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Zirconia – Alumina – Metal Primer
BISCO’s Z-PRIME Plus is a single-component priming agent used to create adhesion between indirect restorative materials and all resin containing cements.
Z-PRIME Plus - A proprietary Formula of concentrated MDP/Carboxylate monomers has been specifically formulated to address the current weakness in competitor’s primers and create a compelling reason to replacethem immediately!
Z-PRIME™ PlusBisco
Bisco Products v.s. Zirconia/Silane Competitors
Clearfil CeramicKuraray
Monobond PlusIvoclar Vivadent
Product Applications Components
Zirconia, Alumina, Metal
Silica-ceramics
Zirconia, Alumina, Metal, Silica-ceramics
Zirconia, Alumina, Metal, Silica-ceramics
BPDM, Phosphate,Ethanol
Silane
Phosphate, Silane*Ethanol
Phosphate, Silane*Ethanol
*: Silane is not stable in the presence of acidic phosphate monomer.
Porcelain PrimerBisco
Issue of Silane Incorporation into Zirconia Primers
Clearfil CeramicKuraray
Monobond PlusIvoclar Vivadent
Porcelain PrimerBisco
Silane Primer Zirconia/Silane Primer
Contain: Silane Contain: Silane & Acidic Phosphate
Silane Methacrylate De-activation of SilanePre-hydrolyzed Silane
OR
Si
O
OCH3
OCH3
OCH3 AcidO
RSi
O
OH
OH
OH
Dimer, Oligomer, Polymer
pH 5.0 3.1 3.7
To maintain a good shelf-life, pH of one-bottle silane primer systems should be adjusted to 4-5.
Self-Condensation of Hydrolyzed Silane
Z-PRIME PlusIndications For Use
BISCO’s Z-PRIME™ PLUS is intended for use as a surface treatment for the following indirect restoration substrates:
Zirconia (e.g. Lava, Cerec, Implant & others) Alumina (e.g. Procera) Metal/alloy (Titanium, PFM, Non-Precious, High
Noble) Composite (Direct & Indirect) Endodontic Posts (Zirconia, Metal, Fiber) Intra-oral repairs
Using the new primer had a significant effect on increasing the bond strength to zirconia of the tested cements between 86% and 160% increase.
G. MILLAN, M. RAAD, M. ATTAR, and D. NATHANSON, Primer Effect on Bond Strength of Resin Cements to Zirconia, J Dent Res 89(Spec Issue A): Abstr. 1018, 2010
Primer Effect on Bond Strength of Resin Cements to Zirconia
Strong Bond Strengths to Different Substrates
23 MPa
Cement-Self Cured
Zirconia
18 MPaAlumina
3 MPa
With Z-PRIME™ Plus with no primer
4 MPa
22 MPaTitanium
23 MPaNon-precious
24 MPaStainless Steel
20 MPaGold
27 MPaComposite
Unique Benefits
Unparalleled bond strengths to Zirconia, Alumina and Metal Restorations
High S/C & L/C Bonds
SBS of Z-PRIME™ Plus on Different Dental Substrates w/ Duolink™
0 5 10 15 20 25 30 35
Fiber Post
Composite
Gold
Rex III
Option
Stainless Steel
Titanium
Ceramic
Alumina
Zirconia
SBS(MPa)
No PrimerZPRIME+ -S/CZPRIME+ -L/C
Bisco’s new DuoLink™ SE Kit including Z-PRIME Plus and Bis-Silane™ offers a system that provides “Confidence in Indirect Adhesion. The stability of the chemistry is demonstrated by not requiring refrigeration…
New
Z-PRIME™ PlusBisco Released 2009
Clearfil CeramicKuraray
AZ PrimerShofuReleased 2009
Metal/Zr PrimerIvoclar Vivadent
Monobond PlusIvoclar VivadentReleased 2009
Product Applications Components Shelf-life
2y/room temp. 2y/r.t.*(Duolink™)
2y/rom temp.2y/refrig.*(ResiCem)
2y/room temp.2y/refrig.*(Multilink)
2y/room temp.2y/refrig.*(Multilink
2y/refrig2y/refrig.*(Panavia)
Zirconia, Alumina, Metal
Zirconia, Alumina
Zirconia, Alumina, Metal
Zirconia, Alumina, Metal, Silica-ceramics
Zirconia, Alumina, Metal, Silica-ceramics
BPDM, Phosphate,Ethanol
Phosphonate,Acetone
Phosphonate, t-butyl alcohol
Phosphate, Silane**Ethanol
Phosphate, Silane**Ethanol
*: Shelf-life of its corresponding cement. **: Silane is not stable in the present of acidic phosphate monomer.
Competitors
Compatible with light-cured and dual-cured resin luting cements
Unique Benefits
Z-PRIME™ PlusDuolink™Bisco
29 MPa
8 MPaClearfil CeramicPanavia F2.0Kuraray
21 MPaAZ PrimerResiCemShofu
Cement-Light Cured
16 MPaMetal/Zr PrimerMultilink AutomixIvoclar Vivadent
26 MPaMonobond PlusMultilink AutomixIvoclar Vivadent
Stronger Bonding: SBS to Zirconia
Z-PRIME™ PlusDuolink™Bisco
23 MPa
9 MPaClearfil CeramicPanavia F2.0Kuraray
13 MPaAZ PrimerResiCemShofu
Cement-Self Cured
8 MPaMetal/Zr PrimerMultilink AutomixIvoclar Vivadent
11 MPaMonobond PlusMultilink AutomixIvaclar Vivadent
Stronger Bonding: SBS to Zirconia
Z-PRIME™ PlusDuolink™Bisco
Durable Bonding: SBS to Zirconia After Aging
Clearfil CeramicPanavia F2.0Kuraray
AZ PrimerResiCemShofu
Aged 3 days in boiling water, equiv. to 6 years at 37 °C. Cement-Light Cured.
Monobond PlusMultilink AutomixIvoclar Vivadent
29 MPa (Day 1) 28 MPa (6 years)
8 MPa (Day 1) 3 MPa (6 years)
21 MPa (Day 1) 18 MPa (6 years)
26 MPa (Day 1) 16 MPa (6 years)
Z-PRIME™ PlusDuolink™Bisco
Durable Bonding: SBS to Zirconia After Aging
Clearfil CeramicPanavia F2.0Kuraray
AZ PrimerResiCemShofu
Aged 3 days in boiling water, equiv. to 6 years at 37 °C. Cement-Self Cured.
Monobond PlusMultilink AutomixIvoclar Vivadent
23 MPa (Day 1) 16 MPa (6 years)
9 MPa (Day 1) 2 MPa (6 years)
13 MPa (Day 1) 6 MPa (6 years)
11 MPa (Day 1) 7 MPa (6 years)
Comparison of Zirconia Restoration Luting Options: SBS to Zirconia
23 MPa
Cement-Self Cured
Primer w/ Resin Cement
Self-Adhesive Resin Cements
Resin Modified Glass Ionomer Cements
8 MPa
4 MPaRelyX Luting+
(3M ESPE)
FujiCEM (GC)
SmartCem2 (Dentsply)
BisCem (Bisco)
UniCem (3M ESPE)
Z-Prime™ Plus w/ Duolink™ (Bisco)
Duolink (Bisco)
12 MPa
11 MPa
Traditional Resin Cement without Primer (Control)
4 MPa
6 MPa
Average Shear Bond Strength of Zirconia Primers with their Corresponding Self-cure Resin
Cements
Contains:Phosphate Monomer (MDP), BPDM, ethanol
Strong Bond between Resin-cements/composites and:ZirconiaAluminaMetals Titanium, Stainless steel, Rexilium, Option, GoldCompositesInstruction for Use:Apply 1-2 coatsDryProceed with cementation. Zr, Al, or
Metal etcDentin
Z-PRIME PLUS
Duolink
Technique For Placement
Clean the internal surface of the restoration; rinse and air dry.
Apply 1-2 coats of Z-PRIME™ Plus, uniformly wetting the internal surface. Dry with an air syringe for 3-5 seconds.
Proceed with cementation using a luting cement (e.g. DUO-LINK™).
ZrD BisCem
For Full/Retentive Zr Crowns use Biscem® with Z-PRIME™ Plus
Z-P
rime
Cementing Zirconia Crowns
ZrDDuoLink Cement
Short/Tapered, Non-retentive Zr Crown adhesively bond with Resin Cement
Z-P
rime
Ad
hesive
Bonding Zirconia Crowns
“Improved marginal adaptation, prevention of microleakage,increased fracture strength, and increased retention insituations where mechanical retention does not exist constitute the benefits of a stable and durable resin bond tozirconia.”
Magne P, et al. New zirconia primer improves bond strength of resin-based cements. Dent Mater (2009), doi:10.1016/j.dental.2009.12.005
New zirconia primer improves bond strength of resin-based cements.
“The groups where the experimental zirconia primer (ZrP-groups) was used presented the highest mean bond strength values.”
“The groups that did not receive the experimental primer (NP groups)and the group treated with the MDP-containing primer(CCP-group) presented the lowest mean bond strength values”
Magne P, et al. New zirconia primer improves bond strength of resin-based cements. Dent Mater (2009), doi:10.1016/j.dental.2009.12.005
New zirconia primer improves bond strength of resin-based cements.
“ “Confidence in Adhesion”Confidence in Adhesion”
Proprietary MDP and carboxylic acid monomers
Significantly enhances bond strengths of other resin cements*
Compatible with light-cured and dual-cured resin luting cement
Convenient, single bottle delivery offers ease of dispensing
Fast/Predictable Cementation
*Data on file, BISCO, Inc.*Data on file, BISCO, Inc.