 138 176 178
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg N09180 < 5 150 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 64 108 98 112
D3-N-MeFOSA (surr.) 1 % 96 140 147 141
D5-N-EtFOSA (surr.) 1 % 50 70 63 65
D7-N-MeFOSE (surr.) 1 % 59 81 67 66
D9-N-EtFOSE (surr.) 1 % 82 114 106 110
D5-N-EtFOSAA (surr.) 1 % 73 125 149 136
D3-N-MeFOSAA (surr.) 1 % 73 116 128 116
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg 160 < 5 2000 N0966
Perfluoropentanesulfonic acid (PFPeS) 5 ug/kg N09290 < 5 N092400 N0940
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg N093000 N0922 N0918000 N09300
Perfluoroheptanesulfonic acid (PFHpS) 5 ug/kg N09620 < 5 N093000 N0936
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg N0943000 N0924 N09110000 1000
Perfluorodecanesulfonic acid (PFDS) 5 ug/kg N09590 < 5 N09110 < 5
13C3-PFBS (surr.) 1 % 72 122 94 122
18O2-PFHxS (surr.) 1 % 107 134 72 106
13C8-PFOS (surr.) 1 % 80 118 156 89
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg 20 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg 360 < 5 15 180
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 5 ug/kg 27 < 5 < 5 < 5
13C2-4:2 FTS (surr.) 1 % 68 103 191 197
13C2-6:2 FTS (surr.) 1 % 90 129 INT INT
13C2-8:2 FTS (surr.) 1 % INT 182 82 INT
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 34
Report Number: 560144-S
Client Sample ID 0990_CONC03_170822
0990_CONC04_170822
0990_CONC05_170822
0990_CONC06_170822
Sample Matrix Solid Solid Solid Solid
Eurofins | mgt Sample No. M17-Au29748 M17-Au29749 M17-Au29750 M17-Au29751
Date Sampled Aug 22, 2017 Aug 22, 2017 Aug 22, 2017 Aug 22, 2017
Test/Reference LOR Unit
PFASs Summations
Sum (PFHxS + PFOS) 5 ug/kg 46000 46 128000 1300
Sum of US EPA PFAS (PFOS + PFOA) 5 ug/kg 43420 33.2 114400 1032
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 5 ug/kg 46420 55.2 132400 1332
Sum of WA DER PFAS (n=10) 10 ug/kg 48642 90.8 143195 1732
Sum of PFASs (n=28) 50 ug/kg 50757 90.8 148870 1808
% Moisture 1 % 9.5 3.5 1.6 < 1
Client Sample ID 0990_SS192_170822
Sample Matrix Soil
Eurofins | mgt Sample No. M17-Au29752
Date Sampled Aug 22, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg N099.3
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg N0913
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5
Perfluorotridecanoic acid (PFTrDA) 5 ug/kg < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5
13C4-PFBA (surr.) 1 % 75
13C5-PFPeA (surr.) 1 % 27
13C5-PFHxA (surr.) 1 % 95
13C4-PFHpA (surr.) 1 % 101
13C8-PFOA (surr.) 1 % 70
13C5-PFNA (surr.) 1 % 48
13C6-PFDA (surr.) 1 % 57
13C2-PFUnDA (surr.) 1 % 44
13C2-PFDoDA (surr.) 1 % 22
13C2-PFTeDA (surr.) 1 % 25
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 14 of 34
Report Number: 560144-S
Client Sample ID 0990_SS192_170822
Sample Matrix Soil
Eurofins | mgt Sample No. M17-Au29752
Date Sampled Aug 22, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
13C8-FOSA (surr.) 1 % 15
D3-N-MeFOSA (surr.) 1 % 19
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % INT
D9-N-EtFOSE (surr.) 1 % INT
D5-N-EtFOSAA (surr.) 1 % 32
D3-N-MeFOSAA (surr.) 1 % 29
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5
Perfluoropentanesulfonic acid (PFPeS) 5 ug/kg < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg N098.7
Perfluoroheptanesulfonic acid (PFHpS) 5 ug/kg < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg N0957
Perfluorodecanesulfonic acid (PFDS) 5 ug/kg 17
13C3-PFBS (surr.) 1 % 123
18O2-PFHxS (surr.) 1 % 104
13C8-PFOS (surr.) 1 % 64
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 5 ug/kg < 5
13C2-4:2 FTS (surr.) 1 % 172
13C2-6:2 FTS (surr.) 1 % 153
13C2-8:2 FTS (surr.) 1 % 68
PFASs Summations
Sum (PFHxS + PFOS) 5 ug/kg 65.7
Sum of US EPA PFAS (PFOS + PFOA) 5 ug/kg 57
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 5 ug/kg 65.7
Sum of WA DER PFAS (n=10) 10 ug/kg 88
Sum of PFASs (n=28) 50 ug/kg 105
% Moisture 1 % 6.0
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 15 of 34
Report Number: 560144-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Polycyclic Aromatic Hydrocarbons Melbourne Aug 26, 2017 14 Day
- Method: LTM-ORG-2140 PAH and Phenols in Soils by GCMS
Heavy Metals Melbourne Aug 26, 2017 180 Day
- Method: LTM-MET-3030 by ICP-OES (hydride ICP-OES for Mercury)
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 28, 2017 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 28, 2017 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 28, 2017 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 28, 2017 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
% Moisture Brisbane Aug 25, 2017 14 Day
- Method: LTM-GEN-7080 Moisture
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 16 of 34
Report Number: 560144-S
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_SS168_170821
Aug 21, 2017 Soil M17-Au29720 X X
2 0990_SS169_170821
Aug 21, 2017 Soil M17-Au29721 X X
3 0990_SS170_170821
Aug 21, 2017 Soil M17-Au29722 X X
4 0990_SS171_170821
Aug 21, 2017 Soil M17-Au29723 X X
5 0990_SS172_170821
Aug 21, 2017 Soil M17-Au29724 X X
6 0990_SS173_ Aug 21, 2017 Soil M17-Au29725 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 17 of 34
Report Number: 560144-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
170821
7 0990_SS174_170821
Aug 21, 2017 Soil M17-Au29726 X X
8 0990_SS175_170821
Aug 21, 2017 Soil M17-Au29727 X X
9 0990_SS176_170821
Aug 21, 2017 Soil M17-Au29728 X X
10 0990_SS177_170821
Aug 21, 2017 Soil M17-Au29729 X X
11 0990_SS178_170821
Aug 21, 2017 Soil M17-Au29730 X X
12 0990_SS179_170821
Aug 21, 2017 Soil M17-Au29731 X X
13 0990_SS180_ Aug 21, 2017 Soil M17-Au29732 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 18 of 34
Report Number: 560144-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
170821
14 0990_SS181_170821
Aug 21, 2017 Soil M17-Au29733 X X
15 0990_SS182_170821
Aug 21, 2017 Soil M17-Au29734 X X
16 0990_SS183_170821
Aug 21, 2017 Soil M17-Au29735 X X
17 0990_SS184_170821
Aug 21, 2017 Soil M17-Au29736 X X
18 0990_QCSS193_170821
Aug 21, 2017 Soil M17-Au29737 X X
19 0990_QCSS193A_170821
Aug 21, 2017 Soil M17-Au29738 X X
20 0990_SS185_ Aug 22, 2017 Soil M17-Au29739 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 19 of 34
Report Number: 560144-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
170822
21 0990_SS186_170822
Aug 22, 2017 Soil M17-Au29740 X X
22 0990_SS187_170822
Aug 22, 2017 Soil M17-Au29741 X X
23 0990_SS188_170822
Aug 22, 2017 Soil M17-Au29742 X X
24 0990_SS189_170822
Aug 22, 2017 Soil M17-Au29743 X X
25 0990_SS190_170822
Aug 22, 2017 Soil M17-Au29744 X X
26 0990_SS191_170822
Aug 22, 2017 Soil M17-Au29745 X X X X X X X X X X X X X X
27 0990_CONC0 Aug 22, 2017 Soil M17-Au29746 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 20 of 34
Report Number: 560144-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
1_170822
28 0990_CONC02_170822
Aug 22, 2017 Solid M17-Au29747 X X
29 0990_CONC03_170822
Aug 22, 2017 Solid M17-Au29748 X X
30 0990_CONC04_170822
Aug 22, 2017 Solid M17-Au29749 X X
31 0990_CONC05_170822
Aug 22, 2017 Solid M17-Au29750 X X
32 0990_CONC06_170822
Aug 22, 2017 Solid M17-Au29751 X X
33 0990_SS192_170822
Aug 22, 2017 Soil M17-Au29752 X X
34 0990_CONC0 Aug 22, 2017 AUS Leachate M17-Au29753 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 21 of 34
Report Number: 560144-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 24, 2017 10:00 AMAddress: 3G Marine Pde Report #: 560144 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Arsenic
Cadm
ium
Chrom
ium
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Polycyclic A
romatic H
ydrocarbons
AU
S Leaching P
rocedure
Moisture S
et
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
1_170822
35 0990_CONC02_170822
Aug 22, 2017 AUS Leachate M17-Au29754 X X
36 0990_CONC03_170822
Aug 22, 2017 AUS Leachate M17-Au29755 X X
37 0990_CONC04_170822
Aug 22, 2017 AUS Leachate M17-Au29756 X X
38 0990_CONC05_170822
Aug 22, 2017 AUS Leachate M17-Au29757 X X
39 0990_CONC06_170822
Aug 22, 2017 AUS Leachate M17-Au29758 X X
Test Counts 1 1 1 1 1 1 1 1 1 1 1 1 6 33 33 39
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 22 of 34
Report Number: 560144-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 23 of 34
Report Number: 560144-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Polycyclic Aromatic Hydrocarbons
Acenaphthene mg/kg < 0.5 0.5 Pass
Acenaphthylene mg/kg < 0.5 0.5 Pass
Anthracene mg/kg < 0.5 0.5 Pass
Benz(a)anthracene mg/kg < 0.5 0.5 Pass
Benzo(a)pyrene mg/kg < 0.5 0.5 Pass
Benzo(b&j)fluoranthene mg/kg < 0.5 0.5 Pass
Benzo(g.h.i)perylene mg/kg < 0.5 0.5 Pass
Benzo(k)fluoranthene mg/kg < 0.5 0.5 Pass
Chrysene mg/kg < 0.5 0.5 Pass
Dibenz(a.h)anthracene mg/kg < 0.5 0.5 Pass
Fluoranthene mg/kg < 0.5 0.5 Pass
Fluorene mg/kg < 0.5 0.5 Pass
Indeno(1.2.3-cd)pyrene mg/kg < 0.5 0.5 Pass
Naphthalene mg/kg < 0.5 0.5 Pass
Phenanthrene mg/kg < 0.5 0.5 Pass
Pyrene mg/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 5 5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 5 5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 5 5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 5 5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 5 5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 5 5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 5 5 Pass
Perfluoroundecanoic acid (PFUnA) ug/kg < 5 5 Pass
Perfluorododecanoic acid (PFDoA) ug/kg < 5 5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 5 5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 5 5 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/kg < 5 5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 5 5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 5 5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 5 5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 5 5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 10 10 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 10 10 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 5 5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 5 5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 5 5 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 5 5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 5 5 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 5 5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 5 5 Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 24 of 34
Report Number: 560144-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 10 10 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 5 5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 5 5 Pass
Method Blank
Heavy Metals
Aluminium mg/kg < 10 10 Pass
Arsenic mg/kg < 2 2 Pass
Cadmium mg/kg < 0.4 0.4 Pass
Chromium mg/kg < 5 5 Pass
Copper mg/kg < 5 5 Pass
Iron mg/kg < 20 20 Pass
Lead mg/kg < 5 5 Pass
Manganese mg/kg < 5 5 Pass
Mercury mg/kg < 0.1 0.1 Pass
Nickel mg/kg < 5 5 Pass
Zinc mg/kg < 5 5 Pass
LCS - % Recovery
Polycyclic Aromatic Hydrocarbons
Acenaphthene % 88 70-130 Pass
Acenaphthylene % 94 70-130 Pass
Anthracene % 94 70-130 Pass
Benz(a)anthracene % 101 70-130 Pass
Benzo(a)pyrene % 104 70-130 Pass
Benzo(b&j)fluoranthene % 99 70-130 Pass
Benzo(g.h.i)perylene % 96 70-130 Pass
Benzo(k)fluoranthene % 116 70-130 Pass
Chrysene % 101 70-130 Pass
Dibenz(a.h)anthracene % 106 70-130 Pass
Fluoranthene % 101 70-130 Pass
Fluorene % 88 70-130 Pass
Indeno(1.2.3-cd)pyrene % 103 70-130 Pass
Naphthalene % 88 70-130 Pass
Phenanthrene % 101 70-130 Pass
Pyrene % 97 70-130 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 96 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 110 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 91 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) % 91 50-150 Pass
Perfluorononanoic acid (PFNA) % 93 50-150 Pass
Perfluorodecanoic acid (PFDA) % 95 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 82 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 87 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 93 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 94 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 90 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 101 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 105 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 113 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 133 50-150 Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 25 of 34
Report Number: 560144-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 104 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 108 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 89 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 86 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 89 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 102 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 92 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 64 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 95 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 88 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 119 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 117 50-150 Pass
LCS - % Recovery
Heavy Metals
Arsenic % 97 80-120 Pass
Cadmium % 100 80-120 Pass
Chromium % 104 80-120 Pass
Copper % 107 80-120 Pass
Lead % 111 80-120 Pass
Manganese % 103 80-120 Pass
Mercury % 119 75-125 Pass
Nickel % 106 80-120 Pass
Zinc % 101 80-120 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au29721 CP % 101 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au29721 CP % 113 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au29721 CP % 100 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au29721 CP % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au29721 CP % 98 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au29721 CP % 95 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au29721 CP % 102 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au29721 CP % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au29721 CP % 91 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au29721 CP % 97 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au29721 CP % 111 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au29721 CP % 90 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au29721 CP % 102 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au29721 CP % 101 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au29721 CP % 92 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au29721 CP % 127 50-150 Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 26 of 34
Report Number: 560144-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au29721 CP % 104 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au29721 CP % 118 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au29721 CP % 96 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au29721 CP % 86 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au29721 CP % 95 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au29721 CP % 104 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au29721 CP % 99 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au29721 CP % 83 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au29721 CP % 95 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au29721 CP % 100 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au29721 CP % 126 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au29721 CP % 144 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au29731 CP % 104 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au29731 CP % 123 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au29731 CP % 100 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au29731 CP % 102 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au29731 CP % 96 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au29731 CP % 102 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au29731 CP % 97 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au29731 CP % 81 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au29731 CP % 97 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au29731 CP % 90 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au29731 CP % 110 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au29731 CP % 98 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au29731 CP % 99 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au29731 CP % 98 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au29731 CP % 98 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au29731 CP % 121 50-150 Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 27 of 34
Report Number: 560144-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au29731 CP % 81 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au29731 CP % 117 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au29731 CP % 92 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au29731 CP % 84 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au29731 CP % 79 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au29731 CP % 120 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au29731 CP % 103 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au29731 CP % 70 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au29731 CP % 77 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au29731 CP % 134 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au29731 CP % 132 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au29731 CP % 107 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au29741 CP % 98 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au29741 CP % 126 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au29741 CP % 96 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au29741 CP % 99 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au29741 CP % 94 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au29741 CP % 99 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au29741 CP % 99 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au29741 CP % 88 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au29741 CP % 95 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au29741 CP % 91 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au29741 CP % 106 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au29741 CP % 89 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au29741 CP % 97 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au29741 CP % 95 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au29741 CP % 103 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au29741 CP % 124 50-150 Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 28 of 34
Report Number: 560144-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au29741 CP % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au29741 CP % 117 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au29741 CP % 90 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au29741 CP % 88 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au29741 CP % 79 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au29741 CP % 112 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au29741 CP % 82 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au29741 CP % 76 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au29741 CP % 112 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au29741 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au29741 CP % 109 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au29741 CP % 119 50-150 Pass
Spike - % Recovery
Polycyclic Aromatic Hydrocarbons Result 1
Acenaphthene M17-Au29808 NCP % 99 70-130 Pass
Acenaphthylene M17-Au29808 NCP % 107 70-130 Pass
Anthracene M17-Au29808 NCP % 111 70-130 Pass
Benz(a)anthracene M17-Au29808 NCP % 104 70-130 Pass
Benzo(a)pyrene M17-Au29808 NCP % 115 70-130 Pass
Benzo(b&j)fluoranthene M17-Au29808 NCP % 111 70-130 Pass
Benzo(g.h.i)perylene M17-Au29808 NCP % 111 70-130 Pass
Benzo(k)fluoranthene M17-Au29808 NCP % 121 70-130 Pass
Chrysene M17-Au29808 NCP % 103 70-130 Pass
Dibenz(a.h)anthracene M17-Au29808 NCP % 127 70-130 Pass
Fluoranthene M17-Au29808 NCP % 101 70-130 Pass
Fluorene M17-Au29808 NCP % 107 70-130 Pass
Indeno(1.2.3-cd)pyrene M17-Au29808 NCP % 123 70-130 Pass
Naphthalene M17-Au29808 NCP % 100 70-130 Pass
Phenanthrene M17-Au29808 NCP % 111 70-130 Pass
Pyrene M17-Au29808 NCP % 103 70-130 Pass
Spike - % Recovery
Heavy Metals Result 1
Arsenic M17-Au29147 NCP % 95 75-125 Pass
Cadmium M17-Au29147 NCP % 101 75-125 Pass
Chromium M17-Au29147 NCP % 120 75-125 Pass
Copper M17-Au29147 NCP % 107 75-125 Pass
Lead M17-Au29147 NCP % 110 75-125 Pass
Manganese M17-Au29147 NCP % 106 75-125 Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 29 of 34
Report Number: 560144-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Mercury M17-Au29147 NCP % 102 70-130 Pass
Nickel M17-Au29147 NCP % 107 75-125 Pass
Zinc M17-Au29147 NCP % 107 75-125 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au29720 CP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au29720 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 30 of 34
Report Number: 560144-S
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au29720 CP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au29720 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
% Moisture M17-Au29728 CP % 20 20 3.0 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au29730 CP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au29730 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 31 of 34
Report Number: 560144-S
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au29730 CP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au29730 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
% Moisture M17-Au29738 CP % < 1 < 1 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au29740 CP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au29740 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au29740 CP ug/kg 11 11 2.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 32 of 34
Report Number: 560144-S
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au29740 CP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au29740 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Polycyclic Aromatic Hydrocarbons Result 1 Result 2 RPD
Acenaphthene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Acenaphthylene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Anthracene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Benz(a)anthracene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Benzo(a)pyrene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Benzo(b&j)fluoranthene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Benzo(g.h.i)perylene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Benzo(k)fluoranthene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Chrysene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Dibenz(a.h)anthracene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Fluoranthene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Fluorene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Indeno(1.2.3-cd)pyrene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Naphthalene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Phenanthrene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Pyrene M17-Au29688 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Heavy Metals Result 1 Result 2 RPD
Aluminium M17-Au29137 NCP mg/kg 15000 16000 8.0 30% Pass
Arsenic M17-Au29147 NCP mg/kg 27 27 <1 30% Pass
Cadmium M17-Au29147 NCP mg/kg < 0.4 < 0.4 <1 30% Pass
Chromium M17-Au29147 NCP mg/kg 47 47 <1 30% Pass
Copper M17-Au29147 NCP mg/kg 6.7 6.6 <1 30% Pass
Iron M17-Au29137 NCP mg/kg 69000 67000 4.0 30% Pass
Lead M17-Au29147 NCP mg/kg 15 16 1.0 30% Pass
Manganese M17-Au29147 NCP mg/kg 8.4 8.4 <1 30% Pass
Mercury M17-Au29147 NCP mg/kg < 0.1 < 0.1 <1 30% Pass
Nickel M17-Au29147 NCP mg/kg < 5 < 5 <1 30% Pass
Zinc M17-Au29147 NCP mg/kg 15 14 4.0 30% Pass
Duplicate
Result 1 Result 2 RPD
% Moisture M17-Au29749 CP % 3.5 3.3 4.0 30% Pass
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 33 of 34
Report Number: 560144-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N07Please note:- These two PAH isomers closely co-elute using the most contemporary analytical methods and both the reported concentration (and the TEQ) apply specifically tothe total of the two co-eluting PAHs
N09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Alex Petridis Senior Analyst-Organic (VIC)
Bryan Wilson Senior Analyst-Metal (QLD)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Inorganic (QLD)
Jonathon Angell Senior Analyst-Organic (QLD)
Joseph Edouard Senior Analyst-Organic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 34 of 34
Report Number: 560144-S
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 562180-L
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Sep 07, 2017
Client Sample ID 0990_SS175_170821
0990_SS176_170821
0990_SS186_170821
0990_SS188_170821
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. M17-Se07449 M17-Se07450 M17-Se07451 M17-Se07452
Date Sampled Aug 31, 2017 Aug 31, 2017 Aug 31, 2017 Aug 31, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.01 < 0.01 < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.02 < 0.01 < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 N090.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 73 75 74 68
13C5-PFPeA (surr.) 1 % 84 88 86 79
13C5-PFHxA (surr.) 1 % 94 94 93 81
13C4-PFHpA (surr.) 1 % 93 89 90 79
13C8-PFOA (surr.) 1 % 88 87 84 72
13C5-PFNA (surr.) 1 % 76 78 76 61
13C6-PFDA (surr.) 1 % 68 70 71 48
13C2-PFUnDA (surr.) 1 % 48 48 49 36
13C2-PFDoDA (surr.) 1 % 38 36 37 31
13C2-PFTeDA (surr.) 1 % 20 18 19 15
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 58 56 60 47
D3-N-MeFOSA (surr.) 1 % 27 24 25 24
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 12
Report Number: 562180-L
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_SS175_170821
0990_SS176_170821
0990_SS186_170821
0990_SS188_170821
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. M17-Se07449 M17-Se07450 M17-Se07451 M17-Se07452
Date Sampled Aug 31, 2017 Aug 31, 2017 Aug 31, 2017 Aug 31, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 17 15 15 14
D7-N-MeFOSE (surr.) 1 % 32 31 30 26
D9-N-EtFOSE (surr.) 1 % 24 23 21 18
D5-N-EtFOSAA (surr.) 1 % 62 63 67 57
D3-N-MeFOSAA (surr.) 1 % 60 63 66 52
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.07 < 0.01 N090.04 0.02
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.29 N090.08 N090.33 N090.83
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 91 91 90 86
18O2-PFHxS (surr.) 1 % 85 86 86 81
13C8-PFOS (surr.) 1 % 59 60 61 48
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 84 78 82 81
13C2-6:2 FTS (surr.) 1 % 77 72 74 73
13C2-8:2 FTS (surr.) 1 % 56 55 60 47
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.36 0.08 0.37 0.85
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.29 0.08 0.34 0.83
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.36 0.08 0.38 0.85
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.39 0.08 0.38 0.85
Sum of PFASs (n=28) 0.1 ug/L 0.39 < 0.1 0.38 0.85
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 9.2 6.9 9.1 8.9
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 8.0 7.3 8.6 8.0
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 12
Report Number: 562180-L
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Sep 15, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Sep 15, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Sep 15, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Sep 15, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
AUS Leaching Procedure Brisbane Sep 15, 2017 7 Days
- Method: LTM-GEN-7010 Leaching Procedure for Soils & Solid Wastes
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 12
Report Number: 562180-L
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Sep 7, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 562180 Due: Sep 14, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Cation E
xchange Capacity
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_SS168_170821
Aug 31, 2017 Soil M17-Se07424 X X X X
2 0990_SS169_170821
Aug 31, 2017 Soil M17-Se07425 X X X
3 0990_SS170_170821
Aug 31, 2017 Soil M17-Se07426 X X X X
4 0990_SS171_170821
Aug 31, 2017 Soil M17-Se07427 X X X
5 0990_SS172_170821
Aug 31, 2017 Soil M17-Se07428 X X X X
6 0990_SS173_ Aug 31, 2017 Soil M17-Se07429 X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 12
Report Number: 562180-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Sep 7, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 562180 Due: Sep 14, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Cation E
xchange Capacity
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170821
7 0990_SS174_170821
Aug 31, 2017 Soil M17-Se07430 X X X X
8 0990_SS175_170821
Aug 31, 2017 Soil M17-Se07431 X X X
9 0990_SS176_170821
Aug 31, 2017 Soil M17-Se07432 X X X X
10 0990_SS177_170821
Aug 31, 2017 Soil M17-Se07433 X X X
11 0990_SS178_170821
Aug 31, 2017 Soil M17-Se07434 X X X X
12 0990_SS179_170821
Aug 31, 2017 Soil M17-Se07435 X X X
13 0990_SS180_ Aug 31, 2017 Soil M17-Se07436 X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 12
Report Number: 562180-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Sep 7, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 562180 Due: Sep 14, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Cation E
xchange Capacity
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170821
14 0990_SS181_170821
Aug 31, 2017 Soil M17-Se07437 X X X
15 0990_SS182_170821
Aug 31, 2017 Soil M17-Se07438 X X X X
16 0990_SS183_170821
Aug 31, 2017 Soil M17-Se07439 X X X
17 0990_SS184_170821
Aug 31, 2017 Soil M17-Se07440 X X X X
18 0990_SS185_170821
Aug 31, 2017 Soil M17-Se07441 X X X
19 0990_SS186_170821
Aug 31, 2017 Soil M17-Se07442 X X X X
20 0990_SS187_ Aug 31, 2017 Soil M17-Se07443 X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 12
Report Number: 562180-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Sep 7, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 562180 Due: Sep 14, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Cation E
xchange Capacity
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170821
21 0990_SS188_170821
Aug 31, 2017 Soil M17-Se07444 X X X X
22 0990_SS189_170821
Aug 31, 2017 Soil M17-Se07445 X X X
23 0990_SS190_170821
Aug 31, 2017 Soil M17-Se07446 X X X X
24 0990_SS191_170821
Aug 31, 2017 Soil M17-Se07447 X X X
25 0990_SS192_170821
Aug 31, 2017 Soil M17-Se07448 X X X
26 0990_SS175_170821
Aug 31, 2017 AUS Leachate M17-Se07449 X X
27 0990_SS176_ Aug 31, 2017 AUS Leachate M17-Se07450 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 12
Report Number: 562180-L
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Sep 7, 2017 12:00 AMAddress: Level 1, 436 Johnston Street Report #: 562180 Due: Sep 14, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
pH (1:5 A
queous extract)
Total O
rganic Carbon
AU
S Leaching P
rocedure
Moisture S
et
Cation E
xchange Capacity
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X
Perth Laboratory - NATA Site # 23736
170821
28 0990_SS186_170821
Aug 31, 2017 AUS Leachate M17-Se07451 X X
29 0990_SS188_170821
Aug 31, 2017 AUS Leachate M17-Se07452 X X
Test Counts 25 25 4 25 12 4
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 12
Report Number: 562180-L
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 12
Report Number: 562180-L
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Se21582 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Se21582 NCP ug/L 0.01 0.01 1.0 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Se21582 NCP ug/L 0.03 0.03 3.0 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Se21582 NCP ug/L 0.01 0.01 2.0 30% Pass
Perfluorooctanoic acid (PFOA) B17-Se21582 NCP ug/L 0.03 0.03 3.0 30% Pass
Perfluorononanoic acid (PFNA) B17-Se21582 NCP ug/L 0.01 0.01 2.0 30% Pass
Perfluorodecanoic acid (PFDA) B17-Se21582 NCP ug/L 0.03 0.03 1.0 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Se21582 NCP ug/L 0.01 0.01 1.0 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Se21582 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se21582 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se21582 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 12
Report Number: 562180-L
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Se07449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Se07449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Se07449 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Se07449 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Se07449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Se07449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Se07449 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Se07449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Se07449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Se07449 CP ug/L 0.07 0.07 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Se07449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Se07449 CP ug/L 0.29 0.28 4.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Se07449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Se07449 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Se07449 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Se07449 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Se07449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 12
Report Number: 562180-L
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionC01 Leachate Fluid Key: 1 - pH 5.0; 2 - pH 2.9; 3 - pH 9.2; 4 - Reagent (DI) water; 5 - Client sample, 6 - other
N09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 12
Report Number: 562180-L