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FALL 2012 EDITION
3120
. .
.
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1
, ,
: ( 1.2 7
)H = 1/
N = ∙ / 2
P = N / 2 = / ( ∙ 2)
J = N ∙ = (2 ∙ ) / 2
W = J / = (2
∙ ) / 3
C = ∙A
V = W / A = (2 ∙ ) / (3 ∙ A)
Ω = V / A = (2
∙ ) / (3
∙ A2
)F = C / V = (4 ∙ A2) / (2 ∙ )
: ( 1.4 7
)1 = 1010 1 = 105 N ()1 = 1 H = 133.322 P1 = 4.184 J ()C = K 273.15 ()
1 = 0.025 4 ()1 = 105 P ()1 = 6 894.76 P1 B = 1 005.06 JF = 1.8(K 273.15) + 32 ()
1 = 0.453 592 37 ()1 = 101 325 P ()1 V = 1.602 176 53 1019 J1 HP = 745.700 W
: = 1.602 176 53 (14) 1019 C
= 4.803 204 40 (42) 1010 = 2.997 924 58 108 /ε0 = 8.854 187 817 10
12 C2 / (N ∙ 2)G = 9.974 2 (10) 1011 3 / (2 ∙ ) = 1.380 650 5 (24) 10 23 J / K
1016 / K = 6.626 069 3 (11) 1034 J ∙
1027 /2π = ħ = 1.054 571 68 (18) 1034 J ∙
1028 ∙
NA = 6.022 141 5 (10) 1
R = 8.314 472 (15) J / ( ∙ K)V ∙ C / ( ∙ K)
102 L ∙ / ( ∙ K) 107 / ( ∙ K)
= 8.205 746 (15) 105 3 ∙ / ( ∙ K) 102 L ∙ / ( ∙ K)
= 1.987 207 (4) / ( ∙ K)F = 9.648 533 83 (83) 104 C / = 9.109 382 6 (16) 10
31 1028
= 1.672 621 70 (29) 1027
1024
: ( .)M. :
= ±√ = + = = ∑ ̅∑ ̅ = −̅ = ∑ ̅ ∑ ̅ ∑ N , NOT 2!
B C:
=
P :+/− → = + + … / → % = % + % + %… = → % = % = log → = ≈ 0.434 29 .
= ln → = = 10 → = ln10 ≈ 2.302 6 = → =
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2
B S:̅ = ∑ ∝, = µ = ∑ ̅ = ∑
∑
= ∑ ̅ = √ = ∑
= ∑ ∑ = ∑ ∑ ∑ = || + ∑ ∑ ̅ = + +
= + : B, G.,G, P., 1999, , 805807. , !
= ∑ ̅∑ ̅…∑ ̅
= ⋯
S : = ̅ ± √ = | ̅ ̅| ( ) = ℎ ℎ
= || (D T ), = ̅ (G T )
Q: = + 3
=
= 10
= T T:∆ = ∆ − ∆ Δ = − = ∆°/ A B: = − + = = =
= +
= + =
=
E: = = = = ° − ln ° = . log @25°
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3
L: = = ℎ
=
=
%
= log = −log = ℓ = = ℓ + ℓ + ⋯ + ℓ
, =
; =
= : = sinθ = sinθ C: = ≈ = − =
=
=
= = = ./
= = = . = √ −
1 ℎ = = = √ 2 =
*
C K
(0.01)K C
K
(0.01)K C
K
(0.01)K
0 14.938 1.15E15 45 13.405 3.94E14 90 12.428 3.73E13
5 14.727 1.87E15 50 13.275 5.31E14 95 12.345 4.52E13
10 14.528 2.96E15 55 13.152 7.05E14 100 12.265 5.43E13
15 14.340 4.57E15 60 13.034 9.25E14 150 11.638 2.30E12
20 14.163 6.87E15 65 12.921 1.20E13 200 11.289 5.14E12
25 13.995 1.01E14 70 12.814 1.53E13 250 11.191 6.44E12
30 13.836 1.46E14 75 12.712 1.94E13 300 11.406 3.93E12
35 13.685 2.07E14 80 12.613 2.44E13 350 12.30 5.0E13
40 13.542 2.87E14 85 12.520 3.02E13 * U , . F , M . E.. @ 25C: (1013.995 /)2 (0.997 05 /L)2 = 1013.998 M(F CRC H C P, 74 .)
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4
O
S75% 80% 85% 90% 95% 97.50% 99% 99.50% 99.75% 99.90% 99.95%
T
S50% 60% 70% 80% 90% 95% 98% 99% 99.50% 99.80% 99.90%
1 1.000 1.376 1.963 3.078 6.314 12.706 31.821 63.657 127.321 318.309 636.619
2 0.816 1.061 1.386 1.886 2.920 4.303 6.965 9.925 14.089 22.327 31.599
3 0.765 0.978 1.250 1.638 2.353 3.182 4.541 5.841 7.453 10.215 12.924
4 0.741 0.941 1.190 1.533 2.132 2.776 3.747 4.604 5.598 7.173 8.610
5 0.727 0.920 1.156 1.476 2.015 2.571 3.365 4.032 4.773 5.893 6.869
6 0.718 0.906 1.134 1.440 1.943 2.447 3.143 3.707 4.317 5.208 5.959
7 0.711 0.896 1.119 1.415 1.895 2.365 2.998 3.499 4.029 4.785 5.408
8 0.706 0.889 1.108 1.397 1.860 2.306 2.896 3.355 3.833 4.501 5.041
9 0.703 0.883 1.100 1.383 1.833 2.262 2.821 3.250 3.690 4.297 4.781
10 0.700 0.879 1.093 1.372 1.812 2.228 2.764 3.169 3.581 4.144 4.587
11 0.697 0.876 1.088 1.363 1.796 2.201 2.718 3.106 3.497 4.025 4.43712 0.695 0.873 1.083 1.356 1.782 2.179 2.681 3.055 3.428 3.930 4.318
13 0.694 0.870 1.079 1.350 1.771 2.160 2.650 3.012 3.372 3.852 4.221
14 0.692 0.868 1.076 1.345 1.761 2.145 2.624 2.977 3.326 3.787 4.140
15 0.691 0.866 1.074 1.341 1.753 2.131 2.602 2.947 3.286 3.733 4.073
16 0.690 0.865 1.071 1.337 1.746 2.120 2.583 2.921 3.252 3.686 4.015
17 0.689 0.863 1.069 1.333 1.740 2.110 2.567 2.898 3.222 3.646 3.965
18 0.688 0.862 1.067 1.330 1.734 2.101 2.552 2.878 3.197 3.610 3.922
19 0.688 0.861 1.066 1.328 1.729 2.093 2.539 2.861 3.174 3.579 3.883
20 0.687 0.860 1.064 1.325 1.725 2.086 2.528 2.845 3.153 3.552 3.850
21 0.686 0.859 1.063 1.323 1.721 2.080 2.518 2.831 3.135 3.527 3.819
22 0.686 0.858 1.061 1.321 1.717 2.074 2.508 2.819 3.119 3.505 3.792
23 0.685 0.858 1.060 1.319 1.714 2.069 2.500 2.807 3.104 3.485 3.768
24 0.685 0.857 1.059 1.318 1.711 2.064 2.492 2.797 3.091 3.467 3.745
25 0.684 0.856 1.058 1.316 1.708 2.060 2.485 2.787 3.078 3.450 3.725
26 0.684 0.856 1.058 1.315 1.706 2.056 2.479 2.779 3.067 3.435 3.707
27 0.684 0.855 1.057 1.314 1.703 2.052 2.473 2.771 3.057 3.421 3.690
28 0.683 0.855 1.056 1.313 1.701 2.048 2.467 2.763 3.047 3.408 3.674
29 0.683 0.854 1.055 1.311 1.699 2.045 2.462 2.756 3.038 3.396 3.659
30 0.683 0.854 1.055 1.310 1.697 2.042 2.457 2.750 3.030 3.385 3.646
40 0.681 0.851 1.050 1.303 1.684 2.021 2.423 2.704 2.971 3.307 3.551
50 0.679 0.849 1.047 1.299 1.676 2.009 2.403 2.678 2.937 3.261 3.49660 0.679 0.848 1.045 1.296 1.671 2.000 2.390 2.660 2.915 3.232 3.460
80 0.678 0.846 1.043 1.292 1.664 1.990 2.374 2.639 2.887 3.195 3.416
100 0.677 0.845 1.042 1.290 1.660 1.984 2.364 2.626 2.871 3.174 3.390
120 0.677 0.845 1.041 1.289 1.658 1.980 2.358 2.617 2.860 3.160 3.373
∞ 0.674 0.842 1.036 1.282 1.645 1.960 2.326 2.576 2.807 3.090 3.291
D F ( 1 )
C E2010 =T.INV(DF,%)
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5
, 95%
2 3 4 5 6 7 8 9 10 20 30 40 50 100 ∞
2 19.00 19.16 19.25 19.30 19.33 19.35 19.37 19.38 19.40 19.45 19.46 19.47 19.48 19.49 19.50
3 9.55 9.28 9.12 9.01 8.94 8.89 8.85 8.81 8.79 8.66 8.62 8.59 8.58 8.55 8.53
4 6.94 6.59 6.39 6.26 6.16 6.09 6.04 6.00 5.96 5.80 5.75 5.72 5.70 5.66 5.63
5 5.79 5.41 5.19 5.05 4.95 4.88 4.82 4.77 4.74 4.56 4.50 4.46 4.44 4.41 4.37
6 5.14 4.76 4.53 4.39 4.28 4.21 4.15 4.10 4.06 3.87 3.81 3.77 3.75 3.71 3.67
7 4.74 4.35 4.12 3.97 3.87 3.79 3.73 3.68 3.64 3.44 3.38 3.34 3.32 3.27 3.23
8 4.46 4.07 3.84 3.69 3.58 3.50 3.44 3.39 3.35 3.15 3.08 3.04 3.02 2.97 2.93
9 4.26 3.86 3.63 3.48 3.37 3.29 3.23 3.18 3.14 2.94 2.86 2.83 2.80 2.76 2.71
10 4.10 3.71 3.48 3.33 3.22 3.14 3.07 3.02 2.98 2.77 2.70 2.66 2.64 2.59 2.54
20 3.49 3.10 2.87 2.71 2.60 2.51 2.45 2.39 2.35 2.12 2.04 1.99 1.97 1.91 1.84
30 3.32 2.92 2.69 2.53 2.42 2.33 2.27 2.21 2.16 1.93 1.84 1.79 1.76 1.70 1.62
40 3.23 2.84 2.61 2.45 2.34 2.25 2.18 2.12 2.08 1.84 1.74 1.69 1.66 1.59 1.51
50 3.18 2.79 2.56 2.40 2.29 2.20 2.13 2.07 2.03 1.78 1.69 1.63 1.60 1.52 1.44100 3.09 2.70 2.46 2.31 2.19 2.10 2.03 1.97 1.93 1.68 1.57 1.52 1.48 1.39 1.28
∞ 3.00 2.60 2.37 2.21 2.10 2.01 1.94 1.88 1.83 1.57 1.46 1.39 1.35 1.24 1.00
DF (L V)
D F ( S V )
, 99%
2 3 4 5 6 7 8 9 10 20 30 40 50 100 ∞
2 99.00 99.17 99.25 99.30 99.33 99.36 99.37 99.39 99.40 99.45 99.47 99.47 99.48 99.49 99.50
3 30.82 29.46 28.71 28.24 27.91 27.67 27.49 27.35 27.23 26.69 26.50 26.41 26.35 26.24 26.13
4 18.00 16.69 15.98 15.52 15.21 14.98 14.80 14.66 14.55 14.02 13.84 13.75 13.69 13.58 13.46
5 13.27 12.06 11.39 10.97 10.67 10.46 10.29 10.16 10.05 9.55 9.38 9.29 9.24 9.13 9.02
6 10.92 9.78 9.15 8.75 8.47 8.26 8.10 7.98 7.87 7.40 7.23 7.14 7.09 6.99 6.887 9.55 8.45 7.85 7.46 7.19 6.99 6.84 6.72 6.62 6.16 5.99 5.91 5.86 5.75 5.65
8 8.65 7.59 7.01 6.63 6.37 6.18 6.03 5.91 5.81 5.36 5.20 5.12 5.07 4.96 4.86
9 8.02 6.99 6.42 6.06 5.80 5.61 5.47 5.35 5.26 4.81 4.65 4.57 4.52 4.41 4.31
10 7.56 6.55 5.99 5.64 5.39 5.20 5.06 4.94 4.85 4.41 4.25 4.17 4.12 4.01 3.91
20 5.85 4.94 4.43 4.10 3.87 3.70 3.56 3.46 3.37 2.94 2.78 2.69 2.64 2.54 2.42
30 5.39 4.51 4.02 3.70 3.47 3.30 3.17 3.07 2.98 2.55 2.39 2.30 2.25 2.13 2.01
40 5.18 4.31 3.83 3.51 3.29 3.12 2.99 2.89 2.80 2.37 2.20 2.11 2.06 1.94 1.80
50 5.06 4.20 3.72 3.41 3.19 3.02 2.89 2.78 2.70 2.27 2.10 2.01 1.95 1.82 1.68
100 4.82 3.98 3.51 3.21 2.99 2.82 2.69 2.59 2.50 2.07 1.89 1.80 1.74 1.60 1.43
∞ 4.61 3.78 3.32 3.02 2.80 2.64 2.51 2.41 2.32 1.88 1.70 1.59 1.52 1.36 1.00
DF (L V)
D F ( S V )
C E2010 =F.INV(%,DF1,DF2)
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6
80% 90% 95% 96% 98% 99%
3 0.886 0.941 0.970 0.976 0.988 0.994
4 0.679 0.765 0.829 0.846 0.889 0.926
5 0.557 0.642 0.710 0.729 0.780 0.821
6 0.482 0.560 0.625 0.644 0.698 0.740
7 0.434 0.507 0.568 0.586 0.637 0.680
8 0.399 0.468 0.526 0.543 0.590 0.634
9 0.370 0.437 0.493 0.510 0.555 0.598
10 0.349 0.412 0.466 0.483 0.527 0.568
11 0.332 0.392 0.444 0.460 0.502 0.542
12 0.318 0.376 0.426 0.441 0.482 0.522
13 0.305 0.361 0.410 0.425 0.465 0.503
14 0.294 0.349 0.396 0.411 0.450 0.488
15 0.285 0.338 0.384 0.399 0.438 0.47516 0.277 0.329 0.374 0.388 0.426 0.463
17 0.269 0.320 0.365 0.379 0.416 0.452
18 0.263 0.313 0.356 0.370 0.407 0.442
19 0.258 0.306 0.349 0.363 0.398 0.433
20 0.252 0.300 0.342 0.356 0.391 0.425
21 0.247 0.295 0.337 0.350 0.384 0.418
22 0.242 0.290 0.331 0.344 0.378 0.411
23 0.238 0.285 0.326 0.338 0.372 0.404
24 0.234 0.281 0.321 0.333 0.367 0.399
25 0.230 0.277 0.317 0.329 0.362 0.393
26 0.227 0.273 0.312 0.324 0.357 0.388
27 0.224 0.269 0.308 0.320 0.353 0.384
28 0.220 0.266 0.305 0.316 0.349 0.380
29 0.218 0.263 0.301 0.312 0.345 0.376
30 0.215 0.260 0.298 0.309 0.341 0.372
C L
F A. C., V. 63, N. 2, J. 15, 1991
95% 97.5% 99%
3 1.15 1.15 1.15
4 1.46 1.48 1.49
5 1.67 1.71 1.75
6 1.82 1.89 1.94
7 1.94 2.02 2.10
8 2.03 2.13 2.22
9 2.11 2.21 2.32
10 2.18 2.29 2.41
12 2.29 2.41 2.55
14 2.37 2.51 2.66
16 2.44 2.59 2.75
18 2.50 2.65 2.82
20 2.56 2.71 2.8830 2.75 2.91 3.10
F : V. B, T.L, O S D, 3 , W S P M S, 1995
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A(OH)3 () 3 10
34 (0.5 M) B(BO3)2 7.8 10
6
BCO3 5.0 109
BCO4 2.1 1010
BF2 1.5 106
(20C) BHPO4 (Ý B2+ + HPO4
2) 1.7 106
B(OH)2.8H2O 3 104
B(IO3)2 1.57 109
(20C, 0.1 M) BC2O4 1 106
BSO4 1.1 1010
CCO3 1.8 1014
C2F(CN)6 8.5 1045
C(OH)2 () 4.5 1015
CC2O4 9 108
CS 1 1027
C(IO3)2 2.3 108
CCO3 () 4.5 109
CCO3 () 6.0 109
CF2 3.9 1011
CHPO4.2H2O (Ý C2+ + HPO4
2) 2.6 107
C(OH)2 6.5 106
C(IO3)2 7.1 107
CC2O4.H2O 1.7 109
(20C, 0.1 M) CC2O4 1.3 108
C3(PO4)2 1 1026
CSO4 2.4 105
(I) C2S 3 10
49
(III) C(OH)3 6 1022
(III) C(IO3)3 1.4 1011
(III) (0.1 M) C(OH)3 1.6 1030
(III) (0.5 M) C(IO3)3 5 106
(II) CCO3 1.0 1010
(II) C(OH)2 1.3 1015
(II) CS () 5 1022 (II) CS () 3 1026 (III) (19C) C(OH)3 3 10
45 (I) CN3 4.9 10
9 (I) CB 5 109
(I) CC 1.9 107 (I) CI 1 1012
(I) C2O (Ý 2C+ + 2OH) 4 1030
(I) C2O 2 1015
(I) (5 M) CSCN 4.0 1014 (II) CCO3 2.3 10
10
(II) CCO4 2.1 1010
(II) C(OH)2 4.8 1020
(II) CS 8 1037 G(OH)3 () 10
37 (1 M) GPO4 1 10
21
(III) A(OH)3 3 106
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I(OH)3 1.3 1037
(1 M) IPO4 2.3 1022
I2S3 4 1070
(II) FCO3 2.1 1011
(II) F(OH)2 7.9 1016
(II) F3(PO
4)
2.8H
2O 1 1036
(II) FS 8 1019 (III) F(OH)3 1.6 10
39 (III) FPO4.2H2O 4 10
27 L2(CO3)3 4.0 10
34
LF3 2 1019
L(OH)3 2 1021
L(IO3)3 1.0 1011
(20C, 0.1 M) L2(C2O4)3 1 1025
(0.5 M) LPO4 3.7 1023
(II) P(BO3)2 7.9 106
(II) PB2 2.1 106
(II) PCO3 7.4 1014 (II) PC2 1.7 10
5 (II) PCO4 3 10
13 (II) P2F(CN)6 8.5 10
45
(II) PF2 3.6 108
(II) P(IO3)2 2.5 1013
(II) PI2 7.9 109
(II) PC2O4 8.5 109
(II) PO () (Ý P2+ + 2OH) 8 1016
(II) PO () (Ý P2+ + 2OH) 5 1016
(II) P3(PO4)2 3.0 1044
(II) PSO4 6.3 107(II) PS 3 1028 LF 1.7 103
MNH4PO4 3 1013
MCO3 3.5 108
M(OH)2 7.1 1012
MF2 7.4 109
MHPO4.3H2O (Ý M2+ + HPO4
2) 1.7 106
M(OH)2 () 6 1010
M(OH)2 ( ) 7.1 1012
(II) MCO3 5.0 1010
(II) M(OH)2 1.6 1013
MS () 3 1011 MS () 3 1014 (HCH3)I 3.5 10
12 (HCH3CH2)I 7.8 10
5 (H2)3(C(CN)6)2 3.9 10
26 (I) H2(N3)2 7.1 10
10 (I) H2B2 5.6 10
23
(I) H2CO3 8.9 1017
(I) H2C2 1.2 1018
(I) H2CO4 2.1 1010
(I) H2(CN)2 5 10
40
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(I) H2HPO4 (Ý H22+ + HPO4
2) 4.0 1013
(I) H2(IO3)2 1.3 1018
(I) H2I2 4.6 1029
(I) H2SO4 7.4 107
(I) H2(SCN)2 2.8 1020
(II) (0.5 M) HB2 1.3 10
19
(II) HO () (Ý H2+ + 2OH) 3.6 1026
(II) HS () 2 1053 (II) HS () 5 1054 (II) NCO3 1.3 10
7
(II) N(OH)2 6 1016
NS () 4 1020 NS () 1.3 1025 NS () 3 1027 (II) P(N3)2() 4.9 10
9
(II) P(OH)2 3 1029
RSO4 4.3 1011
A3AO4 6 1023
AN3 2.8 109
ABO3 5.5 105
AB 5.0 1013 A2CO3 8.1 10
12
AC 1.82 1010 A2CO4 2.1 10
10
A3C(CN)6 3.9 1026
ACN 2.2 1016 A4F(CN)6 8.5 10
45
AIO3 3.1 108
AI 8.3 1017 A2C2O4 3.5 10
11
A2O (Ý 2A+ + 2OH) 3.8 1016
A3PO4 2.8 1018
A2SO4 1.5 105
A2S 8 1051
ASCN 1.1 1012 SCO3 9.3 10
10 SF2 2.6 10
9
(20C) SHPO4 (Ý S2+ + HPO4
2) 1.7 106
S(IO3)2 3.3 107
SC2O4 5 108 (20C, 0.1 M) SC2O4 4 10
7 SSO4 3.2 10
7 (I) TN3 2.2 10
4
(I) TBO3 1.7 104
(I) TB 3.6 106
(I) TC 1.8 104 (I) T2CO4 2.1 10
10
(I) TIO3 3.1 106
(I) TI 5.9 108 (I) T2S 6 10
22
(I) TSCN 1.6 104
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TF4 5 1029
(0.5 M) T(IO3)4 2.4 1015
(1 M) T(C2O4)2 4.2 1022
(II) (4 M) SI2 8.3 106
(II) SO (Ý S2+ + 2OH) 6 1027
(II) SS 1.3 10
26
(IV) UO2 (Ý U
4+ + 4OH) 6 1057
UO2(OH)2 (Ý UO22+ + 2OH) 4 1023
(0.2 M) UO2(IO3)2 (Ý UO22+ + 2IO3
) 9.8 108
(20C, 0.1 M) UO2C2O4 (Ý UO22+ + C2O4
2) 2.2 109
(III) V(OH)3 4.0 1035
(V) () VO(OH)2 (Ý VO2+ + 2OH) 3 1024
(VO)3(PO4)2 (Ý 3VO2+ + 2PO4
3) 8 1026
Y2(CO3)3 2.5 1031
Y(OH)3 6 1024
Y(IO3)3 7.1 1011
ZCO3 1.0 1010
Z2F(CN)6 8.5 1045
Z(OH)2 3.0 1016
Z(IO3)2 3.9 106
ZC2O4 8 109
Z3(PO4)2.4H2O 5 1036
ZS () 2 1025 ZS () 3 1023 F H, 7 E., C, 6 E., S/W/H, 7 E.
1 2 3
CH3CO2H 1.75 105
NH4+ 5.70 1010
C6H5NH3+ 2.51 105
H3AO4 5.8 103 1.1 107 3.2 1012
H3AO3 5.1 1010
C6H5CO2H 6.28 105
H3BO3 5.81 1010
CH3CH2CH2CO2H 1.52 105
H2CO3 4.45 107 4.69 1011
CCH2CO2H 1.36 103 C3H5O(CO2H)3 7.45 10
4 1.73 105 4.02 107 (CH3)2NH2
+ 1.68 1011 HOCH2CH2NH3
+ 3.18 1010 CH3CH2NH3
+ 2.31 1011 +NH3CH2CH2NH3
+ 1.42 107 1.18 1010 EDTA C6H12N2(CO2H)4 1.0 10
2 2.1 103 6.9 107 (K4 = 5.5 10
11)
HCO2H 1.80 104
C2H2(CO2H)2 8.85 104 3.21 105
HOCH2CO2H 1.47 104
H2NNH3+
1.05 108
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1 2 3
HN3 2.2 105
HCN 6.2 1010 HF 6.8 104 H2O2 2.2 10
12
H2S 9.6 108
1.3 1014
HONH3
+ 1.10 106 HCO 3.0 108 HIO3 0.17 CH3CHOHCO2H 1.38 10
4 C2H2(CO2H)2 1.3 10
2 5.9 107 CH2CHOH(CO2H)2 3.48 10
4 8.00 106 HO2CCH2CO2H 1.42 10
3 2.01 106 C6H5CHOHCO2H 4.0 10
4 CH3NH3
+ 2.3 1011 HNO2 7.1 10
4
H2C2O4 0.0560 5.42 10
5
H5IO6 0.02 5 109
C6H5OH 1.00 1010
H3PO4 7.11 103 6.32 108 4.5 1013
H3PO3 0.03 1.62 107
() C6H4(CO2H)2 1.12 103 3.91 106
(NO2)3C6H2OH 0.43 C5H11NH
+ 7.50 1012 CH3CH2CO2H 1.34 10
5 C5H5NH
+ 5.90 106 CH3COCO2H 3.2 10
3 C6H4(OH)CO2H 1.06 10
3
C2H4(CO2H)2 6.21 105 2.31 106 H2NSO3H 0.103 H2SO4 1.02 10
2 H2SO3 1.23 10
2 6.6 108 (CHOH)2(CO2H)2 9.20 10
4 4.31 105 HSCN 0.13 H2S2O3 0.3 2.5 10
2 C3CCO2H 3 (CH3)3NH
+ 1.58 1010
A 4.47103
1.351010
A 9.77103 9.121010 3.311013 A 9.55103 1.58109 A A 7.94103 1.511010 1.38104 C 8.91103 5.621011 1.00108 G A 7.94103 3.391010 8.51105 G 6.76103 7.411010 G 4.47103 1.661010 H 1.70102 6.611010 7.94107 I 4.79103 1.741010 L 4.68103 1.821010 L 6.61103 1.12109 2.951011 M 5.25103 6.171010
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P 2.63103 5.751010 P 1.00102 2.511011 S 6.17103 7.081010 T 8.13103 7.941010 T 4.17103 4.071010 T 6.31103 7.761010 8.511011 V 5.13103 1.911010
/
0.01.6 0.21.8 0.21.8 1.0 / 1.2 2.8 1.65 1.22.8 1.51
, 2.23.6 2.9 4.0 3.1 4.4 3.46 3.05.0 3.04.6 4.10 3.44.8 4.34 3.8 5.4 4.66 4.8 6.0 5.00 4.86.4 6.25 5.2 6.8 6.12 5.67.6 5.08.0
6.0 7.6 7.10 6.4 8.0 7.81 6.88.0 7.28.8 8.46 α 7.3 8.7 7.6 9.2 8.32 8.0 9.6 8.90 8.0 9.6 9.5 8.3 10.5 9.7 GG 10.1 12.0 11.0 R 10.1 12.0
10.813.0 O 11.112.7
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()
A A3+ + 3 Ý A() 1.677
AC2+ + 3 Ý A() + C 1.802
AF63 + 3 Ý A() + 6 F 2.069
A(OH)4 + 3 Ý A() + 4 OH 2.328
A S2O5() + 6 H+ + 4 Ý 2 SO+ + 3 H2O 0.581
SO+ + 2 H+ + 3 Ý S() + H2O 0.208
S2O3() + 6 H+ + 6 Ý 2 S() + 3 H2O 0.147
S() + 3 H+ + 3 Ý SH3() 0.510
A H3AO4() + 2 H+ + 2 Ý H3AO3() + H2O 0.575
H3AO3() + 3 H+ + 3 Ý A() + 3 H2O 0.2475
A() + 3 H+ + 3 Ý AH3() 0.238
B B2+ + 2 + H Ý B()( H) 1.717
B2+ + 2 Ý B() 2.906B B2+ + 2 Ý B() 1.968
B BO+ + 2 H+ + 3 Ý B() + H2O 0.320
B3+ + 3 Ý B() 0.308
BC4 + 3 Ý B() + 4 C 0.16
BOC() = 2 H+ + 3 Ý B() + H2O + C 0.160
B 2 B() + 6 H+ + 6 Ý B2H6() 0.150
B4O72 + 14 H+ + 12 Ý 4 B() + 7 H2O 0.792
B(OH)3 + 3 H+ + 3 Ý B() + 3 H2O 0.889
B BO4 + 2 H+ + 2 Ý BO3
+ H2O 1.745
HOB + H+ + Ý B2(ℓ) + H2O 1.584
BO3 + 6 H+ + 5 Ý B2(ℓ) + 3 H2O 1.513
BO3 + 6 H+ + 6 Ý B + 3 H2O 1.44
B2() + 2 Ý 2 B 1.098
B2(ℓ) + 2 Ý 2 B 1.078
B3 + 2 Ý 3 B 1.062
BO + H2O + 2 Ý B + 2 OH 0.766
BO3 + 3 H2O + 6
Ý B + 6 OH 0.613
C C2+ + 2 Ý C( H) 0.352
C2+
+ 2
Ý C() 0.402C(C2O4)() + 2
Ý C() + C2O42 0.522
C(C2O4)22+ + 2 Ý C() + 2 C2O4
2 0.572
C(NH3)42+ + 2 Ý C() + 4 NH3 0.613
CS() + 2 Ý C() + S2 1.175
C C() + 2 H+ + 2 Ý CH2() 0.776
C2+ + 2 + H Ý C()( H) 2.003
C2+ + 2 Ý C() 2.868
C()+ + 2 Ý C() + 2.891
CSO4() + 2 Ý C() + SO4
2 2.936
C()() + 2 Ý C() + 2 3.608
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C C2H2() + 2 H+ + 2 Ý C2H4() 0.731
C6H4O2 () + 2 H+ + 2 Ý C6H6O2 () 0.700
CH3OH(ℓ) + 2 H+ + 2 Ý CH4() + H2O 0.583
D + 2 H+ + 2 Ý A + H2O 0.390
(CN)2() + 2 H+ + 2 Ý 2 HCN() 0.373
H2CO + 2 H+ + 2 Ý CH3OH 0.237
C() + 4 H+ 4 Ý CH4() 0.1315
HCO2H + 2 H+ + 2 Ý H2CO + H2O 0.029
CO2() + 2 H+ + 2 Ý CO() + H2O 0.1038
CO2() + 2 H+ + 2 Ý HCO2H 0.114
2 CO2() + 2 H+ + 2 Ý H2C2O4 0.432
C C4+ + Ý C3+ 1.72
C4+ + Ý C3+ (1F HCO4) 1.70
C4+
+
Ý
C3+
(1F H2SO4) 1.44C4+ + Ý C3+ (1F HNO3) 1.61
C4+ + Ý C3+ (1F HC) 1.28
C3+ + 3 Ý C() 2.336
C C+ + +H Ý C()( H) 1.950
C+ + Ý C() 3.026
C HCO2 + 2 H+ + 2 Ý HOC + H2O 1.674
HCO + H+ + Ý C2() + H2O 1.630
CO3 + 6 H+ + 5 Ý C2() + 3 H2O 1.458
C2() + 2 Ý 2 C 1.396
C2() + 2 Ý 2 C 1.3604CO4
+ 2 H+ + 2 Ý CO3 + H2O 1.226
CO3 + 3 H+ + 2 Ý HCO2
+ H2O 1.157
CO3 + 2 H+ + Ý CO2 + H2O 1.130
CO2 + Ý CO2
1.068
C C2O72 + 14 H+ + 6 Ý 2 C3+ + 7 H2O 1.36
CO42 + 4 H2O + 3
Ý C(OH)3(, ) + 5 OH 0.12
C3+ + Ý C2+ 0.42
C3+ + 3 Ý C() 0.74
C
2+
+ 2
Ý
C() 0.89C C3+ + Ý C2+ 1.92
C3+ + Ý C2+ (4 F HNO3) 1.850
C3+ + Ý C2+ (8 F H2SO4) 1.817
C(NH3)5(H2O)3+ + Ý C(NH3)5(H2O)
2+ (1 F NH4NO3) 0.37
C(NH3)63+ + Ý C(NH3)6
2+ 0.1
COH+ + H+ + 2 Ý C() + H2O 0.003
C2+ + 2 Ý C() 0.282
C(OH)2() + 2 Ý C() + 2 OH 0.746
C C+ + Ý C() 0.518
C2+ + 2 Ý C() 0.339
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C () C2+ + Ý C+ 0.161
CC() + Ý C() + C 0.137
C2+ + I + Ý CI() 0.86
C(IO3)2() + 2 Ý C() + C 0.079
C()2+ + Ý C() + 2 0.119
CI() + Ý C() + I 0.185
C(EDTA)2 + 2 Ý C() + EDTA4 0.216
C(OH)2() + 2 Ý C() + 2 OH 0.222
C(CN)2 + Ý C() + 2 CN 0.429
C(CN) + Ý C() + CN 0.639
D D3+ + 3 Ý D() 2.295
E E3+ + 3 Ý E() 2.331
E E3+ + Ý E2+ 0.35
E3+
+ 3
Ý
E() 1.991E2+ + 2 Ý E() 2.812
F F2() + 2 H+ + 2 Ý 2 HF() 3.06
F2() + 2 Ý 2 F 2.890
F2O() + 2 H+ + 4 Ý 2 F + H2O 2.168
G G3+ + 3 Ý G() 2.279
G G3+ + 3 Ý G() 0.549
GOOH() + H2O + 3 Ý G() + 3 OH 1.320
G G2+ + 2 Ý G() 0.1
H4GO4 + 4 H+ + 4 Ý G() + 4 H2O 0.039
G A+ + Ý A() 1.69A3+ + 2 Ý A+ 1.41
AC2 + Ý A() + 2 C 1.154
AC4 + 2 Ý AC2
+ 2 C 0.926
H H 4+ + 4 Ý H() 1.55
HO2() + 4 H+ + 4 Ý H() + 2 H2O 1.591
H H3+ + 3 Ý H() 2.33
H 2 H+ + 2 Ý H2() 0.000
2 H+ + 2 Ý H2() (1M HC HCO4) 0.005
H2O +
Ý
H2() + OH
0.8280I I3+ + 3 + H Ý I( H) 0.313
I3+ + 3 Ý I() 0.338
I3+ + 2 Ý I+ 0.444
I(OH)3() + 3 Ý I() + 3 OH 0.99
I IO4 + 2 H+ + 2 Ý IO3
+ H2O 1.589
H5IO6 + 2 H+ + 2 Ý HIO3 + 3 H2O 1.567
HOI + H+ + Ý I2() + H2O 1.430
IC3() + 3 Ý I2() + 3 C
1.28
IO3 + 2 C + 6 H+ + 4 Ý IC2
+ 3 H2O 1.24
IC() + Ý I2() + C 1.22
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I () IO3 + 6 H+ + 5 Ý I2() + 3 H2O 1.210
IO3 + 5 H+ + 4 Ý HOI + 2 H2O 1.154
IC2 + Ý I2() + C
1.056
I2() + 2 Ý 2 I 0.620
I2() + 2 Ý 2 I 0.535
I3 + 2 Ý 3 I 0.535
IO3 + 3 H2O + 6
Ý I + 6 OH 0.269
I IC62 + Ý IC6
3 (1 F HC) 1.026
IB62 + Ý IB6
3 (2 F NB) 0.947
IC62 + 4 Ý I() + 6 C 0.835
IO2() + 4 H+ + 4 Ý I() + 2 H2O 0.73
II62 + Ý II6
3 (1 F KI) 0.485
I F()33+ + Ý F()3
2+ 1.147
F()33+
+
Ý
F()32+
1.120FOH2+ + H+ + Ý F2+ + H2O 0.900
FO42 + 3 H2O + 3
Ý FOOH() + 5 OH 0.80
F3+ + Ý F2+ 0.771
F3+ + Ý F2+ (1 N HC) 0.732
F3+ + Ý F2+ (1 N HCO4) 0.767
F3+ + Ý F2+ (1 N HNO3) 0.746
F3+ + Ý F2+ (1 N H2SO4) 0.68
FOOH() + 3 H+ + Ý F2+ + 2 H2O 0.74
F+ + Ý 0.400
F(CN)63 + Ý F(CN)64 (1M HCO4 H2SO4) 0.72F(CN)6
3 + Ý F(CN)64 (1M HC) 0.71
F(CN)63 + Ý F(CN)6
4 0.356
F()3+ + Ý F()2+ 0.240
FOH+ + H+ + 2 Ý F() + H2O 0.16
F2+ + 2 Ý F() 0.44
FCO3() + 2 Ý F() + CO3
2 0.756
L L3+ + 3 Ý L() 2.379
L()+ + 3 Ý L() + 2 2.601
L P
4+
+ 2
Ý
P
2+
(1 N HNO3) 1.69PO2() + 4 H+ + SO4
2 + 2 Ý PSO4() + 2 H2O 1.685
PO2() + 4 H+ + 2 Ý P2+ + 2 H2O 1.458
3 PO2() + 2 H2O + 4 Ý P3O4() + 4 OH
0.269
P3O4() + H2O + 2 Ý 3PO(, ) + 2 OH 0.224
P3O4() + H2O + 2 Ý 3PO(, ) + 2 OH 0.207
P2+ + 2 Ý P() 0.126
P2+ + 2 Ý P() (1 N HCO4) 0.14
P2+ + 2 Ý P() (1 N H2SO4) 0.29
PF2() + 2 Ý P() + 2 F 0.350
PSO4() + 2 Ý P() + SO42 0.355
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L L+ + + H Ý L( H) 2.195
L+ + Ý L() 3.040
L L3+ + 3 Ý L() 2.28
M M2+ + 2 + H Ý M( H) 1.980
M(OH)+ + H+ + 2 Ý M() + H2O 2.022
M2+ + 2 Ý M() 2.360
M(C2O4)() + 2 Ý M() + C2O4
2 2.493
M(OH)2() + 2 Ý M() + 2 OH 2.690
M MO4 + 4 H+ + 3 Ý MO2() + 2 H2O 1.692
M3+ + Ý M2+ 1.56
M3+ + Ý M2+ (7.5 M H2SO4) 1.51
MO4 + 8 H+ + 5 Ý M2+ + 4 H2O 1.507
M2O3() + 6 H+ + 2 Ý 2 M2+ + 3 H2O 1.485
MO2() + 4 H+
+ 2
Ý
M2+
+ 2 H2O 1.230M(EDTA) + Ý M(EDTA)2 0.825
MO4 + Ý MO4
2 0.56
3 M2O3() + H2O + 2 Ý 2 M3O4() + 2 OH
0.002
M3O4() + 4 H2O + 2 Ý 3 M(OH)2() + 2 OH
0.352
M2+ + 2 Ý M() 1.182
M(OH)2() + 2 Ý M() + 2 OH 1.565
M 2 H2+ + 2 Ý H22+ 0.908
2 H2+ + 2 Ý H22+ (1M HCO4) 0.907
H2+ + 2 Ý H(l ) 0.852
H22+ + 2 Ý 2 H(l ) 0.796H2
2+ + 2 Ý 2 H(l ) (1M HCO4) 0.776
H22+ + 2 Ý 2 H(l ) (1M H2SO4) 0.674
H22+ + 2 Ý 2 H(l ) (1M HC) 0.274
H2SO4() + 2 Ý 2 H(l ) + SO4
2 0.614
H2C2() + 2 Ý 2 H(l ) + 2 C 0.268
H2C2() + 2 Ý 2 H(l ) + 2 C (0.1M KC) 0.334
H2C2() + 2 Ý 2 H(l ) + 2 C (1M KC) 0.282
H2C2() + 2 Ý 2 H(l ) + 2 C (S KC, SCE) 0.241
M H(OH)3
+ 2
Ý
H(l
) + 3 OH
0.236H(OH)2 + 2 Ý H(l ) + 2 OH 0.206
H2B2() + 2 Ý H(l ) + 2 OH 0.140
HO(, ) + H2O + 2 Ý H(l ) + 2 OH 0.0983
HO(, ) + H2O + 2 Ý H(l ) + 2 OH 0.0977
M MO42 + 2 H2O + 2
Ý MO2() + 4 OH 0.818
MO42 + 4 H2O + 6
Ý M() + 8 OH 0.926
MO2() + 2 H2O + 4 Ý M() + 4 OH 0.980
N N3+ + 3 Ý N() 2.323
N NO3+ + 2 H+ + Ý NO2
2+ + H2O 2.04
NO22+ + Ý NO2+ 1.236
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N () NO22+ + 4 H+ + Ý N4+ + 2 H2O 0.567
N4+ + Ý N3+ 0.157
N3+ + 3 Ý N() 1.768
N N(OH)3() + 3 H+ + Ý N2+ + 3 H2O 2.08
NOOH() + 3 H+ + Ý N2+ + 2 H2O 2.05
N2+ + 2 Ý N() 0.236
N(CN)42 + Ý N(CN)3
2 + CN 0.401
N(OH)2() + 2 Ý N() + 2 OH 0.714
N N2O5() + H+ + Ý NO2() + H2O 0.248
N2O5() + 5 H+ + 5 Ý N() + 52 H2O 0.601
NO2() + 2 H+ + 2 Ý NO() + H2O 0.646
NO2() + 4 H+ + 4 Ý N() + 2 H2O 0.690
N HN3 + 3 H+ + 2 Ý N2() + NH4
+ 2.079
N2O() + 2 H+
+ 2
Ý N2() + H2O 1.7692 NO() + 2 H+ + 2 Ý N2O() + H2O 1.587
NO+ + Ý NO() 1.46
2 NH3OH+ + H+ + 2 Ý N2H5
+ + 2 H2O 1.40
NH3OH+ + 2 H+ + 2 Ý NH4
+ + H2O 1.33
N2H5+ + 3 H+ 2 Ý 2 NH4
+ 1.250
HNO2 + H+ + Ý NO() + H2O 0.984
NO3 + 4 H+ + 3 Ý NO() + 2 H2O 0.955
NO3 + 3 H+ + 2 Ý HNO2 + H2O 0.940
NO3 + 3 H+ + 2 Ý HNO2 + H2O (1 M HNO3) 0.92
NO3 + 2 H+ + Ý N2O4() + H2O 0.798
N2() + 8 H+ + 6 Ý 2 NH4
+ 0.274
N2() + 5 H+ + 4 Ý N2H5
+ 0.214
N2() + 2 H2O + 4 H+ + 2 Ý 2 NH3OH
+ 1.833
2 N2 + H
+ + Ý HN3 3.334
O OO4() + 8 H+ + 8 Ý O() + 4 H2O 0.834
OC62 + Ý OC6
3 (1 F HC) 0.85
O OH + H+ + Ý H2O 2.56
O() + 2 H+ + 2 Ý H2O 2.4301
O3() + 2 H+
+ 2
Ý O2() + H2O 2.075H2O2() + 2 H
+ + 2 Ý 2 H2O 1.763
HO2 + H+ + Ý H2O2 1.44
O2() + 2 H+ + 2 Ý H2O 1.2291
HO2 + H2O + 2
Ý 3 OH 0.88
O2() + 2 H+ + 2 Ý H2O2 0.695
O2() + H+ + Ý HO2 0.05
P P2+ + 2 Ý P() 0.915
PO() + 2 H+ + 2 Ý P() + H2O 0.79
PC64 + 2 Ý P() + 6 C 0.615
PO2() + H2O + 2 Ý PO() + 2 OH 0.64
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P P4(, ) + 3 H+ + 3 Ý PH3() 0.046
P4(, ) + 3 H+ + 3 Ý PH3() 0.088
H3PO4 + 2 H+ + 2 Ý H3PO3 + H2O 0.30
H3PO4 + 5 H+ + 5 Ý P4(, ) + 4 H2O 0.402
H3PO4 + 2 H+ + 2 Ý H3PO2 + H2O 0.48
H3PO2 + H+ + Ý P4() + 2 H2O 0.51
P P2+ + 2 Ý P() 1.18
PO2() + 4 H+ + 4 Ý P() + 2 H2O 0.92
PC42 + 2 Ý P() + 4 C 0.755
PC62 + 2 Ý PC4
2 + 2 C 0.68
P PO2+ + Ý PO2() 1.585
P4+ + Ý P3+ 1.006
PO22+ + 4 H+ + 2 Ý P4+ + 2 H2O 1.000
PO22+
+
Ý
PO2+
0.966PO2() + 4 H
+ + 4 Ý P() + 2 H2O 1.369
P3+ + 3 Ý P() 1.978
P K+ + + H Ý K( H) 1.975
K+ + Ý K() 2.936
P P4+ + Ý P3+ 3.2
P3+ + 3 Ý P() 2.353
P P3+ + 3 Ý P() 2.30
R R2+ + 2 Ý R() 2.80
R RO4 + 2 H+ + Ý RO3() + H2O 0.72
RO4 + 4 H+ + 3 Ý RO2() + 2 H2O 0.510R R6+ + 3 Ý R3+ (1 F HCO4) 1.48
R4+ + Ý R3+ (3 F H2SO4) 1.44
RC62 + Ý RC6
3 1.2
R3+ + 3 Ý R() 0.76
2 R3+ + 2 Ý R24+ 0.7
RC63 + 3 Ý R() + 6 C 0.44
R R+ + + H Ý R( H) 1.970
R+ + Ý R() 2.943
R RO4
+ 6 H
+
+ 3
Ý
R(OH)22+
+ 2 H2O 1.53R()33+ + Ý R()3
2+ 1.29
RO4() + 8 H+ + 8 Ý R() + 4 H2O 1.032
R2+ + 2 Ý R() 0.8
R3+ + 3 Ý R() 0.60
R3+ + Ý R2+ 0.24
R(NH3)63+ + Ý R(NH3)6
2+ 0.214
S S3+ + 3 Ý S() 2.304
S2+ + 2 Ý S() 2.68
S S3+ + 3 Ý S() 2.09
S SO42 + 4 H+ + 2 Ý H2SO3 + H2O 1.150
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S () H2SO3 + 4 H+ + 4 Ý S() + 3 H2O 0.739
S() + 2 H+ + 2 Ý H2S() 0.082
S() + 2 Ý S2 0.67
S S() + 4 H+ + 4 Ý SH4() 0.147
SO2(, ) + 4 H+ + 4 Ý S() + 2 H2O 0.990
SO2(, ) + 4 H+ + 4 Ý S() + 2 H2O 0.807
SF62 + 4 Ý S() + 6 F 1.24
S A2+ + Ý A+ 1.989
A2+ + Ý A+ (4F HCO4) 2.000
A2+ + Ý A+ (4F HNO3) 1.929
A3+ + 2 Ý A+ 1.9
AO() + H+ + Ý A2O() + H2O 1.40
A+ + Ý A() 0.7993
A+
+
Ý
A() (1M HCO4) 0.792A+ + Ý A() (1M H2SO4) 0.77
A+ + Ý A() (1M HC) 0.228
A2C2O4() + 2 Ý 2 A() + C2O4
2 0.465
AN3() + Ý A() + N3
0.293
AC() + Ý A() + C 0.222
AC() + Ý A() + C (1M KC) 0.228
AC() + Ý A() + C ( KC) 0.197
AB() + Ý A() + B 0.071
A(S2O3)23 + Ý A() + 2 S2O3
2 0.017
AI() + Ý A() + I 0.152A2S() + H
+ + 2 Ý 2 A() + HS 0.272
A(CN)2 + Ý A() + 2 CN 0.31
S N+ + + H Ý N( H) 1.959
N+ + H2() + Ý NH() 2.367
N+ + Ý N() 2.7143
S S2+ + 2 Ý S() 2.889
S S2O82 + 2 Ý 2 SO4
2 2.01
S2O62 + 4 H+ + 2 Ý 2 H2SO3 0.57
4 SO2 + 4 H
+
+ 6
Ý
S4O62
+ 2 H2O 0.539SO2 + 4 H+ + 4 Ý S() + 2 H2O 0.450
H2SO3 + 4 H+ + 4 Ý S() + 3 H2O 0.450
2 H2SO3 + 2 H+ + 4 Ý S2O3
2 + 3 H2O 0.40
SO42 + 4 H+ + 2 Ý H2SO3 + H2O 0.172
S() + 2 H+ + 2 Ý H2S() 0.174
S() + 2 H+ + 2 Ý H2S() 0.144
S4O62 + 2 H+ + 2 Ý 2 HS2O3
0.10
5 S() + 2 Ý S52 0.340
S() + 2 Ý S2 0.476
2 S() + 2 Ý S22 0.50
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2 SO32 + 3 H2O + 4
Ý S2O32 + 6 OH 0.566
SO32 + 3 H2O + 4
Ý S() + 6 OH 0.659
SO42 + 4 H2O + 6
Ý S() + 8 OH 0.751
SO42 + H2O + 2
Ý SO32 + 2 OH 0.936
2 SO32 + 2 H2O + 2 Ý S2O42 + 4 OH 1.130
2 SO42 + 2 H2O + 2
Ý S2O62 + 4 OH 1.71
T T2O5() + 10 H+ + 10 Ý 2 T() + 5 H2O 0.752
T TO4 + 2 H2O + 3
Ý TO2() + 4 OH 0.366
TO4 + 4 H2O + 7
Ý T() + 8 OH 0.474
T TO32 + 3 H2O + 4
Ý T() + 6 OH 0.47
2 T() + 2 Ý T22 0.84
T() + 2 Ý T2 0.90
T T4+ + Ý T3+ 3.1
T3+
+ 3
Ý
T() 2.28T T3+ + 2 Ý T+ 1.280
T3+ + 2 Ý T+ (1 F HCO4) 1.26
T3+ + 2 Ý T+ (1 F HNO3) 1.23
T3+ + 2 Ý T+ (1 F H2SO4) 1.22
T3+ + 2 Ý T+ (1 F HC) 0.77
T+ + Ý T( H, ') 0.294
T+ + Ý T() 0.336
T+ + Ý T() (1M HCO4 H2SO4) 0.33
T+ + Ý T() (1M HC) 0.551
TC() + Ý T() + C 0.557T T4+ + 4 Ý T() 1.826
T T+ + 3 Ý T() 2.319
T S(OH)3+ + 3 H+ + 2 Ý S2+ + 3H2O 0.142
S4+ + 2 Ý S2+ (1 F HC) 0.139
SO2() + 4 H+ + 2 Ý S2+ + 2 H2O 0.094
S(OH)4() + 4 H+ + 4 Ý S() + 4 H2O 0.008
S(OH)2() + 2 H+ + 2 Ý S() + 2 H2O 0.091
S2+ + 2 Ý S() 0.141
SF62
+ 4
Ý
S() + 6 F
0.25S(OH)62 + 2 Ý S(OH)3
+ 3 OH 0.93
SO2() + H2O + 2 Ý SO() + 2 OH 0.961
S() + 4 H2O + 4 Ý SH4() + 4 OH
1.316
T TO2+ + 2 H+ + Ý T3+ + H2O 0.099
TO2+ + 2 H+ + Ý T3+ + H2O (1M H2SO4) 0.04
T3+ + 2 Ý T+ 0.369
T3+ + Ý T2+ 0.9
TO2() + 4 H+ + 4 Ý T() + 2 H2O 1.076
TO2(, ) + 4 H+ + 4 Ý T() + 2 H2O 0.86
TF62 + 4 Ý T() + 6 F 1.191
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()
T () T2+ + 2 Ý T() 1.60
T W(CN)83 + Ý W(CN)8
4 0.457
W6+ + Ý W5+ (12 F HC) 0.26
WO3() + 6 H+ + 6 Ý W() + 3 H2O 0.091
W5+ + Ý W4+ (12 F HC) 0.3
WO2() + 2 H2O + 4 Ý W() + 4 OH 0.982
WO42 + 4 H2O + 4
Ý W() + 8 OH 1.060
U UO2+ + 4 H+ + Ý U4+ + 2 H2O 0.39
UO22+ + 4 H+ + 2 Ý U4+ + 2 H2O 0.273
UO22+ + Ý UO2
+ 0.16
U4+ + Ý U3+ 0.577
U3+ + 3 Ý U() 1.642
V VO2+ + 2 H+ + Ý VO2+ + H2O 1.001
V(OH)4+
+ 2 H+
+
Ý
VO2+
+ 3 H2O 1.00V(OH)4
+ + 2 H+ + Ý VO2+ + 3 H2O (1 M HC HCO4) 1.02
VO2+ + 2 H+ + Ý V3+ + H2O 0.337
V3+ + Ý V2+ 0.255
V3+ + Ý V2+ (1 M HCO4) 0.21
V2+ + 2 Ý V() 1.125
X H4XO6 + 2 H+ + 2 Ý XO3 + 3 H2O 2.38
XF2 + 2 H+ + 2 Ý X() + 2 HF 2.2
XO3 + 6 H+ + 6 Ý X() + 3 H2O 2.1
Y Y3+ + 3 Ý Y() 2.19
Y2+ + 2 Ý Y() 2.76Y Y3+ + 3 Ý Y() 2.38
Z ZO() + 2 H+ + 2 Ý Z() + H2O 0.439
ZOH+ + H+ + 2 Ý Z() + H2O 0.497
Z2+ + 2 Ý Z() 0.762
Z2+ + 2 + H Ý Z( H) 0.801
Z(NH3)42+ + 2 Ý Z() + 4 NH3 1.04
ZCO3() + 2 Ý Z() + CO3
2 1.06
Z(OH)3 + 2 Ý Z() + 3 OH 1.183
Z(OH)42
+ 2
Ý
Z() + 4 OH
1.199Z(OH)2() + 2 Ý Z() + 2 OH 1.249
ZO() + H2O + 2 Ý Z() + 2 OH 1.260
ZS() + 2 Ý Z() + S2 1.405
Z Z4+ + 4 Ý Z() 1.539
ZO2() + 4 H+ + 4 Ý Z() + 2H2O 1.4
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