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4

CHARACTERIZATION OF THE CONSTITUENTS OF THE STRUCTURAL CHANNELS IN BERYL

Vladimir Bermanec Darko Tibljas Stjepan Scavnicar Department of Mineralogy and Petrology Faculty of Science

University of Zagreb Demetrova I Zagreb

and

Goran Kniewald Center for Marine Research Rutter Boskovic Institute

FOB 1016 Zagreb

In addition to t~e principal elements comprising the forshymula of beryl (Be AlSi) water and carbon dioxide are al~o its essential constituents Their presence and distribution depend on the conditions prevailing durin~ the crystallization of beryl These constituents just like the lRr~P cations (Cs K ~a Li) are located within the structural channel~ which Are formed by the six-member rings of SiO~- tetrahedra

The determination of these volatile components of beryl is comparatively straightforward using IR-spectroscopy Water and carbon dioxide display well-resolved and sharp absorption maxima in the region~ 3700-3500 cm-l and 2400-2300 cm-l respecshytively The quantity of water and carbon dioxide enterin~ the beryl structure is controlled by their fugacities durni~ the crystallization process as well as by available space within the hosting structural channels

Infrared spectra were run on 25 beryls from Yugoslavia and other occurences and their compositions with respect to H 0 and

2CO2 were essentially the same An analysis of these spectra established not only the presence of water and carbon dioxide in the investigated beryls but also provided data on the orienshytation of the water molecules bull Moreover the presence or absenshyce of large cations could also be indirectly assessed

Although the concentrations of these components need not be significant even minor amounts can have profound effects with respect to the beryls symmetry and may provide an explashynation for the anomalous optical biaxiality observed on some beryl crystals

5

IoOOltPOEIIEMEHTH BO BYlIKAHClG1TE CTEEm HA KOXY4) IIJIAmmA

ESoeB Py~apcKo-reonomKH ~axynTeT MTHU

OBoj TPY~ Hua aa aen ~a BO KpaTKH apTH rH npHKaze pe3ynT8THTe ~06H

eHH eo HcnHTYBaeTo Ha cO~prKHaT8 Ha KKKpoeneueHTHTe BO BynKBBcshyKHTe CTeaH Ha Kozyt nnaHHHB 0~pe~8eTo H8 uHKpoeneueHTHT8 e BpmeHo co nouom H8 nOBeKe ueTO~

BO HHCTHTYTOT 38 reoxeuHja H UHHep8AorHj8 npH aK8~eUHjaTa Ha HayshyKHTe Ha CCCP BO MocRBa fiPH OBHe HcnHTyBae BpmeHO e o~pe~ae Ba cne~KHTe uHKpoeneueHTB py6B~Bjyu aeaHjyu nHTHjyu 68PRjyu CTP0HaHjyu aapKoHHjyu BR06HYU X~HHjyU eneueHTHTe o~ rpynaT8 a8 peTKHTe aeujH KBKO R OCTaaaTH uHKpoeneueHTH K8KO mTo ce 6epHnHjyu cK8RARjyu onOBor8nHjyu uonl 6~eH BaH8~Hjyu68K8p aHHK K06enT HHKen 60p KRB8 ~nyop H ~p

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Yuope~BajKH r Bpe~OCTBTe 3a COllPZajOT Ba Py6~jyuoT BO CTeRHTe O~ Ko~ co Bpe~HOCTHTe 38 co~pzajOT Ha P16aaxjYUOT BO CTeRHTe O~ Me~HTep8HCKHOT oporeB noj8c ~oBaraue ~o aa~oK ~eKa 80 CTeHHTe

6

04 K~ nnSHKB8 HMSMe 4sneKY noroneMS conp~HHS HS OBOj eneueHT

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116 7 1-6

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J 117 to 110-15 II III-3ftM__))

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rKSzrBS RS ~os n8Ka BO OBR8 CT8RB RyenBue peneTHBHo Mano aroneUYBsae

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7 HHTHJYIl

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x XSKO TSXBS e as 15 nSTR noroneMs 04 C04PXHBSTS BS CTPOHUHjYUOT

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ce RKounsTK6HnHH eneMeHTa HHBHOT xoe~RUHeHT RS 4RCTPH6YURjS e

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bullbull

8 9

TASEnA xxx I II COAPIAJ HA ampAPHJYHOT H CTPO~HJYHOT BO BYnKAHCKHTE CTEHH HA KOllY nIlAHHHA ( nn )

Ho Ba Sr Ho Ba Sr

l1u-35

l1u-35 32 n-I

33

7 nl-I

28 I

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10 20

27

29-1

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19 22

29

1851 1806

1983 1983 1823

1937 1588

1571 15~6

1456

1596 1706

1315 162lt

1650 1489

1745

1536 1619

1577

117~

1365 127~

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20 1265 12 38

II 78 II 27

81 1191 1187

1353 II 80

46 1281

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1198 1222

1173

l1u-3 27 11 -1

9 15 lI-6

11 -~

5 31

13 ny-I

30 6

MaK-32

HaK-30 ny-2

26 21

lI-3

1539

1315 2332 16~7

1620 1810 22~9

1605 2019 1518

1653 1772 1795 1727 1828

1851

1537 153 I

1723

~ I

930

71i

50 1029 1068 125~

81 1285 ~ I

950 1227 1292

59 1282

1320

75 IH6

86

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to UJIlCAHun CTEMM itA KOX naAMNIt

MI 0 bullbull lib Of 0 bullbull JIb

ny- SI Ja na 17 II 55 d2 5a a1 ll adO a 5 a

1116 5 JU n-1 10 ftmiddot 16 0 ISO

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xJOT bullbullbullbullbullbullbullbull co TClCa AICTII bullbull HaTobullbull CHlIIan_ac 1la

AHanSBTW~KBTe UO~STO~H 3S 60~PXBHSTS HS URPKOHHjYHOT HB06HjygOT R

XS~HHjygOT BO BynKsHCKBTe CTeHH HS Kozyt unSHRBS ce ~S~eHB BO

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DS ~o 290 DDH a CO~PZHHSTS Ha HB06BjYUOT BO rpSH~Te HS 1 us ~o

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reHepsnHo rne~aHO co~pZWHaTS HS UWPKOHBjyKOT BO BynKsHcxHTe CTSH~

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RBCKS BO O~ROC HS Co~pZHHaTS HS HB06HjYMOT W UWPKOHHjygOT BO~BqHR

CTeHH BO 3eMjRHsTs KOpS

10

ElIEUEHTH Ol IPYIJATA IrA PETIltH 3E11n1

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COAepZHH8TB HB BTPKj1UOT BO B1nKBHCKBTS CTSbullbull H8 KozyW unBHHH8 S 8AeHB BO T8~snBT8 xxxvi

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27 JZ -1 ZI n-I

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11

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c III 107 150 211 212

114 5 4l 59 77 12

s 7 5 bullbull 99 119 142

E 111 117 193 20 160

n 07 0 7 160 110

Yb 20 1 23 33 25

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418 nnu OA ApyrB CTPBHS BO~1nKBHcKRTS CTeHB HS KozyW RUSUS ronashy

uo 0~or8T1Base H8 nSCHHTS peTKR asujH 3s CTsnSHOT H8 o~orsTYBsST( ~

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HB ~8KTOT ASK8 UpMUSpHROT USTspHjan BO OCKOBB nOTSKH1B8 OA nOAp8shy

4

CHARACTERIZATION OF THE CONSTITUENTS OF THE STRUCTURAL CHANNELS IN BERYL

Vladimir Bermanec Darko Tibljas Stjepan Scavnicar Department of Mineralogy and Petrology Faculty of Science

University of Zagreb Demetrova I Zagreb

and

Goran Kniewald Center for Marine Research Rutter Boskovic Institute

FOB 1016 Zagreb

In addition to t~e principal elements comprising the forshymula of beryl (Be AlSi) water and carbon dioxide are al~o its essential constituents Their presence and distribution depend on the conditions prevailing durin~ the crystallization of beryl These constituents just like the lRr~P cations (Cs K ~a Li) are located within the structural channel~ which Are formed by the six-member rings of SiO~- tetrahedra

The determination of these volatile components of beryl is comparatively straightforward using IR-spectroscopy Water and carbon dioxide display well-resolved and sharp absorption maxima in the region~ 3700-3500 cm-l and 2400-2300 cm-l respecshytively The quantity of water and carbon dioxide enterin~ the beryl structure is controlled by their fugacities durni~ the crystallization process as well as by available space within the hosting structural channels

Infrared spectra were run on 25 beryls from Yugoslavia and other occurences and their compositions with respect to H 0 and

2CO2 were essentially the same An analysis of these spectra established not only the presence of water and carbon dioxide in the investigated beryls but also provided data on the orienshytation of the water molecules bull Moreover the presence or absenshyce of large cations could also be indirectly assessed

Although the concentrations of these components need not be significant even minor amounts can have profound effects with respect to the beryls symmetry and may provide an explashynation for the anomalous optical biaxiality observed on some beryl crystals

5

IoOOltPOEIIEMEHTH BO BYlIKAHClG1TE CTEEm HA KOXY4) IIJIAmmA

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PYSHllHJYM

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Yuope~BajKH r Bpe~OCTBTe 3a COllPZajOT Ba Py6~jyuoT BO CTeRHTe O~ Ko~ co Bpe~HOCTHTe 38 co~pzajOT Ha P16aaxjYUOT BO CTeRHTe O~ Me~HTep8HCKHOT oporeB noj8c ~oBaraue ~o aa~oK ~eKa 80 CTeHHTe

6

04 K~ nnSHKB8 HMSMe 4sneKY noroneMS conp~HHS HS OBOj eneueHT

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116 7 1-6

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J 117 to 110-15 II III-3ftM__))

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5 I n IlZ -J IZ 71

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1Mbullbullbull MroCTbullbullbull bullbullbull 0

IlE3i1JYIl

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7 HHTHJYIl

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OKOny 20 nnu

EAPHJYII bull CTPOHIlIttJYIl

C04PZHHSTS BS 6spajyuoT U CTpoRUBjYUOT e onpe4eRS KBSHTHTSTHBRO

co nOMom Ba peHTreHO ~nyopecUeBTRs MeT04S npH OBOHe HcnRTyasa ce

406KeHH nonSTOUUmiddotKO ce npHKsZ8RR BO Ts6ensTa XXXIII 04 OBsa Ts6ens ce rne~ ~exs ConpzRBSTS HS 6SpjYUOT BO BynK8HCKHT

CTeHR HS Ko~ nnSBKH8 ce 4BHZW BO rpsRKUKTS on 1515 ns 40 22~9 nn

mTO reRepsnRo rnenaRO e 3S 2 no 3 nSTH noroneMO on C04PZHHSTS BS

6apHjyuoT BO RRTepMenajspHRTe CTeRB ~o aeMjRHsTs Xops

04 OB8S Ts6ens ce rne4s 4eKS x conpZRRsTS BS CTPOHURjYUOT BO Bynxsshy

BCKKTe CTeRR RS Kozr~ ce 4BHZW BO rpSRKQaTe BS 950 na no 1565 nnM

x XSKO TSXBS e as 15 nSTR noroneMs 04 C04PXHBSTS BS CTPOHUHjYUOT

BO RRTepMenHjspHRTe CTeHR BO 3eMjHHsTS Xops

OBSKBOTO roneMO 060rSTyBsae HS 6apHjYUOT R CTPORUHjYUOT j8SHO a60shy

pyas 38 060rsTyaaaeTO B8 npBM8pRROT M8rMSTCKR pSCTon co OBHe 4B8

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ce RKounsTK6HnHH eneMeHTa HHBHOT xoe~RUHeHT RS 4RCTPH6YURjS e

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C04PZRR8TS RS IIHPKOHHjYMOT H KH06RjYUOT BO BynKBHcKKTe CTeRK HS

K~ nnsHKHS e 04pe4eHs co nOMom HS peHTreRO ~nyopecueHTHS MeT04s

S C04PZHHSTS RS xa~HajYUOT e onpe4eHs co nOMom RS HeYTpOHS SKTRBSshy

UKjS

bullbull

8 9

TASEnA xxx I II COAPIAJ HA ampAPHJYHOT H CTPO~HJYHOT BO BYnKAHCKHTE CTEHH HA KOllY nIlAHHHA ( nn )

Ho Ba Sr Ho Ba Sr

l1u-35

l1u-35 32 n-I

33

7 nl-I

28 I

18

10 20

27

29-1

HaK-31

25 n-2

19 22

29

1851 1806

1983 1983 1823

1937 1588

1571 15~6

1456

1596 1706

1315 162lt

1650 1489

1745

1536 1619

1577

117~

1365 127~

13H

20 1265 12 38

II 78 II 27

81 1191 1187

1353 II 80

46 1281

IH9

1198 1222

1173

l1u-3 27 11 -1

9 15 lI-6

11 -~

5 31

13 ny-I

30 6

MaK-32

HaK-30 ny-2

26 21

lI-3

1539

1315 2332 16~7

1620 1810 22~9

1605 2019 1518

1653 1772 1795 1727 1828

1851

1537 153 I

1723

~ I

930

71i

50 1029 1068 125~

81 1285 ~ I

950 1227 1292

59 1282

1320

75 IH6

86

AHanM3MTe ce BDweHM BO MHCTMTYTOT aa reoxeMMja M KMHeoanorMja nOM ~KaAeMMjaTa Ha HaYKMTe Ha CoaeTCKMOT CojY3 HOCX8a ( 1985 J( lIJoHoa HeToAa - PeHTreHo nygDeC~eHTHa ~ KBaHTMTaTMBHa

lI TAnJlA XtXLl toAI HA llHKOJOT bull M05MJ) 1ltUYHOT

to UJIlCAHun CTEMM itA KOX naAMNIt

MI 0 bullbull lib Of 0 bullbull JIb

ny- SI Ja na 17 II 55 d2 5a a1 ll adO a 5 a

1116 5 JU n-1 10 ftmiddot 16 0 ISO

11 51 77 1middot6 ft- UO

JIH I JU1 7J JU1 I

I I 5 150 110

~ I I I

T

I

I l no II

J 110 10 0 100 dSI

Na]] 110 7 5 IllS I

110

110 10 )2 210 bull II 0 5 no n 110 I-J 0

lSO

J 0 co nmiddot o yobullbull~bullbullshy~o ~~omiddot (a~n 1IS ) llrEM Alt eterRoc

xJOT bullbullbullbullbullbullbullbull co TClCa AICTII bullbull HaTobullbull CHlIIan_ac 1la

AHanSBTW~KBTe UO~STO~H 3S 60~PXBHSTS HS URPKOHHjYHOT HB06HjygOT R

XS~HHjygOT BO BynKsHCKBTe CTeHH HS Kozyt unSHRBS ce ~S~eHB BO

Ts6enSTS XXXIV O~ OBSS Ts6ens ce rne~s ~eKS CO~PZHHSTS HS UHPKOHH

jygOT BO BynK8HcxHTe CTeHR HS Ko~ ce ~BBXB BO rpSHR~Te HS 100

DS ~o 290 DDH a CO~PZHHSTS Ha HB06BjYUOT BO rpSH~Te HS 1 us ~o

11 DUM ~S~HBjyKOT ce ~BHZB BO rpSHUUWTe HS 54 us ~o 89 nnM

reHepsnHo rne~aHO co~pZWHaTS HS UWPKOHBjyKOT BO BynKsHcxHTe CTSH~

HS Kozyt e penSTRBHO roneMS S CO~PZBHSTS Ha HR06wjyKOT e aHOManRO

RBCKS BO O~ROC HS Co~pZHHaTS HS HB06HjYMOT W UWPKOHHjygOT BO~BqHR

CTeHH BO 3eMjRHsTs KOpS

10

ElIEUEHTH Ol IPYIJATA IrA PETIltH 3E11n1

OA eneUeHTaTe HS rpynsTB peTKH asujB BO BynKBHcKHTe CTeHH H8 Kozy~ UnSHHH8 ce OApeAsHB aTpKjYUOT nBHTBHOT QepBjYUOT H~OnHjYUOT

CBU8PHjYUOT eyppUHjYUOT TSP~HjYUOT HTSP~BjYUOT nyTeQHjYVOT

OBMS SnSUSHTB CS OApeAeHK co uouom H8 HB1TPOHCK8 8KTHB8QHOHB USTOshy

8 a HTPMj1uOT e OAPSASR co pSHTrSHO tn10pSCQeHTHB ueTOAB

COAepZHH8TB HB BTPKj1UOT BO B1nKBHCKBTS CTSbullbull H8 KozyW unBHHH8 S 8AeHB BO T8~snBT8 xxxvi

TAUDA IIXVI COIfAJ tIA ITPUYIIOT 10 UlKAMCUTI eTlN IIA ItO nnWHA (fin-)

Hbullbull IT_Jy H bull bull IIDII1middot

u 1-3 Il alllH 7 U ) l2 -)) 31

27 JZ -1 ZI n-I

23 Jl 1$ 5 7 7A-6 ZI nl- 23-III I

1$

23 31 JZ II 1$ 13

Zlr-I 5 2 7

76 5 U JZ bullbull -)2 7 alll-) 1 II bullbull -)0 5 n-z 21 1$ 3 n- 2l

2 ZI 5

AtI~1 ca ~ lIeTTIITo rJ raollbullbullbullJa

np Al bull HY_TO bullbull cbullbullbull COT CoJy O RoCII bullbull aJolllbullbullbull5 l TO bullbullrabullbullbullIIYOlllaCbullbull bullbull ( bullbullbull1oI0fG )

O OB8~ T8~en8 ce rnSAB ASK8 COAPZMH8T8 H8 HTPKj1UOT BO~K8HCKHTS CTSHH H8 Ko~ CS ABHZK BO rp8HMQRTe H8 25 uuu a T8B Bse RSKOj8

11

8HOU8nHOCT BO OAHOC HS COAPZRRBT8 HB HTPRj1uoT BO CnMQHH CTSHR OA

asujRHsTS KOpS

nOASTO~TS 3S COAPZMH8TS HS OCT8H8THTe PSTKH asujH ce ABAeHM BO

Ts~ensT8 XXXVII

TAUI XXXVII 1 C04PJ HIMT( 3[JIf 10 I1RICAHCKMH UIENM

HA ICOJ) ( TaDTop_Jan bullbull r J ) ( nn )

JCU JClS JCl9 JesIi-flt La U

c III 107 150 211 212

114 5 4l 59 77 12

s 7 5 bullbull 99 119 142

E 111 117 193 20 160

n 07 0 7 160 110

Yb 20 1 23 33 25

L 010 039 034 051 030

LaS I bullbull 11l 5 12 73

LaY II 393 US 296 lbnIYb

Q 153 1 197 112

JEt 2572 228 3013 COIl 4117

cY 0

20 272 57 76 n

)60 KbullbullpIIT OA _CTO CTpa oI lCobullbullbullocuu

n kbullbullbullbull bull J o OA A bull ollopo

ole) bullbull T-T all J Ia CTp KoaJ bullbull

Je19 nur J OA KOlj bullbull

ole nTII 0 AM na01bullbullbull

OA ASASHSTB TS~Sn8 CS rnSAB AeKB BO B1nKSKCKBTS CTSHH HB Ko~

Un8HHR8 BUSUe pSnBTHBHO roneuo 0~Or8TYBSS HB COAPZMHBTS H8 PSTKMT(

asujH M TOB 0~Or8T1BBS BORSKOR TRUOSM HS CTeHH B3HeC1BS ~PR R

418 nnu OA ApyrB CTPBHS BO~1nKBHcKRTS CTeHB HS KozyW RUSUS ronashy

uo 0~or8T1Base H8 nSCHHTS peTKR asujH 3s CTsnSHOT H8 o~orsTYBsST( ~

H8 nSCHHTS PSTKH aeuja CnyH OAHOCOT uoust1 nBHTBHOT R HTSp~j1KOT

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UOTO 0~or8T1B8S HS TBK8 H8peQSKRTS nHn enBUeHTB jSCHO 1K8Z1BB8T

HB ~8KTOT ASK8 UpMUSpHROT USTspHjan BO OCKOBB nOTSKH1B8 OA nOAp8shy

6

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-]G UJ 25 J6znmiddot2 16 n-Z IU

bullbull U 115 Il bull

116 7 1-6

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J 117 to 110-15 II III-3ftM__))

55 27 za JZ 72 ua n- U Jl 5

5 I n IlZ -J IZ 71

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1Mbullbullbull MroCTbullbullbull bullbullbull 0

IlE3i1JYIl

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middotMHjCKS Me Tons H np TOS ce n06HeHK BP84HOCT 04 OKOny 8 AnM OB8S

K9nHQRRS BS ueaHjyu BO BynxSHCKRTe CT8HH HS Ko~ nnSRRHS jSCHO

rKSzrBS RS ~os n8Ka BO OBR8 CT8RB RyenBue peneTHBHo Mano aroneUYBsae

RS C04P~HSTS Ra ue3HjyuoT BO 04HOC HS RerOBSTS cpe4Hs Bpe 4ROCT BO SHSnorR TKnOBH RS CTeHbullbull

7 HHTHJYIl

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HS 5 AnM OBOj conp~sj BS ueajYM npe4cTsByaa aBOMsnHO RH30K C04Pshy

zsj BO 04HOC RS c04pzSjOT a ueaujyuoT 3S CnaQHH CTeHH ROj H3ReCYB

OKOny 20 nnu

EAPHJYII bull CTPOHIlIttJYIl

C04PZHHSTS BS 6spajyuoT U CTpoRUBjYUOT e onpe4eRS KBSHTHTSTHBRO

co nOMom Ba peHTreHO ~nyopecUeBTRs MeT04S npH OBOHe HcnRTyasa ce

406KeHH nonSTOUUmiddotKO ce npHKsZ8RR BO Ts6ensTa XXXIII 04 OBsa Ts6ens ce rne~ ~exs ConpzRBSTS HS 6SpjYUOT BO BynK8HCKHT

CTeHR HS Ko~ nnSBKH8 ce 4BHZW BO rpsRKUKTS on 1515 ns 40 22~9 nn

mTO reRepsnRo rnenaRO e 3S 2 no 3 nSTH noroneMO on C04PZHHSTS BS

6apHjyuoT BO RRTepMenajspHRTe CTeRB ~o aeMjRHsTs Xops

04 OB8S Ts6ens ce rne4s 4eKS x conpZRRsTS BS CTPOHURjYUOT BO Bynxsshy

BCKKTe CTeRR RS Kozr~ ce 4BHZW BO rpSRKQaTe BS 950 na no 1565 nnM

x XSKO TSXBS e as 15 nSTR noroneMs 04 C04PXHBSTS BS CTPOHUHjYUOT

BO RRTepMenHjspHRTe CTeHR BO 3eMjHHsTS Xops

OBSKBOTO roneMO 060rSTyBsae HS 6apHjYUOT R CTPORUHjYUOT j8SHO a60shy

pyas 38 060rsTyaaaeTO B8 npBM8pRROT M8rMSTCKR pSCTon co OBHe 4B8

eneMeRTS

ESPRjYUOT R CTPORURjYUOT npRn8rS8T RS TSKS HSpeQeRST8 rpyn8 RS nIttH

eneMeHTR XOR BO npoueCRTe BS nspuRjsnHoTo Toneae BS npMspRROT R3shy

BOp ce KOHueRTpRpsne R 060rSTyBSne BO ~nYKnHSTS ~S3a 04HOCHO TRe

ce RKounsTK6HnHH eneMeHTa HHBHOT xoe~RUHeHT RS 4RCTPH6YURjS e

nOMSn 04 enRHRUs

UHPKOmtJY1tl Hi10EHJY1tI H IAltI)mtJYll

C04PZRR8TS RS IIHPKOHHjYMOT H KH06RjYUOT BO BynKBHcKKTe CTeRK HS

K~ nnsHKHS e 04pe4eHs co nOMom HS peHTreRO ~nyopecueHTHS MeT04s

S C04PZHHSTS RS xa~HajYUOT e onpe4eHs co nOMom RS HeYTpOHS SKTRBSshy

UKjS

bullbull

8 9

TASEnA xxx I II COAPIAJ HA ampAPHJYHOT H CTPO~HJYHOT BO BYnKAHCKHTE CTEHH HA KOllY nIlAHHHA ( nn )

Ho Ba Sr Ho Ba Sr

l1u-35

l1u-35 32 n-I

33

7 nl-I

28 I

18

10 20

27

29-1

HaK-31

25 n-2

19 22

29

1851 1806

1983 1983 1823

1937 1588

1571 15~6

1456

1596 1706

1315 162lt

1650 1489

1745

1536 1619

1577

117~

1365 127~

13H

20 1265 12 38

II 78 II 27

81 1191 1187

1353 II 80

46 1281

IH9

1198 1222

1173

l1u-3 27 11 -1

9 15 lI-6

11 -~

5 31

13 ny-I

30 6

MaK-32

HaK-30 ny-2

26 21

lI-3

1539

1315 2332 16~7

1620 1810 22~9

1605 2019 1518

1653 1772 1795 1727 1828

1851

1537 153 I

1723

~ I

930

71i

50 1029 1068 125~

81 1285 ~ I

950 1227 1292

59 1282

1320

75 IH6

86

AHanM3MTe ce BDweHM BO MHCTMTYTOT aa reoxeMMja M KMHeoanorMja nOM ~KaAeMMjaTa Ha HaYKMTe Ha CoaeTCKMOT CojY3 HOCX8a ( 1985 J( lIJoHoa HeToAa - PeHTreHo nygDeC~eHTHa ~ KBaHTMTaTMBHa

lI TAnJlA XtXLl toAI HA llHKOJOT bull M05MJ) 1ltUYHOT

to UJIlCAHun CTEMM itA KOX naAMNIt

MI 0 bullbull lib Of 0 bullbull JIb

ny- SI Ja na 17 II 55 d2 5a a1 ll adO a 5 a

1116 5 JU n-1 10 ftmiddot 16 0 ISO

11 51 77 1middot6 ft- UO

JIH I JU1 7J JU1 I

I I 5 150 110

~ I I I

T

I

I l no II

J 110 10 0 100 dSI

Na]] 110 7 5 IllS I

110

110 10 )2 210 bull II 0 5 no n 110 I-J 0

lSO

J 0 co nmiddot o yobullbull~bullbullshy~o ~~omiddot (a~n 1IS ) llrEM Alt eterRoc

xJOT bullbullbullbullbullbullbullbull co TClCa AICTII bullbull HaTobullbull CHlIIan_ac 1la

AHanSBTW~KBTe UO~STO~H 3S 60~PXBHSTS HS URPKOHHjYHOT HB06HjygOT R

XS~HHjygOT BO BynKsHCKBTe CTeHH HS Kozyt unSHRBS ce ~S~eHB BO

Ts6enSTS XXXIV O~ OBSS Ts6ens ce rne~s ~eKS CO~PZHHSTS HS UHPKOHH

jygOT BO BynK8HcxHTe CTeHR HS Ko~ ce ~BBXB BO rpSHR~Te HS 100

DS ~o 290 DDH a CO~PZHHSTS Ha HB06BjYUOT BO rpSH~Te HS 1 us ~o

11 DUM ~S~HBjyKOT ce ~BHZB BO rpSHUUWTe HS 54 us ~o 89 nnM

reHepsnHo rne~aHO co~pZWHaTS HS UWPKOHBjyKOT BO BynKsHcxHTe CTSH~

HS Kozyt e penSTRBHO roneMS S CO~PZBHSTS Ha HR06wjyKOT e aHOManRO

RBCKS BO O~ROC HS Co~pZHHaTS HS HB06HjYMOT W UWPKOHHjygOT BO~BqHR

CTeHH BO 3eMjRHsTs KOpS

10

ElIEUEHTH Ol IPYIJATA IrA PETIltH 3E11n1

OA eneUeHTaTe HS rpynsTB peTKH asujB BO BynKBHcKHTe CTeHH H8 Kozy~ UnSHHH8 ce OApeAsHB aTpKjYUOT nBHTBHOT QepBjYUOT H~OnHjYUOT

CBU8PHjYUOT eyppUHjYUOT TSP~HjYUOT HTSP~BjYUOT nyTeQHjYVOT

OBMS SnSUSHTB CS OApeAeHK co uouom H8 HB1TPOHCK8 8KTHB8QHOHB USTOshy

8 a HTPMj1uOT e OAPSASR co pSHTrSHO tn10pSCQeHTHB ueTOAB

COAepZHH8TB HB BTPKj1UOT BO B1nKBHCKBTS CTSbullbull H8 KozyW unBHHH8 S 8AeHB BO T8~snBT8 xxxvi

TAUDA IIXVI COIfAJ tIA ITPUYIIOT 10 UlKAMCUTI eTlN IIA ItO nnWHA (fin-)

Hbullbull IT_Jy H bull bull IIDII1middot

u 1-3 Il alllH 7 U ) l2 -)) 31

27 JZ -1 ZI n-I

23 Jl 1$ 5 7 7A-6 ZI nl- 23-III I

1$

23 31 JZ II 1$ 13

Zlr-I 5 2 7

76 5 U JZ bullbull -)2 7 alll-) 1 II bullbull -)0 5 n-z 21 1$ 3 n- 2l

2 ZI 5

AtI~1 ca ~ lIeTTIITo rJ raollbullbullbullJa

np Al bull HY_TO bullbull cbullbullbull COT CoJy O RoCII bullbull aJolllbullbullbull5 l TO bullbullrabullbullbullIIYOlllaCbullbull bullbull ( bullbullbull1oI0fG )

O OB8~ T8~en8 ce rnSAB ASK8 COAPZMH8T8 H8 HTPKj1UOT BO~K8HCKHTS CTSHH H8 Ko~ CS ABHZK BO rp8HMQRTe H8 25 uuu a T8B Bse RSKOj8

11

8HOU8nHOCT BO OAHOC HS COAPZRRBT8 HB HTPRj1uoT BO CnMQHH CTSHR OA

asujRHsTS KOpS

nOASTO~TS 3S COAPZMH8TS HS OCT8H8THTe PSTKH asujH ce ABAeHM BO

Ts~ensT8 XXXVII

TAUI XXXVII 1 C04PJ HIMT( 3[JIf 10 I1RICAHCKMH UIENM

HA ICOJ) ( TaDTop_Jan bullbull r J ) ( nn )

JCU JClS JCl9 JesIi-flt La U

c III 107 150 211 212

114 5 4l 59 77 12

s 7 5 bullbull 99 119 142

E 111 117 193 20 160

n 07 0 7 160 110

Yb 20 1 23 33 25

L 010 039 034 051 030

LaS I bullbull 11l 5 12 73

LaY II 393 US 296 lbnIYb

Q 153 1 197 112

JEt 2572 228 3013 COIl 4117

cY 0

20 272 57 76 n

)60 KbullbullpIIT OA _CTO CTpa oI lCobullbullbullocuu

n kbullbullbullbull bull J o OA A bull ollopo

ole) bullbull T-T all J Ia CTp KoaJ bullbull

Je19 nur J OA KOlj bullbull

ole nTII 0 AM na01bullbullbull

OA ASASHSTB TS~Sn8 CS rnSAB AeKB BO B1nKSKCKBTS CTSHH HB Ko~

Un8HHR8 BUSUe pSnBTHBHO roneuo 0~Or8TYBSS HB COAPZMHBTS H8 PSTKMT(

asujH M TOB 0~Or8T1BBS BORSKOR TRUOSM HS CTeHH B3HeC1BS ~PR R

418 nnu OA ApyrB CTPBHS BO~1nKBHcKRTS CTeHB HS KozyW RUSUS ronashy

uo 0~or8T1Base H8 nSCHHTS peTKR asujH 3s CTsnSHOT H8 o~orsTYBsST( ~

H8 nSCHHTS PSTKH aeuja CnyH OAHOCOT uoust1 nBHTBHOT R HTSp~j1KOT

PenBTRBKo roneUOTO 0~OrsTYBs8 H8 neCHRTS PSTKM aeujR KBKO R roneshy

UOTO 0~or8T1B8S HS TBK8 H8peQSKRTS nHn enBUeHTB jSCHO 1K8Z1BB8T

HB ~8KTOT ASK8 UpMUSpHROT USTspHjan BO OCKOBB nOTSKH1B8 OA nOAp8shy

bullbull

8 9

TASEnA xxx I II COAPIAJ HA ampAPHJYHOT H CTPO~HJYHOT BO BYnKAHCKHTE CTEHH HA KOllY nIlAHHHA ( nn )

Ho Ba Sr Ho Ba Sr

l1u-35

l1u-35 32 n-I

33

7 nl-I

28 I

18

10 20

27

29-1

HaK-31

25 n-2

19 22

29

1851 1806

1983 1983 1823

1937 1588

1571 15~6

1456

1596 1706

1315 162lt

1650 1489

1745

1536 1619

1577

117~

1365 127~

13H

20 1265 12 38

II 78 II 27

81 1191 1187

1353 II 80

46 1281

IH9

1198 1222

1173

l1u-3 27 11 -1

9 15 lI-6

11 -~

5 31

13 ny-I

30 6

MaK-32

HaK-30 ny-2

26 21

lI-3

1539

1315 2332 16~7

1620 1810 22~9

1605 2019 1518

1653 1772 1795 1727 1828

1851

1537 153 I

1723

~ I

930

71i

50 1029 1068 125~

81 1285 ~ I

950 1227 1292

59 1282

1320

75 IH6

86

AHanM3MTe ce BDweHM BO MHCTMTYTOT aa reoxeMMja M KMHeoanorMja nOM ~KaAeMMjaTa Ha HaYKMTe Ha CoaeTCKMOT CojY3 HOCX8a ( 1985 J( lIJoHoa HeToAa - PeHTreHo nygDeC~eHTHa ~ KBaHTMTaTMBHa

lI TAnJlA XtXLl toAI HA llHKOJOT bull M05MJ) 1ltUYHOT

to UJIlCAHun CTEMM itA KOX naAMNIt

MI 0 bullbull lib Of 0 bullbull JIb

ny- SI Ja na 17 II 55 d2 5a a1 ll adO a 5 a

1116 5 JU n-1 10 ftmiddot 16 0 ISO

11 51 77 1middot6 ft- UO

JIH I JU1 7J JU1 I

I I 5 150 110

~ I I I

T

I

I l no II

J 110 10 0 100 dSI

Na]] 110 7 5 IllS I

110

110 10 )2 210 bull II 0 5 no n 110 I-J 0

lSO

J 0 co nmiddot o yobullbull~bullbullshy~o ~~omiddot (a~n 1IS ) llrEM Alt eterRoc

xJOT bullbullbullbullbullbullbullbull co TClCa AICTII bullbull HaTobullbull CHlIIan_ac 1la

AHanSBTW~KBTe UO~STO~H 3S 60~PXBHSTS HS URPKOHHjYHOT HB06HjygOT R

XS~HHjygOT BO BynKsHCKBTe CTeHH HS Kozyt unSHRBS ce ~S~eHB BO

Ts6enSTS XXXIV O~ OBSS Ts6ens ce rne~s ~eKS CO~PZHHSTS HS UHPKOHH

jygOT BO BynK8HcxHTe CTeHR HS Ko~ ce ~BBXB BO rpSHR~Te HS 100

DS ~o 290 DDH a CO~PZHHSTS Ha HB06BjYUOT BO rpSH~Te HS 1 us ~o

11 DUM ~S~HBjyKOT ce ~BHZB BO rpSHUUWTe HS 54 us ~o 89 nnM

reHepsnHo rne~aHO co~pZWHaTS HS UWPKOHBjyKOT BO BynKsHcxHTe CTSH~

HS Kozyt e penSTRBHO roneMS S CO~PZBHSTS Ha HR06wjyKOT e aHOManRO

RBCKS BO O~ROC HS Co~pZHHaTS HS HB06HjYMOT W UWPKOHHjygOT BO~BqHR

CTeHH BO 3eMjRHsTs KOpS

10

ElIEUEHTH Ol IPYIJATA IrA PETIltH 3E11n1

OA eneUeHTaTe HS rpynsTB peTKH asujB BO BynKBHcKHTe CTeHH H8 Kozy~ UnSHHH8 ce OApeAsHB aTpKjYUOT nBHTBHOT QepBjYUOT H~OnHjYUOT

CBU8PHjYUOT eyppUHjYUOT TSP~HjYUOT HTSP~BjYUOT nyTeQHjYVOT

OBMS SnSUSHTB CS OApeAeHK co uouom H8 HB1TPOHCK8 8KTHB8QHOHB USTOshy

8 a HTPMj1uOT e OAPSASR co pSHTrSHO tn10pSCQeHTHB ueTOAB

COAepZHH8TB HB BTPKj1UOT BO B1nKBHCKBTS CTSbullbull H8 KozyW unBHHH8 S 8AeHB BO T8~snBT8 xxxvi

TAUDA IIXVI COIfAJ tIA ITPUYIIOT 10 UlKAMCUTI eTlN IIA ItO nnWHA (fin-)

Hbullbull IT_Jy H bull bull IIDII1middot

u 1-3 Il alllH 7 U ) l2 -)) 31

27 JZ -1 ZI n-I

23 Jl 1$ 5 7 7A-6 ZI nl- 23-III I

1$

23 31 JZ II 1$ 13

Zlr-I 5 2 7

76 5 U JZ bullbull -)2 7 alll-) 1 II bullbull -)0 5 n-z 21 1$ 3 n- 2l

2 ZI 5

AtI~1 ca ~ lIeTTIITo rJ raollbullbullbullJa

np Al bull HY_TO bullbull cbullbullbull COT CoJy O RoCII bullbull aJolllbullbullbull5 l TO bullbullrabullbullbullIIYOlllaCbullbull bullbull ( bullbullbull1oI0fG )

O OB8~ T8~en8 ce rnSAB ASK8 COAPZMH8T8 H8 HTPKj1UOT BO~K8HCKHTS CTSHH H8 Ko~ CS ABHZK BO rp8HMQRTe H8 25 uuu a T8B Bse RSKOj8

11

8HOU8nHOCT BO OAHOC HS COAPZRRBT8 HB HTPRj1uoT BO CnMQHH CTSHR OA

asujRHsTS KOpS

nOASTO~TS 3S COAPZMH8TS HS OCT8H8THTe PSTKH asujH ce ABAeHM BO

Ts~ensT8 XXXVII

TAUI XXXVII 1 C04PJ HIMT( 3[JIf 10 I1RICAHCKMH UIENM

HA ICOJ) ( TaDTop_Jan bullbull r J ) ( nn )

JCU JClS JCl9 JesIi-flt La U

c III 107 150 211 212

114 5 4l 59 77 12

s 7 5 bullbull 99 119 142

E 111 117 193 20 160

n 07 0 7 160 110

Yb 20 1 23 33 25

L 010 039 034 051 030

LaS I bullbull 11l 5 12 73

LaY II 393 US 296 lbnIYb

Q 153 1 197 112

JEt 2572 228 3013 COIl 4117

cY 0

20 272 57 76 n

)60 KbullbullpIIT OA _CTO CTpa oI lCobullbullbullocuu

n kbullbullbullbull bull J o OA A bull ollopo

ole) bullbull T-T all J Ia CTp KoaJ bullbull

Je19 nur J OA KOlj bullbull

ole nTII 0 AM na01bullbullbull

OA ASASHSTB TS~Sn8 CS rnSAB AeKB BO B1nKSKCKBTS CTSHH HB Ko~

Un8HHR8 BUSUe pSnBTHBHO roneuo 0~Or8TYBSS HB COAPZMHBTS H8 PSTKMT(

asujH M TOB 0~Or8T1BBS BORSKOR TRUOSM HS CTeHH B3HeC1BS ~PR R

418 nnu OA ApyrB CTPBHS BO~1nKBHcKRTS CTeHB HS KozyW RUSUS ronashy

uo 0~or8T1Base H8 nSCHHTS peTKR asujH 3s CTsnSHOT H8 o~orsTYBsST( ~

H8 nSCHHTS PSTKH aeuja CnyH OAHOCOT uoust1 nBHTBHOT R HTSp~j1KOT

PenBTRBKo roneUOTO 0~OrsTYBs8 H8 neCHRTS PSTKM aeujR KBKO R roneshy

UOTO 0~or8T1B8S HS TBK8 H8peQSKRTS nHn enBUeHTB jSCHO 1K8Z1BB8T

HB ~8KTOT ASK8 UpMUSpHROT USTspHjan BO OCKOBB nOTSKH1B8 OA nOAp8shy

10

ElIEUEHTH Ol IPYIJATA IrA PETIltH 3E11n1

OA eneUeHTaTe HS rpynsTB peTKH asujB BO BynKBHcKHTe CTeHH H8 Kozy~ UnSHHH8 ce OApeAsHB aTpKjYUOT nBHTBHOT QepBjYUOT H~OnHjYUOT

CBU8PHjYUOT eyppUHjYUOT TSP~HjYUOT HTSP~BjYUOT nyTeQHjYVOT

OBMS SnSUSHTB CS OApeAeHK co uouom H8 HB1TPOHCK8 8KTHB8QHOHB USTOshy

8 a HTPMj1uOT e OAPSASR co pSHTrSHO tn10pSCQeHTHB ueTOAB

COAepZHH8TB HB BTPKj1UOT BO B1nKBHCKBTS CTSbullbull H8 KozyW unBHHH8 S 8AeHB BO T8~snBT8 xxxvi

TAUDA IIXVI COIfAJ tIA ITPUYIIOT 10 UlKAMCUTI eTlN IIA ItO nnWHA (fin-)

Hbullbull IT_Jy H bull bull IIDII1middot

u 1-3 Il alllH 7 U ) l2 -)) 31

27 JZ -1 ZI n-I

23 Jl 1$ 5 7 7A-6 ZI nl- 23-III I

1$

23 31 JZ II 1$ 13

Zlr-I 5 2 7

76 5 U JZ bullbull -)2 7 alll-) 1 II bullbull -)0 5 n-z 21 1$ 3 n- 2l

2 ZI 5

AtI~1 ca ~ lIeTTIITo rJ raollbullbullbullJa

np Al bull HY_TO bullbull cbullbullbull COT CoJy O RoCII bullbull aJolllbullbullbull5 l TO bullbullrabullbullbullIIYOlllaCbullbull bullbull ( bullbullbull1oI0fG )

O OB8~ T8~en8 ce rnSAB ASK8 COAPZMH8T8 H8 HTPKj1UOT BO~K8HCKHTS CTSHH H8 Ko~ CS ABHZK BO rp8HMQRTe H8 25 uuu a T8B Bse RSKOj8

11

8HOU8nHOCT BO OAHOC HS COAPZRRBT8 HB HTPRj1uoT BO CnMQHH CTSHR OA

asujRHsTS KOpS

nOASTO~TS 3S COAPZMH8TS HS OCT8H8THTe PSTKH asujH ce ABAeHM BO

Ts~ensT8 XXXVII

TAUI XXXVII 1 C04PJ HIMT( 3[JIf 10 I1RICAHCKMH UIENM

HA ICOJ) ( TaDTop_Jan bullbull r J ) ( nn )

JCU JClS JCl9 JesIi-flt La U

c III 107 150 211 212

114 5 4l 59 77 12

s 7 5 bullbull 99 119 142

E 111 117 193 20 160

n 07 0 7 160 110

Yb 20 1 23 33 25

L 010 039 034 051 030

LaS I bullbull 11l 5 12 73

LaY II 393 US 296 lbnIYb

Q 153 1 197 112

JEt 2572 228 3013 COIl 4117

cY 0

20 272 57 76 n

)60 KbullbullpIIT OA _CTO CTpa oI lCobullbullbullocuu

n kbullbullbullbull bull J o OA A bull ollopo

ole) bullbull T-T all J Ia CTp KoaJ bullbull

Je19 nur J OA KOlj bullbull

ole nTII 0 AM na01bullbullbull

OA ASASHSTB TS~Sn8 CS rnSAB AeKB BO B1nKSKCKBTS CTSHH HB Ko~

Un8HHR8 BUSUe pSnBTHBHO roneuo 0~Or8TYBSS HB COAPZMHBTS H8 PSTKMT(

asujH M TOB 0~Or8T1BBS BORSKOR TRUOSM HS CTeHH B3HeC1BS ~PR R

418 nnu OA ApyrB CTPBHS BO~1nKBHcKRTS CTeHB HS KozyW RUSUS ronashy

uo 0~or8T1Base H8 nSCHHTS peTKR asujH 3s CTsnSHOT H8 o~orsTYBsST( ~

H8 nSCHHTS PSTKH aeuja CnyH OAHOCOT uoust1 nBHTBHOT R HTSp~j1KOT

PenBTRBKo roneUOTO 0~OrsTYBs8 H8 neCHRTS PSTKM aeujR KBKO R roneshy

UOTO 0~or8T1B8S HS TBK8 H8peQSKRTS nHn enBUeHTB jSCHO 1K8Z1BB8T

HB ~8KTOT ASK8 UpMUSpHROT USTspHjan BO OCKOBB nOTSKH1B8 OA nOAp8shy

12 13

~jSTS BO 3eujsTs KSne HUaUe roneuo MemSampe Ha uSTepKjsnx on KOHTHshyflHTEPATYPA

HeHTsnHSTS KOpS KropHROT OUOTS~ onHOCHO on rpSH~HOTO nonpa~je

HS KOHTRueaTsnHSTS KOpS bull ropHKOT OMOTS~

OCTUlATM IIKKPO EJIEIIEHTH ARTH3G (1976) BEHAVOIR OF TRACE ELEMENTS DURING MAGMATIC PROCESES

A SUMARY OF THEORETICAL MODELS AND THEIR APLICATION ConprwHSTS HS OCTSHSTKTe UHKpO eneueaTK e nSneHS BO Ts6enSTS 6poj

30ur Research US Geol Survey4p41-47XXXVIII

AUBOIN3 BLANCHETR CADETJP CELETP CHARVETJCHORONOWICZJ

COUSINM AND RAMPNOUX3P ( 1970 ) ESSAI SUR LA GEOLOGIE DES DINAmiddot KBapnaTI4TIof naTMTH ~aTHT-KB3p~~aTHTM RIDES Bul Soc Geol France 12 pl060-1095

ALTHERR KREUZERH WENDII LENZH WAGNERAG KELLERJ

Sc 30 30

Be 1 1 HERREW HONDORFA ( 1982 ) A LATE OLIGOCENE EARLY MIOCENE HIGH

20 TEMPERATURE BELT IN THE ATTIC CICLADYC CRISTALINEPb 200 200 100 COMPLEX (SE PELAGONIAN GRECCE) Geol 3b E23Ga 30 30 40 97-164 Hanover 1982Mo 1 1 3

V 20 100 100 AOKIK ( 1963 ) THE KERSUTITES OND AHYKEARSUTITES FROM ALKALIC Cu ROCK OF 3APAN AND SURROUNDING AREAS 3 bull Petr 4 Zn 20 20

30 100 30 198-210

Co 10 30 30 30 KAPAHATAC bullbull ( 1983 ) CAAPIAJH HEKHX HHKPOEflEHEHATA Y TEPUHJAPHHH

Ni 10 30 30 HArHATHTHHA HCT04Hor AEflA JyrOCflABHJE Y 3ABHCHOCTH O~B 10 30 40 ItHXOeOr rEOTEKTOHCKor nOflOIAJA OTHCaj 143 rnACA CpncIltRg 001 001 001 AKaAeMHje HaYKa 14 YMeTHOCTH K~~9F 900 600 1300

KAPAHATAC bullbull (197~) bullbull rEOXEHHJCKE nETPOflOWKE 14 HETAflOrEHETCKE npOBHH

UHJE KPEAHO-TEPUHJAPHE CTAPOCTH AEflA SAflKAHCKOr nOflYOshysite e1ementi osven Hg se odredeni so semikvantitativna spektroheshy CTPOBA H KAflE A3HJE nOce~Ha M3Aa~a CpncKe AK3AeMHJe mijska analiza (D30nov 1985 ) a Hg e odredena so hemijska metoda HaYKa 14 YHeTHocTH K~Hra ~2 bullbull ( NOzerova 1986 )

KAPAHATAC (1983) OCOSEHOCTH H nOJABYB~HBAItE TEKTOHHKE nn04A Y OSflA

CTH THnA TETHCA reoTeKToHHK3 Ho5 1983On OBSS Ta6ens ee rnens neKs BO BynKSHCK1Te creBB HS Ko~ nnSUHS

Rusue penSTBBRO 06erSTyBSampe as conpzsjoT RS onOBOTO BO onROC RS KARAMATAS (1973) ASSOCIATION OF BASIC AND ULTRAB~SIC( ULTRAMAFIC

RerOBSTS cpenHS BpenHOCT COnpzRHSTS HS 6SKSPOT e RCTO TSKS pensshy ROCKS IN YUGOSLAVIA SectVIMagmatism Volcanism

TRBRO usnKY aroneueRS S aroneueHS e K conprwHSTS HS ypSROT HHTeshy Metamorphism Proc of the X th Conqres CBGA 1973

peCHO e neKS BO BynKsHcKHTe CTeBB HS Ko~ Kusue K pensTHBHo o60rsshy

TyBse BO ConpzKHsTsas 60POT K ~nyOpOT TO jacHo yxa~a Ha 3Rs~eshy

BBeTO HS TaKS Hape~eRsTa eUsHsQBjcKs nHtepeHURjaQRjs

14

SUMr1ARY

MICROELEI1ENTS IN THE VOICANIC ROCKS OF KO~UF 110UNTAIN

BBoev Faculty of Geology ~d Mining Stip

A systematic determination of the content of the microelements and the elements of the rare earths was done for the volcanics of the

Kozuf 110untain

Main characteristic of these volcanic rocks is that they are rich in barium and stroncium as well as the other LIL Large Ion Litophile I

elements

These rocks are also enriched in elements of the group of rare earth~ especially in light rare earths

This is a very important characteristic which basically diferenti _ ates them from other tertiary volcanites in 11acedonia bull

I

15

MmiEPAJIOIHKA CTYJmJA HA ~EHOKmCTAJrnTE 011 BYJIKAHCKt1TE

CTEmi HA KOlKY~ II1IAlOOIA

BBoeB PynspcKo-reonomKH ~sKynTeT - mTHn

OnpenyBs~eTo HS THnOT H xeUH3UOT HS rnSBHHTe KHHepSnH on BynKsHcKHTe CTeHH HS Kozy~ nnSHHHS 6eme pesnH3HpSHO BO nepHonOT HS 1985 ronHHS HS YHHBep3HTeToT BO reTHHreH S non pSKOBonCTBO HS np~purspn BOHrT OnpenyBs~eTo 6eme H3BpmeHO co uouom BS eneKTpOHCKS UHKpOCOHnS on THn ( APJI - CEM )

TIPH OB8S onpenyB~e HS rnSBHHTe UHHepSDK aeueHH ce upHuepo~ on Bsjshya8CTsneHHTe CTeBK BO pSUKHTe BS BYnKSHCKHOT KounneKC HS Kozy~ unSHHHE TIPH oBHe HCnHTyBS~S ce n06HeHK noroneu 6poj BS uonSToaH HO uopsnu OrpSHHqeHOCTS HS npoCTopOT oBneKS ce npKKSZSHH csuo nen on HHB KSKO rnSBHH uHHepsnH BO BynKsHcKHTe CTeHH HS Kozy~ nnSHHHS ce onpeshyneHH nnsrHoKnSCH K-~enncnST nHCKyHH nKpoKceHH OCTSH~HOT nen on CTeH8TS ro qHHH UHKPOKpHCTsneCTSTS OCHoBBS KSCS qHj COCTSB e HCTO TSKS onpeneH HO TOj Hee upenueT HS OBOj Tpyn

TIJIAr~OKJIAC~

TIn8rHoKnSCHTe ce HSj3scTsneHH KKHepsnH BO psuKHTeHS BynKsBcKHTe CTeshyHH HS Kozy~ nnsHHHs THe upBeHcTBeHo ce UOjSByBSST KSKO ~eHOKpHCTsnH

S ce nojsBYBSST H KSKO uHKponHTH BO OCHOBHSTS uscs Tpe6s ns BsuoueshyHSK neKs BO OBOj Tpyn Ke 6HnST UPHKSZSHK CSUO pe3ynTsTHTe n06HeHH co nOKom HS eDKTpoHCKS MHKpO COHns S KHKpO~H3HOBpstcKHTe KspSKTepHCTHKH He ce COCTSBeH nen HS OBOj Tpyn Hs 6S3S HS roneuHoT 6poj HS Kepe~s H3BpmeHH co nouom HS eDeKTpoHcKS KHKpocoHns BO nnSrHOKnSCHTe on Kozyt UDSHHHS ce 3s6eneZBHH TpH cnyshyqSeBH KOH ce onHeCyBSST HS xouoreHHTeTOT HS apHsTs H nHncTpH6y~jsTs

HS uoenHHHTe KounOH8HTH BO HHB

1 Cnyqsj Kors Husue HopusnHs aOHsnHocT onHocHo conpzHHSTS HS KsnaHjyuoT ousrs onejKH on aeHTpsDHHTe nenOBK HS apHsTs KOH uepH~epHshyJSTS S npH TOS pSCTe conpZHHSTS HS sn6HTCKSTS KOUUOHeHTS

2 Cnyqsj Kors HKsue OCUHnsawu BO COCTSBOT BS UDsrHoKnscHTe

14

SUMr1ARY

MICROELEI1ENTS IN THE VOICANIC ROCKS OF KO~UF 110UNTAIN

BBoev Faculty of Geology ~d Mining Stip

A systematic determination of the content of the microelements and the elements of the rare earths was done for the volcanics of the

Kozuf 110untain

Main characteristic of these volcanic rocks is that they are rich in barium and stroncium as well as the other LIL Large Ion Litophile I

elements

These rocks are also enriched in elements of the group of rare earth~ especially in light rare earths

This is a very important characteristic which basically diferenti _ ates them from other tertiary volcanites in 11acedonia bull

I

15

MmiEPAJIOIHKA CTYJmJA HA ~EHOKmCTAJrnTE 011 BYJIKAHCKt1TE

CTEmi HA KOlKY~ II1IAlOOIA

BBoeB PynspcKo-reonomKH ~sKynTeT - mTHn

OnpenyBs~eTo HS THnOT H xeUH3UOT HS rnSBHHTe KHHepSnH on BynKsHcKHTe CTeHH HS Kozy~ nnSHHHS 6eme pesnH3HpSHO BO nepHonOT HS 1985 ronHHS HS YHHBep3HTeToT BO reTHHreH S non pSKOBonCTBO HS np~purspn BOHrT OnpenyBs~eTo 6eme H3BpmeHO co uouom BS eneKTpOHCKS UHKpOCOHnS on THn ( APJI - CEM )

TIPH OB8S onpenyB~e HS rnSBHHTe UHHepSDK aeueHH ce upHuepo~ on Bsjshya8CTsneHHTe CTeBK BO pSUKHTe BS BYnKSHCKHOT KounneKC HS Kozy~ unSHHHE TIPH oBHe HCnHTyBS~S ce n06HeHK noroneu 6poj BS uonSToaH HO uopsnu OrpSHHqeHOCTS HS npoCTopOT oBneKS ce npKKSZSHH csuo nen on HHB KSKO rnSBHH uHHepsnH BO BynKsHcKHTe CTeHH HS Kozy~ nnSHHHS ce onpeshyneHH nnsrHoKnSCH K-~enncnST nHCKyHH nKpoKceHH OCTSH~HOT nen on CTeH8TS ro qHHH UHKPOKpHCTsneCTSTS OCHoBBS KSCS qHj COCTSB e HCTO TSKS onpeneH HO TOj Hee upenueT HS OBOj Tpyn

TIJIAr~OKJIAC~

TIn8rHoKnSCHTe ce HSj3scTsneHH KKHepsnH BO psuKHTeHS BynKsBcKHTe CTeshyHH HS Kozy~ nnsHHHs THe upBeHcTBeHo ce UOjSByBSST KSKO ~eHOKpHCTsnH

S ce nojsBYBSST H KSKO uHKponHTH BO OCHOBHSTS uscs Tpe6s ns BsuoueshyHSK neKs BO OBOj Tpyn Ke 6HnST UPHKSZSHK CSUO pe3ynTsTHTe n06HeHH co nOKom HS eDKTpoHCKS MHKpO COHns S KHKpO~H3HOBpstcKHTe KspSKTepHCTHKH He ce COCTSBeH nen HS OBOj Tpyn Hs 6S3S HS roneuHoT 6poj HS Kepe~s H3BpmeHH co nouom HS eDeKTpoHcKS KHKpocoHns BO nnSrHOKnSCHTe on Kozyt UDSHHHS ce 3s6eneZBHH TpH cnyshyqSeBH KOH ce onHeCyBSST HS xouoreHHTeTOT HS apHsTs H nHncTpH6y~jsTs

HS uoenHHHTe KounOH8HTH BO HHB

1 Cnyqsj Kors Husue HopusnHs aOHsnHocT onHocHo conpzHHSTS HS KsnaHjyuoT ousrs onejKH on aeHTpsDHHTe nenOBK HS apHsTs KOH uepH~epHshyJSTS S npH TOS pSCTe conpZHHSTS HS sn6HTCKSTS KOUUOHeHTS

2 Cnyqsj Kors HKsue OCUHnsawu BO COCTSBOT BS UDsrHoKnscHTe