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AGweCY UK, ONLY (aLevo dn)2 REPORT DATE 3. REPORT TYPE AND DATES COVERED4. Final (10 Sept 81 - 9 Sept 84(.. TIL5N UTI . FUNDING NUMBERS

EVALUATION OF CHEMICAL AND ATMOSPHERIC SCIENCES RESEARCH4. 61102F

L AUTHO"2303/Al

~ Joseph E. Earley

7. PW01IG ORGANIZATION NAMES AND ADORESS(IS) L. PIRFORtMING ORGANIZATION

Georgetown UniversityREOTNMRDepartment of ChemistrytWashingotn D.C. 20057 ~ ~*

3. SFONSOW4 G/MO40ft(ORJNG AGENCY NAME(S) AND ADORESSES) Ia. SPONSORING/IMONIT ORINGAGENCY ZIPO NUER

AFOSRBLDG 410BAFB DC 20332-6448 F49620-81-C-0085

11. SUPnAMENTARY NOTES

12%. DISTRUUTION/AVALAUIUY STATEMENT 1 2b. DISTRUTION CODE

13. ABSTRACT (Mtwnmm 200 w w 1

DTICDECO 5 1989

D~

14. SUBJECT TERM 15. NUMBER OF PAGES

11IL. PRCE CODA

IT- SECURITY CLASSIFICATION IL. SECURITY CLASSIFCTIN15.1 SECURITY O.ASSWICATION 20. LIMITATION OF ABSTRACTOF 411PO11 OF TIlS PAGE OF ABSTRACT

unclassified uincasfe r______I___ I_ft; ;; 4 "1-260-50O standara Form 2%8 (89014 oratt)

89 12 0417

FINAL REPORT

EVALUATION OF CHEMICAL AND ATMOSPHERI-- SCIENCES RESEARCH

DR. JOSEPH E. EAkRLEY

F49620-81-C-0085

Ace~nForNTIS FA Im) IC TA,3

GEORGETOWN UNIVERSITY .,

DEPARTMENT OF CHEMISTRY

By.

WASHINGTON, D.C. 20057 Dtr

Dist

A-I _

10 September 1981 -9 September 1984

Georgetown University

Department of Chemistry

Final Technical Report

Contract F49628-81-C-0085

U.S. Air Force Office of Scientific Research

For the per'od September 1, 1981 to September 9, 1984

During the period covered by this report, six plenary meet-

ings of the Chemistry Research-evaluation Panel for AFOSR have

been held. Ti rixty-third chemistry research evaluation meeting

for AFOSR was held at the U.S. Air Force Academy, Colorado on

November 12 and 13, 1981; thirty-nine proposals were considered

at that meeting, and relative rankings for scientific quality

were determined. An interim technical report specifying that

rank-order has been submitted and is appended as Appendix I. The

sixty-fourth chemistry research-evaluation meeting for AFOSR was

held at Alexandria, Virginia, on May 13 and 14, 1982; fifty

proposals were considered at that meeting, and relative rank -- 7-

for scientific qual t'., -: e 3htermined. An interim tec-

report specifying "t rank-order has ,ee2 submitted a-

aLppended as Appendix 1i The sixty-fiftn chemistry ese----.

evaluation meeting for AFOSR was held at New Orleans, Loui. ,

on November 11 and 12. 1082; thirty-five proposals were con--

sidered at that meeting, and relative rankings for scientific

1

\~ I

quality were determined. An interim technical report specifying

that rank-order has been submitted and is appended as Appendix

III. The sixty-sixth chemistry research-evaluation meeting for

AFOSR was held at Washington D.C. on May 12 and 13, 1983; forty-

seven proposals were considered at that meeting, andarelative

rankings for scientific quality were determined. An interim

technical report specifying that rank-order has been submitted

and is appended as Appendix IV. The sixty-seventh chemistry

research-evaluation meeting was held at San Antonio, Texas on

November 10 and 11, 1983; thirty-four proposals were considered

at that meeting, and relative rankings for scientific quality

were determined. An interim technical report specifying that

rank-order has been submitted and is appended as Appendix V. The

sixty-eighth chemistry research-evaluation meeting was held at

Georgetown University on May 10 and 11, 1984; forty-eight pro-

posals were considered at that meeting, and relative rankings for

scientific quality were determined. An interim technical report

has been submitted and is appended as Appendix VI. During the

period of this report, a total of two hundred and fifty-three

chemical proposals were reviewed and ranked.

Panels of evaluators were provided for five contractors'

meetings that dealt wi2:. specific portions of the ongr',ng .FnSR

research prograr These :-.eti-gs were held as follows: Buffa>',

New York, May ,-7° 199!; 2-.buque.r-ue. New Mexico, November 9-11,

1981; Buffalo, New Yc,:k. May 6-7, 1982; Air Force Academy, Cz..

December 1-3, 1982; Hanscom AFB, Mass., October 26-28, 1983.

Interim technical reports covering each of these meetings have

2

been submitted.

Procedures for evaluating atmospheric-sciences research

proposals have been developed and refined. Interim Technical

Reports dealing with that activity have been submitted. Overall

grades are included in appendices I, II, II, IV, V, VI. In

total, two hundred and fifty-three chemical and thirty-six

atmospheric proposals were evaluated of which three earned the

ov#rall rating of A+, one of A/A+, thirty-five of A, five of

A/A-, sixty of A-, thirty-three of A-/B+, one of A-/B, three of

A/B, seventy-three of B+, eleven of B/B+, forty-seven of B, two

of B-, one of B-/C, two of C+, twelve of C or R.

Panel members who served during the period of this report

are:

Prof. Harry R. Allcock Prof. William B. HansonDepartment of Chemistry DirectorPennsylvania State University Center for Space SciencesUniversity Park, Pa. 16802 University of Texas, Dallas

Richardson, Texas 75080

Prof. Jesse L. Beauchamp Prof. H. James HarwoodDivision of Chemistry and Institute of Polymer Science

Chemical Engineering University of AkronCalifornia Inst. of Technology Akron, Ohio 44325Pasadena, California 91125

Prof. Claude F. Bernasconi Prof. James HoltonDepartment of Chemistry Dep+-. of Atmospheric SciencesUniversity of Californa; University of WashingtonSanta Cruz, California 95064 Seattle, Washington 9P!9'

Prof. Joyce Y. Corey J. J. LagowskiDepartment of Chemistry Piper Professor of ChemistryUniversity of Utah University of Tex'sSalt Lake City, Utah 84112 Austin, Texas 78712

Dr. Carol Creutz Prof. Robert J. MadixDepartment of Chemistry Dept. of Chemical EngineerincBrookhaven National Laboratory Stanford UniversityUpton, New York 11973 Stanford, California 93405

3

Dr. Jimmie D. Doll Prof. Dale W. MargerumDepartment of Chemistry Department of ChemistryLos Alamos National Laboratory Purdue UniversityLos Alamos, New Mexico 87545 West Lafayette, Indiana 47907

Prof. Thomas M. Donahue Dr. John P. McTague*Dept. of Atmospheric and Head, National Synchroton

oceanic Sciences Light-SourceUniversity of Michigan Brookhaven National LaboratoryAnn Arbor, Michigan 48105 Upton, New York 11973

Dr. James Economy Prof. Charles U. Pittman, Jr.Manager, Organic and Polymer Department of Chemistry

Research University of AlabamaIBM Corporation University, Alabama 35486San Jose, California 95114

Prof. Mostafa F.A. El-Sayed Prof. William C. StwalleyDepartment of Chemistry Department of ChemistryUniversity of California at University of Iowa

Los Angeles Iowa City, Iowa 52242Los Angeles, California 90024

Prof. Dennis H. Evans Dr. John C. TullyDepartment of Chemistry Bell LaboratoriesUniversity of Wisconsin 600 Mountain AvenueMadison, Wisconsin 53706 Murray Hill, New Jersey 07974

Prof. William R. Gentry Prof. Richard P. Van DuyneDepartment of Chemistry Department of ChemistryUniversity of Minnesota Northwestern UniversityMinneapolis, Minnesota 55455 Evanston, Illinois 60201

Dr. George S. Hammond Dr. Field H. WinslowDirector Bell LaboratoriesIntegrated Chemical Systems 600 Mountain AvenueLaboratory Murray Hill, New Jersey 07974

Allied Corporation, Box 1021RMorristown, New Jersey 07960

*Currentiy Deputy Director, Office of Science and TechnologyPlanning, Executive Office of the President of the United States1600 Pennsy ,ania Avenue, N.W., Washington, D.C.

m A itted by,

Prfsot and Chairma

Principal InvestigatorContract F496281-C-0085

November 1, 1984

4

Appendix I

Georgetown Iffitersity

1tTRN' TLCte41CAI. REPORTF49)6111-iC-O8s

final Ranking

63rd Chemistry. Research fva1ulhtian mecti'n3Air itorce Ctfico of ScicntifiC Research

It Oka

0, West 79 Yates A79 lates64 St3Il@7y

AlA- AIA.46 Seyfcrth S4 surnctt

66 Vitner andl A.5 Davis and A

V Oitmaire Alex~ander 03 Rinatidi

~70 Abra..-niO 68 Nupitcrean S9 Ctw(al

* 1 U~ett 63 Se hvcricl and 6 Scwr:Cd andI I Lao~ rntefln Fpstten

\Si r.~ve74 Davis.matijmo.3"dVen3 11AS

A- /I. -l.77 Sams 76 Golden and

Roqsi61 Berry

46 Rosenth-1l 71 Porter IS SungCa)7) Dhristo S7 m4ulvanei

64 Schultz

$6 Crouch St 0/9 yan

60 Car'per S1Kle aotnd

65 Davis and Ci 63 Stevenson.

Liii K Lett, ind

S0 COuC!1n;4 3"d

41 WaB1 Co(ch 75 xefr'tke an~d

PalSS PCCIand

JS Liu 7 Je E. ~lyjM-r1.lognasek slid C

NHeR ated:J.S Am rarce Acad 7my, cotorado

60 Go.e~uaewib sa ickems(b) . ,--

5.)?nutw es PA U-n m~~l Rhewrite Recommended M) Optua Ba*nkin

5

Appendix II

Georqetown University

INTERIM TECHNICAL REPORTF49628-81-C-0005

Final Ranking

.64th Chemisb'y Research Evaluation MeetingAir Force Office of Scientific Research

I and HI 11

A A26 Kramer 22 Leone

41 Wittig17 Crim,

A/A-33 Fristad

44 Lemal.O Bruckenstein

A- A-

10 Conradt 18 Houston<20 Trogler 34 Dyke

12 Finklea 05 Cavanagh

23 Dewar 19 Benziger

46 Baldeschwieler * 36 Engel15 Yarkony14 Raft40 Steinfeld

A-/Ib+ A-/1+

08 Houk Il Greene

13 Newman and Scheinbeim 439 Rabitz

21 Goodenough and Dickens 45 Redmon43 Dows02 Kouri

B+ B+

45 Dlott 48 Becker

49 Weber 03 Herbst

2 hite 37 Depristo

[38 Mark 07 Rosenfeld

I29 Taft30 Anderman

2 Stegeman et al.31 Cukier11 Raleigh16 Dresselhaus

I09 Allen24 Mele

28hainson

28 Magill35 Cooribe47 Elcern r

CAsterisk indicates tentative 04 Haydockranking. pendinq additlonal review. 06 McCluskey

Brackets indicate equal rankin, . -

6 eph .:31 ftiel Investigator,y 14. 1962Almrwi, Virg ini

6

Appendix III

Georgetown University

INTERIM TECHNICAL REPORTF49628-81-C-0085

Final Ranking

65th Chemistry Research-Evaluation MeetingAir Force Office of Scientific Research

I and 111 11

A+ 72 Collman-Anson

AI<'A 67 Levy86 White

A 93 Katz A 64 Dyke98 Golde

A- 70 Bedford-Thompson A- 60 Mayer66 Setser99 McGowan

A-/B+ 71 Dolbier A-/B+ 69 Barker7S Hall 100 Pritchard97 Krigbaum-Preston #S8 Tellinghausen

@65 Halpern84 Schwarz*

B. 63 Molloy B+ 56 Alfano76 Mulvenay 85 Davidovits79 Jones 91 Heaven96 Nicholson 57 Hichen95 Ring-O'Neal* 78 Lester

B/B 77 Miller

61 Harris B 74 Fry62 Lardner 90 Benard88 Otter

C S Yang

Asterisk * indicates tentative ranking, pendig" furtrer evaua.ticn, not ranked relative to others in the same group.

Ampersand I indicates equal eval -(tie rankings).

7 Jo ph Earle

/P Pr indPpaI InvestigatorNovember 12, 19S2

New Orleans, Louisiana

7

GEORGETOWN UNIVERSITY

DEPARTMENT OF CHEMISTRY

INTIRIM TECHNICAL REPORT FOR AFOSR RESEARCH-EVALUATION

CATEGORY I CATEGORY II

A 38 Boudjouk 11 Stair20 Mat samune 45 Burnett

36 Mosely19) Turro 15) Dagdigian02) Angell 22) Eisenthal

14) Rabitz50 Murray

A- 13 inig 41 Heidner5 Hughes 42 Weitz42 Weitz 37 Wing32 Donald 34 Hanson #27 Grubb 16 Ratner

16 Hansen

A-/B. 25 Michl12 Stills

B' 39 Moriarity 44 Weiss31 Collins 43 Adams18 Shiner 17 Campion3 Hieftje 29 MichelsI Geil 48 Benesch

49 Niedenzu

B/B+ 1 Marchand 26 El Batouay9 Tuazon

B 24 Maddou 33 Thompson23 Winefordner 21) Lauer

30) Me-'nzer

0' SalK

7 Lin

C 28 Ag-wal 8 Su

) equal ranking* preliminary study only af-roved# additional review suggeited

Teser of' ChmistryPrincipal !nveatiatorray 13, 1963

8

Appendix V

Georgetown University

Department of Chemistry

Revised Interim Technical Report for AFOSR Research-Evaluation

CATEGORY I CATEGORY II

A 75 Allcock 74) Fenn80) Leone87 Siebener

A- 89) Osteryoung 70 Julienne63) Pope 86 Ross*

79 Skofronick, Safroni

A-/B. 65) Green 69 Bauer71) Royce 68) Guberman

78) Jordon67 Rich

A/B 81 Klein**

B+ 64 Bray 66 Sentman60 Suter76 Sievers73 Yoke82 Jung

B 59 Goldberg 84 Ogryzlo85 Bradl.y 59 Goldberg88 McGown 85 Bradley58 Farona

61) Krause83) Lyle77 Carper

C 62 Brown t 72 Simpson

) eaial rankingos E. Earle * n, consensus

Professor of Che ' additional review requir,:,

Principal Investi r *' assuming P-I can answer serio

January 31, 1964 questions raised by a revieI Category III

.(Replaces preliminary report dated November 11. 1983)

, , I I l mi i m .. .

Appendix V1

GEORGETOWN UNIVERSITY

L £'ARTMENT OF CHEMISTRY

INTERIM TECHNICAL REPORT FOR APOSR CHEMISTRY RESEARCH- EVALUATION

CATE3GORY I CATEGORY TI

A+36 Jonas 43 Field

A 06 Hubbard 25 Williams29 Bernstein 24 Smalley

19 Winograd *14 Rice *

A- 37 Lit', 50 Thomas22) Heineman 49 And.-rson *16) Burton 30 Weisshaar

31 Eyler32 [Kolb '

1+/A- 26 LevineiS Barker46 Saxon

B+ 03 Eisch 04 Wainer12 Prese 51 Reeves13 Kiabunde 40 Wodarczyk34 Smith 10 Tatarchuk20 Johnston 44 Rosenfeld39 White *23 McMillan36 Chung35 Smit h

B 09 Messing 07 Kouri27 Paciorek 42 Pritt17 Smith 33 Lipps *

28 Shirts11 Cunningham

C 05 Pienta 41 Baldeschvieler--------------------

CATEGORY III

A-/B 02 NestD+/B 45 Auer*3-/C 01 Kaplan

C 48 Hansman

Profcpa IYigst ft saiionl vi-e required

May 11,g 1984

10