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Water
Quantity and Quality
What is Water Pollution?
any physical (temperature, oxygen), chemical (mercury), or biological
(disease, sewage) change to water that adversely effects its use by living
things
Cuyahoga River, Ohio
November 1952
Some river! Chocolate-brown, oily, bubbling with subsurface gases, it oozes rather than flows. "Anyone
who falls into the Cuyahoga does not drown," Cleveland's
citizens joke grimly. "He decays.” Time Magazine,
August 1969
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Groundwater Pollution
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Types of Water Pollution
1. Biological2. Chemical3. Physical
Measured in:Percent (%)Parts per thousand (‰)Parts per million (ppm)Parts per billion (ppb)
Biological Water Pollution
1. Infectious Disease(Pathogens)
2. Oxygen-Demanding Waste
Direct (microbes in water):Typhoid, cholera, dysentery, hepatitis…
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Entamoeba histolytica
Biological Water Pollution
1. Infectious Disease(Pathogens)
2. Oxygen-Demanding Waste
Indirect(Water breeding carriers):malaria, yellow fever,west nile virus…
Treehole mosquito(carried La Crosse ensephalitis)
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Water Borne Disease
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U.S. Water Borne Disease
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Coliform Test
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Detection: Solutions:• Sewage treatment• Immunization
Biological Water Pollution
1. Infectious Disease(Pathogens)
2. Oxygen-Demanding Waste
Dissolved Oxygen
Added by: turbulent water and photosynthesis
Removed by: Increased temperature (exsolution) and respiration/decomposition
Good: > 6 ppm (mosquitoes can survive in 1 ppm)(also measured in % of maximum - Good = 60-80%)
Dissolved Carbon Dioxide
Added by: respiration/decomposition & weathered rock
Removed by: Increased temperature (exsolution) and photosynthesis
Good: 1-10 ppm (usually about 1 ppm)
Oxygen Sag
Measuring DO and other chemical properties
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Chemical Water Pollution
3. Nutrients (Fertilizers)4. Toxic Inorganic
Materials5. Persistent Organic
Pollutants (POP’s)
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Nitrogen, phosphorous
Eutrophication
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Dissolved inorganic nitrogen in Baltic Sea
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& Blue Baby Syndrome
Nitrates
• Typically: 0.1-4 ppm• Unpolluted usually below 1 ppm• Sewage pollution increase up to 20 ppm
Chemical Water Pollution
3. Nutrients (Fertilizers)4. Toxic Inorganic
Materials5. Persistent Organic
Pollutants (POP’s)
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1. Heavy metals mercury,lead, tin…
2. Super Toxic Elements Arsenic, selenium…
3. Acids, salts, chlorine4. Radioactive Isotopes
Arsenic in U.S. Waters
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Some We Will MeasureCopper• natural, fungicides, insecticides, copper pipes• can be lethal to some at 0.1 ppb, algae – 1-10 ppb, fish 500ppb• water standard 0.3 ppm
Acidity (pH)• 6.5-8.2 normal (rainwater is usually a little acidic)• >9 – harmful to fish (inc. salmon)• <5.5 releases metals in seds, bacteria die and organics don’t decay• <5 insects die and fish eggs don’t hatch• <4 lethal to adult salmon
Some We Will MeasureSalinity• Saltwater 3.5%• Freshwater 1-500 ppm• usually >100 ppm is bad for freshwater organisms• >250 ppm tastes salty (max for drinking water)
Total Dissolved Solids• (Ca,Mg,Hco3, NH4, NO3, PO4, SO4, Na, Cl, Na, K)• from dissolved rock, fertilizer, urban runoff,
irrigation, acid rainfall• “watchdog” – high numbers or rapid changes may
indicate problem• typically 50-250 ppm• Drinking water must be below 500 ppm
Chemical Water Pollution
3. Nutrients (Fertilizers)4. Toxic Inorganic
Materials5. Persistent Organic
Pollutants (POP’s)
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Artificial Chemicals
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The Dirty Dozen
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Physical Water Pollution
6. Sediment7. Thermal Pollution8. Solid Waste
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Chattahoochee River, GA
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Yellow River, China
Measured in:
NTU (Nephelometric Turbidity Units)
• Normal levels: 1-50 NTU• Drinking Water: 0.5-1
NTU• Visible: >5 NTU• Higher during storms
Physical Water Pollution
6. Sediment7. Thermal Pollution8. Solid Waste
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Causes: industry dams removal of vegetation
Optimum – Fish 5-20°C (salmon <12°C)
Physical Water Pollution
6. Sediment7. Thermal Pollution8. Solid Waste
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Pollution Sources:Point Source
1. Sewage pipes2. Leaky gas tanks3. Industrial sites4. Injection wells
Pollution Sources:Nonpoint Source
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1. Agriculture (soil, fertilizer,pesticides)2. Urban runoff (from pavement)3. Construction sites4. Air Pollution
Controlling Water Quality
What can we do?
Solutions
1. Legislation2. Source Reduction3. Improved Land Use
Practices4. Remediation5. Sewage Treatment
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Clean Water Act 1972
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1. Established water quality standards2. System for ID’ing point sources3. Pretreatment for industry4. Federal funding for sewage treatment5. Provided for enforcement
Worked well for point sources Nonpoint sources still a problem
Solutions
1. Legislation2. Source Reduction3. Improved Land Use
Practices4. Remediation5. Sewage Treatment
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1. Remove lead from gasoline2. Reduce road salting3. Decrease erosion4. Banning phosphates in detergents5. Reduce fertilizer use, etc.
Solutions
1. Legislation2. Source Reduction3. Improved Land Use
Practices4. Remediation5. Sewage Treatment
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1. Stormwater treatment2. Reduce clearcutting3. Preserve wetlands4. Better construction practices
Solutions
1. Legislation2. Source Reduction3. Improved Land Use
Practices4. Remediation5. Sewage Treatment
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Solutions
1. Legislation2. Source Reduction3. Improved Land Use
Practices4. Remediation5. Sewage Treatment
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Water hyacinths absorb arsenic
Solutions
1. Legislation2. Source Reduction3. Improved Land Use
Practices4. Remediation5. Sewage Treatment
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West Point Treatment Plant, Seattle
Sewage in King County
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