AKRO-PLASTIC GmbH Member of the Feddersen Group
AKROMID® Lite and AKROMID® XtraLite – Lower-density PolyamideCompounds
For the last 28 years AKRO-PLASTIC GmbH has been a developer and manufacturer of high-quality tech-nical compounds specialising in the field of polyamides. The constant demand for weight reduction has resulted in an increase in use of plastics with a lower density, for ex-ample polypropylenes. The auto-motive sector in particular focuses on low-density plastics in its att-empt to reduce fleet consumption and carbon dioxide emissions. The properties of polypropylene alone are inadequate which is why techni-cal thermoplastics, e.g. polyamides are used. This is why AKRO-PLASTIC has developed AKROMID® Lite and AKROMID® XtraLite, a range of compounds with similar properties such as polyamide but with a lower density.
AKROMID® Lite and AKROMID® XtraLite bridge the gap between polypropylene and polyamide. In comparison to polypropylene, AKRO-MID® Lite and AKROMID® XtraLite display a superior surface quality, enhanced mechanical properties and higher heat resistance. In com-parison to PA6 compounds, AKRO-MID® Lite and AKROMID® XtraLite score higher in terms of lower den-sity, lower volume price, superior flowability, reduced moisture ab-sorption and enhanced notched im-pact strength. The objective of the AKROPLASTIC developers was to create a technical polyamide com-pound with a lower density while maintaining the typical properties of polyamide.
2 3
AKROMID® Lite and AKROMID® XtraLiteTypical values for black color material at 23 °C
Test specification
Test method Unit
B31 1 L black(4525)
B3 GF 15 1 L black (4670)
B3 GF 25 1 L black (4637)
B3 GF 30 1 L black (4365)
B3 GF 40 1 L black (4581)
B3 GK 30 1 L black (4674)
B3 GM 10/20 1 L black (4646)
B3 GF 30 1 XL black (4366)
Mechanical properties d.a.m. cond. d.a.m. cond. d.a.m. cond. d.a.m. cond. d.a.m. cond. d.a.m. cond. d.a.m. cond. d.a.m. cond.
Tensile modulus 1 mm/min ISO 527-2 MPa 2,300 1,200 5,200 3,700 7,500 5,600 8,800 6,800 11,000 8,400 3,000 1,600 5,100 3,300 8,200 6,800
Yield stress¹/Tensile stress at break 5 mm/min ISO 527-2 MPa 55 40 105 65 135 88 140 105 160 115 45 28 88 55 115 100
Elongation at break 5 mm/min ISO 527-2 % 45 >50 3.3 5.3 3.3 4.5 3 4.5 3.2 4.2 6.5 37 3.4 6 3 3.5
Charpy impact strength 23 °C ISO 179-1/1eU kJ/m² n.b. n.b. 60 54 68 58 70 67 70 66 37 74 46 44 48 48
Charpy impact strength -30 °C ISO 179-1/1eU kJ/m² n.b. n.b. 60 60 67 54 56 55 55 55 34 31 43 42 45 42
Charpy notched impact strength 23 °C ISO 179-1/1eA kJ/m² 6 18 10 12 15 15 15 16 16 18 3.5 6 7 9 12 13
Charpy notched impact strength -30 °C ISO 179-1/1eA kJ/m² 5 4 6 6 13 10 15 13 15 15 2.7 2.3 4 4 13 13
Thermal properties
Melting point DSC, 10 K/min DIN EN 11357-1 °C 220 220 220 220 220 220 220 220
Heat distortion temperature, HDT/A 1.8 MPa ISO 75 °C 60 193 198 200 201 66 165 160
Heat distortion temperature, HDT/B 0.45 MPa ISO 75 °C 140 215 217 217 217 145 208 186
Flammability
Flammability acc.UL 94 0.8 mm UL 94 Class HB HB HB HB HB HB HB HB
Rate acc. FMVSS 302 (<100 mm/min)
>1 mm thickness
FMVSS 302 mm/min + + + + + + + +
Generalproperties
Density 23 °C ISO 1183 g/cm³ 1.04 1.14 1.22 1.26 1.36 1.25 1.26 1.22
Content reinforcement ISO 1172 % 0 15 25 30 40 30 30 30
Moisture absorption 70 °C/62 % r.h. ISO 1110 % 1.9 1.7 1.5 1.4 1.2 1.4 1.4 1.0
Processing
Flowability Flowspiral² AKRO mm 860 1,000 860 715 650 650 730 785
Processing shrinkage, flow
ISO 294-4 % 1.3 0.5 0.3 0.3 0.4 0.7 0.5 0.4
Processing shrinkage, transverse
ISO 294-4 % 1.9 0.9 0.8 0.9 0.9 1.5 1.2 0.9
¹ = yield stress and elongation at break: test speed 50 mm/min ² = mould temperature: 80 °C, melt temperature: 270 °C injection pressure: 750 bar, cross section of flow spiral: 7 mm x 3,5 mm
n.b. = not broken + = passed“cond.” test values = conditioned, measured on test specimens stored according to DIN EN ISO 1110 “d.a.m.” = dry as moulded test values = residual moisture content <0.10 %
4 5
AKROMID® Lite
UnitA31 1 L black(4652)
A3 GF 15 1 L black (4673)
A3 GF 25 1 L black (4672)
A3 GF 30 1 L black (4436)
A3 GF 40 1 L black (4671)
A3 GF 30 4 Lblack (4678)
S3 GF 30 1 L black (4657)
B3 GFM 10/20 1 Lblack (4679)
d.a.m. cond. d.a.m. cond. d.a.m. cond. d.a.m. cond. d.a.m. cond. d.a.m. cond. d.a.m. cond. d.a.m. cond.
MPa 2,300 1,300 5,300 4,000 7,500 5,800 8,400 6,700 11,800 8,600 8,600 7,000 8,200 6,700 5,000
MPa 54 40 110 75 140 100 150 110 170 130 150 110 130 106 80
% 30 >50 3.4 5.3 3.1 4.2 3 4.4 2.9 3.8 2.8 4 3.1 3.8 3.5
kJ/m² n.b. n.b. 68 56 75 67 77 70 80 73 70 66 60 56 40
kJ/m² n.b. n.b. 61 61 78 66 68 73 68 63 37
kJ/m² 6.5 12 10 11 13 14 15 16 17 17 16 16 15 14 15
kJ/m² 5.0 4.0 7 7 11 11 12 17 16 14 15
°C 262 262 262 262 262 262 220 220
°C 65 240 245 246 246 246 182 156
°C 150 258 260 260 260 260 NA 210
Class HB HB HB HB HB HB HB HB
mm/min + + + + + + + +
g/cm³ 1.04 1.14 1.22 1.26 1.36 1.26 1.23 1.27
% 0 15 25 30 40 30 30 30
% 1.7 1.5 1.3 1.2 1 0.7
mm 1,050 1,170 1,150 1,010 910
% 2.5 1.0 0.8 0.7 0.5
% 1.8 1.0 1.0 1.0 1.0
¹ = yield stress and elongation at break: test speed 50 mm/min ² = mould temperature: 80 °C, melt temperature: 270 °C injection pressure: 750 bar, cross section of flow spiral: 7 mm x 3,5 mm
+ = passed“cond.” test values = conditioned, measured on test specimens stored according to DIN EN ISO 1110 “d.a.m.” = dry as moulded test values = residual moisture content <0.10 %
Typical values for black color material at 23 °C
Test specification
Test method
Mechanical properties
Tensile modulus 1 mm/min ISO 527-2
Yield stress¹/Tensile stress at break 5 mm/min ISO 527-2
Elongation at break 5 mm/min ISO 527-2
Charpy impact strength 23 °C ISO 179-1/1eU
Charpy impact strength -30 °C ISO 179-1/1eU
Charpy notched impact strength 23 °C ISO 179-1/1eA
Charpy notched impact strength -30 °C ISO 179-1/1eA
Thermal properties
Melting point DSC, 10 K/min DIN EN 11357-1
Heat distortion temperature, HDT/A 1.8 MPa ISO 75
Heat distortion temperature, HDT/B 0.45 MPa ISO 75
Flammability
Flammability acc.UL 94 0.8 mm UL 94
Rate acc. FMVSS 302 (<100 mm/min)
>1 mm thickness
FMVSS 302
Generalproperties
Density 23 °C ISO 1183
Content reinforcement ISO 1172
Moisture absorption 70 °C/62 % r.h. ISO 1110
Processing
Flowability Flowspiral² AKRO
Processing shrinkage, flow
ISO 294-4
Processing shrinkage, transverse
ISO 294-4
Product Characterisation
6 7
B3 GF 30 1 blackB3 GF 30 1 L black (4365)B3 GF 30 1 XL black (4366)PP GF 30 black
Ageing conditions:Temperature: 70 °CRel. humidity: 62 %Ageing period: 500 h
Tens
ile s
tres
s [M
Pa]
Tens
ile s
tres
s [M
Pa]
0 1 2 3 4 5 6 7
0 1 2 3 4 5 6
0 2 4 6 8 10 12 14
Tensile Test at 23 °C and 80 °C – Conditioned (Fig. 1)
Tensile Test at 23 °C and -30 °C – Conditioned (Fig. 2)
Tensile Test at 23 °C and 120 °C – Conditioned (Fig. 3)
Elongation [%]
Elongation [%]
Elongation [%]
120
100
80
60
40
20
0
250
200
150
100
50
0
120
100
80
60
40
20
0
23 °C
-30 °C
23 °C
80 °C
23 °C
120 °C
Under a practice-related condi-tioned state, the resistance of AKRO MID® Lite and XtraLite com-pounds is within the range of a standard polyamide compound and above a similar PP compound at room temperatures as well as at -30 °C. At average vehicle interior temperatures of +80 °C, the poly-amide products are significantly more resistant than a PP-GF30. For use in the engine compartment, an AKROMID® B3 GF 30 1 L black (4365) is superior to a B3 GF 30 1 black (PA 6/GF 30) with approx. 2/3 resistance and density reduction of approx. 7 % (fig. 5) and more con-stant properties due to the reduced moisture absorption. (fig. 1 - 3)
Resistance Comparison �MPa� (Fig. 4)
Tens
ile s
tren
gth
�MPa
�
200
160
120
80
40
0PA 6 GF 30
WBWAKROMID® B3
GF 30 1 black
PA 6/PP GF 30WBW
AKROMID® B3 GF 30 1 L
black (4365)
AKROMID® B3 GF 30 1 XL
black (4366)
PP GF 30black
AKROMID® A3 GF 30 1
black
AKROMID® A3 GF 30 1 L
black (4436)
freshly mouldedconditionedConditioning in compliance with ISO 1110
Even though a PP GF 30 exhibits the lowest density in the comparative test, its property profile is inade-quate for many applications. In such cases, engineers usually use a PP GF 40 which actually exhibits a similar density to AKROMID® B3 GF 30 1 L black (4365). Above all, this materi-al is more stable and rigid at room temperature (see fig. 4).
The differences become significant-ly more evident at higher tempera-tures where the polyamide-based AKROMID® compounds produce su-perior results to the PP compounds as shown in the tensile strength-
as that of a competitor PA 6 GF 30 (abbreviated to „WBW”) and is con-siderably above the tensile strength of another competitor PA/PP blend. The superiority of AKROMID® com-pound properties in comparison to competitor products lies in the spe-cial, sensitive compound technolo-gy applied by AKRO-PLASTIC GmbH.
By producing a glass-fibre reinforced PA 6/PP, and PA 6.6/PP blend, this not only reduces the density of the material-based compound, the im-pact of conditioning on the mechan-ical properties is minimised signifi-cantly (see fig. 4). This results in a more constant property profile and offers engineers enhanced product design safety.
Thick
ness
�%�
Density Benefit of AKROMID® Lite and XtraLite(Fig. 5)
100
80
60
40
20
0AKROMID® B3
GF 30 1 black
AKROMID® B3 GF 30 1 L
black (4365)
AKROMID® B3 GF 30 1 XL
black (4366)
PP GF 30 black
7 % 10 %
elongation curves (fig. 1, 2 and 3). In comparison to compounds from PP-based counterparts, a far wider spectrum of use is available for AKRO MID® Lite and AKROMID® XtraLite.
In conditions extremely similar to the practical environment, the re-sistance of AKROMID® B3 GF 30 1 L black (4365) is almost at the same level of an AKROMID® B3 GF 30 1 black and above the average values of PA 6 GF 30 compounds from the competition (see fig. 4). The tensile strength of an AKROMID® B3 GF 30 1 XL black (4366) is almost the same
Tens
ile s
tres
s [M
Pa]
Product Characterisation
8 9
The results of the ZnCl₂ resistance comparison are even more alarm-ing. The state of a standard PA6.6-GF30 deteriorates drastically after just a few hours contact with ZnCl₂ solution (see fig. 7). In contrast, AKROMID® A3 GF 30 1 L black (4436) test specimens exhibit no damage even after 200 hrs of expo-sure to the mechanical load of ZnCl₂ in compliance with the SAE stand-ard J2044 (see fig. 8).
Fig. 7: Significant damage to test specimens made from standard PA6.6-GF30 after just 2 hours immersed in ZnCl₂ solution
Fig. 8: No material damage of AKROMID® A3 GF 30 1 L black (4436) even after 200 hours immersed in ZnCl₂ solution
Fig. 6: Tension rods made from various AKROMID® compounds after immersion in CaCl₂ (in accordance with DBL 5416).
The chemical resistance of AKRO-MID® B3 GF 30 1 L black (4365) and AKROMID® B3 GF 30 1 XL black (4366) is particularly superior to calcium chloride (CaCl₂) and like-wise AKROMID® A3 GF 30 1 L black (4436) exhibits better chemical resistance than zinc chloride (ZnCl₂). Among other uses, CaCl₂ is used in road salt to lower the freezing point and as a dust-binding agent. The chemical reaction between zinc parts and salt can form ZnCl₂. Poly-amide 6 and 6.6 compounds are aggressively corroded by the mate-rials listed above which, in extreme cases, can severely impair a part’s functioning.
Although AKROMID® B3 GF 30 1 black test specimens exhibit signifi-cant damage after immersion in CaCl₂ solution (in accordance with DBL 5416), the tension rods made
of AKROMID® B3 GF 30 1 L black (4365) successfully pass the test. No noticeable change is witnessed with AKROMID® B3 GF 30 1 XL black (4366) (see fig. 6).
AKROMID® B3 GF 30 1 black
AKROMID® B3 GF 30 1 GITblack (4599)
AKROMID® B3 GF 30 1 L black (4365)
AKROMID® B3 GF 30 1 XL black (4366)
A special hydrolysis-stabilised AKRO MID® A3 GF 30 4 L black (4678) passed the requirements of the VW TL 52682 with distinction (status: May 2011). This test stipu-lates a bending strength of at least 25 MPa after immersion in coolant G12++ for between 500 and 1000 hours in compliance with TL 774-G. The values achieved by AKROMID® A3 GF 30 4 L black (4678) are con-siderably higher than this brand (see fig. 9).
The reasons for the excellent rat-ings in terms of chemical resistance of AKROMID® B3 GF 30 1 L black (4365), AKROMID® B3 GF 30 1 XL black (4366) and AKROMID® A3 GF 30 1 L black (4436) are the special combination of compounds as well as the sensitive compounding pro-cess.
Bend
ing
stre
ngth
[MPa
]
Resistance Against Coolant G12++ (Fig. 9)
250
200
150
100
5025
0
d.a.m.
B3 GF 30 1 blackB3 GF 30 1 L black (4365)B3 GF 30 1 XL black (4366)PP GF 30 black
Conditioned
B3 GF 30 1 blackB3 GF 30 1 L black (4365)B3 GF 30 1 XL black (4366)PP GF 30 black
Conditioning in compliance with ISO 1110
Not
ched
impa
ct s
tren
gth
[kJ/
m²]
Notched Impact Strength (Fig. 10)
+23 °C -30 °C
18
16
14
12
10
8
6
4
2
0
The user can thus profit from the following key benefits:
• Higher resistance in comparison to PP compounds
• Approx. 7–10 % weight reduction in comparison to PA compounds
• Outstanding chemical resistance in comparison to:
- ZnCl₂ - CaCl₂ - Coolants (hydrolysis)
These and other benefits open up a wide range of applications for AKRO MID® Lite and AKROMID® XtraLite: not only for the automo-tive industry (cable ducts, fan shrouds, fan wheels, radiator tanks, toothed belt covers, controls, cup holders, handles etc.) but also for industrial applications (casings and covers, sleeves, guide rails etc.) or for the electrical and electronic sec-tor (con trols, switches, sensor hous-ings etc.).
Fig. 9: Resistance against coolant G12++ in accordance with VW TL 52682. The amount is far above the recommended minimum threshold.
Exposure time [h]
0 500 1,000
A3 GF 30 4 L black (4678)
In terms of notched impact strength, an important property for part de-sign, AKROMID® B3 GF 30 1 L black
(4365) exceeds the values of a B3 GF 30 1 black (PA 6 GF 30) not just in a dry state but also when conditioned.
The B3 GF 30 1 XL black (4366) ex-hibits its strengths especially at low temperatures (see fig. 10).
Recommended minimum threshold
10 11
Engine Compartment• Cable ducts• Cable brackets• Fan shrouds• Fan wheels• Engine covers• Intake manifolds• Toothed belt covers
Exterior• Rear window release handles• Door handles• Side mirror casings
Interior• Airbag components• Controls• Cup holders• Glove compartment handles• Air duct holders• Multifunction switches• Switch housings• Seat adjustment lever• Sun visor axles • Handle brackets• Transmission housings
Property PA 6 or PA 6.6
AKROMID® Lite
AKROMID® XtraLite PP
Density 0 + + + +++
Volume price + ++ ++ +++
Flowability + ++ +++ +++
Notched impact strength + ++ ++ ++
Cold impact strength ++ ++ + 0
Surface quality (sink marks) ++ ++ + 0
Warpage ++ + + 0
Stability + + + 0
Heat resistance ++ + 0 -
Resistance to moisture absorption 0 + ++ +++
Chemical resistance + ++ ++ +++
Processing ++ ++ ++ ++
Automotive Applications:
ApplicationsBased on the characteristic features and technical properties, the scope of applications can include the fol-lowing:
Processing RecommendationsAKROMID® B3 GF XX* 1 L, AKRO-MID® B3 GF XX* 1 XL and AKRO-MID® A3 GF XX* 1 L can be pro-cessed on commercially available in-
jection moulding machines with standard screws according to the recommendations of the machine manufacturer. Please refer to the
tables below for our recommended machine, tool and dryer settings (see diagram):
AKROMID® B3 GF XX* 1 L + XL AKROMID® A3 GF XX* 1 L
Flange θ1 60–80 °C 60–80 °C
Sector 1 – sector 4 θ2 220–290 °C 260–300 °C
Nozzle θ3 240–300 °C 270–300 °C
Melt temperature θ4 240–290 °C 270–300 °C
Mould temperature θ5 70–100 °C 70–100 °C
Drying θ6 80 °C, 2 up to 4 h 80 °C, 2 up to 4 h
Holding pressure, spec. Phold 300–800 bar 300–800 bar
Back pressure, spec. Pback 50–150 bar 50–150 bar
Phold
Pback
τ< (-30) °C
The specified values are for reference values. For increasing filling contents the higher values should be used.For drying, we recommend using only dry air or a vacuum dryer. Processing moisture levels between 0.02 and 0.1 % are recommended.For AKROMID® delivered in bags, no predrying is required when properly stored. It is recommended to use opened bags completely.Material processed from silo or open boxes may have absorbed moisture and require a longer drying time.
XX* = 0–40 %
Disclaimer: All specifications and information given in this brochure are based on our current knowledge and experience. A legally binding promise of certain characteristics or suitability for a concrete individual case cannot be derived from this information. The information supplied here is not intended to release processors and users from the responsibility of carrying out their own tests and inspections in each concrete individual case. AKRO®, AKROMID®, AKROLEN®, AKROLOY®, AKROTEK® and ICX® are registered trademarks of the Feddersen Group.
Universal• Guide rails• Casings and covers• Handles and levers• Sleeves• Furniture fittings• Hubs for lawnmowers• Energy chains
Electric/Electronic• Controls• Switches• Sensor housings• Coil bodies • Connectors• Multipoint connectors
Industrial Applications:
θ5 θ4 θ3 θ2 θ1 θ6
We Will Be Pleased to Meet You!
AKRO-PLASTIC GmbH Member of the Feddersen Group Industriegebiet Brohltal OstIm Stiefelfeld 156651 NiederzissenGermanyPhone: +49(0)2636-9742-0Fax: +49(0)[email protected] www.akro-plastic.com
For more locations, visit www.akro-plastic.com
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