Volumetric Analysis -Class XI

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  • 8/12/2019 Volumetric Analysis -Class XI

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    Prepare M/10 NaOH solution (250 ml) and using this solution estimate the

    molarity and strength of the given HCL solution.

    Step I : Preparation of 250 ml of M/10 NaOH :

    Molecular Formula of

    NaOH

    = NaOH

    Molecular Mass = 40 g/mol

    NaOH required to prepare

    250 ml of M/20 NaOH

    = Required molarity X Molecular

    mass of

    NaOH

    X Required volume of NaOH in mL

    1000

    = 1/10 X 40X 250

    1000

    = 1 g

    Weight of the weighing bottle + NaOH = 1.7 g

    Weight of the weighing bottle = 0.7 g

    Weight of NaOH = 1.0 g

    Molarity of NaOH solution = Strength (g/L)

    Molecular mass of NaOH

    = 1 X 1000

    40 250

    = 1 X 4

    40

    = 0.1 M

    Step II : Molecular equation and Ionic equations:

    Molecular equation:

    NaOH + HCl NaCl + H2O

    Ionic Equation:

    OH- + H

    + H2O

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    Step III : Simple Procedure

    a) Burette solution : HCl

    b)Pipette Solution : M/10 NaOH

    c)Medium : Aqueous

    d)Temperature : Room temperaturee)Indicator : Phenolphthalein

    f)End Point : Appearance of pink colourg)Molecular Mass of HCl : 36.5 g/mol

    Step IV: Observation Table:

    NaOH X HCl

    Sl.No. Volume ofNaOH in mL

    Burette readings in mL Volume ofHCl in mLInitial Final

    1 20 0 19.2 19.22 20 0 19.1 19.1

    3 20 0 19.1 19.1

    Concordant Value: 19.1 mL

    StepV: Calculation of Molarity of HCl

    In the balanced equation,

    1moles of NaOH reacts with 1 moles of HCl

    V HCl X M HCl 1

    ----------------------------------- = ----------V NaOH X M NaOH 1

    V HCl X M HCl 1

    = ---------- X V NaOH X M NaOH1

    1 1V HCl X M HCl = ---------- X 20 X ------1 10

    1 1

    19.1 X M HCl = ---------- X 20 X ------1 10

    1 1 1M HCl = ---------- X 20 X ------ X -----

    1 10 19.1

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    1 X 20 X 1 X 1M HCl = -----------------------------------

    1 X 10 X 19.1

    M HCl = 0.104712 M

    Therefore, Molarity of given HCl Solution = 0.104712 M

    StepVI: Calculation of Strength of HCl Solution:

    Strength of HCl Solution = Molarity of HCl X Molecular mass of HCl

    = 0.104712 X 36.5 g/L

    = 3.821988 g/L

    Step VII: Result:

    Molarity of given HCl = 0.1047 M

    Strength of given HCl Solution = 3.821988 g/Litre.

    **************************

    2.0000

    0 .500

    0.050

    0.001