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09 September 2015
Challenge the future
DelftUniversity ofTechnology
Wastewater in the Urban Water CycleApproach and Technologies in the
Dutch Water Sector Prof.Dr.ir. Jules B. van Lier / [email protected]
WWTP Harnaschpolder
- Delft
2
Groningen
U Twente
Nijmegen
Wageningen
Utrecht
Amsterdam
Rotterdam
Leiden
Tilburg
TU Eindhoven
Maastricht
Universities in the Netherlands
TU Delft
University Students ()Utrecht University 23.000Universiteit van Amsterdam 22.000University of Groningen 20.000Erasmus University Rotterdam 16.000Vrije Universiteit Amsterdam 16.000University of Nijmegen 15.000Leiden University 15.000
Delft University of Technology 13.600Universiteit Maastricht 11.000Tilburg University 10.000Technische Universiteit Eindhoven 8.000University of Twente 8.000Wageningen University 8.000
University of Technology
QS ranking Civil/structural engineering: 13
Times Higher Education World Reputation Rankings: 51
20.000
3
Sanitary Engineering: the Urban Water Chain
Fresh
Water
Drinking
waterTreatment
Waste
Treated
Water
Household/
Economic
activitySewerage
4
Online and Campus Education
Massive Open Online Courses
(MOOCs)
Open Course Ware (OCW)
Online Distance
Education
Campus Education
• Free on EdX platform: www.edx.org
• High quality ‘Youtube’ lectures & materials
• Tutorials, homework, exam
• Massive numbers; one way direction
• Bachelors Level
• Certificate of Completion
• Free via TUD website
• Filmed campus lectures + materials
• Big Exposure, Worldwide audience
• Both Bachelor and Master level
• Unknown numbers; one way direction
• No accredited certificate
• Paid enrollment
• Learning Activities & Course Materials
• Enrolled students only, limited numbers
• Master level
• Accredited Certificate equivalent to On Campus
• Full Master Degree
• Paid enrollment
• Classic On-campus Education
• Top-class education and research facilities
• World famous university library
• Active student societies
• Great opportunities to participate in special
student projects
5
Boundary condition drinking water:
water quality
High quality water supply
• No waterborne diseases
• No chlorine
• No pesticides
• No hard water
• No corrosion and metals
• No leakage (2-3% losses)
• No need for home filters
• No need for bottled water
• No wasting of water
6
We drink from the tap…
0
50
100
150
200
lite
r p
er
pe
rso
n p
er
ye
ar
Italy
Franc
e
Bel
gium
Ger
man
y
Swis
s
Irel
and
UK
Net
herla
nds
Consumption mineral water
Bottled drinking water:
• 150 times more expensive
• 30 times higher environmental impact
Price drinking water: 1.50 - 1.70 Euro/m3
Full cost recovery
7
Drinking Water in the
Netherlands:
• Well developed organization
• Large scale infrastructure
• Specialized technologies
Groundwater
Infiltration water
Surface water
Bank filtration
11 drinking water companies
8
High quality effluents:
• Extensive C removal
• Extensive N & P removal
• Effluents for discharge
• Cost-effective management
• Full cost recovery by public taxes
(polluter pays)
• Guaranteed urban drainage
• Minimizing combined sewer overflows
• Effluents for Reuse?
• Resources from sewage?
Boundary conditions wastewater:
Effluent criteria
9Waste water treatment
Since 20th century: Management of water quality control in the Netherlands (major task!)
Who is responsible??
Water Boards /
Water Authorities:- Keeping Holland dry..! since 1200..!
- Preventing inundations
- Strategic defences
1850: 355 Water Boards2015: 22 Water Boards
(and decreasing?)
10
Water Boards very often Launching
Customer for New Developments
“Golden Triangle” research:
Universities Companies / industry
Government / Authorities
11
Regulations on wastewater treatment
• Water pollution <=> Wastewater treatment
• clean water act (1972)
• WVO: law on pollution of surfacewaters (1970): - C-removal- polluter pays!! 40-50 € (+) /p.e./year
(max 3 p.e./ household)
Obligatory sewage treatment for
- municipalities &
- industries!
12
BOD removal& nitrification
BOD removal & nitrification: Trickling
filters
14
Regulations on wastewater treatment
• International:Northsea & Rhine agreement on nutrientremoval (1990)
=> nitrogen (N): 10 mg/L=> phosphorus (P): 1 mg/L
• Low loaded activated sludge systems- extended aeration- oxidation ditches- carroussels
15
Biological process
Screen Grit
removal
Primary
settling Selector
Anaerobic
tank
Anoxic
tank
Aerobic
tank Final
clarifier
Influent Effluent
Return sludge Secondary
or Waste sludge
Optional post
Treatment
Primary
sludge
Thickener
Sludge
DigesterBiogas
Dewatering
Rejection water
treatment
Sludge treatment
WWTP Harnaschpolder
- Delft
Removes:
‘C’: BOD < 20 mg/l
‘N’: < 10 mg/l
‘P’: < 1 mg/l
Current standard
Basic WWTP process:
activated sludge &
biological nutrient
removal (BNR)
16
Regulations on wastewater treatment
• European Water Framework Directive (EWFD) (2010)Pollution load approach!
- More ‘relaxed’ in rural ‘insensitive’ areas- More stringent in congested areas
- very stringent N, P restrictions in NL- down to 2.2 mg/L N- down to 0.1 mg/L P
Need for advanced nutrients (N/P) removal in NL
- post denitrification
- sludge reject water treatment
- chemical P removal in addition to ‘bio-P’
17
Optimised N/P removal in BNR plant
Biological process
Screen Grit
removal
Primary
settling Selector
Anaerobic
tank
Anoxic
tank
Aerobic
tank Final
clarifier
Influent Effluent
Return sludge Secondary
or Waste sludge
Optional post
Treatment
Primary
sludge
Thickener
Sludge
DigesterBiogas
Dewatering
Rejection water
treatment
Sludge treatment
Babe,
Anammox
Denitrifying sand filters
Chemical P removal
18Sectie Gezondheidstechniek
Upcoming concerns in wastewater treatment
Carbon (soluble
and solids)
Increased nutrients
removal
Pathogenic organisms ?
Micro-pollutants (incl. heavy metals)
Prevention of pollution(ecosystem approach)
EWFD / KRW
N: 10/15 → 5 → 2.2
P: 1/2 → 0.3 → 0.1
19
Final effluent polishing?
Polishing effluents with membranes?
MF/PAC – aeration
Advanced oxidation of effluents?
BIO AOP
Techniques, eg.:
- O3
- H2O2 (/UV: radicals)
- Fenton Fe3+/Fe2+ catalysis
- TiO2 with UV light
..€€€€..
UF post treatment
Increased attention for micro-pollutants, pathogens, antibiotics resistance
20
MBR applications for high quality
effluents? MBR Ootmarsum
MBR Varsseveld
MBR Terneuzen
MBR Heenvliet
www.waterforum.net
www.grontmij.nl
www.mbrvarsseveld.nl
www.scheldestromen.nl
Energy costs 3-4 x more expensive!
TUD research
21
Current challenges of STPs in NL:
- More stringent discharge criteria (EWFD)
- Energy efficiency / less fossil fuel consumption
- Recovery of resources
- Reduction green house gas emissions (CH4, N2O, etc.)
- Less micro-pollutants in effluent
- No (antibiotic) resistant bacteria / pathogens in effluent
- Etc.
Current and upcoming effluent restrictions set the boundary
conditions for new developments (like resource recovery)
22
Fossil fuel concern / carbon foot print: increasing the energy efficiency
increasing sustainability
July 1, 2008: CovenantDutch Union of Water Boards & Ministry of Economic Affairs
2%/year energy eff. increaseor 30% less energy in 2020!
Where / how
to ‘extract’ the
energy out of the water??
23
Reducing the Operational Energy at
Conventional Sewage Treatment plants
Energy efficient aeration:
• fine bubble replacing surface aeration
• optimised aeration control
• compressor type/capacity
Energy efficient sludge dewatering:
• dewatering type (energy/chemicals)
• dewatering result
Miscellaneous:
• mixing and pumping requirements/design
• optimal operation (control of STP’s)
• energy efficient techniques
Measures targeting energy saving
24
Conventional STP with Anammox in
sludge reject water line:
Aeration
tank
Bar
screen
Sand
trap
Sedim.
TankSedim.
Tank
Sludge
treatment
INFLUENT
EFFLUENT
Sludge
digestion
Thickeners
3 x less energy for N removal!
air / energy
N2
AnammoxNH4
+ + NO2- →
N2 + 2H2OCHP
More COD to digestion!
25
• Tekst (Verdana 20)
• Tekst (Verdana 20)
– Tekst (Verdana 18)
• Tekst (Verdana 16)
Anammox® Reactor
Granular Biomass
* About 20 full-scale references* 70 ton N /day removed
26
Sedim.
TankSedim.
Tank
Sludge
treatment
INFLUENT
EFFLUENT
Sludge
digestion
Thickeners
Conventional Activated Sludge: Energy
Recovery via Sludge Digestion
Energy recovery !(covers 40% of current fossil use)
Energy recovery ??
Chemical energy in organic matter (= COD)
1 kg COD
13.5 MJ
3.8* kWh
5-6 times energy requirement…
Aeration tank
FossilEnergy
0.5-1.0 kWh/kg COD rem.
1 kg sludge 1.5-2.0 kg COD
6.7* kWhtheor
2.3 kWh electric (35% eff.)
27
Producing Energy at the STP ?
• Less flaring of biogas
• More efficient CHP/gasmotors
• Better operation existing sludge digesters
• New and better sludge digesters: more CH4 per ton sludge!
• Pre-treatment of sludges: Cambi, Sustech (TPH)
• More “sludge-energy” to anaerobic digesters
Increase primary sludge production
External sludge: co-digestion?
Sludge drying: dried sludge (90% DS): 10-
16 MJ/kg (lignite: 10-20; petrol: 40)
Others?
- Total sewage sludge Netherlands: 1,500,000 ton excess sludge/y (22-23% dry weight)
- Incineration costs: 500-600 € / ton DS ( 175-200 x 106 €/y)
Water Board initiative!
28
Aeration
tank
Bar
screen
Sand
trap
Sedim.
TankSedim.
Tank
Sludge
treatment
INFLUENTEFFLUENT
Sludge
digestion
Thickeners
air / energy
N2
Anammox CHP
Enhanced Primary Sludge Production
Poly electrolytes
FeCL3
Problem:Insufficient COD left for conventional N removal!
29
‘cold’
Anammox
Bar
screen
Sand
trap
Sedim.
TankSedim.
Tank
Sludge
treatment
INFLUENTEFFLUENT
Sludge
digestion
Thickeners
air / energy
N2
Anammox CHP
Poly electrolytes
FeCL3
A stage
aeration
A-B system with Anammox as B stage
Pilot reactor STP
Dokhaven, Rotterdam
30
More efficient WWTP: Delft/TUD!NEREDA: First full scale May 2012
Van Loosdrecht / De Kreuk
Granular Aerobic Sludge
Government
31
Former situation:
Activated sludge
30,000 p.e., 1,000 m3/h
Partial N-removal
Chemical P-removal
Present situation:
Granular sludge
53,000 p.e., 1,500 m3/h
N = 8 mg/l
P = 0.3 mg/l (biological)
Advantages:
35% reduction energy consumption!
75% reduction space requirement!
Decreased investment and operational costs
Highly efficient for BOD, N, P
Produced sludge mass contains bio-plastics
City of Epe: First full scale
May 2012
32
NEREDA: Application in Garmerwolde (NL)
Recent results (2015):
Original AB system (CAS) treating 60% 45% of flow
New Nereda system treating 40 55% of flow• 50-60% less energy
requirement• TN < 7 mg/L• TP < 1 mg/L
34
Resources from Sewage Treatment Plants:The “Green Deal” between Ministry & Water Authorities
Bound N
(NH4+)
Phosphate
Plastics
Energy
Proteins / biopolymersFibres
Water
?Check sustainability…!!
36
WWTP effluent use in industrialised
countries
• Growing interest in reuse of water for high quality purposes
• Secondary effluent as secure water flow
• Potential water source for agriculture, industry, households (?)
37
DOW: STP effluent upgrading
to ultra pure water
Secondary effluent Evides: Reverse Osmosis plant
to produce demiwater from City
effluent
38
The Urban Water Chain
Fresh
Water
Drinking
waterTreatment
Waste
Treated
Water
Household/
Economic
activity
Waste
water ‘well’
Cycle
‘Resource
Factory’
Energy
Nutrients
Stabilised
org.
Other?