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8/12/2019 Volumetric Analysis -Class XI
1/3
Prepare M/10 NaOH solution (250 ml) and using this solution estimate the
molarity and strength of the given HCL solution.
Step I : Preparation of 250 ml of M/10 NaOH :
Molecular Formula of
NaOH
= NaOH
Molecular Mass = 40 g/mol
NaOH required to prepare
250 ml of M/20 NaOH
= Required molarity X Molecular
mass of
NaOH
X Required volume of NaOH in mL
1000
= 1/10 X 40X 250
1000
= 1 g
Weight of the weighing bottle + NaOH = 1.7 g
Weight of the weighing bottle = 0.7 g
Weight of NaOH = 1.0 g
Molarity of NaOH solution = Strength (g/L)
Molecular mass of NaOH
= 1 X 1000
40 250
= 1 X 4
40
= 0.1 M
Step II : Molecular equation and Ionic equations:
Molecular equation:
NaOH + HCl NaCl + H2O
Ionic Equation:
OH- + H
+ H2O
8/12/2019 Volumetric Analysis -Class XI
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Step III : Simple Procedure
a) Burette solution : HCl
b)Pipette Solution : M/10 NaOH
c)Medium : Aqueous
d)Temperature : Room temperaturee)Indicator : Phenolphthalein
f)End Point : Appearance of pink colourg)Molecular Mass of HCl : 36.5 g/mol
Step IV: Observation Table:
NaOH X HCl
Sl.No. Volume ofNaOH in mL
Burette readings in mL Volume ofHCl in mLInitial Final
1 20 0 19.2 19.22 20 0 19.1 19.1
3 20 0 19.1 19.1
Concordant Value: 19.1 mL
StepV: Calculation of Molarity of HCl
In the balanced equation,
1moles of NaOH reacts with 1 moles of HCl
V HCl X M HCl 1
----------------------------------- = ----------V NaOH X M NaOH 1
V HCl X M HCl 1
= ---------- X V NaOH X M NaOH1
1 1V HCl X M HCl = ---------- X 20 X ------1 10
1 1
19.1 X M HCl = ---------- X 20 X ------1 10
1 1 1M HCl = ---------- X 20 X ------ X -----
1 10 19.1
8/12/2019 Volumetric Analysis -Class XI
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1 X 20 X 1 X 1M HCl = -----------------------------------
1 X 10 X 19.1
M HCl = 0.104712 M
Therefore, Molarity of given HCl Solution = 0.104712 M
StepVI: Calculation of Strength of HCl Solution:
Strength of HCl Solution = Molarity of HCl X Molecular mass of HCl
= 0.104712 X 36.5 g/L
= 3.821988 g/L
Step VII: Result:
Molarity of given HCl = 0.1047 M
Strength of given HCl Solution = 3.821988 g/Litre.
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2.0000
0 .500
0.050
0.001