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H:\Files\TGOLD\11048\WRM Reports\2014\2nd Qtr\r14 Second Qtr WRM Report.doc\HLN\11/6/2014\065 11/6/2014 1:47 PM
WATER RESOURCES MONITORING
2014 SECOND QUARTER REPORT
BLACK BUTTE COPPER PROJECT
Prepared for:
Tintina Alaska Exploration Inc. Suite 2560-200 Granville Street
Vancouver, BC, Canada V6C1S4
Prepared by:
Hydrometrics, Inc. 3020 Bozeman Avenue
Helena, MT 59601
November 2014
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TABLE OF CONTENTS
LIST OF TABLES ...........................................................................................................iii
LIST OF FIGURES .........................................................................................................iii
LIST OF APPENDICES. .................................................................................................iii
1.0 INTRODUCTION .....................................................................................................1-1
2.0 SURFACE WATER MONITORING PROTOCOL ..................................................2-1
2.1 FLOW MEASUREMENT .............................................................................2-1
2.2 FIELD PARAMETERS .................................................................................2-2
2.3 WATER QUALITY SAMPLING .................................................................2-2
2.4 FIELD QUALITY CONTROL ......................................................................2-3
3.0 GROUNDWATER MONITORING PROTOCOL ...................................................3-1
3.1 STATIC WATER LEVEL MEASUREMENT .............................................3-1
3.2 FIELD PARAMETERS AND WATER QUALITY SAMPLE
COLLECTION ...........................................................................................3-1
4.0 RESULTS ..................................................................................................................4-1
4.1 STREAM DISCHARGE ...............................................................................4-1
4.2 GROUNDWATER LEVELS ........................................................................4-1
4.3 WATER QUALITY DATA ...........................................................................4-6
4.4 FIELD QUALITY CONTROL ......................................................................4-7
5.0 REFERENCES ..........................................................................................................5-1
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LIST OF TABLES
TABLE 1. SURFACE WATER MONITORING SITES .......................................1-2
TABLE 2. GROUNDWATER MONITORING SITE COMPLETION DATA .....1-3
TABLE 3. ANALYTICAL METHODS AND DETECTION LIMITS FOR
SURFACE WATER AND GROUNDWATER SAMPLES .................1-5
TABLE 4. SAMPLE CONTAINER AND PRESERVATION
REQUIREMENTS ................................................................................2-3
TABLE 5. JUNE 2014 SURFACE WATER QUALITY DATA ...........................4-2
TABLE 6. JUNE 2014 GROUNDWATER QUALITY DATA .............................4-3
TABLE 7. JUNE 2014 WATER LEVEL DATA ...................................................4-4
LIST OF FIGURES
FIGURE 1. BASELINE MONITORING SITES .....................................................1-4
FIGURE 2. JUNE 2014 POTENTIOMETRIC MAP ...............................................4-5
LIST OF APPENDICES
APPENDIX A LABORATORY ANALYTICAL REPORT
APPENDIX B LABORATORY QA/QC REPORT
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WATER RESOURCES MONITORING
2014 SECOND QUARTER REPORT
BLACK BUTTE COPPER PROJECT
1.0 INTRODUCTION
Hydrometrics conducted the 2014 Second Quarter Water Resources Monitoring Event for the
Black Butte Copper Project on June 9 – 11. The quarterly monitoring schedule includes
sample collection and/or field measurements at eleven surface water sites (five sites for flow
and field parameters and six sites for water quality and flow) as well as eleven groundwater
sites, to establish baseline pre-mining conditions for surface water and ground water in the
vicinity of the proposed mine. Surface water monitoring sites are listed in Table 1 and
groundwater sites are listed in Table 2. Static water levels were also collected at twelve
additional wells/piezometers (Table 2). Surface water and groundwater site locations are
shown on Figure 1.
Water quality samples were submitted to Energy Laboratories in Helena, MT for analysis of
physical parameters, common constituents, nutrients, and a comprehensive suite of trace
constituents as listed in Table 3. With the exception of aluminum, trace constituents were
analyzed for the total recoverable fraction for surface water samples; aluminum was analyzed
for the dissolved fraction. All trace constituents for groundwater samples were analyzed for
the dissolved fraction.
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TABLE 1. SURFACE WATER MONITORING SITES
Site Location Northing Easting Field
Parameters and Flow
Laboratory Analyses UTM - WGS 1984
Zone 12 N (meters)
SW-1 Sheep Creek - Downgradient site; at bridgeon county road 119 5182710 507148
X X
SW-2
Sheep Creek - Upgradient site; Highway 89 right of way approximately 0.6 miles east of county road intersection 5179844 511040
X X
SW-3
Unnamed Trib. to Sheep Creek - at intersection of county road 119 and forest service road. 5180581 506996
X X
SW-4
Unnamed Trib. to Sheep Creek - approximately 0.6 miles southwest of Co. Rd/USFS Rd intersection 5180114 506308
X
SW-5
Unnamed Trib. To Butte Creek - West of Moose Pass, where jeep trail crosses drainage. 5181465 503914
X X
SW-6
Unnamed Trib to Little Sheep Creek - approximately 0.25 miles south of county road. 5179536 507919
X X
SW-7
Unnamed Trib to Little Sheep Creek - Upgradient site, approximately 1-mile upgradient of SW-6. 5179000 506420
X
SW-8 Little Sheep Creek - Approximately 0.5 miles from Highway 89. 5179476 509575
X
SW-9 Butte Creek - at USFS road crossing. 5179271 503944 X
SW-10 Butte Creek - approximately 0.7 miles upstream of SW-9. 5178322 504665
X
SW-11
Butte Creek - Downgradient of confluence with Unnamed Trib to Butte Creek (west of Moose Pass). 5181021 501951
X X
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TABLE 2. GROUNDWATER MONITORING SITE COMPLETION DATA
Well Name
Easting (meters)
Northing (meters)
G.S. Elev. (feet amsl)
M.P. Elev. (feet amsl) Total
Depth (feet, bgs)
Perforated/ Screen
Interval (feet, bgs)
Filter Pack Interval
(feet, bgs) UTM- WGS 1984 Zone 12 North
Monitoring Wells MW-1A
506935.22 5180841.55 5635.81 5637.73 38 25 - 34 25 - 34 MW-1B
506934.19 5180845.46 5636.14 5637.90 98 88 - 98 88 - 98 MW-2A
506598.18 5180331.93 5743.72 5745.31 62 52 - 62 47 - 62 MW-2B
506596.96 5180328.73 5743.44 5745.53 80 70 - 80 65 - 80 MW-3
506484.07 5180740.22 5760.06 5762.17 305 285 - 305 278 - 305 MW-4A
507201.47 5180855.43 5610.12 5612.12 23 14-23 11-59 MW-4B
507200.12 5180858.49 5610.07 5612.07 59 39-59 37-59 MW-6A 507809.18 5179492.9 5680.08 5681.87 15 5-15 3-15MW-6B 507792.76 5179490.7 5683.41 5685.31 50 40-50 37-50MW-7 507451.7 5179500.7 5747.48 5749.46 50 40-50 37-50MW-8 507036.00 5179398.3 5809.10 5810.93 80 70-80 67-80
Test Wells (water level only) PW-1 506301.42 5180698.4 5912.07 5913.74 213 140-211 108-213 PW-2 506443.15 5180865.03 5793.08 5794.88 215 132 - 212 121 - 212 PW-3
506846.43 5180479.42 5655.21 5657.42 131 90-127 80-130 PW-4
506901.79 5180688.26 5678.13 5680.01 242 200-239 191-242
Piezometers (water level only) PZ-01
507650.01 5180255.63 5628.69 5630.34 5.3 2.3-5.3 NA PZ-02
507400.72 5180778.79 5611.81 5613.51 5.3 2.3-5.3 NA PZ-03
507249.21 5180618.91 5616.08 5617.74 9.3 6.3-9.3 NA PZ-04
506991.74 5181110.82 5599.34 5602.7 7.7 4.7-7.7 NA PZ-05
507080.04 5181214.68 5598.16 5599.79 5.4 2.4-5.4 NA PZ-07A
506258.39 5180074.65 5776.57 5777.50 5.4 2.4-5.4 NA PZ-07B
506258.47 5180075.00 5776.57 5777.59 5.4 2.4-5.4 NA PZ-08
507090.31 5180573.81 5618.90 5621.29 5.4 2.4-5.4 NA PZ-09
507883.78 5180178.58 5634.73 5637.27 5.4 2.4-5.4 NA
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MW-4AMW-4B
MW-1BMW-1A
PZ-08PZ-07A
PW-5PW-7PW-6
PW-4PW-2
PW-1
PW-3
MW-7
MW-8MW-6A/6B
MW-3
MW-2AMW-2B
SW-5
SW-6
SW-3 SW-2
SW-1
SW-11
SW-9
SW-7
SW-4
SW-8
SW-10
PZ-05PZ-04
PZ-03PZ-02
PZ-01
PZ-07BPZ-09
Copyright:© 2013 National Geographic Society, i-cubed
LEGEND!( SW Sites - FlowP SW Sites - Flow/WQ@? Piezometers (approx. Location)@A Groundwater Monitoring Site&( Test Wells
o
Coon
0 5,2002,600
FeetV:\11
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eport
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Sites
.mxd
Sheep CreekGaging Station
Baseline Monitoring SitesBlack Butte Copper Project
Meagher County, Montana
Creek
Figure 1
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TABLE 3. ANALYTICAL METHODS AND DETECTION LIMITS FOR SURFACE WATER AND GROUNDWATER SAMPLES
Parameter Analytical Method(1) Project-Required Detection
Limit (mg/L) Physical Parameters
TDS SM 2540C 10 TSS SM 2540C 10
Common Ions Alkalinity SM 2320B 4
Sulfate 300.0 1 Chloride 300.0/SM 4500CL-B 1 Fluoride A4500-F C 0.1 Calcium 215.1/200.7 1
Magnesium 242.1/200.7 1 Sodium 273.1/200.7 1
Potassium 258.1/200.7 1 Nutrients
Nitrate+Nitrite as N 353.2 0.01 Total Kjeldahl as N A 4500 N org 0.5
Total Nitrogen Calculated 0.5 Total Phosphorus E365.1 0.01
Trace Constituents (SW - Total Recoverable except Aluminum [Diss], GW - Diss)(2) Aluminum (Al) 200.7/200.8 0.009 Antimony (Sb) 200.7/200.8 0.0005 Arsenic (As) 200.8/SM 3114B 0.001 Barium (Ba) 200.7/200.8 0.003
Beryllium (Be) 200.7/200.8 0.0008 Cadmium (Cd) 200.7/200.8 0.00003 Chromium (Cr) 200.7/200.8 0.01
Cobalt (Co) 200.7/200.8 0.01 Copper (Cu) 200.7/200.8 0.002
Iron (Fe) 200.7/200.8 0.02 Lead (Pb) 200.7/200.8 0.0003
Manganese (Mn) 200.7/200.8 0.005 Mercury (Hg) 245.2/245.1/200.8/SM 3112B 0.000005
Molybdenum (Mo) 200.7/200.8 0.002 Nickel (Ni) 200.7/200.8 0.001
Selenium (Se) 200.7/200.8/SM 3114B 0.0002 Silver (Ag) 200.7/200.8 0.02
Strontium (Sr) 200.7/200.8 0.0002 Thallium (Tl) 200.7/200.8 0.0002
Uranium 200.7/200.8 0.008 Zinc (Zn) 200.7/200.8 0.002
Field Parameters Stream Flow HF-SOP-37/-44/-46 NA
Water Temperature HF-SOP-20 0.1 °C Dissolved Oxygen (DO) HF-SOP-22 0.1 mg/L
pH HF-SOP-20 0.1 s.u. Specific Conductance
(SC) HF-SOP-79 1 µmhos/cm
(1) Analytical methods are from Standard Methods for the Examination of Water and Wastewater (SM) or EPA’s Methods for Chemical Analysis of Water and Waste (1983).
(2) Samples to be analyzed for dissolved constituents will be field-filtered through a 0.45 m filter.
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2.0 SURFACE WATER MONITORING PROTOCOL
Quarterly surface water monitoring includes discharge (flow) and field parameter
measurements at all eleven sites; water quality samples for laboratory analysis were collected
at six of the eleven monitoring sites. Below is a summary of the methodologies used for the
surface water monitoring, which consisted of the following steps:
1. Measurement of stream flow and stage (at sites instrumented with staff gages);
2. Collection of field parameters; and
3. Water quality sample collection.
2.1 FLOW MEASUREMENT
Surface water flow measurements were collected using a Marsh-McBirney current meter and
wading rod (area-velocity method) or 90° v-notch cutthroat flume. Stage measurements were
measured at staff gages at selected sites.
The Marsh-McBirney current meter is used to measure stream flow at larger, wadeable
stream sites. Measurement of stream flow was performed in accordance with the area-
velocity method developed by the USGS (USGS, 2010). In general, the entire stream width
is divided into subsections and the stream velocity is measured at the midpoint of each
subsection at a depth equivalent to six-tenths of the total subsection depth. The velocity in
each subsection is then multiplied by the cross-sectional area to obtain the flow volume
through each subsection. The subsection flows are then summed to obtain the total stream
flow rate. Stream flow measurements are typically collected in a stream reach as straight and
free of obstructions as possible, to minimize potential measurement error introduced by
converging or turbulent flow paths.
Stream flow measurements on smaller streams were obtained by using a portable 90° v-notch
cutthroat flume. To measure stream flow, the flume was placed and leveled in the streambed,
and the full stream flow directed through the flume throat. Water depth or head
measurements were then collected at specified locations in the converging and (if applicable)
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diverging sections of the flume. The head measurements were used to verify proper
functioning of the flume and to calculate stream flow based on the water depth.
2.2 FIELD PARAMETERS
Surface water monitoring included measurement of the field parameters that consisted of pH,
specific conductance (SC), dissolved oxygen (DO), and water temperature. Field parameters
were collected before stream flow measurements, or upstream of the location where stream
flows were measured to ensure the measurements were not affected by streambed
disturbance.
Field meters were calibrated daily according to factory instructions, with calibration results
recorded in the field notebook and/or on calibration forms. Field parameter measurements
were obtained directly in the stream; however, in high velocity areas pH was measured in a
clean container filled with sample water to limit possible errors due to streaming potentials.
Results were recorded in the field notebook and on standard sample forms.
2.3 WATER QUALITY SAMPLING
Water quality grab samples were collected from each surface water-monitoring site by
passing an uncapped sample container across the area of flow. Sample containers were
rinsed three times with sample water prior to sample collection. Water quality samples were
collected in containers and preserved as summarized in Table 4.
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TABLE 4. SAMPLE CONTAINER AND PRESERVATION REQUIREMENTS
Parameters Sample
Containers Preservative
Field Parameters
None None
Common Constituents 500 mL HDPE
Cool to 4°C
Nutrients (Nitrate+Nitrite) 250 mL HDPE
H2SO4 to pH <2 Cool to 4°C
Trace Constituents (total recoverable, except dissolved for aluminum)
250 mL HDPE
Filter dissolved samples (0.45 µm) HNO3 to pH <2
Cool to 4°C
Following preservation, samples were stored on ice in coolers at approximately 42°C for
transport. Dissolved trace constituents were filtered by passing unpreserved sample water
through a 0.45 µm filter using a peristaltic pump. All raw sample containers (used for
filtration), tubing and filters were discarded after one use to eliminate any cross-
contamination between samples.
All water quality sampling information, including sample sites, sample numbers, date and
time of sample collection, field parameter measurements, flow measurements, and other
notes and observations, were documented in waterproof ink in a dedicated project field
notebook, and on standard field forms. Photos were taken at each site to document
conditions at the time of sampling and to provide reference for future monitoring events.
2.4 FIELD QUALITY CONTROL
One field duplicate was collected to evaluate the reproducibility (precision) of the field
sampling protocols. Field duplicate samples are replicate samples from a single sampling
location submitted to a laboratory for the same set of analyses. For the purposes of this
project, field duplicates were collected by filling two sample containers consecutively from
the sampling location. Duplicates were submitted to the same laboratory, and were identified
with different sample numbers.
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3.0 GROUNDWATER MONITORING PROTOCOL
Groundwater monitoring included collection of field parameters and water quality samples
from eleven monitoring wells. The collection of groundwater samples from site monitoring
wells will generally consist of three steps:
1. Measurement of static water level;
2. Well purging and monitoring for field parameter stabilization; and
3. Water quality sample collection.
3.1 STATIC WATER LEVEL MEASUREMENT
Prior to collection of samples or removal/introduction of any equipment into the well, the
static water level was measured at each well using an electric water level probe to determine
the depth of groundwater below a specified measuring point (top of PVC well casing).
Water level measurements will be combined with surveyed measuring point elevations to
compute groundwater elevations at each monitoring point.
3.2 FIELD PARAMETERS AND WATER QUALITY SAMPLE COLLECTION
Dedicated HDPE tubing is installed in all eleven monitoring wells, and a 12-volt submersible
pump was used to purge and sample all monitoring wells with the exception of MW-3. Due
to the depth of water in well MW-3, a grundfos pump was used for purging and sampling.
Purging consisted of removing three well volumes while routinely monitoring field
parameters (pH, dissolved oxygen, temperature, specific conductance) during removal of
each well volume. Field meters were calibrated daily according to factory instructions, with
calibration results recorded on calibration forms.
Samples for laboratory analysis were collected after one of the following purge conditions
was met:
A minimum of three well volumes have been removed and successive field parameter
measurements agree to within the stability criteria given below; or
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At least five well volumes have been removed although field parameter stabilization
criteria are not yet met; or
The well has been pumped dry and allowed to recover sufficiently such that adequate
sample volumes for rinsing equipment and collecting samples can be removed.
Criteria for field parameter stabilization are as follows:
Parameter (Units) Stability Criteria pH (standard units) 0.1 s.u.
Water temperature (°C) 0.2 °C
Specific conductance (µmhos/cm) 5% (SC 100 µmhos/cm)
3% (SC > 100 µmhos/cm)
Dissolved oxygen (mg/L) 0.3 mg/L
NOTE: Stability criteria obtained from USGS National Field Manual for the Collection of Water Quality Data: Chapter A4, Collection of Water Samples (September 1999).
Following well purging, final field parameter measurements were collected and recorded,
and groundwater quality samples were obtained. Samples for trace constituents were filtered
through a 0.45µm filter prior to preservation, to allow analysis for the dissolved fraction.
Sample containers were rinsed three times with sample water prior to sample collection, then
preserved as appropriate for the intended analysis (e.g., nitric acid preservation to pH <2 for
metals analysis), and stored on ice in coolers at approximately 42°C during transport.
Groundwater sampling equipment reused between monitoring locations (12-volt or Grundfos
sampling pump and short piece of discharge line) were thoroughly decontaminated between
uses. Equipment decontamination consisted of the following steps:
Rinse with about two gallons of soapy water (Alconox or other non-phosphate
detergent); and
Rinse with about 2 gallons of distilled water.
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4.0 RESULTS
The field parameters and analytical results for the 2014 Second Quarter Monitoring are
presented in Table 5 (surface water) and Table 6 (groundwater). Below is a brief summary
of the monitoring results. The Laboratory Analytical Data Report for this monitoring event
is located in Appendix A.
4.1 STREAM DISCHARGE
Stream discharge measured at surface water sites in June 2014 ranged from 98.33 to 115.29
cfs in Sheep Creek and from 0.021 to 1.86 cfs in its tributaries when flow was encountered.
Dry conditions were observed at site SW-5.
4.2 GROUNDWATER LEVELS
Depth to water in the wells and piezometers ranged from 1.24 to 68.48 feet below the
measuring point (typically top of casing). Table 7 summarizes the depth to water levels and
calculated water level elevations for each groundwater level monitoring point. The
shallowest water was found in wells and piezometers completed in the Sheep Creek
Alluvium (MW-4A and PZ-01 through PZ-05) and in the shallow bedrock wells near the
contact of or beneath the Sheep Creek Alluvium (MW-1A, MW-4B). As expected, the
deepest groundwater levels were in wells completed in higher elevation areas (PW-1 and
SC12-116).
Groundwater elevations were calculated for each well from the depth to water level
measurements and measuring point elevations. The groundwater elevations for bedrock
wells were used to construct a bedrock potentiometric surface (Figure 2). Groundwater flow
in the bedrock is generally to the northeast towards the Sheep Creek alluvium with gradients
ranging from 0.07 to 0.04. The steepest gradient within the bedrock aquifer is located in the
northern portion of the study area near wells PW-1 and MW-3. The lower gradient is in the
area near the portal of the proposed decline.
TABLE 5. JUNE 2014 SURFACE WATER QUALITY DATA
Site Code SW-1 SW-2 SW-3 SW-4 SW-6 SW-6 DUP SW-7 SW-8 SW-9 SW-10 SW-11
Surface Water Human Health
Standard
Surface Water Aquatic Standard
(Chronic)Field Sample ID (BBC-1406-) -109 -110 -101 -102 -106 -107 -105 -108 -103 -104 -100
Flow (CFS) 115.29 98.33 0.31 NM 0.5 -- 0.021 1.09 1.86 1.67 1.59 -- --pH (s.u.) 8.13 8.22 8.17 7.8 7.93 -- 7.66 7.86 7.73 8.01 8.17 -- --Specific Conductance (µmhos/c 254 2.55 378 372 351 -- 399 398 425 425 401 -- --Temperature (C) 8.1 6.8 11.3 12.6 6.6 -- 6.2 7.7 5.3 5.6 10.8 -- --Dissolved Oxygen (mg/L) 10.21 10.53 9.37 8.27 9.9 -- 9.42 9.47 10.35 10.59 9.5 -- --
Total Suspended Solids 11 <10 <10 -- <10 <10 -- -- -- -- <10 -- --Total Dissolved Solids 145 144 220 -- 221 221 -- -- -- -- 233 -- --
Alkalinity as CaCO3 130 130 190 -- 200 210 -- -- -- -- 200 -- --Sulfate 3 3 13 -- 8 8 -- -- -- -- 14 -- --Chloride 1 1 1 -- <1 <1 -- -- -- -- <1 -- --Fluoride <0.1 <0.1 0.2 -- 0.1 0.1 -- -- -- -- 0.2 4 --Calcium 39 38 45 -- 50 51 -- -- -- -- 52 -- --Magnesium 10 9 22 -- 21 21 -- -- -- -- 23 -- --Sodium 2 2 2 -- 3 3 -- -- -- -- 2 -- --Potassium 1 1 <1 -- <1 <1 -- -- -- -- 1 -- --
Nitrate and Nitrite as N <0.01 <0.01 <0.01 -- 0.02 0.02 -- -- -- -- 0.04 10 --Nitrogen, Kjeldahl, Total as N <0.5 <0.5 <0.5 -- <0.5 <0.5 -- -- -- -- <0.5 -- --Total Nitrogen <0.5 <0.5 <0.5 -- <0.5 <0.5 -- -- -- -- <0.5 -- --Total Phosphorus 0.02 0.01 <0.01 -- 0.01 0.01 -- -- -- -- 0.03 -- --
Aluminum 0.025 0.029 <0.009 -- <0.009 <0.009 -- -- -- -- <0.009 -- 0.087
Antimony <0.0005 <0.0005 <0.0005 -- <0.0005 <0.0005 -- -- -- -- <0.0005 0.0056 --Arsenic <0.001 <0.001 <0.001 -- <0.001 <0.001 -- -- -- -- <0.001 0.01 0.15Barium 0.084 0.074 0.138 -- 0.105 0.102 -- -- -- -- 0.095 1 --Beryllium <0.0008 <0.0008 <0.0008 -- <0.0008 <0.0008 -- -- -- -- <0.0008 0.004 --Cadmium <0.00003 <0.00003 <0.00003 -- <0.00003 <0.00003 -- -- -- -- 0.00003 0.005 0.00022+Chromium <0.01 <0.01 <0.01 -- <0.01 <0.01 -- -- -- -- <0.01 0.1 --Cobalt <0.01 <0.01 <0.01 -- <0.01 <0.01 -- -- -- -- <0.01 -- --Copper <0.002 <0.002 <0.002 -- <0.002 <0.002 -- -- -- -- <0.002 1.3 0.0073+Iron 0.38 0.33 0.07 -- 0.23 0.24 -- -- -- -- 0.3 -- 1Lead <0.0003 <0.0003 <0.0003 -- <0.0003 <0.0003 -- -- -- -- 0.0003 0.015 0.0022+Manganese 0.017 0.011 <0.005 -- 0.02 0.019 -- -- -- -- 0.019 -- --Mercury <0.000005 <0.000005 <0.000005 -- <0.000005 <0.000005 -- -- -- -- <0.000005 0.00005 0.00091Molybdenum <0.002 <0.002 <0.002 -- <0.002 <0.002 -- -- -- -- <0.002 -- --Nickel <0.001 <0.001 <0.001 -- <0.001 <0.001 -- -- -- -- <0.001 0.1 0.041+Selenium <0.0002 <0.0002 <0.0002 -- <0.0002 <0.0002 -- -- -- -- <0.0002 0.05 0.005Silver <0.02 <0.02 <0.02 -- <0.02 <0.02 -- -- -- -- <0.02 0.1 --Strontium 0.116 0.119 0.107 -- 0.15 0.147 -- -- -- -- 0.181 4 --Thallium <0.0002 <0.0002 <0.0002 -- <0.0002 <0.0002 -- -- -- -- <0.0002 0.00024 --Uranium <0.008 <0.008 <0.008 -- <0.008 <0.008 -- -- -- -- <0.008 0.03 --Zinc 0.002 <0.002 <0.002 -- <0.002 <0.002 -- -- -- -- 0.003 2 0.094+
NOTES: concentrations that are in bold exceed DEQ 7 standards for Human Health and/or Aquatic (chronic)
All information summarized from MDEQ Circular DEQ-7 (October 2012 Printing). Surface water standards for metals and metalloids are based on total recoverable concentrations, except for aluminum is dissolved.
FIELD PARAMETERS
+ = hardness dependent parameter values shown for a hardness of 75 mg/L; which is approximately the lowest hardness recorded in the baseline data. Concentrations that are in bold are based on hardness of individual samples.
DISSOLVED TRACE CONSTITUENTS (mg/L)
TOTAL RECOVERABLE TRACE CONSTITUENTS (mg/L)
NUTRIENTS (mg/L)
COMMON IONS (mg/L)
GENERAL PARAMETERS (mg/L)
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TABLE 6. JUNE 2014 GROUNDWATER QUALITY DATA
Site Code MW-1A MW-1B MW-2A MW-2B MW-3 MW-3 DUP MW-4A MW-4B MW-6A MW-6B MW-7 MW-8
Groundwater Human Health Standard
Field Sample ID (BBC-1406-) -207 -206 -205 -204 -210 -211 -209 -208 -200 -201 -202 -203FIELD PARAMETERSStatic Water Level 2.29 21.19 41.89 41.51 37.4 -- 4.21 3.81 7.06 10.24 30.92 28.31 --pH (s.u.) 7.12 6.19 7.24 7.28 6.97 -- 7.26 7.45 7.06 7.51 7.45 7.87 --Specific Conductance (µmhos/cm) 346 616 386 513 871 -- 507 487 416 447 550 316 --Temperature (C) 6.9 7.9 7.2 7.6 9.8 -- 4.5 6.2 5.6 6.4 7.4 7 --Dissolved Oxygen (mg/L) 9.63 0.24 7.07 0.57 0.11 -- 2.36 0.28 7.32 4.43 0.69 0.2 --GENERAL PARAMETERSTotal Suspended Solids 30 <10 <10 <10 <10 <10 <10 <10 98 54 111 17 --Total Dissolved Solids 188 411 213 292 600 604 277 265 239 266 330 165 --COMMON IONS (mg/L) Alkalinity as CaCO3 170 83 190 230 210 210 260 250 210 220 230 150 --Sulfate 9 230 16 43 280 280 13 15 <1 16 63 12 --Chloride 1 1 1 1 1 1 2 1 1 1 4 <1 --Fluoride 0.2 0.2 0.3 0.3 0.7 0.7 0.1 0.1 0.2 0.5 0.4 0.3 4Calcium 42 57 44 56 83 84 75 70 53 47 60 27 --Magnesium 18 30 23 31 54 56 21 22 24 23 39 24 --Sodium 2 5 3 3 16 16 3 2 3 15 3 3 --Potassium 1 3 1 2 3 3 1 1 <1 1 1 <1 --NUTRIENTS (mg/L)Nitrate and Nitrite as N 0.4 <0.01 0.18 <0.01 <0.01 <0.01 <0.01 <0.01 0.15 0.12 <0.01 <0.01 10Nitrogen, Kjeldahl, Total as N <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 --Total Nitrogen <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 --Total Phosphorus 0.02 0.03 <0.01 <0.01 0.01 0.01 <0.01 <0.01 0.06 0.04 0.04 0.01 --DISSOLVED TRACE CONSTITUENTS (mg/L)Aluminum 0.016 <0.009 <0.009 <0.009 <0.009 <0.009 <0.009 <0.009 0.01 <0.009 <0.009 <0.009 --Antimony <0.0005 0.0007 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 0.0014 0.0011 0.006Arsenic <0.001 0.059 <0.001 0.003 0.067 0.067 <0.001 <0.001 <0.001 <0.001 0.002 0.003 0.01Barium 0.16 0.014 0.08 0.028 0.01 0.01 0.178 0.133 0.16 0.11 0.052 0.073 1Beryllium <0.0008 <0.0008 <0.0008 <0.0008 <0.0008 <0.0008 <0.0008 <0.0008 <0.0008 <0.0008 <0.0008 <0.0008 0.004Cadmium <0.00003 <0.00003 <0.00003 <0.00003 <0.00003 <0.00003 <0.00003 <0.00003 <0.00003 <0.00003 <0.00003 <0.00003 0.005Chromium <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.1Cobalt <0.01 0.03 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 --Copper 0.004 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 1.3Iron 0.03 21.5 <0.02 0.24 1.2 1.21 0.03 <0.02 <0.02 <0.02 0.02 0.05 --Lead <0.0003 <0.0003 <0.0003 <0.0003 <0.0003 <0.0003 <0.0003 <0.0003 <0.0003 <0.0003 <0.0003 <0.0003 0.015Manganese <0.005 0.083 <0.005 0.019 0.021 0.02 0.167 <0.005 <0.005 0.03 0.107 0.109 --Mercury <0.000005 <0.000005 <0.000005 <0.000005 <0.000005 <0.000005 <0.000005 <0.000005 <0.000005 <0.000005 <0.000005 <0.000005 0.002Molybdenum <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 0.003 0.005 --Nickel <0.001 0.012 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 0.1Selenium <0.0002 <0.0002 <0.0002 0.0003 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 0.05Silver <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 0.1Strontium 0.0983 1.62 0.0927 0.106 15 15.1 0.167 0.183 0.149 0.198 0.169 0.0897 4Thallium 0.0006 0.0126 0.0003 0.0024 0.0004 0.0004 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 0.002Uranium <0.008 <0.008 <0.008 <0.008 <0.008 <0.008 <0.008 <0.008 <0.008 <0.008 <0.008 <0.008 0.03Zinc <0.002 0.017 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 2
NOTES: concentrations that are in bold exceed DEQ 7 standards for Human HealthAll information summarized from MDEQ Circular DEQ-7 (October 2012 Printing).
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Easting (meters)
Northing (meters)
Ground Surface Elev.
Measuring Point Elev.
Depth to Water Level
Water Level Elev.
(feet, amsl) (feet, amsl) (feet, bmp) (feet, amsl)
MW-1A 506935.22 5180841.55 5635.81 5637.73 2.29 5635.44
MW-1B 506934.19 5180845.46 5636.14 5637.9 21.19 5616.71
MW-2A 506598.18 5180331.93 5743.72 5745.31 41.89 5703.42
MW-2B 506596.96 5180328.73 5743.44 5745.53 41.51 5704.02
MW-3 506484.07 5180740.22 5760.06 5762.17 37.4 5724.77
MW-4A 507201.47 5180855.43 5610.12 5612.12 4.21 5607.91
MW-4B 507200.12 5180858.49 5610.07 5612.07 3.81 5608.26
MW-6A 507809.18 5179492.9 5680.08 5681.87 7.06 5674.81
MW-6B 507792.76 5179490.7 5683.41 5685.31 10.24 5675.07
MW-7 507451.7 5179500.7 5747.48 5749.46 30.92 5718.54
MW-8 507036 5179398.3 5809.1 5810.93 28.31 5782.62
PW-1 506301.42 5180698.4 5912.07 5913.74 68.48 5845.26
PW-2 506443.15 5180865 5793.08 5794.88 57.12 5737.76
PW-3 506846.43 5180479.42 5655.21 5657.42 12.61 5644.81
PW-4 506901.79 5180688.26 5678.13 5680.01 50.26 5629.75
PZ-01 507650 5180256 5628.69 5630.34 2.62 5627.72
PZ-02 507400.7 5180779 5611.81 5613.51 NM --
PZ-03 507249.2 5180619 5616.08 5617.74 5.02 5612.72
PZ-04 506991.7 5181111 5599.34 5602.7 1.24 5601.46
PZ-05 507080 5181215 5598.16 5599.79 2.68 5597.11
PZ-07A 506258.39 5180074.65 5776.57 5777.5 5.14 5772.36
PZ-07B 506258.47 5180075 5776.57 5777.59 6.61 5770.98
PZ-08 507090.31 5180573.81 5618.9 5621.29 3.43 5617.86
PZ-09 507883.78 5180178.58 5634.73 5637.27 4.31 5632.96
Piezometers
TABLE 7. JUNE 2014 WATER LEVEL DATA
Well Name
UTM- WGS 1984 Zone 12 North
Monitoring Wells
Test Wells
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5800
5780
5760
5740
57205700 5680
5660
5640
5620
MW1A MW1B
MW2A
MW2B
MW3
MW4A
MW4B
MW-6A
MW-6BMW-7
MW-8
5635.44 5616.71
5703.42
5704.02
5724.77
5607.91
5608.26
5674.81
5675.075718.54
5782.62
5845.26
5737.76
5644.81
5629.75
PW1
PW2
PW3
PW4
LEGEND
Monitoring Well/Water Elevation
Pumping Well/Water Elevation
Dry Stream Channel
Potentiometric Contour
ProposedDecline
Scale (feet)
K:\P
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ct\1
1048
\WR
M R
epor
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014\
Sec
ond
Qua
rter\F
ig2_
Pot
entio
met
ric M
ap.s
rf
Perched groundwaternot used in development of potentiometric surface
PW-1
0 1000 2000
Figure 2June 2014 Potentiometric Map
Black Butte Copper ProjectMeagher County, Montana
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4.3 WATER QUALITY DATA
Surface water quality was relatively similar at all of the monitoring sites. Water samples
showed near neutral to slightly basic pH (7.66 – 8.22s.u.), relatively low total dissolved
solids (144 mg\L to 233 mg/L), and were calcium bicarbonate type water. Numerous trace
constituents were detected at low levels at one or more sites, including: dissolved aluminum
and total recoverable barium, iron, lead, manganese, strontium, uranium, and zinc (Table 5).
Groundwater quality showed some differences related to well depths and completion zones.
Wells MW-1A, MW-2A and MW-4A are located in the shallow unconsolidated overburden
deposits and exhibited a neutral pH (7.12-7.26 s.u.), low sulfate concentration (9 to 16 mg/L)
and low or non-detectable concentrations of most dissolved trace constituent (Table 6). Well
MW-1B has historically had similar water quality as wells completed in the sulfide ore zone
(MW-3). These wells had a slightly lower pH (6.19 to 6.97 s.u.) and higher concentrations
of dissolved solids (411 to 600 mg/L) and sulfate (230 to 280 mg/L) compared to the other
wells. Dissolved trace constituents that are present at detectable concentrations in MW-1B
and MW-3 include antimony, arsenic, barium, cobalt, iron, manganese, nickel, strontium,
thallium, and zinc (Table 5). Wells located in the shallow bedrock above the sulfide ore
zones include MW-2B, MW-4B, MW-6A, MW-6B, MW-7 and MW-8. These wells had
near neutral pH (7.06-7.87 s.u.), sulfate concentrations of <1 to 63 mg/L, and low
concentrations of dissolved trace constituents including aluminum, antimony, arsenic,
barium, iron, manganese, molybdenum, selenium, strontium and thallium.
June 2014 water quality results were compared to human health and aquatic life (chronic)
standards per MDEQ Circular DEQ-7 (MDEQ, 2012). No surface water concentrations
exceeded DEQ-7 surface water human health standards or chronic aquatic life standards in
June 2014 (Table 5). Groundwater constituents exceeding DEQ-7 human health standards in
June 2014 include strontium at MW-3 and thallium at MW-1B and MW-2B.
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4.4 FIELD QUALITY CONTROL
Quality control and quality assurance for the June 2014 monitoring event were evaluated
using results of two field duplicate sample (collected at surface water site SW-6 and
groundwater site MW-3) and standard laboratory QC samples. For the field duplicate
samples, all parameters were within control limits. For laboratory QC samples, two matrix
spikes were outside the recovery control limits of 90-110% for total kjeldahl nitrogen and
nitrate plus nitrite. The QC data did not indicate any systematic data quality issues for the
June 2014 data set. A summary of the June 2014 QA/QC Review is included in Appendix B.
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5.0 REFERENCES
EPA, 1983. Methods for Chemical Analysis of Water and Wastes. EPA-600/14-79-020.
Revised March 1983. MDEQ, 2012. Circular DEQ-7, Montana Numeric Water Quality Standards, October 2012. USGS, 2010. Discharge Measurements at ????, 2010. Stations: USGS Techniques and Methods Book 3, Chapter A8, 87 p. By D.P. Turnipseed
and V.B. Sauer.
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APPENDIX A
LABORATORY ANALYTICAL REPORT
ANALYTICAL SUMMARY REPORTANALYTICAL SUMMARY REPORTANALYTICAL SUMMARY REPORTANALYTICAL SUMMARY REPORT
Lab ID Client Sample ID Collect Date Receive Date Matrix Test
H14060256-001 BBC-1406-200 06/09/14 12:05 06/12/14 Aqueous Metals by ICP/ICPMS, DissolvedAlkalinityConductivityMercury, DissolvedFluorideAnions by Ion ChromatographyNitrogen, Nitrate + NitriteNitrogen, Total KjeldahlNitrogen, Total (TKN+NO3+NO2)Digestion, Mercury by CVAADigestion, Total P WaterTKN PrepPhosphorus, TotalSolids, Total DissolvedSolids, Total Suspended
H14060256-002 BBC-1406-201 06/09/14 12:40 06/12/14 Aqueous Same As Above
H14060256-003 BBC-1406-202 06/09/14 13:10 06/12/14 Aqueous Same As Above
H14060256-004 BBC-1406-203 06/09/14 14:05 06/12/14 Aqueous Same As Above
H14060256-005 BBC-1406-204 06/09/14 15:20 06/12/14 Aqueous Same As Above
H14060256-006 BBC-1406-205 06/09/14 15:55 06/12/14 Aqueous Same As Above
H14060256-007 BBC-1406-206 06/09/14 17:20 06/12/14 Aqueous Same As Above
H14060256-008 BBC-1406-207 06/09/14 18:00 06/12/14 Aqueous Same As Above
H14060256-009 BBC-1406-208 06/10/14 9:20 06/12/14 Aqueous Same As Above
H14060256-010 BBC-1406-209 06/10/14 9:55 06/12/14 Aqueous Same As Above
H14060256-011 BBC-1406-210 06/10/14 14:35 06/12/14 Aqueous Same As Above
H14060256-012 BBC-1406-211 06/10/14 14:50 06/12/14 Aqueous Same As Above
H14060256-013 BBC-1406-212 06/11/14 14:00 06/12/14 Aqueous Same As Above
H14060256-014 BBC-1406-213 06/11/14 14:30 06/12/14 Aqueous Same As Above
Tintina Resources Inc
Project Name: 11048 Black Butte Copper Project
Work Order: H14060256
PO Box 431
White Sulphur Springs, MT 59604
June 26, 2014
H944 - Black ButteQuote ID:
Energy Laboratories Inc Helena MT received the following 21 samples for Tintina Resources Inc on 6/12/2014 for analysis.
Page 1 of 52
ANALYTICAL SUMMARY REPORTANALYTICAL SUMMARY REPORTANALYTICAL SUMMARY REPORTANALYTICAL SUMMARY REPORT
The analyses presented in this report were performed by Energy Laboratories, Inc., 3161 E. Lyndale Ave., Helena, MT 59604, unless otherwise noted. Any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QA/QC Summary Report, or the Case Narrative.
The results as reported relate only to the item(s) submitted for testing.
If you have any questions regarding these test results, please call.
Report Approved By:
H14060256-015 BBC-1406-100 06/10/14 11:30 06/12/14 Aqueous Metals by ICP/ICPMS, DissolvedMetals by ICP/ICPMS, Tot. Rec.AlkalinityConductivityMercury, Total RecoverableFluorideAnions by Ion ChromatographyNitrogen, Nitrate + NitriteNitrogen, Total KjeldahlNitrogen, Total (TKN+NO3+NO2)Metals Digestion by EPA 200.2Digestion, Mercury by CVAADigestion, Total P WaterTKN PrepPhosphorus, TotalSolids, Total DissolvedSolids, Total Suspended
H14060256-016 BBC-1406-101 06/10/14 15:45 06/12/14 Aqueous Same As Above
H14060256-017 BBC-1406-106 06/11/14 9:20 06/12/14 Aqueous Same As Above
H14060256-018 BBC-1406-107 06/11/14 9:45 06/12/14 Aqueous Same As Above
H14060256-019 BBC-1406-109 06/11/14 11:10 06/12/14 Aqueous Same As Above
H14060256-020 BBC-1406-110 06/11/14 12:00 06/12/14 Aqueous Same As Above
H14060256-021 BBC-1406-111 06/11/14 12:30 06/12/14 Aqueous Same As Above
Page 2 of 52
Project: 11048 Black Butte Copper Project
CLIENT: Tintina Resources Inc
Work Order: H14060256 CASE NARRATIVE
06/26/14Report Date:
Tests associated with analyst identified as ELI-B were subcontracted to Energy Laboratories, 1120 S. 27th St., Billings, MT, EPA Number MT00005.
Page 3 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-001
Client Sample ID: BBC-1406-200
Collection Date: 06/09/14 12:05
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/13/14 09:20 / cmm10mg/L98Solids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:43 / blm10mg/L239Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 17:38 / SRW4mg/L210Alkalinity, Total as CaCO3 A2320 B
06/14/14 00:07 / cmm1mg/L1Chloride E300.0
06/14/14 00:07 / cmm1mg/LNDSulfate E300.0
06/17/14 10:37 / SRW0.1mg/L0.2Fluoride A4500-F C4
NUTRIENTS
06/19/14 11:30 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:06 / cmm0.01mg/L0.15Nitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:20 / cmm0.01mg/L0.06Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/18/14 23:53 / dck0.009mg/L0.010Aluminum E200.8
06/18/14 23:53 / dck0.0005mg/LNDAntimony E200.8
06/18/14 23:53 / dck0.001mg/LNDArsenic E200.8
06/18/14 23:53 / dck0.003mg/L0.160Barium E200.8
06/18/14 23:53 / dck0.0008mg/LNDBeryllium E200.8
06/18/14 23:53 / dck0.00003mg/LNDCadmium E200.8
06/13/14 13:25 / sld1mg/L53Calcium E200.7
06/18/14 23:53 / dck0.01mg/LNDChromium E200.8
06/18/14 23:53 / dck0.01mg/LNDCobalt E200.8
06/18/14 23:53 / dck0.002mg/LNDCopper E200.8
06/18/14 23:53 / dck0.02mg/LNDIron E200.8
06/18/14 23:53 / dck0.0003mg/LNDLead E200.8
06/13/14 13:25 / sld1mg/L24Magnesium E200.7
06/18/14 23:53 / dck0.005mg/LNDManganese E200.8
06/25/14 10:57 / sbk5E-06mg/LNDMercury E245.1
06/18/14 23:53 / dck0.002mg/LNDMolybdenum E200.8
06/18/14 23:53 / dck0.001mg/LNDNickel E200.8
06/13/14 13:25 / sld1mg/LNDPotassium E200.7
06/20/14 20:19 / dck0.0002mg/LNDSelenium E200.8
06/18/14 23:53 / dck0.02mg/LNDSilver E200.8
06/13/14 13:25 / sld1mg/L3Sodium E200.7
06/18/14 23:53 / dck0.0002mg/L0.149Strontium E200.8
06/18/14 23:53 / dck0.0002mg/LNDThallium E200.8
06/18/14 23:53 / dck0.008mg/LNDUranium E200.8
06/18/14 23:53 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 4 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-002
Client Sample ID: BBC-1406-201
Collection Date: 06/09/14 12:40
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/13/14 09:21 / cmm10mg/L54Solids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:52 / blm10mg/L266Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 17:44 / SRW4mg/L220Alkalinity, Total as CaCO3 A2320 B
06/14/14 00:18 / cmm1mg/L1Chloride E300.0
06/14/14 00:18 / cmm1mg/L16Sulfate E300.0
06/17/14 10:39 / SRW0.1mg/L0.5Fluoride A4500-F C4
NUTRIENTS
06/19/14 11:32 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:09 / cmm0.01mg/L0.12Nitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:21 / cmm0.01mg/L0.04Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 00:20 / dck0.009mg/LNDAluminum E200.8
06/19/14 00:20 / dck0.0005mg/LNDAntimony E200.8
06/19/14 00:20 / dck0.001mg/LNDArsenic E200.8
06/19/14 00:20 / dck0.003mg/L0.110Barium E200.8
06/19/14 00:20 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 00:20 / dck0.00003mg/LNDCadmium E200.8
06/13/14 13:47 / sld1mg/L47Calcium E200.7
06/19/14 00:20 / dck0.01mg/LNDChromium E200.8
06/19/14 00:20 / dck0.01mg/LNDCobalt E200.8
06/19/14 00:20 / dck0.002mg/LNDCopper E200.8
06/19/14 00:20 / dck0.02mg/LNDIron E200.8
06/19/14 00:20 / dck0.0003mg/LNDLead E200.8
06/13/14 13:47 / sld1mg/L23Magnesium E200.7
06/19/14 00:20 / dck0.005mg/L0.030Manganese E200.8
06/25/14 11:02 / sbk5E-06mg/LNDMercury E245.1
06/19/14 00:20 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 00:20 / dck0.001mg/LNDNickel E200.8
06/13/14 13:47 / sld1mg/L1Potassium E200.7
06/20/14 20:23 / dck0.0002mg/LNDSelenium E200.8
06/19/14 00:20 / dck0.02mg/LNDSilver E200.8
06/13/14 13:47 / sld1mg/L15Sodium E200.7
06/19/14 00:20 / dck0.0002mg/L0.198Strontium E200.8
06/19/14 00:20 / dck0.0002mg/LNDThallium E200.8
06/19/14 00:20 / dck0.008mg/LNDUranium E200.8
06/19/14 00:20 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 5 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-003
Client Sample ID: BBC-1406-202
Collection Date: 06/09/14 13:10
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/13/14 09:03 / cmm10mg/L111Solids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:42 / blm10mg/L330Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 17:50 / SRW4mg/L230Alkalinity, Total as CaCO3 A2320 B
06/14/14 00:29 / cmm1mg/L4Chloride E300.0
06/14/14 00:29 / cmm1mg/L63Sulfate E300.0
06/17/14 10:40 / SRW0.1mg/L0.4Fluoride A4500-F C4
NUTRIENTS
06/19/14 11:33 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:11 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:22 / cmm0.01mg/L0.04Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 00:24 / dck0.009mg/LNDAluminum E200.8
06/19/14 00:24 / dck0.0005mg/L0.0014Antimony E200.8
06/19/14 00:24 / dck0.001mg/L0.002Arsenic E200.8
06/19/14 00:24 / dck0.003mg/L0.052Barium E200.8
06/19/14 00:24 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 00:24 / dck0.00003mg/LNDCadmium E200.8
06/13/14 13:50 / sld1mg/L60Calcium E200.7
06/19/14 00:24 / dck0.01mg/LNDChromium E200.8
06/19/14 00:24 / dck0.01mg/LNDCobalt E200.8
06/19/14 00:24 / dck0.002mg/LNDCopper E200.8
06/19/14 00:24 / dck0.02mg/L0.02Iron E200.8
06/19/14 00:24 / dck0.0003mg/LNDLead E200.8
06/13/14 13:50 / sld1mg/L39Magnesium E200.7
06/19/14 00:24 / dck0.005mg/L0.107Manganese E200.8
06/25/14 11:06 / sbk5E-06mg/LNDMercury E245.1
06/19/14 00:24 / dck0.002mg/L0.003Molybdenum E200.8
06/19/14 00:24 / dck0.001mg/LNDNickel E200.8
06/13/14 13:50 / sld1mg/L1Potassium E200.7
06/20/14 20:27 / dck0.0002mg/LNDSelenium E200.8
06/19/14 00:24 / dck0.02mg/LNDSilver E200.8
06/13/14 13:50 / sld1mg/L3Sodium E200.7
06/19/14 00:24 / dck0.0002mg/L0.169Strontium E200.8
06/19/14 00:24 / dck0.0002mg/LNDThallium E200.8
06/19/14 00:24 / dck0.008mg/LNDUranium E200.8
06/19/14 00:24 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 6 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-004
Client Sample ID: BBC-1406-203
Collection Date: 06/09/14 14:05
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/13/14 09:07 / cmm10mg/L17Solids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:48 / blm10mg/L165Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 17:57 / SRW4mg/L150Alkalinity, Total as CaCO3 A2320 B
06/14/14 00:40 / cmm1mg/LNDChloride E300.0
06/14/14 00:40 / cmm1mg/L12Sulfate E300.0
06/17/14 10:41 / SRW0.1mg/L0.3Fluoride A4500-F C4
NUTRIENTS
06/19/14 11:34 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:12 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:23 / cmm0.01mg/L0.01Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 00:28 / dck0.009mg/LNDAluminum E200.8
06/19/14 00:28 / dck0.0005mg/L0.0011Antimony E200.8
06/19/14 00:28 / dck0.001mg/L0.003Arsenic E200.8
06/19/14 00:28 / dck0.003mg/L0.073Barium E200.8
06/19/14 00:28 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 00:28 / dck0.00003mg/LNDCadmium E200.8
06/13/14 13:54 / sld1mg/L27Calcium E200.7
06/19/14 00:28 / dck0.01mg/LNDChromium E200.8
06/19/14 00:28 / dck0.01mg/LNDCobalt E200.8
06/19/14 00:28 / dck0.002mg/LNDCopper E200.8
06/19/14 00:28 / dck0.02mg/L0.05Iron E200.8
06/19/14 00:28 / dck0.0003mg/LNDLead E200.8
06/13/14 13:54 / sld1mg/L24Magnesium E200.7
06/19/14 00:28 / dck0.005mg/L0.109Manganese E200.8
06/25/14 11:18 / sbk5E-06mg/LNDMercury E245.1
06/19/14 00:28 / dck0.002mg/L0.005Molybdenum E200.8
06/19/14 00:28 / dck0.001mg/LNDNickel E200.8
06/13/14 13:54 / sld1mg/LNDPotassium E200.7
06/20/14 20:32 / dck0.0002mg/LNDSelenium E200.8
06/19/14 00:28 / dck0.02mg/LNDSilver E200.8
06/13/14 13:54 / sld1mg/L3Sodium E200.7
06/19/14 00:28 / dck0.0002mg/L0.0897Strontium E200.8
06/19/14 00:28 / dck0.0002mg/LNDThallium E200.8
06/19/14 00:28 / dck0.008mg/LNDUranium E200.8
06/19/14 00:28 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 7 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-005
Client Sample ID: BBC-1406-204
Collection Date: 06/09/14 15:20
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/13/14 09:13 / cmm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 12:22 / blm10mg/L292Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 18:02 / SRW4mg/L230Alkalinity, Total as CaCO3 A2320 B
06/14/14 00:51 / cmm1mg/L1Chloride E300.0
06/14/14 00:51 / cmm1mg/L43Sulfate E300.0
06/17/14 10:43 / SRW0.1mg/L0.3Fluoride A4500-F C4
NUTRIENTS
06/18/14 11:00 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:13 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:24 / cmm0.01mg/LNDPhosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 00:33 / dck0.009mg/LNDAluminum E200.8
06/19/14 00:33 / dck0.0005mg/LNDAntimony E200.8
06/19/14 00:33 / dck0.001mg/L0.003Arsenic E200.8
06/19/14 00:33 / dck0.003mg/L0.028Barium E200.8
06/19/14 00:33 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 00:33 / dck0.00003mg/LNDCadmium E200.8
06/13/14 13:58 / sld1mg/L56Calcium E200.7
06/19/14 00:33 / dck0.01mg/LNDChromium E200.8
06/19/14 00:33 / dck0.01mg/LNDCobalt E200.8
06/19/14 00:33 / dck0.002mg/LNDCopper E200.8
06/19/14 00:33 / dck0.02mg/L0.24Iron E200.8
06/19/14 00:33 / dck0.0003mg/LNDLead E200.8
06/13/14 13:58 / sld1mg/L31Magnesium E200.7
06/19/14 00:33 / dck0.005mg/L0.019Manganese E200.8
06/25/14 11:23 / sbk5E-06mg/LNDMercury E245.1
06/19/14 00:33 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 00:33 / dck0.001mg/LNDNickel E200.8
06/13/14 13:58 / sld1mg/L2Potassium E200.7
06/20/14 20:36 / dck0.0002mg/L0.0003Selenium E200.8
06/19/14 00:33 / dck0.02mg/LNDSilver E200.8
06/13/14 13:58 / sld1mg/L3Sodium E200.7
06/19/14 00:33 / dck0.0002mg/L0.106Strontium E200.8
06/19/14 00:33 / dck0.0002mg/L0.0024Thallium E200.8
06/19/14 00:33 / dck0.008mg/LNDUranium E200.8
06/19/14 00:33 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 8 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-006
Client Sample ID: BBC-1406-205
Collection Date: 06/09/14 15:55
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/13/14 09:18 / cmm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 12:26 / blm10mg/L213Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 18:09 / SRW4mg/L190Alkalinity, Total as CaCO3 A2320 B
06/14/14 01:25 / cmm1mg/L1Chloride E300.0
06/14/14 01:25 / cmm1mg/L16Sulfate E300.0
06/17/14 10:44 / SRW0.1mg/L0.3Fluoride A4500-F C4
NUTRIENTS
06/18/14 11:01 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:14 / cmm0.01mg/L0.18Nitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:25 / cmm0.01mg/LNDPhosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 00:37 / dck0.009mg/LNDAluminum E200.8
06/19/14 00:37 / dck0.0005mg/LNDAntimony E200.8
06/19/14 00:37 / dck0.001mg/LNDArsenic E200.8
06/19/14 00:37 / dck0.003mg/L0.080Barium E200.8
06/19/14 00:37 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 00:37 / dck0.00003mg/LNDCadmium E200.8
06/13/14 14:02 / sld1mg/L44Calcium E200.7
06/19/14 00:37 / dck0.01mg/LNDChromium E200.8
06/19/14 00:37 / dck0.01mg/LNDCobalt E200.8
06/19/14 00:37 / dck0.002mg/LNDCopper E200.8
06/19/14 00:37 / dck0.02mg/LNDIron E200.8
06/19/14 00:37 / dck0.0003mg/LNDLead E200.8
06/13/14 14:02 / sld1mg/L23Magnesium E200.7
06/19/14 00:37 / dck0.005mg/LNDManganese E200.8
06/25/14 11:27 / sbk5E-06mg/LNDMercury E245.1
06/19/14 00:37 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 00:37 / dck0.001mg/LNDNickel E200.8
06/13/14 14:02 / sld1mg/L1Potassium E200.7
06/20/14 20:40 / dck0.0002mg/LNDSelenium E200.8
06/19/14 00:37 / dck0.02mg/LNDSilver E200.8
06/13/14 14:02 / sld1mg/L3Sodium E200.7
06/19/14 00:37 / dck0.0002mg/L0.0927Strontium E200.8
06/19/14 00:37 / dck0.0002mg/L0.0003Thallium E200.8
06/19/14 00:37 / dck0.008mg/LNDUranium E200.8
06/19/14 00:37 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 9 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-007
Client Sample ID: BBC-1406-206
Collection Date: 06/09/14 17:20
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/13/14 09:21 / cmm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:44 / blm10mg/L411Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 18:17 / SRW4mg/L83Alkalinity, Total as CaCO3 A2320 B
06/14/14 01:58 / cmm1mg/L1Chloride E300.0
06/14/14 01:58 / cmm1mg/L230Sulfate E300.0
06/17/14 10:45 / SRW0.1mg/L0.2Fluoride A4500-F C4
NUTRIENTS
06/18/14 11:02 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:15 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:26 / cmm0.01mg/L0.03Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 00:42 / dck0.009mg/LNDAluminum E200.8
06/19/14 00:42 / dck0.0005mg/L0.0007Antimony E200.8
06/19/14 00:42 / dck0.001mg/L0.059Arsenic E200.8
06/19/14 00:42 / dck0.003mg/L0.014Barium E200.8
06/19/14 00:42 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 00:42 / dck0.00003mg/LNDCadmium E200.8
06/13/14 14:06 / sld1mg/L57Calcium E200.7
06/19/14 00:42 / dck0.01mg/LNDChromium E200.8
06/19/14 00:42 / dck0.01mg/L0.03Cobalt E200.8
06/19/14 00:42 / dck0.002mg/LNDCopper E200.8
06/13/14 14:06 / sld0.02mg/L21.5Iron E200.7
06/19/14 00:42 / dck0.0003mg/LNDLead E200.8
06/13/14 14:06 / sld1mg/L30Magnesium E200.7
06/19/14 00:42 / dck0.005mg/L0.083Manganese E200.8
06/25/14 11:40 / sbk5E-06mg/LNDMercury E245.1
06/19/14 00:42 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 00:42 / dck0.001mg/L0.012Nickel E200.8
06/13/14 14:06 / sld1mg/L3Potassium E200.7
06/20/14 20:45 / dck0.0002mg/LNDSelenium E200.8
06/19/14 00:42 / dck0.02mg/LNDSilver E200.8
06/13/14 14:06 / sld1mg/L5Sodium E200.7
D 06/13/14 14:06 / sld0.0003mg/L1.62Strontium E200.7
06/19/14 00:42 / dck0.0002mg/L0.0126Thallium E200.8
06/19/14 00:42 / dck0.008mg/LNDUranium E200.8
06/19/14 00:42 / dck0.002mg/L0.017Zinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
D - RL increased due to sample matrix.
Page 10 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-008
Client Sample ID: BBC-1406-207
Collection Date: 06/09/14 18:00
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/13/14 09:21 / cmm10mg/L30Solids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:45 / blm10mg/L188Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 18:24 / SRW4mg/L170Alkalinity, Total as CaCO3 A2320 B
06/14/14 02:09 / cmm1mg/L1Chloride E300.0
06/14/14 02:09 / cmm1mg/L9Sulfate E300.0
06/17/14 10:45 / SRW0.1mg/L0.2Fluoride A4500-F C4
NUTRIENTS
06/18/14 11:04 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:17 / cmm0.01mg/L0.40Nitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:29 / cmm0.01mg/L0.02Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 00:46 / dck0.009mg/L0.016Aluminum E200.8
06/19/14 00:46 / dck0.0005mg/LNDAntimony E200.8
06/19/14 00:46 / dck0.001mg/LNDArsenic E200.8
06/19/14 00:46 / dck0.003mg/L0.160Barium E200.8
06/19/14 00:46 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 00:46 / dck0.00003mg/LNDCadmium E200.8
06/13/14 14:09 / sld1mg/L42Calcium E200.7
06/19/14 00:46 / dck0.01mg/LNDChromium E200.8
06/19/14 00:46 / dck0.01mg/LNDCobalt E200.8
06/19/14 00:46 / dck0.002mg/L0.004Copper E200.8
06/19/14 00:46 / dck0.02mg/L0.03Iron E200.8
06/19/14 00:46 / dck0.0003mg/LNDLead E200.8
06/13/14 14:09 / sld1mg/L18Magnesium E200.7
06/19/14 00:46 / dck0.005mg/LNDManganese E200.8
06/25/14 11:44 / sbk5E-06mg/LNDMercury E245.1
06/19/14 00:46 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 00:46 / dck0.001mg/LNDNickel E200.8
06/19/14 00:46 / dck1mg/L1Potassium E200.8
06/20/14 20:49 / dck0.0002mg/LNDSelenium E200.8
06/19/14 00:46 / dck0.02mg/LNDSilver E200.8
06/13/14 14:09 / sld1mg/L2Sodium E200.7
06/19/14 00:46 / dck0.0002mg/L0.0983Strontium E200.8
06/19/14 00:46 / dck0.0002mg/L0.0006Thallium E200.8
06/19/14 00:46 / dck0.008mg/LNDUranium E200.8
06/20/14 20:49 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 11 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-009
Client Sample ID: BBC-1406-208
Collection Date: 06/10/14 09:20
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/13/14 09:22 / cmm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:45 / blm10mg/L265Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 18:29 / SRW4mg/L250Alkalinity, Total as CaCO3 A2320 B
06/14/14 02:20 / cmm1mg/L1Chloride E300.0
06/14/14 02:20 / cmm1mg/L15Sulfate E300.0
06/17/14 10:46 / SRW0.1mg/L0.1Fluoride A4500-F C4
NUTRIENTS
06/18/14 11:05 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:18 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:30 / cmm0.01mg/LNDPhosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 00:50 / dck0.009mg/LNDAluminum E200.8
06/19/14 00:50 / dck0.0005mg/LNDAntimony E200.8
06/19/14 00:50 / dck0.001mg/LNDArsenic E200.8
06/19/14 00:50 / dck0.003mg/L0.133Barium E200.8
06/19/14 00:50 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 00:50 / dck0.00003mg/LNDCadmium E200.8
06/13/14 14:13 / sld1mg/L70Calcium E200.7
06/19/14 00:50 / dck0.01mg/LNDChromium E200.8
06/19/14 00:50 / dck0.01mg/LNDCobalt E200.8
06/19/14 00:50 / dck0.002mg/LNDCopper E200.8
06/19/14 00:50 / dck0.02mg/LNDIron E200.8
06/19/14 00:50 / dck0.0003mg/LNDLead E200.8
06/13/14 14:13 / sld1mg/L22Magnesium E200.7
06/19/14 00:50 / dck0.005mg/LNDManganese E200.8
06/25/14 11:48 / sbk5E-06mg/LNDMercury E245.1
06/19/14 00:50 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 00:50 / dck0.001mg/LNDNickel E200.8
06/13/14 14:13 / sld1mg/L1Potassium E200.7
06/20/14 20:54 / dck0.0002mg/LNDSelenium E200.8
06/19/14 00:50 / dck0.02mg/LNDSilver E200.8
06/13/14 14:13 / sld1mg/L2Sodium E200.7
06/19/14 00:50 / dck0.0002mg/L0.183Strontium E200.8
06/19/14 00:50 / dck0.0002mg/LNDThallium E200.8
06/19/14 00:50 / dck0.008mg/LNDUranium E200.8
06/19/14 00:50 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 12 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-010
Client Sample ID: BBC-1406-209
Collection Date: 06/10/14 09:55
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/13/14 09:22 / cmm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:46 / blm10mg/L277Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 18:36 / SRW4mg/L260Alkalinity, Total as CaCO3 A2320 B
06/14/14 02:31 / cmm1mg/L2Chloride E300.0
06/14/14 02:31 / cmm1mg/L13Sulfate E300.0
06/17/14 10:48 / SRW0.1mg/L0.1Fluoride A4500-F C4
NUTRIENTS
06/18/14 11:06 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:19 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:33 / cmm0.01mg/LNDPhosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 00:55 / dck0.009mg/LNDAluminum E200.8
06/19/14 00:55 / dck0.0005mg/LNDAntimony E200.8
06/19/14 00:55 / dck0.001mg/LNDArsenic E200.8
06/19/14 00:55 / dck0.003mg/L0.178Barium E200.8
06/19/14 00:55 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 00:55 / dck0.00003mg/LNDCadmium E200.8
06/13/14 14:17 / sld1mg/L75Calcium E200.7
06/19/14 00:55 / dck0.01mg/LNDChromium E200.8
06/19/14 00:55 / dck0.01mg/LNDCobalt E200.8
06/19/14 00:55 / dck0.002mg/LNDCopper E200.8
06/19/14 00:55 / dck0.02mg/L0.03Iron E200.8
06/19/14 00:55 / dck0.0003mg/LNDLead E200.8
06/13/14 14:17 / sld1mg/L21Magnesium E200.7
06/19/14 00:55 / dck0.005mg/L0.167Manganese E200.8
06/25/14 11:52 / sbk5E-06mg/LNDMercury E245.1
06/19/14 00:55 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 00:55 / dck0.001mg/LNDNickel E200.8
06/13/14 14:17 / sld1mg/L1Potassium E200.7
06/20/14 21:20 / dck0.0002mg/LNDSelenium E200.8
06/19/14 00:55 / dck0.02mg/LNDSilver E200.8
06/13/14 14:17 / sld1mg/L3Sodium E200.7
06/19/14 00:55 / dck0.0002mg/L0.167Strontium E200.8
06/19/14 00:55 / dck0.0002mg/LNDThallium E200.8
06/19/14 00:55 / dck0.008mg/LNDUranium E200.8
06/19/14 00:55 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 13 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-011
Client Sample ID: BBC-1406-210
Collection Date: 06/10/14 14:35
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/17/14 11:45 / SRW10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:46 / blm10mg/L600Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 18:43 / SRW4mg/L210Alkalinity, Total as CaCO3 A2320 B
06/14/14 02:43 / cmm1mg/L1Chloride E300.0
06/14/14 02:43 / cmm1mg/L280Sulfate E300.0
06/17/14 10:55 / SRW0.1mg/L0.7Fluoride A4500-F C4
NUTRIENTS
06/18/14 11:07 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:23 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:34 / cmm0.01mg/L0.01Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 01:12 / dck0.009mg/LNDAluminum E200.8
06/19/14 01:12 / dck0.0005mg/LNDAntimony E200.8
06/19/14 01:12 / dck0.001mg/L0.067Arsenic E200.8
06/19/14 01:12 / dck0.003mg/L0.010Barium E200.8
06/19/14 01:12 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 01:12 / dck0.00003mg/LNDCadmium E200.8
06/13/14 14:21 / sld1mg/L83Calcium E200.7
06/19/14 01:12 / dck0.01mg/LNDChromium E200.8
06/19/14 01:12 / dck0.01mg/LNDCobalt E200.8
06/19/14 01:12 / dck0.002mg/LNDCopper E200.8
06/13/14 14:21 / sld0.02mg/L1.20Iron E200.7
06/19/14 01:12 / dck0.0003mg/LNDLead E200.8
06/13/14 14:21 / sld1mg/L54Magnesium E200.7
06/19/14 01:12 / dck0.005mg/L0.021Manganese E200.8
06/25/14 11:56 / sbk5E-06mg/LNDMercury E245.1
06/19/14 01:12 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 01:12 / dck0.001mg/LNDNickel E200.8
06/13/14 14:21 / sld1mg/L3Potassium E200.7
06/20/14 21:24 / dck0.0002mg/LNDSelenium E200.8
06/19/14 01:12 / dck0.02mg/LNDSilver E200.8
06/13/14 14:21 / sld1mg/L16Sodium E200.7
D 06/13/14 14:21 / sld0.0003mg/L15.0Strontium E200.7
06/19/14 01:12 / dck0.0002mg/L0.0004Thallium E200.8
06/19/14 01:12 / dck0.008mg/LNDUranium E200.8
06/19/14 01:12 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
D - RL increased due to sample matrix.
Page 14 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-012
Client Sample ID: BBC-1406-211
Collection Date: 06/10/14 14:50
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/16/14 09:44 / blm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:46 / blm10mg/L604Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 18:51 / SRW4mg/L210Alkalinity, Total as CaCO3 A2320 B
06/14/14 02:54 / cmm1mg/L1Chloride E300.0
06/14/14 02:54 / cmm1mg/L280Sulfate E300.0
06/17/14 10:57 / SRW0.1mg/L0.7Fluoride A4500-F C4
NUTRIENTS
06/18/14 11:08 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:26 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:35 / cmm0.01mg/L0.01Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 01:30 / dck0.009mg/LNDAluminum E200.8
06/19/14 01:30 / dck0.0005mg/LNDAntimony E200.8
06/19/14 01:30 / dck0.001mg/L0.067Arsenic E200.8
06/19/14 01:30 / dck0.003mg/L0.010Barium E200.8
06/19/14 01:30 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 01:30 / dck0.00003mg/LNDCadmium E200.8
06/13/14 14:43 / sld1mg/L84Calcium E200.7
06/19/14 01:30 / dck0.01mg/LNDChromium E200.8
06/19/14 01:30 / dck0.01mg/LNDCobalt E200.8
06/19/14 01:30 / dck0.002mg/LNDCopper E200.8
06/13/14 14:43 / sld0.02mg/L1.21Iron E200.7
06/19/14 01:30 / dck0.0003mg/LNDLead E200.8
06/13/14 14:43 / sld1mg/L56Magnesium E200.7
06/19/14 01:30 / dck0.005mg/L0.020Manganese E200.8
06/25/14 12:09 / sbk5E-06mg/LNDMercury E245.1
06/19/14 01:30 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 01:30 / dck0.001mg/LNDNickel E200.8
06/13/14 14:43 / sld1mg/L3Potassium E200.7
06/20/14 21:33 / dck0.0002mg/LNDSelenium E200.8
06/19/14 01:30 / dck0.02mg/LNDSilver E200.8
06/13/14 14:43 / sld1mg/L16Sodium E200.7
D 06/13/14 14:43 / sld0.0003mg/L15.1Strontium E200.7
06/19/14 01:30 / dck0.0002mg/L0.0004Thallium E200.8
06/19/14 01:30 / dck0.008mg/LNDUranium E200.8
06/19/14 01:30 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
D - RL increased due to sample matrix.
Page 15 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-013
Client Sample ID: BBC-1406-212
Collection Date: 06/11/14 14:00
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/16/14 09:44 / blm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:47 / blm10mg/LNDSolids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 18:58 / SRW4mg/LNDAlkalinity, Total as CaCO3 A2320 B
06/14/14 03:05 / cmm1mg/LNDChloride E300.0
06/14/14 03:05 / cmm1mg/LNDSulfate E300.0
06/17/14 11:01 / SRW0.1mg/LNDFluoride A4500-F C4
NUTRIENTS
06/18/14 11:09 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:27 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:36 / cmm0.01mg/LNDPhosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 01:34 / dck0.009mg/LNDAluminum E200.8
06/19/14 01:34 / dck0.0005mg/LNDAntimony E200.8
06/19/14 01:34 / dck0.001mg/LNDArsenic E200.8
06/19/14 01:34 / dck0.003mg/LNDBarium E200.8
06/19/14 01:34 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 01:34 / dck0.00003mg/LNDCadmium E200.8
06/13/14 14:47 / sld1mg/LNDCalcium E200.7
06/19/14 01:34 / dck0.01mg/LNDChromium E200.8
06/19/14 01:34 / dck0.01mg/LNDCobalt E200.8
06/19/14 01:34 / dck0.002mg/LNDCopper E200.8
06/19/14 01:34 / dck0.02mg/LNDIron E200.8
06/19/14 01:34 / dck0.0003mg/LNDLead E200.8
06/13/14 14:47 / sld1mg/LNDMagnesium E200.7
06/19/14 01:34 / dck0.005mg/LNDManganese E200.8
06/25/14 12:13 / sbk5E-06mg/LNDMercury E245.1
06/19/14 01:34 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 01:34 / dck0.001mg/LNDNickel E200.8
06/13/14 14:47 / sld1mg/LNDPotassium E200.7
06/20/14 21:46 / dck0.0002mg/LNDSelenium E200.8
06/19/14 01:34 / dck0.02mg/LNDSilver E200.8
06/13/14 14:47 / sld1mg/LNDSodium E200.7
06/23/14 14:23 / dck0.0002mg/LNDStrontium E200.8
06/19/14 01:34 / dck0.0002mg/LNDThallium E200.8
06/19/14 01:34 / dck0.008mg/LNDUranium E200.8
06/19/14 01:34 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 16 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-014
Client Sample ID: BBC-1406-213
Collection Date: 06/11/14 14:30
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/16/14 09:44 / blm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:47 / blm10mg/LNDSolids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 19:02 / SRW4mg/LNDAlkalinity, Total as CaCO3 A2320 B
06/14/14 03:16 / cmm1mg/LNDChloride E300.0
06/14/14 03:16 / cmm1mg/LNDSulfate E300.0
06/17/14 11:02 / SRW0.1mg/LNDFluoride A4500-F C4
NUTRIENTS
06/18/14 11:10 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:28 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:37 / cmm0.01mg/LNDPhosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 01:39 / dck0.009mg/LNDAluminum E200.8
06/19/14 01:39 / dck0.0005mg/LNDAntimony E200.8
06/19/14 01:39 / dck0.001mg/LNDArsenic E200.8
06/19/14 01:39 / dck0.003mg/LNDBarium E200.8
06/19/14 01:39 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 01:39 / dck0.00003mg/LNDCadmium E200.8
06/13/14 14:51 / sld1mg/LNDCalcium E200.7
06/19/14 01:39 / dck0.01mg/LNDChromium E200.8
06/19/14 01:39 / dck0.01mg/LNDCobalt E200.8
06/19/14 01:39 / dck0.002mg/LNDCopper E200.8
06/19/14 01:39 / dck0.02mg/LNDIron E200.8
06/19/14 01:39 / dck0.0003mg/LNDLead E200.8
06/13/14 14:51 / sld1mg/LNDMagnesium E200.7
06/19/14 01:39 / dck0.005mg/LNDManganese E200.8
06/25/14 12:18 / sbk5E-06mg/LNDMercury E245.1
06/19/14 01:39 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 01:39 / dck0.001mg/LNDNickel E200.8
06/13/14 14:51 / sld1mg/LNDPotassium E200.7
06/20/14 21:51 / dck0.0002mg/LNDSelenium E200.8
06/19/14 01:39 / dck0.02mg/LNDSilver E200.8
06/13/14 14:51 / sld1mg/LNDSodium E200.7
06/23/14 14:41 / dck0.0002mg/LNDStrontium E200.8
06/19/14 01:39 / dck0.0002mg/LNDThallium E200.8
06/19/14 01:39 / dck0.008mg/LNDUranium E200.8
06/19/14 01:39 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 17 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-015
Client Sample ID: BBC-1406-100
Collection Date: 06/10/14 11:30
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/16/14 09:45 / blm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:52 / blm10mg/L233Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 19:07 / SRW4mg/L200Alkalinity, Total as CaCO3 A2320 B
06/14/14 03:27 / cmm1mg/LNDChloride E300.0
06/14/14 03:27 / cmm1mg/L14Sulfate E300.0
06/17/14 11:03 / SRW0.1mg/L0.2Fluoride A4500-F C4
NUTRIENTS
06/18/14 14:36 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:30 / cmm0.01mg/L0.04Nitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:38 / cmm0.01mg/L0.03Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 01:43 / dck0.009mg/LNDAluminum E200.8
06/13/14 14:55 / sld1mg/L52Calcium E200.7
06/13/14 14:55 / sld1mg/L23Magnesium E200.7
06/19/14 01:43 / dck1mg/L1Potassium E200.8
06/13/14 14:55 / sld1mg/L2Sodium E200.7
METALS, TOTAL RECOVERABLE
06/19/14 01:48 / dck0.0005mg/LNDAntimony E200.8
06/19/14 01:48 / dck0.001mg/LNDArsenic E200.8
06/19/14 01:48 / dck0.003mg/L0.095Barium E200.8
06/19/14 01:48 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 01:48 / dck0.00003mg/L0.00003Cadmium E200.8
06/19/14 01:48 / dck0.01mg/LNDChromium E200.8
06/19/14 01:48 / dck0.01mg/LNDCobalt E200.8
06/19/14 01:48 / dck0.002mg/LNDCopper E200.8
06/19/14 01:48 / dck0.02mg/L0.30Iron E200.8
06/19/14 01:48 / dck0.0003mg/L0.0003Lead E200.8
06/19/14 01:48 / dck0.005mg/L0.019Manganese E200.8
06/25/14 12:22 / sbk5E-06mg/LNDMercury E245.10.0001
06/19/14 01:48 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 01:48 / dck0.001mg/LNDNickel E200.8
06/20/14 22:04 / dck0.0002mg/LNDSelenium E200.8
06/19/14 01:48 / dck0.02mg/LNDSilver E200.8
06/19/14 01:48 / dck0.0002mg/L0.181Strontium E200.8
06/19/14 01:48 / dck0.0002mg/LNDThallium E200.8
06/19/14 01:48 / dck0.008mg/LNDUranium E200.8
06/19/14 01:48 / dck0.002mg/L0.003Zinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 18 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-016
Client Sample ID: BBC-1406-101
Collection Date: 06/10/14 15:45
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/16/14 09:45 / blm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:53 / blm10mg/L220Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 19:39 / SRW4mg/L190Alkalinity, Total as CaCO3 A2320 B
06/14/14 04:00 / cmm1mg/L1Chloride E300.0
06/14/14 04:00 / cmm1mg/L13Sulfate E300.0
06/17/14 11:04 / SRW0.1mg/L0.2Fluoride A4500-F C4
NUTRIENTS
06/18/14 14:37 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:43 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:39 / cmm0.01mg/LNDPhosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 01:52 / dck0.009mg/LNDAluminum E200.8
06/13/14 14:58 / sld1mg/L45Calcium E200.7
06/13/14 14:58 / sld1mg/L22Magnesium E200.7
06/19/14 01:52 / dck1mg/LNDPotassium E200.8
06/13/14 14:58 / sld1mg/L2Sodium E200.7
METALS, TOTAL RECOVERABLE
06/19/14 01:56 / dck0.0005mg/LNDAntimony E200.8
06/19/14 01:56 / dck0.001mg/LNDArsenic E200.8
06/19/14 01:56 / dck0.003mg/L0.138Barium E200.8
06/19/14 01:56 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 01:56 / dck0.00003mg/LNDCadmium E200.8
06/19/14 01:56 / dck0.01mg/LNDChromium E200.8
06/19/14 01:56 / dck0.01mg/LNDCobalt E200.8
06/19/14 01:56 / dck0.002mg/LNDCopper E200.8
06/19/14 01:56 / dck0.02mg/L0.07Iron E200.8
06/19/14 01:56 / dck0.0003mg/LNDLead E200.8
06/19/14 01:56 / dck0.005mg/LNDManganese E200.8
06/25/14 12:26 / sbk5E-06mg/LNDMercury E245.10.0001
06/19/14 01:56 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 01:56 / dck0.001mg/LNDNickel E200.8
06/20/14 22:09 / dck0.0002mg/LNDSelenium E200.8
06/19/14 01:56 / dck0.02mg/LNDSilver E200.8
06/19/14 01:56 / dck0.0002mg/L0.107Strontium E200.8
06/19/14 01:56 / dck0.0002mg/LNDThallium E200.8
06/19/14 01:56 / dck0.008mg/LNDUranium E200.8
06/20/14 22:09 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 19 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-017
Client Sample ID: BBC-1406-106
Collection Date: 06/11/14 09:20
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/16/14 09:46 / blm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:55 / blm10mg/L221Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 19:52 / SRW4mg/L200Alkalinity, Total as CaCO3 A2320 B
06/14/14 04:34 / cmm1mg/LNDChloride E300.0
06/14/14 04:34 / cmm1mg/L8Sulfate E300.0
06/17/14 11:05 / SRW0.1mg/L0.1Fluoride A4500-F C4
NUTRIENTS
06/18/14 14:39 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:32 / cmm0.01mg/L0.02Nitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:40 / cmm0.01mg/L0.01Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 02:14 / dck0.009mg/LNDAluminum E200.8
06/13/14 15:02 / sld1mg/L50Calcium E200.7
06/13/14 15:02 / sld1mg/L21Magnesium E200.7
06/13/14 15:02 / sld1mg/LNDPotassium E200.7
06/13/14 15:02 / sld1mg/L3Sodium E200.7
METALS, TOTAL RECOVERABLE
06/19/14 02:19 / dck0.0005mg/LNDAntimony E200.8
06/19/14 02:19 / dck0.001mg/LNDArsenic E200.8
06/19/14 02:19 / dck0.003mg/L0.105Barium E200.8
06/19/14 02:19 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 02:19 / dck0.00003mg/LNDCadmium E200.8
06/19/14 02:19 / dck0.01mg/LNDChromium E200.8
06/19/14 02:19 / dck0.01mg/LNDCobalt E200.8
06/19/14 02:19 / dck0.002mg/LNDCopper E200.8
06/19/14 02:19 / dck0.02mg/L0.23Iron E200.8
06/19/14 02:19 / dck0.0003mg/LNDLead E200.8
06/19/14 02:19 / dck0.005mg/L0.020Manganese E200.8
06/25/14 14:12 / sbk5E-06mg/LNDMercury E245.10.0001
06/19/14 02:19 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 02:19 / dck0.001mg/LNDNickel E200.8
06/20/14 22:13 / dck0.0002mg/LNDSelenium E200.8
06/19/14 02:19 / dck0.02mg/LNDSilver E200.8
06/19/14 02:19 / dck0.0002mg/L0.150Strontium E200.8
06/19/14 02:19 / dck0.0002mg/LNDThallium E200.8
06/19/14 02:19 / dck0.008mg/LNDUranium E200.8
06/20/14 22:13 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 20 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-018
Client Sample ID: BBC-1406-107
Collection Date: 06/11/14 09:45
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/16/14 09:46 / blm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:56 / blm10mg/L221Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 20:16 / SRW4mg/L210Alkalinity, Total as CaCO3 A2320 B
06/14/14 04:45 / cmm1mg/LNDChloride E300.0
06/14/14 04:45 / cmm1mg/L8Sulfate E300.0
06/17/14 11:06 / SRW0.1mg/L0.1Fluoride A4500-F C4
NUTRIENTS
06/18/14 14:40 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:33 / cmm0.01mg/L0.02Nitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:46 / cmm0.01mg/L0.01Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/19/14 02:23 / dck0.009mg/LNDAluminum E200.8
06/13/14 15:06 / sld1mg/L51Calcium E200.7
06/13/14 15:06 / sld1mg/L21Magnesium E200.7
06/13/14 15:06 / sld1mg/LNDPotassium E200.7
06/13/14 15:06 / sld1mg/L3Sodium E200.7
METALS, TOTAL RECOVERABLE
06/19/14 02:27 / dck0.0005mg/LNDAntimony E200.8
06/19/14 02:27 / dck0.001mg/LNDArsenic E200.8
06/19/14 02:27 / dck0.003mg/L0.102Barium E200.8
06/19/14 02:27 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 02:27 / dck0.00003mg/LNDCadmium E200.8
06/19/14 02:27 / dck0.01mg/LNDChromium E200.8
06/19/14 02:27 / dck0.01mg/LNDCobalt E200.8
06/19/14 02:27 / dck0.002mg/LNDCopper E200.8
06/19/14 02:27 / dck0.02mg/L0.24Iron E200.8
06/19/14 02:27 / dck0.0003mg/LNDLead E200.8
06/19/14 02:27 / dck0.005mg/L0.019Manganese E200.8
06/25/14 14:16 / sbk5E-06mg/LNDMercury E245.10.0001
06/19/14 02:27 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 02:27 / dck0.001mg/LNDNickel E200.8
06/20/14 22:17 / dck0.0002mg/LNDSelenium E200.8
06/19/14 02:27 / dck0.02mg/LNDSilver E200.8
06/19/14 02:27 / dck0.0002mg/L0.147Strontium E200.8
06/19/14 02:27 / dck0.0002mg/LNDThallium E200.8
06/19/14 02:27 / dck0.008mg/LNDUranium E200.8
06/20/14 22:17 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 21 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-019
Client Sample ID: BBC-1406-109
Collection Date: 06/11/14 11:10
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/16/14 09:47 / blm10mg/L11Solids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:57 / blm10mg/L145Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 20:22 / SRW4mg/L130Alkalinity, Total as CaCO3 A2320 B
06/14/14 04:56 / cmm1mg/L1Chloride E300.0
06/14/14 04:56 / cmm1mg/L3Sulfate E300.0
06/17/14 11:07 / SRW0.1mg/LNDFluoride A4500-F C4
NUTRIENTS
06/18/14 14:41 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:34 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:47 / cmm0.01mg/L0.02Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/13/14 15:17 / sld0.009mg/L0.025Aluminum E200.7
06/13/14 15:17 / sld1mg/L39Calcium E200.7
06/13/14 15:17 / sld1mg/L10Magnesium E200.7
06/19/14 02:32 / dck1mg/L1Potassium E200.8
06/13/14 15:17 / sld1mg/L2Sodium E200.7
METALS, TOTAL RECOVERABLE
06/19/14 02:36 / dck0.0005mg/LNDAntimony E200.8
06/19/14 02:36 / dck0.001mg/LNDArsenic E200.8
06/19/14 02:36 / dck0.003mg/L0.084Barium E200.8
06/19/14 02:36 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 02:36 / dck0.00003mg/LNDCadmium E200.8
06/19/14 02:36 / dck0.01mg/LNDChromium E200.8
06/19/14 02:36 / dck0.01mg/LNDCobalt E200.8
06/19/14 02:36 / dck0.002mg/LNDCopper E200.8
06/19/14 02:36 / dck0.02mg/L0.38Iron E200.8
06/19/14 02:36 / dck0.0003mg/LNDLead E200.8
06/19/14 02:36 / dck0.005mg/L0.017Manganese E200.8
06/25/14 14:29 / sbk5E-06mg/LNDMercury E245.10.0001
06/19/14 02:36 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 02:36 / dck0.001mg/LNDNickel E200.8
06/20/14 22:22 / dck0.0002mg/LNDSelenium E200.8
06/19/14 02:36 / dck0.02mg/LNDSilver E200.8
06/19/14 02:36 / dck0.0002mg/L0.116Strontium E200.8
06/19/14 02:36 / dck0.0002mg/LNDThallium E200.8
06/19/14 02:36 / dck0.008mg/LNDUranium E200.8
06/20/14 22:22 / dck0.002mg/L0.002Zinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 22 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-020
Client Sample ID: BBC-1406-110
Collection Date: 06/11/14 12:00
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/16/14 09:48 / blm10mg/LNDSolids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:58 / blm10mg/L144Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 20:28 / SRW4mg/L130Alkalinity, Total as CaCO3 A2320 B
06/14/14 05:07 / cmm1mg/L1Chloride E300.0
06/14/14 05:07 / cmm1mg/L3Sulfate E300.0
06/17/14 11:09 / SRW0.1mg/LNDFluoride A4500-F C4
NUTRIENTS
06/18/14 14:42 / eli-b0.5mg/LNDNitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:36 / cmm0.01mg/LNDNitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/LNDNitrogen, Total Calculation
06/18/14 09:48 / cmm0.01mg/L0.01Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/13/14 15:21 / sld0.009mg/L0.029Aluminum E200.7
06/13/14 15:21 / sld1mg/L38Calcium E200.7
06/13/14 15:21 / sld1mg/L9Magnesium E200.7
06/19/14 02:57 / dck1mg/L1Potassium E200.8
06/13/14 15:21 / sld1mg/L2Sodium E200.7
METALS, TOTAL RECOVERABLE
06/19/14 03:02 / dck0.0005mg/LNDAntimony E200.8
06/19/14 03:02 / dck0.001mg/LNDArsenic E200.8
06/19/14 03:02 / dck0.003mg/L0.074Barium E200.8
06/19/14 03:02 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 03:02 / dck0.00003mg/LNDCadmium E200.8
06/19/14 03:02 / dck0.01mg/LNDChromium E200.8
06/19/14 03:02 / dck0.01mg/LNDCobalt E200.8
06/19/14 03:02 / dck0.002mg/LNDCopper E200.8
06/19/14 03:02 / dck0.02mg/L0.33Iron E200.8
06/19/14 03:02 / dck0.0003mg/LNDLead E200.8
06/19/14 03:02 / dck0.005mg/L0.011Manganese E200.8
06/25/14 14:33 / sbk5E-06mg/LNDMercury E245.10.0001
06/19/14 03:02 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 03:02 / dck0.001mg/LNDNickel E200.8
06/20/14 22:39 / dck0.0002mg/LNDSelenium E200.8
06/19/14 03:02 / dck0.02mg/LNDSilver E200.8
06/19/14 03:02 / dck0.0002mg/L0.119Strontium E200.8
06/19/14 03:02 / dck0.0002mg/LNDThallium E200.8
06/19/14 03:02 / dck0.008mg/LNDUranium E200.8
06/20/14 22:39 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 23 of 52
LABORATORY ANALYTICAL REPORT
Client: Tintina Resources Inc
Project: 11048 Black Butte Copper Project
Lab ID: H14060256-021
Client Sample ID: BBC-1406-111
Collection Date: 06/11/14 12:30
Matrix: Aqueous
Report Date: 06/26/14
DateReceived: 06/12/14
Prepared by Helena, MT Branch
Analyses Result Units Analysis Date / ByRL Method
MCL/
QCLQualifiers
PHYSICAL PROPERTIES
06/16/14 09:48 / blm10mg/L11Solids, Total Suspended TSS @ 105 C A2540 D
06/13/14 09:59 / blm10mg/L163Solids, Total Dissolved TDS @ 180 C A2540 C
INORGANICS
06/13/14 20:35 / SRW4mg/L150Alkalinity, Total as CaCO3 A2320 B
06/14/14 05:18 / cmm1mg/L1Chloride E300.0
06/14/14 05:18 / cmm1mg/L4Sulfate E300.0
06/17/14 11:16 / SRW0.1mg/LNDFluoride A4500-F C4
NUTRIENTS
06/18/14 14:43 / eli-b0.5mg/L3.0Nitrogen, Kjeldahl, Total as N E351.2
06/13/14 10:39 / cmm0.01mg/L0.01Nitrogen, Nitrate+Nitrite as N E353.2
06/20/14 17:00 / abb0.5mg/L3.0Nitrogen, Total Calculation
06/18/14 09:49 / cmm0.01mg/L0.02Phosphorus, Total as P E365.1
METALS, DISSOLVED
06/13/14 15:25 / sld0.009mg/L0.021Aluminum E200.7
06/13/14 15:25 / sld1mg/L45Calcium E200.7
06/13/14 15:25 / sld1mg/L11Magnesium E200.7
06/19/14 03:20 / dck1mg/L1Potassium E200.8
06/13/14 15:25 / sld1mg/L2Sodium E200.7
METALS, TOTAL RECOVERABLE
06/19/14 03:37 / dck0.0005mg/LNDAntimony E200.8
06/19/14 03:37 / dck0.001mg/LNDArsenic E200.8
06/19/14 03:37 / dck0.003mg/L0.067Barium E200.8
06/19/14 03:37 / dck0.0008mg/LNDBeryllium E200.8
06/19/14 03:37 / dck0.00003mg/LNDCadmium E200.8
06/19/14 03:37 / dck0.01mg/LNDChromium E200.8
06/19/14 03:37 / dck0.01mg/LNDCobalt E200.8
06/19/14 03:37 / dck0.002mg/LNDCopper E200.8
06/19/14 03:37 / dck0.02mg/L0.37Iron E200.8
06/19/14 03:37 / dck0.0003mg/LNDLead E200.8
06/19/14 03:37 / dck0.005mg/L0.011Manganese E200.8
06/25/14 14:37 / sbk5E-06mg/LNDMercury E245.10.0001
06/19/14 03:37 / dck0.002mg/LNDMolybdenum E200.8
06/19/14 03:37 / dck0.001mg/LNDNickel E200.8
06/20/14 22:44 / dck0.0002mg/LNDSelenium E200.8
06/19/14 03:37 / dck0.02mg/LNDSilver E200.8
06/19/14 03:37 / dck0.0002mg/L0.139Strontium E200.8
06/19/14 03:37 / dck0.0002mg/LNDThallium E200.8
06/19/14 03:37 / dck0.008mg/LNDUranium E200.8
06/20/14 22:44 / dck0.002mg/LNDZinc E200.8
Report
Definitions:
RL - Analyte reporting limit. MCL - Maximum contaminant level.
QCL - Quality control limit. ND - Not detected at the reporting limit.
Page 24 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: A2320 B Batch: R97974
Lab ID: MB 06/13/14 16:31Method Blank Run: PHSC_101-H_140613A
Alkalinity, Total as CaCO3 4.02.3 mg/L
Lab ID: LCS 06/13/14 16:35Laboratory Control Sample Run: PHSC_101-H_140613A
Alkalinity, Total as CaCO3 98 90 1104.0590 mg/L
Lab ID: H14060255-015ADUP 06/13/14 16:55Sample Duplicate Run: PHSC_101-H_140613A
Alkalinity, Total as CaCO3 104.0 0.248 mg/L
Lab ID: H14060255-016AMS 06/13/14 17:05Sample Matrix Spike Run: PHSC_101-H_140613A
Alkalinity, Total as CaCO3 91 80 1204.0670 mg/L
Lab ID: H14060256-015ADUP 06/13/14 19:13Sample Duplicate Run: PHSC_101-H_140613A
Alkalinity, Total as CaCO3 104.0 1.3210 mg/L
Lab ID: MB 06/13/14 19:20Method Blank Run: PHSC_101-H_140613A
Alkalinity, Total as CaCO3 4.02.2 mg/L
Lab ID: LCS 06/13/14 19:24Laboratory Control Sample Run: PHSC_101-H_140613A
Alkalinity, Total as CaCO3 98 90 1104.0590 mg/L
Lab ID: H14060256-016ADUP 06/13/14 19:46Sample Duplicate Run: PHSC_101-H_140613A
Alkalinity, Total as CaCO3 104.0 0.3190 mg/L
Lab ID: H14060256-017AMS 06/13/14 19:58Sample Matrix Spike Run: PHSC_101-H_140613A
Alkalinity, Total as CaCO3 90 80 1204.0750 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 25 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: A2540 C Batch: TDS140613A
Lab ID: MB-1_140613A 06/13/14 09:42Method Blank Run: ACCU-124 (14410200)_14061
Solids, Total Dissolved TDS @ 180 C 1ND mg/L
Lab ID: LCS-2_140613A 06/13/14 09:42Laboratory Control Sample Run: ACCU-124 (14410200)_14061
Solids, Total Dissolved TDS @ 180 C 99 90 110101970 mg/L
Lab ID: H14060256-003A DUP 06/13/14 09:43Sample Duplicate Run: ACCU-124 (14410200)_14061
Solids, Total Dissolved TDS @ 180 C 510 0.6332 mg/L
Lab ID: H14060256-001A MS 06/13/14 09:43Sample Matrix Spike Run: ACCU-124 (14410200)_14061
Solids, Total Dissolved TDS @ 180 C 99 80 120102230 mg/L
Lab ID: H14060256-004A DUP 06/13/14 09:48Sample Duplicate Run: ACCU-124 (14410200)_14061
Solids, Total Dissolved TDS @ 180 C 510 3.0170 mg/L
Lab ID: MB-26_140613A 06/13/14 09:54Method Blank Run: ACCU-124 (14410200)_14061
Solids, Total Dissolved TDS @ 180 C 10ND mg/L
Lab ID: LCS-27_140613A 06/13/14 09:54Laboratory Control Sample Run: ACCU-124 (14410200)_14061
Solids, Total Dissolved TDS @ 180 C 99 90 110101970 mg/L
Lab ID: H14060256-018A MS 06/13/14 09:57Sample Matrix Spike Run: ACCU-124 (14410200)_14061
Solids, Total Dissolved TDS @ 180 C 97 80 120102170 mg/L
Lab ID: H14060256-017A DUP 06/13/14 10:47Sample Duplicate Run: ACCU-124 (14410200)_14061
Solids, Total Dissolved TDS @ 180 C 510 1.8217 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 26 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: A2540 D Batch: TSS140613A
Lab ID: MB-1_140613A 06/13/14 09:02Method Blank Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 1ND mg/L
Lab ID: LCS-2_140613A 06/13/14 09:03Laboratory Control Sample Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 91 80 1201091.0 mg/L
Lab ID: H14060256-003A DUP 06/13/14 09:03Sample Duplicate Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 510 4.6106 mg/L
Lab ID: H14060256-004A DUP 06/13/14 09:07Sample Duplicate Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 510 6.116.0 mg/L R
- RPD greater than method limit. Difference < PQL - RPD not applicable.
Lab ID: MB-25_140613A 06/13/14 09:12Method Blank Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 10ND mg/L
Lab ID: LCS-26_140613A 06/13/14 09:12Laboratory Control Sample Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 94 80 1201094.0 mg/L
Lab ID: H14060256-005A DUP 06/13/14 09:13Sample Duplicate Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 510ND mg/L
- RPD greater than method limit. Difference < PQL - RPD not applicable.
Lab ID: H14060256-006A DUP 06/13/14 09:18Sample Duplicate Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 5108.00 mg/L
Method: A2540 D Batch: TSS140616A
Lab ID: MB-1_140616A 06/16/14 09:38Method Blank Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 1ND mg/L
Lab ID: LCS-2_140616A 06/16/14 09:41Laboratory Control Sample Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 97 80 1201097.0 mg/L
Lab ID: H14060264-001A DUP 06/16/14 09:42Sample Duplicate Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 5104.00 mg/L
- RPD greater than method limit. Difference < PQL - RPD not applicable.
Lab ID: H14060256-018A DUP 06/16/14 09:47Sample Duplicate Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 5104.00 mg/L
Method: A2540 D Batch: TSS140617A
Lab ID: MB-1_140617A 06/17/14 11:43Method Blank Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 1ND mg/L
Lab ID: LCS-2_140617A 06/17/14 11:44Laboratory Control Sample Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 92 80 1201092.0 mg/L
Lab ID: H14060290-001A DUP 06/17/14 11:44Sample Duplicate Run: ACCU-124 (14410200)_14061
Solids, Total Suspended TSS @ 105 C 510 4084.0 mg/L R
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
R - RPD exceeds advisory limit.
Page 27 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: A4500-F C Analytical Run: PH_140617A
Lab ID: ICV1_140617A 06/17/14 10:31Initial Calibration Verification Standard
Fluoride 100 90 1100.10.7 mg/L
Lab ID: CCV6_140617A 06/17/14 10:49Continuing Calibration Verification Standard
Fluoride 94 90 1100.10.2 mg/L
Lab ID: CCV7_140617A 06/17/14 11:10Continuing Calibration Verification Standard
Fluoride 94 90 1100.10.2 mg/L
Method: A4500-F C Batch: 140617A-F-ISE-W
Lab ID: MBLK1_140617A 06/17/14 10:36Method Blank Run: PH_140617A
Fluoride 0.0050.009 mg/L
Lab ID: H14060256-001ADUP 06/17/14 10:38Sample Duplicate Run: PH_140617A
Fluoride 100.1 0.00.2 mg/L
Lab ID: H14060256-004AMS 06/17/14 10:42Sample Matrix Spike Run: PH_140617A
Fluoride 94 85 1150.10.7 mg/L
Lab ID: H14060256-011ADUP 06/17/14 10:56Sample Duplicate Run: PH_140617A
Fluoride 100.1 0.00.7 mg/L
Lab ID: H14060256-021ADUP 06/17/14 11:17Sample Duplicate Run: PH_140617A
Fluoride 100.10.1 mg/L
Lab ID: H14060256-021AMS 06/17/14 11:18Sample Matrix Spike Run: PH_140617A
Fluoride 96 85 1150.10.5 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 28 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.7 Analytical Run: ICP2-HE_140613C
Lab ID: ICV 06/13/14 12:51Initial Calibration Verification Standard7
Aluminum 102 95 1050.104.09 mg/L
Calcium 101 95 1051.040.3 mg/L
Iron 101 95 1050.0204.02 mg/L
Magnesium 101 95 1051.040.5 mg/L
Potassium 102 95 1051.040.8 mg/L
Sodium 101 95 1051.040.5 mg/L
Strontium 103 95 1050.100.820 mg/L
Lab ID: CCV-1 06/13/14 12:54Continuing Calibration Verification Standard7
Aluminum 103 95 1050.102.57 mg/L
Calcium 101 95 1051.025.4 mg/L
Iron 100 95 1050.0202.51 mg/L
Magnesium 99 95 1051.024.7 mg/L
Potassium 102 95 1051.025.5 mg/L
Sodium 102 95 1051.025.4 mg/L
Strontium 102 95 1050.102.56 mg/L
Lab ID: ICSA 06/13/14 13:05Interference Check Sample A7
Aluminum 106 80 1200.10531 mg/L
Calcium 94 80 1201.0468 mg/L
Iron 92 80 1200.020184 mg/L
Magnesium 101 80 1201.0506 mg/L
Potassium 0 01.0-0.102 mg/L
Sodium 0 01.00.0504 mg/L
Strontium 0 00.100.0159 mg/L
Lab ID: ICSAB 06/13/14 13:09Interference Check Sample AB7
Aluminum 105 80 1200.10523 mg/L
Calcium 93 80 1201.0464 mg/L
Iron 92 80 1200.020183 mg/L
Magnesium 101 80 1201.0503 mg/L
Potassium 103 80 1201.020.6 mg/L
Sodium 103 80 1201.020.5 mg/L
Strontium 103 80 1200.101.03 mg/L
Lab ID: CCV 06/13/14 13:39Continuing Calibration Verification Standard7
Aluminum 104 90 1100.102.60 mg/L
Calcium 101 90 1101.025.2 mg/L
Iron 101 90 1100.0202.52 mg/L
Magnesium 98 90 1101.024.5 mg/L
Potassium 102 90 1101.025.6 mg/L
Sodium 103 90 1101.025.6 mg/L
Strontium 103 90 1100.102.57 mg/L
Lab ID: CCV 06/13/14 14:25Continuing Calibration Verification Standard7
Aluminum 104 90 1100.102.61 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 29 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.7 Analytical Run: ICP2-HE_140613C
Lab ID: CCV 06/13/14 14:25Continuing Calibration Verification Standard7
Calcium 102 90 1101.025.5 mg/L
Iron 101 90 1100.0202.54 mg/L
Magnesium 101 90 1101.025.2 mg/L
Potassium 101 90 1101.025.2 mg/L
Sodium 101 90 1101.025.3 mg/L
Strontium 103 90 1100.102.57 mg/L
Lab ID: CCV 06/13/14 15:10Continuing Calibration Verification Standard7
Aluminum 102 90 1100.102.55 mg/L
Calcium 100 90 1101.025.0 mg/L
Iron 100 90 1100.0202.49 mg/L
Magnesium 100 90 1101.025.0 mg/L
Potassium 102 90 1101.025.4 mg/L
Sodium 102 90 1101.025.4 mg/L
Strontium 100 90 1100.102.50 mg/L
Method: E200.7 Batch: R98015
Lab ID: ICB 06/13/14 13:17Method Blank Run: ICP2-HE_140613C7
Aluminum 0.002ND mg/L
Calcium 0.030.04 mg/L
Iron 0.0030.006 mg/L
Magnesium 0.04ND mg/L
Potassium 0.04ND mg/L
Sodium 0.02ND mg/L
Strontium 0.0003ND mg/L
Lab ID: LFB 06/13/14 13:21Laboratory Fortified Blank Run: ICP2-HE_140613C7
Aluminum 99 85 1150.104.95 mg/L
Calcium 98 85 1151.049.0 mg/L
Iron 98 85 1150.0204.89 mg/L
Magnesium 100 85 1151.049.9 mg/L
Potassium 97 85 1151.048.5 mg/L
Sodium 96 85 1151.048.2 mg/L
Strontium 99 85 1150.100.991 mg/L
Lab ID: H14060256-001BMS2 06/13/14 13:32Sample Matrix Spike Run: ICP2-HE_140613C7
Aluminum 104 70 1300.0305.22 mg/L
Calcium 100 70 1301.0103 mg/L
Iron 99 70 1300.0204.97 mg/L
Magnesium 103 70 1301.075.3 mg/L
Potassium 102 70 1301.051.9 mg/L
Sodium 101 70 1301.053.1 mg/L
Strontium 102 70 1300.0101.18 mg/L
Lab ID: H14060256-001BMSD 06/13/14 13:36Sample Matrix Spike Duplicate Run: ICP2-HE_140613C7
Aluminum 104 70 130 200.030 0.25.23 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 30 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.7 Batch: R98015
Lab ID: H14060256-001BMSD 06/13/14 13:36Sample Matrix Spike Duplicate Run: ICP2-HE_140613C7
Calcium 98 70 130 201.0 1.0102 mg/L
Iron 99 70 130 200.020 0.24.98 mg/L
Magnesium 100 70 130 201.0 1.474.2 mg/L
Potassium 103 70 130 201.0 0.252.0 mg/L
Sodium 102 70 130 201.0 0.753.4 mg/L
Strontium 103 70 130 200.010 0.91.19 mg/L
Lab ID: H14060256-011BMS2 06/13/14 14:36Sample Matrix Spike Run: ICP2-HE_140613C7
Aluminum 105 70 1300.0305.26 mg/L
Calcium 101 70 1301.0133 mg/L
Iron 99 70 1300.0206.15 mg/L
Magnesium 106 70 1301.0107 mg/L
Potassium 102 70 1301.054.7 mg/L
Sodium 102 70 1301.066.8 mg/L
Strontium 70 1300.01016.0 mg/L A
Lab ID: H14060256-011BMSD 06/13/14 14:39Sample Matrix Spike Duplicate Run: ICP2-HE_140613C7
Aluminum 106 70 130 200.030 0.65.29 mg/L
Calcium 104 70 130 201.0 0.8135 mg/L
Iron 100 70 130 200.020 1.06.22 mg/L
Magnesium 108 70 130 201.0 0.9108 mg/L
Potassium 104 70 130 201.0 1.155.3 mg/L
Sodium 103 70 130 201.0 1.167.5 mg/L
Strontium 70 130 200.010 0.716.1 mg/L A
Lab ID: H14060256-021BMS2 06/13/14 15:32Sample Matrix Spike Run: ICP2-HE_140613C7
Aluminum 104 70 1300.0305.21 mg/L
Calcium 100 70 1301.095.0 mg/L
Iron 99 70 1300.0204.98 mg/L
Magnesium 105 70 1301.063.5 mg/L
Potassium 101 70 1301.051.9 mg/L
Sodium 101 70 1301.052.2 mg/L
Strontium 102 70 1300.0101.16 mg/L
Lab ID: H14060256-021BMSD 06/13/14 15:36Sample Matrix Spike Duplicate Run: ICP2-HE_140613C7
Aluminum 104 70 130 200.030 0.35.22 mg/L
Calcium 99 70 130 201.0 0.794.4 mg/L
Iron 99 70 130 200.020 0.24.97 mg/L
Magnesium 102 70 130 201.0 1.862.4 mg/L
Potassium 104 70 130 201.0 2.653.3 mg/L
Sodium 104 70 130 201.0 2.653.6 mg/L
Strontium 103 70 130 200.010 0.81.17 mg/L
Qualifiers:
RL - Analyte reporting limit. A - The analyte level was greater than four times the spike level. In accordance with the method % recovery is not calculated.
ND - Not detected at the reporting limit.
Page 31 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.8 Analytical Run: ICPMS204-B_140619A
Lab ID: ICV STD 06/18/14 11:49Initial Calibration Verification Standard20
Aluminum 99 90 1100.100.297 mg/L
Antimony 101 90 1100.0500.0607 mg/L
Arsenic 99 90 1100.00500.0596 mg/L
Barium 100 90 1100.100.0602 mg/L
Beryllium 101 90 1100.00100.0302 mg/L
Cadmium 105 90 1100.00100.0314 mg/L
Chromium 102 90 1100.0100.0609 mg/L
Cobalt 101 90 1100.0100.0603 mg/L
Copper 102 90 1100.0100.0610 mg/L
Iron 103 90 1100.0200.309 mg/L
Lead 98 90 1100.0100.0591 mg/L
Manganese 100 90 1100.0100.298 mg/L
Molybdenum 101 90 1100.00500.0607 mg/L
Nickel 102 90 1100.0100.0613 mg/L
Potassium 106 90 1100.503.18 mg/L
Silver 101 90 1100.00500.0303 mg/L
Strontium 101 90 1100.100.0608 mg/L
Thallium 99 90 1100.100.0595 mg/L
Uranium 99 90 1100.00100.0594 mg/L
Zinc 104 90 1100.0100.0624 mg/L
Lab ID: ICSA 06/18/14 11:53Interference Check Sample A20
Aluminum 97 70 1300.1038.9 mg/L
Antimony 0.0500.000110 mg/L
Arsenic 0.00500.000202 mg/L
Barium 0.100.000161 mg/L
Beryllium 0.00103.00E-06 mg/L
Cadmium 0.00100.000341 mg/L
Chromium 0.0100.00112 mg/L
Cobalt 0.0100.000209 mg/L
Copper 0.0100.000390 mg/L
Iron 98 70 1300.02098.3 mg/L
Lead 0.0100.000264 mg/L
Manganese 0.0100.000169 mg/L
Molybdenum 105 70 1300.00500.838 mg/L
Nickel 0.010-1.00E-05 mg/L
Potassium 102 70 1300.5041.0 mg/L
Silver 0.00500.000297 mg/L
Strontium 0.100.000837 mg/L
Thallium 0.106.80E-05 mg/L
Uranium 0.00104.20E-05 mg/L
Zinc 0.0100.00170 mg/L
Lab ID: ICSAB 06/18/14 11:58Interference Check Sample AB20
Aluminum 97 70 1300.1038.9 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 32 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.8 Analytical Run: ICPMS204-B_140619A
Lab ID: ICSAB 06/18/14 11:58Interference Check Sample AB20
Antimony 0 00.0500.000155 mg/L
Arsenic 109 70 1300.00500.0109 mg/L
Barium 0 00.100.000199 mg/L
Beryllium 0 00.0010-5.00E-06 mg/L
Cadmium 94 70 1300.00100.00941 mg/L
Chromium 110 70 1300.0100.0220 mg/L
Cobalt 98 70 1300.0100.0196 mg/L
Copper 104 70 1300.0100.0207 mg/L
Iron 99 70 1300.02099.2 mg/L
Lead 0 00.0100.000351 mg/L
Manganese 99 70 1300.0100.0198 mg/L
Molybdenum 104 70 1300.00500.830 mg/L
Nickel 102 70 1300.0100.0205 mg/L
Potassium 104 70 1300.5041.5 mg/L
Silver 93 70 1300.00500.0186 mg/L
Strontium 0 00.100.000830 mg/L
Thallium 0 00.105.40E-05 mg/L
Uranium 0 00.00106.70E-05 mg/L
Zinc 116 70 1300.0100.0116 mg/L
Lab ID: ICV STD 06/18/14 21:46Initial Calibration Verification Standard20
Aluminum 102 90 1100.100.305 mg/L
Antimony 101 90 1100.0500.0603 mg/L
Arsenic 99 90 1100.00500.0596 mg/L
Barium 100 90 1100.100.0601 mg/L
Beryllium 103 90 1100.00100.0310 mg/L
Cadmium 105 90 1100.00100.0315 mg/L
Chromium 102 90 1100.0100.0613 mg/L
Cobalt 100 90 1100.0100.0600 mg/L
Copper 105 90 1100.0100.0629 mg/L
Iron 104 90 1100.0200.311 mg/L
Lead 100 90 1100.0100.0602 mg/L
Manganese 102 90 1100.0100.305 mg/L
Molybdenum 102 90 1100.00500.0609 mg/L
Nickel 104 90 1100.0100.0622 mg/L
Potassium 101 90 1100.503.04 mg/L
Silver 101 90 1100.00500.0304 mg/L
Strontium 103 90 1100.100.0619 mg/L
Thallium 100 90 1100.100.0599 mg/L
Uranium 100 90 1100.00100.0602 mg/L
Zinc 104 90 1100.0100.0624 mg/L
Lab ID: ICSA 06/18/14 21:50Interference Check Sample A20
Aluminum 99 70 1300.1039.4 mg/L
Antimony 0.0509.90E-05 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 33 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.8 Analytical Run: ICPMS204-B_140619A
Lab ID: ICSA 06/18/14 21:50Interference Check Sample A20
Arsenic 0.00500.000160 mg/L
Barium 0.100.000120 mg/L
Beryllium 0.00101.70E-05 mg/L
Cadmium 0.00100.000362 mg/L
Chromium 0.0100.00108 mg/L
Cobalt 0.0100.000232 mg/L
Copper 0.0100.000358 mg/L
Iron 98 70 1300.02098.4 mg/L
Lead 0.0100.000256 mg/L
Manganese 0.0100.000147 mg/L
Molybdenum 107 70 1300.00500.858 mg/L
Nickel 0.0100.000616 mg/L
Potassium 103 70 1300.5041.3 mg/L
Silver 0.00500.000352 mg/L
Strontium 0.100.000694 mg/L
Thallium 0.106.30E-05 mg/L
Uranium 0.00104.70E-05 mg/L
Zinc 0.0100.00161 mg/L
Lab ID: ICSAB 06/18/14 21:54Interference Check Sample AB20
Aluminum 100 70 1300.1040.2 mg/L
Antimony 0 00.0500.000128 mg/L
Arsenic 108 70 1300.00500.0108 mg/L
Barium 0 00.100.000184 mg/L
Beryllium 0 00.00101.40E-05 mg/L
Cadmium 94 70 1300.00100.00941 mg/L
Chromium 110 70 1300.0100.0219 mg/L
Cobalt 97 70 1300.0100.0195 mg/L
Copper 104 70 1300.0100.0207 mg/L
Iron 100 70 1300.02099.9 mg/L
Lead 0 00.0100.000342 mg/L
Manganese 97 70 1300.0100.0194 mg/L
Molybdenum 106 70 1300.00500.849 mg/L
Nickel 106 70 1300.0100.0212 mg/L
Potassium 105 70 1300.5042.0 mg/L
Silver 92 70 1300.00500.0185 mg/L
Strontium 0 00.100.000686 mg/L
Thallium 0 00.105.80E-05 mg/L
Uranium 0 00.00107.30E-05 mg/L
Zinc 118 70 1300.0100.0118 mg/L
Method: E200.8 Batch: 24932
Lab ID: MB-24932 06/18/14 18:03Method Blank Run: ICPMS204-B_140619A19
Antimony 3E-05ND mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 34 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.8 Batch: 24932
Lab ID: MB-24932 06/18/14 18:03Method Blank Run: ICPMS204-B_140619A19
Arsenic 6E-05ND mg/L
Barium 0.0002ND mg/L
Beryllium 5E-05ND mg/L
Cadmium 3E-05ND mg/L
Chromium 5E-05ND mg/L
Cobalt 2E-05ND mg/L
Copper 0.0003ND mg/L
Iron 0.002ND mg/L
Lead 3E-05ND mg/L
Manganese 0.00010ND mg/L
Molybdenum 3E-05ND mg/L
Nickel 0.0003ND mg/L
Selenium 0.0002ND mg/L
Silver 7E-05ND mg/L
Strontium 2E-05ND mg/L
Thallium 2E-05ND mg/L
Uranium 3E-05ND mg/L
Zinc 0.001ND mg/L
Lab ID: LCS-24932 06/18/14 18:08Laboratory Control Sample Run: ICPMS204-B_140619A19
Antimony 98 85 1150.00100.489 mg/L
Arsenic 98 85 1150.00100.488 mg/L
Barium 96 85 1150.0500.480 mg/L
Beryllium 97 85 1150.00100.243 mg/L
Cadmium 97 85 1150.00100.243 mg/L
Chromium 99 85 1150.00500.496 mg/L
Cobalt 93 85 1150.00500.464 mg/L
Copper 98 85 1150.00500.489 mg/L
Iron 95 85 1150.0202.38 mg/L
Lead 95 85 1150.00100.477 mg/L
Manganese 92 85 1150.00102.31 mg/L
Molybdenum 99 85 1150.00100.493 mg/L
Nickel 100 85 1150.00500.501 mg/L
Selenium 98 85 1150.00100.490 mg/L
Silver 93 85 1150.00100.0464 mg/L
Strontium 98 85 1150.0100.492 mg/L
Thallium 97 85 1150.000500.486 mg/L
Uranium 99 85 1150.000300.494 mg/L
Zinc 97 85 1150.0100.485 mg/L
Lab ID: H14060256-019CMS3 06/19/14 02:41Sample Matrix Spike Run: ICPMS204-B_140619A19
Antimony 100 70 1300.00100.499 mg/L
Arsenic 99 70 1300.00100.496 mg/L
Barium 102 70 1300.0500.594 mg/L
Beryllium 97 70 1300.00100.242 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 35 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.8 Batch: 24932
Lab ID: H14060256-019CMS3 06/19/14 02:41Sample Matrix Spike Run: ICPMS204-B_140619A19
Cadmium 97 70 1300.00100.241 mg/L
Chromium 101 70 1300.00500.508 mg/L
Cobalt 93 70 1300.00500.467 mg/L
Copper 98 70 1300.00500.489 mg/L
Iron 98 70 1300.0202.82 mg/L
Lead 100 70 1300.00100.499 mg/L
Manganese 92 70 1300.00102.32 mg/L
Molybdenum 105 70 1300.00100.523 mg/L
Nickel 97 70 1300.00500.484 mg/L
Selenium 97 70 1300.00100.486 mg/L
Silver 94 70 1300.00100.0472 mg/L
Strontium 98 70 1300.0100.608 mg/L
Thallium 98 70 1300.000500.492 mg/L
Uranium 98 70 1300.000300.488 mg/L
Zinc 94 70 1300.0100.474 mg/L
Lab ID: H14060256-019CMSD 06/19/14 02:44Sample Matrix Spike Duplicate Run: ICPMS204-B_140619A19
Antimony 99 70 130 200.0010 0.90.494 mg/L
Arsenic 97 70 130 200.0010 1.50.488 mg/L
Barium 98 70 130 200.050 3.70.572 mg/L
Beryllium 94 70 130 200.0010 2.80.235 mg/L
Cadmium 95 70 130 200.0010 2.10.236 mg/L
Chromium 101 70 130 200.0050 0.30.506 mg/L
Cobalt 91 70 130 200.0050 2.40.456 mg/L
Copper 97 70 130 200.0050 1.00.484 mg/L
Iron 97 70 130 200.020 0.92.80 mg/L
Lead 98 70 130 200.0010 2.20.488 mg/L
Manganese 90 70 130 200.0010 2.32.26 mg/L
Molybdenum 103 70 130 200.0010 1.80.514 mg/L
Nickel 96 70 130 200.0050 0.40.482 mg/L
Selenium 99 70 130 200.0010 1.20.493 mg/L
Silver 92 70 130 200.0010 2.10.0462 mg/L
Strontium 96 70 130 200.010 2.20.595 mg/L
Thallium 97 70 130 200.00050 1.10.486 mg/L
Uranium 95 70 130 200.00030 2.80.475 mg/L
Zinc 93 70 130 200.010 0.70.470 mg/L
Method: E200.8 Batch: R98112
Lab ID: ICB 06/18/14 12:40Method Blank Run: ICPMS204-B_140619A20
Aluminum 0.00020.0008 mg/L
Antimony 1E-05ND mg/L
Arsenic 3E-05ND mg/L
Barium 3E-050.0002 mg/L
Beryllium 2E-05ND mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 36 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.8 Batch: R98112
Lab ID: ICB 06/18/14 12:40Method Blank Run: ICPMS204-B_140619A20
Cadmium 6E-06ND mg/L
Chromium 3E-05ND mg/L
Cobalt 2E-05ND mg/L
Copper 3E-053E-05 mg/L
Iron 0.00020.002 mg/L
Lead 8E-06ND mg/L
Manganese 2E-05ND mg/L
Molybdenum 3E-05ND mg/L
Nickel 6E-05ND mg/L
Potassium 0.05ND mg/L
Silver 3E-05ND mg/L
Strontium 5E-067E-06 mg/L
Thallium 1E-05ND mg/L
Uranium 6E-06ND mg/L
Zinc 0.0003ND mg/L
Lab ID: LFB 06/18/14 12:45Laboratory Fortified Blank Run: ICPMS204-B_140619A20
Aluminum 98 85 1150.100.0498 mg/L
Antimony 103 85 1150.0500.0515 mg/L
Arsenic 102 85 1150.00500.0512 mg/L
Barium 103 85 1150.100.0519 mg/L
Beryllium 102 85 1150.00100.0508 mg/L
Cadmium 104 85 1150.00100.0522 mg/L
Chromium 103 85 1150.0100.0514 mg/L
Cobalt 103 85 1150.0100.0515 mg/L
Copper 107 85 1150.0100.0536 mg/L
Iron 97 85 1150.0200.147 mg/L
Lead 101 85 1150.0100.0508 mg/L
Manganese 100 85 1150.0100.0498 mg/L
Molybdenum 100 85 1150.00500.0499 mg/L
Nickel 106 85 1150.0100.0529 mg/L
Potassium 101 85 1150.501.01 mg/L
Silver 104 85 1150.00500.0208 mg/L
Strontium 105 85 1150.100.0524 mg/L
Thallium 100 85 1150.100.0502 mg/L
Uranium 99 85 1150.00100.0494 mg/L
Zinc 111 85 1150.0100.0553 mg/L
Lab ID: H14060256-001BMS 06/18/14 23:58Sample Matrix Spike Run: ICPMS204-B_140619A20
Aluminum 101 70 1300.0300.0604 mg/L
Antimony 104 70 1300.00100.0520 mg/L
Arsenic 107 70 1300.00100.0538 mg/L
Barium 102 70 1300.0500.211 mg/L
Beryllium 105 70 1300.00100.0527 mg/L
Cadmium 101 70 1300.00100.0503 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 37 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.8 Batch: R98112
Lab ID: H14060256-001BMS 06/18/14 23:58Sample Matrix Spike Run: ICPMS204-B_140619A20
Chromium 105 70 1300.00500.0528 mg/L
Cobalt 99 70 1300.00500.0496 mg/L
Copper 104 70 1300.00500.0522 mg/L
Iron 100 70 1300.0200.155 mg/L
Lead 103 70 1300.00100.0513 mg/L
Manganese 101 70 1300.00100.0515 mg/L
Molybdenum 105 70 1300.00100.0529 mg/L
Nickel 103 70 1300.00500.0513 mg/L
Potassium 104 70 1301.01.92 mg/L
Silver 103 70 1300.00100.0207 mg/L
Strontium 100 70 1300.0100.200 mg/L
Thallium 103 70 1300.000500.0517 mg/L
Uranium 100 70 1300.000300.0504 mg/L
Zinc 106 70 1300.0100.0548 mg/L
Lab ID: H14060256-001BMSD 06/19/14 00:02Sample Matrix Spike Duplicate Run: ICPMS204-B_140619A20
Aluminum 100 70 130 200.030 1.60.0594 mg/L
Antimony 103 70 130 200.0010 1.00.0515 mg/L
Arsenic 107 70 130 200.0010 0.10.0538 mg/L
Barium 103 70 130 200.050 0.30.211 mg/L
Beryllium 104 70 130 200.0010 0.90.0522 mg/L
Cadmium 100 70 130 200.0010 0.50.0501 mg/L
Chromium 104 70 130 200.0050 1.00.0523 mg/L
Cobalt 98 70 130 200.0050 1.30.0489 mg/L
Copper 103 70 130 200.0050 0.70.0519 mg/L
Iron 100 70 130 200.020 0.30.155 mg/L
Lead 102 70 130 200.0010 0.90.0509 mg/L
Manganese 100 70 130 200.0010 0.80.0511 mg/L
Molybdenum 104 70 130 200.0010 0.40.0527 mg/L
Nickel 103 70 130 200.0050 0.10.0513 mg/L
Potassium 102 70 130 201.0 0.91.90 mg/L
Silver 102 70 130 200.0010 1.20.0204 mg/L
Strontium 98 70 130 200.010 0.60.198 mg/L
Thallium 102 70 130 200.00050 1.60.0509 mg/L
Uranium 100 70 130 200.00030 0.20.0505 mg/L
Zinc 104 70 130 200.010 2.00.0538 mg/L
Lab ID: H14060256-011BMS 06/19/14 01:17Sample Matrix Spike Run: ICPMS204-B_140619A20
Aluminum 98 70 1300.0300.0495 mg/L
Antimony 102 70 1300.00100.0509 mg/L
Arsenic 105 70 1300.00100.119 mg/L
Barium 100 70 1300.0500.0602 mg/L
Beryllium 99 70 1300.00100.0497 mg/L
Cadmium 95 70 1300.00100.0473 mg/L
Chromium 102 70 1300.00500.0508 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 38 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.8 Batch: R98112
Lab ID: H14060256-011BMS 06/19/14 01:17Sample Matrix Spike Run: ICPMS204-B_140619A20
Cobalt 94 70 1300.00500.0474 mg/L
Copper 101 70 1300.00500.0503 mg/L
Iron 70 1300.0201.26 mg/L A
Lead 100 70 1300.00100.0498 mg/L
Manganese 99 70 1300.00100.0706 mg/L
Molybdenum 104 70 1300.00100.0536 mg/L
Nickel 100 70 1300.00500.0509 mg/L
Potassium 109 70 1301.04.63 mg/L
Silver 93 70 1300.00100.0186 mg/L
Strontium 70 1300.01015.1 mg/L A
Thallium 101 70 1300.000500.0508 mg/L
Uranium 100 70 1300.000300.0509 mg/L
Zinc 102 70 1300.0100.0521 mg/L
Lab ID: H14060256-011BMSD 06/19/14 01:21Sample Matrix Spike Duplicate Run: ICPMS204-B_140619A20
Aluminum 98 70 130 200.030 0.50.0498 mg/L
Antimony 101 70 130 200.0010 0.80.0505 mg/L
Arsenic 104 70 130 200.0010 0.50.118 mg/L
Barium 101 70 130 200.050 0.50.0605 mg/L
Beryllium 100 70 130 200.0010 0.80.0501 mg/L
Cadmium 94 70 130 200.0010 0.70.0470 mg/L
Chromium 103 70 130 200.0050 1.50.0516 mg/L
Cobalt 93 70 130 200.0050 1.30.0468 mg/L
Copper 102 70 130 200.0050 1.60.0511 mg/L
Iron 70 130 200.020 0.31.27 mg/L A
Lead 100 70 130 200.0010 0.10.0499 mg/L
Manganese 98 70 130 200.0010 1.30.0697 mg/L
Molybdenum 104 70 130 200.0010 0.00.0536 mg/L
Nickel 102 70 130 200.0050 1.60.0517 mg/L
Potassium 108 70 130 201.0 0.24.62 mg/L
Silver 96 70 130 200.0010 2.50.0191 mg/L
Strontium 70 130 200.010 2.614.7 mg/L A
Thallium 102 70 130 200.00050 1.00.0513 mg/L
Uranium 100 70 130 200.00030 0.60.0512 mg/L
Zinc 102 70 130 200.010 0.10.0521 mg/L
Lab ID: H14060256-021BMS 06/19/14 03:24Sample Matrix Spike Run: ICPMS204-B_140619A20
Aluminum 98 70 1300.0300.0638 mg/L
Antimony 100 70 1300.00100.0503 mg/L
Arsenic 105 70 1300.00100.0526 mg/L
Barium 99 70 1300.0500.112 mg/L
Beryllium 103 70 1300.00100.0513 mg/L
Cadmium 100 70 1300.00100.0498 mg/L
Chromium 102 70 1300.00500.0511 mg/L
Cobalt 97 70 1300.00500.0485 mg/L
Qualifiers:
RL - Analyte reporting limit. A - The analyte level was greater than four times the spike level. In accordance with the method % recovery is not calculated.
ND - Not detected at the reporting limit.
Page 39 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.8 Batch: R98112
Lab ID: H14060256-021BMS 06/19/14 03:24Sample Matrix Spike Run: ICPMS204-B_140619A20
Copper 102 70 1300.00500.0512 mg/L
Iron 100 70 1300.0200.165 mg/L
Lead 99 70 1300.00100.0496 mg/L
Manganese 98 70 1300.00100.0530 mg/L
Molybdenum 101 70 1300.00100.0508 mg/L
Nickel 102 70 1300.00500.0510 mg/L
Potassium 102 70 1301.02.26 mg/L
Silver 99 70 1300.00100.0198 mg/L
Strontium 96 70 1300.0100.186 mg/L
Thallium 100 70 1300.000500.0499 mg/L
Uranium 97 70 1300.000300.0487 mg/L
Zinc 104 70 1300.0100.0536 mg/L
Lab ID: H14060256-021BMSD 06/19/14 03:28Sample Matrix Spike Duplicate Run: ICPMS204-B_140619A20
Aluminum 101 70 130 200.030 2.30.0653 mg/L
Antimony 101 70 130 200.0010 0.10.0504 mg/L
Arsenic 105 70 130 200.0010 0.70.0529 mg/L
Barium 99 70 130 200.050 0.10.112 mg/L
Beryllium 106 70 130 200.0010 3.00.0529 mg/L
Cadmium 101 70 130 200.0010 1.50.0505 mg/L
Chromium 103 70 130 200.0050 1.60.0519 mg/L
Cobalt 97 70 130 200.0050 0.10.0485 mg/L
Copper 105 70 130 200.0050 2.60.0525 mg/L
Iron 99 70 130 200.020 0.70.164 mg/L
Lead 101 70 130 200.0010 2.10.0507 mg/L
Manganese 99 70 130 200.0010 0.80.0534 mg/L
Molybdenum 101 70 130 200.0010 0.00.0508 mg/L
Nickel 103 70 130 200.0050 1.30.0517 mg/L
Potassium 100 70 130 201.0 0.72.25 mg/L
Silver 100 70 130 200.0010 1.00.0200 mg/L
Strontium 94 70 130 200.010 0.40.186 mg/L
Thallium 103 70 130 200.00050 3.40.0516 mg/L
Uranium 100 70 130 200.00030 3.30.0504 mg/L
Zinc 107 70 130 200.010 2.30.0548 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 40 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.8 Analytical Run: ICPMS204-B_140620A
Lab ID: ICV STD 06/20/14 14:56Initial Calibration Verification Standard2
Selenium 104 90 1100.00500.0622 mg/L
Zinc 103 90 1100.0100.0617 mg/L
Lab ID: ICSA 06/20/14 15:00Interference Check Sample A2
Selenium 0.00500.000557 mg/L
Zinc 0.0100.00142 mg/L
Lab ID: ICSAB 06/20/14 15:05Interference Check Sample AB2
Selenium 100 70 1300.00500.00997 mg/L
Zinc 113 70 1300.0100.0112 mg/L
Lab ID: ICV STD 06/20/14 19:48Initial Calibration Verification Standard2
Selenium 101 90 1100.00500.0607 mg/L
Zinc 105 90 1100.0100.0629 mg/L
Lab ID: ICSA 06/20/14 19:52Interference Check Sample A2
Selenium 0.00500.000658 mg/L
Zinc 0.0100.00149 mg/L
Lab ID: ICSAB 06/20/14 19:56Interference Check Sample AB2
Selenium 100 70 1300.00500.0100 mg/L
Zinc 111 70 1300.0100.0111 mg/L
Method: E200.8 Batch: 24932
Lab ID: MB-24932 06/20/14 22:00Method Blank Run: ICPMS204-B_140620A19
Antimony 3E-05ND mg/L
Arsenic 6E-05ND mg/L
Barium 0.0002ND mg/L
Beryllium 5E-05ND mg/L
Cadmium 3E-05ND mg/L
Chromium 5E-05ND mg/L
Cobalt 2E-05ND mg/L
Copper 0.0003ND mg/L
Iron 0.002ND mg/L
Lead 3E-05ND mg/L
Manganese 0.00010ND mg/L
Molybdenum 3E-05ND mg/L
Nickel 0.0003ND mg/L
Selenium 0.0002ND mg/L
Silver 7E-05ND mg/L
Strontium 2E-050.0001 mg/L
Thallium 2E-05ND mg/L
Uranium 3E-05ND mg/L
Zinc 0.001ND mg/L
Method: E200.8 Batch: R98231
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 41 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E200.8 Batch: R98231
Lab ID: ICB 06/20/14 15:52Method Blank Run: ICPMS204-B_140620A2
Selenium 7E-05ND mg/L
Zinc 0.0003ND mg/L
Lab ID: LFB 06/20/14 15:56Laboratory Fortified Blank Run: ICPMS204-B_140620A2
Selenium 107 85 1150.00500.0537 mg/L
Zinc 110 85 1150.0100.0552 mg/L
Lab ID: H14060256-009BMS 06/20/14 20:58Sample Matrix Spike Run: ICPMS204-B_140620A2
Selenium 113 70 1300.00100.0562 mg/L
Zinc 106 70 1300.0100.0544 mg/L
Lab ID: H14060256-009BMSD 06/20/14 21:02Sample Matrix Spike Duplicate Run: ICPMS204-B_140620A2
Selenium 113 70 130 200.0010 0.40.0564 mg/L
Zinc 106 70 130 200.010 0.10.0544 mg/L
Method: E200.8 Analytical Run: ICPMS204-B_140623A
Lab ID: ICV STD 06/23/14 11:36Initial Calibration Verification Standard
Strontium 98 90 1100.100.0588 mg/L
Lab ID: ICSA 06/23/14 11:40Interference Check Sample A
Strontium 0.100.000880 mg/L
Lab ID: ICSAB 06/23/14 11:46Interference Check Sample AB
Strontium 0 00.100.000871 mg/L
Method: E200.8 Batch: R98262
Lab ID: ICB 06/23/14 12:08Method Blank Run: ICPMS204-B_140623A
Strontium 5E-06ND mg/L
Lab ID: LFB 06/23/14 12:13Laboratory Fortified Blank Run: ICPMS204-B_140623A
Strontium 107 85 1150.100.0536 mg/L
Lab ID: H14060256-013BMS 06/23/14 14:28Sample Matrix Spike Run: ICPMS204-B_140623A
Strontium 117 70 1300.0100.0584 mg/L
Lab ID: H14060256-013BMSD 06/23/14 14:32Sample Matrix Spike Duplicate Run: ICPMS204-B_140623A
Strontium 119 70 130 200.010 1.70.0595 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 42 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E245.1 Analytical Run: HGCV202-H_140625A
Lab ID: ICV 06/25/14 10:19Initial Calibration Verification Standard
Mercury 100 90 1100.000100.00020 mg/L
Lab ID: CCV1 06/25/14 10:24Continuing Calibration Verification Standard
Mercury 103 95 1050.000100.00021 mg/L
Lab ID: CCV 06/25/14 11:31Continuing Calibration Verification Standard
Mercury 107 90 1100.000100.00021 mg/L
Lab ID: CCV 06/25/14 12:30Continuing Calibration Verification Standard
Mercury 109 90 1100.000100.00022 mg/L
Lab ID: ICV 06/25/14 13:18Initial Calibration Verification Standard
Mercury 98 90 1100.000100.00020 mg/L
Lab ID: CCV1 06/25/14 13:22Continuing Calibration Verification Standard
Mercury 101 95 1050.000100.00020 mg/L
Method: E245.1 Batch: 25051
Lab ID: MB-25051 06/25/14 10:32Method Blank Run: HGCV202-H_140625A
Mercury 1E-061E-06 mg/L
Lab ID: LCS-25051 06/25/14 10:36Laboratory Control Sample Run: HGCV202-H_140625A
Mercury 109 90 1100.000100.00016 mg/L
Lab ID: H14060256-003BMS 06/25/14 11:10Sample Matrix Spike Run: HGCV202-H_140625A
Mercury 90 70 1300.000100.00013 mg/L
Lab ID: H14060256-003BMSD 06/25/14 11:14Sample Matrix Spike Duplicate Run: HGCV202-H_140625A
Mercury 93 70 130 200.00010 3.70.00014 mg/L
Lab ID: H14060256-011BMS 06/25/14 12:01Sample Matrix Spike Run: HGCV202-H_140625A
Mercury 105 70 1300.000100.00016 mg/L
Lab ID: H14060256-011BMSD 06/25/14 12:05Sample Matrix Spike Duplicate Run: HGCV202-H_140625A
Mercury 99 70 130 200.00010 5.80.00015 mg/L
Method: E245.1 Batch: 25052
Lab ID: MB-25052 06/25/14 13:31Method Blank Run: HGCV202-H_140625A
Mercury 1E-06ND mg/L
Lab ID: LCS-25052 06/25/14 14:07Laboratory Control Sample Run: HGCV202-H_140625A
Mercury 96 90 1100.000100.00014 mg/L
Lab ID: H14060256-018CMS 06/25/14 14:20Sample Matrix Spike Run: HGCV202-H_140625A
Mercury 95 70 1300.000100.00014 mg/L
Lab ID: H14060256-018CMSD 06/25/14 14:24Sample Matrix Spike Duplicate Run: HGCV202-H_140625A
Mercury 105 70 130 200.00010 110.00016 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 43 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E300.0 Analytical Run: IC102-H_140613A
Lab ID: ICV 06/13/14 16:43Initial Calibration Verification Standard2
Chloride 103 90 1101.0100 mg/L
Sulfate 105 90 1101.0420 mg/L
Lab ID: CCV061314-3 06/13/14 22:27Continuing Calibration Verification Standard2
Chloride 107 90 1101.0110 mg/L
Sulfate 106 90 1101.0420 mg/L
Lab ID: CCV061314-4 06/14/14 01:03Continuing Calibration Verification Standard2
Chloride 107 90 1101.0110 mg/L
Sulfate 106 90 1101.0420 mg/L
Lab ID: CCV061314-5 06/14/14 03:38Continuing Calibration Verification Standard2
Chloride 107 90 1101.0110 mg/L
Sulfate 106 90 1101.0420 mg/L
Method: E300.0 Batch: R98024
Lab ID: ICB 06/13/14 16:54Method Blank Run: IC102-H_140613A2
Chloride 0.0080.04 mg/L
Sulfate 0.080.2 mg/L
Lab ID: LFB 06/13/14 17:05Laboratory Fortified Blank Run: IC102-H_140613A2
Chloride 91 90 1101.046 mg/L
Sulfate 95 90 1101.0190 mg/L
Lab ID: H14060255-015AMS 06/13/14 23:00Sample Matrix Spike Run: IC102-H_140613A2
Chloride 91 90 1101.046 mg/L
Sulfate 99 90 1101.0200 mg/L
Lab ID: H14060255-015AMSD 06/13/14 23:11Sample Matrix Spike Duplicate Run: IC102-H_140613A2
Chloride 92 90 110 201.0 1.247 mg/L
Sulfate 99 90 110 201.0 0.2200 mg/L
Lab ID: H14060256-006AMS 06/14/14 01:36Sample Matrix Spike Run: IC102-H_140613A2
Chloride 92 90 1101.047 mg/L
Sulfate 102 90 1101.0220 mg/L
Lab ID: H14060256-006AMSD 06/14/14 01:47Sample Matrix Spike Duplicate Run: IC102-H_140613A2
Chloride 92 90 110 201.0 0.347 mg/L
Sulfate 102 90 110 201.0 0.3220 mg/L
Lab ID: H14060256-016AMS 06/14/14 04:11Sample Matrix Spike Run: IC102-H_140613A2
Chloride 91 90 1101.047 mg/L
Sulfate 102 90 1101.0220 mg/L
Lab ID: H14060256-016AMSD 06/14/14 04:23Sample Matrix Spike Duplicate Run: IC102-H_140613A2
Chloride 91 90 110 201.0 0.247 mg/L
Sulfate 101 90 110 201.0 0.4220 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 44 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E351.2 Analytical Run: SUB-B225712
Lab ID: ICV 06/18/14 10:05Initial Calibration Verification Standard
Nitrogen, Kjeldahl, Total as N 100 90 1100.5010.0 mg/L
Method: E351.2 Batch: B_80615
Lab ID: MB-80615 06/18/14 10:56Method Blank Run: SUB-B225712
Nitrogen, Kjeldahl, Total as N 0.2ND mg/L
Lab ID: LCS-80615 06/18/14 10:57Laboratory Control Sample Run: SUB-B225712
Nitrogen, Kjeldahl, Total as N 102 90 1104.0255 mg/L
Lab ID: H14060256-014D 06/18/14 11:11Sample Matrix Spike Run: SUB-B225712
Nitrogen, Kjeldahl, Total as N 100 90 1100.5010.4 mg/L
Lab ID: H14060256-014D 06/18/14 11:13Sample Matrix Spike Duplicate Run: SUB-B225712
Nitrogen, Kjeldahl, Total as N 100 90 110 100.50 0.010.4 mg/L
Lab ID: B14061338-003DMS 06/18/14 14:48Sample Matrix Spike Run: SUB-B225712
Nitrogen, Kjeldahl, Total as N 90 90 1100.5010.1 mg/L
Lab ID: B14061338-003DMSD 06/18/14 14:49Sample Matrix Spike Duplicate Run: SUB-B225712
Nitrogen, Kjeldahl, Total as N 92 90 110 100.50 2.010.3 mg/L
Method: E351.2 Analytical Run: SUB-B225772
Lab ID: ICV 06/19/14 10:47Initial Calibration Verification Standard
Nitrogen, Kjeldahl, Total as N 97 90 1100.509.74 mg/L
Method: E351.2 Batch: B_80669
Lab ID: MB-80669 06/19/14 11:19Method Blank Run: SUB-B225772
Nitrogen, Kjeldahl, Total as N 0.2ND mg/L
Lab ID: LCS-80669 06/19/14 11:20Laboratory Control Sample Run: SUB-B225772
Nitrogen, Kjeldahl, Total as N 91 90 1104.0228 mg/L
Lab ID: B14061336-004DMS 06/19/14 11:35Sample Matrix Spike Run: SUB-B225772
Nitrogen, Kjeldahl, Total as N 93 90 1100.509.27 mg/L
Lab ID: B14061336-004DMSD 06/19/14 11:36Sample Matrix Spike Duplicate Run: SUB-B225772
Nitrogen, Kjeldahl, Total as N 89 90 110 100.50 4.68.85 mg/L S
Lab ID: B14061391-010CMS 06/19/14 11:49Sample Matrix Spike Run: SUB-B225772
Nitrogen, Kjeldahl, Total as N 72 90 1100.509.43 mg/L S
Lab ID: B14061391-010CMSD 06/19/14 11:51Sample Matrix Spike Duplicate Run: SUB-B225772
Nitrogen, Kjeldahl, Total as N 58 90 110 100.50 168.06 mg/L SR
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
R - RPD exceeds advisory limit. S - Spike recovery outside of advisory limits.
Page 45 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E353.2 Analytical Run: FIA203-HE_140613A
Lab ID: ICV 06/13/14 09:25Initial Calibration Verification Standard
Nitrogen, Nitrate+Nitrite as N 97 90 1100.0100.974 mg/L
Lab ID: ICB 06/13/14 09:29Initial Calibration Blank, Instrument Blank
Nitrogen, Nitrate+Nitrite as N 0 00.010-0.0105 mg/L
Lab ID: CCV 06/13/14 10:05Continuing Calibration Verification Standard
Nitrogen, Nitrate+Nitrite as N 95 90 1100.0100.474 mg/L
Lab ID: CCV 06/13/14 10:21Continuing Calibration Verification Standard
Nitrogen, Nitrate+Nitrite as N 94 90 1100.0100.471 mg/L
Lab ID: CCV 06/13/14 10:38Continuing Calibration Verification Standard
Nitrogen, Nitrate+Nitrite as N 95 90 1100.0100.474 mg/L
Method: E353.2 Batch: R97982
Lab ID: LFB 06/13/14 09:26Laboratory Fortified Blank Run: FIA203-HE_140613A
Nitrogen, Nitrate+Nitrite as N 94 90 1100.0110.938 mg/L
Lab ID: MBLK 06/13/14 09:31Method Blank Run: FIA203-HE_140613A
Nitrogen, Nitrate+Nitrite as N 0.001ND mg/L
Lab ID: H14060256-001CMS 06/13/14 10:07Sample Matrix Spike Run: FIA203-HE_140613A
Nitrogen, Nitrate+Nitrite as N 93 90 1100.0111.08 mg/L
Lab ID: H14060256-001CMSD 06/13/14 10:08Sample Matrix Spike Duplicate Run: FIA203-HE_140613A
Nitrogen, Nitrate+Nitrite as N 91 90 110 200.011 1.51.06 mg/L
Lab ID: H14060256-011CMS 06/13/14 10:24Sample Matrix Spike Run: FIA203-HE_140613A
Nitrogen, Nitrate+Nitrite as N 89 90 1100.0110.889 mg/L S
Lab ID: H14060256-011CMSD 06/13/14 10:25Sample Matrix Spike Duplicate Run: FIA203-HE_140613A
Nitrogen, Nitrate+Nitrite as N 89 90 110 200.011 0.50.885 mg/L S
Lab ID: H14060256-021DMS 06/13/14 10:40Sample Matrix Spike Run: FIA203-HE_140613A
Nitrogen, Nitrate+Nitrite as N 91 90 1100.0110.916 mg/L
Lab ID: H14060256-021DMSD 06/13/14 10:42Sample Matrix Spike Duplicate Run: FIA203-HE_140613A
Nitrogen, Nitrate+Nitrite as N 92 90 110 200.011 1.20.927 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
S - Spike recovery outside of advisory limits.
Page 46 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: E365.1 Analytical Run: FIA202-HE_140618A
Lab ID: ICV 06/18/14 08:34Initial Calibration Verification Standard
Phosphorus, Total as P 102 90 1100.0100.256 mg/L
Lab ID: ICB 06/18/14 08:36Initial Calibration Blank, Instrument Blank
Phosphorus, Total as P 0 00.0100.00328 mg/L
Lab ID: ICV 06/18/14 08:37Initial Calibration Verification Standard
Phosphorus, Total as P 102 90 1100.0100.255 mg/L
Lab ID: CCV 06/18/14 09:14Continuing Calibration Verification Standard
Phosphorus, Total as P 98 90 1100.0100.0984 mg/L
Lab ID: CCV 06/18/14 09:28Continuing Calibration Verification Standard
Phosphorus, Total as P 98 90 1100.0100.0982 mg/L
Lab ID: CCV 06/18/14 09:45Continuing Calibration Verification Standard
Phosphorus, Total as P 98 90 1100.0100.0980 mg/L
Method: E365.1 Batch: 24957
Lab ID: LCS-24957 06/18/14 09:10Laboratory Control Sample Run: FIA202-HE_140618A
Phosphorus, Total as P 97 90 1100.0100.392 mg/L
Lab ID: MB-24957 06/18/14 09:11Method Blank Run: FIA202-HE_140618A
Phosphorus, Total as P 0.0010.004 mg/L
Lab ID: H14060255-017Dms 06/18/14 09:16Sample Matrix Spike Run: FIA202-HE_140618A
Phosphorus, Total as P 99 90 1100.0100.199 mg/L
Lab ID: H14060255-017Dmsd 06/18/14 09:17Sample Matrix Spike Duplicate Run: FIA202-HE_140618A
Phosphorus, Total as P 99 90 110 200.010 0.20.200 mg/L
Lab ID: H14060256-009CMS 06/18/14 09:31Sample Matrix Spike Run: FIA202-HE_140618A
Phosphorus, Total as P 94 90 1100.0100.192 mg/L
Lab ID: H14060256-009CMSD 06/18/14 09:32Sample Matrix Spike Duplicate Run: FIA202-HE_140618A
Phosphorus, Total as P 94 90 110 200.010 0.50.193 mg/L
Method: E365.1 Batch: 24958
Lab ID: LCS-24958 06/18/14 09:41Laboratory Control Sample Run: FIA202-HE_140618A
Phosphorus, Total as P 98 90 1100.0100.393 mg/L
Lab ID: MB-24958 06/18/14 09:42Method Blank Run: FIA202-HE_140618A
Phosphorus, Total as P 0.0010.002 mg/L
Lab ID: H14060264-002BMS 06/18/14 09:52Sample Matrix Spike Run: FIA202-HE_140618A
Phosphorus, Total as P 104 90 1100.0100.306 mg/L
Lab ID: H14060264-002BMSD 06/18/14 09:53Sample Matrix Spike Duplicate Run: FIA202-HE_140618A
Phosphorus, Total as P 104 90 110 200.010 0.20.305 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 47 of 52
Project: 11048 Black Butte Copper Project
Client: Tintina Resources Inc
Work Order: H14060256
QA/QC Summary Report
06/27/14Report Date:
Analyte Result %REC RPDLow Limit High Limit RPDLimitRLUnits QualCount
Prepared by Helena, MT Branch
Method: SW7470A Analytical Run: HGCV202-H_140625A
Lab ID: ICV 06/25/14 16:45Initial Calibration Verification Standard
Mercury 97 90 1100.000100.000195 mg/L
Qualifiers:
RL - Analyte reporting limit. ND - Not detected at the reporting limit.
Page 48 of 52
Shipping container/cooler in good condition?
Custody seals intact on all shipping container(s)/cooler(s)?
Custody seals intact on all sample bottles?
Chain of custody present?
Chain of custody signed when relinquished and received?
Chain of custody agrees with sample labels?
Samples in proper container/bottle?
Sample containers intact?
Sufficient sample volume for indicated test?
All samples received within holding time?(Exclude analyses that are considered field parameterssuch as pH, DO, Res Cl, Sulfite, Ferrous Iron, etc.)
Container/Temp Blank temperature:
Water - VOA vials have zero headspace?
Water - pH acceptable upon receipt?
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
No
No
No
No
No
No
No
No
No
No
No
No
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Not Present
Not Present
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No VOA vials submitted
Not Applicable �
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1.3°C On Ice
6/12/2014Wanda Johnson
Hand Del
abb
Date Received:
Received by:
Login completed by:
Carrier name:
BL2000\sdull
6/17/2014
Reviewed by:
Reviewed Date:
Contact and Corrective Action Comments:
None
Temp Blank received in all shipping container(s)/cooler(s)? Yes No� � Not Applicable �
Lab measurement of analytes considered field parameters that require analysis within 15 minutes of sampling such as pH, Dissolved Oxygen and Residual Chlorine, are qualified as being analyzed outside of recommended holding time.
Solid/soil samples are reported on a wet weight basis (as received) unless specifically indicated. If moisture corrected, data units are typically noted as –dry. For agricultural and mining soil parameters/characteristics, all samples are dried and ground prior to sample analysis.
Standard Reporting Procedures:
Workorder Receipt Checklist
Tintina Resources Inc H14060256
Page 49 of 52
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APPENDIX B
LABORATORY QA/QC REVIEW
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BLACK BUTTE QA/QC REVIEW JUNE 2014 WORK ORDER #: H14060256
1. INTRODUCTION
This validation applies to inorganic analytes from 29 water samples collected for the Black Butte Tintina groundwater and surface water-monitoring program in June 2014. The total number of samples included 17 water samples, 2 field blanks, 2 field duplicates, and 8 field observations.
Validation procedures used are generally consistent with:
(Check all that apply) X EPA CLP National Functional Guidelines for Inorganics Data Review X Guidance on Environmental Data Verification and Data Validation EPA
QA/G-8
Overall level of validation: Contract Laboratory Program (CLP) X Standard Visual
2. DELIVERABLES
All laboratory document deliverables were present as specified in the CLP-Statement of Work (CLP-SOW) and/or the project contract. X Yes No
All documentation of field procedures was provided as required. X Yes No
3. FIELD QUALITY CONTROL SAMPLES
Blanks Please note that the highest blank value associated with any particular analyte is the blank value used for the flagging process.
DI, trip, Rinsate, or any other field blanks have been carried out at the proper Frequency. X Yes No Reported results on the field blanks are less than the contract required detection
limits (CRDL) or the project required detection limits (PRDL) if project detection limits have been specified. X Yes No
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Field duplicates
Field duplicates were collected at the proper frequency. X Yes No
Field duplicate relative percent differences (RPD’s) were within the required control limits (RPD of 20 percent or less for water matrix, 35 percent or less for soil matrix). If the sample or duplicate result is less than 5 times the PRDL, the RPD criteria are not used. In these cases, the difference between the sample and the duplicate result must be within ± the PRDL for water matrix, within ± 2 times the PRDL for soil matrix. X Yes No
4. LABORATORY PROCEDURES
Laboratory procedures followed CLP-SOW SW-846 X Methods for Chemical Analysis of Water and Wastes XRF Standard Operating Procedures
Holding times met X Yes No
Consistency with project requirements Analyses were carried out as requested. X Yes No
Project specified methods were used. X Yes No
5. DETECTION LIMITS
Reporting detection limits met project required detection limits (PRDL). Yes X No – see following notes.
NOTES: Energy Laboratories raised the reporting limit for strontium due to sample matrix on all surface water samples. However, raising the reporting limits did not seem to impact any of the data results.
6. LABORATORY BLANKS
Please note that the highest blank value associated with any particular analyte is the blank value used for the flagging process.
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Preparation blanks Preparation blanks were prepared and analyzed at the required frequency. X Yes No All the analytes in the preparation blank were less than the CRDL (or the PRDL
if a project detection limit has been specified). X Yes No
7. LABORATORY MATRIX SPIKES
A matrix spike sample (pre-digestion) was analyzed for each digestion batch and/or matrix, or as required in the CLP-SOW. X Yes No
Matrix spike recoveries were within the lab specified control limits.
Yes X No – see following table
QC Sample Id Parameter %
REC Lab Flag
Lab Advisory Limits (% REC)
B14061391-010CMS TKN 72 S 90 – 110 H14060256-011CMS N+N 89 S 90 - 110 S – Spike recovery outside of recovery limits
8. LABORATORY DUPLICATES
Laboratory duplicate samples were analyzed at the proper frequency. X Yes No
The laboratory duplicate relative percent differences (RPD’s) were within the required
control limits. Yes X No – see following table
QC Sample Id Parameter %
RPD Lab Flag
Lab Advisory Limits (% RPD)
H14060256-004ADUP TSS 6.1 R 5 H14060290-001ADUP TSS 40 R 5 H14061391-010CMSD TKN 16 R 10 R – RPD exceeds advisory limits
Matrix spike duplicate recoveries were within the lab specified control limits. Yes X No – see following table
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QC Sample Id Parameter %
REC Lab Flag
Lab Advisory Limits (% REC)
H1406139-010CMSD TKN 89 S 90 – 110 H14060256-011CMSD N+N 89 S 90 - 110 S – Spike recovery outside of recovery limits
9. LABORATORY CONTROL STANDARDS
LCSs were prepared and analyzed at the proper frequency. X Yes No
LCS recoveries were within the required control limits (80-120 percent for water, within the certified range for soils). X Yes No