Download pdf - 1. .Identinfi.ct aot1ft SaR-F3cTFyp(CmB(()F/niFF ... · SaR-F3cTFyp(CmB(()F/niFF l.fivs/ ecnFSaf-FB(yhmbx(1/12 1. Identification of the substance/mixture and of the company/undertaking

SafetyDatasheet

Silicate Resin 3P S1

Standard (Comp. B)

according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830

1/12

1. Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1 Productidentifier

FluviusSilicateResin-3PTypeS1Standard(Comp.B)

1.2 Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

“B”componentforwaterglass–polyisocyanatebasedtwo-com-

ponentsyntheticresin.Thesyntheticresin(components“A”+“B”)

isusedfortheliningofsewerpipesandmanholes.Theapplication

hastobecarriedoutunderprofessional,industrialconditionsby

personshavingproperprevioustraining.

1.3 Detailsofthesupplierofthesafetydatasheet

Company FluviusGmbH

Street/POB Schiessstrasse56

Postcode/City/Country D-40549Düsseldorf

Phone +49(0)211-691682-0

Telefax +49(0)211-691682-19

E-mail [email protected]

1.4 Emergencytelephonenumber

Medical emergency information in case of intoxication

Giftinformationszentrum(GIZ)Mainz

Emergency +49(0)613119240

telephonenumber (AdviceinGermanorEnglish)

2. Hazardsidentification

2.1 Classificationofthesubstanceormixture

2.1.1 ClassificationaccordingtoRegulation(EC)No1272/2008(CLP)

Hazard classes Hazard statements

SkinIrrit.2 H315Causesskinirritation.

SkinSens.1B H317Maycauseanallergicskinreaction.

EyeIrrit.2 H319Causesseriouseyeirritation.

AcuteTox.4. H332Harmfulifinhaled.

Resp.Sens.1 H334Maycauseallergyorasthmasym-

ptomsofbreathingdifficultiesifinhaled.

STOTSE3 H335Maycauserespiratoryirritation.

Carc.2 H351Suspectedofcausingcancer.

STOTRE2 H373Maycausedamagetoorgans

throughprolongedorrepeatedexposu-

re:respiratorysystem,inhalation.

2.2 Labelelements

2.2.1 LabelingaccordingtoRegulation(EC)No1272/2008(CLP)

Hazard pictograms

Signal word Danger

Hazard statements

H315 Causesskinirritation.

H317 Maycauseanallergicskinreaction.

H319 Causesseriouseyeirritation.

H332 Harmfulifinhaled.

H334 Maycauseallergyorasthmasymptoms

ofbreathingdifficultiesifinhaled.

H335 Maycauserespiratoryirritation.

H351 Suspectedofcausingcancer.

H373 Maycausedamagetoorgansthrough

prolongedorrepeatedexposure:

respiratorysystem,inhalation.

Phone: 810-412-4740 · www.S1Eonline.com

SafetyDatasheet


Standard (Comp. B)


2/12

Precautionary statements

P260 Donotbreathedust/fume/gas/mist/

vapours/spray.

P280 Wearprotectivegloves/protective

clothing/eyeprotection/faceprotection.

P285 Incaseofinadequateventilationwear

respiratoryprotection.

P302+P352 IFONSKIN:Washwithplentyofsoap

andwater.

P304+P340 IFINHALED:Removevictimtofresh

airandkeepatrestinaposition

comfortableforbreathing.

P309+P311 IFexposedorifyoufeelunwell:Calla

POISONCENTERordoctor/physician.

Hazarddeterminingcomponent(s)forlabelling

Diphenylmethandiisocyanate,isomersandhomologes(CAS:9016-

87-9);Tris(2-chloro-1-methylethyl)phosphate(CAS:13674-84-5).

2.3. Otherhazards

Themixturedoesnotmeetpersistent(P)andbioaccumulation(B)

criteria,butitmeetsthecriteriafortoxicity(T).Themixtureisnot

PBTorvPvB.

Name EC-No. CAS-No. REACH-No. Content(%) ClassificationaccordingtoRegulation

(EG)No.1272/2008(CLP)

Hazardcategories1 H-phrase(s)1

Isocyanicacid,polymethylen-

epolyphenyleneester

(PolymericMDI)2

(polymer) 9016-87-9 (polymer) >60 AcuteTox.4

SkinIrrit.2

EyeIrrit.2

Resp.Sens.1

SkinSens.1B

Carc.2

STOTSE3

STOTRE2

H332

H315

H319

H334

H317

H351

H335

H373

Tris(2-chloro-1-methyl-ethyl)

phosphate(TCPP)

237-158-7 13674-84-5 3 >10 AcuteTox.4 H302

Phenol,isopropylated,

phosphate(3:1)4

273-066-3 68937-41-7 5 <2,5 Repr.2

STOTRE2

AquaticChronic2

H361

H373

H411

Hexamethylene-1,6-

diisocyanatehomopolymer

500-060-2 28182-81-2 6 ≤2 AcuteTox.4

SkinSens.1

STOTSE3

H332

H317

H335

3. Composition/informationoningredients

Mixtures / Chemical characterization

1SeeSection16forthefulltextoftheabbreviationsdeclaredabove.2Contains<25%4,4’-MDI(4,4'-methylenediphenyldiisocyanate)(CAS:101-68-8).301-2119486772-26-XXXX

4Themixturecontains<1%Triphenylphosphate(CAS:115-86-6).5Wehavestillnotreceivedthedatafromoursuppliers.601-2119488934-20-XXXX


SafetyDatasheet


Standard (Comp. B)


3/12

4. Firstaidmeasures

4.1 Descriptionoffirstaidmeasures

Generaladvice Soiled,fairlysoakedclothingandshoes

mustbeimmediatelyremoved.

Incaseofinhalation Ifinhaled,removetofreshair.Ifnot

breathing,giveartificialrespiration.

Getmedicalattentionimmediately.

Incaseofskincontact Intheeventofcontactwiththeskin,

preferablywashalternatelywitha

cleanserbasedonpolyethyleneglycol

andwithplentyofwarmwaterandsoap.

Consultadoctorintheeventofaskin

reaction.Washthelessclothingbefore

reuse.Cleanshoesthoroughlybefore

reuse.

Incaseofeyecontact Holdtheeyesopenandrinsewithwater

forasufficientlylongperiodoftime(at

least10minutes).Getmedicalattention

immediately.

Incaseofingestion DONOTinducethepatienttovomit,

medicaladviceisrequired.Nevergive

anythingbymouthtoanunconscious

person.Providedthepatientiscon-

scious,washoutmouthwithwater.

Informationtophysician Theproductirritatestherespiratory

tractandmaytriggersensitisationof

theskinandrespiratorytract.Treatment

ofacuteirritationorbronchialconstric-

tionisprimarilysymptomatic.Following

severeexposurethepatientshouldbe

keptundermedicalreviewforatleast

48hours.

4.2 Mostimportantsymptomsandeffects,bothacuteanddelayed

Headache,nausea,shortnessofbreath,sorethroat,rednessonthe

skin.Repeatedorprolongedcontactmaycauseskinsensitization.

Repeatedorprolongedinhalationexposuremaycauseasthma.

4.3 Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Dependingonthedegreeofexposure,periodicmedicalexaminati-

onissuggested.

5. Firefightingmeasures

5.1 Extinguishingmedia

Suitable Foam,CO2ordrypowder.Waterspray

extinguishingmedia maybeusedifnootheravailableand

thenincopiousquantities.

Unsuitable Highvolumewaterjet.

extinguishingmedia

5.2 Specialhazardsarisingfromthesubstanceormixture

Carbondioxide,carbonmonoxide,hydrogencyanide,nitrogenoxi-

des,isocyanate.Thesubstances/groupsofsubstancesmentioned

canbereleasedincaseoffire.

5.3 Adviceforfirefighter

Reactionbetweenwaterandhotisocyanatemaybevigorous.

Preventwashingsfromenteringwatercourses,keepfireexposed

containerscoolbysprayingwithwater.

Specialprotective Fire-fightersshouldwearappropriate

equipment protectiveequipmentandself-contained

breathingapparatus(SCBA)withafull

face-pieceoperatedinpositivepressure

mode.Safetyboots,gloves,safetyhel-

metandprotectiveclothingshouldbe

worn.

Furtherinformation Intheeventoffireand/orexplosiondo

notbreathefumes.Fireinvicinityposes

riskofpressurebuild-upandrupture.

Containersatriskfromfireshould

becooledwithwaterand,ifpossible,

removedfromthedangerarea.Dueto

reactionwithwaterproducingCO2gas,

ahazardousbuild-upofpressurecould

resultifcontaminatedcontainersare

re-sealed.Containersmayburstifover-

heated.


SafetyDatasheet


Standard (Comp. B)


4/12

6. Accidentalreleasemeasures

6.1 Personalprecautions,protectiveequipmentandemergencyprocedures

Immediatelycontactemergencypersonnel.Evacuatethearea.

Keepupwindtoavoidinhalationofvapours.Clean-upshouldonly

beperformedbytrainedpersonnel.Keepunauthorizedpersons

away.

Fornon-emergency Removenotaffectedpeople.Informthe

personnel relevantemergencyservicesandautho-

rities.

Foremergency Peopledealingwithmajorspillages

responders shouldwearfullprotectiveclothing

includingrespiratoryprotection.Use

suitableprotectiveequipment.

6.2 Environmentalprecautions

Donotallowcontaminatedextinguishingwatertoenterthesoil,

ground-waterorsurfacewaters.Avoiddispersalofspiltmaterial

andrunoffandcontactwithdrainsandsewers.

6.3 Methodsandmaterialforcontainmentandcleaningup

Absorbspillagesontosand,earthoranysuitableadsorbentma-

terial.Leavetoreactforatleast30minutes.Donotabsorbonto

sawdustorothercombustiblematerials.Contaminatedabsorbent

materialshallbedisposedaccordingtoSection13.)Washthespilla-

geareawithwater.

6.4 Referencetoothersections

Informationregardingexposurecontrols/personalprotectionand

disposalconsiderationscanbefoundinsection8and13.

7. Handlingandstorage

7.1 Precautionsforsafehandling

Protective measures

Providesufficientairexchangeand/orexhaustinworkrooms.Inall

workplacesoftheplantwherehighconcentrationsofisocyanate

aerosolsand/orvapoursmaybegenerated(e.g.duringpressure

release,mouldventingorwhencleaningmixingheadswithanair

blast),appropriatelylocatedexhaustventilationmustbeprovided

inordertopreventoccupationalexposurelimitsfrombeingexcee-

ded.Theairshouldbedrawnawayfromthepersonnelhandlingthe

product.Theefficiencyoftheventilationsystemmustbemonito-

redregularlybecauseofthepossibilityofblockage.Atmospheric

concentrationsshouldbeminimisedandkeptaslowasreasonably

practicablebelowtheoccupationalexposurelimit.

Advice on general occupational hygiene

Noeating,drinking,smokingortobaccouseattheplaceofwork.

Contactwithskinandeyesandinhalationofvapoursmustbe

avoidedunderallcircumstances.Keepequipmentclean.Abasic

essentialinsampling,handlingandstorageisthepreventionof

contactwithwater.Keepstocksofdecontaminantreadilyavailable.

7.2 Conditionsforsafestorage,includinganyincompatibilities

Storeinaccordancewithlocalregulations.Storeinoriginal

containerprotectedfromdirectsunlightinadry,cooland

well-ventilatedarea,awayfromincompatiblematerialsandfood

anddrink.Keepcontainertightlyclosedandsealeduntilreadyfor

use.Containersthathavebeenopenedmustbecarefullyresealed

andkeptuprighttopreventleakage.Donotstoreinunlabelled

containers.Useappropriatecontainmenttoavoidenvironmental

contamination.Suitablecontainers:steel,stainlesssteel.Unsuitab-

lecontainers:copper,copperalloyandgalvanisedsurfaces.

7.3 Specificenduse(s)

Fortherelevantidentifieduse(s)listedinSection1theadvicementi-

onedinthissection7istobeobserved.


SafetyDatasheet


Standard (Comp. B)


5/12

8. Exposurecontrols/personalprotection

8.1 Controlparameters

Aworkplaceexposurelevel(WEL)of0.02mg/m3fortotalisocya-

nates(asNCO)asan8hourTWA,andashorttermWEL(15min)

of0.07mg/m3havebeenassignedintheUnitedKingdom.ABMGV

forisocyanates,basedonthemeasurementofurinarydiamines,

hasbeensetat1 µmoldiamine/molcreatinine.

(http://www.hse.gov.uk/foi/internalops/sectors/manuf/03-10-07.htm)

8.2 DNEL/PNEC-values

The risk characterization of MDI (CAS: 9016-87-9) is the following

Workers

Acute/short-term exposure

systemiceffects(dermal) DNEL=50mg/kgbw/day


systemiceffects(inhalation)DNEL=0,1mg/m3


localeffects(dermal) DNEL=28,7mg/cm2


localeffects(inhalation) DNEL=0,1mg/m3

Long-term exposure

systemiceffects(inhalation)DNEL=0,05mg/m3

Long-term exposure

systemiceffects(dermal) Notapplicable.

Long-term exposure

localeffects(inhalation) DNEL=0,05mg/m3

Long-term exposure

localeffects(dermal) Notapplicable.

PNECsediment AsPMDIisareactantwithwater,access

ofwatertoPMDIandviceversaisstrictly

controlled.Furthermore,PMDIpolyme-

rizesinthepresenceofwaterandthus

exposureofPMDItosedimentishighly

likelytobenegligible.Therefore,PNEC

sedimentcannotbederivedforPMDI.

PNECsoil 1mg/kgsoildw(dryweight)

PNECoral TherearenodataoneffectsoforalPMDI

tobirds.Exposuretobirdsisnotexpected

anddatafromexperimentalanimals

showPMDItobeofloworaltoxicity.

8.3 Exposurecontrols

Respiratoryprotection Respiratoryprotectionincaseofvapour/

aerosolrelease.Combinationfilterfor

gases/vapoursoforganic,inorganic,acid

inorganicparticles(f.e.EN14387Type

ABEK)shallbeused.

Handprotection Chemicalresistantprotectivegloves

(EN374).

Suitable materials also with prolonged, direct contact

(Recommended: Protective index 6, corresponding > 480 minutes

of permeation time according to EN 374)

butylrubber(butyl) 0,7mmcoatingthickness

nitrilerubber(NBR) 0,4mmcoatingthickness

chloroprenerubber(CR) 0,5mmcoatingthickness

Unsuitable materials

polyvinylchloride(PVC) 0,7mmcoatingthickness

Polyethylene-Laminate ca.0,1mmcoatingthickness

(PE-laminate)

Eyeprotection Safetyglasseswithside-shields

(framegoggles)(e.g.EN166)

Bodyprotection safetyshoes

(e.g.accordingtoEN20346)

Generalsafetyand

hygienemeasures

Donotbreathevapour/spray.Withproducts

freshlymanufacturedfromisocyanates

bodyprotectionandchemicalresistant

protectiveglovesisrecommended.Wearing

ofclosedworkclothingisrequired

additionallytothestatedpersonal

protectionequipment.Noeating,drinking,

smokingortobaccouseattheplaceofwork.

Takeoffimmediatelyallcontaminated

clothing.Handsand/orfaceshouldbe

washedbeforebreaksandattheendofthe

shift.Attheendoftheshifttheskinshould

becleanedandskin-careagentsapplied.


SafetyDatasheet


Standard (Comp. B)


6/12

9. Physicalandchemicalproperties

9.1 Informationonbasicphysicalandchemicalproperties

Appearance liquid,dark-brown

Odour damp

Odourthreshold nodata

pH-value notapplicable

Meltingpoint/

freezingpoint nodata

Boilingrange nodata

Flashpoint >200°CMDI

Evaporationrate nodata

Flammability nodata

(solid,gaseous)

Ignitable,explosiverangenodata

Vapourpressure <0,00001mbar(at20°C)

Vapourdensity nodata

Density 124±0,02g/cm3(at25°C)

Solubility Reactswithwaterattheborderarea

withslowCO2appearanceintonon

soluble,highmeltingpointornot

meltingpolyurea.

Partitioncoefficient notapplicable

(n-octanol/water)

Self-ignitiontemperature nodata

Decomposition

temperature nodata

Viscosity 310-370mPa·s(at20°C)

Explosiveproperties non-explosive

Oxidisingproperties nodata

9.2 Otherinformation

Notapplicable.

10. Stabilityandreactivity

10.1 Reactivity

Reactswithwater,acids,alcohols,amines,basesandoxidants.

10.2Chemicalstability

ThemainremovalmechanismofMDIsintheenvironmentis

hydrolysis.MDIreactsquicklywithwatertoformpredominantly

solid,insolublepolyureas.Underconditionstypicalofmanytypes

ofenvironmentalcontact,i.e.withrelativelypoordispersionofthe

isocyanate,theinterfacialreactionleadstotheformationofasolid

crustencasingpartiallyreactedproduct.Thiscrustrestrictsin-

gressofwaterandegressofamine,andhenceslowsandmodifies

hydrolysis.

Stability in organic solvents

AllMDIisomersandformsarehighlyunstableindimethylsulhpoxi-

desolvent,watercontentoftheDMSOisincreasingbreakdown.

MDIismorestableinEGDE(ethyleneglycoldimethylether)as

solvent.

(Read-acrossbasedon4,4’-methylenediphenyldiisocyanate-CAS

101-68-8.)

10.3Possibilityofhazardousreactions

Reactionisslowwithcoldorwarmwater(<50°C),withhotwater

orsteamthereactionisfaster,producingcarbon-dioxidecausing

pressureincrease.Acids,alcohols,amines,basesandoxidants

causefireandexplosionhazard.

10.4Conditionstoavoid

Hightemperature,moisture,stronglight.

10.5Incompatiblematerials

Substancestoavoid acids,alcohols,amines,water,alkalines.

10.6Hazardousdecompositionproducts

Nohazardousdecompositionproductsifstoredandhandledas

prescribed/indicated.


SafetyDatasheet


Standard (Comp. B)


7/12

11. Toxicologicalinformation

Informationisrelatedto4,4-Methylenediphenyldiisocyanateifno

otherismentioned.

11.1 Informationontoxicologicaleffects

Acutetoxicity– Harmful

oral Rats(female)

LD50

=632mg/kg

Tris(2-chlor-1-methylethyl)phosphate

(CAS-Number:13674-84-5)

Acutetoxicity– Harmful

inhalation Rats

LC50

>2,24mg/lair(1h)

OECDGuideline403

Rats

LC50

>7mg/lair(4h)

dustsandmists

OECD403AcuteInhalationToxicity/

433AcuteInhalationToxicity-FixedDose

ProcedureTris(2-chloro-1-methylethyl)

phosphate(CAS-Number:13674-84-5)

Acutetoxicity– Notclassified.Basedonavailabledata,

dermal theclassificationcriteriaarenotmet.

Rabbit

LD50

>9400mg/kg

bw(24h)

OECDGuideline402

11.2 Irritation/Corrosion

Summarizedtheresultsofthestudiestogetherwithhumanoccup-

ationalcasereportssupporttheofficialclassification.

Skincorrosion/ Irritating

Skinirritation Irritatinginrabbits.(4h/14days)

OECDGuideline404

Eyedamage/ Notirritatinginrabbits

Irritation (24h/21days)

OECDGuideline405

(Read-acrossbasedonmethylenediphe-

nyldiisocyanate-CAS26447-40-5.)

Summarizedtheavailableanimaldatawouldnotsupportclassifica-

tionofMDIasaneyeirritant.Buttogetherwithhumanoccupatio-

nalcasereportsinwhichsymptomsofeyeirritationwerereported

thelegalclassificationaseyeirritantshouldbeapplied.

11.3 Sensitisation

Animaldataaswellasstudiesinhumansprovideevidenceof

possibleskinsensitisation,andofrespiratorysensitisationdueto

MDI.AnimalstudiesindicatethatMDIisastrongallergen.Human

casereportsdescribetheoccurrenceofallergiccontactdermatitis

duetoMDIexposure.

Skinsensitisation MiceSensitizing.

OECDGuideline429(LLNA)

Respiratorysensitisation GuineapigSensitizing.

11.4 Mutagenicity

Notclassified.Basedonavailabledata,theclassificationcriteria

arenotmet.

11.5 Carcinogenity

Carc.Cat.2 Rats(inhalation)

NOAEC=0,2mg/m3air(Toxicity)

(2years;6h/day,5days/week)

NOAEC=1mg/m3air(Carcinogenicity)


LOAEC=6mg/m3air(Carcinogenicity)


OECDGuideline414

11.6 Reproductivetoxicity

Notclassified.Basedonavailabledata,theclassificationcriteria

arenotmet.

Effectsonfertility Nofertilitynormultigenerationstudies

areavailableforMDI.

Rats(inhalation)

NOAEL=4mg/m3air(developmental

toxicity)(10days;1/day,6h)

NOAEL=4mg/m3(maternaltoxicity)

(10days;1/day,6h)

OECDGuideline453

Phenol,isopropylated,phosphate(3:1)(CAS:68937-41-7)maybe

assumedtoinfluencefertilityormayharmthefoetusinwomb.

Phone: 810-412-4740 · www.S1Eonline.comPhone: 810-412-4740 · www.S1Eonline.com

SafetyDatasheet


Standard (Comp. B)


8/12

11.7 STOT-singleexposure

MDIsareirritanttotherespiratorytract.

11.8 STOT-repeatedexposure

Harmful Rats(inhalation)

LOAEC=1mg/m3air


Targetorgans:respiratory–lung

OECDGuideline453

11.9 Aspirationhazard

Notclassifiedduetolackofdata.

12. Ecologicalinformation

Informationisrelatedto4,4-Methylenediphenyldiisocyanateifno

otherismentioned.

12.1 Toxicity

12.1.1 Aquatictoxicity

Short-termtoxicitytofish

Freshwaterfish LC50

>1000mg/l(96h)

(Brachydaniorerio) OECDGuideline203

Oncorhynchusmykiss LC50

=1,6mg/l(96h)

Phenol,isopropylated,phosphate(3:1),

CAS:68937-41-7

Pimpephalespromelas LC50=10,8mg/l(96h)

(fathedminnow) Phenol,isopropylated,phosphate(3:1),

CAS:68937-41-7

Fisch LC50

=56,2mg/l(96h)

Tris(2-chlor-1-methylethyl)phosphate

(CAS-Number:13674-84-5)

Long-termtoxicitytofish

Datawaiving.Inaccordancewithcolumn2ofREACHAnnexIXthe

long-termtoxicitytestingonfishshallbeproposedifthechemical

safetyassessmentaccordingtoAnnexIindicatestheneedto

investigatefurthertheeffectsonaquaticorganisms.Thecorrespon-

dingPEC/PNECratioswouldbelessthan1.Takingintoaccountthe

scientificandexposurearguments,itappearsappropriatetowaiver

thelong-termfish/plant/soilandsedimenttoxicitystudies.

Short-termtoxicitytoaquaticinvertebrates

Freshwaterinvertebrates EC50

>1000mg/l(24h)

(Daphniamagna) OECDGuideline202

Freshwaterinvertebrates EC50

=131mg/l(48h)

(Daphniamagna) Tris(2-chlor-1-methylethyl)phosphate

(CAS-Number:13674-84-5)

Long-termtoxicitytoaquaticinvertebrates

Freshwaterinvertebrates NOEC>=10mg/l(21h)

(Daphniamagna) OECDGuideline211

Toxicitytoaquaticalgaeandcyanobacteria

Freshwateralgae EC50

>1640mg/l(72h)

(Desmodesmus OECDGuideline201

subspicatus)

Freshwateralgae EC50

=82mg/l(72h)

(Desmodesmus Tris(2-chlor-1-methylethyl)phosphate

subspicatus) (CAS-Number:13674-84-5)

Toxicitytoaquaticplantsotherthanalgae

Datawaiving.NotrequiredbyREACHannexes.However,a

mesocosmstudywithPMDIexistsinwhichthetoxicitytowards

macrophytes(PotamogetoncrispusandZannichelliapalustris)was

assessed.Notoxicitywasobservedataloadingof1000and10,000

mg/l,approximately100%ofthesubstancewasfoundinthesedi-

mentashardenedmaterial.

Toxicitytomicroorganisms

Microorganisms EC50

>100mg/l(3h)

(activatedsludge) OECDGuideline209

Toxicitytootheraquaticorganisms

Thisinformationisnotavailable,butnotrequiredunderREACH.

12.1.2Sedimenttoxicity

Datawaiving.AnnexXstatesthatthisstudyneednotbeconducted

ifthechemicalsafetyassessmentdoesnotindicateaneedto

furtherinvestigatetheeffectsonsedimentorganisms.


SafetyDatasheet


Standard (Comp. B)


9/12

12.1.3Terrestrialtoxicity

Toxicitytosoilmacroorganismsexceptarthropods

Eiseniafetida EC50

>1000mg/kgsoil

dw(14days)

OECDGuideline207

Toxicitytoterrestrialarthropods

Datawaiving.Basedonthechemicalsafetyassessmentand

theriskassessment,thereisnoneedtofurtherinvestigatethe

terrestrialarthropodstoxicityasthereisnoriskfortheterrestrial

environmentasindicatedbythePEC/PNECratiobeing<0.239.

Direct/indirectexposuretosoilisunlikely.

Toxicitytoterrestrialplants

Avenasativa EC50

>1000mg/kgsoil

dw(14days)

Lactucasativa EC50

>1000mg/kgsoil

dw(14days)

OECDGuideline208

Toxicitytosoilmicroorganisms

Datawaiving.AnnexXstatesthatthisstudyneednotbeconduc-

tedifthechemicalsafetyassessmentdoesnotindicateaneedto

furtherinvestigatetheeffectsonsedimentorganisms.

Toxicitytootherabove-groundorganisms

Datawaiving.NotrequiredbyREACHannexes.

12.1.4Conclusiononclassification

Hazardoustotheaquaticenvironment(acute)

Basedonavailabledata,theclassificationcriteriaarenotmet.

(EC/LC50

forfish,invertebratesandalgae>1000mg/l)

Hazardoustotheaquaticenvironment(chronic)

Basedonavailabledata,theclassificationcriteriaarenotmet.

(NOECforalgae>1640mg/L;NOECforinvertebrates>10mg/l).

12.2Persistenceanddegradability

Phototransformationinair

Half-life(DT50

) 1day

Hydrolysis

MDIreactswithwatertoformpredominantlyinertpolyurea.

Half-life(DT50

) 20h(at25°C)

Reactionratehydrolysis 0.5-1h

(Read-acrossbasedonOligomerMDI–CAS32055-14-4)

Phototransformationinwaterandsoil

Therearenophototransformationdatainwaterandsoilforthe

testsubstance.

Biodegradationinwater

Undertestconditionsnobiodegradationobserved.

(28days)OECDGuideline302C

Biodegradationinwaterandsediment

Datawaiving.InaccordancewithAnnexXI,simulationbiodegrada-

tiontestsaretechnicallynotfeasibleasthetestsubstancereacts

quicklywithwater.ThecorrespondingPEC/PNECratioswouldbe

lessthan1.Takingintoaccountthescientificandexposureargu-

ments,itappearsappropriatetowaiverthelong-termfish/plant/soil

andsedimenttoxicitystudies.

Biodegradationinsoil

Datawaiving.SeeatBiodegradationinwaterandsediment.

12.3Bioaccumulativepotential

Bioaccumulation-aquatic/sediment:Duetothehighreactivityof

thesubstancesoftheMDIcategorywithwater,bioaccumulation

testscaninprinciplenotbeperformedwiththesesubstances.

However,onebioaccumulationtestwith4,4'MDIandamesocosm

studywithPMDIwithanindicationofbioaccumulationpotential

havebeenperformed.Asnoanalyticalmeasurementsweredone,

itcannotbedeterminedifthevaluesaretrulyrelatedtoMDI.

However,basedontheavailableinformationandthereactivityof

MDIsubstancesofthecategoryapproach,nonewbioaccumulation

studyisdeemednecessary.


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12.4Mobilityinsoil

Adsorption/desorption Datawaiving.AccordingtoAnnexVIII

thestudyneednotbedoneifthetest

substancedegradesrapidly.Thecorres-

pondingPEC/PNECratioswouldbeless

than1.Takingintoaccountthescientific

andexposurearguments,itappears

appropriatetowaiverthelong-termfish/

plant/soilandsedimenttoxicitystudies.

Volatilisation TheestimatedHenry’sLawConstant,

calculatedfromthemeasuredvapour

pressureandthecalculatedwater

solubility,is2.263x10-7atm-m3/mole.

Hence,volatilizationisunlikelytobea

significantremovalmechanismforMDI

substancesofthecategoryapproach.

BCF(Cyprinuscarpio) 200(28days)

OECDGuideline305E

Terrestrialbioaccumulation

Nodataisavailableonterrestrialbioaccumulation,butitisnot

requiredunderREACH.

12.5ResultsofPBTandvPvBassessment

ConclusionforthePcriterion

TheresultsfromthebiodegradationtestindicatethatPMDIis

notbiodegradable.Basedonexperimentalhydrolysisandindirect

photolysishalf-lives,PMDIisnotconsideredtobepersistentinthe

environmentandisidentifiedasnotP.Basedonthejustification

inthecategoryapproach,itisassumedthatallMDIanalogues

includedinthecategoryarenotP.

ConclusionfortheBcriterion

AlthoughMDIhasahighmeasuredlogPowvalue(4.51),afull

bioaccumulationtestwith4,4’-MDIindicatedthatthebioaccumu-

lationpotentialislow.Duetothefasthydrolysis,exposureofthe

environmenttothesubstanceisunlikelyorverylow,thereisno

potentialforsignificantbioaccumulationpossible.Hence,4,4’-MDI

doesnotfulfiltherequirementsfortheBcriterionandisnotiden-

tifiedasB.Basedonthejustificationinthecategoryapproach,itis

assumedthatallMDIanaloguesincludedinthecategoryarenotB.

13. Disposalconsiderations

13.1 Wastetreatmentmethods

Theproductsbecominguselessandthecontaminatedcontainers

notsuitableforproductstoragemustbehandledashazardous

wasteinaccordancewithEUandregionalhazardouswasteregu-

lations.

EuropeanWasteCataloguecode

080501

13.1.1 Product/Packagingdisposal

Contaminatedpackagingshouldbeemptiedasfaraspossible;than

itcanbepassedonforrecyclingafterbeingthoroughlycleaned.

Wrappingscleanedfromcontaminationwithsuitablecleaning

process(e.g.bysteaming,treatingwithwashingfluid,etc.)mustbe

consideredasnonhazardouswaste.

13.1.2Wastetreatmentoptions

Incinerateinsuitableincinerationplant,observinglocalauthority

regulations.

ConclusionfortheTcriterion

Theconcentrationstestedwerefarabovethewatersolubilityof

theMDIsubstances(7.5mg/l).However,thewatersolubilitylimitof

MDIisfarabovethecriteriaforTandonthebasisofaquatic

toxicitytestsMDIisidentifiedasnotT.However,accordingto

AnnexIof67/548/EECMDIisclassifiedasXn,R48,which

automaticallytriggersaT.BasedonthisclassificationMDIis

identifiedasT.

12.6Otheradverseeffects

Itisnotexpectedthatsubstancehasaneffectonglobalwarming,

ozonedepletioninthestratosphereorozoneformationinthe

troposphere.

Secondarypoisoning:Basedontheavailableinformation,thereis

noindicationofabioaccumulationpotentialand,hence,secondary

poisoningisnotconsideredrelevant.

Exposuretobirdsisnotexpectedanddatafromexperimentalani-

malsshowMDItobeofloworaltoxicity.


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14. Transportinformation

Landtransport(ADR/RID/GGVSE)

Seatransport(IMDG-Code/GGVSee)

Airtransport(ICAO-IATA/DGR)

14.1 UNnumber

Notdangerousgoods.

14.2UNpropershippingname

Notdangerousgoods.

14.3Transporthazardclass(es)

Notdangerousgoods.

14.4Packaginggroup

Notdangerousgoods.

14.5Environmentalhazards

Marinepollutant no

14.6Specialprecautionsforusers

EmSnumber Notdangerousgoods.

14.7TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode

Notrelevant.

15. Regulatoryinformation

15.1 Safety,healthandenvironmentalregulations/legisla-tionsspecificforthesubstanceormixture

Information regarding relevant Community safety, health and

environmental provisions

ISOPA,theEuropeanDiisocyanate&PolyolProducersAssociation

haselaboratedaGuidelinedocumentforthesafetreatmentofMDI

containingproducts.TheGuidelineshavebeenbuiltintothisdata

sheet.

15.2ChemicalSafetyAssessment

InaccordancewithREACHChemicalSafetyAssessmenthasnot

beencarriedoutfortheproduct.However,theresultsfromthe

CSAfor4,4’-MDIweretransposedintothisSDS.

16. Otherinformation

Theinformationgivencorrespondswithouractualknowledgeand

experience.Thisinformationismeanttodescribeourproductin

viewofpossiblesafetyrequirements.Classificationofthemixture

isbasedontheclassificationofcomponents.

16.1 Indicationofchanges

DuetothetransitiontotheclassificationaccordingtoCLP,the

safetydatasheetshallberegardedasfullynew.

16.2Abbreviationsandacronyms

bw bodyweight

CASnumber ChemicalAbstractsServicenumber.

CLP Regulationonclassification,labelling

andpackaging.

DNEL Derivednoeffectlevel.

dw dryweight

ECnumber EINECSandELINCSnumber.

EC50

Halfmaximaleffectiveconcentration.

EINECS EuropeanInventoryofExistingCommer-

cialChemicalSubstances.

ELINCS EuropeanListofNotifiedChemical

Substances.

LC50

Lethalconcentration,50%.

LD50

MedianLethaldose.

LOAEC LowestObservedAdverseEffect

Concentration.

NOAEC NoObservedAdverseEffect

Concentration.

NOAEL NoObservedAdverseEffectLevel.

NOEC NoObservedEffectConcentration.

OECD OrganisationforEconomicCooperation

andDevelopment.

PBT Persistent,BioaccumulativeandToxic.


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PolymericMDI Polymethylenepolyphenyl

poliisocyanate.

PEC PredictedEnvironmentalConcentration.

PNEC PredictedNoEffectConcentration.

REACH TheRegistration,Evaluation,Authorisa-

tionandRestrictionofChemicals.

vPvB VeryPersistentandVery

Bioaccumulative.

16.3Keyliteraturereferencesandsourcesfordata

safetydatasheets,receivedfromtherawmaterialssuppliers.

16.4Fulltextofabbreviations

H- Phrases

H302 Harmfulifswallowed.

H315 Causesskinirritation.

H317 Maycauseanallergicskinreaction.

H319 Causesseriouseyeirritation.

H332 Harmfulifinhaled.

H334 Maycauseallergyorasthmasymptoms

orbreathingdifficultiesifinhaled.

H335 Maycauserespiratoryirritation.

H351 Suspectedofcausingcancer.

H373 Maycausedamagetoorgansthrough

prolongedorrepeatedexposure:

respiratorysystem,inhalation.

H411 Toxictoaquaticlifewithlonglasting

effects.

P- Phrases

P260 Donotbreathedust/fume/gas/mist/

vapours/spray.

P280 Wearprotectivegloves/protective

clothing/eyeprotection/faceprotection.

P285 Incaseofinadequateventilationwear

respiratoryprotection.

P302+P352 IFONSKIN:Washwithplentyofsoap

andwater.

P304+P340 IFINHALED:Removevictimtofresh

airandkeepatrestinaposition

comfortableforbreathing.

P309+P311 IFexposedorifyoufeelunwell:Calla

POISONCENTERordoctor/physician.

Hazard classes

AcuteTox. AcuteToxicity

AquaticChronic Hazardoustotheaquaticenvironment

Carc. Carcinogenity

EyeIrrit. Seriouseyeirritation

Repr. Reproductivetoxicity

Resp.Sens. Respiratorysensitization

SkinIrrit. Skinirritation

SkinSens. Skinsensitization

STOTRE Specifictargetorgantoxicity–

repeatedexposure

STOTSE Specifictargetorgantoxicity–

singleexposure
