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waterworks internationa l llc • po box 58545 • dubai • +97150-4546747 < [email protected] > Advanced Oxidation Technology [ AOT ] The principle of Advanced Oxidation Technolog y is to generate Hydroxyl Radicals ( - OH ) , a highly reactive oxidizing agent that reacts with and destroys most Inorganic, Organic and Heavy Metal pollutants in Water & Waste Water. WATER  W o r k s o z o - t e k Detailed Oxidation The effect of WaterWorks’ advanced oxidation on Organics &  Inorganics. Page 2 Bacterial Disinfection & Viral Inactivation WaterWorks’ effect on  Algae, Bacter ia, Virus,  Fungi..... Page 3 WaterWorks Treatmen t Results WaterWorks’ advanced oxidation Treatment Results Table. Page s 5 & 6 WaterWorks In Industry WaterWorks’ applications in various Industries. Page 9 WATERWORKS OZO-TEK WaterWorks International LLC, a pioneer in Innovative & Emerging T echnolog ies i ntroduces W aterWorks Ozo-T ek : Industry Specic Water & Waste Water Treatment solutions. W aterW orks Ozo-Tek employs the potency of Liquid Ozone and works on the principles of Advanced Oxidation T echnology . WaterWorks Ozo-Tek can be tailored to industry specic Waste Water Treatment processes . Be it MEDICAL, INDUSTRIAL, DOMESTIC MUNICIPAL SEWAGE or any other commercial EFFLUENTS. W aterW orks specializes in the treatment of Efuent and wastewater with High Loads Of Bacteria, T oxicity , Chemicals & Heavy Metals, neutralizing them to meet all compliance standards, separating Solid Contaminants from the Efuent chemically. Due to this the treated efuent is ready for discharge or reuse within hours thereby making the Treatment Plant ready for the next batch of waste water .

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< i n f o @ w a t e r w o r k s . b i z >

Advanced Oxidation

Technology [ AOT ]

The principle of Advanced

Oxidation Technology is to

generate Hydroxyl Radicals

( - OH ) , a highly reactiveoxidizing agent that reacts

with and destroys most 

Inorganic, Organic and

Heavy Metal pollutants in

Water & Waste Water.

WATER W o r k s o z o - t e k

Detailed Oxidation

The effect of  WaterWorks’ 

advanced oxidation on Organics & 

 Inorganics.

Page 2

Bacterial Disinfection

& Viral Inactivation

WaterWorks’ effect on

 Algae, Bacteria, Virus,

 Fungi.....

Page 3

WaterWorks Treatment

Results

WaterWorks’ advanced 

oxidation Treatment Results

Table.

Page s 5 & 6

WaterWorks In Industry

WaterWorks’ applications in

various Industries.

Page 9

WATERWORKS OZO-TEK

WaterWorks International LLC, a pioneer in Innovative &

Emerging Technologies introduces WaterWorks Ozo-Tek :

Industry Specific Water & Waste Water Treatment

solutions.

WaterWorks Ozo-Tek employs the potency of Liquid Ozone andworks on the principles of Advanced Oxidation Technology .

WaterWorks Ozo-Tek can be tailored to industry specific Waste Water

Treatment processes . Be it MEDICAL, INDUSTRIAL, DOMESTIC

MUNICIPAL SEWAGE or any other commercial EFFLUENTS.

WaterWorks specializes in the treatment of Effluent and wastewater

with High Loads Of Bacteria, Toxicity, Chemicals &

Heavy Metals, neutralizing them to meet all

compliance standards, separating Solid

Contaminants from the Effluent chemically.

Due to this the treated effluent is ready for

discharge or reuse within hours thereby

making the Treatment Plant ready for the

next batch of waste water.

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Why Ozone ?. Why WaterWorks Ozo-Tek?

Safety: There are no dangerous chemicals to transport, store, or 

handle. Perhaps even more important, the chance of overdosing 

with dangerous and hazardous chemicals is limited.

Classified under Generally Recognizes As Safe (GRAS) as listed 

by the United States Food and Drug Administration (USFDA).

as a disinfectant for bottled waters.

 Disinfection: Ozone kills microorganisms with

a process known as “cellular lysis” . In

the Oxidation process, Ozone ruptures the

cellular membrane of microorganisms and 

disperses the bacterial cytoplasm into

solution, thus making reactivation impossible.

This process takes place in about 2 seconds.

WATER WORKS

Ozone destroys E. coli 3,125 times

faster than Chlorine.

Oxidation Of ORGANICs & Pesticides. WaterWorks Ozo-Tek is a very powerful agent in

treating Organic Materials.

Organics are either Natural (Humic and Fulvic Acids)

or Synthetic (Detergents, Pesticides) in nature.

Some Organics react with Ozo-Tek very rapidly to

destruction, within minutes or even seconds ( Phenol,

Formic Acid), whereas other react more slowly with Ozo-

Tek ( Humic & Fulvic Acids, several Pesticides,

Trichloroethane...) Soaking meats and produce in diluted

Ozo-Tek solution for 10 to 15 min. can greatly reduce

contamination.

Oxidation Of INORGANICs.

Oxidation of Inorganics with Ozo-Tek will not result

in the complete removal of metals, but it does facilitate

their Oxidation, Precipitation and subsequent Removal

through Filtration. Iron and Manganese are easily and

readily Oxidized into a particulate for filtration

downstream.

Sulfides are rapidly Oxidized to Sulfates, thus

eliminating the “rotten egg” taste and odour associated

with Sulfides.

Heavy Metals such as Arsenic, Copper, and Lead are easily reduced to below

detection limits with Ozo-Tek followed by filtration. Trace Metal removal of 

Cadmium and Zinc through Oxidation with Ozo-Tek and subsequent Filtration

has been found to be effective in reaching MCL levels established by the USEPA 

in the SDWA. Nitrite ion is oxidized very quickly to Nitrate as are Organic

Nitriles, Nitrites, Nitrous Compounds, Hydroxylamine and the like.

In the case of Iron, Manganese and several Arsenite or Arsenate compounds,

Oxidation takes place very rapidly, leaving insoluble compounds which are easily

removed by a Granular Activated Carbon Filter. Sulfide ions are oxidized

sequentially to Sulfate ions, an innocuous substance. The first stage of this

oxidation is very rapid, quick and efficiently removing any Sulfurous odours.

Nitrite ions are Oxidized to Nitrate ions, which are stable and innocuous

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The extent of Bacteria Destruction and Viral Inactivation is directly 

related to the concentration of ozone in the water and its contact time

with the microorganisms.

Bacteria are the most rapidly destroyed.EColi Bacteria are destroyed by Ozone concentrations of just over .01

mg/liter and contact time of 15 second at temperatures of 25 degrees C

(77 degrees F) and 30 degrees C (86 degrees F).

Streptococcus Fecalis are much more easily destroyed.

At Ozone concentrations of about 0.025 mg/liter, 99.99% inactivation is

obtained in 20 seconds or less at both temperatures.

Legionalla Pneumophila ( the bacteria responsible for Legionnaires

disease) is destroyed with relatively low dosages of ozone. This is one of 

many reasons that Ozone Based Treatment has become so popular in

the treatment of cooling tower water.

Viruses are more resistant than Bacteria. But only just. Pioneered by 

French public officials, it has been found that inactivation of viruses in

excess of 3-log (99.9%) can be achieved by maintaining a 0.4 residual

of ozone for a minimum of 4 minutes

Poliovirus types I, II and III are inactivated by exposure to

concentrations of dissolved Ozone of 0.4 mg/liter over a four minute

contact period.

WaterWorks Ozo-Tek which

personifies Ozone but in Liquid

Form is a very powerful Oxidizing

agent, is effective against Bacteria,

Virus, Fungi, Algae and Spores.

What is more important is that it is

equally effective against a variety 

of bacteria species that are

normally resistant to other biocides.

In addition to its strong biocidalaction which is long lasting, Ozo-

Tek is a nontoxic, nonpolluting,

nonresidual and environmental

friendly biocide.

It is a universal biocide that is

suitable for all industries.

WATER WORKS

BacterialDisinfection &

Viral Inactivation. WaterWorks Ozo-Tek is a complex

formulation in liquid form.

It works on Pathogens / Germs /

Bacterial Contaminated Media in two

ways.

First, it kills the Pathogens / Germs /

Bacteria by an Oxidative Degradation

Reaction (ODR).

Second, it further enhances the

already long lasting Oxidative effect,

thereby ensuring the prevention of further

growth of Pathogens / Bacteria.

This synergic reaction of WaterWorks

is achieved by a formulation in

combination with special manufacturing 

process.

WaterWorks has

3000 ppm of  Nascent Oxygen in

Liquid Form captured in it and it is

engineered for Sustained Dosage Release.

Algae Control:

Ozonation

by 

WaterWorks will

disrupt the Metabolic Processes of 

many types of Algae by Oxidizing &

Destroying its essential organic

components.

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WATER WORKS

Advantages Of WaterWorks’ Ozo-Tek Ozonisation.

* ) Oxidation of all Organic, Inorganic and Heavy Metals ( Into Oxides ) in a Single Treatment.

* ) Sustained Release with Strong & Rapid Action.

* ) BOD & COD Control. An almost instant reduction of over 90 %.

* ) Optical Clarity in Treated Water.

* ) Almost Zero SLUDGE in Sewage Treatment.

* ) Odour Free Treated Water. Any stink is arrested immediately and there will be no smell around the plant area.

* ) BIOFOULING in filter membranes is eliminated giving the system longer life and making them more efficient.

* ) Arrests ALGAE growth & prevents future formation.

* ) ECO Friendly - Leaves no undesirable Taste or Odour. And Non Toxic.

* ) No Requirement of complicated Aerators.

* ) Low POWER LOADS: The power required to operate our plants is minimal and restricted to running the transfer 

pumps, drying and filter systems.

* ) Effective on most Pathogens even at High Concentrations.

* ) FLASH LOADS’ management : Any flash load of wastewater in both quantity and discharge can be handled instan

by merely increasing the quantity of WaterWorks’ Dosage.

* ) Over 90 % of the Water is reusable soon after Treatment.

* ) Ozo-Tek treated Effluent when fed to Reverse Osmosis Systems increase the life of the Membranes, Improves their 

Efficiency and Reduces Rejects.

* ) Ozo-Tek can be tailored to be Industry Specific and is suitable for DOMESTIC, INDUSTRIAL & MEDICAL Applicati

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WATER WORKS

Ozone is the disinfectant of 

choice for most water bottling

plant operations. Unlike

Chlorine, Ozone leaves no

undesirable taste or odor. Taste

and odor by-products such as

Unsaturated Aldehydes are

readily Oxidizable with Ozone.

Ozone is 152% stronger thanChlorine and destroys E-Coli ,

3125 times faster than Chlorine.

WaterWorks Ozo-Tek Vs.Conventional : Cost Benefit

Analysis.WaterWorks LLC performed a

cost benefit comparison of the current

Surface Agitator Aerators versus a

proposed Ozo-Tek’

based Oxidation

Treatment System.

This comparison

evaluated current

operational costs

associated with the

surface aerators

versus operational

costs associated with

a complete

oxidization system. The cost

benefit analysis identified differences

in energy consumption and treatment

efficiencies between the two systems

and weighed the associated

“nonfixed” costs such as sludge

removal and disposal.

Additionally, the study examined

the differences in energy consumption

and treatment efficiencies between

several municipal and industrial

wastewater treatment

systems which have

already started to switch

from surface aerator 

systems to a new

oxidization system.

It was found that the cost

difference as regards

capital investment, power

consumption, and

operational running cost

are cut down by more

than 50% as against conventional

method treatment plants.

OZO-TEK SE AGE T EATME T RES LTS

Parameters Maximum

Tolerance Limits

Ozo-Tek

Treated Results

I - S Test

Protocols

% Parameter 

Reduction

Color - Colorless IS 3025 ( P.4 ) Colorless

Odour - Odourless IS 3025 ( P.5 ) Odourless

Total Suspended Solids, mg/l 100 10 IS 3025 ( P.17 ) 90%

Total Dissolved Solids, mg/l 2100 1230 IS 2488 ( P.5 ) 40%

Chlorides as Cl, mg/l 1000 190 IS 3025 (P.32) 81%

pH Value 5.5 - 9.0 7.9 IS 3025 (P.11 )

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WATER WORKS

Sulphates as SO4 mg/l 1000 44 IS 3025 ( P.24 ) 96%

Oil & Grease mg/l 10 ND IS 3025 ( P.39 ) 100%

Total Residual Chlorine 1 Nil IS 3025 ( P.26 ) 100%

Ammonical Nitrogen, mg/l 50 12.1 IS 3025 ( P.34 ) 74%

Total Keldal Nitrogen as N 100 13.8 IS 3025 ( P.34 ) 87.2%

Free Ammonia, mg/l 5 0.65 IS 2488 ( P.4 ) 80%

BOD - 3 Days at 27o C, mg/l 10 3 IS 3025 ( P.44 ) 70%

COD, mg/l 250 64 IS 2488 ( P.5 ) 75%

Arsenic as AS, mg/l 0.2 < 0.01 IS 3025 ( P.37 ) 90%

Mercury as Hg, mg/l 0.01 < 0.001 IS 3025 ( P.48 ) 90%

Lead as Pb, mg/l 0.1 < 0.01 IS 3025 ( P.47 ) 90%

Cadmium as Cd, mg/l 2.0 < 0.01 IS 3025 ( P.41 ) 90%

Hexavalent Chromium as Cr 6, mg/l 0.1 < 0.01 IS 3025 ( P.38 ) 90%

Copper as Cu, mg/l 3.0 < 0.01 IS 3025 ( P.42 ) 90%

Zinc as Zn, mg/l 5.0 0.16 IS 3025 ( P.49 ) 90%

Selenium as Se, mg/l 0.05 < 0.01 APHA 80%

Nickel as Ni, mg/l 3.0 0.12 IS 2488 ( P.2 ) 90%

Cyanide as CN, mg/l 0.2 < 0.01 APHA 90%

Fluoride as F, mg/l 2.0 0.10 IS 3025 ( P.23 ) 90%

Dissolved Phosphates as PO4 mg/l 0.10 < 0.05 IS 2488 ( P.4 ) 50%

Sulphide as S, mg/l 2.0 Nil IS 2488 ( P.1 ) 100%

Phenols as C6H5OH, mg/l 1.0 max < 0.001 IS 3025 ( P.43 ) 90%

Manganese as Mn, mg/l 2.0 0.06 APHA 90%

Iron as Fe, mg/l 3.0 0.09 IS 3025 ( P. ) 90%

Vanadium as V 0.2 < 0.01 APHA 90%

Nitrate Nitrogen 10.0 1.80 APHA 80%

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OZONE : WHITE PAPER 

What Is Ozone ?Ozone, first discovered in 1840, received its name from the Greek word “Ozein”, which means to smell.

Ozone is a Triatomic Allotrope of Oxygen (a form of oxygen in which the molecule contains three atoms instead of two).

Its chemical formula is O3 and it is always present in trace quantities in the Earth's atmosphere.

Ozone is produced when Oxygen molecules (O2 ) are split into two oxygen atoms (O1 ) while in the presence of other oxygen

molecules. These Oxygen atoms (O1 ) then combine with molecular oxygen (O2 ) to yield Ozone,O3.

Ozone is generated naturally by short-wave solar ultraviolet radiation, and appears in our upper atmosphere (Ozonosphere) in the

form of gas.

CHARACTERSTICS OF OZONE

Color Pale Blue

Odour Detectable In Concentrations as low as 0.01 ppm in air.

Oxidation Potential 2.07 V in Alkaline Solution. Strongest stand alone oxidizer currently available

and is 152 % stronger than Chlorine

Density 150% that of Oxygen.

Form Factors GAS at Ambient Temperature. Condenses to Dark Blue LIQUID at -170°F.

Freezes to SOLID at -420°F.

Decomposition Decomposes readily* at temperatures exceeding -212°F.

Stability Time & Temperature dependent. At room temperature unreacted Ozone will

revert back to Molecular Oxygen completely within hours. Ozone is an unstable 

gas with a 1/2 life in the order of minutes.

Disinfectant Destroys Microorganisms, Viruses & Cysts quickly without much reaction from pH

or Turbidity

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Color Removal.Color derived from the decomposition of 

naturally occurring Humic materials

(organics) is easily removed with Ozone

 followed by GAC filtration.

Toxins & Pesticides. Pesticides such as Phosolone and Aldrin are

Oxidized to destruction. Toxic Cyanide

ions are readily oxidized by Ozone to the

much less toxic Cyanate ion.

Turbidity & Micro Flocculation.Ozone used as a coagulation aid prior to

the injection of chemicals, enhances the

 process through micro flocculation and 

reduces chemical demand. It is not a

replacement to the coagulation process, but 

as a superior coagulant aid.

OZONE : WHITE PAPER 

The Mechanics Of Ozone :The USEPA has identified over 

700 individual organic compounds,

many of which may be readilyOxidized to Carbon Dioxide by

Ozone, while a few others are not

affected at all.

The use of Ozone on Organics is

typically followed by Filtration with

Granular Activated Carbon (GAC).

Advanced Oxidation Process

Advanced Oxidation Process

(AOP) refers to increasing the

Reactivity of Ozone in Water.

Forcing Ozone to react via a Free

Radical Pathway performs this. There

are two methods commonly used to

attain AOP:

1. (O3 + H2O2)

2. (O3 + UV)

This Free Radical Process

degrades many molecules that areresistant to Ozone alone. AOP

utilized on Organics that normally

react to Ozone will reduce the initial

Ozone dosage required by

approximately 20%.

AOP is used most often to control

Organics (Taste, Odor, Color, THM

Precursors, Micro Pollutants and

Pesticides).Trihalomethane (THM) precursors

(Humic and Fulvic Acids) are not

formed until they are Chlorinated.

Therefore, it is best to control the THM

precursors prior to Chlorination (if 

required after Ozonation) by partially

oxidizing them with small amounts of 

Ozone. Normally, the Ozonated

water is then passed through sand

and/or GAC filtration. The partially

oxidized THM precursors arebiologically degraded in the sand

and / or GAC filters.

Volatile Organic Contaminants

(VOCs) may be reduced dramatically

(up to 97%) by Ozonation followed

by GAC.

Synthetic Organic Contaminants

(SOCs) Micro pollutants can be

removed by Ozone or AOP. Thisremoval leads to the transformation of

these molecules into toxic or non-toxic

by-products, which are easily

removed through subsequent GAC

filtration.

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WATER WORKS

WATERWORK : APPLICATIONS IN INDUSTRY

Industry Treatment & ReUse Applications

MUNICIPAL CORPORATIONS,

GOLF CLUBS

SEWAGE Treatment of City Discharge. REUSE for Groundwater &

Surface Water Body Recharge [ Lakes & Ponds Refills ], HighwayPlantation, Garden & Landscape Watering.

HOSPITALS, CLINICS,

LABORATORIES & BLOOD

BANKS.

Treatment of Medical Liquids Discharge. Best Disinfectant.

Sterilization of Surgical Instruments, Linen, Floor Cleaning,

Fumigation. REUSE for Landscape Watering.

PHARMACEUTICALS Treatment Of Process Effluent & SEWAGE Discharges. REUSE.

HEAVY INDUSTRIES Treatment Of Process Effluent & SEWAGE Discharges. REUSE.

WATER PARKS Water Stabilization & Disinfectant. Complete Reuse capability.

LAUNDRY Disinfectant & REUSE

SWIMMING POOLS Water Stabilization & Disinfectant. Complete Reuse capability.

AUTOMOBILE Treatment Of Process Effluent & SEWAGE Discharges. REUSE.

DYEING Treatment Of Process Effluent & SEWAGE Discharges. REUSE.

COOLING TOWERS ALGAE Free water for continuous REUSE.

TECHNOLOGY PARKS SEWAGE Treatment . REUSE for Landscape Watering & Cooling.OIL EXTRACTION UNITS Treatment Of Process Effluent & SEWAGE Discharges. REUSE.

DAIRY INDUSTRY Treatment Of Process Effluent & SEWAGE Discharges. REUSE.

DISTILLERY / BREWERY Treatment Of Process Effluent & SEWAGE Discharges. REUSE.

ANIMAL FARMS WATER Treatment & Disinfectant.

AQUA CULTURE FARMS WATER Treatment & Disinfectant.

AGRICULTURE WATER Treatment & Post Harvest Preservative of Produce.

FOOD PROCESSING Disinfectant, Preservation & Waste Water Treatment.

PAPER INDUSTRY Treatment Of Process Effluent & SEWAGE Discharges. REUSE.

BOTTLED WATER, FOOD &

BEVERAGE

Equipment & Bottling Disinfectant, BOTTLE Washing. Treatment Of 

Process Effluent & SEWAGE Discharges.

TRANSPORT INDUSTRY VEHICLE Washing & CONTAINER Disinfection.

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WW : TYPICAL TR EATMENT PROCESS

PRIMARY TREATMENT :Screening

The effluent is screened using Mild

Steel Grate Bars.

All solid particles thus

screened / filtered off shall be

manually removed periodically and

disposed through

regular municipal sources.

Or this solid organic waste can be

collected in a pit, located in

an isolated place and allowed to

turn into “compost”, which may 

probably be used

as Organic Manure for 

gardening.

SECONDARY TREATMENT :1.Equalization

The effluent / wastewater shall be

collected in the transit collection sump

for equalization.

The oxidizing liquid Ozo-Tek is

dosed at this tank as per the

required measure. Normal

Agitation is provided for proper 

mixing for 30 minutes.

2.Flocculating, Coagulating

and Dosing System – (Lime / PAC / Alum / Poly ) assuitable.

THIS STEP IS ONLY REQUIRED IN

THE CASE OF EFFLUENT TREATMENT 

Flocculent and Coagulant are stirred

for a proper mix in the

Equalization tanks that is fitted

with a slow stirring system coupled

with a dosing

dispenser system that are measure

dosed by atomized state for precise

dosing. Normal Agitation is provided

for proper mixing for 30 minutes.

TERTIARY TREATMENT :The treated Effluent / Sewage

stored in the Clarifier Water Tank sha

be pumped

through Media filters (Media:

Granular Activated Carbon & Graded

Sand), where

the color, turbidity and COD

present will completely be minimized

The treated

effluent / water are then collected

in the final collection tank. The

collected treated

water shall be pumped and

maybe reused for gardening and

irrigation. The same

water could be used for back 

washing of filters. The back wash

drain, filter rinse

drain and the decanted water 

shall be pumped / drained back to

equalization tank.

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Disclaimers & Safety Notes :

WaterWorks dosage is Industry Specific

and should be tested for 

optimization.Technical Assistance is

strongly suggested for Proper Dosage & Treatment.When properly handled,

WaterWorks compounds are safe, easy to

use chemicals. We strongly recommend you

contact us before experimenting with,

designing, installing or modifying an

application system or using this chemical.

Acknowledgements :

WaterWorks LLC. would like to

acknowledge the two major sources of 

information relating to Ozone in water 

treatment. The American Water Works Association Research Foundation

(  AWWARF  ) and the International 

Ozone Association ( IOA ) have gone to

 great lengths in researching Ozone and its

effects on constituents found in water and 

hence have strived to dispel  the mystery

associated with the use of Ozone.

To the scientists, chemists,

engineers, treatment plant 

 personnel  , and to those contributing credible information to the IOA

and the AWWARF  , we express a sincere

Thank You.

WATERWORKS : SALIENT BENEFITS

Plant Size & Treatment Costs.WaterWorks’ based treatment 

Plant Area required would more than

50% LESS compared to ConventionalTreatment Plants. Optionally the

WaterWorks’ plant can be designed

for Underground Operation (below 

Parking / Landscape / Garden

areas).

For example Land area required

for a 100 Kl plant would be

50 x 75 = 3750 Sq. Feet.

The costing of the plant is alsomuch too less compared to

conventional treatment and

treatment plants.

Adaptability & MaintenanceCosts.

With WaterWorks’ existing

Conventional Treatment Plants couldbe made to perform more efficiently 

with minimum modifications for 

maximum results.

Maintenance of a WaterWorks’

based plant is very easy with low 

running cost, as there is no

complicated machinery.

Disinfection Costs.WaterWorks can be compared

with other biocides, disinfectants and

antiseptic solutions, but oncomparison WaterWorks is more

economical than most of the

disinfectants that are commonly used,

apart from being more effective.