Sébastien Balibar

Laboratoire de Physique Statistique de l ’ENS (Paris)

see: « The discovery of superfluidity » J. Low Temp. Phys. 146, 441 (2007)and « The enigma of supersolidity » Nature 464, 176 (2010).

When matter waves become visibleWhen matter waves become visible

from superfluidity to supersolidityfrom superfluidity to supersolidity

The City University of New York, 8 June 2011The City University of New York, 8 June 2011

Outline

- Some liquids flow more easily than others

- They are called « superfluids »- They are called « superfluids »

- - Video sequences show their astonishing propertiesVideo sequences show their astonishing properties

- - quantum mechanics at the macroscopic scale of the visible worldquantum mechanics at the macroscopic scale of the visible world

- superfluidity, superconductivity, and now supersolidity are - superfluidity, superconductivity, and now supersolidity are superstates of matter related to each othersuperstates of matter related to each other

- - 15 Nobel prizes. Perhaps some more to come.15 Nobel prizes. Perhaps some more to come.

- the discovery of superfluidity - history – Great scientists - the discovery of superfluidity - history – Great scientists compete at the beginning of World War IIcompete at the beginning of World War II

the flow of an ordinary liquid

the flow velocity V is proportional to - the height difference h, that is the pressure applied to the liquid- the cross section of the tube- the inverse of the viscosity

flowflowvelocity velocity

VV

heightheightdifferencedifferencehh

Jean-Louis Marie Poiseuille French engineer born in 1797,became a medical doctor, studied the flow of blood

tubetube

reservoirreservoir

Décember 1937: 2 simultaneous discoveries

Jack Allen et Don Misener (Cambridge, UK) : along thin capillaries and below 2.2K, the flow is independent of the applied pressure, even of the diameter of the capillary (from 10 m to 1 mm)

Jack Allen et Don Misener (Cambridge, UK) : along thin capillaries and below 2.2K, the flow is independent of the applied pressure, even of the diameter of the capillary (from 10 m to 1 mm)

Piotr Kapitza (Moscow): below 2.2 K

very fast flow through a slit only

0.5 micrometers thick, between 2 polished disks

he calls liquid helium « superfluid » below 2.2 K

Piotr Kapitza (Moscow): below 2.2 K

very fast flow through a slit only

0.5 micrometers thick, between 2 polished disks

he calls liquid helium « superfluid » below 2.2 K

below 2,2 Kelvin (2.2K = -271 °C), that is near the absolute zero (0 Kelvin = -273,15 °C) where the thermal agitation stops in matter, 2 different research groups study the flow of liquid helium

below 2,2 Kelvin (2.2K = -271 °C), that is near the absolute zero (0 Kelvin = -273,15 °C) where the thermal agitation stops in matter, 2 different research groups study the flow of liquid helium

prehistory of the discovery of superfluidity 1927 – 1937

1930: W.H. Keesom and J.N. van der Ende (Leiden): liquid He II flows very easily through narrow slits (superleaks)

1932: McLennan et al. (Toronto): liquid He stops boiling below 2.2K

Several steps :1927-32: W.H. Keesom, M. Wolfke and K.

Clusius (Leiden): liquid He has two different states which they

call « helium I » above 2.2K and « helium II » below 2.2K. A singularity in the specific heat at 2.2 K (the « lambda point »)

B.V. Rollin (Oxford, 1935), W.H. Keesom and A. Keesom (Leiden, 1936)

J.F. Allen R. Peierls and M.Z. Uddin (Cambridge, 1937) :

helium II is a very good thermal conductor

the film by J.F. Allen and J. Armitage(St Andrews, Scotland, 1972 - 82)

a very fluid liquid

Wilhelm, Misener, et Clark (Toronto 1935): helium II is much less viscous than helium I (using a “torsional oscillator”).

Near the end of 1937 in Moscow as in Cambridge: could the large thermal conductivity be due to some kind of convection because the viscosity is small ?It was known that helium II flows easily through pores

Rollin (Oxford 1936): in a beaker, liquid helium II goes up along the sides, around the top rim and escapes spontaneously !

two articles side by sideNature n°141 (January 1938), page 74 (received December 3, 1937) :P. Kapitza, « viscosity of liquid helium below the lambda point »and page 75 (received December 22. 1937) :JF Allen et A.D. Misener: « Flow of liquid helium II »

But who found first ? Piotr Kapitza ? Allen et Misener cite their competitor Kapitza: « A survey of the various properties of liquid helium II has prompted us to investigate

its viscosity more carefully. One of us had previously deduced au upper limit of 10-5 cgs units for the viscosity of helium II by measuring the damping of an oscillating cyclinder. We had reached the same conclusion as Kapitza in the letter above ; namely that, due to the high Reynolds number invovled, the measurements probably represent non-laminar flow ».

19 days later: did they simply reproduce the work of Kapitza ?Kapitza received the Nobel prize in 1978 (not Allen nor Misener)Kapitza invented the word « superfluid » to qualify heliumII, this strange liquid:« by analogy with superconductors, the helium below the lambda-point enters a special

state which might be called superfluid »

the flow of a superfluidthe flow of a superfluid

Piotr Kapitza, an Piotr Kapitza, an outstanding physicistoutstanding physicist

born in 18941918: doctorate in electrical engineering St Petersburg1921: joins Rutherford in Cambridge (UK), father of

nuclear physics Nobel prize 1908. 1929: Fellow of the Royal Society1934: builds a helium liquefier which produces its first drops of liquid on April 19th. But

retained in USSR by Stalin on Sept. 24th during Mendeleiev’s 100th anniversary1934-37: obtains from Stalin that an Institute is built for his research, from Rutherford

that buys his equipment (except the liquefier…) . He builds a new liquefier which starts producing liquid helium on February 22nd, 1937.

December 5th, 1937: letter to Nature: “I am sending herewith a short note…, which I hope you will kindly publish... I think this is an important note and I should be glad if you could arrange it to be published as soon as possible, and with the day of dispatch. Please …send the proofs either to Prof. P.A.M. Dirac, Dr. J.D. Cockcroft, or to Dr. W.L. Webster ... I hope you will kindly help me in publishing this note very soon ...  »

1946: refuses to work on the Soviet atomic momb under the authority of Béria 1953 : Stalin dies and Beria is executed1978: Nobel prize in Physics (40 years after the discovery)

born in 18941918: doctorate in electrical engineering St Petersburg1921: joins Rutherford in Cambridge (UK), father of

nuclear physics Nobel prize 1908. 1929: Fellow of the Royal Society1934: builds a helium liquefier which produces its first drops of liquid on April 19th. But

retained in USSR by Stalin on Sept. 24th during Mendeleiev’s 100th anniversary1934-37: obtains from Stalin that an Institute is built for his research, from Rutherford

that buys his equipment (except the liquefier…) . He builds a new liquefier which starts producing liquid helium on February 22nd, 1937.

December 5th, 1937: letter to Nature: “I am sending herewith a short note…, which I hope you will kindly publish... I think this is an important note and I should be glad if you could arrange it to be published as soon as possible, and with the day of dispatch. Please …send the proofs either to Prof. P.A.M. Dirac, Dr. J.D. Cockcroft, or to Dr. W.L. Webster ... I hope you will kindly help me in publishing this note very soon ...  »

1946: refuses to work on the Soviet atomic momb under the authority of Béria 1953 : Stalin dies and Beria is executed1978: Nobel prize in Physics (40 years after the discovery)

Two Canadian immigrants in Cambridge

Jack Allen, born in 1908 in Winnipeg, doctorate in 1933 in Toronto,

- 1935: hired by Rutherford in Cambridge to replace Kapitza,

- worked there thanks to the liquefier built by Kapitza

- had attracted a young Canadian student, Don Misener in 1937

Jack Allen, born in 1908 in Winnipeg, doctorate in 1933 in Toronto,

- 1935: hired by Rutherford in Cambridge to replace Kapitza,

- worked there thanks to the liquefier built by Kapitza

- had attracted a young Canadian student, Don Misener in 1937

the work by Allen et Misener was independent of the work by Kapitza (except for the liquid helium supply):- they had been working on this subject since 6 months at least - series of measuremnts using several capillaries with different sizes- a proof in their notebook (November 1937 ) John Cockcroft, Director of their laboratory, had asked them to write down their article, and asked Nature to publish the 2 letters side by side.

the work by Allen et Misener was independent of the work by Kapitza (except for the liquid helium supply):- they had been working on this subject since 6 months at least - series of measuremnts using several capillaries with different sizes- a proof in their notebook (November 1937 ) John Cockcroft, Director of their laboratory, had asked them to write down their article, and asked Nature to publish the 2 letters side by side.

Was Kapitza’s work also independent ?Was Kapitza’s work also independent ?

J.F. Allen

Any contacts between Moscow and Cambridge ?

David Schoenberg 22 Jan 2001: no contactsa

t that time ti would have been too dangerous to communicate

But letters from Kapitza show the opposite: regular contacts

Rutherford to Kapitza on October 9th 1937: mentions the « interesting work on helium in Cambridge » and dies on October 21stKapitza to Cockcroft on Nov. 1st : « It is difficult to believe that there is no more Rutherford…Things in the lab are not going badly at all. We just started the new liquefier and the first time it gave four liters per hour… »Webster had visited Moscow in September On Dec. 10th, Kapitza writes to Niels Bohr: « I had your letter about the death of Rutherford…May be you remember what I was telling you during your visit here [ in June 1937]… the results are quite interesting…I am sending herewith a copy of my preliminary note to Nature… »

Indépendent, but not equivalent

Kapitza:From the measurements we can conclude that the viscosity of helium II is at least 1500 times smaller than that of helium I at normal pressure… The flow must have been turbulent… »Allen-Misener: « the observed type of flow in which the velocity becomes almost independent of pressure, most certainly cannot be treated as laminar or even as ordinary turbulent flow. Consequently any known formula cannot, from our data, give a value of the viscosity which would have much meaning »

At that particular time, the most remarkable work was done in Cambridge.

Why is it that Kapitza received his Nobel prize only 40 years later?

How came the idea that superfluidity is ananologous to superconductivity? From discussions with Lev Landau, the genius of Soviet Physics at that time?

February 5th, 1938 : the fountain effect

J.F. Allen and H. Jones, discover

non-classical thermal properties

which they publish in Nature 141, 243, 1938

When heat is supplied on one side of a porous plug, the pressure of superfluid He increases so much that it produces a liquid jet

In a classical fluid, the liquid level should decrease

the fountain effectthe fountain effect

Fritz London, 5 March 1938, Institut Henri Poincaré :« it seems difficult not to imagine a connexion with the condensation phenomenon of the Bose-Einstein statistics... On the other hand, it is obvious that a model which is so far away from reality that it simplifies liquid helium to an ideal gas cannot...  » was a rough approximation which could not give quantitative agreement with experimental measurements.

London’s historical breakthrough

visible matter waves: Quantum mechanics jumps to the macroscopic scale

In 1924, Einstein extends work by a young Bengali physicist, Satyendra Nath Bose:The accumulation of indistinguishable atoms in the same quantum state leads to the formation of a macroscopic matter waveThis was first considered as unrealistic but London proposed that it was actually at work in superfluid helium.

Experimental evidence in 1995 thanks to the work of Cornell, Wieman (Boulder) and Ketterle (MIT), Nobel prizes in 2001

a laser is a coherent ensemble of photonsa Bose-Einstein condensate is a coherent

ensemble of atoms (or molecules)

low temperaturelow temperature

high temperaturehigh temperature

Fritz London

1900 : birth in Breslau (today Wroclaw in Poland)

1921: Doctorate in Munich

1927: understands the binding of the H2 molecule with Walter Heitler

1933: joins Schroedinger in Berlin

and soon escapes from the Nazi Germany towards England

1936: London and his wife Edith are attracted in Paris by Paul Langevin, Jean

Perrin, Frédéric Joliot-Curie and Edmond Bauer, a group of lelft wing

intellectuals linked to the « Front Populaire », and starts working again at the

Institut Henri Poincaré

1938: proposes that BEC could explain the superfluidity of liquid helium where

quantum fluctuations are large.

1939 (september!): escapes from France to Duke University (USA)

1954: dies of a heart attack

Laszlo Tisza invents the « two-fluid model »

- born in 1907, studies in Budapest then with Max Born in Gottingen and Heisenberg in Leipzig.

- Accused of being a communist by the Hungarian nazi power: 1 year of prison in 1934

- Teller recommends him for a post-doc position with Landau in Kharkov (1935-36)

- Arrives in Paris in 1937, invited by Paul Langevin at the Collège de France where he meets London

- Sends an article to Nature on April 16th 1938 on the « two fluid model »

the 2-fluid model: a remarkable success

Together with F. London, Tisza explained all the properties of superfluid He which were known in 1938: -point, flow, thermal effects and also

-the apparent contradiction between measurements of the viscosity in Toronto and in Cambridge.

- the motion of helium liquid films (Rollin, Kurti and Simon 1936)

there should be 2 independent velocity fields !the fountain effect is a thermomechanical effect : at constant chemical potential P increases with T.There should be a reverse effect: some cooling associated with flow through a narrow channel, to be soon discovered in Oxford by Daunt and Mendelssohn Nature 143, 719 (1939)In his next 2 articles (Comptes Rendus Ac. Sciences Paris, 207, 1035 and 1186 (1938) ) Tisza also predicted that, in addition to density waves (ordinary sound) there should be thermal waves (later called « second sound » by Landau) in a superfluid.

liquid helium should be a mixture of two components: condensed and non condensed atoms

a crucial test

July 1938: at a small meeting in London, Tisza presented his predictions of « temperature waves » and « offered it to make or break his theory »

At that stage, Fritz London kept his opposition to the idea that two independent velocity fields could exist in liquid helium.

April 1939: Landau escapes from Stalin’s jails

1908: Lev Davidovitch Landau born in Baku 1927: Doctorate in Leningrad at the age of 19!

Rockefeller fellowship , Landau travels to Germany, Switzerland, England and Copenhagen where he works with Niels Bohr

1932-37: Foundation of « Landau’s school » in Kharkov

Mars 1938: a leaflet against Stalin, Landau arrested by the NKVD (the KGB)

April 1939: Kapitza obtains that Landau is liberated to understand superfluidity by offering his own freedom as a guarantee to Beria. Landau starts working again near Kapitza in Moscow.June 1941: Landau publishes a theory of superfluidity in the USA and in USSR

Landau’s school

Landau was born in 1908, one year after Tisza

but he graduated in 1927 (at the age of 19 !)

and founded his famous school in Kharkov with 5 students or postdocs who passed the «Teorminimum exam »

1: Kompaneez

2 : E. Lifshitz

3: Akhiezer

4: Pomeranchuk

5: L. Tisza

1937: Landau moves to Moscow

and Tisza moves to Paris

Landau’s theory

Both papers start with the same statements:

« It is well known that liquid helium at temperatures below the -point possesses a number of peculiar properties, the most important of which is superfluidity discovered by P.L. Kapitza. »

According to Landau, the discovery was thus made in Moscow by the man who saved his life.

The paper continues with:« L. Tisza suggested that helium II should be considered as a degenerate ideal Bose gas... This point of view, however, cannot be considered as satisfactory... nothing would prevent atoms in a normal state from colliding with excited atoms, ie when moving through the liquid they would experience a friction and there would be no superfluidity at all. In this way the explanation advanced by Tisza not only has no foundations in his suggestions but is in direct contradiction with them. »

Landau‘s astonishing agressivity ...

Two different theoretical approaches

Landau never cited Fritz London . Apparently, he considered him as a bad physicistLandau never appreciated his former student Tisza

Fritz London had considered the ground state of superfluid helium at rest Landau had considered the hydrodynamic properties for which the introduced a theory of excitations in quantum fluids, but he always refused London’s idea of a connexion with Bose-Einstein’s condensation.

Each of them had found part of the truth, but they died before realizing it (London from a heart attack in 1954, Landau in 1968 after a car accident in 1960 and the Nobel prize in 1962).

The 2-fluid model had been introduced by Tisza with some mistakesLandau corrected it and wanted all the gloryLandau recieved the London prize, in 1960 ! Proposed par Tisza !!

What happened after the war?

1946: Peshkov’s experiments show that Landau was right in his corrections of Tisza’s theory

1947: Bogoliubov predicts superfuidity in a Bose Einstein condensate as soon as the atoms interact with each other.

1949: Osborne, Weinstock and Abraham show that superfluidity does not exist in liquid helium 3 at temperatures comparable to helium 4 (Bosons and Fermions, the importance of quantum statistics which Landau totally ignored)

1950 : J. Bardeen develops the theory of superconductivity with R. Schrieffer and L. Cooper . Bose-Einstein condensation of pairs of Fermions. A letter to London:

“ Dear Prof. London,

You may be interested in the enclosed manuscript on superconductivity; they are both based on your approach…'’

1956: Penrose and Onsager generalize Bose-Einstein condensation to interacting system as “off diagonal long range order” in the density matrix.

1957: Superconductivity is understood by Bardeen Cooper and Schrieffer (BCS) who get the 1972 Nobel prize. Bardeen gives part of his prize money to support the “London memorial award”.

more recently

1972: Osheroff, Lee and Richardson discover at Cornell that liquid helium 3 ( a Fermi system) becomes superfluid also, but at 2 milliKelvin, a temperature

1000 times lower than for helium 4.

It is a consequence of the formation of 3He-3He pairs as in superconductors.

3 more Nobel prizes in 1996 + Leggett in 2003.

1995: E. Cornell, C. Wieman and W. Ketterle discover Bose Einstein condensation in gases of cold atoms (Rubidium, Sodium and many others later).

Evidence for superfluidity is soon found in these quantum gases.

The rotation of superfluids is anomalous, a phenomenon analogous to the behavior of superconductors in a magnetic field.

Another 3 Nobel prizes in 2001.

A large list of Nobel prizes for superconductivity:

H. Kammerlingh Onnes in 1913, J. Bardeen L. Cooper and R. Schrieffer (“BCS”) in 1972, I. Giaever and B. Josephson in 1973, J. Bednorz and A. Muller in 1987, A. Abrikosov, V.L. Ginzburg in 2003

anomalous rotation anomalous rotation of superfluids :of superfluids :

quantized vorticesquantized vortices

and in Rubidium gas

( KW Madison, F. Chevy, W. Wohlleben et J. Dalibard, 2000)

in liquid helium 4

(E.J. Yarmchuk, M.J.V. Gordon et R.E. Packard, 1979)

a consequence of macroscopic quantum

coherence

Superfluidity and superconductivity today

Superconductivity has important applications:

mainly for building high field electromagnets

MRI medical imaging uses superconducting wires cooled down by liquid helium

The large particle accelerator LHC at CERN (Geneva) uses superconducting magnets in a 27 km long annulus filled with superfluid helium to understand the structure of elementary particles

the CERN annulus near Geneva

the magnets of the LHC are cooled down to 1.9K with superfluid helium

follow their temperature onhttp://hcc.web.cern.ch/hcc/cryogenics/cryo_magnets.php

MRI medical imaging uses superconducting magnets cooled down in liquid helium

… and supersolidity

In 2004 at Penn State University,

Eunseong Kim and Moses Chan

have discovered that not only liquid helium 4 but also solid helium 4 rotates in a non classical way.

Is it really possible that a solid is superfluid ? A quite astonishing property.

A supersolid would be elastic like a solid but a fraction of it would flow without any resistance through the rest.

We are here at CUNY to prove, or disprove, that supersolidity exists in solid helium. We don’t know the answer yet.

Some more Nobel prizes to come ? I don’t know either.

rigid axis ( Be-Cu)

solid Hein a box

excitation

thank you for your attention !