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WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
What is the GHS?
> A common and coherent approach to defining and classifying hazards, and communicating information on labels and safety data sheets.
> Target audiences include workers, consumers, transport workers and emergency responders.
> Provides the underlying infrastructure for establishment of national, comprehensive chemical safety programs.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Why is the GHS needed?
> No country has the ability to identify and specifically regulate every hazardous chemical product.
> For example, in the United States, there are an estimated 650,000 such products.
> Adoption of requirements for information to accompany the product helps address protection needs.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Why? (cont.)
> Many different countries have come to the same conclusion about using information dissemination as a regulatory means to address chemical hazards.
> While similar, they are different enough to require multiple labels and safety data sheets for the same product in international trade.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Why? (cont.)
> Countries with systems have different requirements for hazard definitions, as well as information to be included on a label or material safety data sheet.
> For example, a product may be considered flammable or toxic in one country, but not in another to which it is being shipped.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Benefits of Harmonization
> Countries, international organizations, chemical producers and users of chemicals all benefit.• Enhance protection of humans and
environment.
• Facilitate international trade in chemicals.
• Reduce need for testing and evaluation.
• Assist countries and international organizations to ensure the sound management of chemicals.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Major Existing Systems
> UN Transport Recommendations> European Union (EU) Directives on
Substances and Preparations> Canadian Requirements for Workplace,
Consumers and Pesticides> US Requirements for Workplace,
Consumers and Pesticides
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Principles Of Harmonization
> Protections will not be reduced. Comprehensibility will be key.
> All types of chemicals will be covered. Categorization will be based on intrinsic properties (hazards) of chemicals.
> All systems will have to be changed.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
The Scope of the GHS
> Covers all hazardous chemical substances, dilute solutions and mixtures.
> Pharmaceuticals, food additives, cosmetics and pesticide residues in food will not be covered at the point of intentional intake, but will be covered where workers may be exposed, and in transport.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
The GHS Elements
Classification Criteria• Health and Environmental Hazards
• Physical Hazards
• Mixtures
Hazard Communication• Labels
• Safety Data Sheets (SDSs)
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Health and Environmental Hazards
• Acute Toxicity• Skin Corrosion/Irritation• Serious Eye Damage/Eye Irritation• Respiratory or Skin Sensitization• Germ Cell Mutagenicity• Carcinogenicity• Reproductive Toxicity• Target Organ Systemic Toxicity - Single
and Repeated Dose• Hazardous to the Aquatic Environment
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Physical Hazards
• Explosives• Flammability - gases, aerosols, liquids, solids• Oxidizers - liquids, solids, gases• Self-Reactive • Pyrophoric - liquids, solids• Self-Heating• Organic Peroxides• Corrosive to Metals• Gases Under Pressure• Water-Activated Flammable Gases
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Comprehensibility
Guiding principles: Information should be conveyed in more
than one way. The comprehensibility of the components of
the system should take account of existing studies and evidence gained from testing.
The phrases used to indicate the degree (severity) of hazard should be consistent across different hazard types.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Labels
The UN Working Group identified about 35 different types of information that are currently required on labels by different systems.
To harmonize, key information elements needed to be identified.
Additional harmonization may occur on other elements in time, in particular for precautionary statements.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Key Label Elements
• Product identifier
• Supplier identifier
• Chemical identity
• Hazard pictograms*
• Signal words*
• Hazard statements*
• Precautionary information
*Standardized
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Pictogram Shape and Color
For transport, pictograms will have the background and symbol colors currently used.
For other sectors, pictograms will have a black symbol on a white background with a red diamond frame. A black frame may be used for shipments within one country.
Where a transport pictogram appears, the GHS pictogram for the same hazard should not appear.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Signal Words
“Danger” or “Warning”
Used to emphasize hazard and discriminate
between levels of hazard.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Hazard Statements
Describe nature of hazard and degree of hazard.• Harmful if swallowed.
• May cause liver and kidney damage.
• Highly flammable liquid and vapor.
• May cause fire or explosion; strong oxidizer.
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AND THE ENVIRONMENT
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Precautionary Information
Recommended measures to minimize or prevent adverse effects resulting from exposure to a hazardous chemical or its improper storage/handling. • Do not eat/drink/smoke when using this product.• Keep away from heat.• Do not breathe dust or mists.• Wash hands and face thoroughly after handling.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Role of the SDS in the GHS
The SDS should provide comprehensive information about a chemical substance or mixture.
Primary Use: The Workplace Employers and workers use the SDS as a
source of information about hazards and to obtain advice on safety precautions.
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
ANSI MSDS LAYOUT SECTIONS I & II
> SECTION I• Chemical Product
and Company Identification
» Emergency Phone Number
» Chemical Formula
» Product Code/ Identifier
» Recommended Use
> SECTION II• Hazard Identification
» Chemical Hazards
» GHS Pictograms and Label Requirements
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
ANSI MSDS LAYOUT SECTION III
> SECTION III• Composition/Information on Ingredients
» Ingredient
» CAS Number
» Percent
» Laboratory Protective Equipment
» Storage Color Code
» Trade Secret Information
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
ANSI MSDS LAYOUT SECTIONS IV & V
> SECTION IV• Potential Health
Effects» Inhalation
» Ingestion
» Skin Contact
» Eye Contact
• First Aid Measures» Inhalation
» Ingestion
» Skin Contact
» Eye Contact
> SECTION V• Fire-Fighting Measures
» Fire
» Explosion
» Fire Extinguishing Media
» Special Information
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AND THE ENVIRONMENT
CONVERGE
ANSI MSDS LAYOUT SECTIONS VI, VII & VIII
> SECTION VI• Accidental Release Measures
> SECTION VII• Handling and Storage
> SECTION VIII• Exposure Controls/Personal
Protection» Airborne Exposure Limits
» Ventilation Systems
» Personal Respirators
» Skin Protection
» Eye Protection
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AND THE ENVIRONMENT
CONVERGE
ANSI MSDS LAYOUT SECTIONS IX & X
> SECTION IX• Properties
» Appearance
» Odor
» Solubility
» Specific Gravity
» pH
» % Volatiles by volume
» Boiling Point
» Melting Point
» Vapor Density (Air=1)
» Evaporation Rate (BuAc=1)
» Vapor Pressure
> SECTION X• Stability and Reactivity
» Stability
» Hazardous Decomposition Products
» Hazardous Polymerization
» Incompatibilities
» Conditions to Avoid
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
ANSI MSDS LAYOUT SECTIONS XI, XII, XIII & XIV
> SECTION XIII • Disposal Considerations
> SECTION XIV • Transportation
Information» Domestic (Land, DOT)
» International (Water, IMO) – Proper Shipping Name– Hazard Class– UN/NA– Information reported for
product/size
> SECTION XI• Toxicological
Information
> SECTION XII • Ecological
Information» Environmental
Fate
» Environmental Toxicity
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AND THE ENVIRONMENT
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ANSI MSDS LAYOUT SECTIONS XV & XVI
> SECTION XV • Regulatory Information
» Chemical Inventory Status
» Federal, State and International Regulations
> SECTION XVI • Other Information
» NFPA Ratings
» Label Hazard Warning
» Label Precautions
» Label First Aid
» Product Use
» Revision Information
» Disclaimer
» Preparer
WHERE BUSINESS
AND THE ENVIRONMENT
CONVERGE
Implementation Schedule
> December 1, 2013 - employee training deadline
> June 1, 2015 - chemical manufacturer compliance deadline
> June 1, 2016 - deadline to update labeling and HazCom program including updated SDSs