ADEQARK A N S A SDepartment of Environmental Quality
August 16, 2011
Scott CrumpManager E & P ServicesQuantum Resources Management LLC, Nipper A-I & A-31401 McKinney Street, Suite 2400Houston, Texas 77010
RE: Application for RegistrationAFIN: 14-00734 Registration No.: 2258-A-REG315
Dear Mr. Crump:
The Department has reviewed your facilityJ s application for registration for the facility located atHWY 160 TO 19,T/S TO CR79,GO .4M,T/R GO.4M,T/R TO SITE, Taylor in ColumbiaCounty, Arkansas.
The Department has detennined that the information certified in the application fulfills therequired criteria for registration as specified in Arkansas Air Pollution Control Code (Regulation18), Section 18.315 and other applicable regulations. Your registration number has beenassigned as 2258-A-REG3I5.
This registration is your authority to construct, operate, and maintain the equipment and/orcontrol apparatus as set forth in your registration request received on July 27, 2011. QuantumResources Management LLC, Nipper A-I & A-3 is required to update this registration should thefacility operations or emissions change so that the current registration no longer reflects actualoperationsa
Please maintain a copy of this letter and the application at the facilitya
Sincerely,
Thomas RheaumePennit Branch Manager, Air Division
c: Compliance Monitoring
ARKANSAS DEPARTMENT OF ENVIRONMENTAL QUALITY5301 NORTHSHORE DRIVE / NORTH LITTLE ROCK / ARKANSAS 72118w5317 / TELEPHONE 501-682-0744 / FAX 501-682-0880
www.adeq.state.ar.us
a ENERCONExcellence-Every project. Every day.
July 22, 2011
Arkansas Department of Environmental QualityAir Permitting Section5301 Northshore DriveNorth Little Rock, AR 72118
RE: Registration for Oil and Gas Production FacilityNipper A-1 & A-3 Facility, Columbia County, Arkansas
Dear ADEQ Staff,
Please find enclosed a Registration Application for Nipper A-1 & A-3 Facility located in Columbia County,Arkansas. Quantum Resources Management (QUANTUM) is submitting this Registration pursuant to theArkansas Pollution Code Regulation 18.315 - Registration.
Per the submittal requirements in this application, QUANTUM is submitting a complete, original signedapplication package. Per the registration instructions in 18.315, we expect that ADEO will invoiceQUANTUM for the $200.00 annual fee once the registration is processed.
This property is owned by OR Energy a publicly traded company and as such does not require adisclosure statement. The information can be found on their annual report: http://phx.corporateir.neUExternal.File?item=UGFyZW50SUQ90TMwNjI8Q2hpbGRJRDOtMXxUeXBIPTM=&t=1
The following Sections are included in the application:
Attachment 1: ADEQ Registration FormAttachment 2: Location and Process DescriptionAttachment 3: Location MapAttachment 4: Process Flow DiagramAttachment 5: Emissions Summary and CalculationsAttachment 6: Representative Analytical Results -Mattie Peterson - 5/16/2011
Thank you for your assistance in this matter. Please contact me at 972-484-3854 if you have anyquestions regarding this submittal.
Sincerely,Enercon Services, Inc.
Rickie SalasProject Engineer
Cc: Patrick Navratil, Environmental Asset ManagementScott Crump, Quantum Resources Management
Claudine BendeckSenior Compliance Specialist
12700 Ford Road Suire 200 Dallas, TX 75234 972.484,3854 972.484.8835 enercon.com
Attachment 1ADEQ Registration Form
ADEQArkansas Department of Environmental Quality
AIR DIVISION
REGISTRATION FOR FACILITIES
REGULATION 18.315
March 2009
REGISTRATION FORM
AFIN I I DATE I IFACILITY PHYSICAL LOCATION
Facility Name Nipper A-I & A-3 IPhysical Address or
Section 16, Township 18S, Range 22WLocation
Physical City Taylor
Physical Zip 71861
UTMZone 15 I UTM Easting 472,581 UTM Northing 13 670 166(nearest meter) (nearest meter) , ,
NAICS Code211111 NAICS Description
Oil & Gas Exploration &Production
FACILITY AIR CONTACT
Contact First Name Scott
Contact Last Name Crump
Contact Position Manager E & P Services
Contact Mailing Address 1401 McKinney Street Suite 2400
Contact Mailing City Houston
Contact Mailing State Texas Contact Mailing Zip 77010
Contact Phone # (713) 452-2200 Contact FAX
Contact Email Address [email protected]
INVOICE MAILING ADDRESS
Organization Name Quantum Resources Management LLC
Invoice Contact First Name Scott
Invoice Contact Last Name Crump
Mailing Address 1401 McKinney Street, Suite 2400
Invoice Mailing State Texas Invoice Mailing Zip 77010
Invoice Contact Phone (713) 452-2200 Invoice Contact FAX
2
1. Organization Status of Applicant
Please check the box which appropriately describes the legal organization of the applicant.
Solely Owned Proprietorship 0 Corporation 0 Limited Partnership10
General Partnership D OTHER: ~ Please Specify: ILimited Liability Company
2. lfthe applicant is a corporation, indicate if it is a domestic (Arkansas) corporation or a foreign(chartered outside of Arkansas) corporation. Domestic D Foreign~
3. If the applicant is a corporation, is it currently registered to do business with the Arkansas Secretary ofState? Yes~ No D
4. Registration Information
New Facility 0 IExisting Facility ~
Existing Facility with an Air Permit D List Current Permit No. The permit will be voided with this registration.
Modification of Current Registration D List Current Registration No.
5. Attach a brief description of the facility, processes and sources of air pollution emissions.
6. What are the estimated total actual emissions from this facility?
Pollutant Tons/year
PM OTPY
PM lO 0.03 TPY
S02 OTPY
VOC 31.98 TPY
CO 0.29 TPY
NOx 0.34 TPY
Single HAP* OTPY
Combination HAP* OTPY
Air Contaminants** OTPY
HAP* - Hazardous Air Pollutant**Cannot exceed 25 tons per year
7. Attach an explanation of how the emissions estimate was detennined e.g. AP-42, test information, etc.
8. Has a Disclosure Statement been submitted to the Department previously? Yes D No ~(Ifno, please attach a disclosure statement)
9. Do you wish to be added the Air Pennits Newsletter email list? Yes D No ~If yes, list the email address(es) you wish to use:(or you can email [email protected] with "subscribe" (no quotation marks) in the subjectbox.
3
10. The registration requires an annual fee of $200. The Department will send an invoice when the annualfee is due. Submit this Registration to:
Arkansas Department of Environmental QualityAir Permitting Section5301 Northshore DriveNorth Little Rock, AR 72118
4
CERTIFICATION OF APPLICATION"Responsible Official" means one of the following:
1) For a corporation: a president, secretary, treasurer, or vice-president of the corporation in charge of aprincipal business function, or any other person who performs similar policy or decision-makingfunctions for the corporation, or a duly authorized representative of such person if the representative isresponsible for the overall operation of one or more manufacturing, production, or operating facilitiesapplying for or subject to a permit and either:
A) the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25 million (in second quarter 1990 dollars); or
B) the delegation of authority to such representative is approved in advance by the permittingauthority.
2) For a partnership or sole proprietorship: a general partner or the proprietor, respectively;
3) For a municipality, State, Federal, or other public agency: either a principal executive officer or rankingelected official. For the purposes of this part, a principal executive officer of a Federal agency includesthe chief executive officer having responsibility for the overall operations of a principal geographic unitof the agency (e.g., a Regional Administrator of EPA).
I certify under penalty of law that this application and all attachments were prepared under my direction or supervision inaccordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted.Based on my inquiry ofthe person or persons who manage the system, or those persons directly responsible for gathering theinformation, the information submitted is, to the best of my knowledge and belief: true, accurate, and complete. I am aware thatthere are significant penalties for submitting false information, including the possibility offine and imprisonment for knowingviolations.
Paul W. Geiger, III
Typed/printed name ofresponsible official
Vice President ofOperations
Title
Date
5
Attachment 2Location and Process Description
6
&Quantum ResourcesManagement, LLC
Location
Attachment 2: Location and Process DescriptionNipper A-1 &A-3, Columbia County, Arkansas
The site is located at Latitude 33° 10' 11.8" N, Longitude 93° 17' 38.7'" W in a rural areaof Columbia County, Arkansas.
From Taylor (the nearest town), the site is east on E Pine 81. toward N Hays Ave for 0.2miles, turn right on AR-160 E/E Pine 81. and travel east for 0.4 miles. From there, turnright onto AR-19 S and travel south for 436 f1. From there, take the first left ontoColumbia Rd 79 and travel east for 0.4 miles. From there take the first right and travelsouth for 0.4 miles. From there, take the first right and travel west for 0.1 miles. Arrive atsite at the end of the road.
Attachment 3 indicates the location of the Nipper A-1 &A-3 site.
Facility and Process Description
The equipment at the site consists of the following:
• 3- 400 barrel (bbl) oil storage tanks• 1- 400-bbl produced liquid storage tank! gun barrel• 1- Heater Treater• 1- Wellhead with an electric pump jack
Product is pumped from the wellhead using an electric pump jack and is routed to a
heater treater along with effluent product from Nipper A-3. From the heater treater gas
is directed off site to sales and all liquids are moved to a 400-bbl produced liquid
storage tank. The produced liquid storage tank is utilized as a Gun Barrel separator. Oilflows from the top of this tank into a 400-bbl oil storage tank and produced water isremoved from the bottom and sent to Nipper A-1 SWD. Two additional 400-bbl oilstorage tanks are used in series as overflow containers for the first. The site widethroughput of produced water is projected to be 111 bbl per day (bbl/day). The site wide
throughput of oil is projected to be 15.04 bbl/day. The site wide throughput of naturalgas is projected to be 15,000 cubic feet per day (15.00 MCFD). All liquid material is
trucked off-site to sales (oil) or disposal/injection (water).
Attachment 4 is a process flow diagram for the site.
12100 Ford Road Suire 200 Dallas, TX 75234 972.484.38547
972.484.8835 enercon.com
Attachment 3Location Map
8
Quantum Resources Management, LLCNipper A-1 and A-3
Sec. 16 - T188 - R21WN 33° 10' 11.8" I W 93° 17' 38.7"Taylor, Columbia County, AR
N
+E;;J ENERCON
Attachment 3Location Map
Macedonia Quadrangle
Project No: QRM010 9
Attachment 4Process Flow Diagram
10
From Nipper A-3
Fluids
GasTo Sales
"'0CI) L..o Q)::::J-"'O~e>a..
Produced Waterr-------------- ~ Produced Water toNipper A-1 SWD
r--------III Truck Loading AreaII IL I
* 400-bbl AST is utilized as a Gun Barrel separator. Oil flows fromthe top of this tank into OTK-1 and produced water is removed
from the bottom of this tank via truck loading activities.
Nipper A-1
F:::I ENERCONQuantum Resources Management, LLCNipper A-1 and A-3
Sec. 16 - T185 - R21WN 33° 10' 11.8" I W 93° 17' 38.7"Taylor, Columbia County, AR
GB - Gun BarrelHT - Heater TreaterOTK - Oil TankPWTK - Produced Water Tank
Legend: N
+Not to Scale
Attachment 4Process Flow Diagram
Project No: QRM010 11
Attachment 5Emissions Summary and Calculations
12
Attachment 5:
Site:
Emissions Summary and Calculations
Quantum Resources Management, LLC
Nipper A-1 &A-3 Columbia County, Arkansas
Emissions Summary - Potential Emission Rate
NOx CO voe PM10 HAPs HCHO 502
Emission Source Ib/hr TPY Ib/hr TPY Ib/hr TPY Ib/hr TPY Ib/hr TPY Ib/hr TPY Ib/hr TPY
LL-1, LL-2 16.80* 0.32
FLASH 6.11 26.76
OTK-1 0.17 0.73
OTK-2 0.17 0.73
OTK-3 0.17 0.73
GB-1 0.02 0.10
FUG-1 0.59 2.59
HT·1 0.08 0.34 0.07 0.29 0.004 0.019 0.01 0.03
Total 0.08 0.34 0.07 0.29 24.03 31.98 0.01 0.03 0.00 0.00 0.00 0.00 0.00 0.00
* This is the calculated maximum Ib/hr. based on loading factor of 8000 gal/hr (one average tank truck volume)
NOx - Nitrogen oxide
CO - Carbon monoxide
VOC - Volatile organic compoundsPM 10 - Particulate matter
HAP - Hazardous air pollutant
Ib/hr - pound per hour
TPY - tons per year
OTK- Oil tank
PWTK- Produced water tank
GB- Gun Barrel
HT- Heater Treater
FUG- Fugitive
COMP - Compressor
gal/hr - gallons per hour
13
Company Name:
Facility:
EPN:
Methodology:
Quantum Resources Management, LLC
Nipper A-1 & A-3
LL-1, LL-2The emissions are estimated using equation 1 from AP-42 Chapter 5.2, Transportation And Marketing Of PetroleumLiquids, Jan. 1995. Emissions are estimated conservatively
Liquid Loading #1 • Produced Water
Loading Loss Assumptions
Variable Value Unit Reference
S Submerged loading: dedicated normal service 0.6 AP-42, Table 5.2-1
AP-42 Figures 7.1-5,7.1-6, &TableP True vapor pressure of liquid loaded 0.5 psia 7.1-2
M Molecular weight of vapors 50 Ib/lb-mole AP-42, Table 7.1-2
T Temperature of bulk liquid 520 R (F+460) AP-42, 5.2-4
Equation Used: 12.46* (SPMfT)L Loading loss pound per 1000 gal of liquid loaded 0.10 Ib/10A 3 AP-42, 5.2-4
Emissions Factor Assumptions
Variable Value Unit Reference
A I Activity Rate 1,701,630.00 gallons/year Maximum ThroughputL I Loading Loss 0.10 Ib/1000 gal Calculated Above
Total Maximum Potential to EmitvacEmissions(Uncontrolled) Emissions Uncontrolled 0.09 TPY Equation Used: E=A*L*(1-(ER/100))
LL - Loading loss
14
Liquid Loading #2 - Produced Oil Loading
Loading Loss Assumptions
Variable Value Unit ReferenceS Submerged loading: dedicated normal service 0.6 AP-42, Table 5.2-1
AP-42 Figures 7.1-5,7.1-6, &TableP True vapor pressure of liquid loaded 2.8 psia 7.1-2
M Molecular weight of vapors 50 Ib/lb-mole AP-42, Table 7.1-2
T Temperature of bulk liquid 520 R (F+460) AP-42, 5.2-4
Equation Used: 12.46* (SPMfT)L Loading loss pound per 1000 gal of liquid loaded 2.00 Ib/10A3 AP-42, 5.2-4
Emissions Factor AssumptionsVariable Value Unit Reference
A I Activity Rate 230,563.20 gallons/year Maximum ThroughputL I Loading Loss 2 Ib/1000 gal Calculated Above
Total Maximum Potential to EmitvacEmissions(Uncontrolled) Emissions Uncontrolled 0.23 TPY Equation Used: E=A*L*(1-(ER/100»
Total Maximum Potential to Emit (Produced Water and Oil)vaeEmissions(Uncontrolled) Emissions Uncontrolled 0.32 TPY
a) Vapor pressure of water is 0.35 psia.
Produced water may contain small amounts of hydrocarbons.
Therefore, 0.5 psia was used for a conservative estimate of vapor pressure.
b) Separated oil parameters were obtained from representative sample analysis
psia - pounds per square inch absolute
Ib/lb-mole - pound per pound-mole
R - Rankine
E - emissions
ER- Emission Rate
F - Fahrenheit
15
Company Name:
Facility:
EPN:
Methodology:
Quantum Resources Management LLC
Nipper A-1 & A-3
LL-1, LL-2The emissions are estimated using equation 1 from AP-42 Chapter 5.2, Transportation And Marketing OfPetroleum Liquids, Jan. 1995. Factors for loading losses are based on the characteristics of oil found in AP-42with a factor of .10 (versus 2.0 for oil)
Liquid Loading No.1 (LL-1), Produced Water (Ib/hr)
Loading Loss Assumptions
Variable Value Unit Reference
Submerged loading: dedicated normalS service 0.6 AP-42, Table 5.2-1
AP-42 Figures 7.1-5,7.1-6, &p True vapor pressure of liquid loaded 0.5 psia Table 7.1-2
M Molecular weight of vapors 50 Ib/lb-mole AP-42, Table 7.1-2
T Temperature of bulk liquid 520 R (F+460) AP-42, 5.2-4
Loading loss pound per 1000 gal of Equation used: 12.46* (SPMIT)L liquid loaded 0.10 Ib/10A3 AP-42, 5.2-4
Emissions Factor AssumptionsVariable Value Unit Reference
A I Activity rate 8,000.00 gallons/hr Maximum throughputL I Loading loss 0.10 Ib/1000 gal Calculated above
Total Maximum Potential to Emitvac Emissions(uncontrolled)
LL - Loading loss
I Emissions uncontrolled I 0.8000 I Ib/hr IEqUation used: E=A*L*(1-(ER/10C
16
Liquid Loading No. 2 (LL.2), Produced Oil Loading (Ib/hr)Loading Loss Assumptions
Variable Value Unit Reference
Submerged loading: dedicated normalS service 0.6 AP-42, Table 5.2-1
P True vapor pressure of liquid loaded 2.8 psia Table 7.1-2
M Molecular weight of vapors 50 Ib/lb-mole AP-42, Table 7.1-2
T Temperature of bulk liquid 520 R (F+460) AP-42, 5.2-4
Loading loss pound per 1000 gal of Equation Used: 12~46* (SPMfT)L liquid loaded 2.00 Ib/10A3 AP-42 , 5.2-4
Emissions Factor Assumptions
Variable Value Unit Reference
A I Activity rate 8,000.00 gallons/hr Maximum throughput
L I Loading loss 2 Ib/1000 gal Calculated above
Total Maximum Potential to Emit
vae Emissions I(uncontrolled) Emissions uncontrolled I 16.00 I Ib/hr IEqUation used: E=A*L*(1-(ER/10C
a) Vapor pressure of water is 0.35 psia.
Produced water may contain small amounts of hydrocarbons.
Therefore, 0.5 psia was used for a conservative estimate of vapor pressure.
b) Separated oil parameters were obtained from representative sample analysis
psia - pounds per square inch absolute
Ib/lb-mole - pound per pound-mole
R - Rankine
F - Fahrenheit
17
Company Name: Quantum Resources Management LLC
Facility: Nipper A-1 & A-3
EPN: FLASH
Flash Emissions - Produced Oil
Total sample MOL WT 215.48
Base pressure: 14.65
Gas oil ratio (SCF/STbbl): 16.04
From Mattie Peterson analYSIS performed by SPL reported on 05/16/11 (attached)
Component Normalized (WT%) 1 Ib/lbmol IbsGas/STbbl
Nitrogen 0.017 0.03663 0.0015
Carbon dioxide 0.148 0.31891 0.0134Methane 0.030 0.06464 0.0027
Ethane 0.116 0.24996 0.0105
Propane 0.222 0.47837 0.0202
Isobutane 0.228 0.49130 0.0207
n-Butane 0.532 1.14636 0.0483
Isopentane 0.493 1.06233 0.0448
n-Pentane 0.882 1.90055 0.0801
I-Hexanes 0.389 0.83822 0.0353
n-Hexane 0.714 1.53854 0.0648
Benzene 0.002 0.00431 0.00022,2,4 Trimethylpentane 0.614 1.32306 0.0557
n-Heptanes 2.494 5.37412 0.2264
Toluene 0.134 0.28875 0.0122
n-Octane 3.150 6.78768 0.2860
Ethylbenzene 0.111 0.23919 0.0101
M-, 0-, P-Xylenes 0.677 1.45881 0.0615
n-Nonane 2.089 4.50142 0.1897
Decanes plus 86.958 187.37884 7.8947
Total 100.000 215.48200 9.07881 " ..
Produced Oil Flash EmissionsGas density (Ibs/cf) 0.566Production rate (bbl/day) 15.04
Total flash emissions (TPY) 24.919
WT% - weight percentageIbsGas/STbbl - pounds of gas per standard barrel
18
Flash Emissions - Produced Water
Total sample MOLWT 215.48
Base~ure: 14.65Gas oU ratio (SCF/STbbl): 16.04
Component Normalized (WT%) 1 Ibnbmol IbsGaslSTbbl
Nitrogen 0.017 0.03663 0.0015Carbon dioxide 0.148 0.31891 0.0134Methane 0.030 0.06464 0.0027
Ethane 0.116 0.24996 0.0105Propane 0.222 0.47837 0.0202
Isobutane 0.228 0.49129 0.0207
n-Butane 0.532 1.14635 0.0483
Isopentane 0.493 1.06232 0.0448
n-Pentane 0.882 1.90053 0.0801
I-Hexanes 0.389 0.83822 0.0353n-Hexane 0.714 1.53853 0.0648
Benzene 0.002 0.00431 0.0002
2,2,4 Trimethylpentane 0.614 1.32305 0.0557
n-Heptanes 2.494 5.37407 0.2264
Toluene 0.134 0.28874 0.0122
n-Octane 3.150 6.78762 0.2860
Ethylbenzene 0.111 0.23918 0.0101
M-, 0-, P-Xylenes 0.677 1.45880 0.0615
n-Nonane 2.089 4.50138 0.1897Decanes plus 86.958 187.37710 7.8947
Total 100.000 215.48000 9.0787
1 From "Mattie Peterson" analysis performed by SPL reported on 05/16/11 (attached)
Produced Water Flash Emissions
Gas density (lbs/cf) 0.042Production rate (bbl/day) 111
Total flash emissions (TPY) 1.839
Total Flash Emissions (Oil and Produced Water)
Total flash emissions (TPY) I 26.759
19
Company Name: Quantum Resources Management, LLC
Facility: Nipper A-1 & A-3
EPN: OTK-1
Total Maximum Potential to Emit (Working/Breathing)
Working and Working and Total TotalBreathing Breathing1 Number of Annua,1 Annual
Type Pollutant (TPV) (TPV) Tanks (#) (Ib/hr) (TPY)
ail (400-bbl) vae 0.17 0.73 3 0.50 2.20
Gun Barrel (400-bbl) vae 0.02 0.10 1 0.02 0.10Total vae 0.19 0.83 4 0.52 2.30
1Working and Breathing Losses are calculated using TANKS 4.09d
20
Company Name: Quantum Resources Management
Facility: Nipper A-1 & A-3
EPN: FUG-1Methodology: The emissions are estimated using fugitive emission factors specified in the TCEQ "Air Permit
Technical Guidance for Chemical Sources" Equipment Leak Fugitives, dated October 2000. Fugitivevalve, relief valve, and pump counts are conseratively estimated. Fugitive flange/connection count isestimated by multiplying the valve count by 2.5.
voe Emission estimates: It is conservatively assumed that all components are in Vapor Service. Allcomponents were adjusted for vac content in stream. A copy of the gas analysis for a similar inletgas is provided.
Emission Factor Number of voe Emissions H2S Emissions
Source Description (Ib/hr/comp) Components (Ib/hr) (tpy) (Ib/hr) (tpy)
Vapor Stream/GAS
System valves 0.00992 220 0.338 1.478 0.000 0.000
Relief valves 0.01940 4 0.012 0.053 0.000 0.000
Other 1 0.00441 12 0.008 0.036 0.000 0.000
Pumps 0.00529 a - - - -Flanges 0.00086 664 0.088 0.387 0.000 0.000
Compressors 0.01940 a - - - -Connections 0.00086 448 0.060 0.261 0.000 0.000
Open-ended Lines 0.00441 8 0.005 0.024 0.000 0.000
Oil Stream
System valves 0.00550 52 0.044 0.194 0.000 0.000
Relief valves 0.01650 4 0.010 0.045 0.000 0.000
Other 1 0.00309 8 0.004 0.017 0.000 0.000
Flanges 0.00024 304 0.011 0.050 0.000
Pumps 0.02866 0 - - - -Compressors 0.01650 a - - - -Connections 0.000243 112 0.004 0.018 0.000 0.000
Open-ended Lines 0.003090 8 0.004 0.017 0.000 0.000
21
Emission Factor Number of Estimated voe Emissions Estimated H25 Emissions
Source Description (Ib/hr/comp) Components (Ib/hr) (tpy) (Ib/hr) (tpy)
Gun Barrel/ProducedWater Stream
System valves 0.000216 8 0.000 0.001 0.000 0.000
Relief valves 0.0309 0 - - - -Other 1 0.0006 a - - - -
Flanges 0.0000 72 0.000 0.000 0.000 0.000Pumps 0.000052 0 - - - -
Compressors 0.0309 0 - - - -Connections 0.000860 16 0.002 0.009 0.000 0.000
Open-ended Lines 0.000550 4 0.000 0.001 0.000 0.000
TOTAL voe EMISSIONS 0.592 2.59 0.000 0.000
1: "Other" includes diaphragms, dump arms, hatches, instruments, meters, polished rods, and vents
Connectors estimated at 2.5 times the number of valves.
Assumptions: Gas vae (wt%):
H2S (wt%)
15.465%
0.001%
22
Site:
Facility:EPN:
Quantum Resources Management
Nipper A-1 &A-3
HT-1
Equipment InformationHour
Fuel Rate1 OperatedHeater Name Type Size (MMBTU/hr) (scf/hr) (hrs)
HT-1 Heater treater 0.8 784.314 8760
1Assume gas heat content is 1020 Btu/scf
Controlled Maximum Potential to EmitAnnual
Emission Factors Emissions EmissionsPollutant (lb/MMSCF) Reference (Ib/hr) (TPV)
NOx 100 AP-42, Table 1.4-1 , Small Boilers 0.08 0.34
CO 84 AP-42, Table 1.4-1, Small Boilers 0.07 0.29
vac 5.5 AP-42,Table 1.4-2 0.004 0.019
PM 7.6 AP-42,Table 1.4-2 0.01 0.03
MMBTU/hr - million British thermal units per hour
scf/hr - standard cubic feet per hour
Ib/MMSCF - pound per million standard cubic feet
Ibs/CF - pounds per cubic feet
bbl/day - barrels per day
Btu/sef - British thermal units per standard cubic foot
23
TANKS 4.0.9dEmissions Report - Summary Format
Tank Indentification and Physical Characteristics
Nipper A-1 &A-3 Gun BarrelTaylorArkansasQuantum ResourcesVertical Fixed Roof Tank
0.0012.00
20.0012.0020.0016.00
16,920.59114.19
1,932,193.20
Aluminum/DiffusePoorAluminum/DiffusePoor
N
Dome
IdentificationUser Identification:City:State:Company:Type of Tank:Description:
Tank DimensionsShell Height (tt):Diameter (tt):liquid Height (tt) :Avg. Liquid Height (tt):Volume (gallons):Turnovers:Net Throughput(gallyr):Is Tank Heated (y/n):
Paint CharacteristicsShell Color/Shade:Shell ConditionRoof Color/Shade:Roof Condition:
Roof CharacteristicsType:Height (ft)Radius (tt) (Dome Roof)
Breather Vent SettingsVacuum Settings (psig): -0.03Pressure Settings (psig) 0.03
Meterological Data used in Emissions Calculations: Little Rock, Arkansas (Avg Atmospheric Pressure = 14.62 psia)
TANKS 4.0.9d
Emissions Report - Summary Format
Liquid Contents of Storage Tank
Nipper A-1 &A·3 Gun Barrel • Vertical Fixed Roof TankTaylor, Arkansas
LiquidDaily Liquid Surf. Bulk Vapor Liquid Vapor
Temperature (deg F) Temp Vapor Pressure (psia) Mol. Mass Mass Mol. Basis for Vapor Pressure
Mixture/Component Month Avg. Min. Max.(deg Avg. Min. Max. Weight. Fract. Fract. Weight Calculations
F)
Gun Barrel Liquid All 71.14 60.46 81.81 64.81 0.4145 0.2912 0.5822 21.2255 20.22Crude oil (RVP 5) 3.5650 2.9041 4.3412 50.0000 0.1193 0.2361 207.00 Option 4: RVP=5Water 0.3774 0.2604 0.5379 18.0200 0.8807 0.7639 18.02 Option 2: A=8.1 0765, 8=1750.286, C=235
24
TANKS 4.0.9dEmissions Report - Summary Format
Individual Tank Emission Totals
Emissions Report for: Annual
Nipper A-1 &A·3 Gun Barrel • Vertical Fixed Roof TankTaylor, Arkansas
I 1 Losses(lbs)
!Components I Working Loss I Breathing Loss I Total Emissions
IGun Barrel Liquid I 173.80 I 26.891 200.69
IWater 1 132.761 20.541 153.31
ICrude oil (RVP 5) I 41.04 1 6.351 47.39
25
TANKS 4.0 Report
TANKS 4.0.9dEmissions Report - Summary Format
Tank Indentification and Physical Characteristics
IdentificationUser Identification:City:State:Company:Type of Tank:Description:
Tank DimensionsShell Height (tt):Diameter (tt):Liquid Height (tt) :Avg. Liquid Height (tt):Volume (gallons):Turnovers:Net Throughput(gallyr):Is Tank Heated (yIn):
Paint CharacteristicsShell Color/Shade:Shell ConditionRoof Color/Shade:Roof Condition:
Roof CharacteristicsType:Height (tt)Radius (tt) (Dome Roof)
Breather Vent SettingsVacuum Settings (psig):Pressure Settings (psig)
Nipper B-2 OilTaylorArkansasQuantum ResourcesVertical Fixed Roof Tank
20.0012.0020.0016.00
161920.596.04
102,251.10N
Gray/LightPoorGray/LightPoor
Dome0.00
12.00
·0.030.03
Meterological Data used in Emissions Calculations: Little Rock, Arkansas (Avg Atmospheric Pressure =14.62 psia)
TANKS 4.0.9d
Emissions Report - Summary FormatLiquid Contents of Storage Tank
Nipper B-2 Oil - Vertical Fixed Roof TankTaylor, Arkansas
Mol. Basis for Vapor Pressure
Weight CalculationsMixturefComponent
Crude oil (RVP 5)
LiquidDaily Liquid Surf. Bulk Vapor Liquid
Temperature (deg F) Temp Vapor Pressure (psia) Mol. Mass
Month Avg. Min. Max. (deg F) Avg. Min. Max. Weight. Fract.
All 70.40 60.23 80.58 64.51 3.5161 2.8909 4.2452 50.0000
VaporMass
Fract.
207.00 Option 4: RVP=5
TANKS 4.0.9dEmissions Report - Summary Format
Individual Tank Emission Totals
Emissions Report for: Annual
Nipper B-2 Oil - Vertical Fixed Roof TankTaylor, Arkansas
I II Losses(lbs) IIcomponents II Working LosslI Breathing Lossil Total Emissionsl
ICrUde oil (RVP 5) II 321.01\1 626.67/1 947.671
file:///CllProgram Files (x86)ffanks409d/surnmarydisplay.htm[7/1 l/201 1 II :09:29 AM]
26
Attachment 6Representative Analytical Results
Mattie Peterson 5/16/2011
27
Certificate of Analysis:
HOUSTON LABORATORIES8820 INTERCHANGE DRIVE
HOUSTON, TEXAS 77054PHONE (713) 660-0901
2011050117-004A
For: Claudine BendeckEnercon Services, Inc.12100 Ford Rd' l Ste. 200Dallas. Tx 75234
Company:Well:Field:Sample of:Conditions:Sampled by:Sample date:
Remarks:
Enercon Services, Inc.Mattie PetersonColumbia County. ARKLiquid62 psi @ 83 ofBB04/18/2011Cylinder No.: 5100
Report Date: 5/16/2011
Analysis: (GPA 2103M ) Mol. 0/0 MW Wt. 0/0 Sp. Gravity L.V.%Nitrogen 0.130 28.013 0.017 0.8094 0.017Methane 1.982 16.043 0.148 0.3000 0.400Carbon Dioxide 0.148 44.010 0.030 0.8180 0.030Ethane 0.833 30.070 0.116 0.3562 0.265Propane 1.086 44.097 0.222 0.5070 0.356Iso-butane 0.845 58.123 0.228 0.5629 0.329N-butane 1.971 58.123 0.532 0.5840 0.740Iso-pentane 1.473 72.150 0.493 0.6244 0.642N-pentane 2.634 72.150 0.882 0.6311 1.136i-Hexanes 0.972 86.177 0.389 0.6795 0.478n..Hexane 1.787 86.177 0.714 0.6640 0.8742,2,4 trimethylpentane 0.004 114.231 0.002 0.6967 0.002Benzene 1.693 78.114 0.614 0.8846 0.564Heptanes 5.449 93.766 2.494 0.7279 2.906Toluene 0.314 92.141 0.134 0.8719 0.125Octanes 6.073 110.799 3.150 0.7215 3.575E-benzene 0.226 106.167 0.111 0.8718 0.104M-,O-,P-xylene 1.373 106.167 0.677 0.8731 0.633Nonanes 3.621 118.773 2.089 0.7707 2.297Decanes Plus 67.386 278.067 86.958 0.8361 84.527
............... ,....,.....---- ...... _ ............... _ ..__~11111111-
_ .. _ .... IIIIIIr______~~ ...........
100.000 100.000 100.000
Calculated Values Total Sample Decanes PlusSpecific Gravity at 60 of 0.8128 0.8361Api Gravity at 60 of 42.596 37.729Molecular Weight 215.482 278.067Pounds per Gallon (in Vacuum) 6.776 6.971Pounds per Gallon (in Air) 6.769 6.964Cu. Ft. Vapor per Gallon @ 14.65 psia 11.897 9.544
~y~Southern Petroleum Laboratories, Inc.
28
CERTIFICATE OF ANALYSISCertificate of Analysis: 2011 050117-004A
HOUSTON LABORATORIES8820 INTERCHANGE DRIVE
HOUSTON, TEXAS 77054PHONE (713) 660·0901
Customer:Attn:
Enercon Services. Inc.
Claudine Bendeck
12100 Ford Rd., Ste. 200
Dallas, TX 75234
Report Date:
PO I Ref. No.:
05/16/11
Sample Point: Field Sep.
Company:Field:Well :
Enercon Services, Inc.
Columbia, Co. ARK
Mattie Peterson
Sample Of: Liquid
Sample Date/Time: 4/18/2011
Sample Psig & Temp: 62 psi @ 83 of
Sampled By: BB-SPL
Cylinder # : 5100
Comments: Staged Flash from 62 psi @ 83°F to 0 psi @ 60°F
Analytical DataLab Date
Parameters Results Units Method Tech. Analyzed
Shrinkage Factor 0.9920 Shrink-EOS CS 05/16/11
Flash Factor 16.039 CU.Ft.lSTBbl. Shrink-EOS CS 05/16/11
29
..,Uj....__..........__~__.,,? CERTIFICATE OF ANALYSIS
tertificate of Analysis: 2011050117-004A
HOUSTON LABORATORIES8820 INTERCHANGE DRIVE
HOUSTON. TEXAS 77054PHONE (713) 660~0901
Customer:Attn:
Enercon Services, Inc.
Claudine Bendeck
12100 Ford Rd., Ste. 200
Dallas, TX 75234
Report Date:
PO I Ref. No.:
05/16/11
Sample Of: Liquid
Sample Date/Time: 04/18/11
Sample Psig & Temp: 62 psi @ 83 of
Sampled By: BB-SPL
Cylinder # : 5100
Enercon Services, Inc.
Columbia, Co. ARK
Mattie Peterson
Sample Point: Field Sep.
Comments: EOS Flash Gas Composition
Staged Flash from 62 psi @ 83°F to apsi @ 60°F
Company:Field:Well:
NITROGENC02METHANEETHANEPROPANEI-BUTANEN·BUTANEI-PENTANEN-PENTANEHEXANESBENZENEHEPTANESTOLUENEOCTANESE-BENZENEm,o,&p-XYLENENONANESDECANES PLUS
TOTALS
MOL 0/04.7423.531
62.932
13.3306.2532.1363.6161.0031.3640.3970.2720.2340.0130.0790.0030.0140.0150.067
100.000
WEIGHT %
5.1426~015
39.08215.51610.673
4.8068.1362.8003.8111.2990.8230.8750.0480.3440.0130.0580.0710.488
100.000
GPM's @ 14.73
5.0112.2810.6561.1520.2750.3780.0970.0980.0510.0040.0160.0010.0040.0030.011
10.037
CALCULATED VALUES
REAL DRY BTU AT 14.73 PSIA, 60 DEG.FREAL WET BTU AT 14.73 PSIA, 60 DEG.FRELATIVE DENSITYCOMPRESSIBILITY FACTOR
GPM's @ 14.73 psia, 60 Deg.F
1372.61348.80.8957
0.99490C2+
10.037C5+
0.937
30
...miliiiiii... -~--.,., CERTIFICATE OF ANALYSIStertificate of Analysis: 2011050117-004A
HOUSTON LABORATORIES8820 INTERCHANGE DRIVE
HOUSTON I TEXAS 77054PHONE (713) 660-0901
EOS Liquid Residue Composition
Staged Flash from 62 psi @ 83°F to 0 psi @ 60°F
Customer:Attn:
Company:Field:Well:
Sample Point:Comments:
Enercon Services. Inc.
Claudine Bendeck
12100 Ford Rd., Ste. 200
Dallas, TX 75234
Enercon Services, Inc.
Columbia, Co. ARK
Mattie Peterson
Report Date: 05/16/11
PO I Ref. No.:
Sample Of: Liquid
Sample Date/Time: 4/18/11
Sample Psig & Temp: 62 psi @ 83 of
Sampled By: BB-SPL
Cylinder # : 5100
MOL% WEIGHT 0/0 LV°t'oNITROGEN 0.009 0.002 0.004CO2 0.387 0.039 0.095METHANE 0.059 0.017 0.015ETHANE 0.506 0.096 0.197PROPANE 0.951 0.266 0.383I-BUTANE 0.811 0.299 0.372N-BUTANE 1.928 0.710 0.918I-PENTANE 1.485 0.679 0.789N-PENTANE 2.667 1.220 1.405HEXANES 2.825 1.514 1.655BENZENE 1.730 0.857 0.706HEPTANES 5.586 3,421 3.607TOLUENE 0.322 0.188 0.156OCTANES 6.230 4.429 4.560E-BENZENE 0.232 0.156 0.130m,o,&p-XYLENE 1.409 0.948 0.779NONANES 3.715 2.984 3.003DECANES PLUS 69.148 82.175 81.226
TOTALS 100.000 100.000 100.000
CALCULATED VALUES TOTAL C10+
Molecular Weight 157.788 186.763BTU I Lb. 16,554 15,697BTU I Gal. 100,411 96,294Cu. Ft./ Gal. At 14.73 Psia, 60°F 14.555 12.436Lbs. I Gal. (Absolute Density) 6.066 6.135Lbs. J Gal. (Weight in Air) 6.058 6.127Specific Gravity at 60°F (Water =1) 0.7276 0.7358API Gravity at GO°F 63.0 60.8
31