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Contrib Mineral Petrol (2017) 172:10 DOI 10.1007/s00410-016-1324-y

ORIGINAL PAPER

Zircon record of fractionation, hydrous partial melting and thermal gradients at different depths in oceanic crust (ODP Site 735B, South-West Indian Ocean)

A. Pietranik1 · C. Storey2 · J. Koepke3 · S. Lasalle2,4 · EIMF

Received: 22 June 2016 / Accepted: 16 December 2016 / Published online: 14 February 2017 © The Author(s) 2017. This article is published with open access at Springerlink.com

Site 735B gabbro. Zircons from oxide gabbro are scarce and variable in composition consistent with their crystal-lization from melts formed by both fractionation of mafic magmas and hydrous remelting of gabbro cumulate. On the other hand, zircon from plagiogranite is abundant and each sample is characterized by compositional trends consistent with crystallization of zircon in an evolving melt. However, the trends are different between the plagiogranite at 500 m bsf and the deeper sections, which are interpreted as the record of plagiogranite formation by two processes: remelt-ing of gabbro cumulate at 500  m bsf and fractionation at deeper sections. Zircon from both oxide gabbro and pla-giogranite has δ18O from 3.5 to 6.0‰. Values of δ18O are best explained by redistribution of δ18O in a thermal gradi-ent and not by remelting of hydrothermally altered crust. Tentatively, it is suggested that fractionation could be an older episode contemporaneous with gabbro crystallization and remelting could be a younger one, triggered by defor-mation and uplift of the crustal pile.

Keywords Oceanic crust · Felsic melt · Zircon crystallization · Fractionation · Hydrous melting · Trace elements · Hf, O isotopes

Introduction

Oceanic crust constitutes approximately 60% of the Earth’s crust and its continuous formation at ocean ridges depletes underlying mantle in incompatible elements. The elements are later distributed within the oceanic crust by magmatic and hydrothermal processes. The lower oceanic crust com-prises predominately mafic to ultramafic rocks evolving in a general framework of fractional crystallisation, crystal accumulation and intercumulus melt removal (e.g., Klein

Abstract Felsic veins (plagiogranites) are distributed throughout the whole oceanic crust section and offer insight into late-magmatic/high temperature hydrother-mal processes within the oceanic crust. Despite constitut-ing only 0.5% of the oceanic crust section drilled in IODP Site 735B, they carry a significant budget of incompatible elements, which they redistribute within the crust. Such melts are saturated in accessory minerals, such as zircon, titanite and apatite, and often zircon is the only remaining phase that preserves magmatic composition and records processes of felsic melt formation and evolution. In this study, we analysed zircon from four depths in IODP Site 735B; they come from the oxide gabbro (depth approxi-mately 250 m below sea floor) and plagiogranite (depths c. 500, 860, 940 m below sea floor). All zircons have similar εHf composition of c. 15 units indicating an isotopically homogenous source for the mafic magmas forming IODP

Communicated by Gordon Moore.

Electronic supplementary material The online version of this article (doi:10.1007/s00410-016-1324-y) contains supplementary material, which is available to authorized users.

* A. Pietranik anna.pietranik@uwr.edu.pl

1 Institute of Geological Sciences, University of Wroclaw, Wroclaw, Poland

2 School of Earth & Environmental Sciences, University of Portsmouth, Portsmouth, UK

3 Institut für Mineralogie, Leibniz Universität Hannover, Hannover, Germany

4 EIMF - Edinburgh Ion Micro-Probe Facility, The School of GeoSciences, The University of Edinburgh, Edinburgh, UK

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2003; Coogan 2014). While oceanic crust formed at fast-spreading rates exhibits a relatively uniform seismic stra-tigraphy (e.g. Canales et al. 2003) and is regarded as lay-ered and relatively homogeneous, oceanic crust generated at slow-spreading ridges is characterized by larger hetero-geneity. Here, crustal accretion is dominated by tectonic rather than solely by magmatic processes (e.g. Cannat 1996; Dick et al. 2006). Also, typical oceanic crust sections from slow-spreading ridges are constructed from numerous magma pulses evolving separately, without the presence of long-lived axial magma lenses, as characteristic for fast-spreading ridges (e.g. Dick et  al. 2000). The late stage of magmatic evolution of oceanic crust, either after or con-temporaneous with the extraction of basaltic melts from the cumulate pile, involves formation of diorites, quartz-dior-ites, tonalites and trondhjemites, collectively termed “oce-anic plagiogranites” (for definition see Koepke et al. 2007). The consensus is that the felsic lithologies crystallized from evolved melts at temperatures above 800 °C (e.g. Robinson et al. 2002). They carry a significant budget of incompat-ible trace elements (e.g. Godard et  al. 2009), and as they travel upwards, they redistribute these elements throughout the oceanic crust.

Therefore, plagiogranite evolution affects the mobil-ity and distribution of the incompatible elements within the oceanic crust during the magmatic stage but possibly also during later interaction of the crust with seawater and finally in subduction zones and in the mantle, where the subducted crust is partially melted. The interaction between the oceanic crust and seawater has a significant effect and is best illustrated by the change in oxygen isotope composi-tion through the oceanic crust section. In a typical profile, the crust is altered with δ18O values up to 13‰ in the vol-canic part of the crust and δ18O down to 4‰ in the plu-tonic part of the crust (e.g. Gregory and Taylor 1981). This is respectively higher and lower than approximately 5.6‰, a value typical for unaltered basalt. The alteration is also observed in plagiogranites as most of the major mineral assemblages in plagiogranite veins are strongly hydrother-mally altered (Robinson et  al. 2002), and it is, therefore, difficult to reconstruct the magmatic stage of plagiogran-ite crystallization based on major minerals or whole rock geochemistry. However, zircon remains often unaltered and is a suitable phase in the felsic veins that records the magmatic evolution of the crust and offers insight into late stages of oceanic crust development. In particular, zircon isotope and trace element composition may contribute to the on-going debate on the origin of felsic melts in oceanic crust and constrain their origins as extremely fractionated mafic melts versus melts formed by hydrous remelting of cumulate gabbros (e.g. Koepke et al. 2004; Brophy 2009). Previous O isotope analyses of oceanic zircon showed uni-form δ18O values around 5.7‰, which was not interpreted

in terms of possible plagiogranite formation processes. On the other hand, O isotope analyses in zircon from ophiolitic plagiogranites ranged from 3.9 to 5.6‰, which is consist-ent with remelting of altered oceanic crust to produce the felsic melts (Grimes et al. 2013).

Site 735B offers unparalleled insight into in  situ oce-anic crust formed at ultra-slow ridges. Tectonic processes uplifted the plutonic section of the crust and ODP Leg 176 drilling recovered approximately 1500  m of mostly gab-broic rocks. In this study, we present zircon compositions from four depth levels in Site 735B and interpret them in the context of related oxide gabbro and plagiogranite for-mation. We also show that the zircons record contrasting processes of the felsic melts’ formation, with the upper part of Site 735B being dominated by felsic veins produced pos-sibly by hydrous partial melting of gabbro and the lower part dominated by felsic veins formed by extreme fractional crystallization of MORB. We demonstrate that zircon is a particularly useful tool that offers insight into oceanic crust development at the interface between late-magmatic and post-magmatic metamorphic processes; a regime where the petrological record is mostly obscured by later low temper-ature hydrothermal alteration.

Analytical methods

Zircons were separated from core pieces (usually quarter of the core section or less and a few cm long). One or sev-eral core pieces from similar depths were crushed together in a jaw crusher and then the crushed material was sieved. Next, the divided material was carefully panned and examined under a binocular microscope, the zircons were picked using tweezers and mounted in epoxy resin. Once polished to reveal the interiors of the grains, the zircons were imaged by charge contrast in a Scanning Electron Microscope (SEM) at the University of Bristol. Then the zircons were analysed for O, Hf and major and trace ele-ments. Detailed description of the analytical procedures is given in Appendix 1. Full data sets are given in Appendices 2 to 5 (Appendix  2: O isotope data, Appendix  3: Hf iso-tope data, Appendix  4: trace element data by LA-ICPMS (Laser Ablation-Inductively Coupled Plasma Mass Spec-trometry), Appendix  5: microprobe data). Oxygen iso-topes were analysed using a CAMECA IMS 1270 second-ary ionisation mass spectrometer (SIMS) at the University of Edinbourgh. Hafnium isotopes were analysed using a Thermo-Scientific Neptune MC-ICPMS (Multi Collector-Inductively Coupled Plasma Mass Spectrometer) coupled to a New Wave Research UP193HE Deep-UV (193  nm) ArF Excimer laser ablation sampling system at the Univer-sity of Bristol (Bristol Isotope Group). Major elements: Zr, Si, Hf, P and Y were analysed using an electron microprobe (EPMA) CAMECA SX100 at the University of Warsaw.

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The analytical conditions were: 60nA beam current, 15 kV voltage and focused beam. Trace elements were analysed using Laser Ablation-Inductively Coupled Plasma Mass Spectrometer (LA-ICPMS: Asi Resolution ArF 193  nm laser coupled to an Agilent 7500CS quadrupole mass spec-trometer) at the School Of Earth and Environmental Sci-ences at the University of Portsmouth. Trace elements were analysed twice with the first attempt, at a different labora-tory resulting in failure; only the second attempt at the Uni-versity of Portsmouth was successful. The first attempt left 70 micron holes in many zircon grains.

Site 735B—petrography and geochemistry

Site 735B is located at the Atlantis II Transform Fault (Fig.  1) on the ultra-slow-spreading Southwest Indian Ridge with spreading rate estimated at 16 mm/year (Fisher and Sclater 1983). Site 735B is situated on the Atlantis Bank, which is a flat, uplifted block of the seafloor cur-rently residing 720  m below sea level (Natland and Dick 2002a). The drilling had a total depth of 1508 m and was completed during two legs: Leg 118 in 1987 and Leg 176 in 1997. Over 860 m of igneous rock was recovered during the second leg, which represents 86% recovery (Natland and Dick 2002b).

The Hole735B drillcore is represented predominately by olivine gabbro (over 76%) and oxide gabbro (approximately 24% vol., Natland and Dick 2002a; Hertogen et  al. 2002) The olivine gabbro was divided into three sections with boundaries at approximately 250 m b.s.f. (below sea floor) and 500 m b.s.f. The uppermost two are more primitive as illustrated by their higher Mg/(Mg + Fe2+) ratios and lower TiO2 wt % than those in the third section (Natland and Dick 2001). They are separated by an approximately 50 m thick zone of massive oxide gabbro, the thickest horizon of oxide gabbro in Hole 735B (Fig. 2a). Oxide gabbros are distrib-uted through the olivine gabbro suite in all three sections with sharp contacts between the two lithologies (Ozawa et  al. 1991). The oxide gabbros have higher TiO2 con-centration in whole rock and generally lower An content

Fig. 1 a Location of Hole 735B and b Bathymetric map of the Atlantis II Fracture Zone modified from Dick et al. (1991)

Fig. 2 Sampling sections (grey bands representing the range of depths from which the analysed samples were taken) related to the downhole logs from Site 735B showing a abundances of major rock types, modified after Dick et  al. (1999), the profile was simplified such that gabbro comprises troctolitic gabbro, olivine gabbro and gabbro and oxide gabbro comprises disseminated Fe-Ti oxide gabbro, Fe-Ti oxide gabbronorite and Fe-Ti oxide gabbro, b relative abun-

dance of felsic veins modified after Robinson et  al. (2002) and Mg number in primitive gabbro modified after Natland and Dick (2002a). The remaining profiles show data obtained in this study c-d) δ18O and ɛHf in the whole zircon populations analysed in different sections and e uncorrected Ti-in-zircon temperature in different sections, calcu-lated using the calibration from Watson et al. (2006)

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in plagioclase and Mg/(Mg + Fe) in olivine and pyroxene compared to olivine gabbros (Ozawa et al. 1991). The oxide gabbros are also characterized by disequilibrium between Fe-Ti oxides and major minerals as well as alignment of the oxides along shear zones (Dick et al. 2000; Niu et al. 2002). These together point to complex origins of oxide gabbros and suggest that they may contain, beside typical cumulate minerals, significant amounts of liquid expelled from the crystallizing olivine gabbros (Dick et al. 2000).

Felsic veins (plagiogranite) constitute approximately 0.5% volume of Site 735B (Niu et al. 2002; Robinson et al. 2002). The veins are up to several centimetre thick and have predominately leucodiorite composition (Robinson et  al. 2002). Interestingly, they are distributed throughout the whole of Hole735B section suggesting that their distri-bution could be controlled by late shearing and melt expul-sion (Dick et al. 2000).

Samples

Zircon was separated from drill cores from four depth inter-vals as shown in Table 1. The intervals are called Section 1 to 4 in the following paper.

The samples from Section 1 are all located in oxide gab-bro (classified as interstitial olivine bearing oxide gabbro or olivine Fe-Ti oxide microgabbro according to Ozawa et al. 1991). They belong to the massive 55 m oxide gabbro sec-tion emplaced between two olivine gabbro sections (Nat-land and Dick 2002a). The oxide gabbro horizon is also divided into several parts (Ozawa et al. 1991). The zircon was taken from the part which is strongly differentiated and characterized by evolution towards the lowest An in plagi-oclase and the lowest Mg/(Mg + Fe) in olivine and clino-pyroxene from the top to the bottom of the oxide gabbro section (Section IV of the oxide gabbro from Ozawa et al. 1991).

The samples from Sections 2 to 4 all contain felsic veins. The samples from Section 2 comprise a single 3-cm thick felsic vein in olivine gabbro and the samples from Sec-tion 3 comprise a single felsic 1.5-cm thick vein and Sec-tion 4 includes multiple thin felsic veins. All the veins in

the Sections 3 and 4 are located within olivine gabbro. In samples with thin veins whole samples (1/4 core sections) were crushed, sieved and panned in search for the zircon grains. However, we believe that zircon comes from the veins since the samples composed entirely of olivine gab-bro did not yield a single zircon grain.

Zircon: structure, chemical and isotope composition

Section  1 (248–265  m b.s.f.): Only seven zircon grains were found in the Section  1 samples. The zircon grains are 100–150 µm in diameter along their z axes. They can be classified as Type 2 grains according to Grimes et  al. (2009), i.e. subhedral grains showing magmatic, oscil-latory and/or sector zoning (Fig.  3). The zircon grains can be divided into three groups based on their composi-tion, each group is located in its own compositional field for many trace elements (Fig.  4). Despite the chemical variability, all of the zircons have typical magmatic REE patterns. Group 1 comprises two grains, which are bright in the contrast images. The Group 1 zircon has the high-est Ti and lowest U contents. The Ti content is from 16 to 25 ppm, and therefore, is the highest from all analysed grains in Site 735B. Group 2 comprises four grains (three analysed by LA-ICPMS and all four by EPMA). The grains have dark charge contrast cores and lighter rims. They have the lowest Ti, Hf, Nb, Ce, P, LREE, MREE and Ta contents compared to all other grains from Section  1. The zircons are also characterized by the least negative Eu anomaly, lowest Th/U and highest HREE/MREE and HREE/LREE. Interestingly, zircons with composition similar to those in Group 2 were not observed in the database of Grimes et al. (2009), in particular because of their pronounced Eu anom-aly. Group 3 is represented by a single grain, which has the highest Hf, U, Th, P, Y, REE (minus Eu), Nb, Ta contents and moderate Ti contents. The grain also has the most neg-ative Eu anomaly. High Hf, Y and P contents in the grain were confirmed by EPMA (Table SM5). The high concen-trations of U, Th, P, Y, REE, Nb, Ta are similar to those of some grains from leucocratic veins analysed in Section 3; however, the grain has higher Hf concentration. Similar

Table 1 Characteristic of Sections 1 to 4 as defined in this study

Sample names are original names given by the ODP Leg 176 Scientific Party

Depth [m b.s.f.] Lithology Sample names

Section 1 248–265 Oxide gabbro 118-0735B-052R-04W-47-51; 118-0735B-053R-03W-131-135; 118-0735B-053R-04W-28-32; 118-0735B-053R-05W-47-54; 118-0735B-054R-02W-35-44

Section 2 506–513 Plagiogranite 176-0735B-090R-01W-38-46 and 176-0735B-090R-01W-61-67Section 3 859–870 Plagiogranite 176-0735B-138R-04W-54-58Section 4 940 Plagiogranite 176-0735B-146R-01W-61-64; 176-0735B-146R-01W-74-78

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grains were analysed and are included in the databases of Grimes et  al. (2009). O isotopes varied slightly between groups (Fig. 5) and δ18O was the highest in Group 1 zircon (from 4.0 to 5.0‰), slightly lower in Group 2 (from 3.7 to 4.4‰) and the Group 3 grain had δ18O of 3.5‰. Hf iso-topes were uniform with εHf from 15.2 to 15.5 (Fig. 2).

Section 2 (506–513 m b.s.f.): Zircons from this section are the most uniform in trace element composition from all of the sections. The zircon grains are 100–500  µm in diameter along their z axes, and are subhedral to euhedral. They have concentric or sector zoning. Larger grains have dark cores in contrast images surrounded by lighter man-tles and then darker rims (Fig.  3). Elongate, highly lumi-nescent zones occur close to the zircon rims, usually along one of the zircon faces. The luminescent parts are not char-acterized by clearly distinct compositions compared to

other parts of zircon grains. Larger zircon grains are zoned from cores to rims and have enrichment in most of the elements, particularly P, Nb, Ta, REE, U and Th (but not Ti, which is similar throughout the grain). The rims also have slightly higher Hf contents and are characterized by a more pronounced negative Eu anomaly. One small grain was analysed by EPMA that had much higher P and Y than the remaining grains, but similar Hf. In fact, its P and Y contents are similar to the Group 3 grain from Section 1. Oxygen and Hf isotopes are uniform in the whole section and the observed variations are mostly within the analytical uncertainty; δ18O varies from 4.7 to 5.8‰ (Figs. 2, 5) and εHf has values from 14.6 to 16.0 (Fig. 2).

Sections 3 and 4 (860–940 m b.s.f.): The zircons from both sections have a similar appearance and range of trace element contents. These sections have large variations in

Fig. 3 Charge contrast images of representative zircon grains from different depth sections and the corresponding Hf concentrations. The points are evenly spaced along the shown traverses

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trace element contents in zircon, but limited ones in ele-ment to element ratios (Fig.  6). The zircon grains are 100–500 µm in diameter along their z axes and are subhe-dral to euhedral. They have concentric or sector zoning. Euhedral, luminescent cores are often present within euhe-dral grains (Fig.  3). Numerous grains are fragmented and

have irregular sector zoning. Differences in trace element contents occur between grains and in a single grain in the core to rim direction. Generally, Hf increases and Ti and Eu anomaly decreases in the core to rim direction and these parameters correlate with each other for the whole zircon population (Fig. 4). Other elements, e.g. REE, Nb, U, Th,

Fig. 4 Distinct compositional groups at different depths of the oce-anic crust. Circles this study, Crosses literature database. Three groups from Section 1 are outlined in case their composition is sub-stantially different. Light grey crosses show zircon composition from a wide variety of oceanic gabbro lithologies from three differ-

ent localities including Mid-Atlantic Ridge (Holes 1275D, 1270D, 1309B, 1309D and Kane core complexes) and Southwest Indian Ridge (Hole 735B). Dark grey crosses represent zircon from the sam-ple JR-31 29−2, collected by dredging during RRS James Clark Ross Leg 31 (Schwartz et al. 2010)

Fig. 5 Variations of δ18O with elemental abundances in zircon from different depths. The range typical for δ18O values in zircon in equi-librium with mantle melts is after Valley et  al. (2005), the range of

δ18O expected in differentiating MORB is estimated from the equa-tion δ18O=0.052*SiO2WR + 3.03 (Spulber and Rutherford 1983) and the range of SiO2 is taken from Robinson et al. (2002)

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have complex trends with increasing Hf, i.e. their concen-trations increase with Hf with the maximum values and the large range of concentrations observed at Hf = 14,000 ppm; at Hf contents > 14,000  ppm they decrease (Fig.  7). The grains with highest contents of P, Y, U, Th and REE are similar to the grain from Group 3 in Section 1 and the other single grain from Section 2. Generally, Section 3 has more grains with elevated trace element contents and also con-tains the grain with the highest concentrations of P, Y, U, Th and REE compared to other sections. Section 3 zircons have δ18O ranging from 3.8 to 5.5‰, whereas Section  4 zircons range from 4.6 to 5.9‰ (Figs.  2, 5). The δ18O decreases with increasing P content in the whole of the zircon population of Sections 3 and 4 (R2 = 0.5 for EPMA dataset). Section 3 has an εHf range from 14.2 to 15.9 and Section 4 from 13.9 to 15.4 (Fig. 2).

Zircon: comparison between the sections

Section 1” zircons do not have any clear trends in Hf ver-sus other trace elements, the values are rather scattered

or constant for Groups 1 and 2 depending on the element (Figs.  4, 7). The only consistent trend seems to be rapid decrease in Eu anomaly with increasing Hf (Fig. 4).

The zircons from Section  2–4 are from plagiogranite and have overlapping compositions for many of the trace elements. However, Sections 3 and 4 are characterized by higher variability in trace element contents compared to Section  2 and generally higher maximum concentrations of all trace elements except Ti and Hf (Figs. 4, 6). In con-trast, many elemental ratios such as HREE/LREE, HREE/MREE, Eu anomaly and Nb/Ta have similar ranges and low variability in all three sections (Fig.  6). Sections  3 and 4 have higher Th/U ratios and Ce/other REE ratios than Sec-tion 2 (Fig. 6).

Generally, Hf increases in the core to rim direction in the zircons from Section  2–4 and diagrams of Hf [ppm] versus other trace elements should approximate the magma evolution as plagiogranite melts crystal-lized. This is because Hf-rich zircon is stabilized at lower temperatures. The zircons from Section  2 have different trends in Hf versus trace elements diagrams to zircons

Fig. 6 Comparison of elemental concentrations and ratios between different sections. The single analysis in the oxide gabbro column with high elemental concentrations in A, B and C graphs belongs to Group 3

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from Sections  2 and 4 (Fig.  7). In detail, Section  2 zir-cons have only slightly increasing contents for many ele-ments (Ce, HREE, Y, Th, U, Nb, Ta) with increasing Hf content or more random distribution for other elements (other LREE, MREE). In contrast, Sections 3 and 4 zir-cons have abrupt increases of these elements up to c. 14,000  ppm Hf, which then decrease at higher Hf con-centrations. Interestingly, similar trends were observed for natural whole rock compositions in SiO2 versus REE concentrations (Brophy 2009), where SiO2 should reflect magma evolution in a similar manner as Hf reflects it in zircon. For elemental ratios, trends are similar between

Sections  2,  3 and 4 with decrease in Eu anomaly and increase in Yb/Gd ratio with increasing Hf (Fig. 4).

Zircon: comparison with other datasets

Trace elements were analysed in oceanic zircons from a few localities including over 30 analyses of zircon from ODP Site 735B (Grimes et  al. 2009). Another dataset includes zircons from a felsic vein intruding oxide gabbro, the sam-ple of which was dredged during Leg 31 (Schwartz et  al. 2010). Generally, our analyses fit well with the database of Grimes et al. (2009) and usually plot in the middle of a

Fig. 7 Compositional trends for trace elements with increasing Hf in zircon. Since Hf generally increases in the core to rim direction (Fig. 3) the plot shows a possible record of changing zircon composition as magma evolved

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cloud defined by magmatic zircon (Type 1 and 2, euhedral and subhedral to anhedral magmatic grains, respectively) in this database (Fig. 4). Trends defined by Site 735B zir-con are usually tighter and better defined than the general trends; however, the direction of element versus element change is similar. Porous grains (Type 3—defined as hydro-thermal grains in Grimes et al. 2009) are usually outside of the compositional range of zircons analysed in this study. The only group of zircons that is not within the composi-tional range of the dataset of Grimes et al. (2009) is Group 2 zircon from oxide gabbro (Fig. 4).

The zircon grains analysed in the sample described by Schwartz et  al. (2010) usually plot outside the composi-tional fields defined by the zircon analysed in this study. Their Hf concentration is higher and also most of the trace element concentrations are higher or similar to the maxi-mum values observed in zircon from Sections 3 and 4. In fact, the zircon composition seems to overlap partly only with the single grain constituting Group 3 in Section  1 (Fig.  4), which suggests that Group 3 is a separate and important group and not a single outlier.

Discussion

The felsic melts may form within oceanic crust either by extreme fractional crystallization of mafic melts (classical approach, e.g. Aldiss 1981) or by remelting of hydrated oceanic crust (e.g. Koepke et al. 2007). Also, the melts may be separated from their host rocks and may intrude into the overlying already frozen gabbroic crust as a system of thin veins redistributing incompatible elements during the process (Dick et al. 2000, 2016). As the chemical compo-sition of the felsic veins is often affected by accumulation and hydrothermal alteration, zircon may preserve records of the processes responsible for felsic melt formation and evolution. Here we examine different aspects of felsic melt formation by interpreting trace element and isotope compo-sitions of zircon.

Oxide gabbro: diverse processes of felsic melt formation recorded in Groups 1 to 3 zircon

A characteristic feature of the oceanic crust at Atlantis Bank is the presence of oxide gabbros with Fe-Ti oxide contents that may reach 5–30%. Mineral assemblages of the oxide gabbros are not in equilibrium implying formation in at least two stages (Dick et al. 2000). In the first stage prim-itive gabbro cumulate is intruded by more evolved ferrous melt, which crystallizes and forms a second stage cumu-late (Dick et al. 2002). In particular, Fe-Ti oxides crystal-lize from these evolved, late percolating melts (Dick et al. 2002). These melts could be derived from a fractionating

gabbro pile below, or they could represent separated Fe-rich silicate melts formed by liquid immiscibility (Natland et al. 1991; Dick et al. 2000; Leader 2013). This complex origin of late melts in oxide gabbros is recorded also in zir-cons analysed in this study, as zircon forms three chemi-cally distinct groups. We attribute the differences in zircon chemistry between the groups to different stages of oxide gabbro formation. In particular:

a. Group 1 zircon records high temperature crystalliza-tion in evolving melt derived from a source depleted in incompatible elements. These zircons have the highest Ti contents, which can be roughly related to tempera-tures of crystallization of approximately 800–870 °C (depending on the Ti-activity assumed for calculations; Watson et al. 2006; Ferry and Watson 2007). These zir-cons could have been formed during primitive or oxide gabbro crystallization in intercumulus melt pockets. Interestingly, some trace elements vary strongly in the Group 1 zircons, but some are uniformly low. Variabil-ity of any trace element is the expected consequence of crystallization from a fractionating melt. On the other hand, low concentration and lack of variability suggests crystallization of another accessory mineral before zircon that impoverished the melt in some elements, in this case in P, Ce, U and Th as well as Nb and Ta. Apatite is a common P-bearing mineral in Site 735B (Meurer and Natland 2001) and may also be enriched in Ce, U and Th. Therefore, it could be responsible for depleting evolving melt in these elements. How-ever, Nb and Ta are compatible in Fe-Ti oxides such as ilmenite (Klemme et al. 2006) and low concentrations of these elements in zircon suggests that zircons from Group 1, but also Group 2 crystallized after massive crystallization of Fe-Ti oxides or were formed in silicic melts contemporaneous with immiscible ferrous ones. Alternatively, the melt was formed in a source already depleted in Ti-Fe rich melts. The latter may be envis-aged as hydrous remelting of primitive gabbro from which oxide-rich melts were already removed. Other minerals that can impoverish melt in Ti, Nb and Ta are titanite or rutile, however, rutile was not reported in oceanic crust and titanite would have caused Nb/Ta fractionation, which is not observed in Group 1 zir-con (Ta has approximately three times higher partition coefficient than Nb in titanite, e.g. Green and Parsons, 1987). Regardless of the process, the implication is that group 1 zircon crystallization is closely connected to crystallization or escape of oxide-rich melts and shows that after formation of Ti-Fe rich melts the silicic melt was still present in the gabbroic crust and could evolve to produce plagiogranite (for details see the next sec-tion).

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b. Group 2 zircons record low temperature crystalliza-tion from melts depleted in incompatible elements and with unusual fractionation signals—melts formed by hydrous remelting. Zircons of Group 2 have composi-tions where all the elements, which were impoverished in Group 1 zircons, have even lower concentrations in Group 2. This indicates that apatite and Fe-Ti oxides or titanite crystallized before the formation of the melt from which Group 2 zircons crystallized (the pres-ence of titanite is implied by high Nb/Ta ratios in this group). Most interesting are low Hf and Ti concentra-tions, low negative Eu anomaly (0.4–0.8 compared to 0.1–0.3 in other groups) and high Yb/Gd ratios, and we suggest that these parameters record formation of felsic melts by hydrous partial melting. The debate on the origin of plagiogranite has focused recently on two possible scenarios: hydrous partial melting of oceanic crust versus extreme fractional crystallization. Both processes produce high Si melts, but partial melting produces melts with lower Ti (Koepke et al. 2007) and REE contents (Brophy 2009). Also, microstructural record in gabbros from Site 735 drilled during IODP Leg 176, particularly the formation of plagioclase strongly enriched in anorthite content at grain bounda-ries, indicates that felsic melts were produced during the late stage evolution by hydrous partial melting of just frozen cumulate rocks (Koepke et al. 2004; Wolff et al. 2013). Experimental results, simulating hydrous gabbro melting show that extreme modal changes occur over the first 10% of melting with plagioclase abundance decreasing by over 20% and that of amphi-bole increasing from 0 to 50% (Koepke et  al. 2004). Such interplay between amphibole and plagioclase should be clearly recorded in the chemical composi-tion of resulting melts and specifically in Eu anomalies and HREE/MREE ratios. Low negative Eu anomalies and high Yb/Gd in Group 2 zircons could be a result of zircon crystallization in an early, low volume melt produced in the regime of plagioclase melting and amphibole crystallization. Therefore, Group 2 zircon could represent crystallization in melts formed by low volume, hydrous gabbro melting. As Group 1 zircons closely resemble Group 2 zircons for many elements, it may suggest that formation of their parental melts was also related and Group 1 zircons represent crystalliza-tion in melts produced by higher volumes of hydrous gabbro melting. One and probably the only way to dis-tinguish between different scenarios of Group 1 zircon formation is to sample, identify and date the chemi-cally diverse groups of zircon from oxide gabbros; a work for future study.

c. Group 3 zircon crystallized in highly evolved melt pro-duced by fractionation of mafic melts. This zircon has a different composition compared to Groups 1 and 2, and it also has the lowest δ18O of 3.5‰. In this study, the group is represented by a single grain, but grains of similar trace element composition were also sampled from a felsic vein crosscutting oxide gabbro (Schwartz et al. 2010) and they also occur in plagiogranite from lower Section 2, 3and 4. Extremely high concentration of Hf, P, Y, REE, Th and U as well as Nb and Ta are consistent with crystallization in highly evolved melts formed by fractional crystallization. In particular, REE concentrations should increase in silicic melts formed by fractional crystallization as compared to the melts formed by gabbro melting (Brophy 2009). However, recent experiments of Wolff et  al. (2013) produced small amounts of unusually high P, Zr and Ti melt, immiscible from the silicic melt. Such melt is expected to be rich both in incompatible elements and Nb and Ta, and therefore, crystallization of the Group 3 zircon in such a melt cannot be excluded. These two differ-ent scenarios could be perhaps distinguished by care-ful, precise dating of zircon of known composition as fractional crystallization of the gabbro pile and its remelting could be potentially spaced in time. Schwartz et  al. (2010) obtained old ages for zircons similar in composition to Group 3 zircon (12.46  Ma, therefore older than the assumed age of oceanic crust formation), which may suggest that they represent an early process of gabbro crystallization. Also, similar compositions of zircons from different depths may indicate that the zir-cons formed in early fractionated melts that travelled through the cumulate oceanic crust.

Relationship between zircon in oxide gabbros and in felsic melts from deeper sections

Grimes et  al. (2009) showed that zircons from late stage assemblages in gabbros and plagiogranitic veins from slow-spreading ridges have overlapping compositions for many trace elements and elemental ratios. The typical trend is decrease in Ti concentration in zircon without substantial change in other elements, followed by low variation in Ti accompanied by large variation in Hf and other incompat-ible elements. The first trend was observed mostly in zir-cons from gabbros, whereas the latter was in plagiogran-ites. The change from one trend to the other was interpreted to record change from (1) crystallization in a fractionating melt to (2) crystallization in melt whose composition was buffered by numerous major and accessory phases (Grimes et al. 2009). Similar trends are observed in this study, with Group 1 zircon from oxide gabbro recording crystallization with decreasing temperature and zircons from plagiogranite

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veins recording crystallization at constant temperature, probably from buffered, late stage melts. The buffering of melt composition by different phases during plagiogranite crystallization is also recorded in low variations in elemen-tal ratios, such as Eu anomaly (controlled by plagioclase), Yb/Gd (controlled by amphibole, clinopyroxene or apatite) or Nb/Ta (controlled by titanite or Fe-Ti oxides).

The continuous trends in trace element against trace element diagrams, recorded in zircon in the study of Grimes et  al. (2009), suggest continuous fractionation of melts with less evolved melts trapped in gabbros and more evolved melts forming plagiogranites. Interestingly, in this study zircons from oxide gabbro and plagiogranite do not overlap in composition. Despite that there seems to be a link between the composition of oxide gabbro zir-cons (Group 1) and plagiogranite zircons, as zircons with similar Hf content (9000–10,000 ppm in oxide gabbro and 10,000–11,000  ppm in plagiogranite) have similar ranges of trace elements (Fig. 7). In detail, if an element has a low concentration and low variation in oxide gabbro (e.g. Nb, Ce, Yb, Th, U) it has similar low concentrations and low variability in plagiogranite zircons. Likewise, if the ele-ment is variable and has higher concentration in zircons from oxide gabbro, the same is observed in plagiogranite zircons (Fig. 7). This continuity in trace element composi-tion of zircon is better observed in oxide gabbro and zircon from plagiogranite from Section 2, which has lower REE, U and P concentrations compared to zircon from Sections 3 and 4, and therefore, is more similar to Group 1 zircon from oxide gabbro. This may indicate that melts crystalliz-ing zircon in both oxide gabbro and Section 2 plagiogranite may have been derived from a similar source, for example an evolving gabbro pile. In that context melts from oxide gabbro (Group 1) would have been less evolved and have had a higher temperature of crystallization than the plagi-ogranitic melts.

Processes responsible for O isotope variations

The fractionation of O isotopes between zircon and sili-cate melt is fairly well established and generally δ18O in zircon should not vary with melt fractionation (e.g. Trail et  al. 2009). Most oceanic zircons have uniform δ18O of 5.2 ± 0.5‰ in equilibrium with the mantle-derived melts (Grimes et  al. 2011), suggesting that felsic oceanic melts crystallizing zircon evolve by simple fractional crystalli-zation. In our study, the range of δ18O is larger, from 3.5 to 6.0‰, with plagiogranite zircons having an average mantle-like δ18O value of 5.2 ± 0.5‰ (i.e. identical to the Grimes et al. 2011 average). In contrast, zircons from oxide gabbro have a lower average δ18O of 4.3 ± 0.4‰. Also, in plagiogranites, the distribution of δ18O is not uniform and Section 3 seems to have lower δ18O compared to Section 2

and 4. These low δ18O zircons could not crystallize from a mantle-derived melt and require additional processes of O isotope fractionation occurring within the oceanic crust.

Values of δ18O lower than 5.0‰ in zircon are consist-ent with derivation of melts by partial melting of a hydro-thermally altered source (e.g. Schmitt and Vazquez 2006; Bindeman 2008). In particular, the lower values are the result of hydrothermal alteration of oceanic crust at tem-peratures above 200 °C. However, the zircon from Sec-tion  1 Group 2, which has a clear trace element record of crystallization in melts formed by such melting, also has the highest δ18O of all of the zircons in oxide gabbro (4.5–5.0‰). On the other hand, the lowest δ18O values are in zircons with high trace element concentrations (Group 3 Sections 1, 3), which we attribute to fractionation of res-titic melt in the gabbro pile and not to remelting. Therefore, low δ18O in oceanic zircon cannot be explained purely by hydrous remelting, but also δ18O in the range 4.5–5.0‰ or higher does not contradict that such melting happened. In detail, because of the shallow pressure, the amount of water needed to produce hydrous partial melting could be very low (e.g. less than 3 wt% for water saturation in basalts at 2 kb, Berndt et al. 2002), resulting in very low water/rock ratios (e.g. less than 0.03), making it very hard to detect any seawater influence by isotopic means. Also, in gabbros drilled at ODP Site 735, the δ18O variation with depth is complex and never reaches values below 5‰. The upper 800 m of gabbro have depleted δ18O (c. 5.1‰) values and the lower 700 m have mostly enriched δ18O values (6–7‰; Alt and Bach 2006; Gao et  al. 2006), so the remelting of this crust could not produce low δ18O melts.

Another way to fractionate oxygen isotopes is liquid immiscibility with silica-rich liquids having δ18O higher by up to 1‰ than coexisting Fe-rich liquids (Kyser et al. 1998; Lester et al. 2013). Since we observe lower δ18O than those in equilibrium with mantle melts rather than higher, they could have not been produced by fractionation between immiscible melts.

Finally, large δ18O redistribution may happen due to dif-fusion in response to a thermal gradient (Li and Liu 2015). In detail, in the water-rich environment mass dependent O isotope fractionation occurs with light O isotopes moving towards the high temperature region (Bindeman et al. 2013; Li and Liu 2015). In that context, we can envisage that such gradients existed within the oceanic crust. For example, low δ18O (<5.2‰) is mostly confined to chemically vari-able zircon from oxide gabbro, suggesting that redistribu-tion of O isotopes occurred after melts were emplaced in the oxide gabbro. Taking that into account we suggest that perhaps the oxide gabbro section acted as a hot zone due to longer crystallization and higher contents of evolved melts. Such conditions would trigger redistribution of δ18O in a thermal gradient, similar to that observed in the Bindeman

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et al. (2013) experiments. What may be important here is the sequence in time when separate melts arrived into such a hot zone: (1) early melts represented by Group 3 zircon intruded the oxide gabbro when the temperature was the highest and the redistribution of O isotopes could be the most extensive, (2) melts that crystallized Group 1 zircons were intruded later, when temperature was lower and the redistribution was less pronounced, and (3) low tempera-ture melts crystallizing Group 1 zircons were almost not affected by δ18O redistribution. Generally, the results show that more data on fractionation of O isotopes are needed to understand their variation in some environments. Interest-ingly, the zircon record from oxide gabbro offers the most insight into the late-magmatic to post-magmatic processes in the oceanic crust. This is perhaps because the thick zone of the most evolved oxide gabbro crystallized over a longer time span or was injected by variable melts several times during oceanic crust formation and evolution.

Different origin of plagiogranites at c. 500 m b.s.f. and c. 900 m b.s.f.

The composition of zircons in Section 2 (c. 500 m b.s.f.) and Sections  3 and 4 (850–940  m b.s.f.) is different with the latter including zircons with several times higher con-centrations of many trace elements. Also, zircons from Sections 2, 3 and 4 plot differently in Hf versus other ele-ments diagrams (Fig. 7). Hafnium content in oceanic zircon should increase with increasing melt evolution and Hf is usually well correlated with decreasing Ti content; there-fore, decreasing temperature (Watson et  al. 2006) both in continental (Clairborne et  al. 2006) and oceanic environ-ments (Grimes et al. 2009). Thus, increasing Hf in zircon can be roughly related to increasing Si content in the sur-rounding melt. Section  2 zircons show slightly increas-ing concentrations of incompatible elements only at the very late stage for the highest Hf concentrations. On the other hand, zircons from Sections 3 and 4 have very rapid increases in most trace elements with increasing Hf. The enrichment factor, calculated as the averages of Sections 3 and 4 zircon compositions divided by the average Section 2 zircon composition varies from 2.2 to 2.4 (for Ta, MREE and P) to 3.6–4.8 (for LREE and Th). Interestingly, the two different trends observed in Sections 2, 3 and 4 mimic trends observed for plagiogranite whole rock composi-tions with increasing silica content (Brophy 2009). Rapid increase in the most incompatible elements, especially LREE, is expected in a melt evolving by fractional crystal-lization of basaltic magma (Brophy 2009), and that is what is also observed in Sections  3 and 4. On the other hand, slight changes in the incompatible elements with increas-ing silica was attributed to melts formed by hydrous partial melting of oceanic crust and this pattern is similar to that

observed for trace elements versus Hf for Section 2 zircons (Fig.  7). Another parameter of plagiogranites formed by hydrous gabbro melting is inherently low Ti content caused by prior removal of Ti-rich melts (Koepke et al. 2007). Ti-rich melt would have been also enriched in Nb and Ta, the elements which are lower in Section 2 zircon compared to Sections 3 and 4 zircon. Therefore, we conclude that plagi-ogranite from Section 2 could be a result of hydrous partial melting and plagiogranite from Sections 3 and 4 formed by fractional crystallization of intercumulus melts. The dif-ference in the magma evolution trends between hydrous melting and fractional crystallization is the result of early amphibole crystallization in the restite after hydrous melt-ing (Koepke et  al. 2007; Brophy 2009), whereas amphi-bole appears late during basaltic magma fractionation. Another test that should distinguish amphibole-present from amphibole-absent conditions is the shape of the Nb versus Hf trend. Niobium is more compatible in amphi-bole than in any other major phase, which may constitute part of a cumulate or restite assemblage (GERM database).Therefore, similar to REE, a substantial increase in Nb with increasing Hf is expected if amphibole is absent, and that is observed in zircons from Sections 3 and 4. In contrast, Nb should not increase much when amphibole remains as a restitic mineral and that is observed in Section 2 zir-cons. Therefore, Nb variations confirm that two different processes are responsible for plagiogranite formation, i.e. hydrous melting for Section 2 and fractional crystallization for Sections 3 and 4.

Melt compositions at different depths

Isotope melt composition is recorded in ɛHf of zircon, which can be directly related to the Hf isotope composi-tion of mantle-derived magmas forming the crustal pile. In our study ranges of ɛHf mostly overlap, although a larger spread in values, as well as lower values, occurs in Sec-tions  3 and 4, compared to Sections  1 and 2. This may imply slightly different isotope compositions of the mantle source and more depleted mantle for the upper 0.5 km of the oceanic pile compared to the lower depths. Alterna-tively, low variabilty in Hf isotope values in the upper sec-tion may be linked to the process of remelting that homog-enized previously more variable isotope compositions.

Trace element melt composition in equilibrium with zircon can be calculated based on known partition coef-ficients (Sano et al. 2002) and is another way to illustrate differences between different sections of oceanic crust at Site 735B. Reconstructed REE contents of melts from Sec-tions 1 and 2 are different from both the measured, whole rock, plagiogranite REEs and MOR basalts (Fig.  8a). On the other hand, reconstructed melts from Sections  3 and 4 overlap with the whole rock plagioclase compositions

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(Fig. 8b). The latter have typical REE patterns of fraction-ated melts, which is consistent with zircon crystallizing in felsic melts evolving by extreme fractional crystallization. In contrast, low REE contents, the concave down pattern and positive Eu anomaly observed in Section  1 recon-structed melts are consistent with partial melting of REE impoverished source such as gabbro cumulate. The recon-structed melts from Section 2 have higher LREE contents, but not Ce and HREE, indicating perhaps more fractionated melts derived from a similar source to Section 1 melts or more intense melting of LREE-bearing phases e.g. apatite, which initially remained in the restite. Low reconstructed Ce concentration in the melt for both Sections 1 and 2 also indicates different redox conditions in the lower and upper parts of the oceanic crust. Reduced conditions (low concen-tration of Ce+4) for felsic melts formed above 0.5 km (Sec-tions 1 and 2) can be explained by low rock to water ratios during the gabbro remelting, the conditions suggested also by O isotopes in zircon. Altogether, the composition of reconstructed melts is consistent with different processes governing the formation of the majority of plagiogranitic melts in upper and lower ocean crust sections in ODP Site 735B.

Model of felsic melt formation in slow-spreading oceanic crust

Our proposed model suggests that felsic melts in oceanic crust were formed in two processes by fractional crystal-lization of mafic melts and by hydrous remelting of the cumulate gabbro pile (Fig.  9). The melts formed by frac-tional crystallization dominate in the lower section (below 0.5  km) but are present also in the upper section (above 0.5 km). We assume that after formation such melt could travel upwards, intrude the overlying gabbro pile and crystallize zircon at different stages of melt fractionation (Fig. 9). Depending on the local thermal conditions in the oceanic pile the melts could have been affected by redis-tribution of O isotopes in a thermal gradient. Therefore, the δ18O below 5.2 ± 0.2‰ in these melts are due to ther-mal redistribution and not due to remelting of hydrother-mally altered oceanic crust. As such, the source of water for the melting is unknown and could be seawater and/or fluids derived from the oceanic crust crystallization. How-ever, since the records of hydrous partial melting are lim-ited to the upper 500 m of the Site 735B section, it favours seawater as the possible trigger of hydrous partial melting (Fig. 9).

The ages of the two stages could be tentatively related to the 206Pb/238U zircon ages of Schwartz et  al. (2010). Zircons with high incompatible element contents are old (12.76 ± 0.2 Ma) and are similar in composition to the zir-cons from Sections  3 and 4 and scarce zircons from the

upper sections. Therefore, the age of the extreme fractiona-tion of the melts represented by the zircons can be placed at 12.76 ± 0.2  Ma. The hydrothermally altered zircons dated by Schwartz et al. (2010) are 12.0 ± 0.16 Ma and can be related to hydrothermal alteration and fluid movement through the crustal pile. We conclude that the same process could be also responsible for wet partial melting at lower depths, and therefore, at higher temperatures, which prob-ably characterized Sections 1 and 2 (Fig. 9).

Conclusions

The analysed zircons from four depth sections in IODP Site 735B have variable trace element and δ18O compositions and rather uniform ɛHf, suggesting that (1) magmas form-ing the oceanic crust section were derived from an isotopi-cally homogenous source, but (2) diverse processes were

Fig. 8 Reconstructed melt REE patterns using partition coefficients between plagioclase and melt of Sano et  al. (2002). Plagiogranite rock compositions from IODP Site 735 B are from Robinson et  al. (2002) and the basalt composition is from the GERM database

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responsible for the formation of felsic melts, which resulted in variability in trace elements and δ18O in zircons.

The processes can be grouped in two stages: (1) the pre-sumably older one is consistent with formation of fraction-ated melts; these processes are represented by felsic veins and zircons from deeper Sections 3 and 4, and scarce zircon grains in Sections 1 and 2—this stage could be contempo-raneous with formation of Fe-rich melts; (2) the younger one is consistent with several episodes of hydrous remelt-ing of cumulate gabbro; these processes are represented by felsic veins and zircons from upper Sections 1 and 2—this

stage postdates formation of Fe-rich melts and melting affected a source, which was already impoverished in ele-ments compatible in Fe-Ti oxides.

Our study shows that chemical diversity of oceanic zir-con can be linked to different processes of felsic melt for-mation and distribution through the oceanic crust. The study of zircon offers insight into how different incompat-ible elements were mobilized, and since chemically distinct zircons can be targeted for dating, what the time-frame was for elemental redistribution. Also, zircon provides information on the processes that occurred close to the

Fig. 9 Formation of plagiogranite melts in two stages shown in the schematic section through the oceanic crust at the IODP Site 735 B (the section modified after Natland and Dick 2002a). Stage 1 includes formation and distribution of felsic melts by fractional crystalliza-tion, the melt’s distribution is shown in black and possible depths of zircon crystallization are marked with zircon shaped symbols. Stage 2 includes formation of felsic melts by hydrous partial melt-

ing, the melts dominate in the upper part of the oceanic section and are related to the crustal uplift via detachment faults (dashed lines). The chemical composition of zircon formed in each stage is shown below the schematic sections. Symbols in black show zircon crystal-lized during each stage. Stage 1 is represented mostly by zircon from Sections 3 and 4, but also by that from Group 3 Section 1 (S1G3) and 12.76 Ma zircons from Schwartz et al. (2010)—Schw.’10

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subsolidus and the magmatic/hydrothermal boundary and can clearly separate the elemental changes related to those two environments.

Acknowledgements Rafał Tyszka and Elżbieta Słodczyk help with data collection is greatly appreciated. The project was funded by a grant no. 1017/S/ING/15-I. Three reviewers are thanked for insightful comments.

Open Access This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.

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