Conditional

Name, of ,iesticide' ,product::

M~tri:bti:iin4F '.. ; (un~er FIFAA, ,as amended)

'Nam~' and: Mqressof Registrant (include zIp Code): , '.

~~~,-,~>-'" 'E>hql?p1Wr,u,si Inc. ,lew,Plaza

'NJ' 68611'

, ,

lsrrar:'lon' i's in nO~i;lYto'be construed as an. endoo:l r~s~em~'~en~:t;'t ~o,r~t:b:~~~;:e~t::t~;~i:~~; ':protect health aild'" the environment,the.J

II,',~Q","'C~ 'regist,rationof a pes't·fCideiii:accOrctance, regis~radciii'qf,a,prociuct under ,'this Act ·,'1s . . useof'tM name:or'to ,its use:if1thasbeen

, • • ,', .1.,;

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prodlitt is ~onditionany: registered in ,accot4~ceW!th'FIFRAsci9tiq1,l~(~)(7j(?,t);P;6~4~~':YQU ' I/,ClI.I;!.H"I;; in '\¥r:itingto: ",":' '" ',', ',-: ,,:,.: ' " ',':"""':':"" ,. :,',

'I. ~ubmit'outstanclipg'data requiremeIlt$ 8:3.,o'.63p (one y~stw~g~s~biiity s~dy)aO(~;83Q,~320 (corrosiOii characteristics study)within+ye~frdm the dateofthislette1\.' ,,' ". :}<:

{ ",,' • "','. • .> •••• ~,.

2.:Changethe EPA·Reg,~o.onlabel',f(om7~i506,.to ;o506;.6g~· ; >. • , '

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4. Add\'or rinsafe" at the end ofthes~tein~!w"bQ'ncitcOl1tap:rina~e w-ater when disP9.sing qr eqllipment washwaters." in the section Enwonmental Hazards ol1'p~ges 2 and:6;" .

5. Move the sections Environmental Hazard~andGround Water Advisory form beforePPEtoafter Us~r Safety RecqrnrnendatiOlis on pages 2 and 6: ' . ' , '

Date:

5/12/2005

/T6In~1ns. I"rll\,'"M Manager (25) Division

'. ' '.' .

i p~ge2 EPA Reg. No. 70506-68 ,

7., Qnpage 7, under the$ectio~ "Generai:Pr~c~u!i~J;l~i'P1gRestrictions" adgthe followiIlg, .'.' ,;,;;;;1

'rdsttiction: "Do ,n(Jt rotafe ariy crop riot1isfed,.,'o~:;fhis:1i:lb~1 for 18T1JonthsjolIowingapplicdtforil''' ',', ':'!;

~.lPh~~~ 17;}~9V~ ~ .~<))t ~'Ili)tii,,~~~,~~~·~~LdQJ)qt ~l~f!~~Qr;:~~"i>;;i.'!r : •. oats .....• Cool,.wetweathef conditions duiirigthe·:e~.Iy:stage:6fgr(rwth mayincte:asethe ...' ',' :"';;)';."::: ' po,ssiblliiy ofinjury tosorghum~" frqm ilie$p~~i~;~tetautionS:se~iion in' SCrY;:l3.~,s: ;:uPl' " , ;',.:., M,ETRIBUZIN 1'1usTREFtAN .. Add.t1:).~ StA~~qi~llt".oO not rop:iteahyqrOp'l1ofltste#orzt~is' label for 18 monthsfollowing applicatjon/'to the'Sp~ciat Prepautions section. : .,: ," ",' "'; ; , . , . ~ , . ,

9. On page' 22, in the sec1i:~>n Special Precautio!1~, for UPI METRIBUZIN plus CPMMAND;:. ': \:':. .. :., remove "O~ts" and "Rye" from the ~temlent ~'Do,not rotate to wheat, oats, barley,rye, alfalfa; Or);.,., ..

t;»?":~;i,:;~;~."~~g, ~~W 4Itlwt~ll, of~~yea,r: of aii~ii~~tl'Qll,~qt"if'Lt!i9~Bipl~:~f~~ f,qllo\\jng~X~~;~.~~91d:~j~: .. ' ,. . , ..... , .. " . 'In~yoccUr."A:ddthe$teIn<::nt "1)o:,Tl(itr6tat~'(;Jf1Ycrbp:hotliste.a·onthis:labezJor 18rndriihs"":/:'

'··il~~'~ ···ft;;~;'~;~~;~~:;;~7;;~~~:,t;~~;~::i':

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seed Cqp1 ill the fall of the year of apl?li~aH9n otin"the spring of the folldwin,g,f~~l<l§~6PfuJPiY'" '.' m~ occUr." Add thestaternent "])0: h~trq'tateanY:9topnot listed on this labelforI8;7JiQnths;~:<·".:, following ci.pplic;atioy/." totheSpe¢l~rPrecEu~ttQ~ s,ection.M~~these ,s~e chMg~~orin~ge;2,3', .. >"., ,/. ", ,; i

·~~:;;:;;;;~~~t;:~;;ffH~9;qfd:~~!i~~{~C'~~~~t~:~ . PRODtICT/ACRE. . ... .. ' .., ", '., .. , ., ";"',::g;>

..... :/-: 1:;:~\"; ;:<..; , .' ': :;::.. ~': . ,

q. On page 31 and44,remove:th~,prodlJctsBladex and.Extrn.zine Ufrom the tankmix lis~:)is; " .,' ,';,., ;.:;.,;; th¢sepro~llFts havebeell c~cel1ed. ., ': "", .... \i~

1 . 13;. Onpage33, remove the statement "Do notpl~ts~nsitivecrops such as oni()p5, lettuce, cole' cr*p~, ~dcucurbits durip~the nex: growin;~i;~~~~nfollowing lJl>1,METRIBU~'~~>: ::, ,~;: ',", "

, applicatIOl).."fr,omthe sectIOn SpeCIal Precallti0nS;'i Add 1he s~t~ment. "Do. 'not ro~qte;:£i'nycrfJP;'" , ndtl{stedon ,this label/or 18 m()nthSfdllow.l~g~pplictztion." totheSpecia:l PrecautiQnSsectibn;

. . . . '.~;. ... '., . .. . ... . ;. \.: ,.' .

14. Onpage.37 anq49 ofthesecti6ns ASPARAGUS and TOMATO,.niake thestate111ent "~erial Applitation is Prohibited'; BOLD and mo've these statements to their respective,Special Precautions section. '. . ; . .,.

, .

151• On page 46, add the statement '~l)o. nof'rotate a~y crop not listed on this label for 18 m()nths' folZowingapplication."fo the Special Precautions,section in SUGARCANE.

J({ On page 52, add thefollowing items :tothe\~/"ihter~Wlw~tllStoi varietiest1iat artHoleraht'to . ~Clate'#~cQI@leIided fonise with.Metribw:ip:'4F';4$lipro.Mason;, 4'griPto SHiloh,:\piltdf(i~g:'

. 502,DeltdKing 9027, TR8555, 'tR8557, andtR /1768: '., '.

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, page 3 " 'EPA R~g. No. 7Q$Q~'7,68

J 7. 'On page, 52, add, the fonowing items to the Winter Wheat lIst ofVarieti~sthat are sensitive, add nbttecon:ili1ended for use, with Metribuzin 4F:' AgrlPro Clemens, EK 102" EK 114, Pioneer

'" 2643, (mti Ploneer 2691. ' '

18. On page S4 add the statemenf"Do not rotat~ any crop not listed on this labeljor 18 months , !oUowingiippUcation" after tliestatement "De not plant creps in treated ~eas for at lf~ast 10 , lllolithsf()UewlngFallapplJ¢!l.tiens. "m.t11~secti()nsFOR WEEP CONTROL IN A

wi;WA. rIf,'ALf9W§o/lIEi\T,~9TL}Tlq~ and'FOR WEED CONTROL IN AFALLOW " , ROT~'fION'WIrnJ3J\RLEY:ANI) WH,EA1:: ,

"~.":.-':":., ", ',. . ,<" ," .. ".«'<~~.

1~~:'9n:p~g~ 55, reITI()ye "Cetten'" 8Jl:~l'i~ce."#()p1 the 81110nth section offheCr~p'\~~ta~6h" ",: ' ' R~~o~eh4a.tiops,ta91e. ReWQve, "pth~r¥t()p~,n()t listed (e.xceptroot cropsrfr0m:,·the~;2,iJ:lpq.lh •

",' ,se~ti()ParidADD",'potatoes" and "rice3." In,fue18 menth,sectien chan.ge '~othet rootcrop!?'~J~.' ,

" '~other rootcrO,p~notJi~ted",a,h~ ADP,"£ilCotQer;,9ropsnot listed 'en this la.bel. ,; 'AJSQ;' ad(i',~;ihli:a ' , fept.ngt~stating"D6 ~~tr~tate 'ricejtftei)my a~lil!cation to a primary crop~eat.~r.tfitlAA' 1~1art A

.. " 6f Metrib4ziriAF per season;'" Andfinli!Uy, add,.tlJ.e followingstat~mentat fueen(rofth,et~pl~. ' "W',',," "Ij)o #ot !~tatp ailycrop'not1i~te(i ()n~~'l~be~' after app,lication of Me¢bdzin 4Ftg.s,iigflfcaije."

, :~ ,,: ~ . :'.,;, J I . <:::,':; ' ... ..-:: .

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>~!", ," ,,:' ':,,' ,0, ;"', ' , ' < ,:,;:<,''', .,~,';,,;, " Yoli'will$ubttiit<;nle {1),'90:py;efyoPr,tiIi~p~ted labeling before yoU;.tpl~ftS~;tl1e;,p1:6d#ct>i;~'

for, shipment. }f;these condition~ ar~,.~ot ~()1!J.PHed with, the registration wlll ,be subJectto '. ," , cancellation in accerdance Willi FIFRA section 6(e). A stamped copy oflabelmg:'is enClosed for your records. ' ':

If you have any qlll'$lions. pIe",," conla<it HOrI hnsQn at 7Z3/305-541O. '

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" J Oin ms , p '(jductManage; (25) ,

\ erbicideBranch ",-.;Registration Division (75Q5C),

;'.

[ ContainerL~b~1] i .1",:· UPIMETRIBUZIN,4FHEIffi'ICIDE

~. . ... . . ',.;' ~ .. ,

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. For c'ontroLof certain grasses and'broadleafweeds. . 'I ' ,';' .' " ACTrvEINGREDIENT: Metrlbuiin:#: ,/

I 4~Amino-6-(1.1-dimethyletbyl)-3-(methylthio )-1 ;2.4-triazin"5( 4H)-one .......................... 41 % INERT INGREDIENTS:· .................................... ,....................................................... 590/0'"

*Coqtains 4 lb active ingredient per'gallon.

KEEPOVT ,()F. REACH QF CIuLDREN '

,CAUTION PRECAUTIO&ARYSTATEMENl'S

HAZARDS TO mJMANS Al'oUlDOMESTICANIMALS

100%/

CAUTION: Harmful if swallowed·or'absorbedtbr0ugb skin. Avoid contact with eyes, skin. or clothing .. '

FIRST AID If Swall'owed· • Call a poison controlcellteq)r ~oc~orillllnedi~teJY'for treatment advic~ ..

• , Have personsip:a'.glas~ Qfwatefif ableJo swailow, .' ~ " .' '. .

'\'. '. ~ ~rOd:~~~uce VO~tingUnle~stOld U)d.O so by,apois~n pontrol center. ,

';' • Do notgive anything by mouth to an unconscious person. If OriSkin 'or Clothing • Take off conJarriinl'lted clothing.

• Riiise skin,hnntediatelywithplenty of water for 15 to 20 minutes,,' '. Call a poison control center or doct'or f'or treatment advice. '

,Have the product container or label. with you wpen (:alling.apoison control ct<ilter or d'oc;:tor, For 24-hour medi<;al eniergency assistance. C'ontacdhe Natioilal Pois'onC'ontrol Center, at 1 ~800,222-1 2.22.

• Note, To Physician: Treat the patient symptomatically.'SymptomsofPoisoning: Tpe c~mpound does not

'. . '. caus~any definite. symptoms (hat would be diagnostic; Poisoning is accompanied,~ybreathingd~culties. and ,sedation. " "" " ,

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EOR CH,EMICAL .EMERG:E;NGr: 'saill, leak,fjre, exposure, ;~racciden~ ,'., : " ., 'CailCli:¢MTRECIit':r .. 860:424~9300· . . ',' .,::, "

' •. ·.upj' .... '. uttiitdPhosphorus. Inc.

423 Rivervie\y Plaza Trenton. NJ 08611 1-800-247-1557 www.upi-usa.com

UPI Metribuzin4F Master Label

EP AReg. No. 70506-EPA;Establishment No,_ Net C'onten(s:

ACtEPrED . . WillI: COMMENTs til· EPA .·LtUcr QalDd

MAR 3 0'2005 lJadIr tIIe·FecbI1IlIIIecdcide. Fuqiclde,aad . ROdensicIde Act ..amended, ,fbr .JIIe jlCSticldOi' ~:., EPA·Reg. No.

'7bEcW --- (0<8

. " ., .... ~ ~', .:. ~ ....... 'I' .... .. . . '." .. , .... ,

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Pagel of 56: .' •• •••••

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•••••• . """ "." . ".. ." ... , .... , . . ... ••••• . . . . • ••••••

. .~

.' PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS CAUTION. },~ Harmful ifswallowed or absorbed through skin. Avoid contact with eyes, skin or c1othing ..

Do nqt contaminate feed or food. Keep out of reach of children. Obtain prompt medical aid if poisoning sl10uld occur.

, . ENVIRONMENTAL HAZARDS Do n6fapply directly to water, or toareaswheresurfa~e. waterisprysent:or tointei:tiCfulareasbelowthe meanJiigh water mark.l · Do nou;ontaminatewater when·di~Posingo(equipinentwashwaters. .

GROUND WATER ADVISORY . ME~RIB UZIN ii{ a. chemical which can tta vel (seep or leach) through soil and. can contaminate ground water which may be usbd as drinking water. METRlBUZIN has been found in gt:Ound water as a result of agricultuniluse. Users are advisbd not to applyMETRIBUZIN where the water table (ground water) is close LO the surface, and where the solIs are very Permeable. i.e. well drained soils such as loamy sands. Your local agricultural agencies can provide further infonpation on the type of soil in your area and the location of ground water. .

PersOnal Protection Equipment (PPE)

t(!,.:~JJ;:i' •. ·.;··. ~p~~Fat~::&l~~~h:::~:d::i ;:~. ;:,. : .... :, .;Cnenii~~~e~istt;mtgloves made.oianY water~oot:matClial

••

~'socks pll:ls'i'ootwear . , " , " ..

. Follo~maniJfacturer's instructions for cleaning/maintaining PPE. If no such instructions Jor wash~bJes. use deterg~~t~d . hot water. Keep and wash PPE separately from other laundry. . .

I I .

When handlers usc closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Pro.tection Standard (WPS) for agricultural pesticides (40 CPR 170.240(d)(4-6», the handler PPE requirements maybe redu~d 9r modified as specified in the WPS.

User :SafetyRec6riunenC:ladons User ~MUId: '

• :::.. , I W ~shhands befo.re' eating, drinking, chewing gum. using tobacco. or using toilet. ~l Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean .

. ! Clothing, . .. ~ . RemovePPEirDmediately after handling this product. Wash theoutside·o.f gloves before

removing. As soon as possible, washing tho.roughly and change into clean clothing.

, AGRICULTURAL USE REQUIREMENTS Use this product o.nly in accordance with its labeling and with the Worker Protection Standard, 40 <;:FR Part! 70.'Re'fer to : label booklet under "Agricultural Use Requirements" in the Directions for Use section for ihlomiatibnaboutti:iis~~iid:aql;

i . " .. /~." ......

Refer, to. the label booklet for Directions for Use and Storage and Disposal~ <, .

• ; " , • <'

Noti~e: Rea~the entire labe1.Us'e:only aCcording to label directions~. Before buying or using this p~oduct, read "Co~ditions of Sale and Limitation of Warranty Liability~' inside the label booklet. . . .

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UPI Melri buzin 4F Ma.<tter Labe) Page 2 of 56

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tLa~1 Booklej]

tTPIMETRIBUZIN 4F<IIERBICIDE., ", '. ._""" ' ," " ". .' .. ,. ., . . '~... ." . -' " . .

For c6ntrol of certain grasses and broadleaf weeds.

ACTIVE INGREDIENT: Metribuzin*:

4-Amino-6-(l,l-<limethylethyl),3-(metbylthlo)-1,2,4-triazin,5(4H)-one ... , ....... , ............... 41 % INERTINGREDmNTS: ................. ;.; ...... ; ........ ;, ...... , .. : .. ' .......... , ........... ' ..... , ........ , ........... 59%,

j '*Con~ains 4lb activeingredieritpergallon.

I i j' KEEP OUT 'OF REACH OF CHILDREN

CAUTION

, FIRST AID IfSw~nowed . ' Call a poison control Center or doctor immediately 'for treatment advic~ .

• lbve person,sip ~ glass ofwaterifableiosWallow, : . • Do not induce volniting unl~ss told to do so by apoisoncontrolcenl~r ,

i or doctor. " " ' '

1. "

j • DO not give anything by inouth t.o,an uncOnscious person. :, !

, If On; Skin or CIQthing • Ta~e off contaIninatedclothing r ' Rinse skin immediatelYyVith,plentyofwaler for 15 to 20 minutes. i .' 1, • Call a poison control center or doctor fOf'treatmentadvice.

Havelthe product container or label witl:l. you, when Calling a poison control center(jr doctor. For 24,hour medical emergency aSsistance, contact the National Poison ContrOl Cenier at 1-800-222-1222. Note:To Physician: Treat the patient symptomatically. Symptoms of Poisoning. The compound does not cause any definitesymplOms that would bediagnosiic. poisoning is , accompanied by breathing difficulties

, and sedation. ' "

FORCHEMICALEMERGF;NCY: Spill, leak,ftre, exposure,or accident, Call CHEMTRECatl-800-424~9300 . I

" I L

,

United Phosphorus, Inc. 423 Riverview Plaza Trenton, NJ 08611 80().,247-isS7 .wvvw;upi-usa;com,

UPl Metrlbuzin 4FMaster I:.ibel .,.

EPA Reg. No. 70506-. EPA Establishment No. . NetContentS: .

Page 30f::>6

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TABLE OF CONTENTS Precalltionary Statements ,." .. , ..... ; ..... ': .... , ... /:,:, ............ , ........ :'.': .. '".: .... ' .. , ......... :.: : ......... : ...... . ~ds to Humans ...... , ............. , ........................................ , .................................... " First Aid .... ' ................... ",' ..... ' ... ; ................... : .' .......... , ...... ' .................................... .

D;:~~~~:;~;~~.~~.::::::::::::::::::::::::::::::~::::::::::::::::::::::::::::::::::,::::::::::::::::::::::'::::: ~~~~: ~~~~: arid:~~~~i~·ti~~~··: :::::: ::::'::: ::::::::: ::::::: ::::::: :::::::: :::: :::::::::::::::::::::::: :~. Chetnigation ' ..... , .•. ',,' .,.'," .' ....... , .... ::, .':;:,., .,,;., ~ .::.,., ,.,:. '," .,.:., .... '.", .. . J., ..... ',. ',""""" '," ',," ',' .: .. ,., .. ..

, Aepat,I?rift.R.educ!ion AdVISOry InfoI1ilatiQn, ....•. , .".; ...... " .....•.... " ...... ".", .. : .. ".,. ,,' •.. ' ........ '." ... . "Applicatipn with Herbicide Spray Equiprrifmt .. , .•. , ....... ' .... , .• ' .. ,,;., ~ ..... ,: ......... ,.; .. ,., ... , ".; , ... :. ,Ap,plicaiion of UPJ METRIBUz:rN4F inFhlld,Fert1Iiiers ... :; •. , ....... " ........... , ....... ' .. : ... : .: ..... ,:;.,' .... ,. 'C~n:imercial Impregnation and Application of UP I METRIBUZIN 4F on DryB,uIic Fertilizer ... ' .. , .. ; ..•..... ,'"

. Soy~eans' (Except in California) ........... , .............. ' ......................... : ....... "' ..... , ............. , ..... . W~edsControlled by UPI METRIBUZIN 4F + UPI METRIBUZIN 4F Tank mix Combinations ...................... ..

DIU METRIB:PZIN 4F(Alone) Preemergence .: ................... ; ......... ; ............ : .......................... .. Usesjof t]PIMET-RIBt:JZIN 4F Herbicide in Combination with Other Herbicides ..................... , .......... ..

, Se~l1~l*aI,Applk:a!i()n of Scept~r FQl10wing upI METRIBUZIN 4F. .................. , ..... ', ...... , ...... "," ,,: .. ". Up,IMETRlBUZIN4Foil Coarse (Light) Sdils ...... , ....................... : ...... , ..... ' ......................... ', ... ,

,(9JRLA~AP~LICATIONS) .•..•........ H:.~: .........•........... H .... '~ ..... :., ..... : ..................... " .... ,; ...•....... 'Ul';I;~UZIN 4F and $on aI an -,Overlay ........ "," ....... H" •• H., ....... , ........ ;., ••••• ; ••••• , •• , •••• , ........ .

U~I METRIBUZIN4F and Treflan - OverIay; ..... ', ..... ,' ... , ., ... : ........... ;' ... ;; ............... ; ..... '.;.',." ..... , ; .. : .. .. UfllMETRIBUZIN 4F andDual-Overlay ., ....... , ........ , .. ' ................................. ;' ........................ ' UIjI METRIBUZIN 4F and,PrOwl- Overlay ............... H " ........... , ......... H ......... ' ............... ".; ....... ..

(PPI fI'ANK MIXES) ................................... ' ........................................ , ...................... . Sppt-Shot Application of UPIMETRIBUZIN4F with Dual.l~sso. Prowl. Treflan. or Sonalail ............... .. EXtended Split-Shot Application of UP I METRIBUZINAF with Dual or Lasso ................................... . mil MErRIBUZIN 4Fplus Sonalan :... TaDkMix ....... '", ..................... ; ... ' ............ ; ........................ .

"~i~~~1~~E~I2~.~.;//·'//~.~~.~?;t/)."',;.i/E/>.\·}/i+:i.":~:' lJ1l1~lBPZIN 4F plus Comm,ence '-' Tarik ¥ix (Early Application) .,; ....... ; •.... , ... '" .' ... ' .,.' ............ .. tJRlMETRIBUZIN4F plus Commence ~ Tank MiX ., ... '; , .. ;." , .. ; ... : ......... ' ..... , .: ... ,;, .'.'. ;'." ,' ........ "" .. '. ,> .. ' UIfI,METRIBUZIN 4F plus Freedom - Tank: Mix,., .. ·.: .. ; ....... ;. , ........... , .,; ..................... " .. " ','," ;'.: .. , .' .. ,:. UP:I.METRIBUZIN 4F plus ,Canopy and. a Grass Herbicide-:- Tank MIx H'~"""'"'''''''' H .. H ................ ;

uP;I METRIBUZIN 4F plus Command and a Grass, Her~icide - Tank: Mix .. H .................................... .

UP;I METRIBUZIN 4F plus Scepter and a GrassHerbicid~ - Tank Mix..................................... ....... , Uill METRIBUZIN 4F plus Pursuit and a Grass Herbicide - Tank Mix ......................................... :.:;. ;, .... . URLMETRIBUZIN ,4F plus Pursuit Plus - Tank Mix ..... ;,,: ... ; .. ;; """~ .. H .......... , ••••••• , •• " ••••••• ; .......... ..

: (PRE~EMERGENtETANKMIXES);' ... H ... ;; ............ ; ... ; .... : ..... ; .... ; .... : .................... ;~ .... '" " "

uPIMEmmUZIN 4F plus Dual-Tank MlxH .... ; ........... : ...... , ............. ;; ................. ; ........... ' ....... ,

.., UP;TMETRIBUZIN 4Fplus Ptowl-Tank.Mix ........... ; .. : .:: ... ,,:.;~,,;; .............. ; ...... : ... ~ ................ :' .. ; ·.i

UIlI METRIBUZIN4F plus Lasso,..., Tank Mix ... : ................ : .. :'.;::'~': .................... :,~ ..... ~ ... : ............... : 'UP!'METRIBUziN 4F plus Pursuit Plus"- Tank Mix ......... ; ...................... ; ....................... : ............... : .. ~ ... ~ . ,', . uPI METRIBUZIN 4F plus Linuron Plus Dual or Lasso -Tank Mix .... : ........................................... '

'(MINIMUM TIll OR NO-TILL) ........ ". ................................... ' ...... ' ...... , ...................... , ... . ,Burndown Weed Control ............ , ........................................................... ' .................. .. Post-emergence, Directed Sprays .' ... , ............... ' ....... ' ................................................ ', .... .

P()latOes ....................... ,: ....... , ...... " ............. ,:,.~ ..................... , .............. , ............ , ... ,. UPI METRIB UZIN 4F -' ,Preeme,rgence ." .... , .. , ... , .... ;,"" ., .... , ...... ,,',,"' .... ,; .... ";''','','' ',".',' '," "," ',0," •• :, ...... ,

l,JP,1 METRIBUZIN 4F - Postt<m.ergence .. ; .......... ' .. ;; ....... , ....... "., ... , ....... : .. , .. ,': .•. ;., ...... ,.,., ........ , .•.. i ••• ,; ... '~

!~~!.r.~l~;~~!~;.: .. ::}·':::;:::'::;:::·:;·::::,·::i:i,:-;:::',::::::.'.';:'.':~';:::.:.:'::: .. :.' .. ::. Alfalfa ll:lld Sainfoiri (all areas except California) ............ ; .............................................. ..

. UPIM~nibuiin 4F Ma.~terLabel Page4of56

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I~:;~~?:~··-~~~;f;~~~~~(;;~·-·-·--····: --... --;,.. .... -.-~----.... --.--.--.-.... -... -.

I Alfalfa and Sainfoin (California only).:,: •......... :: ........... · .............................. : ....• ; ............ . Alfatfa - TankMix with Gramoxone Extra ..................................................................... .. Alf;Ufa - Post Dormant Appli~ation .................................... ;.;:; ......................... ;; ................... .

~:~t:g~~.::::::::::::::::::::::::::::::::: ~~:::::::::::::::::::::::: ::::::: '.:::::::::'.:::::::::::::.::::::::::::::::: : ... .. i· I I

Field Corn ............................................................................................................... . Garbanzo Beans (Chickpeas) ........................................................................................ . Lentils and Peas ..................... ~ ..................................................... " ........................... . Sugru;cane .. ' .............................................................................................................. .

HaWaif·OnlY ................................................... : ........................................ ; ................... . . ' Louisiana and Texas Only ..................... " ............ , .. ,.; ............................................. : ...... ..

F1ori.dll:·OnlY ............................................... , ......... , .... , ...... ,.".'!: ...... : .............. ; ......................... .. Tom~tt~s .............. : ...................... .-......... ; ............ : ... :., ........... : ............................................... , ......... , Cereals ........................ , ..................... : .............................................................. , ..... ; ..... .

Spting and Winter Barl¢ylWinter Wheat.; ....... , .................... ~ .................. , ............... , .... '" :. ~ , v ••• '. '. '

DryJahd (Noh~Irrigated)Winter ·Wheat .......................... , ......................................... , ........ .. . Wh,eatIFallowlWheat Rotation ................ , .....•...•. , ....... , .••.•.. ; ... , ................... : ..... , .• , .......... ,. Bail<:y and WheatIFiulowlBarley and Wheat Rotation ........................ :: ............................. .

Crop .. Rotation Recommendations· .................... ~ ............... : .................................................. .

• . Storage and'Djsposal ..................................... ; .............................................................. ..

CONPITIONS OF SALE AND LIMITATION OF W AR.RJ.).NTY AND UABILITY ....................... ..

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'UPIMetribuzin 4F'Master Label. Page50f56

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PREC~U'J:'IONARY S:r Al'EMENl'S HAzARDS TO HUMANS AND DOMESTICANlMAtS CAutION. ' , , , " , " " "", , , ' ',' Hannful if swallowed Qr abs6rb~d thiough skin, Avoid con~act with eyes, ,skin or clQthiilg.

! . - .'. .~ - <",', • ,. • •

; , , ,ENWRONMENTAtlIAZARnS"", Donm,apply dite~tly to water, ono aie,as';wheres\lfface water ,ispresentor't(riPt~rtidalarea below, the mean.high watet ' mark} Do not contarrrinate water when dispoSing ofequiprpent washwaters.:' '

. GROUND WATERAI>VISQRY , MET;RffiUZIN is a chemical which can travel (seepor:1each) throughsoii and can contarrrinaleground water which may be used as drinking water. METRIBUZIN has beenfound in ground water as a result of agricultural use. Usersare advised not to apply METRIBUZIN where the water table (ground water) is close to the surface, and where the soils are very Permeable, i,e. well drained soils such as loamy sands. Your local agricultural agencies can provide further infOnrtiOnOn the, type of soil in your area and the location of gr()und water.

,,'PerS~natPr9tectioil ~1l!'pDlent (PPE) , AppIlpa~ois,a!idoili#rbap.dlefS mukweat: ,

-; :Long~sleevedshlrtand long pants ,,' " • ' , ." Cheffijcal~resistant gloves inade' of any watetprOQf:in,clterial

1 .. -: "Socks plus footwear , ' ,

Follow mailUfacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use dete~genl and , hot water. Keep and wash PPEseparately from other l!mhdry.

When handlers use closed systems; enclosed cabs, or aircraft fn a manner that meets the requirements listed in the Worker Protection.$tanda(d (WPS) for agricultural pesticiqes (40 CFR 170.240(d)(4-6); the h<mdler PPErequirelllents may be reducbg <?r mOdified as specified in the WP;S;' , . .

. '. . User:~eV'. Re~ommendatioDS " User should:' .

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.'. Wli~h ljands before eatiJig~ drirtlting~ Chewing gum; )~sing tob~cco or using toile~; Remove clothing iInmediately if pesticide gets inside, Then.wasbthoroughly.and put on clean Clothing: . .

Remove PPEimn1:ediately after handli,ng this product Wash the ()uts~4e of gloves before removing. As sOon as possible, washing thoroughly and changeihto clean clothing .

: AGRICULTURAL USE REQUIREMENTS Use 4is product only in accordance with its labelingll1ld with the Worker Protection Standard, 40 CFR p,art 170. This Standard contains requirements for the protection of agric~tural workers on farms, forests, l1~~~eFi,es, ahdgteenllOu~es;anclhandie'rSofagrlCultl.lt<vpesticides .. It 'contaip,s requireriwrtts fonrtrining; . d,ecMtaminauon,notificati9n. andemergencyassi~tarice .. lt Il,lSQ C~l1~S 'spec,ifjcins)riIction$,ano .. exceptions pertaining to .thestatemen.ts O'n thislabel abouqJers()nal protective eqwpment (pPEYand.. ,

,restri~ted-entryinterval. The.requirements in this box only apply to. uses of this prod\lct~at are covered by ' .. the ~orker PrO~¢~tj9nStandard. . ";'',1<' ."

Do not enter or allow worker entry into treated M¢as .during the restrictC(,i enlf)' interval (REI) of 12. b'OUrs. .

Exception: If the product is soil-injected or soil-incotporated"the Worker f'rotection Standard, under certain circUllliitafiCes, allows workers [0 enter the !.teated area if ther,e will be no contact With ah~hing that has been treated. ,"

1, " PPE required for early entry to treated areas that is permitted up.der t;he Worker Protection Standard and that involves contact'with anything that has been trea~ed,'s'uch ~ plants, soil, or water is::;:;;" '. Coveralls '. " ,

- Waterproof .glov.es ~ Shoes pJussocks

UP! Metribuzin 4F Ma~Ler Label Page 6 of 56

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NOVCE: Read these entire~Directionsand Co,nclitions ofS,aIe~t-or~u~llg METRIB:U~4FFlo'Vable Herbicide. ," . "" .";' , .

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t," .' ' , DIRECTIONS"FORUSE , ' , ,It is 4 violation of Federal law to use this product in a uiannerinconsi'sien,tv"iili its Iabeling" Don6tapplYJhi~ pt9ductin a, wayt~at will contact workers or other persons,either directly' or through drift Only protected handlers may be iii the area' d~gapplication. For any requirements specific to your Stale or ,Tribe, consJJIt the agency responsible for pesticide regulation. '

GENERAL INFORMATION upr~ETRIBUZIN4F cannot be applied with lOW-Pressure or high-volume hand~Wand equipment

I , ' ' MIXING'

, Wbeiusing UPLMETRIBUZIN4F, make .sure ,the wrayeris completely clean, free· of rus~ or'corrosion ,wbichoccurs from Wint~r storage.' .Examine strainers and,screensto~ sure thesprayerisciean'from previously used pesticides.' " ,:,' " ,

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Any tank mix containing UPIMETRIBUZIN 4Fshould be kept agitated and spmyed out immediately. Do not allow tank ,mixes to stand for prolonged periods of time. ' "

'The ~i'QPer niixing,pro~dure fot UPI ME'fRJBUZIN 4F alon¢ or ill tanlqnix combina:.tioJ;ls with other herbicides is,: , 1. Fill the spray tank % to li3 fuIlwith cleaii water. ~. Add recommended rate of UPI MErRIBUZIN4Fwhile recirculating and With agitator runl1iJ:tg. 3. Follow the triple rinse procedure described under "STORAGE AND PlSpoSAL" to llisuni that all product is " i remoyedfromthecontainer.,' " " ,,', ' , , ' 4., Mix thoroughly and add clean water. tofiU,spray.tintkto desired level. 5)" Add the oilier herbicide td tanklast and agitate thoroughly., ' , 4. Continue agltati0ll during application and'untif sprayer tarikisempty.

$OII;. TEXTURE: ,.AJ;'Qseq on this label, "Coarse~oil,s",are l(YaJriy sand orsanqy loam soils. "Medium solls" are l(j~, slltlpam, silt, sand)iclay, or sandy clay]oam. ''Fine,soilsi;' ate silty clay, silty clay loam, clay, or clay loam. Silty day loam;soils are transitional soils and may be classified as medium textured soils in some regions of the U.S. ' '

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can~ration: (Cent~r Pivot andSelf'PropEille«lLateral Move Systems): 'spnnki.erirrig~tiori.~Jsten1slllti~t'bea9c~~tery , chlibJated f()rapplicatiori;bf UPI'MErRmUZIN 4F. Greater accuracy in calibratloo (ai'l(ldisttil:mtlonJwill,be achleyed 'by , illjectlng a larger volume of a more dilute mixture of product and water per hour, ,Follow the steps below to c8:ubnite, ' cen'ter pivot and lateral move systems:" , I" ' ,

1'. Determine number of minutes required to make, one complete revolution while applying 1A to % inch of water per acre.,

2. 'With the systeI1l at operating'pressure determine the exa:ct number of minutes required to inject one gallori of water. ,

3; Divide the time reqUired for olle revolution (Slept) by the 4me required to mjectonegaHon(~tep ~~}.this gives , /\ totalgaiions of product.:water'miJ(.ture to be added tonutse tanI<. ' "

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UPI M~tribiizin 4PMaSler LabeJ " ,

Page 7of,56

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4. Add required amount of water to nurse tank and start tbe, agitation system. Then add sufficient UPI . METRIBUZIN 4F at the recommended rate (See RECOMMENoEDBROADCAST APPLICATIONS) to the

. L '.nurse tank. . '" '. , , . ; ,~

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EXA;MPLE: If 20 hours ( 1200 ,minutes)· w~re required foroit¢ teyol~tiQh 'and if 2 minutes were. ff~q#ed 'to inject one gailon,then~atotaLof6()0: gallQn~ Qfpr04jlct~water mcttur:~'are,r~q~4"~d (PbO~2=600); to:treat :13$ acres at 1 plntiacH~; ,

'135 pinis(16gallqns and 7pints) ofUp.fMETRIBtJz.tN4Far~i~qUired; . . .

If you have questions about calibration, you should contact State Extension Service Specialists; eqwpmentinantifact1irets. or other experts.

Do npt connect any irrigation system (including greenhouse systems) used for pestlcideapplication to a public water system unless the pesticide label-prescribed safety devices for public water systems are in place.

kpetson knowledgeable of the chemigation system and responsible forits operation, or under the sup,ervisionofthe · respdnsiblepersbn, sluillshutthe system.downan,d make' necessary adjustmentssh'ould the need arise.. . . .c",) ,'.' ". .'. ....:' ...... ". " .. ' , " '. """ :Tl:l~systeql:mtistconiain a functional check vf!lve, vacuumreliefvaive. and.lowpressure drain appropriately locatedonihe~·· 'mgationpipelif\e to prevent water source, contamination from backflow. .

The be1>ticid~ l~jection pipeline must contaih a fiIn~tioftal, automatic,quick-ciosing check valve to prevent theJlow'bftluid 6ackltowaro the injection pump. . .

I '. . '" ' The pesticide injec:tion pipeline must. also contain a functional. normally closed, solenoid-operated valve 10catOOon the intaIre side of the injection pump and connected to the systein interlock to prevent fluid from being withdrawnJrom'the supply tank when the irrigation system iseitherautomatieally or .manually shut down ..

I , '.. . . ..... '. .... , Thesystenrniust contain'functional interlbckingcontrols to auiomatiCally shut off the pesticideinjection pump when the . , , ..! '.:, .' . ".' .' .' . ~, .. ." 'water .pump :mbtor' stops. · ! .... ,.: '~, ., ,. " .,', .', ... :',. 'I'he: ip'igationline or water pump mu.sUIlc]ude a.,functioniil pressure sw~tch y,ihicb Will StOP thewaler puwpmotor when the ~ater preSSlJl:t\ decreases' to the point Wpere pesticiile di~triputionis adversely affected, '

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. . SystJms mustuse a metering puwp, such as apasitive displacement injection pump (e;g. diaphragm puwp) effectIvely designedal1d constructed .of materials that are compatible with pesticides and Cllpable of bemg fitted with a system interiock

! 'Do npt apply when wiDd speed favors drift beyond the ar~aintended for treatment.

I . . ...... '. ". ' .. ' .. Mai~tain 'continuous agitation in.the injection, nurse tanks during the' herbicide application, sufficientio keep herbicide in."

,susp¢nsion: . . ., • . . , , ; . i " . . , . . .' . ,.' .... .' :", .'.~.

Appl~ specified dosage In 1/4 to 3/4 inch of water (1;4 to 112,inchof water on.sandysoils) per ~cre asa.continuH\Js<: :', .injec~oI)..in center pivot and lateral moye systems orin the l~t I? to 30 minutes of set in permanent,solid se~sprink!er . . .

· systems; Application of more than .the quantity of irrigation water recommended on this label may result. in decreased· . product performance by removing the chemical frolll thezpne eff(lcti veness. Where sprinkler distribution patiernsdonot. ;. overlitP sufficiently, unacceptable weed control mayi~sMlJ"-fWheresprinkler distribution pattemsoverlap excessively; crop ;injurt may result. Allow sufficient time forpesticide'to:beflushedthrough all lines and all nozzles beforeturniilg Off ' irriga'tion water, 'To insure that lines are flushed, and free of remainihgpesticide, 'an indicator dye may be injected into the lines ~o mark the end of the application period.

';' '.. Use 4 minimum of 1 part water to· 1 ,part herbiCide·for injectj.on~Th~ use ofa'large,rvolumecof water will io~~fegteliter accu~acyaridmore,uniformc;listribtition.. ' " . .,' ,:'.' .... . • .. , . ; <; .>. ,

. ' 1 .. """ . , . ; ,:5":',',, . .'" . . .'. '..' j' :. AERIAL DRIFTREDUC1IQN:#>YISORY JNFO~A.rIQN.,' .'" .

Avoi{ling spray drift at the application site is the .re,sponsil;>ility pfith¢ ·applicator. Th~ iil~ractioil'.of'Il1any:equ.i.pfuent~and~' ,weat~er -related factors deternline the potenthil fot spray' ifriit, The;ipplicatoi arid the ,growetate responsible for consi~ering all thes~ factors when making decisions,' " , .

UPIMhtribuzili 4FMaster Label . Page 8.6f56

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',C; Th.1;Uowing 4rl~ ... nage"""nl req~n" muSt be followod 10 avo,d,off-tatgel dri~move_1 from aerial applications ,"'~ , to .!lgpcultur!llfiel~ crops. These requirements do not apply' to foi~try applications; pubIlchealth uses or to applications Jlsmg dryformulations., '" , '" . " , ..

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i. The distance of the outer most nozzles on the boom IDUS,t not exceed 3/4 the length of the wingspan or rotor: 2. Nozzles must always point backward paraliel wjth the air stream and never bepojnted downwards mote than 45

degrees. ' 3. Where states have more stringentregulatlons, they should be observed. 1. The applicator should be filmiliar with and take into account the information covered in theAerial nrHtReduction 1 Advisory Information.' . - "' . ... .. : ." '.' '. . . . ."

INF9RMATIONON DROPLE'I; SIZE:, Th~most eff~ti.veway to reduce drift potenti~'js \o,apply Jargy droplets.The' best C:lrift management strategy is to apply theJargest droplets that provide sufficient coverag~ and, control. Applying lru:ger

, dropiets redu~ driftpOteIltial, but will not pre~ent drift if applicatioris are made imprOperly, or under urifavorable etl\(~onniental conditions (see Wihd,Temperature, and ,Humidity, and Tei:r!peratUte Inversions). '

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CONTROLLING DROPLET SIZE: ~ Volume-,Use high flow rate .nozzles to apply the, highest practical spray volume. Nozzles with higber rat~s flows

produce larger droplets. ~, ,Pressure -- Do not exceed the nozzle nianJlfacturer's recOmmended pressures. For many nozzle ~ypesJow~r !pressureproduces l!ltger drpplets'.When~ti.gher floW rat~s at"e ileeded~ ,lise higher flow rate nozzles instead of

ji1ct~ingpre$sili:e. . . • 'Numberofnozzles- Use the minimum Olimberofnozzlesthat provide unifoi:m:coverage. '. ' Nozzle; Orientation - OrieD-tihg~ozzles ,sotl,iatthe simiy IS r¢le~ed p~an~l to the airstreatn pr04uces,larger

droplets than other'orieniationsand is the,recoIiimended practice. Significant deflectlonJrom horizontal will. ' reduce droplet size and.increase cifilt potential. '

i '.1; Nozzle Type - use a nozzle type that is designedJor the intended application. With mostnozzlerypes, narrower. spray angles produce larger droplets. Cortsiiierusing low~drift nozzles. Solid stream nozzles oriented straight back produce tbe largest droplets and tbe lowest drift. .

BOqM LENGTH: For some use patterns, reducing. the effective boomlengtlt to less than 3/4 of the wingspan or rotor lengt maY further reduce drift witho1Jt reducihgswath width. , " .

APPPICATIONHEIGj{T: ApPlicatloIis :s~()uldnQtbc .~deata.height greater:than.10 feet aboxe,U}etop. of~e'lru:ge$t pIaritS 1Jnle~s a greater height isrequi.reclf()rair¢t'aft's~~tY\Milingapplic~tions at theJ6west1ieighitharissafe,redci~ils " expo~ureofcltopIets toexaporation and wind: . ' . .. . ", , ,

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SW ATHADJUSrMENT: 'WhenappIlcations are made with a crosswind, the swath will be;displaced dowri~in(L '. ' " 'Therbfore, on the up and downward edges of the field,the applicator must compeI!sate for this dispIacemt!n~ \)y.adjusting iliepath of tbe aircraft upwind. Swath adjustment distance should increase, with increasing drift potential (high wind, smaller drops~ eic,) , .

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WIND: Drift potential .is lowest betwe~n wind. speeds of 2to '10 mph. However, many factors, including droplet ,size ana equipment type determine drift potential 'at any given speed. Application shOUld be avoided below 2 mph duetovariilbIe wind[directionand high inversion potential. NOTE: Local terrain can influence~d patterns. Everyappli6~tors~oJldl?e . farni:U.ar with local wind patterns and how theyaffectspl'ay drift. ". ;, . .;,\ '

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TEMPERA TURE'AND HUMIDITY:.When making applicationsin.lowrelative humidity "set up equipinehit9proa~¢~ ,larger droplets io compensateJor evaporation. Droplet evaporation is most severe. when conditions are hothho(and dry" '

TE~ERATURE INVERSIONS: Applications ~houldnot Occur during a temperature inversion becaris~'drift potential is high. Temperature inversions restrict vertical air miXing; which causes small suspended dropleis to remain.ih a , conc~Iltrated cloud, This clou,d can move il). unpredktable, directions due to the light variable winds e<>ni.i'\1on during' iliver~ions. Temperature inversions are characterized 'byinC,reasingtemperatures with altitude and are common on nights with iimited cloud covcr and light to no wind. They begin)o form,as the sun sets and often continue into the morning. Their presence can beindicated by ground fog~ however, if fog i~not present, inversions can also be identified by the mov~ment of smoke from a ground ,source or anaircrat'tsmoke,generalOr. Smoke that layers and moves hirer-aUy,in a' ,conc~ntrated cloud (undedow windconditions)indiCates:ari~in:version, while'smoke that movesupward;Iiti<;i.rapidly '.' qissipares indicates good vertical air miXing. ., ,' .. , " ' ". " '

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UPIM~[ribuzin 4FMa,~er UibeJ Page 9 of 56,

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SENSITIVE AREAS: UPI METRmUZIN 4F should only be applied when the potential for drift to adjacent sensitive areasi(~.g. residential areas; bodies of water, known habitat,for threatened or endangered species, non "target crops)'is minimal (e.g. when wind is blowing away from the sensitive areas).; ,

, APPLICATION .OFuplMET~imzI1\~·4F WITH I '. H.E~JCIPESPRA)~EQrn:r~NT,,· , " " ,

U~¢ ~. s.tandatdlow pressm:e ;(40 to40 p~i) Mrhicide hoon,L spf!lyereq\lippe~ ~i~sqi~ple noziJes and.screepsJ).o' f:i~er tl1~,n ·:;O~ii1r.~lf iil tl9zi.l,e and.ih~n* straiiters, .Agitate 'th()rou~hIY lJef9re~~d ,clwiiig applicalioil with byp~ssa~it~tion.: '

GRqUND ~PPtJ:CATIQN: Apply the proper rate of UPI METRlBtJZrN 4F.in a'minimum. of 10 toAOgallons of spray mixt*e per acre, broadcast.

Banded Application: Use proportionally Jess UPI ,METRmUZIN 4F per acre in a band versus a,broadcast application. For hand application use 1/4 to 1 gallon of spray mix per inch of baM width regardless of row spacing,

EXAMfLES: (1) To treat a IS-inch band' on rows 30 inches apart. use one-half of the broadcast rate of UPI " ME~RIaU4JN 4E (2) To treat a 14-inch band on rows 42 inches apart, use onecthirdof the broadcast rate oil-WI

,·ME11RIBUZIN 4F. ' :"",>,.,' , ',. ',I, .

• ',,;: > ,'. ! . :,.' '~" .' >.. ' , .' . . , '". .": " '., . . .... ' :.' . ..' ..... . ~. ..' . ~:ER;IAl; APPLlCA TION:\Yherepertnitte.<i; apply speCified rate in a minimum of 2 to 10 gallon~ of sptay;tni~tut~per, '

-aCre.' Do not apply aerhilly wben windspeed:isgreater than 10 mph. ' " ;' . . . - .. ' .. . , ' , NOllE: 'Do ,not apply aerially whenupI METRmUZIN 4F 1s UUlkmixed with~so,

1. " , ' '" " , , For ~II Applications of UPI METRIBUZIN 4F: Sp,rayer must be accurately caIibrat¢dbefore applying UPI METRmtJZIN 4F. Check sprayer during application to be sUre it is working properly and delivering a uniform spray pattern. As the volume of spray mixture decreases per acre, the,importancc of accurate calibration and uniform application incr~es. A void over application. mis~application. and boom and spray swath overlapping thatwilUncreasespray dosage. (Crop injury may occur as a result. ) Avoid spray skips: and gaps which allow' weeds, to grow in untreated ~soil. 'Do, not " , apply when :weather condi!i,ons, favor spr~y drift and/or, vihensensitive or ,cool season crops,such,ascole Crops~ onions, peas;jor s1tawberriesare preseiltin,adjacent fields odnareaswhere wheatisgrowingiil co~e textutedsoils.,

'S~~~R<::~EA~: Spray equipmeilt must,be thoroughly cle,aned to remove remaining traces of'herJ:!jcide thattnight injUt# oilier ~OPSJo be sprayed. ofain anyremaiiling spray solution of UPI MEXRrsUZIN.4F from the spray"lank and disp(l,seof according toI~bel disp<>salinstructions. Rinse the spray tank and refil1with water, adding a heavy-duty detergent at the tate Mone C\lP pet 20 ,gallons of water. Recycle this miJ!;tUi:ethrough the equipm,entfor 5IIl.iIi.u~es and spraY, out Repeat this procedure twice., Fill the spray tank with clean water.recyc1e for 5 minutes, and spray ouL,' Ciean pump and nozzle screens tboroughly. Wash away any spray mixture from the outside of spray tank, nozzles or spray rig.

, All rinse water m.ust be disposed ofin cOmpliance With local, state, and FederalgUidelines. ' ,

" ,!PPLICA'rION OF UPlME'fRIBUZI~ 4F IN FLUID FERTILIZERS' UPI METRmUZIN 4F lJ!aY be applied ihfluid f~rtilit~!soliitions'to,~faIfa an~ soybeans by following the appropriate,

, 'rriixh~g procedures,aildcompatibility che«k.' When using tank.mixcombinati()ns, be sure all compori~nts' ~e compaii'~le, ' . . . )"

:ComPatibility checkS of UPI ME1'RIBUZIN 4F and tank mixco~binatiOriS whichinc1ude UPI'METRlJfOZIN 4F; sh6ulct be made for each batch offluidiet:tilizers, because of the variabiIlty of. th¢se fertilizers~ , •

COllIpatibility Check: " ' 1. Pre-mix 2 teaspoonsful of UPI ME1RIBUZIN 4F with 8 teaspoonsful of water (1:4 ratio) in a qmirtjat'by adding

the water first and followed with UPl METRIBUZIN 4F. " Mix thoroug~ly. If a second herbicide is t6 pe used, double the amount Of water (1:8 ratio) and add the second herbiCide after mixing UPI METRIBUZIN '4F frrsL',

2. Then pour 1 pint of fluid Jertilizer into the quart jar anel shake well. ~. Allow to statidfor5minute,s,

THI$COMPATJBILITY CHECK SHOULD oN!. y BEUSEDwH~~ MIXING.WITHFLUIJj ;F~T1:I0IZ~~S.

Interi>r~t;ltion'of Resul~: If the solution in thejar appears to b~ri~ormlwitb6ut signs ofaggjom~ra~~Il. Qt~jtl10ut a separ~tion of an oily film on top ()f the fei-ti.ijzer. ihe mixtUJ:'emay be;,pse(:L; If not. repeat the cp®:atibiliry,@eC;k·using twice the amount of waler ot add a compatibility agent to the water., ~nepatati6n occurs,'but the riiixtliI'e can be re­suspended by shaking. then app1ication.i~ possible with good agitation irithe spr~y tank.

UPl Metribuzin 4F Ma~r Label Page 10 of 56

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Tank Mixing GuMelines: 1 .

i L Acldthe req\lired amoli,ilt of waJer anc,l compatibility agent (ifrequire(l) 10 the tank. Starta~~tion:~Y!ltemwhile I adding upr METRIBUZIN 4F and follow by adding the· fluid fertilizer and. agitate.· . 2. If a second herbicide is to be used, follow as above in 1, but use twice the ~niouilt of water. Start agitation and

add UPI METRffiUZIN 4F and follow by adding the second herbicide, and then ~ontinue fIlling the tank with fluid fertilizer,

3. Maintajn continuous agitation to assure \,Il).iform spray mixture until the tank is emptied.

COMMERICAL IMPREGNATION AND APPLICATION OF UPlMETRIBUZIN 4FON DRY BULK FERTILIZER

Dry l;mlkfertilizer may be impregnated orooatedWith UPlMETRlBUZIN4F for<application to established aifalfaa!1dto soyb~ans. AlI:iecommendations, cautions, and specialpiecautions on thisl~bel mustbe followed along'withstate '. ri~gul~tiQns relatin,gio dry bulk fertilizer blending, iinpregnating and l<ibeling:' . ..

IinP~eg!lation: To impregnate, l,lse. asyste.m cqnsis,tingofabelt, conveYor, or close<!.!irum which is us~dfor diybulk . fertiliz,er blend~ng., Any eommo~lIy used fertilizer can be.impregnated with UPIMETRffiUZIT:-l4F e)\.cept atrimonimn

nitrate, potassium niti:ate, or sodium nitrate; Dp not use on powderlimestQne .

Apply using a minImum of 200 Ibs dry bulk fertilizer per acre and up to a maximum of 450 lbs per acre. To impregnate or coat dry bulk fertilizer •. mix UPI METRIB UZIN 4F wi~ sufficient water to .form a sprayable slurry. The deli very nozzles must,be directed to deliver a fine spray toward the fertiliierfor thorough coverage while avoiding spray contact with , mixing equipment. Uniform impregnation of UPI METRIBUZIN 4F to dryt)ulk fertilizerWil~ vary and if the absorptivity is not adequate,anadsorptivepowder,may be added to produce' a dry, free-flowing mixture. Micro-~el E (Jolu,ts~Manville .Prodfict Corporation) is the:recomniendedabsorbent powder. When another herbicide is used With UPI METRlBtfZIN.4F,

! • ..' '. .. ..... ... , mix and: impregnate inrtnediately. I '. ...... .. '"

Appl~ immed~Sltely ~fter impregnation unless experienct! has shown that impregnated fertilizer can be stored with~ut bec<$ing lumpy and difficult to spread.

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Ra~: Select the recommended rate of UPI METR.IBUZIN 4F per acre from the appropriate section of this label and refer'to the formula below to determine the amount of UPIMETRIBUZIN 4F which is to be impregnated on a ton of dry bulk fertilizer based on the amount of fertilizer which will.be distributed on one acre.

Pints UPlMETRffiUZIN 4F X 20001b Fertilizer = PintsUPlMETRIBUZIN 4F Per Acre Per Acre.' .. Toil of Fertilizer ..

AFPJ.JCATION: Uniform applicatlonis essential for satisfactory weed cOntroL Accurate. calibration of fertilizer application equipment is essential foruriiform distiibutiont.oihe soil surface. The recommended method ofapplicatiph fs tOapply 112 the recomihellded rate and overlap 50 percent or to double apply by splitting the middles to obtain the best ',. ' distriblitionpattern. . " .

. If fertilizer materials are excessively dusty. use diesel oil or other suitable additive to reduce dust prior to impregnation as dustY fertilizer will result in pOOr distribution during application. Crop injury andlor poor weed coritrolinay occur where theithpregnated fertilizer is not uniforn1Iy applied. . , . .

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INC9RPORA TION ANDCOMBINA TION US~: WhepUPI METRffiUZIN 4F is to be ~ed in eombiri~ti()n with another herbicide, follow directions oil thisJabel for combinations, rates, crops, *ncorporation, and speCial precllution's. !' .. ..... .' .'. .

• .~9YBEAl'JS i . (Except in California) .' .

UPI METRIBUZIN 4F: herbicide tank mix combinations aie recommended for preplant incorporated applications, pre­emergence surface applications, Split-Shot application and:Extended Split"Shot application. UPIMETRlBUZIN 4F is also recommended as an overlay application following a preplant incorporated application of a recommended grass herbiCide and alone as a pre-emergence surface application. All these applications can be applied with ground equipment, and sprne can be applied witli aerial spray equipment. InadditiQn, UPI METRIBUZIN 4Fean be applied as a poste'mergence directed spray to soybeans in certain states.

UPI ~etribuzin 4F Ma .. ;fer Lai:lel Page liof56 ',' ~ ,,;,i . '

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speC~1 Precautions (soybeans): . Injury to soybeans may occu(when UPl MEfRlBUZIN 4F is used under the following. conditions:

.. When soils have a calcareous surface area or a pH of 7.5 or higher . • Due (0 the sensitivity of certain soybean varieties, UPI METRIBUZIN 4F is not recommended for use on Altona,

AP 55, AP 71, Asgrow 6520, Burlison, Coker 102, Coker 156; Dassel,.GL 3202, Govan, Maple Amber, NB 3665, NKS 1884, Paloma 350, Portage, Regal, Semmes, Terra-Vig 505, Terra-Vig606, Tracy. Vansoy. and Vinton 81. Consult your UPI Representative or your seed supplier for information on.the tolerance (0 UP! METRIBUZTN 4F of newly released soyb~an ,:arieties. prior to use of ,UP I METRIBUZlN 4F.

~. When applied inconjuIiction with soil-applied prgimicphosphate pesticides.; Over application or boom overlapping rnayresultoin stand10ss and soil residues. Uneven application or improper incorporationeandecrease the hivel of weed control and/or increase the levei of

. injury .. •

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When applied to any soil with'less than 1/2% organic matter. Soil incorporation deeper than recommended. When sprayers are not calibrated accurately.

• When heavy rains occur soon after application, especially in poorly drained areas where water may stand for several days.'''' .. ,

• When soybeans are planted less than 1-112 inches deep, particularly in pre-emergence application.

;Acti~ati~)D: A minimum ~olmt of Illoisrure is required to activate UPIMETIW3UZIN 4F. In areas iflQw{airif~~l,pre­emergence app1icalion~ to dry soil should be foUQwe<J with, light irti~il.tion of 1/4 acre incl1·ofwater., ,DonQtapply hCI;lVY lrrig~tion mediately afrerapplication. -As Withmiuiy surface-applied herbicides, weeqcontrQlartcl <:top tblenlnceinay . vary :.vith rainfallandlor soillexture. '

I . . Gra~ng and Feeding Treated Vines: Trealed vines may be grazed or fed to livestock 40 days after application, when UPJ METRIBUZIN 4F is applied alone or with Treflari®, Dual®;Prowl®, or Lasso®.. .

Do not use treated vines for feed or forage when UPI METRlBUZIN 4F is applied with Sonalan®, linuron plus Lasso, or . linuron plus Dual. .'

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RatelRanges: Where a rate change is shown, use a lower rate on ,soils that are coarse-textured or low in organic matter. Use a higher rate on soils that are relatively fine-textured,in organic matter. .

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Repl~nting: Ifreplanting is necessary in fields treated with UPI METRlBUZIN 4F as directed on thislabel,thc field may, be replanted to soybeans. When replanting, a mi Dimum of tillage is recommended. Do not apply a second. treatment as, ,injury to soybeans may occur. .

WEEDS CONTROLLED BY UPI METRIBUZIN 4F AND.UPI ~TRIBUZIN 4F HERBICIDE TANK MIX COMBINATIONS C=Control S=Suspension or Erratic Control P=Poor or No Control O=No irifoi'nlation (Control may range from poor to excellent) l=UPJ METRmUZIN 4F Alone I4=UPI ME11UBUZIN ~F Plus Dual 17=Extendcd Split-Shot .. 2=UPI METRIBUZIN 4F Split-Shot 5=UPl METRIBUZIN 4F Plus Prowl 8=UPI METRmUZIN 4F Plus Sonalan 3=UPIMETRIBUZIN 4F Plus TreOan 6=UPI METR mUZIN4F Plus Lasso 9=UPI METRIBUZIN 4F Plus Linuron.-mus (Lasso or Dual), ANNUAL BROADLEAF WEEDS 1 2 3 4 5 6 7 8, 9 Black Nightshade (Solanilm niRrurri) P P P C P C C P

, S

"Bristly Starbur (Acanthospermum hi.qjidUin) C C C C C C C C C Buffalobur (Solanum roslralUm.l C C,. P P P P C P ,0' ;', CarpeiWeed (Mollugo vefticillatiJ) ....... ,' C C C C C 0 C ··C _~:C

COCklebur (Xanlhiilmpensvlvtiiiicuin) S 'C 'S S S 'S C S " -, :' 'S" "< Ccrpperleaf, Hophombeain (AcalYPha ostrVae!olia) .C ·C C C C C C 0 '0 Florida BeJ!J!arweed (Desmodium ronuosum) C· C- C C C C C C C Florida Pusley (Riclwrdia scabra) ·0 C C C C C C. ~C

.;.

C Galinsoga (Galins01!G .f"".) C C C C C C C C C Hon;eweed Marestail (CmlVza cQlUJdensis) 0 0 0 0 0 0 C 0 0 Jimsonweed (Datura Slramfmium) C C C C C C C C S Knotweed (Po/Yf((llIum spp.) C C C C C C C C C Kochia (Kochia .~coparia) C C C C C C C C C Lamb:iQuarters (Chenopodium .fPP.) C C C C C C C C .C Momihgglory, 'IvyJeaf (ipomoea hederacea) P' p, 5 P P P P P. P Momingglory, Pitled(lpolnoea locunose) ,P P '5 P P p, P P P Mornihlllllory, 5mallflower (JaCQUeITUJnlieliamnifolill) P P I C P P P P P' .,p

,MorilinJ!~lory, Tull (Ipomoea purpurea) p P 5 P P P P P P Pigweeds (Amaralllhus,spp.) . C' C 'C C C C C C '.' ,·,':;··· .. 0· '

..

Prickly Sidafreaweed (SitkJ spinosa) C C C C C C C C C ,

UPI Mctribuzin 4F Master Label Page 12 of 56 .', >,-'

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Purslane (Porrulaca o/eracea) C C C C C C C C C Rugweed, Common (Ambrosia anemisiijolia) C C C C C C C C C Redweed (Melochio corchon/olia) C C C C C C C. C C Russian Thistle (SalsoUl Iulli) C C C C C C C C C Sesbanla (Sesbania sr",.) C C ·C C ·c c: c c C

. Shepherdspurse (Capselia bursa-paslOris) C C C C C C C C C Sicklepod (Cassia;ohrusifolia) C C S C. S C C S S SmartWeeds(PoIYJ(lInum spp.) G C C C -C' C' C C S. Sponed Spurge (EUphiJrbia matu/ata) C C P C P C C P 0 Spurred AnOOa (Anoda crist ora) C C C C C :C C C 0 Sunflower (HeliantiUls spp.) C C S S S S C S P Velvetleaf (AbutiliJn iheoTlil,.asri) C C' C C C C C C C Venice Mallow' (Hibiscus lriollum). C C C C C C C C C Wild Mustards (Brossica .vPP.) C C C C C C C C .C

WEEDS CONTROLLED BY UPI METRIBUZIN4F AND UPI METRmUZIN 4F HERBICIDE TANK MIX COMBINATIONS C=Control S=Suspension OR Erratic Control P=Poor or No Control O=No information (Control mayran2e from' poor to excellent) l=UPIMETRmUZIN 4F Alone 14=UPI METRmUZlN4F PlusDuaJ 1.7=Extended Splil-Shol . 2";UPl METRmUZlN 4F Split-Shot .. 5=UPI METRmUZIN 4F Plus Prowl '8=UPI METRmUZIN 4FPlu8 Sonalan

.. 3=UPI METRmUZlN 4F Plus Treflan 6=UPI METRIBUZlN4F Plus Lasso' geUPI METRIBUZIN 4F Plus Linuron plus (Lasso or Dual) ANNQALGRASSES 1 '2 3 4 ! 5 6 7 S· 9 Bamyard:Grnss (Echinochioa cruscRaUi) S 'C C C··' C C C C C BluegiaSs·(p(la.anhllli) C 'C C C C C C C C BrOlidleaf Signalgrass (Bradljana pUltyphVlla) C C C C C C. C C 0 BroWtitCiD Millet (Pallicum ramo,mm) C C C P C S .C 0 0 Crolb)iilss (Dig/loria spp.) C C C C C C C C C Crowfootgrass (Dactvloctellium aeRYlJtum) C C C C C C ·C 0 0 CupgraSS (EriClchliJa {(radiUs) P C P P P P C 0 0 Foxtails (Setaria spp.) . S C C C C C C C C Goosegrass (Eleu.fine illdica) . C C C C C C C C C JohnsOngra~s. Seedlinll (Sorllhumhalcpense) C C C C' C C C C 0 Juilglerice (Echiliochloa colonum) 'C C C C C C C C 0

, Nut.~ge. Yello", (Cyperus esculenlus) P .1' P .C P C C P 0 'PaniCtiin; Fall (PalliculII dichO/omlflorum) P C C, ·C C C C C iG Panicu'm, Texas:(Pimicum te.tanum) P C C P C S S C 0 Red,Rice (OryW sativa) P C· C C P "C C 0 0

i Sandbitr (Cencilrus S]jp.) P C C P T S S :0 0 Shattercane (SOI:1Lhum bie%,.) P C C P .p P P C 0 Sorghum, VoJoriteer,(Somhum spp.) P C C P P P .1' 0 P Sprailgletop (Leploi:hUia spp.) P C C P P P P 0 l' Stinkgi:as.~ (Eragmslis spp.) P C C P P P P 0 l' Wheat: Volunteer (Triticum SP11.) P l' P P 'p P P 0 P Witcbilrass(Panicunt capUlare) P C C C C C C C 0

SOYBEANS: UPI METRIBUZIN 4F ALONE Preetnergence Application: The foIl()wingrates of UP I METRIBUZlN 4F may be applied pre"emergence to soybeans thro~gh center pivot or lateral move sprinkler irrigation systems that apply water in a uriiforIli manner. Refer to ,'. "Ghernigation"section ofthis label' for directions; .

UPl METRIB tJ,ZIN 4F can be applied br()adcast qr banded. This application maybe made·dllrihgplanting6r asa s¢plirate' . oper4tion after planting bllt before crop emerge.nce. See the "General Information" section. in the front of this iabel.

Do not apply to sand soils, or to sandy loam or loamy sand soils containing less than 2% organic matter. Do not incorporate into soil or apply more than once persea.,ono'·-:"-~'··

UPI Metribuzin 4F Ma~lerLabel Page 13 of 56

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. Pints of UPI METRIBUZIN 4F Per Acre .. ·:Or~anic Matter

SOIL TEXTURE LesS than 2%. Zto'4%" Over 4%' COARSE SOILS (Sandy loam. loamy sabd) Do Not Use' .' 3/4 1 MEDIUM SOILS (Loam, silt loam, silt., sandy clay, sandy 3/4 to 1 1 to 1-1/4 1-1/4 to l-U2 C1ayloam) FINE SOILS (Silty clay. silty clay loam' clay, clay loam) Lto 1-114 l-1I4to 1,112 1-112 to 1-3/4 Mississippi Delta Only .1-112 1-3/4 2 I For, control oflambsquaners, redrool pigweed and wild mustard, and for suppression of green, yellow and giant foxtails on alkaline (calcareous) soils in Nebraska, Minnesota; South Dakota,and.Norih Dakota only, applyuPI METRIBUZIN 4F at rates, of Y2 ptlacre onmeditim soils and 112 to 3/4ptlacre on fine sOils.regardlessof soil organic matter percei)tilge (use 3/4 pt only where . soil ~H is less than 15 and wet:d pressureislleavy).The.i12 pt'lacre:rateofm>l METRIBuzIN 4F alone can be app:Iie<i regat~less.ofSoil pH: For' cOntrol of othetweeds listed, oil this lilbel.use uPI¥ETRlBUZIN 4F at full 'rates reconinientled In the .table :above, but noie. that crop injury may occur on spils ha:Vinga calcareous surface area or a pH pf 7.5 or hjgh~, 2 5iltyc1ay loam soils.are transitional soils and maybe classified as medium textUred soils in some regions of the US . .3 Re~er to the appropriate section of this label for use or UP! METRlBUZIN 4F on soybeans in coarse soils with 0.5% or more orgariic matter iii certain states, ' , .

U~ES OFUPI METRIBUZIN 4F HERBICIDE IN COMBINATION WIm OTHER HERBICIDES

SQYBEANS: SEQUENTIAL APPLICA nON OFSCEPTER® FOLLOWING UPIMETRIBUZIN 4F If ne~ed! application of UPI METRIa UZIN 4F alone or iIi a reiisteredt~ mix according to directiqns on ,this label, Dlay beJollowedby an early postemergence application of Scepter herbici(ie(1.5lb/galliquld or 70 DG)for control of., ". cocklebur.' Apply 1/6"to 1/3" pintof Scepter, (0, '7 to'L4 .ounces ofScep~~ 70 PG) in a minin:ium~f 20 gallons Qfwaieiper act:e.[Use 1/6 pint of Scepter (O~7 ounces ofsdepter70 DG) if coeJdebllfs are' less than 3.inclles tall or have,f~wer1han3 leav~s and ate actively growing. For,cocidcburs less than ~ inchestalf'and~ctivelyw-()wirig use 1I3pini ot's~epter(i.4 ounces of Scepter 70 DG) per acre, Donat use Scepter wheri soybeans or cockleburs havebeellsubjeci:ed to stress, conditions'such as temperature or moisture extremes. DO.not exceed a total of 2/3 pint Scepter (2~8 ounces of Scepter 70 DG) per acre in one season. Wait at least 10 days after application of Scepter before cultivating.

When preparing the spray mixture with Scepter, acid 2 pints of nonionic surfactant approved for use on growing crops and cont~~ng at least 80% active ingredient per 100 gallolls of mixture. Apply crop oil concentrate (COC) at the rate specified on the COC labeL .

Use$cepter only in the states where it is, registered as listed 00 the product label.

;ii.. '.':, Appl~ Scepter:iIt lelis!90.d.ys I>eJi)¢b""'SI Of"'y~~"" Do not gtax< or feed soybea.Iom.,., bay, at ,traw .t"·"~stOCk: -Refe! to the Scepter hi~el for additiomlI.ctiutions and. precautions, directions, limitations, and information on en Vifonmental hazards and planting of roiational crops.

SOYBEANS: SPLIT·SHOT APPUCATION A pnlplant incorporated application of UPIMETRIBUZIN 4F tank mixed with either Tieilan, Lasso, Dual, Prowi or Sonalan and followed by a pre-emergence surface application ofUPI METRffi(fZIN 4F alone after planting but prior to soybean emergence; will control more broadleafand grass weeds in soybeans than when either herbiCide is used alone. . .

'. 'Referl to the Tre~an, ~so, Dtial,,I>rowI or Sonw.an labels, and to !l.pprOpriatesections of this:label fo(dil:ectjons ()n,soil' , prepa:ra~on, llerbicide application; incorporationtechIjiques,l:!erbiqide, ratb's;'weed' species controlled,',and, restrittipnj(for . usingt~I:c~·coml:>inations of tJplME'rroB'QZIN 4:F,C~ewUfob~¢ive the,,"SpedalPrecautions" 'seetjoriconeenung the u~e of Ul'lMErRIBUZ!N 4F in tarik mixcOll1bin~tioiis,Oti;soYbeap~. '."' .

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When a Split-SllOt application ofTlPI METRlBUZINAF wit)l Pro"YI, Tteflan, or Sotialanis used, the preplaritincorporated. tank mix may be:~pplied up to 21 days prior to planting soybeans; with Duai or Lasso, the preplan!' incoipoiated ·tank.mix may be applied ,up 14 days prior to planting.

On mediunl and frnetextured soils witbgreater than 2% organic matter, a rateninge is recommended for the UPI METRIBUZIN 4F pre-emergence overlay application. 'Therugher rate should be used (a) in fields with a history of severe broadleaf weed pressure, (b) when the time between preplahtiiicorporated tank mix and: pre-emergence overlay applications approaches the maxiinum stated above. iilldlor{cj wb~n th~ organic matter content ofthe soilis.at the upper end Of the iIiQicated range. . .

UPTMbtribuzin 4F.Master Label Page 14,of56

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for black nightshade control, refer to the appropriate sections of the Lasso, Dual, or Sonalan labels for specific instructions. \

'. SPLIT·SHOT APPLICATION

Pre.plant Incorporated Tank mix. Application - FOLLOWED BY':' Preemereence' Overlay Application ) Rate ()f lJPI MF;TRIBUZIN 4F I , (Pint/Acre)

011 anie Matter SOIL, Rate of Combination Plus RateofUPI. TExTuRE' Product/Acre METRIBUZIN . Less Than 2% 2%i04% Over4% .

4F.I'intlAcre COARSE Treflan I pt (Light) sand, or :La.~so 2 to 2-112 qt loamy sand. or Ou811-1I4 to 1-1/2 pt. Plus 112·Followed by 114 114 114 to 112 sandy loam . or Prowl 1-112 pI.

or Sonalun 1-114 to 2 PI. MEDIUM Tretlan 1·112 pt. Loam"silt loam .. or Lasso 2-112 to 3 ql. 3/4-. Followed by 114 114 (0112 Y2103/4 sandy l=lay loam, or Ouall-ll2 pI. .Plus 'or si1(~ sapdy clay. or Prowl l-il2pl. 1122_ Followed by 112 .112 to 3/4 (3/4 to 1)3

I ' .. or Son alan 1-314'to 2-112 ut: MI" ; ".1>,,,

FINE ,(Heavy) .. Treflan 2 pt: Silty clay loam", orLasso 2-112 fO 3 qi: 1.0- Followed by 1/4 114 [0 112 112 to 3/4

. clay loam, sihy or Oual2 to 2·112 pt. Plus or clay, clay orProwll-ll2to2pt. 3/42

_ Followed by 112 . .112103/4 (3/4 to Il or Sonalan 2-1/4 to 31>t.

>I< Silty clay loam soils are transitional soils and may be classified as medium textured soils in some regions of the U.S.

I On ~oarse textured soils, do not use on sand soils with less than 1 % organic matter, or on loamy sand or sandy loam soils will) Jess than 0.5% organic matter. However, on coarse textured soils with a calcareous surface ~ or a pH of7.5 or higher do not use on sand soils with less than 2% organic matter, or on loamy sand o~ sandy loam soils with less than 1 % organic matter .

. 2 Use this lower rate of UP! METRIBUZJN4F in the preplant Incorporated tank mix on soils having a calcareous surfaqe area or aplJ of 7.5 or higher, and in those situations where S()ils within a field v,ary extremely in texture or organic matter COntent. . . . . .. . 3 Rtxiuee this preen1erg~nce overlay rate UPI.MJ!TRIpUZIN 4F by 1/4 ptlacre when iJsing SPLiT-SHOTappIlcation on soils WIth over 4% organic matter and which.have a calcareous,surface area or a pH of7.5 or·higher. .

:" SOYBEANS: EXTENDED SPLIT·SHOT APPLICATION (J nchides No-Till, Reduced· Till, Ridge. Till, Strip-Till, Mulch· Till)

An early preplant (surface-applied or shallow incorporated) application of UPIMETRIBUZIN 4F lank mixed with either Dual or Lasso, followed by a pre-emergence surface applicl!tionof UPI METRIBUZIN 4F tank mixed with Dual or Lasso after planting but prior t() soybean emergence, will control more broadleaf and grass weeds.in soybeans than either herbicide alone.

An Extended SPLIT -SHOTapplica:tion will decrease the need for tiilageand/or COlitact herbicides for the control of exis4ng vegetation prior to planting, while providlng residual control of weeds afteiplanting.

When an Exte1'!ded SPLIT-SHOT application of UPI METRrimzIN 4F with Dual or Lasso is used, mepreplant tank mix cotlJbination IDaY be applied 15 to 30 days prior to planting soybeans. Follow directions on me labeJ accompanying'the product fOf SPLIT-SHOT applications from 0 to 14 days before planting.

Where ~rate range is recommended, the higber rates should be used (a) in tields with a history of severe weed pressure, (b) when the time between early preplant tank mix andpre-emergence overlay applications approaches the maximum 30 days, (c) when the organic matter content of the soil is at the upper end of the indicated range, (d) when heavy crop residues .are present on the soil surface, and/or (e) when the early preplant tank mix application is shallow incorporated (e.g.llse 2 to 2 112 qt Lasso in the early preplant tank mix when surface applied and use 2-1/2lo'3ql. La.<;so wherithe tank mlx.is to be iightl,y incorporated). . ' . '. .

Whe~ weeds exceed 1 to 1-112 inchesinb,eig~t or dillmcter atapplicatiop; use a contact he~l?ici<.le,.stichasRQund~UP® or I .' . .

Gramoxone. . ,

Refer to the Dual or Lasso label, and to appropriate sections of this label for additionai information on soil preparation, herbicide application, weeds controlled, precautions, restrictions, limitations and sprayer clean-up. .

UPI Meuibuzin 4F Master Label Pa~e 15 of 56

"......,.."..,....,..."...,..-~...,.--....,..,.-----.,---------- .. ---.... -.. '"'-.-,-... i .

: EXTENDED SPLIT -SHOT APPLICATION ' . Early Pi-eplant Tank MIx Application . " Preemergence Overlay Application . 'l"" ! (Suiface.Applied lir Sh8Jlowlncorporated)

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; Rate of ' Rate of UP I Followed Rateot ·Rate of UPI METRmUZIN 4F Combinatkln METRIBUZIN By . ,Combination Pint.'lIAcre·

SoU Product/Acre Plu.~ 4FPtlA Product/Acre Plus Organic Matter Textprel 112 to 2% 2 to4% Over 4%

;

COARSE Dual )-)/3 pt. (Light) or Dual 213 pt. Suoo, Lasso Plus 112 to 3/4 Or Plus l/4 1/.1 toJI2 112

loamy sund. 1-112 ro 2 qt. Las.~ [.1/2qL sandy\loam l\fEDIUM Dual 1-3/4 pI. . Loarti.sill ·or Dual 3/4pL

. loam:, sandy .. Las!jO Plus 23/4 toJ or Plus 1/2 [/2-314 3/4. tol clilyloam. 2 to 3qi. Lasso 1102qt. silt. sandy

clay ItINE Pual2 pI.

UIeJivy) or' Dual [ pt .'

Silty!clay Lasso' Plus 21 (0 1-114 or .. "{

Plus 112 112 10 314 314 to 1 loam~.clay 2 to 3 qt. Lasso 1 to 2 ql. loam; silty c1ay.ielay' -

*Silty1clay.loam soils are transitional soils and may be cl~jfied as medium textured soiL~ insorne regio~s of the U.S; . . IOn cOarse textured soils. donol use, on sand soil with,Ies.~ than I % organic matter. However. on coarse textured soils with.a calcareous suiface area~ra pH op.s orbigher. dO.not use on sanqsoils with lesS than 2%,organicmatter, or onJoumysand,or sandyJoam soils with less than 1% .. orgamc matter. '. ,"". '., . '

. lUse t.\te lower rate.of U,PDyIETRffiUZI1'! ~Fin the early prepl~J.Ulpk mi~ on Soils having a calcareous R\lrface area ()f a pH of 75 orltigh~.,and:i1:l those rate Situations where· soils Within a fie[dvarv extTeniely in textUre or orllanic matter Content. . '. . ' . _ '

: SOYBEANS: UP~ METRIBUZIN 4F plus Sonalan. UPI ~ETRIBUZIN 4F plus Sonalan Overlay AppliCation: UPI METRIBUZIN 4F F may be applied as a pre­emergence overlay application following a preplant incorporatedapplicalion of Sonalan 3 BC. Consult the Sonalan label for specific directions on usc, recommendations, restrictions and any additional weeds not specified on this label.

UPI METRIBUZIN 4F plus Sonatan Tank mix Appli<:ation: Incorporate the tank mixture into the top I to 2 inches of soil within 21 days before planting according to label directions fcir Sonalan. .

Apply UPI METRIB UZIN 4F plus Sonalan preplant iltcorponited if furrow iirigaticin is used or when a periocl of dry w.eath~ after application is expected; If soy~ans.are planted on beds, apply and incorporate the tank mixture after bed 'formation. " - . . , " '

MiXirig: Refer to the "General Information" section in the front of this label.

Application: Somilanshould be uniformly applied and thoroughly mixed into the soil within 2 days after application. For specific application information. refer to the ''Oenerallnformation'' section in the frontofthis label.

,BROADCAST RATES UPI METRIBUZIN 4F Soruilan 3EC

, SOn.. TEXTURE PtlAcre PtlAcre 'COARSE! (Srindy·loaIri:;loamysand) 112 1~1/4. to 2 ':"''ii'-''N;:,

MEDJUM'(Loam,siItIoam, silt. sandy Clay, sandy Clay Ibam) , " , 3/4' J-3/4to 2-112 "

.. FINE"' (Silty'clity; silty clay loam", clay, clay loam) L 2-1/4 to:3 .I Do not use on coarse soils with less than 1 % organic maner. . . 2 Silty clay loam sollsare transitional soils and maY 'be classified as mediUlll textured soils i,n sorncregions oftheU.S~ 3 For;control oflambsquarrers. redrootpigweed, wild mustard"and green and yellow foxtails on alkaline (calcareous) s(lils in Minnesota, Nebraska, South Dakota. and North Dakota only, applyUPI METRIBUZIN 4Fat rates of 1/2 pt/acre on medium soil~ and 112 to 3/4 pt/acre on fine soils regardless of soil organic matter percentage (use 3/4 pt only where soil pH is less thall 7.5 and weedlJrcssure is heavy); The 112 pt rate of UP I METRIBUZlN 4Fin tank mix combination with Sonalan can be applied reganpess of soil pH. For control of other weeds not listed on the label. use UPI METRIBUZIN 4F at full rares recommended in the taJ"le above, but note that crop injury may occur on soils havinea calcareous surface area or a pH of 7.5 or hiaher. Spcci8J Precautions: For adclitional precautions. restrictions. limitations, incorporation, and sprayer clean-upinfonnation, refer to thCi appropriate sections of this Jabel and the Sonalan label.. '. ., For biack nightshade control. ,refer to the Sonalan hibeJ forsjiecific rates and application instructions. ,

; I . .

UPT Melribuzin 4F Mast,er Label 'Page 16 of 56

SOYBEANS:UPI METRIBUZIN 4F plus TREFLAN UPI METRIBUZIN4F and Treflan Overlay Application: UPJ METRIBUZIN 4F may be applied as a prec:emergence'. broadcast or band overlay application fpllowing a pre-plant incorporated treatment of Treflan. Consult the Treflan label for specific directions for use, recommendations, restrictions and any additional weeds not specified on this Jal:>el.

UPI METRIBUZIN4(i'plus Treflan Tank mix Applicati9n:. ASi~gle <Ipplicatiop of It ta~ mix c()mbiOA~()n oLUPI . METRIBUZlN 4P and Treflan Ee wil~conttolmOl:e broadleaf 311.4 grass weeds in soyb(;!an,s thaJ) when.eit1i¢f'4.erbicid~ is used kIone. '. '. . .

1<';

Preplire the soil surface by deep plowing, offset disking or tand~~ldisking prior to th¢ application of the herbicide' com~ination. The soil surface should be well prepared and free of Clods and trash.

This UPI METRIBUZIN 4F plus Treflan tank mix combination may be applied and incorporated inlOthe soil up to 10 days beforp planting.

Mixipg: Refer to the "General Information" section in the front of this label. . . . . i". " ..

App~Cation: For specific application information refer to the "General Information" section in the front of this label.

. ' •. ·.ApPl~UPI METRllH,JZIN 4f plus TreflantQthe soil surface ilildincorPor:ate in the,sa.!ll~ operation.ifpQssib}e. Variable weed'coiitrolmayresult from delayediilcotpoiationjfUPI~UZIN 4F plus Treflan are applied toaWet~warnisoil surface or'if the wind velQcity is io miles per hour or highet.Use machinery that tnixes UPJ METRIBUZIN 4Fplus TreflllO thoroughly with thc soil. Incorporation may be delayed up to 24 hours after. appiication .. Shallow incorporation with implements setto cut less than 2 inches deep mayresultin erratic weed control. Do not use spike oispring-tootb harrows alone for incorporation.

•

IncoJ.poration Equipment:

i. Sct PTO-driven equipment (tillers,cullivators. hoes) to cut 2 to 3 inches deep and spacefl)tors to provide a clean . swe~p of the. soil. PTO equipment should not be operated at a speed greater <~an 4 lniles perhoux:~.

2. Set qisk tpcut 4 to 6 inchesgeep,ah4 ()perate twice in diff~rent directipnsl\t'4 to6miles pefholirs. . q. Set mUlch treader andother~imilar dIsk-type implements rocut,3 to4inches, deep aild'op(;!r!ltQ[wi,ce ii1diffefe*,~ I directions at 5 to 8 miles Per bOilr. . . . . . ' . . ... ..

4. Forcoarse and medium texfilred soils only: Set f()lliJ,lg cUltivator to cut 2 to. 4 inches deep and operate twiCe at. 6 t08 miles per hQur. Set bed conditioner (Do-Al1)to cut 2 to 4 inches deep andoperare at 4to 6 tniles per hour .

SOIL TEXTURE COARSE1 (Sandj'loam loamy sand) MEDIUM (Loam, silt loam, silt. sandy clay, sandy clay loam) FINE,(SiI7 clay, silty clay loam',cIay, clay loam)' . ,

BROADCAST RATES UPlMETRlBUZIN 4F PUAcre

, 112

3/4

'J Do not use on ·coarsesoils.withJess than 1 % organic mauer:

Treftan ECPt Per Acre

1-112

2

2. SiltY clliY loam. soils are tran,sitiomil. soils and may.be classified as medium texmred soils iii som.e regions of the US. 3 For!controlof lambsquaners, redroot pigweed, wild mustard, and gI:een andyello.\V .foxtails o'naIkaline (calcareous) soils in' . Minnesota, Nebraska, South Dakota. arid North;ptpcota only. apply UPl~TRIBUZIN4F at rates of 112 ptl,acreOil'mediuin soils,~ and 1I~ to 3/4 ptlacre on fine soils regardless of soil organic matter percentage (use % pt only where soil pHis less than 7.5 and weed.' pressure is heavy), The !liz pt rate of UPI METRlBUZINAF in tank mix .combination with Treflan can be applied regardless Of soil . pH. For control of other weeds not listed on the label, use UPI~PZIN 4F at full rates recommended in the table a\x)Ve, but . note that crop inJury may occur on soilshavine a calcareous surface' area or a pH of 70S or hi,Aher. Speci8l Precautions: Seedling disea.~e. cold weather. excessive moisture, h!gh Sall concentration or drought may weaken soybean seedlings and increase the possibility of damage from the tank mix. Do not plant soyb~sdeyper than 2 inches. . •. .. , ,In theTentral United States. do not plant sorghum or oats for 12 nlonthswhere the tank mix has been applied l?uless ~Oinchcs (if. .. . more of: irrigation and/or rainfall (total) was used to produce thd:rop: Ifless than 20 inches total water was used.to "pro<luCi the crqp' during the year,donot plant either tTOP for 18 months ·after the tank mix application; Cool. :wet w~ther conditions during thc,early., stage pf growth inayintTease ~epossibility of injury to sorghq.m, ,. ',. " . . . : ,:", .," : .,' For additional precautioris, restrictions. limitations and sprayer Clean,upinfonnation reter·to the appropriate section of thisJaheJ.:Do not usetbistank.miX combination on soils containing charcoal in Arkansas~ Lonisiatia. and Mississippi.. '. ' ,

UPI Metribuzin 4F Master Label. Page 17 of 56

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SOYBEANS: UP! ME:UZI-N~~~-US-D:: 1sJ:: UPI ~TRmUZIN 4FplusDual' Ovetlay Application: . Applya;prepl~t iilcorpora:tedtreatmentof Dual 813 asdirecteQ . 'onth~tproduct label for use on:soybea.ns; 'Follow with apre~eiriergence treatm,ent.ofUPlMETRlBUZm 4F as directed'.oil this hlbelfor use on soybeans.

UPIMETRIBUZIN 4F PLUS DUAL TANK MIX APPLICA TIONS Preplant Incorporated Application: Incorporate the tank mixture into the top 2 inches of soil within 14 days before plant~ng using a disk, harrow, rolling cultivator, or similar implement

Apply UPI METRIBUZIN 4F plus Dual preplant incorporated iffiIrrow irrigation is used or when a period of dry weather after llPplicationis expected. If soybeans are planted on beds, apply and incorporate the tank mixture after bed formation.

Pre~~mergence Application: Dry weather followingpre-emergence application of UPlMETRIBUZm 4F plus Dual tatik. mixtt/remay reduce effectiveness. If weeds develop, cultivate uniformly witb shallow tillage equipment such liSa rotary"

"'hoe that will pot iliwlag~ soybeans. . ";. . .

Mixi~g Insti:uctions:Re£er to the "Generallnformation;' section in dte fr~nt of this label.

Fo~ i¢"ormation on applying UPI METRIBUZIN4F inl1uid or dry fertilizer, refer t6 the ·~Applicationof UP! MEI;RIBUZIN 4F in Fluid Fertilizers" or ''Commercial Impregnation and Application of UPIMETRIBUZIN 4F on Dry

. Bulk :Fertilizer" sections 'in the front of this label.

Special Precautions (UPI METRmUZIN 4F and Dual): For additional preca\ltions, restrictions, limitations, and sprayer clean-up information refer to the appropriate :sections of this 1abel andtbe DualliibeL .

i .' '. BR(),.\;J)CAST~ TES· . .• , UPIMETRIBUZIN 4F Plus Dual Tank Mix Preemer2ence Applications

Organic Matter \

SOIL TEXTURE 0.5%t03%' .Ovet3% METRIBUZ!N Dual8E METRIBUZIN Dual8~

4FWUAcre) PtlAcre 4F (PtiAcre) PtlAcre COARSE (Loamy sand, sandy loam) 112 1-114 3/4 1-112 MEDIUM (Loam, silt loam, silt) 314 1-112 1 2 FINE (Silty clay loam", sandy clay loam, silty cIay; sandy clay~ clay loam, Clay) . I 2 1 to 1-1/4 2 to 2-1/2

, .MISSISSIPPI DELTA ONLY: (Silty clay, clay);.. '. . ltol-1I2 .. 2 1-112 2t02-li2 J ,00 notuse,onsaiid sOils. 00 not apply UPIMETRIBUZIN 4F~andDual overlay or tank: rriixpreemergence on Joamy sartd with lesitt4an 2% organicilJatter. . .... ... . . 2'Silty clay loam soils ate transitional soils .and may be ciaSSified as medium textured SOils in some re~ions of the US.

; 'BROADCAST RATES

UPI METRIBUZIN 4F PlUs DUAL Tank Mix PrePlant Incorporated Apmications OrganiC Matter

SOIL TEXTURE 0;5% to Less Than 3% 3 % or Greater UPI UPI

METRIBUZIN Dual8E METRIBUZIN Dual8E i 4F (PtiAcrefc;'.' :::!:'PtlAere 4F (PtlAcre) PtlAcre

COARSE' (Loamy sand, sandy loam) .112 1-1/4 112 ;Fin MEDIUM (Loam, silt loam, silt) 3/4 . 1-112 .3/4 '2 FINE (Silty clay Ioam-. sandy cIay loam, silty ' .. clay; sandy clay, clay loam, clay) 1 2 1 2 t02~112 M~0SIS~IPPI DJ):L TA ONLY: (SiltycIay. " , ~ .. '

cIa ! . Ito!-]/4 .2 1 to 1.-114 .2 to 2e lh . po not use on sand soils; DO,not apply UP} METRIBUZIN·4F plilsDucil tank mix preplantincorpor:ited' on sari4 orlo~ysand

with less than 2% ocgailic matter or crop injury may occur. . . 2 Silty clay loam soils are transitional soils and may be classified as medium textured soils in some regions ciftheU .S.

,

. . SOYBEANS: UPI ~TRIBU,ZIN 4F Plus PROWL UPI METRIBUZIN4Fplus Prowl Overlay Application: Apply a preplant inco~oratedtreatment of Prowl as directed on that product label [or use on soybeans. Follow with a pre-emergence treatment of UPI METRIB UZIN 4Fas directed on. this label for use on soybeans.

uprMetribuzin 4F Master Label Page 18 of 56

,. '-:' " '(i" ;.,. f".,<

,:"""\,,,-,-. c~U~~ETRmUZJN4F-p-IUS-' :-pr-o-W;-I ~Ta-nk-Dll-.X-A~P::tio~C'C'~j

'.,.:.' ' ,Prep~ant Incorporated 'Application: Prepare the solI by plowing or dhiking·to,mlx previous crop residues into the ,soil to

•

.. ~>

a depth of 4 to 6 inches. For specific,application information refer to, the "Genetal,lllformation" section in the front of this ~~ ,

, '

IncorPorate the tank mixture into the top 1 or 2 inches of soil within 7 days after application according to label' directions for Prowl. Mechanical incorporation is not required if a rain ,of one-quarter inch or more occurs within 7 days after a:ppli~tion. Soybeans must be planted no later than 7 days after application,of the tank mixture.

Pre"J-merge:nte Application: Except for minimumand:n()-tillagesystelIiS,the seedbedshould,be firm and freeo,f trash and Clods., }iotspecific al'plicat!:oil infoI'Iru,ltion reftn: tothe:''G~neral InfCltmati()fl" sectio~ in ihefront,df this. labeL Do nQt ap~l)( Prowl pre~emergence north of Intersrnte 80~, ", ' ,"" ,

This ~pplication must be made after planting and before crop emergence. Do not incorporate. !

If cul~ivationjs necessary because of soil crusting, soil compaction or weed gertnination, before rain or irrigation, use shallow tilling equipment such as notary hoe that does not damage soybeans.,

Mixing instructions: Refer to the "General Information" section inthe front of this label.

For iDfoPnationon applyingUPI METRIBUZIN 4Fin,fluidor dry fertilizer refer to .the "Applicationo! UPI 'MI3TRJBl.JZJN 4F in Fluid Fertiijzets" or u<:;oIlIDlerci;ll TJi1pregna~OI~ ;lD.d Application Clf UPI METRmUZIN 4F Qn Dry BWR!Fei1jlizer" s'ectiOli~ ii:l the front ohhis label. '. .', "

,Speciai Precautions (lWI METRIBUZIN 4FplusPro~l): Soil incorPoration deeper than the recommended: will r~duce ' . weedic(lntroland can result in crop injury.

For additional precautions restrictions, limitations, and sprayer deane up information, refer to the appropriate sections of this label and the Prowl label.

, Southern States and Eastern CoaStal Plains

For ,use only in Alabama, Arkansas, Florida; Georgia, Louisiana, Mississippi, North carolina, Oklahoma, South~tem Missouri "Bootheel'; Region and Coastal ' Plains of Delaware*, Maryland"', New Jersey·, and Virginia*.' ,

·*UPI ~TRIBUZIN4Fplus Prowlis.not recollUllended fo~ u~e~n soils with less than 2% organic,~tterinthe.coastalPlain of New Jersey or the DelmarvaPeninsula. . . : "'. ' / " .

~ '. ,BROAJ)'CAST RATES' UPI METRmUZIN4FPl~ Pr~:wl TankinixApplications

i SOIL TEXTURE UPi METRlBUZIN 4F PtlAcre Prowl PtI Acre COARSE' (Sandy loam, loamy sand) 1/2' 1-1/2 ,

I " . , i-1I2 MEDIUM (Loam, silt loam, silt, sandy 3/4

clay, sandy clay loam) l

F.JNE:' (siltY clay, silty clay loam', clay, clay loam).. 1 1-112 to 2 I Do hot use on sand soils. Do not u~eon loamy sand or sandy 19am containing less than 1 % org;mic matter. 2 SiltY clay loam soils are transitional soils and may be ,classified as medium textured soils in'c:eitain, regioris of the U.S. 'Do riot, use on muck or peat soils. ,:::~>:".':p;~. "t ".

,

UPI M'etiibuziri 4FMaster Label Page 19 of 56

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•.• :_ ......... ~ __ ~." ... _ .• ~~-'N_.;' .• :~; i

';:

.. ::~:~1 FhyP

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NORTHEASTERN AND NORTH CENTRAL STATES For use only in lllinois. Indiana. Iowa. Kansas, Kentucky, Michigan, Minn~ota. Nebraska, New York. North Dakota. Ohio. Pennsylvania. South Dakota, Wisconsin and Missouri (except in the "Bootheel" Reliion).

BROADCASTRATES . UP) METRIBUZIN 4F Pins Prowl Tank Mix Applications

SOIL TEXTURE

COARSE' (Sandy loam, Loamy sand) MEDIUM (Loam. silt loam. sandy clay, sandy blay loam) FINE~(Siity clay, silty clay loam2

• clay. clay

. Organic Matter . .11.2 to 3%

UPI METRIBUZIN

4F (PtIAcre) 1/2· 3/4

Prowl PtJAcre

1-112 to 2

Over 3% UPI

METRIBUZIN 4F (PtIAere)

3/4 3,4 to 1

Prowl .PtJAere

1-1/2 .!-lf2t02

loam) 3/4 to 1 1-112 to 2 1 to 1-1/4 2 to 2-1/2 Do not use on sand soils. Do not use on loamy sand or sandy loam containing less than 1 % organic matter. Where a range of rates

is shown for medium arid fme soils. use the higher rate if heavy weed.infestations are anticipated. . '. 2 Silty claY loam soils are transitional soils and may be classified as me4iumtextured Soils in some regi()ns of the U.S.

Do not use on muck or peat soils. . .....

SOYBEANS: UPI METRIBUZIl~4F Plus LASSO . UPI METRIBUZIN 4F Plus Lasso Tank mix AppUcation

PREEMERGENCE UPI METRIBUZIN 4F may be used in a tank mix combination with Lasso as a pre-emergence band or broadcast application to soybeans in accordance with the specified soil types and dosages recommended.

For specific information regarding spray equipment, dilution rates, mixing. directions for use, methods of application. , limitations and restrictions refer to the appropriate section of this label.

S~ecil~l Preca~tions (upI METRIBUZIN 4F Plus,L3$s(»):" For additional precautions, restrictions,limi~ationsand ..... spraypr ~lean-up infonnation. refer to th~ appropriate sections of thisJabel and the Lasso label: Refer to the Lasso label for perti~ent recommendations, directions for use. restrictions andany additional weeds not specified on thi.s label.

;

Do not use on muck soils.

RECOMMENDED APPLICATIONS . BROADCAST RATES

UPI METRIBUZIN 4F Plus Lasso Tank MiX Preemergenee Applications Organic Matter

son) TEXTURE 112t03% Greater Than 3% uPI PIns Lasso UJ>1 Pins Lasso

. METR.IBUZIN' QtJAere " METRIBUZIN ,QtJAere 4F. (Pt/Acre) 4F,(PtlAcre)

COARSE1 (Sandy loam) 112 . plus 1":1l2oto 2,' 3/4 plus 1-11210 2 MEDIUM (Loam; silt 3/4 plus 1-112 to 2 1 plus I-In to 2 Joam,:silt,sandy clay, sandy c1ayloam)y <.~ .. ~v .. ~.

FINE' (Silty clay. silty clay 1 plus 2 1 to 1-114 . plus 2 to 2 .. 112 loam3, clay. clay loam) . MISSISSIPPI DELTA ONLY (Silty clay [0 UPI METRIBUZIN 4E PtlA£r~ + LaS§Q QllA£[~ heavy clay) 2+'2 to 2-112 ,.

Do not use UPI METRIBUZIN 4F plus Lasso on sand or loamy sand soils with .less than 2% organic matter. 2 For'comrol of lambsquarters. redroot pigweed. wild mustard,/rtCCrt. and yellow foxtails on alkaline (calcareous) soils .in Minnesota, Nebraska, South Drikota,arid North Dakota only,appiY.UPI METRIBUZlN 4F at rates of 1/2 ptlacre on medium soils and 1/2 to 3/4ptlacre oli fine soils regardless ~f soil organic matter percentage (use3/4 ptonly where·soi1 pH is less:than 7:5 arid, ' weed pressure is heavy). The 112 ptlacre rate ofUPl MEI:RiSpZIN4Fcltarik nUx: combinatic)fi with Lasso can be applied . regardless of soil pH. For control of other weeds use UPi'METR:IBUZlN 4F at full rates recominended ili.the table above, but note qlat crop injury may occur on soils having a calcare<lUs surface area or a pH of 7.5 or higher. 3 Silty clay loam soils are transitional soils and may be classified as medium textured soils in some regions of the U.S.

UPI Melribuzin 4F Master Label Page 20 of 56

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Pre]ll"".lncorj>orated: For specificapplicaliori.infonnation refer to the''GeneraI Information" section in thefron! oHhis . :J~ . labelJ. . ..

. . ,~ P" ' ~~~.~ ,';.A l(. ••• :

. AppiYUPI METRIBUZIN 4F plus Lasso preplant incorporated ifJurrow irrigation is ~~d or ~hen a period of dry weather after ~pplication is expected. Ifsoybeans are planted on b~ds, apply ahdincorporate the tank mixture after beet formation. Apply within 7 days prior to planting and shallowly.incorporateinto the upper 1 to 2 inches of soil.. . .

, ; RECOMMENDED APPLICATIONS

BROADCAST RATES UPIMETRmUZIN 4F Plus LaSso Tank Mix Preplant Incorporated Applications

SOIL TEXTURE . UPI METRIBUZIN 4F PtiAcre Lasso QtlAcre COARSE (Loamy sand, (over 2% 112 200.2"1/2 organiic TIUltterJ, sandy loam) MEDll.JM (Loam, silt loam; silt) t 3/4: . 2-112;103

I FINEi·(SiliY clay loam', sandy clay loam; ... ' .1 2-112;(03 'silty clay. ;sandy Clay, clay loam, clay)

;

'"

MissisSippfDeltit OnJy(Silty clay; Clay) 1 to 1-114 2-112 i03 • 1 po not use 'PPI METRIB.UZIN 4Fplus Lasso on sand or!oamy sand soils with less than 2% organic matter. .. ; 2 Siltyclayloiun soils are transitional soils andtnay be.classified as medium textured soils in somer~ons oftheU.S~

SOYBEANS: UPI METRIBUZIN 4F Plus COlllll'1and® UPI METRIBUZIN 4F may be applied in combin~tion wiihCommand 4EC as a preplant or shallow incorporated application f()cthe control of certain wpeds in. soybeans. Consult the Command 4EC label for specific directions on use, recotiunendations, re~.trictionS and any a~.ditional weeds not specified on tbis label. .. ! '. . ... . '

Mixing: Refer to the'''General Information~" section in thdront oUbis label.

App~cation: UPI METRIBUZIN 4.fplusCommandAEC: may only be applied with ground :t'lquipmentasa prepl~tor shallow incorporated application. UPLMETRIBUZiN 4F plus Command 4EC should 'be immediately incorporated into the top f to 3 inches after application unless surface is dry. On .dry .soils, incorporate into the top 1 103 incheswithin,3 n()lIrs

. of farik mix application. . .

Do nOlapply this iank mix within 10()() feet of towns and subdivisioIlS, cQmmereial vegetll.ble, fruit, nurseries or greenhouse operations,

A mihlmum of 15 . gallons spray. volume per ~re isrecon':nliended with appropriate nozzle types and sizes to prQduce a coarSe spray droplet. The use of an approved a,gricult~aLdriftreducing additive is recommendedJor application volumes' of 1$ to 40 gailonsper acre. the use ofanapprove!1agrlCuitural drift reducing additive is required atspray volumes of 10 to 15'gationsper acre.' .'

.. Note~ Off~site movement of Co.mmaild spray drift or vapors can cause foliar whiteningo~ yellowing of some vegetation .. Priori to application of Command~read and sirictly follow all precautions and appijcation instructions as set forth in that labeL' .

For additionarinformation on application,tefer to the "General Information" section in the front of this label and the Command label. .

• .. ;.:," ... ; .. ,,,.:,. WEEDS CONTROLLED

Bristly Starbur Purslane Broadleaf Signalgrass Carpetweed Corilmon Ra.,crweed CrabgraSS'" .

,-copperleaf . Ri:dweed F()xtail, Green) Floricl<l Beggarweed Sesbania' . Foxtail, Yellow'" F1orid:iJ, Pusley SIfuihweeps Foxfail, Rbbust P)Jrpl¢ GaIin~oga Spurred . Anod a Goosegtass' Jimsonweed Velvetleaf lOlm$ongrass (seedling)"'. Knoty..eed venice Mallow Fall.Panicum* Lam~squarters Wild Musta,rds Texas Panicum Pigweeds. . Bamyardgrass'" Witchgrass Prickly Sidaffeaweed Bluegrass "'Use -2 ntl A Command 4EC on Coarse and medium teXtured soils Withhigh..JlQpplations of these weeds.

UPT Membuzin4FMasier Label Page 21 oi.56

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',. "1;

RECOMMENDED APPLICATIONS 4.\~ BROADCAST RATES

UPl METRIBUZIN 4F Plus Command 4EC Tank Mix Preplant Inco~ated A~Ucation Organic Matter

SOIL TEXTUREl 0.5% t03% Over 3% UPI Command4EC UPI Command4EC

METRIBUZlN PtlAcre METRIBUZIN .PtlAcre 4F (Pt/Acre) 4F (PtlAcre)

. COARSE' (Sandy loam, loamy sand)) 112 1-1/2 to 2 112 . 1-112 to 2 MEDIUM (Loam, silt loam, silt, sandy clay, slmdy clay loam) 112 to 3/4. I-ll2to2 112 to 3/4 1-112 to 2 FINE:(Silty clay, silty clay loam', clay,

. clav loam) 1/2 to 3/4 '1-112 to 2 3/4 to 1 1-1/2 to 2 Crop injury may occur on soils having a calcareous surface area or a pH of 7.1 or higher.

2. Do not use on coarse soils with less than 1 % organic matter. 3 Siltv,c!av loam soils are transitional soils and may be classified as medium textured soils in some re~ons of the U.S. Special Precautions: Do not rotate to wheat, oats, barley. rye, alfalfa or seed com in the fall of the year of application or in the spring of the following year as crop injury may occur. Do not appJy when weather conditions favor drift. Do not use treated vines for feed or forage. Obserye all cautions and limitations on labelirig of all products usCd in mixtures. Do not apply aerially or. through irrigation eqUipment.

SOYBEANS: UPI METRIBUZIN 4FPlus COnllDelice®

UPI ¥ETRIBUZIN 4F plus Commence Tank mix Early Preplant Incorporated Application: UPI METRIBUZIN 4F in a tank mix with Commence 5.25EC may be applied broadcast preplant incorporated up to 30 days before planting soybeans for the control of certainbroadleaf weeds and grasses. Refer 10 the Commence herbicide label for additional directions for use, weeds controlled, recommendations, restrictions and limitations not specified on this label.

MiXiilg: Refer to the "General Information" section on this label.

Application: For infoI'l?ation on applying;UPI METRffiUZlN 4F, refer to the "General Information" section on this label.

RECOMMENDED APPLICA nONS \ , ,

UPI METRIBUZIN 4FPtus Commence 5.15 EC'Tank Mix • EarlyPreplant InC()rporated Applicationa

, Ol"2anic Matter , 112 to 3% Over 3%

SOlLTEXTURE UPI METRIBUZIN Commence 5.25 UPI METRffiUZIN Commence 5.25 EC 4F(PtlAcre) ECPtlAcre 4F (Pt/Acre) . PtJAcre

COARSEb % I-1I3to2 314 1-113 to 2 MEDIUM 1 2 to 2·114 1 2 to 2-114 FINE 1 2·2/3 1-1/2 2-2/3 • For use on soils with a pH of 7.5 or lower. b Do not llse on coarse soils with less than' L% otnanic matter.

, Re.~trictions and Limitations! Do not apply aerially or through irrigation equipment. 'Do not apply when weather conditions favor drift. Do not allow sprays to drift onto adjacent deSirableplants . .Do not use . treate<! vines for feed or fotage~ Do not .rOtate to wheat:, oats, barley, rye, alfalfa or seed.com in theJall of~year of application or in the spring of tbe. following vear as crop injury may occur. "h"'·v~V"'· V

UPI METRIBUZIN 4F plus Commence Tank mix Preplant Incorporated: UPI METRffiUZIN 4F may be lank mixed· with Commence 5.25 Ee for preplant incorporated application to control certain weeds in soybeans. Refer to the "General Information" section of this label for information on mixing, application, restrictions, speciiu precautions and weeds controlled by UPI METRffiUZIN 4F. See appropriate sections ofthe Commence 5.25 'EC herbicide label for additional precautionary statements, directions for use, recommendations and 'additional weeds controlled.

UPI Mctribuzin 4F Master Label . Page 22 of 56

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, RECOMMENDED APPLICATIONS .

UPIMETRIBUZIN 4F~Plus Commence S;2SEC TankMJX " Pi:eplantlncorporated Application , . Orl!ailic Matter i

ll2to 3% .- Over 3% SOIL'TEXTURE1 UPI CommenceS.2S EC UPI CommenceS.2S EC

METRIBUZIN (PtIAcre) METRIBUZIN (PtIAcre) 4F (PtJAcre) 4F(PUAcre)

COARSE~ (Sandy loam, loamy sand) Yl 1-1/3·to 2 112 1-113 to 2 MEDIUM (Loam, silt loam, ,silt, sandy clay, sandy cbiy loaIll) 11'2 to 3/4 i t62-1I4, 112 to.3i4 2toH/4 ,FlNEi(Siltyclay, silty clay -

," loam\ clay, c1ayloam) . ' 112: to 3/4 . ;- 2·213 3/4tol 2-2/3 '. Ctop irijurymay occur "on s6ilshavilig a crucweous ~iuface area ora pH of 7. r or higher.. -2 Do not use on coarse soils with less than 1 % organic matter: ' 3 SiltY. clayloain soiis are transitional soils aodmay be Classified as medium textured soils in some regions of the O.S .

. Specilll Precautions (UPlMETRIBUZIN 4F plus Commence): Do not rotate to wheat, oats, barley, rye, alfalfa or seed corn in theJaJi of the year of applicatiori or in the spring of'theJollowing year as a crop injury may occur. ' Do nqt apply when weather conditions favor drift. Dooot use treated vines for feed or forage. Do not apply aerially or through irrigation equipment, , . .-

Do not allow sprays to drift onto adjacent desirable plants.

I . , SOYBEANS:IWI METRIBUZIN 4F Plus Free(fom® '. . UPl:r\ffiTRffi UZIN 4F may be tank mixed with Freedom3EC forpreplant incorporated application to control certaln

.. weed~ in 'sOybeans, Refer to 'the"GeneralInforlna.tfo~":sectit)itof this label for information on:t$lng; ap.Rli~aUo~,· restrittions, special precautions arid weedscontrolle<!'by UPI METRffiU:z:!..'N.. 4F. See apprOpriate .·se~tiOnsOf the Freedom 3 EC!herbicid~ labelfor additional pre9autionary_statements, directions fot:use,recointneIidations~andaddicloiw weeds. -controll~d.· . .

RECOMMENJ)EDAPPLICA TIONS BROADCAST RATES

UPI METRIBUZIN 4F Plus Fre'edorrNtank MIx.Prej)\ant Incorporated Apolication Ofl!anic Matter '.

soh. TEXTURE 112 to 3% Greater than 3%

UPI Plus . Freedom 3EC UPI . 'Plus Freedom3EC • METRIBUZIN ,:t(QtJA) 'METRIBUZIN ' (QUA) . <;

4F (Pt/A) . ~, ' .. _; . }

4F(PtIA) ", , .

, CpARSE(Sandy 112 Plus 2~3/4 to 3~ 112 3/4 Elus 3 ,to 3:112 . ,

loam)' MEDIUM~ (Loam, silt 3/4- Plus 2-3/4 to 3-112 1 Plus 3~lI2t04

.' loam.jsilt, sandy clay, ' sandy!clayloam) FINE~ (Silty clay, silty I Plus 3-1I2t04 Itol-1/4 Plu~ 3-112 to 4-112 clay Ibam3• clay, clay .'

loam) MI~ISSIPPI UPI METRI~UZIN 4FPtlAs;re": Freedom 3ECQi/Acre DELTA ONLY (Silty 2 + 3-1/2 to 4-112 . . clayi6 heavy clay)

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.Do riotuseUPI METRIBUZIN 4Fplus Freedom on san~odo1UIiy.~irid soils with leSs than 2%.organic matlcr. I::

.... -.-.-.-.-::::.~.---

2 For tontrOlonambsquarter~. redroot pigWeed. wild ,mustafd.greeqand yellowJoxtai1s on. alkaline (calcareous) soils in ....... .. ", , "

Minnbsota, NribraSka • .south Dakota, and North Dakqta0i!1y.oapplY '(fP,t,¥E,TRmUZIN 4J<at rates ofil2ptJa,cre.:Olipl~ill!Il:S~iJs4' Ii. and 112 to 3/4 ptlacre on fin(! soils regardless of soil organic matter percentage (use 3/4 pt only where.soilpH is'lessthim 7;5 3Il'f" 'Of weed pressure is heavy). The liZ ptlacre rate of UP! M.ETRIBUZIN4F:ii1l!ink mil!- combinatibnwith Freedom can he app~eil' .. : : regarc!less of soil pH.Fpr control of other weeds uselJPIMEnUBPZIN 4F atfull.rates recommended in the table·above; but note *at <-'fOp injury may occur on soils having a calcareous surfaCeare~or apH Of 7.5 othigher; . ~ Silty clay loam soils are transitional soils and may be classified as medium textured soils in:someregions of the U.S, Do not use on muck soils. Do ndt allow sprays to drift onto adjacent desirable plants .

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. UPl Metribuzin 4FMiu-lterLabel . 't'". .. -

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• ' SOYBEANS: upI METRIBUZIN4F PI,~ Canopy® Plus a Grass Herbicide " A tankmix cOinbinationofUPI METRIBUZIN 4Fplus Canopy 75 DF pl!Jsa registered and recommended grass herbicide (Du~, Lasso, Prowl. Sonabn 6iTreflan) is recommended to(CClIitrol of the following weeds in soybeans:

WEEDS CONTROLLED Annual Grasses AnnualBroadleaves

,B anl yard grass Johnsongrass (seedling) BristlyStarbur PricklySidaffeaweed Bluegrass Junglerice Carpetweed Purslane BrolldleafSignalgrass Pani¢um, I'all Cocklebur Ragweed,Common Browiltop Millet Panicum,Texas Copperleaf, Hophombeam ,Redweed CrabgTass ' Sandbill Florid!l BeggarweeCl, Russian Tfu$tle Crowfootgrass Sprangletop Florida Pusley Sesbania Foxtails S tirikgrass Galirisoga Shepl1erospurse Goosegrass Jimsonweed Smiutweed

, Knotweed Spurred Anoda Kochia Velvetleaf Lambsquartcrs Venice Mallow Pigweed Wild Mustard

, ." ~ . Tank; mix combinations which include Dual, Lasso or Prowl can be applied pre~emergence broadcast or preplant incorporated broadcast. When Sonala,nor Treflan are used in .the tank mix; applypre-plantincorporated Broadcast. Refer ,to th~ table below for recommended:rates of each product to be used in tank mix combinations. '

RECOMMENDED APPLICATIONS' BROADCAST RATES . UPI METRffiUZIN <iF Plus Canopy: 75 DF Plus A Grass Herbicide

Soil Tret1an DUal Prowl Lasso SonBIan UPI CailopyDF Texture! (PtIAcre) (PtlAcre) (PtlAcre) (QtlAcre) PtlAcre) METRffiUZIN (OzlAcre)

4F (ptlAcre) 1-1/4 to 1- 1-1114 to

COARSE1 1 112 1-1/2 '2 to 2-112 2 1/2 3 1-112 t02 1-112 to 2 1-1/4 to

MEDIUM 1-112 2-112 to 3 2-112 112 to 3/43 3 "

2 to 2-1/2 1-112 to 2- 2-114 to ~

,FINE 2 112 2~ll2l0 3 3 3/4to 1133 ,,3t04, I Do ll,otuseoQsOils withil pH greilt(lrthllD 7.0. . " ' . , 2 Refer to'~Soil Texture" paragraph onthis~~lfor specific soil classification., " '. 3 Uselhe lower rate of UP! METRiBUZIN 4F in preplaIitihcorpotated tarik rniX·as in those siLUiltions 'Vhere soils within a field vary extremely in.texture or organic matter Content . IMPORTANT: If weeds escape in fields treated with these tarik mix combinations, postemergencc application of a;registered and recommended herbicide will be needed for control. " , Refedto the "General Information" section of this label for mixing and application directions. SPE<:fIAL PRECAUTIONS: For additional precaution~, restrictions, limitations and sprayer dean-up information, refer to the appropriate sections of the labels for UPI ~RIBUZIN 4F an~ Canopy 75 DF. Do not use treated vines for feed or forage.

i SOYBEANS: UPI METRIBUziN 4FPlus COJD.Dt8IidPIUs a. Grass Herbicide, . " UP! i\mTRIBUZIN 4F truly be appli:ed with C()miIlah~4EC and,a grass herbiclde (Tretlan. Lasso, ,DualPro\vf of Sonaian) (otthe control .o(certainbroaQieaf weedsapd gta'~ses iI.1 soybe~hs> This combiDaUQ.u willpr()Vicle improved;cqntroi: of .' heavyinfestationsbf v6l velleaf. ji1ilSbnw~ed andcoffitri6ri'ragweed. UPI METlUBUzIN'4F and toIiiinruiCi;iEC'pIiis Ii, . grass'llerbicide may be appIledpreplant incotpOf~ted:"roadcaSt; Gansult theComIiiandt Treflan. Lasso! ,Dual, Prowl or SonalanlabeIs for speCific diI:ections for u!,;e, recomme:ndations, festrictio,ns and additional weeds contr()lled not $peCified on thIS label.

Mixing: Refer to the "General. Information" section in the front of this label.

Application: For specific application information, refer to the "General Information" section in the front' of this label.

UPI Metribuzin 4F Master Label Page 24 of 56

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, WEEDS, CONTROLLED 'f:g' " Annual Grasses AilniIalBrOlidleaves"j " rj ,

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Bamyardgrass Fox:tails , BristlyStafuuf- " Ragweed.Common ,

, Blueg'rass Goosegrass Carpetw~~ Redweed BroadlearSignalgrass Johnsongrass (seedling) Copperleaf,',Hophombeam, Russian Thistle

, Browntop Millet Panicum. Fall Florida Beggarweed Sesbania Crabgrass Witchgrass Florida Pusley , Shepherdspurse Cro"'footgrass ,Galinsoga Sickiepod

Jimsonweed Smartweeds Knotweed SpolledSpurge

i Kochia Spurred Anoda I

Lainbsquarters Velveueaf , "Pigweeds Venice Mallow

; prickiy SidaITeaweed Wild Mustards , ,Purslane

up! ¥ETR1B UZIN 4Fand CdIIllhahd plus TreHari, Lasso; Dual,,Pi'owl or 5ciruuan will provide suppressio!! (reduce the coinpetition) of cocklebur andsunHower. " ,

RECOMMENDED APPLICATIONS ; BROADCAST RATES

UPI METRIBUZIN 4F Plus Commd Plus A Grass Herbicide SOIL Treflan D1Ull Prowl Lasso Sonalan UPI Command 4ECJ

Texture (PUAcre) , (PUAcre) (ptlAcre) (QtlAere) (PUAcre) METRIBUZIN (PUAcre) , 4F (PtlAcre)

1-1/4 to COA'RSE 1 1-112 1-112 2to.2-1I2 1-114 to 2 1/2 112 to,3/4 ,

1-112t02 1~3/4 to 2" !

MEDIuM 1.-112 1-112t02 2-112 to 3 1/2 112 to 3/42 1/2toJ/4 , 1-1/2 to 2"

FINE 2 2 to 2-112 112 2-il2 to 3 2-114 to 3 3/4to f~ 112to3/4 Refer to "SoH Texture" paragraph on this label for specific soil clllssincation. On coarse textured soils with a calcareous suiface

area or a pH of 7.5 Or higher, do not use on loamy sand or sandy loam soils with less than i % organic matter 2 The:bigher rate of UP I METRlBUZlN 4F is recommended for the c.ontrolofsicklepodand hemp sesbania. Use the lowerrate of UPl METR1BUZlN 4F in the preplantincorporated tankmix on soils having a calcareOus surface area or a pH of 7.5 or higher, and ' in those situations where soils within a Held vary extremely in texture or organic matter ,content. ' 3 Higller rate is recommended under moderate tohe~ weed infestations.

SOYBEANS: UPI METRIBUZIN 4F Plus Scepter Pb.isa Grass lIerbicide UPI METRIBUZIN 4F may beappJied with Scepter herbicide and a grass herbicide (Treflan,.LasSQ, Dual, Prowl.or' . Sonalari) for the control of certain broadleaf weeds and grasses in soybeans .. UPI METRIBUZIN 4F and Scepter plus Treflan or Sonalanmay'be applied preplarit incorporated broadcast. UPIMETRIBUZIN 4Fand Scepter pIllS Lasso; Dual or. Prowl may be applied preplant incorporated,pre~emergence broadcast or in a band application.

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ConsWt the Scepter, Treflan, Lasso, Dual, Prowl or Sonalan labels for specific directions for use, recommendations; restrictions and additional weeds controlled not specified on this label.

!

Mixihg: Refer to the "General Information" section in the front of this label.

App~cation:. For specific application ,information, refer to the "General InfOrmation" sectioil in the frOht of this label. !

w~s C9otroUed: UPI METRIB'tJZlN 4F plus ScepietphlsTreflail, Lasso, -Dti~, PrQwl or SOlialan Will ¢Qlitrplthe folJowillgbroadleafweeds and grasses; .... '

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UPI~~tiipl!zin 4FMa~ter Label Plige 25 of 56

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WEEDS CONTROLLED . ,,- Annual Grasses Annual Broadleaves ," ~; .

Barnyardgrass Foxtails Bristly Starbur Pigweeds Bluegrass Goosegrass Buffalobur Prickly Sidaffeaweed Broad~eaf Signalgrass Johnsongrass (seedling) Carpetweed Purslane Browritop Millet Panicum, Fall Cocklebur Ragweed. COplmon Redweed ,Crab~ss Witchgrass Coffee Senna Russian Thistle Crowfootgrass Coppeileaf, Hophombeam Sesbania

! Florida Bcggarweed Shepherdspurse F1oridiPulsey' SiCkIepod Galinsoga SrhartWeeds Jimsonweed Spotted Spurge

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Knotweed Spurred Anoda Kochia Sunflower Lambsquarters Veivetleaf Monungglory, Pitted Venice Mallow Mornihgglocv; Smallflower Wild Mustards

UPI METRIBUZIN 4F and Scepter plus Treflan. Lasso. Dual. Prowl or SonaJan will suppress (reduce the competition of) ivyleaf and tall momingglory, and red rice. I,>, " '"

RECOMMENDED APPLICATIONS ~BROADCAST RATES '

Soli Trefian DuaI Prowl LassO "SonaJaD' UPI Scepter (1.S Scepter Texture! (PtlA) (PtJA) (PtlA) (Qt/A) (Pt/A) METRIBUZIN Ib/Gal liquid3 70DG3

4F(PtlA) PtJA)-or'· (OvA) COARSE 1 1-114 to 1·112 2 to 1-114 to 2 1/1 1/3 to 112 L4 to 2.1

1-112 2-112 MEDJUM 1-112 1-112 to 2 1-112 to 2-112 to 3 1-3/4 to 2- 1/2 to 314' 113 to 1/2 1.4 to 2.1

2 1/2 FINE 2 2 to 1-112 to 2-112 to 3 2-1/4 to 3 3/4 to 1- 113 to 112 1.4 to 2.1

2-112 2-112 Refer to "Soil Texture" paragraph on this label for specific soil classification. On coarse textured soils with a calcareous surface

area or a pH,of 7.5 or higher. do not use on loamy sand or sandy loam soils with less than I %oiganic matter, . 2 The pigher rateofUPIM~TRmUZIN4Fisrecommcndcil fcirpreemcrgence tank mix application and for the control of sickJepod 3ild.l:1emn sesbanill. Use the low!!frate (lt1JPI ME:rRlBUZIN 4F in thepreplailt incorporate<!: tank mix on .soils haying a calcltieous surface area or a pH of 7:5 or higher, and in those siniations where soils within a field varyextremely.in.textureCof . organic ,mattercoplent. . 3 Higher rate is recommended under moderate to heliVi' weed infestations .

SOYBEANS: UPI METRIBUZIN 4F Plus Pursuit® and a Grass Herbicide UPI METRIBUZIN4F may be tank mixed with Pursuit herbicide and a registered and recommended grass herbicide (Dual, Lasso, Prowl, Sonalan or Treftan) for control of certain broadleaf and grass weeds in soybeans. Refer to the product labels for Pursuit. Dual, Lasso, Prowl, Sonalan or Tretlan for additional directions for use, recommendations, restrictions and limitations not included on this label. '

Tank;mix combinations ofUPlMETRIBUZIN4F,Pursuit and Dual. Lasso.or Prowl can beapplied.broadcastpre­emergence or preplant incorporated. When the grass herbicide used'is Sonalan or Treflan. apply the tankmix broadcast preplhnt incorporated.

1 Mixing and Application: Refer·to·the "General Information" section.ofthis label for directio~son mixing and application" of UPI METRmuZIN 4F. .

RECOMMENDED APPLICATIONS , BROADCAST ,RATES

UPI METRIBUZIN 4F Plus pUrsuit and a Grass Herbicide* SOIL TEXTURE UPI METRIBUZIN4F (pt/Acre) Pursuit (OvAcre)

COARSE 112 4 MEDIUM 315 to 3/4 4 FINE 3/4 to 1·'·· ·4

'* For. control of grass weeds, inCludeDLial, Lasso, Prowl, Sonalan; or Tfeflan,at label rates in the tank !nix with up1 METRiBUZIN 4F and Pursuit herbicides. . '.. ." Restrictions and Limitations: Donat apply thistankmix with aefiw.or irrigation equiplllent.DO not appfywhen weather conditions favor drift. or allow sprays to drift onto adjacent desirable pll\1lts.· .Do not use treated vines for feed or forage. Refer to appropriate sections of the Pi.Irsuit herbicide label for restrictions 'on use area and rotationalcr~s. .' .

UP) Metrlbuzin 4F Master Label Page 26 of 56

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, SOYBEANS:upI METRIBUZIN 4F PIu.':IPursuit Plus Herbicide r ... : .. "

UPI M.ETRIB UZIN 4F may ,be U!1ik nllx(;)d with Pt,irsuit Plus herbicide fQT, broa4c~t pre.:emergence or preplartt incorporated application to soybeans fot,control of certain broadleaf and, grass weeds, Refeno tI;le Pursuit Plus herbiCide label for additional directions for use, recommendations, restrictions and liri}itations nbt included on this label.

Mixi~ and AppUcatlon: Refer to the "General Information;' section of this label for directions ,on mixing and application o(UPIMETRIBUZIN 4F. '

RECOMMENDED APPLICATIONS BROADCAST RATES

UPI METRmUZIN 4F Plus PUrsuit Plus Herbicide SOIL TEXTURE UPI METRIBUZIN4F (PtIAcre) Pursuit Plus (PtIAcre)

COARSE 112 2-1/2 MEDIUM 3/5 to 3/4 2-112 FINE· 3/4 tol 2-1/2

. RestrictionS and Limitations: Do not apply this tank mix with aerial 'or irrigation equipment. Do not apply when weather conditions favor drift. or allow sprays'to drifl onto desirable plants. 'Do notuse treated vines for.feed or forage . Refer to appropriate sections of the Pursuit Plus herbicide label for restrictions on use area.and rotational crops.

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SOYBEANS: UPI METRIBUZIN 4F,Plus Linuron Plus (Lasso or Dual) UPl METRIBUZIN 4F plus Linuron Plus (Lasso or Dual) Tank mix Applicatl()n: UPI METRIBUZIN 4F may be applied in combination with linuron 50 DF or 4L and Lasso 4 or Dual8EC as a pre-emergence application for the control of ce~n weedsjn soybeans. Consult the linuron, La..';~o, or Dual labels for specificdireclions for use, recommendations, restribtions and any additional weeds not specified on thislabel. "

.Mixfug: Refer to .me ,"General Information" selftion in th~ front of this label. . .

Appl~catlon: Applications can be matie only with ground spray eqUipment ii1 accordance with· specified soil types ~d dosage rates. For specific application information, refer to the "General Information" section in the front of this label.

UPI METRIBUZIN 4F Plus Linuron Plus (Lasso or Dual) Broadcast Rates (0.5%t03% Oramlie Matter Only)

SOIL TEXTURE UPI METRIBUZIN Linuron 50 DF (Ib/Aere) Lasso 4\ Dua18EC 4F or (QUAere) Or (PtIAcre)

(puAcre) 4L (PUAcre) COA~SE~ (Sandy, loamy . 1I4to 3/8 113 to lJ2 3/4 to 1 or 1 to 1-114 sand, sandy Jown) MEDIUM (Loam, silt 3/8 to 112 112 to}14 1 to 1"112 Or 1-1/4 ~o 1-112 lown;silt; sandy clay, sandy clay loam) FINE (Silty clay, silty day 112 to 3/4 3/4 to 1-112 1-114 to 2 Or 1-112t02 loam2, clay. clay loam) Do not use UP1 METRIBUZlN 4F plus linuron (Lasso or Dual) on sand soils with less than 1 % organic matter.

2 SHtyelay loam soils are transitional soils and may be classified as medium textured soils in some regions of the U,S. SpecUli Precaotions: For additional precautions, ~s4'!,c,t!,Q~s. limitations, and sprayer clean-up information. refer to the appropriate sections of this label and the Hnuron label and the Lasso or Dual labels. '

For Use in Coarse (Li~ht) Soils in Alabama, Arkansas,Florida,Goorgia, Louisiana, Mississippi, Missouri, North Carolina, OkIahOJ:ru~, South Carolina; Temiessee,Texas,andVirginfa. " ,

UPl MEtRIB UZIN4F herbicide is recommended ,alone or In combination with Trefian. Lasso. or DuaHor use in;coarse­textured. low organic matter soils in the states lIsted abo~e for 'tllecontrol of certain. weeds in soybeans. Refer to the appropriate sections of this label and the Treflan. Lasso or Dual htbel for specific directions for use,:recommendations. restriCtions. and any additional weeds not specified on this label. .

Mixing: Refer to the "General Information" section in the front of this label.

Application: For speCific application information, refer to the "General Infonnation" section in the front of this label.

UPI MetriblJzin 4F Master Label ,Page 27 01'56

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BROADCAST RATES UPI METRIBUZIN4F (A1o~e)Pre.emergence AwUcation

Soil Texture Organic Matter UPI METRJBUZIN4F(PtIAcre) Coarse (Light) Soils (Sand J. Loamy 0.5% or Above 112 to 314" Sand, Sandy Loam) J Not reconunended for use on sand with less than 1 % organic matter. 2 Use the higher rate under heavy weed pressures and/or on soils higher in organic matter.

UPI METRIBUZIN 4F in CombinatioR with Other Herbicides: UPI METRIB UZIN 4F is recommerided in a. tank mix combination with Treflan as a preplant incorporatedappllcation or as a pre-emergence overlay application Jollowinga preplant incorporated app]jcation ofTreflan. UPI.METRIBUZIN 4F is also recommended.for use as a pre-emergence application in combination with Lasso or Dual.

For Use in Coarse (Light) SOlIs , .' (Broadcast Rates) '. SOn., TEXTURE ORGANIC COMBINATION PLUS UPIMETRIBUZIN 4F

MATIER PRODUCT/ACRE (PtIAcre) COARSE (Light) SOILS 0.5% or Above Preplant Iilcorporated Sandl~Loamy Sand, Sandy Treflan 4EC 1 pt Plus 112 to 3/42

Loam , Preemergence Plus Lasso 4EC l-la t02 qt ,Plus, 112 to 3/42

Dua18EC 1-114 to I-In Plus 112 to 3/42

, I Not recommended for use on sand with less. than 1% organic matter. , ..

2 Use. the higher rate under heavy weed pressuresand/ot oilsolls highetin organic matter. , : Special Precautlons: Do not use on sand soils With less thnii 1 % 'organic matter, or on sandy loam orloarny sand S'oils wiihless tbap. 0.5% organic matter.' . . For additional precautions, restrictions. limitations and sprayer clean-up information, refer to the appropriate sections of this label and the Treflan, Lasso, or Dual labels.

FIELD CORN AND SOYBEANS: BURNDOWN WEED CONTROL UPI METRIBUZIN 4F can be used as part of a herbicide prQgram for burndown of ex.isting vegetation prior to crop emergence.in conservation tillage systems. UPI METRIBUZIN 4F may be tank mixed with 2;4-D low volatile ester (L VE), Gramoxone Extra, ()r RounduplRoundup Ultra(fouchdown for control of emerged weeds prior to field coni or soyb~an emer~ence. UPI METRmUZIN 4F tank inixes with 2,4-DB; Fusion, POast Plus or SeleCt may also be used in soybeans .for control of emerged weeds prior to crop emerge~ce. UPI.ME!RIBUZIN 4F burnd(iwn tank mixes can be applied before planting or prior to crop emergence in the following areas:

Fiehl Corn: niinois, Indiana, Iowa, Kansas, Kentucky, Michigan, Minnesota, Missouri, Nebraska, Ohio, South Dakota, and Wisconsin. '

Soy~ans: All areas for all products except Fusion tank mixes - see Fusion section of.this label for recommended states.

Application: UPI METRIBUZIN 4F may be app]jed up to 30 days prior to planting orpre-emergence. Apply only by ground equipment when UPI METRIBUZIN 4F is used for burndown of existing vegetation in conservation tillage systems. UPI METRIBUZIN 4F and tank mix partner burndown rates are listed in the following three tables:

UPI METRIBUZIN 4F BURNJ)OWN RATES· FIELD CORN AND SOYBEANS i

CROPS APPLICATION TIMING:", '!t!ii.:,UPlMETRJBUZIN 4F RATEJ91J~ Field Corn P:ceplliIit 0 to 39 days .

Iowa Nebraska 3t08 i Kansas South Dakota Preemergence I Missouri

Field Corn Preplant 10 (0 30 days 3 to 8 lliir10is Minnesota Iildiana Ohio Preplant 0 to 9 days Kentucky Wisconsin 3 to 6 Michigan Preemergence -

Soybeans Preplant, () to 30, days

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P.reemetgence

UPI Me;t;ribu,zin 4FMaster Label .. ' Pa~e 28 of56

i UPI METRIBUZIN 4F PLUSTANKMIX PARTNER;BURNDOWN RATES-FIELD CORN OR SOYBEANS PRODUCT .- ' RATE . b'DIRECTIONS AND REMARKS

UPI¥ETRIBUZIN 4F ":3 t() gil ovA* Ins()yj:i~s,:apply a~ l~aSt:7. qayspreplant when using2,4-D L VE!lt 1/4tq 112 Ib: , + lI~noilbai1A

ai/AandatJiiisi3(jidayspreplantwi,th rates.greater than l/21b aiJA Include crop \

12"U)LvE tlilco~~entratetcOc) afthe rate ofl glilll00 gal of ~ray solution (1% v/v). .. , ·1 In com,appiy aiieast7 days prepla~t or'at least 3 daysajterplantmgbut before i cOm eniernence!

UPfMETRIBUZlN 4F 3 to 8 fl ovA'" Must be applied prior to crop emergeJlce. Use 24 to 32 fluid ounces of , + + GtamoxoneExiraforweeds less than 4 inches in height a!,ld 32 to 48 fluid ounces , GramoxolJe Extra 24 to 48 fl ovA when, weeds .. life 4 to 6 inches in hc;lghL Apply in 20 to 6il gallons of water per

acre. Include,either nonionic surfactant at 1. quart per 100 gallOm.(0.25% v/v) or cropoilwncentrate at 1 gallon per 100 ~lons (1 % v/v} of !>pray solution.

UPI METRIBUZIN 4F 3 to 8fl oVA* For this tank miX follow the Directions and Remarks Sections above for UPI + +. MErRIBUZIN 4F+ 2,4-DLVE'and UPIMETRIBUZIN 4F+ GramoxoneExtra;

Gr1unoxone Extra 24 to 48 fi oVA paying special attention to crop phinting.restrictionswith2,4-D L VE. Include + + either noniqnic surfactant or crop oil concentratein this tank mix ..

l2,4-DLVE 1!4 to llb,aiJA .,

•• )JPI ry1ETRIBUZIN 4F 3't08 fl ovA Must b(!appliedprior.locrop emergence. Use the higher rates as weeds, approach

i '. + + the maxiit,uln weed heights liSted {nthe "Weeds Controlled'; section belOw.' ' .• " .-

I Roundupl 12 to 24f1 oVA Apply in'lOto '20 gallollsof water per acre. With Roundup and Touchdown; . ~oundup Ultra include nonionic suifactant.at 2 quarts pet 100 gallons (0.5% vfv) ,and ammonium.

I Or or sulfate (spray grade) at 17 pounds per 100 gallons of spray. solution. With iToilchdown '. 8 to i6 flovA ,Roundup. mtra, iiidudeammonium sillfate (spray grade) at 17 poUhdS per .1 00 :

gallons of spray solution. Anyglyphosate formulation registered and labeledJor, use infield com or so-'ybeans ma.,J' be tatJk miXed 'With UPlMETRIBUZIN 4F.

UPl METRIBUZIN 4F 3 to 8 fl oVA* For this' tank. miX follow the Directions and Remarks Sections above for UPI i + + METRIBUZIN 4F+2,4-D LVE and UPIMETRIBUZlN 4F+ Roundup!Roundqp I Roundup! 12 to 24 fl oVA mtraITouchdown,paying special attention to planting restrictions with 2,4-D

Roundup Ultra LVE.Use theadjuv~t recoffilDendatio\1S under the uplME~UZl1'l4f't~, .. , Or or Roundup/R.oundup mtraITouchdown tank mix. Do not use crop oil concentrate: iI'ollchd,owi1 8 to i6f1 ovA .... ..' • • • >

~ . + .+ , 114 to lib aiJA 12;4-DLVE

i~ If applied to field com in Illinois, Indiana, Kentucky, l\1jchigan, Minhesotll"Ohio and Wisconsin, refer to Table "UPI METRIBUZIN 4F Bumdown R.'ltes - Field Com ad Soybeans;' for correct UPI METRIBUZIN4F tate based on ~icatioii tlmirig; ,

UPI METRIBUZIN 4F PLUS TANK MIX pARTNER BURNDOWN RATES - SOYBEANS ONLY ,PRODUCT RATE DIRECTIONS AND,REMARKS

• UPI NfETRIBUZIN 4F . 3 io 8 fl ovA Apply preplant on or before soybean emergence . Includenonionic surfactant at 2 + + quarts per 1 00. gallons (0.5% v/v) of spray solution.

i 2,4-DB 118 to 7/32 lbaiJ A UPIMETRIBUZIN 4F 3 to 8 novA For use only in Delaw!lfe, Illinois, Indiana, Iowa, Kansas, Kentuc!<y,Maiyland; ... , I" . ".

Michigan; Minnesota, Missouri, Nebraska, North Dakota, Ohio, Peimsylvanii' •. : + +

I Fuslon 4toSfloVt\. S.outh D$OI&, Virginia, West Virginia; andWis(;9nstn .. F()r thist@k;)lii,,{{(}lIow::

i + .+ the planting restrictions undertheDirections and Remarks· Sectiori'ilbov6forUPI . !2,4-DLVE 1/4 tollb,aiJA

' . METRIBUZIN 4F + 2,4~D L VB. Fusion rates of 4,6 arid 8 tl .. oz:\Vii(co~troL -; cerUrln grasses up to 2,4, and 6 inches1n height respectively. Iil~lu~eeither.crop'

0; oil concentiate at 1 gallon per'fOOgallon(l.O%i,r/V) or nollionic silffacta,nt atqo 2,qucirts, per 100 gallons (0:25 to 0.5% v/v) of spray solution. Refer to the Fusion

, label for additional information. ' .. '0:;;;, -.upI ¥ETRIBUZIN 4F ." 3. to 8 f1 oVA For thisiank,mix follow the planting restrictioDs\iinder the Directions and

+ + RematksSection.abQve forUPI METRIBUZIN4F + 2,4-D LVE. The 8 and 12 i P()ast Plus 8 to 12 fl OVA fl oz. rate ofPoaSt Plus will control c~ain grasses up to 2 a,nc:\ Jinches in height,

+ + respectively. Ihclude either crop oil concentrate at the rate of1 gallon per 100 2,4-DLVE 1/4 to I ib aiJA gallons ofspraysolqtiori (1%.v/v) or bash HC:,it 1 pint per acre. R~f~.r: to the

. Poast Plus labeLfor additiOlial information. '. '. , ,

UPIMETRIBUZIN 4F 3 t080zlA For this ta,pkriiix follow Jheplanting restriction under the Directions ana .. I + . + RemarkS S~tion,abOvdor(]Pi METRIBUzrN 4F +2,4-D'LVE: TheYand 4.

1 ,. Select 3toAfloVA fluidQ;jnce.~cU:efofS~lect will control certain grassesup'to 3imd4 inches:ih • l + + .height" respecti~elY. Iflc1ilde crop oil concentrate at iherate of L quari:Pet acre 2,4-DLVE 1/4 to lIb aiJA .and 28% PAN (urea animonium nitrate) ata rate of 1 to.2 quarts ,per.acre:<Refer : to the SeltlCt labef fOr!uiditional information.

UPI Metribuzin 4F Master Label Page 29 of 56

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SpecfulPtecautions.DonOl apply these treatments af!er crop emergence. Observe all precautions and limitations onthe labelipg;of allproducts used in timk mixtures. Refer to the General Information section orLhis label for additional '

, information(precaUlions. and limitations. '"

Field:Com: ' • Do not apply on coarse textured sOils with less than 1.5% organic matter. • D() not apply more than 6 oz. ofUPI METRIBUZIN 4F per acre on soils with less than 2% organic matter. • Do not apply on soils having pH 7.0 or greater. , • Do nol apply more than 8 ounces UPI METRlBUZlN 4F (0.25 pound active ingredient) per acre, per growing season, • Corn,seed should be planted a minimum of 1-112 inches deep. • UPI METRIB UZIN 4F may only be used in hybrid seed com production fields ifboth inbred, parents are knoWiltobe

tolerant to UPI METRlBUZIN 4F. ' I "

Soybeans: , ' " " • fi,.pply,'only 2,4-D low volatile ester formulations which are registered andrecomme'nded for preplant or burndown

rise in soybeans. • IDonol apply tank mixtures containing 2A-D L VE if wind is blowing toward desired susceptible plants (i.e. c(~ttoil.

t~bacco, tomato, etc.) or when wind speeds exceed 6 miles per hour. '

}'~ng restrictions: Corn treated with UPI METRlBUZIN 4F may be harvested for silage or grain 60 days after treanhent. Soybean vines or hay treated wiLh UPI METRlBUZIN 4F may be grazed or fed to livestock 40 days after appli~ation. Do not feed hay, forage, fodder or graze 2,4~D, Select. or Fusion treated vegetation. Follow the most restriftive preharvest interval of all products used in a tank mixture. !

W eedsControllf~d: UPI METRlBUZIN4F in Umk mixtures wiLh the above herbicides. will provide bilrildowncoIitrol of the weeds listed below

WEEDS CONTROLJ.ED.BY BURNDOWN.R-'rns Ol"UPt.M~:TRlBUZJN 4FPLUS WEED~ CONTROLLED 2.<~;D Poast SeleCt + Fusion + Roundupl Roundup! Gr4moxnne Gnlm9,x,(lOC' 2A·DB

'! LVE Plus + 2,4-DLVE 2,4·PLVE ROuDduj! Roundup Ultra! Extra Extra,+ 2,4·D Ultra! Touchdown + 2,4· 2;4-DLVE

j LVB ToUchdown DLVE ANNUAL GRA~l?S MAXIMUM BURNDOWN HEIGHT (lNt'HF,s) Barley ,. · 8 4106 Bamvard~rnss 2103 3104 6 4106 CtablUliss spp: 2103 · 6 4106 Foxtail: spp. 2[03 3104 2106 H 4t06 Johllsonj!l1\Ss, Needling 2103 · H 4106 Panicum. fall Does 2to3 3 2t06 6 4106 Does Sandbw-. field No! . · . 8 4106, not Sbanercane Control 2103 . 8 4106 conti'Ol Wheat,ivolunteer, . :fbese . · , 6' 4.106 .these

. Witchgi'ass SPecies '2103' ~' 6 4t06 'sPecies BROADLEAVF,s MAXIMUM BURNDOWN.HEIGHT (JNCHF~")

Buffalobilr ,. '6 6 ,4106 4.:06 · 'Chickweed. common 6 6 8 4to6 4106 2. Cocklebur. common 6 6 8 4io6 4106, 6 Dandelion, common 6dia' 2 din 6 dial , 4diao 6diil" 2dili

, Henbit: 4 4 4 4106 4106 · Horsevieedlmarestail 6'" 4" 6 3 6' 2' Jim~oDweed 6 6 6 4tn6 4(06 2 Kochia, 4'" 4 4 4 4 Ladvslhumb 6 6 8' 4106 4to6 3 Lambsquarters, common 6 6 8 4106 4106 2, Lellllce: prickly 6 4 6 4106 4106 2 MalloW. Venice 6 6 6 4106

" ,4106 ·

MominllAlorv. spTi,(''':':t,--;~;,: ~ ... 6 2 4 2 :.<;<" ; l--:; ,'U 4 4 MU:~iard. spp,

.:" .,,~~ -, , 6 6 8 4106 ' c .. ).}::\ ',""'"' '-4 10,6 " 2

peJin'ycress.,field 6 6 ' 6 ' 4106 4(06: 2' . Pigweed, spp.lannual) 6 6 8 4ro6 4,106 :3 Ra2weed. common 6 6" 8 4(06, 4t06, '2' Ragweed. giant 6"" 4' 6 4 6 ··2 Shepherdspu~e 6 6 6 4106 4106 .' Sida. prickly 6 4 4 4 4 I Smanweed, Petinsy]vania n (\ 8 4100 4106 3 Suol1ower. common 6 6 6 4106 4106 4 Thistle.' Russian 4'" 2104'" Ii 4 4t06 3" Velvelleaf 6 6 R 4too 4 III 6 3 Watefheinp. spp. 6 6 8 4-106 4!06 3 • Use 2;4·D LVE at 0.5 pound active ingredient per acre, b Use II minimum RounduplRoundup Ultrn rote of 16 fI oziA and a minimumTouchdowrirate of 10.6 It o1lA. 'llNC UPI METRIBUZIN 4F at 4 oziA (nl' optimum control. • Suppression only, , " Dbes'not control triaiine resistant biotype.,

RESIDUALWE,ED CONTROL

... i . _ ,

UPIl'4etribuZin 4F Ma.<'1er Label Page306f56

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UPIMETRIBUZIN 4Fburndown programs can.be used as part of a full season weed control program in both field corn and soybeans when. 1) applied as.a tankmixture withresidllaI herbicides. or 2) followed with a postemergence weed control program. which is registered for use on thai.crop,

For rksidual control. UPI METRIB UZIN 4F burndoWnprograms ~y include tank mixes with the following herbicides or cOlnbination of herbicides: ..'

Fieid CorD. Alachlo]" Dual AtraziiJe D~al II Banve! Extrazine II Bicep Frontier Bicep IT Guardsman Bicep Lite Hartless Bladex Harness Xtra. Broadstrike + Dual Lariat Broadstrike Plus Linex Bullet Linuron Clarity Lorox 'Cycle Marksman atlse,only Pursuit resistantJiolerani corn hybrids.

, Soybeans Alacillot Frontier Broadstrike + Dnl1l Ge~ Canopy Linuron Conuhand Newl..orox Plus . Detail Pentagon Dual: Preview Dual II Prowl.

Pentagon PrOWl Pursuit" PursuitPlus' .' Ramrod Ramrod! Atrazine Simazine Surpass Surpass 100 Topnotch

Pursuit J>ursuit Plus Scepter

. UPI Metribuzin 4F" Squadron Turbo

blJPI,ME~BU;lIN 4F used (alone and in tarik mixes) on soybeatlsat higher labeled rates thim ~ose)isted for bumdown weed control will also provide residual control o( those weeds listedin the ''Weeds Controlled byUPl ME~UZIN.AF lihdUPI·METRmUZ(N4FTimk IlJij{ Coiitbinlitions" sCctionof the UPI METRmuiIN 4F label. Refet to me individual product hibels for additional information, precautiqns, .and lirniiations.

j

i SOYBEANS:SOUTIij!::RNANDSOUTHEASTERNSTATES ONLY I'. Postemergence Directed Spr~yApplicatioDs . '.'

UPl~TRIBUZIN 4F canbe applied in postemergen~e directed sprays to soybeails for control of certain weeds which escape preplant or pre-emergence herbicide applications and for control of additional flushes of weeds that may occur after soybeans have emerged. Postemergence directed sprays of UPI METRIBUZIN 4F can be applied to soybeans in addition to a pre-emergence or pre-plant application of UPI METRIBUZIN 4F herbicide according to label directions.

Wee~s Controlled: UPI METRIBUZIN 4F, applied postemergence to soybeans as a directed spray according to .. directions on this label, will control the following at rates shown (broadcast basis) when grasses~nd cOJIllIl{)nragweed are less than linch tall and other broa:d1eaves are less than 3 inches tall: .. " , ,.' \ ,-, .. ," . . -

I WEEDS ,C()NTROLJ;ED i ~ 1/2PUAcre 112 to 1Pt/Acre 1Pt/Acre .

<,;

. Florida beggilrweed (Desmodium tO~O$u1Jl) Sespariill ($esba!lia spp.) Ragweed. cpr.nirlon. (Ambrosia .. ;,%,{;(~:':, Pjgw~eds"(Amaranthus spp.)'·'~""":":::;·<";' .Prickly Sidaffeaweed (Sida spo!losaj artemisiifolia) Carp~tweed (Mollugo verticillata) Cocklebur (Xanthiu71Ipensy[vanicwn) Dayfiowet (CommeJina spp.) Mexicanweed (Capero!lia c;asraniifolia) Purslane (Portulaca oliiracea) Sicklepod (Ca~'sia obtusifolia) Velvetleaf (Abutilon thebphtastl) Crabgcass(Digitaria spp,), .. Atth~ raieoTl/2;pt!aeierri6rningglory' species. (Ipilmoea:ipp.) hOrSen~tt~e,(Sqlanum spp,) Flonda ptisley, (R,icltardia scal/ra) , . spotted spurge (El,tpIUJrbiamacuiata) and wild poinsettia (Euphprbiahei'erophylla) are suppressed when UPI METRm UZIN ~Fis . appliJd before these weeds are 3 inches tall. The 1 ptlacre tate will' supp~essbroaci:Ieafslgnalgrass (Brachiaria platYphyUdj ,up 1Q' ..

1 incn tall. .

1 UPI METRIBUZIN 4F POSTEMERGENCE DIRECTED SPRAY

UPI Metribuzin 4F Master Label Page 31 of S6

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RECOMMENDED,APPLICATIONS • Crop UPl ME1'RIBUZlN4F PtlAcre " ; REMARKS'

Apply proper dosage using 10 to 40 gallons of water per acre as 'a Soybeans directed spray ina 6 to 8 inch band of each side of the row after (Alabama, soybeans are. siriches tali and· before broadleafweeds are 3iilches Arkarlsas,' Florida, 112 to1 tall and before grasses and common ragweed are 1 inch tall. For best Georgia, Kentucky, (Broadcasl aasis) results the spraymusl cover weed foliage with minimum or ho Louisiana, contact with soybean foliage. Add a nonionic, surfactant such as Mississippi, Ortho X-77 to the' spray mixture to obtain better wetting of weed leaf Missouri, North ~urfaces. To detennine the correct dosage of WI METRIB UZlN 4F Carolina, Oklahoma, for a band application see "Banded Application" under.the ''General South Carolina, Tennessee and

Information" ~ection in the front (If this lahel.

TexaS) If necessary, a se.i::ohd posteiIleigerii::e~ireCted.sptay ajJplicatioilcan. , be made after 7 day~. .. .. .

Do not feed orgraze.green soybean vines. ,Po not harvest soybeans or use dry soybean vilies or feed offotage within 70 days oflast application.

Spechll PrecautionS (Directed PoStemergence): Do not apply direcdyto soybeans or serious crop i11iury will occur. Donot allow; spray to contact more than the lower 114 to 1/3 of soybean plants. Soybean leaves contacted by the spray will be killed . rio not apply UPI METRlBUZIN 4F posteniergence to sensitive soybean varieties. See "Special Precautions" in the frOlitofthis labeL. To avoid injury to .other crops or desirable plants fn>m spray drift. sprayer pressure must not exceed 30 psi and the sprayermu.st be fitted:with nozzles no smaller than 8002-T-Jet (or~uivalent). Do not apply under weather conditions whiCh,fa\'ordrift.

i POTATOES

UPIMETRIBUZIN'4F herbicide is recommended for use inground,' aircraft or specified chemigationequipment as a pre­emerigenceandlor post-emergence application. to potatoes. Early maturing. smooth skinned white and all.red skinned . varie,tiesmay be injured with post-ernergence applications. The varieties Atlantic, Bellchip, Centennial,ChipbeIle,and Shepoqyare sensitive to UP1 METRlBUZIN 4F. Avoid post2emergence applications on these. varieties. Pre-emergence applications on these varieties may cause crop injury under adverse weather conditions,on coarse soils. under high soil pH, with higher rates per acre and with mechanical incorporation.

I

Ground Application: upI METRIBUZI.N4Fis recomm~nded for use with grouildspray eqwpIhentapplied as a pre­emergence andlor post-etnergence application forcontrol·Of the listed grass and broadleafweeds in potatoes. Apply as a unifonn broadcast spray at 20 or more gallons per acre,

,j . '.

Aerial Appliciition: UPIMETRIBUZIN 4Fniay be appliedin aerial spray equipment as a pre-emergenceandlor POSl-emergence applicationat.5 or more gallons pcracre. . ' .

CbetPigation: UPI MEnUsUZIN 4F may be applied pre-emergence andlor earlypost-emergence topoiatoes,llsip.g cent~r pivot, solid set and lateral roll systems. Apply specified. dosage in 114 to 3/4inches of water per acre (114 to 112 . inches on sandy soil) as a continuous injection in self-propelled systems or apply in the last 15. to 30 l11inutesof the setin other: systems. Be sure all the UPI METRIBUZTN 4F has been. flushed from the .lines before shutting down the system.

. WEEDS CONTROLLED. UPI METRIBUzIN 4F applied to potatoes according [0 ~ir~~tiolls, ~Ii proyide economic control of the following weeds. For optimum contro)~ applications should be made before weei:l~'are>lirich tall. (See NOTE) BroadJeaves Grasses Carpetweed. common Mustard, tansyi . .Ragweed, common .- BarnyardgrassJ Johnsongra$s, seedling I '. C:ock(ebur, commonl

•2 Mustard, tlllnble 1 Shephetdsplifse 1 CrabgrasS, large ,. Panicum, fali l

. ....

Jimsdnweed1 Mustard. wild l Sicklepod·. . Crabgrass, smooth' Signal grass, broadleafJ•

KOchl~ Pcnnycress, field'.2 Smartw~d. Pennsylvania!'! . Foxtail, giant' .

Lam~sqtJarters, .common 1.2 Pigweed, redroot/·J . Sunflower,common3 Foxtail, greenl

Mustard, indian' . Pigweed, smooth1.2 Thistle; Russian2 Foxtail....yeilow' I W~s controlled with pre-emergence applications. 2 Weeds controlled with post-emergence applications. 3 Weeds requiring two applications for control.

UPIMetribuzin 4FMasterLabei ", .". . ." Page 3'2 o'r56

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, HARD TO CONTROL WEEDS

Although UP! METRIBUZIN 4F Illliynot pf9yide cogunerciaily accej:itable~ontroi in every instah<;~. it will suppt:ess gtoWthof the followin .. weeds and reduce their competition with 'Potaloplants.' ' " Broadleaves Grasses ,Kochia \ Purslane, Common Batnyardgtass I Nutsedge, yellow Nightshade. hairy Sunflower, common NOTE: Where ttiazine"tesistant weeds are present; UP! METRlBUZIN4Falorte may not provideadecjliate,comroL

1

RECOMMENDED BROADCAST APPLICATIONS CROP UPlMETRmUZIN' REMARKS

PotatO,es

Potatoes (except earl y manufacturing smooth, skinned, red skinne<t,and other'spedfied varieties.)

!

4F (PtIAcre)

112 to 1

PRE-EMERGENCE: Apply specified dosage as a broadcast spray. Do not mechanically incorporate into soil. Use the 112 to Ipinu'aere rate,for control of wild mustard' (Bras,~ica spp.) only. On sand soils or sensitive varieties. do not exceed I pint/acre. POST·EMERGENCE: Apply specified dosage as a broadcast spray over the'tops of potato plants,'" Use rates of 112 to 1 pint/acre forcontral of reqrOot pigw~ and common lambsquartets only. Apply tl).e 1 pint/acre rate for control of other weeds listed on thisJabel. '

SPLIT APPLICATIONS: Thi.s prOduct may be applioo on~e pre­eJriergeilce iirid,ollcejJOst-emergence,as dirC9ted above. '" Do not exceed 2 pint lotaLperacreperseason.

ID~O, OREGON, AND WASHlNGTONONLY: TWoj:ioSt~emergence applications canbe,made as broadcast sprays over the tops,of poiato plants if uP! ME1'RIBUZIN 4F is not applied pre-emergence. Use 112 to 1 pint/acre for control of redroot pigweed and lambsquarters only. On,coarse(sandy) soils with low organic matter do not exceed 3/4 pint/acre pet application.

, On-medium and heavy soils only. use 1 pint/acre per application for control 'of other weeds listed, on this label and, for suppression of hairy nightshade. Make the first application early in the s~on while weeds, are still smalL

: Allow at least 14aays before the second application. Do not apply after Julie 30 if treated land is to bepiantedto crops oilier than potatoe.~.

>10 SP'ECIALPRECA UTIONS (Po'tatoes): , ', , . Do npt li's~ {]PI METR.I:8 tJZIN <iF on pOUltQ¢sm I<.ern County, California. Do noUipply niore trulll atoml of2 pints UPI METRIBUZ!N4F per acre ina single crop season regardless of the method of application. Do not inake post-emergence applications prior to rainfall or irrigation on recently cuitivated potatk>es, or wIthin 3 days after periods of cool, wet cloudy weather or injury may occur. - ' Post-'emergence applications may cause some chlorosis or minor necrosis. These symptoms may be more severe if seed~piece decay is occurring or if growing conditions favor crop stress. Post~mergence applications;may be made only ouusset or white skinned varieties that are not early maturing. POtato varieties may vary in their response to herbicide application. When usingUPI ME1RIBUZIN 4F for the fIrst time 011 a particular variety, always determine crop tolerance before using on,a field scale. Donbtapply UPlMETRIBUZIN 4F within 60 days of harvest.

, Do notuse aif'blastsprayers. Do not apply to,sweelpotatoes or yams.-

'Donp! plant sensitive crops such' as onions, lettuce, cole crops and .cucurbits dUring the next growing season folloWing .UPI~TRIB.UZIN 4P.application. ..~,~t ... ;~·;:'t~j~;~;", .. . . Certain cereal varieties are sensiti ve to UPI METRIBUZIN 4F (see cereal flecti()n of ,this label forseilsitive varieties)

. and should not be planted during the next growing. seasollunless the following cultural practices occur: 1. Potato vines leftin rows as a result of harvest must be uniformly distributed over the soil surface prior to : plowing and, 2. Plow with a moldboard plow to a depth sufficient to mix the upper 8 inches of soil.

TANK MIXES: UP1 METRIBUZIN 4F may be tank mixed with the following herbicides: DuallDual n, Eptam, Prowl 3.3 EC and Matrix. lnaddition. three-way tank mix comi:>inations may be used for UPI METRIBUZIN 4F plus DuallDual II, , Eptamor Prowl 3.3 EC plus Matrixwhenappliedpre"emergence~ Refer to'each product's labeLfor'precautionary state~ents,restiiCtions,appliCation informati()n and,weedscontrolled;

UP) Meulbuzin 4F Ma'iterLabei Page 33 of 56

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=". . ,,' .,/ . DuaJ!Dual n: ,UPI METRIBUZIN 4F may be applied ina tank mixco.mbillat:lon with Dual/Du31 n as a pre-emergence " broadcaStapplication~ ApplyUFI METRJ.BUZIN 4F at 3/4.to 2 pinis:per·acreand DUalJDuaUIat 1.5 to 3 pints per acre > >

.' , 'j,\ . according to the respective labels'for use of eachproouct alone ol1!,pmatoes. '

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Ep~fu: UPI METRIBUZIN .4F may be tank mixed with Eptain at rates and uses permitted on each product's labeL

Prowl 3.3 EC:t.f{JIMETRIBUZIN 4Fmay be applied in tank mix combination with Prowl asa pre-emergence.or early post-,emergence broadcast application. As a pre..emergencemix, app~y UPI METRIBUZIN 4F al 1 to 2 piIns per acre and Prowl at 1.2 103.6 pints per acre. As an early post-emergence Spray, apply UPI METRIBUZIN 4F at 112 to 1 pint per acre and Prowl at).2 to 3.6 pints per acre before the crop is in me 6-inch growth stage.

Matrix J except the follQwing colln.ties in ColoraQ(): Al~oSIl, Conejos, .Costilla, Rio Gra'!lde Illld Sagtlacl}e )::u:PI. ME'tRIBUZIN 4Finay be applied intanKmix combination with Matrlx as a.pre;.emergenceandl()t'earlypost-emergence appli'cation for improved control on 'weeds su.chas Russian thistle, kochia and' common lambsquarters. As a pre­emergence 1I,llx, apply UPJ METRIBUZIN 4F at 1~ to 1.125 pints per,acte arldMatriXat 1 to i-iii oz .. prOduct pet acre. As an early post-emergence spray, applyUPI METRIBUZlN4F at 1/2 to 1 'pint per acre and Mattix at 1 to 1-1/2:oz. product per acre; Use l:! non-ionic surfactant at a rate of 0.125% vlv (1 ptlt 00 gallons of water)~ Apply before the crop exceeds '14 inches in height. Post-emergence applications of Matrix treatments,should be made prior to June 30 .

ALF ALF A AND SAINFOIN UPI METRmUZIN 4Fherbicide is recommended for use in ·alfalfa and sainfom in the following areas: • Alfalfa and sainfoin (includi!)g mixed stands with grasses) (all areas except California). • Alfalfa and sainfoin (including mixed stands with grasses) (California only). ..illiaifa ~Tank mix OOinbination\vith Gramoxone (Colorado,ldaho, Montana, Nevada, Oregon, Utah, Washihgtoll,

Wyon:ling. and tbe followingCaiiforrlia courtties:DelNorte,Lassen, Modoc, Nevada, Plumas, Sh(iSta. Sien:a, and Siskiyo~). . _

• . Alfalfa "':Postdormant applicationofUPlMETRmUZIN 4Fimpregnated on dryfertilizer only (Connecticut, lllinois, . ~diana,Iowa, Kansas. Kentucky, Michigan, Minnesota, Nebraska, New Mexico, ;New York,Ohio, Oklahoma, fennsyIvania, Soutl1 Dakota, Tennessee, Texas,anq Wisconsin). ! ,

UPI METRIBUZIN 4F is recommended for Use in aeriai or ground spray equipment as a broadcast surface application to established crops of alfalfa and sainfoiil for the control of certain grass and broadleaf weeds.

APPLICA TION:Refer to "GeneralInformation" in the front of thislabel for detailed information on the application of UPI METRIBUZIN 4F. For information on applying UPI METRlBUZIN 4F in fluid or on dry fertilizer refer JO the "Application ofUPI METRIBUZIN 4FinAuid FeTti~zers'! or "ConUnercial Imptegnation .. and Application of uPi METRIBUZIN 4F on Dry Bulk Fertilizer" under the, "GeneralJnformation;; ~ectiQri of this l!ibel. . , . . ~~,' ,

SPECIAL PRECAUTIONS: Use UPI METRmUZlNAFonly on'established alfalfa and srunfoin. Do'notapply UPI· METRIBUZIN 4Fafter growth begins in the springorbefme'gI'owth ceases in the fall, except as specified onthishibel.

Do not graze' or hlllVest within 28 days after application.

For best weed control, apply UPI METRIBUZIN 4F when weeds are less than 2 inches tall or before weed foliage is 2 inches in diameter. Reduced weed control may occur when extended dry conditions follow application of UPI METcRIB UZIN 4F.

Crop injury may occur when: • Crop is under stress condiiionssuch as diseases, insect infestations, pOOrly drained soils, dtpushtor winter injury at

.t:i.mC ohpplicat1on; • Grop is treated within 12 monthsfafierseeding.: . • Thereis excessive irrigation or rainfalliminediately after application. Do not apply more than ~inchof water illtbe

fIrstirrigation after UPI METRlBUZIN 4F is applied.

ALFALFA and S~OIN (All Areas Except California) RECOMMENDED BROADCAST APPLICATIONS

CROP UPI METRffiUZIN4F REMARKS

Alfalfa and Sainfoin (Except California)

liP] M,ehibuzin 4FM,aster ,Label

(PtiAcre 1/2 to 2 :Select the proper dosage accoidingto weeds known t() be and present in field

to be treated. On lOamY sand soils in ,Oregon am~ Washington, do. not apply motetlhm 1 lof.UPlMETRIBUZiN ,4F.eracre. . . '.

" .. ... _ ... __ ,:._. __ :c": .... ,·.:::!:··;"~,_~._,, .. -".;_,-'-'-''-'--~_'--.:CJ

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FOR USE ON J.\1IXED ST~NDS OF, ALF~FA AND GRAsSES Rates' of 1 to 1 ~i/2pt of UPI METRIBUZIN 4F per liCr~Will prqvide partial reductionofforage grass stands .. Thesexates may 1?e used to reduce forage' grass stands to prevent crowding out of alfalfa. Highet rates· will severely reduce forage grass ,stands.

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UPI METRIB UZIN 4F shOuld hot be used 01). sand soils. Iil areas West of the Rocky Mountains, avoid. lisingUPI METIuBUZIN 4F on 'soils wIth calcareous surface area; blghlevels oflime orsodilim,orapHgreateqhah 8.2.

, i WEEDS CONTROLLED -.ALFALFAandSAlNFOIN (Except California)'

1/2 to.3/4Pt UPI 314 to 1 PtUPI '2 Pi UPI METRIBUZIN METRIBUZIN METRIBUZIN 1 to 2 Pt UPIMETRIBUZlN 4F/Acre 4F/Acre

4F/Acre 4F/Acre .. Chickw¥ed; Common Cheat (Bromus Broadleaves Mustanl. Tansy Grasses Broadleaves (Sreilaria media) secalinus) Fleabane. Rough (Descurainia Foxtail, Green Chickweed. MOl!sear

Deadnenle. Purple (Erigeron strigosus) pinnaia) (SetaritJ viridis) (Cerasiium vulgatum) (Lamium purpureum) Fixweed (Descurainia Pepperweed Linle Barley Daildelion(Taraxacum Downy broine (Rromus sophia) (Lepidiuln (H(irtieum pusillum) officinale) teclllrum) Henbit (Lamium virginii:um) Smooth Brome Ragweed. Common Japanese brorne amplexicau/c)· . Pigweed. Redroot (Bromus illerinis) (Ambrosia.anemisiifolia) (Bromus japonicus) Kochia (Kochia (Amarcinthus Wild Oat~ (Avena Grasses' .

.. Pennycress (77ziasp'i 'scqparia) ' . relrof/e,tus)' Jama) ,

Barnyardgr~s'(Echinochloa arverue) LanibSquarters. Prickly Lenuce . crus-galli);' .

'Rescuegrass (Broml/of (:'ommori "i: .. (Lacfuca sl!rri()la)' BluegraSs (Pqa annuli) cqiharticus) (Chenqpo4(u/iz i!1bJ,lm)' White Cockle, Foxtajl13ar1ey ~Hordeum Shepherdspurse MareStiIlr(fiorsewtied) . (MelliTidrium jilbarum) . (Capseliabursa (HfppuriSVjilgaris) . album) pas/oris) Meadow Salsify WiidBuckwheat

(Tragopogon pra/ensis) (Polygonum. , Mustard •. BJue . convolvuillS)

(Ch07;ispora telletta) Yello\\, Rocket

j Mustard. Jim Hill (Barbarea (tumble) (Sisy!'lhrium: VUlgaris)

aitis.fiinum)

Weeds Partially Controlled: At the fate of2 pt/acre UPl METRIBUZIN4F may be used to reduce the competition from curly dock (Rumex crispu.i). Atl lO 2 pt/acre, UPlMETRIBUZIN 4F Illli~beusedtb h:duce the competition of Gennan Moss or kilawel(Scleanthus.annus). .

ALFALFA AND SAINFOIN (California Only) . . ·.(Including MiXed. Stands with Grasses) , .

UPI METRIBUZIN4F is recommendedJor use iriaerial or ground spray equipment as a broadcast surface application to dOIlIllmtestablished crops of alfalfa and sainfoin. '

. ;, /

APPLICA nON: UPI METRIBUZIN 4F.is reconune'nded for usein aerial or ground spray equipment as a broadcast surface application to dormant established crops of alfalfa and sainfoin for control of certain grass and broadleaf weeds. Do not apply UPI METRIBUZIN4F after growth begins in the spring or before growth ceases in the fall. Do not apply to either alfalfa or sainfoin during the first growing season after seeding. .

For iIlfofJl)alion on applyingUPI METI~JBUZIN4F intiuid,ferti~lzersolutio~s to alflilia,tefer, tQ the;apptopriat~~ti~tiQl'\of . this label. . .> • ," , • •

" '," - , ,.., "<h':"

F()r ultormatiOiHlri cOIllffiercial impregnation, and applicatioIi of UPI METRmUzrN 4F Q1l,dty1:ltillc fet:trii:i¢f,~efettbthe . appr6priate secti()!i;Qfthislaoel.' . .. ; .' ., '. ., ; .. ':;+iijJii.~t1 . '. .

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.UPI Metribuzin 4F Ma.~ter Label Page 35 of.56

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, WEEDS CONTROLLED 3/4 to',l, Pt UP}>, " ' ;~ ~ ... 2 P.trUPI +.;:,

METRffiUZIN 4F/Acre 1 (0,2 Pt (]pI'METRpjUZ!N 4F/Acre METRmUZIN i'

4F/Acre , Cl1~lltgr!l,Ss (Q9wny bCQme) aroacllea:V~ . Mustard, Tiiilsy (Descurilihiapinliatil) Broadleaves .', (Broniussecallnu,i) . Chickweed, Common Pepperweed. Virginia (upidium 'Paildelion (Tafaxacum

i (Stellar-fa media) virginicuin) officina/e) ; Fixweed (Descllrainia Shepherdspurse (Capsella bursa.pasTOris)

Sophia) White Cockle. (Melandrium album) Grasses Henbit (Lamium Wild 'Buckwheat (Polygonum convolvulus) Barnyardgrass

. ampiexicaule) Yellow Rocket (Barbarea vulgariS) (EchiTUJchloa crus· Kochia (Kochia scoparia) gaili) Meadow'Salsify Grasses Bluegrass (Poaannua) (Tragopogqn prarensis) ~inQOth J3rome eStella ria media) F();lttail Bar.ley

" Mustard. Blue (Chlori.rpora Wild Oats (Avenafarua) (Hordeunfjubatum) I teni!lia) . , , I' RECOMMENDED BROADCAST APPLICATIONS' , "

CROP '. UPI METRmUZIN 4F . '{ .~. REMARKS " 't"':>o.~-< v

1 uUAcre Alfalfa and Sele<:tthe proper dosage accoidillg to weeps knO\Yl1 to be present in the field:to Sainfdi~ be treated. Apply specified dosage in 20 to 40 gallonso[water per acre with (Califprnia Only) 3/4. t02 grouridspray equipment or 3 to 10 gallons of water per acre with aerial Spray

equipment fitted with nozzles suitable for broadcast applications ofherbicides. i Treat oniy dbrmiii'lt established crops Of alfalfa and sainfoin. Injury may occur to ,

alfalfa if UPI METRIBUZIN 4F is applied earlier than 12 months after seeding;

!. Do:no~ appiy after Spring growth begins or before growth ceases in the Fall. Do noi graze or harvest within 28 days after application. .

" At th~2 pt/acJ'!'l rate, UPlMETRIBUZIN4F maY be used fot sUpp:ression o!ctirly dock ' , . . '.

f ",'

FOR!USE ON MIXED STANDS OF ALFALFA AND GRASSES: Rates of 1 to 1·1/2 prof UPIMETRIBUZIN 4F per: acre will provide partial reduction of forage grass stands. ' These rateS may be used to reduce forage grass standsio prevent crow4ing out of alfalfa. Higher rates will severely reduce forage grass stands.

t" 0"

I , Do n9tapplywith aerjal equipment when wind speedisgrea,ter than 10 mph. Do Dot apply when weather cOil~itions favor spray; drift and/or when sensitive cool season crops; such as cole crops, onions, peas. or strawberries; are present in adjacent fields. Applications shouid not be made when weather conditions favor spray drift, especiaUyin areas where

• whea~ is growing on coarse textured soils in adjacent fields. orinjuiy may occur.

! ALFALFA: uplMETRffiUZJN 4Fplus Gran;l~xoneEx;traTankJ\fix '.. :, , ColotMo, I«laho; MOfitana;N.~vad~ Oregon, U)ilIli washington, WYQIDing, and the foilow'iitgCalifomia:counties:

. De(N9(te, Lass~n" Modoc, Nevada, Plumas, Shasta;,Sierra, ,and Siskiyou.: " . \ . . '.' . . . ! . .

Application: UPI MEJ'RIBVZJN 1F plus Gmmoxone Extra herbicide 'tank mix application isrecori:lme~ded for wie,' durinhthe (lormant season, in aerial or ground spray equipment as a broa~ast surface appiication to established aIfalfafor thecdntrol of certain,grass and broadleaf weeds. Do not apply UPlMETRIBUZIN:4F/Gramoxone Extra tank mix to grow\h that is more than 2.inches tall. Appiy once per season. Do not apply following cuttings during growing season, Use a minimum Of 10 gallons of waterpefacre with aerial spray equipment.arid it minimum of 20 gallons of water per acre-;dj(\'f'~i' With ground spray equipment. Add a non· ionic spreader at label rates to the spray solution.

Weeds ControUed:. UPIMETRIBUZIN 4Fplus Gramoxone Extra (1-1/2 to 2"112 pints/acre) tankmix.applicationwill cotitrbt established weeds. Gramoxone controls weedS by conucractivity. . .

UPI M ~buzin4F Master Label Page 36. of 56

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WEEDSCONTROLLED' 112 to~ Pi UPI .3/400 1"1I2Pt UP!,;.

..... : .. ~ ,

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METRIBUZIN 4F/Acre .METRIBUZIN 4F/A~re 1 TO 1·112 Pt UPlMETRlBUZIN 4F/Acre Common Chickweed .Bluegrass Bhid4ustard Prickly lettuce

Cheat Commtin lainbSquarters Redroot pigweed. .•. Dowl'l:ybrome Fixweed Rough fleabane

i Fieldpennycress Green foxtail Ry~grass Henbit Groundsel Smooth brome Japanese brome .' Jim Hill mustard Sow thistle Rescuegrass Koehia Tansy mustard Shepherdspurse . Little barley White cockle ..

Mru;estiill (Horse weed) . Wild oats. Mea40w salsify Wild buckWheat

t Permetweed Yellow rocket

i RECOMMENDEDAPPLICA nONS Dosage/Acre .. ;. ,. 'REMARKS UPI METRIBUZIN 4F Apply specified dosages ofUPI METRIBUZJ:!Il4F and Gramoxone Extram at least 10 gallons of water

:112 to 1-112 Pt per acre with aerial equipm!'nt Or at 'east 20 ga110nsof w!lter per acre with ground equipment. Do not apply this tank mix to alfalfa growth if more than 2 inches tall. For best weed control, apply when ,

Plus .brQadl~w~s an<i grasses are 1-6 mches tallan<i are actively growing .. Care s\loulc:tbe takento avoid overlaps. Do not apply more .than 1 pt cjf UPfMETRIBUZIN4F,per acre,on loamy.sand soils. ·ReduCed

GtamoxoneExtra ,-,:eed cOli.tti>1 may occur when extended dry Ctmditioris followappllcationof~IMET:RIB(JZIN 4F,' 1'-112 to 2~li2.Pt. Crop injury mayoccurif alfBlrais under stress conditions such as 4iseases;~nsect'iirfestati()~; droughlor

wfuter iniurvorif UPI METRIBUZIN .4F is applied to aifalfa earlier than 12 inonthsarter,sUding.

FOR USE ON MIXED STANDS OF ALFALFA AND GRASSES: Rates of 1 to I-J/2 ptofUPlMETRlBUZIN 4F per a{:re will provide partial reduction of forage grass stands. These rates may be used to reduce forage grass stands to prevent crowding out of alfalfa.

Do not graze or harvest Within 42 days after application.

In areas west of the Rockies, avoid the use ofUPI METRIBUZIN 4F on soil!) with calcareous surface, sQi}s witll high levels oHime or sodium, and with pH greater tJ::fanS.2. .

Do n~t apply when weather coiiditions favor sptaydrift. Aerial a:pplicationshould no.t- be made when: WInd spe~d IS greater than rOmph. [)O not use on ,sanq soil.

Refer; to the Gramoxone Extra.Iabel for additional directions, weed species controlled and precautions.

Post.Dormant Application of UP I METRIBUZIN 4F Impregnated on Dry Fertilizer Only . .

UPI MBTRlBUZlN 4F may be applied after dormancy has broken, but prior to three inches of new alfalfashoot growth, . . only when impregnated on dry fertilizer in Connecticut; illinois, Indiana, Iowa, Kansas, Kentucky, Michigan; Minnesota,

Nebraska, New Mexico, New York, Ohio. Oklahoma, Pennsylvania. South Dakota, Tennessee, Texas, and Wisconsm. I

Apply at rates of 1-1l~ to 2pt per acre as directed 0n.,W~,:~.~l?yl for application during dormancy. Apply on~y W.h~n.~lfalf!l foliageis dry or crop injury'may occur .. Whenusingtliis:applicauon methO<i. do not harvest or graze tr¢ated?lfalfafot60 days lUter application. I .

Aeri~l application is prohibited ASPARAGUS (EstabliShed) .

UPI METRrBUZIN 4F is recommended for use in ground spray equipment or sprinkler irrigation (center pivot, lateral mov~. or solid set) systems as a single pre-emergence broadcast. application. or as a split application consisting of a pre­emergence broadcast application followed by a post harvest broad9ast application.

Refer to the "General Informatiop" section of this labelfor directions.

UPI Metribuzin 4F Muster Label Page 37 of 56

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UPI METR IBUZIN 4F. applied to established asparagus according to directions. will effect,ively control the following weeds: ' ,

Broadleaves Chickweed, Conpnori (SId/aria media) Jimsonweed (DatUra straliumium) Lainb~quattets (Chenop()diumalbuin) pigweed, Re4root (Amaranthuk .

,rerrqfl,exus)' ,

WEEDS CONTROLLED,'

Ragw¢eq.Cqrriil1Ori (AmiJr()sia, artemisiifolia),· •. Smartweed; :Perihsylvarua( Pdlygonum pejlsylvalliclf1i1) , ' . Sottel, Red (Rumex ac~tosel/a) Velvedelif (Abutiion' thedphrasti) .

Grasses ,Crabgrass.(Dtgitarla:spp.) . 'Eoxtails (Serqria spp:) , ' Sandbut,FieId( Centhrus p{lucifl("ru,~)' . ,

RECOMMENDEJ} BROADCAST APPLICATIONS CROP UPl METRIBUZlN4F REMARKS,

\ pt/Acre Aspiu'agus 2t()4 PRE· EMERGENCE APPLICATION ONLY: Make a single surface

application in early Spring before asparagus spears or ferns emerge. Ifthe field,is to be disked, applyUPI METRIBUZIN 4F lifter diskingbut ~eforet'!J.ecrop emerges. Use the lower rate for. control of the broadleafweedslisted above. Use the highe~rat~i.. ~J~~idswith a lj,is(ory, of severe inf¢stlitions of gtasses,~~,: tor j: • ,.,....w.

:' maximum reSidual contro); Do not apply with 14 days. of harvest: SPLITAPPLICATIONPRE"EMERGENCE AND POSTHARVEST Asp~agus 1 to 2preemergence

i Pre.emeI:genceApplication: ' Apply before asparagus spears orferns emerge. i

t plus If the field is to bcdisked, apply after disking but prior to crop emergence. Do , not apply ~thin 14 days of harvest. ! 2 to 3 post harvest Post Harvest Application: Apply after last harvest of the season but prior to :

emergence., Theiowet combination rates may be used for control of common ragweed, llmilisq~iuters, redroot pigweed, and red sorrel. Use the lligher combination rates for other weeds -listed orin fields with severe grass infestations or for maXimum post harvest control of emer~ed weeds.

IMPQRT ANT: The total amount of UPl METRIBUZIN 4Fapplied in one crop season may riot exceed 4 pt. per <¢re; SPECIAL PRECAUTIONS (AsparaguS): Do not rise on newly seeded asparagus or on young plants'dliringthe [JISt growing season after setting crowns. . '. . , Dd'~OTAPPLY 'P(:)ST HARVEST APPLICATION'S UNTIl:.AFrER THE LAST HARVEST OF SPEARS.

CAJpiOTS Special Co~«!itionsof Sale Provision for Use on .Carr9~: , The follqwing directions fottise were developed uild.er Qle direction OfIR4(government min:or cropsuseprog'riutl)~'As such; the testing was done independently. Buyer is advised that UPI makes no aSsurances regarding satisfaction with the product and all risks of crop injury or prOduct performance are a~sumed by the Buyer. .

Apply UPI METRIBUZIN 4F herbicide with ground equipment as specified below under ''Recommended Applications". For effective control of broadleaf weeds with post-;emergence applications,. applyUPI METRIBUZIN 4Pbefore weeds are 1 inch in height or diameter. Thorough spray 'coverage is essential for adequate weed control.

i

.... Do:nlt use,air blastor other high pressure spray equipment to make post~en'iergence.apPliC~tiOrts ofUPI METRIBuZIN:, . " 4F.~efer.LOthe appropriate section of this laoeHot additionalinformaUon,regardingspray equipment. diiutionriites;·':;'··

'mixing, sptayercleanup, restrictions, container disposal and cautions. . .'

. . ... ,Refer to "Mixing" under the "General InfOI:mation" section on the front Q(tl)is ~abel. ~ ,}. 1;<'<1 f";':"·,;'y·:;'

For sbecific application information. see "Generalli:tformation" and "Application" secti ons at the front of this labeL

UPI METRIBUZIN 4F applied to carrots according to directions will effectively control the following weeds:

WEEDS ,CONtROLLED Carp~tweed(Mullugo veriicillala) 'Gali~oga (GaUnsoga parviflora)

,Horseweed (Conyzacanadensis) :Lamb-squarters,Common( Chenopodium album) 'Mustard, Wild (Sinapis arvensis)

UP! Metribuzin 4F Master Label

" .' Pigwe,ed"R,edroot"(Amaranthus retroflexus) , Pigweeo;:SmoOth (Amaranth'us hybridus) .. ', , . Prickly Letruce (IAtuC(l serribld)

ShepherdspPrse (QapseU{ibursq;pdstoris) .. • Pineappleweed (Matricdria ri1iltricario./des) .

Page 38 of 56

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".", . .-. RECOMMENDED APPLICATJONS

CROP UPI METRIBUZlN4F REMARKS -. ; ptlAcre <", c."

Carrots 112 Apply.specified dosage per acre as a broadcast spray over the tops of carrot plants .. ;

Application should be made after carrots have formed 5-6 true leaves but before weeds are 1 ineb in height or diameter. If needed, a second application may be made after an interval of at least 3 weeks. Applications may be made up to 60 days of harvest.

IMPORTANT: The total amount of UPl METRIBUZIN4F applied in one crop seasonmay'not exceed 1 pt per acre. SPECIAL PRECAU:nONS: Do not apply to carrots grown for seed. Do not apply within. 3 days.after periods of cool, wet or cl<>udy weather or crop injury will occur. Do not apply UPI METRIBUZIN4F within 3 days of any other chemiCal unless . sp~ified on this label. Do not apply on very bot days or excessive crop injury will result. Do not apply until carrots have at least 5-6 ~e leaves, Earlier applications will resultin.excessivc crop damage. - . .,

Crop iJ.1jury or delayed maturity may resuli from applications of UPI METRIBUZIN 4F if carrots are growing under stress conditions such as periods of drought or cool,wet and cloudy weatherprCceding application.

Following ail. application of UPI METRIBUZIN 4F, chlorosis (yellowing) and burning of tbe leaf tissue may occur. . .

For n~wly introduced varieties of carrots with unknown tolertmceto UPI METRIBUZIN 4F, treat only a si:nall.area to determine of UPI METRIBUZIN 4F can be used without injury to the crop.' .

FIELD CORN Postemergence A,pplication UPl METRIBUZIN4F.is recommended for controL Of selected broadleaf weeds when applied as a tank mix cOmbin~tion with bertainbroadleaf herbicides presently registered, .~d reco1Illllended for poste~rgenCe use in field corn., .HerbiCides whiell may be tank mix~d wiih UPI METRIBUZIN 4Fiilcltide: . . "'..

2,4-D Atr'.dine Banvel Basagran BucLrillBuctrH Gel

Buctril + atrazine (Premix) Clarity Laddok S-12 Marksman Pilrsuit*

. * U~e only on Pursuit resistant/tolerant com hybrids (IMI-corn). : . .

Resource Scorpion III Tougb

APPLICATION: UPI METRIBUZIN 4F may be:appJied ~o field com after crop emerge~ce untiljust priorm tasseling. Broa~casl applications may be madewithgrollnd or aerial equipment. For optimum weed. control, apply treatments .when

·.wee$ are smaIl and actively growing, but before teaching the maximum heights listed in the Weeds C9i~troll~d, tabJe, ~, . 1 . .' " "- ",

POSTEMERGENCE BROADCAST APPLICATION Ground Application: Adjust nome height above ctbp and weed canopy to ensure uniform spray coverage.G~llonage should be increased with increasing, weed .size and population density. .

For tank inixes of ~PI METRIBUZIN 4F plus ~tra7..ine, Basagran, Laddok S-12, Buetril, Buetril + atrazine, Pursuit. Reso).rrce, Tough, or 2,4-0 amine formulations. use flat nozzles spaced a maximum of 20 inches apart. Best results are achieved using a minimum of spray volume of 10 gallons per acre and spray pressure from 20 to 24 psi.

,J!9rjil@I'ME'rRIBUZIN 4f ta~ nilires with B.anvel, 9arity. Mark.~nlah, oc2,4-D low vol.a-t,!l~}~§tet fonnuiauons, use dt;i,ft" , , ~e<luCingnozz]es ~hid~ are specific~lyde.signeclJoj:>~ucee()ru:se: sprays and reduce the amQuljt ofdr.iftabl~fihes; .. : . Aciditional m~ures which will. help avoid poteiltlaidriIt .~.·sensitiye crops aridplaptSihcludteusing aniinimumspray vohiipe of 20 gallons per acre and keeping spray pressures at or belo", 20 psi unless otherwise specified by the nozzle' mamifacturer. . '.

For further precautions and additionalinstructionsandreconimendations, consult the tank mix partner's labeL

Aerial Application: Apply in a minimum spray volume of J gallons per acre. For optimum spray coverage and , distribution, use a minimum of 5 gallons per .acre and a maximum pressure of 40 psi. Use a boom and nozzle configuration which will provide a unifonn deposition pattern and coveragewith low drift potential. A void overlaps to prevent potential crop injury. Do not apply near sensitive crops or sensitive platUS gr()wing near the treated area. Do not apply when wind . speedis greater than 10 mph or when winds are moving toward ~erisitive crops or plants.' To avoid drift hazards.applic~tor

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UPI Mctribuzin 4F MI!--~ter Label Page390fS6

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musdfo.llo.w the mo.strestrictive labeling o.f the products !)sed in.8 tank mix, Refer to. the appro.priate tank mix partner's lribel'for further precautio.ns and.reco.nimendatio.ns.· . .

POST DIRECTED APPLICATION l]PIMETRIB UZIN 4F in tank mix co.mbinatio.'ns with Banvel, 2,4-D, B uctril o.r Scorpio.n III may be applied Po.st directed,. tnfield co.m .. Use dro.p no.zzles and 'appro.priate spacm,g to direct spray ,belo.wthe Corn who.rland, upper leaves, . The t()p of the'target weedcallo.pyinust be sufficiently belo.w the whorl and upper leaves .o.fthe crop to. permit this applicatio.n and provideadequatesprayco.verage, The height differential required between the crop and weed canopy will depend o.n the specific equipment us.ed. Apply before tassel emergence. For further, prec~utio.ns and additio.nalrecommendations, refer to. the appropriate tank mix partner's label.

ADJUVANTS Theadjuyarit types listeclbelow maybe utilized with cenain UPI METRIBUZIN 4FtaIikmix cofubinations. Consulnhe tank ¥rlx reco.rrunendations .sectio.n fbrthe appro.prlate lldjuvant and, ~ate. Use of no.Necorrunended adjuvant o.riates.may resul~ in severeleafburn, crop,stunting, andlorstancf:reductil,m, Use o.niy adjuvants which are exemptfro.m to.lerance ' requirements under 40 CFR 180:1001. ...'. ..... '. ','

UAN(urca amm0riiumnitrate) is co.rruno.nly referred to. as 28, 30, o.r 32% N.

.• Ammonium sulfate (spray grade) may be used as an alternative to. VAN with certain tank mix co.mbinatio.ns.

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": :/< "i'1 :,~L "

Non-ionic surfactants sho.uldco.ntam at least 80% active ingredi~nt.

DO NOT USEcrop o.il co.ncentrate (coq o.r llDy.adjuvl:llltc6ntaining vegetable or petroleum o.ilswith any UPI METRIBUZIN 4Ftankmixtures as severe leave burn. cro.p stunting! and/or stand reductio.n may o.ccur.

~NFASTNESS . .' '. . . . '.. ..". . .. .' , UPI ¥E'flUBUZIN 4F will no.t reduce rainfastness o.f the reco.rrunended tank mix, panners. Refer to thejndividual product. label$ forrainfastnessreco.mniendatio.ns. . '.,

. SPRAYER CLEANUP Refer to. each tank mix partner's label and the Sprayer Cleanup section o.f tile UPI METlUBtrZIN 4F label fo.r specific instructionso.n cleaning spray equipmeiit. Special att~J;ltio.n sho.uld be given to the required cleanup proCedures for 2,4-D. Ban vel , Clarity. and Marksman. .

SPECIAL PRECAUTIONS

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po. not use o.n.com grownJor seed, sweet corn,po.pcorn, or white corn . .00. no.tapplymorethan 0.25 pounds a}METRIBUZlN(5-113 punces UPI METRIBUZIN 4F),peracre per use seaso.n. Do. not apply when field co.rnis under:stressJsee Stress stalementbelow). Do no.t use aerial ap,plicatio.ns if sensitive cropso.r plants are gro.wlrigin .the viCinity o.fthearea to be treated. Do no.t allow spray drift onto sertsitivecrops.orplants. . ' IDo not use on sand, loamy sand.o.r sandy loam. seils that have less than 0.5% organic matter. Do. not use on sand or loamy sand so.ils in Washington. Orego.n o.r Idaho.or crop injury may occur. Observe all precautions and llinitatio.nso.n labeling of all products used in the tank mixtures.

Stre~s is any co.nditlorii'orcombination o.f conditions which impairsn6rmal cro.p growth. Weather; disease;ins¢ctTa~ge," fertility or o.ther factors may caUSl! stress. Applicatio.nsmade befo.fI::orafter the co.rn is un4er stress fro.fu theSe facto.tsor fro.m ·perio.ds ofprolo.ngedcool. Wf;!t and.clo.udy weather o.r wid~ly fluctuiUingday and nig~ttinie t~mperatures;,may.t:~~lilt ' in temporary leafburn,sellowillg andlotstuiltingof the crop~ . Recovery.fro.m damag'eis gcIietauy raRid with "no la~tirig .... effe<:{son new growth. :tJilc!et ex.trefue stress. stand reductio.ns nulyOCcl.lr. . . . ' .

~,. •• • • "" '" " < " "

" " ". " ~"

FeedingRestric.tions: Fieldco.tn treated with UPI ME1'RIBUZIN 4F IDIIY be .grazed or harvcstedfo.rsilage'or,grain60 ,-,.' days arter.treatIilent.Fo.llow the mo.st restrictive prehan'estintetVal on the labels o.f the products used inthe.·:tatikinixtures.

TANK MIX COMBINATIONS

The (JPl METRffiUZIN .4Ftank,mixtures listed belo.w can be utilized forcontrolof cenain annual broadleafweeds;

UPI~etribllz!n:4F Master Label Page 40 ofS6

~ " "

iI~tft , ,~

•

'J/ ,:y.,

""

r-----'-----~U~P'::'":I M~E~TR1B=.",U""Z~IN-::-4.,."F"..."P:-::O:-::S'::::TEME=:'-:~R:::c"G=EN==C~E:-:B:-:R:-:O:-AD'"=· :-:C::-:A-:::S=T-=RE-='-=C-=O:-:MM=-=E:::-ND=T~IO:-;:N-:-:S:-' --'--------,

PRODUCT .' UPI METRlBUZIN 4F

+ t,4 .. D Amine

or :2.4-DLVE

UPlMETRffiUZIN 4F (, . i + I Atrazine "

UPI ~TRIBUZlN4F , +

Banvel Or

Clarity

UPIMETRffiUZIN4F ; . +

, Basagran

UP[~UZIN4F

i + 1 Buciril ,Or IBuctril Gel

UPI METRffiUZIN 4F +

Buctril + Atrazirie . , (Premix)

UPI~UZ1N 4F .. I '+ Ji;addokS-12 I

UPI METRIBUZIN 4F f

iMarksmim !

UPfMETRIBUZIN 4F +

PursUit i '.

RATE ,I DIRECTIONS AND REMARKS~ 3 flozlA

+ 1/2 teil pt/AI

or 113 to 112 ptJA J

3 fl ozlA

Apply as a broadCast spray during the interval from com emergence. until com is 8,inches tall: Apply only to varieties known to be tolerant to 2,4-D. DQ NOT USE ADJUVANTS. 2,4-DJIiay cause injury to nearby sensitive crops. 2,4-D applications may result in brittle cl)mstalks, and. winds or cultivatil)n maY cause stalk brealcage. To reduce damage, df:lay cultivation 8 to IO'days after application. . Apply ~a bioadcasLspray during the interval from,com emergence.,untilcomis 12,inches

+ tall. . AllOll_ionicsurfactant (I qr/l00 gal. of spray solution) inaybe'arldedto improve weed 112 to 1-112JbafJA control. AtraziIiejs.a restricted '.use heri:Jicide. FollQw all ,state ,and Jederallllbf:l

. reconlmendatibnsandrestriccions pertWninO'toatrlizine applications. . . 3.f1'ozlA

+ , 1/2 to 1 ptJA

or 112 to 1 ptJA

3 fl9z1A +.

1 ptJA

2.4 io 3 fl,07lA +

1 ptlA or

112 ptlA 2,4 to ~ fl ozlA .

+ 1-112 t02 ptJA

3 fl.o7lA

Apply ail a broodcast'spray during thiUnteri'ral fromcoril emer,gencelliroughthe five leaf stageot\vhencom is 8 inches tall, whichever occurs fti'sl Fot:Banvei applications to com

,greater than.S 'inches in height, consult the Banvellabel for ,use rates and restric,tions. If growing coqditions'are.dry and plants are suessed, addition of a non-ionic surfactant (1

·qtll00gal. of spray solution) may improve weed control. For corn growth on coarse textured soils, apply Banvel or.Clarity at 0.5 ptiA; regardless of application method. Applicati,o!1may cause injury to nearby sensitive crops or plants. Application may result in temporary l~ing of corn plants. Delay cultivation until plants rel11rn tonormill'growth patterns'to avoid stalk breakage . Apply as a.]:lIoadcast spray,afier corn emergence btlt before com exceeds 30 inches in . : h~ight,and the Cropcariopy closes the row. Adjuvants such as UAN'(05 to1 gallA), " anmioni~in~suifate (i 7Ibi.J~OO gai. ofspraysolutil)n), or non-ionic silrfac~t (l qtilOQ gal, ofsjJraysolution),may improve weed controL . : .....,:'; ., .. Apply as aoroaOcast spraywhen corn is inth.e fourth true lear stage or later butbefore :the crop canopy closes the row .. DO NOT USE ADJUYANTS. Occasional temporary corn . leafQurn maY .occur and is similarLO Ibat observe.d from liquid fertilizers: Recovery. is gener3nyrapid with no lasting effoct. To reduce potential for crop damage, applicatiOn should be rruide'to. <!ri'. com foliage when weather conditions are not extreme. . Apply as llQroadcast spray during the interval from com emergence until cOmjs 12 inches tall. DO NOT USE AD.royANTS. Occasional temporary com leaf burn may occur and is sirnilaI-'to that observed from liquid fertilizers. Rocovery is generally rapid with no lasting effect.. To relluce potential for crop damage, application should be made. tl) dry cl)rn foliage wb~'weatherconditi6ns are not extreme. . Apply as. a,l)rpad~ast ~prayaftf:r comemerg(!nce unti,l, the corn is 12'incMs tau. Adjuvants

+ §us;h !IS U~(6.:5to 19aL'A) may fu~re,as~ 'YeeQc¢niiol, La~dok S-12cplit~ attilz,iJi¢" '

J .33 to i.66, pt/ Ak~~~t~()r;;~~6~nk~~~0:=in!:1I9Wallslate. and federal bbel recommendati()~S llJid

+ 1-112 to 2ptlA

3 fl ozlA +

2(0 4 o7lA

Apply as a broadcast spraYduring the.ihtervalfrom COllleII!ergence lliroughi:h~.fiveilelif . stageorwheri crupis 8 inches tall, which~ver occurs flrSt.'DONOT USKADruyANTS.,:. Application may cause injury to nearby;sensitive eropsor plants. Applicati()h Ina,Yresullin " . temporary leaning Of com plants. Delay cultivationuntll plants return to normal growth patterns to. avoid stalk breakage. Marksman .. contains atrazine, and is.a restriCted use· product. . Follow ill slate and federallilbel recommendations and restrictions pertairiingto atraziIii' ,

Uile only on designated IMI-Com hybrids {hybrids which are resistant/tolerant to Pursuit}. ApplY,the4.Q ounce rate of Pursuitif grasses are present orbroadleaf weeds are '~ear :i:h~ '0 ' . n'lilxiriiuni heightSsboWh. Apply in cotnbinati~'with a,noh-iQnic $lirfitctimt (1 c@OO,gal, of spraYsolutiori):and UAN (Lto 2gtlM., " ';,;,S.;:jf ",'

.. ;; ,

UPI METRmUZIN 4F 1 +

3 fl, o7JA . Applyils,abroadcast.spraY tafield com:from2~leaf through 1 O~leaf(Visib~eJ~f 1;011iiis) i;;;,;,;U'",; <+ ... <rY~~i~, iJ~ge:;A~li'Yimi~~ucti,~~onioruc;surfaciant (0.25% vlV)or ai~minurnstJlfate{2.50Ib~A) "",;i.'C' •

I Resource UPlMETRIBUZIN 4F

I + Tough

4to 60z:lA. may tDcrea~e'weedcontrol. ,"', . '. '3 fl:ozlA Apply as a broadcast spray after corn emergencebuibefore corn height.exceed,JO.~ches .. '

+ and th.e crop cariopycloses the row. A non-ioilicsutfactant (1 qtlIOO,gai.of'spray s6lution) 1 to 2 ptlA may be added toiinproveweed contro\. Use the highf:r rates of Tough as weeds approach

to maximum height Iistedor,are found in high density. Tough may improve control on triazine/ill resistant weeds.

* Consult the appropriate tank mix. partner' Ii label for additional reeolJ¥llendations or restrictions. The most restrictive labeling applies to tanknlixes with UPlMETRIBUZlN 4F. . ; .. J Application rate is based on, but not restricted to; 4 pounds active.iiJgredient per gallon of 2,4-D.

.-"".

UPl Mttribuzin 4F Master Label Page 41 of 56

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--'TI1J; '---, -..:.------...."UP=I-.M--E--T--RIB"="U ..... ZIN=,....,4--F--PO--. "::-ST=.--D--IRE~CT=E--D"""RE~C~O--MME-::::-:~ND=A"""TI=-:O""'N--S~-""'---------'· . >.;

. PRODUCT. UPI METRffiUZIN 4F

14-D~ne . ."'

or 2A-DLVE

UPI METRIBUZlN 4F . + : Banvel

: RATE., "":" ,> DIRECTIONS ANDREMARKS*: . 3 to 4.5 fl ozl A fpr CQmgreaterQUin ~ inshestall,apply as adite.cted spray with drop noz.z1esbefore tassel

4- emergen~~Applyoruytovarieties known to be tolerant t02.4-D~DONOTUSE . 3/4 to 1, 1~ pttAi ADJlJyA:NTS~·.·2;4"Dniliy c!luse inJucyt6 nearby sensitiv¢ crops .. 2;4-D applicatioiis may

or . . resultin britileeonrsclIks, :and winds or cultivation may cause'stalkbreakage; To'reduce . 112 to *.ptlAI damaere, dclay:cultiva:tion g to 10 days;after application.

:3 .104.5 t1 ozlA For comS.to 36'inches tall. apply as a dire¢tedspraY with drop .nozzles. Application may -+ be miKleupto15 days prior to corn tasseling. Ifgtowing conditions are dry imdplatits are

'h ptiA stressed, addition of a non7ionic surfactant (1 qtllOO gal. of spray solution) may improve weed control. For com grown on coarse texturedsoils,apply Banvelat 0.5 ptlacre, regardless of applic;ation.mithod. Application may cause injury to nearby sensitive crops or plantS. Application may result in temporary leaning of com plants. Delay cultivation until plaritsretum to norinalgrowtbpattems to avoid stalk breakage.

UPI Iy.IETRlBUZIN 4F 3 to 4.5 fl ozlA Apply!l,$ a,directed spray with drop nozzles before taSsel emergence .. DO NOT USE + + AD.JUyANTS.Occasiomil temporary com leaf bum may oc;cur and is sjmilar.to iliat

,Buttril 1 to'1,-i/2ptlA obs~tv¢frQinliquid' fertllizets~ Recovery is generally rapid with no lastilig effect.· Til Or or redUce potel1tial for crop damage, application should be made to dry corn foliag~\¥hen

,;Btictril Gcl 112.to 3/4 ptiA '.; o>wcathcrcori!:iitiousareillot·exti'eme. , . '. ."," ' UPI lVtE'rRIBUZlN 4F 3 to 4:5 fl. ozJ A For com 8 to 24 jIiches' tail, apply as a directed spray with dropnowes. Include non"iomc

, + ' + sllrfactant (1 qt.l1OOgal.)plus U~ (2.5 galJlOO gill.) for op~mum weed c;orttroJ. . 'Scoroionlll 4oz.lA

'" Consult the appropriate tank mix partner's label for additional recommendations or restrictions. Themosirestrictive hibeling applies to tank lhixes with UPI METRIBU7.lN 4F. 1 Application rate is based on, butnot restricted to, 4jJ()unds activeingI'edientcQer-.ianon of 2,4,D.

: WEEDS CONTROLLED"'; POSTEMERGENCEBROADCAST APPLICATION These tank mixtures with UPlMETRlBUZIN 4F will c6ntiolthe following annual weeds 1li> to the maximum heights listed:

·.lJPfMETRmUZlN 4F+ " , l ' Buctr'iV

BanveY . Buctril+ . 2,4-D

l.addok ' Atra!iue. Clarity . Basallran Airazlne . Marksman Pursuit '8-12 :Resource Tou!!h

COMMON WEED .. - ~ .,

. '~NAME MAXIMUM wEED HEIGHT INJNCIIES* .

Amaranth. Palmer 4" 4 2" '4" 4 4 8" 6 4 4 Buckwhctit, wild 3 3. 3 3. 2 3 2 3 4 Buffalobur 4 4 4 4 1 Burcucumber 4 4 2 4 4 Carpetweed 2 2 2 :2 2 2 2 3 4 Cocklebur, common S 8 8 8 S 8 8" S 3 6 Eclipta 3 3 3 3 3 3 3 3 Henbit 3 3 2 2 2 4 3 3' 4 HorseweedlmareStail 3 4 1 I 3 .6 2 3 .. ·· JimsonWeed. 5 5 6 .5 5 5 5 6 3 5 KnQt\I{eed 6 6' 6 4 2 6 4 6 4. Koc.hia 2' 2 1 ' 2" 2" 2 .2 2' .4

. Ladysthumb 6 6 6 6 4 6 4 6 4 '6 I

Lamb~quarters;. ' 68 6 1 6 6 6 4 5 4 4 eoinmon· Lettuct!, priCJ.;ly 4 4 3 4 5 3 Mallow, VeniCe 2 2 2 ·.,2il'?,1';':· ~; .2 2 2 4 Momingglory, entire 3 3 1 3 3 3 2 2 leaf Momiilgglory, ivyJeaf 3 3 1 .3 3 3 2 2 Morningglory, pitted 3 3 ] 3 3 3 2 2 Momiilgglory. tall 3 3 1 3 3 3 2 ') ...

. Mustard. tansy 4 4 4 4 4 4. 4 4 Mustard. wild 4 4 4

, 4" 4· ' 4 4 4 4

Night",hade; black 6 6 . . 6 1 6 . 3 '1 4 Nightshade, eastern 6 6 6' : .black i

". l' 6' :3 I 4,

, Pigwe~d, redroot 6" 6 2" 6" . 6 6 'SO 6" 4 '6 Pigweed, smooth 6" 6 2" 6" 6 6 S\' 6" '4 6 Poorjo¢ 3 3 3 3 3 3 3 3 Purslane. common 1 3 4 1 .3

UPI Metribuzin 4F Master Label Page 42 0(56

< ••• '" ••• :~,... •

•

••

Pilsley; Florida . 3 3 3 3 3 3 3 3 Ragwe.ed, common 5 5 3 5 5 6 3 4 3 Ragwe'ed, giant 4 5 2· ; 4 3 6 4 4 Sicklepod 3 3 3 3 3 3 3 3 2 Sida. prickly 1 1 3 1 1 2' I 2 2 1 Sm~eed. 6 6 6 6 4 6 4 6 4 Penn~ylvania

Sunflo~er. common 6 6 6 6 6 6 5 6 5 Thistle'. Russian I 3 3 1 3 1 1 3 Velvet)eaf 6" 6 6 6 4 6 5 6 6 Walerhemp. spp. 5' 5. 2' 5a 5 5 40 ~.

." 4 5 ~. When weeds are approachin'g the maximum height listed orfOilnd in high .densities, use the higher. rate ofUPIMETRIBUZIN 4F ana the selected tank iriix pru:tners~ . . . . a These treatments will not control triazine resistant blotypes. b TIIe'se treatinentS will·not <:bnth>1 ALS resistant biotypeS.

! WEEDS CONTROLLED -POST DIRECTED APPLICATION Thesci tank mixtures with UPI METRIBUZIN 4F will crintrolthe f6I1owinl!: anilUaI weeds uti to the maximum weed heil!hts listed:

UPI METRlBUZlN 4F+ "'-. 2.4-D Banver BuctriJ Scorpion In "

COMMON WEED NAME MAXIMUM WEED HEIGHT IN INCHES • Amatimth. Palmer 12 12 6 8 Cocklebur, corrimon 12 12 12 15 Jimsonweed 12 10 1.0 8 Ladysiliuinb 6 8 6 6 LambsQilarters, common . 12 12 10 12 Mominggl~i:y, entire leaf 18 . 18 6 12 MominggtQJ;Y, ivyleal' 18 18 6 12 Morninl!;glory, pitted 18 .. 18 6 12 Mornin~glory. tall 18 18 6 12 Ni<dltshade, black 10 8 8 6 Nightshade, eastern black 10 .8 B 6 Pigweed, redroat 12 12 6 8 Pigweed, smooth 12 12 6 8 Ragweed, common 8 8 8 1.0

. Ra!!Weed, giant 12 12 8' 15 Smartweed; f>ennsylvania 6 8 6 6 Suuflower,.conurton .12 12 12 12 Velvetleaf 10 . 8, 8 8 Waterheinp, tall 12 12 6 8 '" When weed~ ate approaching themaxirr.mm height listed or found in high den~ities, use the higher rate ofUP1 Iy.1ETRIBUZlN 4F and the selected tank mix partners ..

PERENNIAL WEED SUPPRF.,8S10N

The following UPI METRIBUZIN 4F tank mixtures will provide top growth burndown and .in s(!ason suppression of the following perennial 'weeds; however, regrowth may occur. For the best performance on these weeds, use the maximum rates <>fUPI Mb"'TRIBUZIN 4F, Banvel, Buctril, Buctril + atrazine, Clarity. Marksman, 2,4DLVE or Pursuit recorilmended for these tank mixtures.

.';:::-<.·'i';'''"'''··-'':··

j UPI METRIBUZIN <iF·

COMMON WEED BartveJlClarity Buci1iJl 2;4-DLVE Marksman Pursuit NAME Buctril +

atrazine Bindweed, .field x x x' Dandelion, common x x x Dock; curly x x x Smart weed, swamp x x x Thistle, Canada x x x x x

UPI ~ctribili.in 4F Master Label Page.43 Of 56

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FIELD CORN:P~PLANT AND PRE~EMERGENCE (Dlinois, Indiana, IoWa, Kansas,KentU~kY,'Michigan, Minnesota, Missouri, Nebraska, Ohio,

, ; , , South'Dakota and'Wisconsin) , , UPI J\1ETRIBUZIN 4F is recommended for additionahesidual control of certain broadleaf weed species in corn when

appliect as a tank mix combination with both grass ·andbroadleaf herbicides registered and recommended for use in field C()rnJUPI METRrBUZIN 4F can be tankmixe4 with recommended rates ofthefcillowingberbicides: '., , . .' .

Alach,1or Bullet 'HiunessExtra Atrazine Clarity Lariat Ban~el Cycle ~linex Bitep: Dual LfntirOfl Bicep)! . Dual.IILorox Bicep Lite Extrazine II Matksrilan Bladex' Frontier. Pentagon Broadstrike + Dual Guardsmiln Prowl

. Broadstrike Plus Harness Pursuit Plus * * Use' only on Pursuit resistantftolerant corhhybrids (lMI com).

Pursuit:" RaIiJtod' Ratnrodl Atrazine SiiruiZtne Surpass Surpass 100 Topnotch

App$cation:, UPI METRIBUZIN 4F rtiaybeapplied to field cornpteplant.withoutincorporation up to 30 days prior to .plaJlting'orpre-emergence. Applications may be made by either ground or aerial equipment. For tank:mixes,JollowJhe :mostirestrictive appIicationmethods of all ptodilctS used;'

Special precautions: • Do not apply more than 8 ounces UPT MEtRiBuZIN 4F (0.25 pound active ingredient) per acre per gtowingseason. • Do not apply on soils having pH 7.0 or greater. • Corn seed ,should be planted ami.nirilU~ of 1 Y2 inches deep. • UP1METRIBUZIN 4F may only be used in hybridseeo. corn production fields if both inbred parents are known to be.

tolerant to UPI METRIBUZIN4F. • ~()t recommended for use on muck soils.as reduc&l weed control may result • 0bserveall precautions and limitations.on iabeting of.all products uSed in tmkmixes, .

! ,. .

f .'. '.., ' , Feeffi,~g restrictions: Corn treated with UPI METRIB UZIN 4F may ~e harvested for silage or grain 60 days after treaupent . For'tank mixes, follow the rilostrestrictiyepreharvest inieli'liI of all products. used. . ~ . .

,. WIiiEDS .CONTROLLED*: UPI METRIBUZIN 4F; will aid in the residuliI. pre-emergence controI.ofthe follbwing weed speCies when tank mixed with othertegistered grass arid/or broadleaf corn herbicides: . Horseweed/matestail PigWeed, spp . Sunflower Ladysthumb Ragweed, comnion Velvetleaf LambsQuarters, common Smattweed, Pehnsylvatiia W aterhem~, tall .* For control of emerged weeds refer to ihe"BumdoWn Weed Control" section of theUPI METRIBUZIN 4F label.

: UPI METRIBUZlN 4F FffiLDCORN RATE RECOMMENDATIONS

STATES APPLICATION TIMING UPlMETRIBUZlN 4F REMARKS , FLOVA .,

Iowa, Nebraska. Prej>limt 0 to 30 days Apply asa.broa<!c~:spray,pr.iorto 'KansaJ • South 'Dakot!l 3 t08 com .eIllergence frpm the soit '. Missouri Preemergence Do. not apply UPIMETRIBllZIN4P'

on:cOatSc textureP soils'Wiih le.<;S .than ,/:;::<.;~':,.;,: ... L~% ()~g<!Iii~,matler,

lIIinois Minnesota Do not apply more than 6 fI ozUPI iIidiami Ohio ME1RIBUZIN 4F per acre on soil~ Kentucky Wisconsin Preplant 10 to 30 days 3to.8 withle.'IS than 2.0% orgailic.matter .. Michigan For heavy weed infestations and/or

early preplunt applications uSe the higher rates of UPI MlITR IB UZIN 4f.

Preplant 0 to 9 days

, !?r~¢(!rgence 3 . .1'06 ,

.,

Consult the label of herbiCide tank mixpanners to detennine proper use rares·forthe.other product(s).

UPI M,etribuzin 4F Master Label Page 44 of 56

BURNDOWN WEED CONTROL- FIELD CORN SeePage 28

GARBANZO BEANS (Cbic){peas) California, Idaho, Oregon, and Washington

. Special Conditions of Sale for Use on Garbanzo Beans (Chickpeas): The following directions for use were developed under the direction of IR-4 (governIil~ntmi~or crops use program). As such, the testing was done independenily.' Buyer is advised that ffiJI.iDakesno assurartces regardiilg satisfastionwith the product and that all risks· of crop injury or pfoducL . perfopnanceare assumed by the Buyer. . ,

UPI ME'r:RiB UZlN 4F herbiCide is recommended as. a pre~metgeIlce application for tI:le su:ppres~ion of certain broadleaf weed,S in garbanzo beans. . .

WEEDS SUPPRESSED* Co:minon Chickweed Common Lambsquarters Dog Fennel (Maywecd)' Shephcrdspurse . Field'Pennycress Wild Mustard· Henbit ' Pigweed .;. Suppression is a reductionin weed size and growth compared to a lion-treated area in the same field. UPl METRI~UZIN 4F

~' ~'~u~sed~~~o~n~e~w~il~ln~o~t~c~on~t~ro~l~m~'~=i=n~e-~r~==ffi=tan~tw~eed~~S~Pt~~ie~s.~ _________________________________ -__ ~~· ____ ~ _.,i .': ,

RECOMMENDED APPLICATIONS- . , I

UPI1METRlBUZIN4F "..,' -REMARKS , PtlA j

: 112 to 3/4 Applied sp~ifjed dosage in a single preemergence application using 10 to 40 g~ons of water per acre with ground spray equipment. ApPly before or after planting but before crop emergence.

, Thorough incorporation, either by rainf~ or by mechanical means, is essential ror weed . , suppression. UiJder dry conditions. incorporate UPI METRffiUZIN 4F into the top 1 to.2 inch~ of soil with spike harrows, or siniilar shallow incoiporation equipment,. then. cross harrow to insure uniform soH incorporation .. Where soil surface is moist at the time of application and rain follows before weed. emergence. a broadcast application should provide adequate weed suppression.

Use on coarse-textured soils, sandy soils or any soil with less than 1:5% organic matter will likely cause crop .injury.

Use the bigher iat~ on fme textured soils (bighin clay 9rorganic maHer) iU1d·fu·field .with abistoty· .:of high weed populations. ' '.

SPECIAL PRECAUTIONS: Crop injury may.resultif crop is under stress conditions. caused by cold weather:poor,soil fertility, disea.~e or inseCt damage. . .. Crop injury may result if application is fOllowed by heavy rrun; Avoid' application of more than Vz inch of irrigation within one month after application .of UPI METRffiUZIN 4F, or crop injury may.occur. Do nocuse on clay knobs or p()orly covered .subsoils. Do not apply pre-emergence on sh~ow seedlings less than 2 inches deep. Do not graze or feed treated vines to livestock within 40 d.ays after application, Main~ain continuous spray tank agitation to keep materi~in suspension. Avoid overlapping of spray swaths and shut off spray bloom~ while turning. slowing ()r stopping, or crop injury will OCI-'Ur. ' .. NOTE: 'ThIs treatment may cause some chlorosis or minor nel-'fosis. Becausegatbanzo bean varieties may vary in their susceptibility to UPI METRIBUZIN 4F, determine crop tolerance prionoadoptlon as a field scale practice to prevent possible,,: injury. , ..,.:i;C;;}:oc'" "

"" ::!ti(;ji;:t;:+

LENTILS AND PEAS ! . (Idaho, Oregon,' Washingtoh, Montana, and North Dakota)

UPI METRffiUZIN 4F berbicideis recommended as a pre-emergence and post-emergence application for the suppression' f . b adl af d' I . 'Id . . 0 certam ro e . wee S In entl s an peas.

. WEEDS SUPPRESSED* Common Chickweed ** Lambsquarters Dog FenneJ Shepherdspurse ** Fieldj Pennycress Wild Mustard Henoit** . Com Spurry '. Redroot Pigweed ' Pcnnsy1vani!i Smanweed ,.

<.

Pineappk W ced .. Prostrate Knotweed· . *Suppression.isa reduction in'weed sp:e and growth compared to a nori-treated area in the same·fjeld. ' '

** Pre-emergence application only

UPI Mell'ibuzin 4F Master Label Page 45 of 56

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PR&EMERGENCE APPLICATION: Make a single pre-emergence application ofUPI METRIBUZlN 4F at 3/8 to 3/4 pint per acre per crop,year. Apply in 1 0. or more gallons of water per acre with ground spray equipmentor ,5 or more gallobs of water per acre with aerial sprayequipmenl. ApplyUPlMETRIBUZIN 4Fbefore orafter,planting.Thorough incorporation; either by rrunfaU or'by mechanical means, is essential for weed suppression. Under dry conditions, . incoq>orate UPI METRIB UZIN 4F into the· top 1 to 2 inches of soil with spike harrows, or similar shallow incorporation. equipment, then cross harrow to. ensure uniform soil incorporation. Where soil surface is moist at the time of application and rrull fullows before weed emergence, a: broadcast application should provide adequate weed suppression.

Use the higher rate on fine-textured soils (high in clay or organic matter) and in fields with a history ofhlgh weed populations. .

UPI METRIBUZlN 4Fmay be applied pre- or post- plant incorporated as a tank mix combination with FARGO 4EC. Follow the "Directions for USE" statements on both producllabels.

POST.EMERGENCE APPLICATION: Onepost~emergenceapplication may be made per season, Use 1/410 112 pint of UPI METRIBUZlN 4F per acre on lentils. and spring peas. On. winter peas, use 3/8 to. 112 pint of UPI METRIBUZIN 4F per acre. For suppression of dog fennel, usell2pirit UPI METRIBUZIN4F,.per acre. Apply specified doSS:ge in,20.:or more gallons of water per acre with ground spray equipment or 5 ormore.gall()'ns of water per acre with aerial spray equip,ment. Do not exceed 40. psi with ground spray equipment. Apply as broadcast spray when weeds are small (less than 2 Inches in height or diameter) and before crop is 6 Inches tall. ,.

Temporary chlorosis of the crop may occur. There is an added risk of crop injury if a post-emergence application is made following a previo\ls post-emergence or post plant Incorporated UPI METRIBUZlN 4F application.

Do not apply over very moist soils or wet crop foliage. Do not apply post-emergence within 3 days after periods of cool, wet, or ,cloudy weather or crop injury may occur. .

I .. Do not apply within 24 hours of treatment with otherpesucides.

SPE(iAL PRECAUTIONS (aU applications): Do not apply more than 1 pint of UPI METRIBUZIN 4F per ' acre per year, Crop injury may resultiC crop is unqer stress conqitjons callsed by cold weather, low fertility, disease or irisect damage.

Crop injury may also result if application is followed by heavy rain.

Do not use on coarse-textured. soils, sandy soils, or soils with less than 1.5% organic malter.

Do not apply to "Estin" lentils.

Do not use on clay knobs or,poorly covered subsoils.

Do nbt apply.on'shallow seedlings less than 2 inches deep (pre-emergence only).

Do not apply within 50. days of harvest of peas, or within 75 days of harvest of lentils. Do not g:raze or feed treated vil).es to livestock withln40 days after application.

Maintain continuous spray tank agitationtdk~ep material in suspension. Avoid overlapping and shut off spray booms while turning, slowing or stopping, or crop injury will.occur.

NO'}1E: This treaunent may cause some chlorosis or minor necrosis. Because lentil and pea varieties may vary in tlieit, . susceplibilityto UPI METRIBUZIN 4F, determining crop tolerance prior to adoption l)S a field,scaie pta~ticejssugg!!sted to prevent possible injury. For additional prt!cautions, restrictions, liinitations; and sprayer ciean-up.:informati6nJef~r to' the appropriate sections of this labe!. " .

SUGARCANE Special Precautions

For aerial and chemigation application methods on sugarcane the maximum application rale is 4 pIS. UPI METRIBUZ1N 4F per acre. To assure that spray will not adverSely affectadjacenl sensitive nontarget piants, apply this product by aircraft at a minimum upwind distance of 400 flo from sensitive plants.

UP) Metribuzin 4F Master Label Page 46 of 56

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SUGA~CANE i " \', ,'" , (Hawaii only) , ,

UPI ¥ETiUBUZIN 4F, as~lective herbicide, is effective 'as a pre~~mergence and an earlyposte,mergente ~roa:dcast appiiQation for control of certain grass and broadleaf weeds, When applied as a spot treatment, it also provides excelleht contr?l of perennial grasses and broadleaves,

Ground Application': UPIMETRIBUZIN 4F should be, mix~dby filling the spray tank half full of dean water. Then add the rdcominended amount of UPI METRIBUZIN4F to'suit the total tIlnk capacity and the raJC of applica,tionper acr~ (pref~rably 25 to 35galloris per acre); Complete filling the tank and maintain sufficient agifution,dui'ing mixing ,and,

. spraying to ensure a uniform spray mixture. . . . , '. ., '.

Aerial, Application:' uPlMETRIBU.ZIN 4F is-recommended for use in aerial spray equipmenhs apre~emergence o~, postclTIergence application 'to irrigated sugarcane. Aeriruspray equipment should be caIibratedto appJy:theproper amount ofU~I METRIBUZIN 4F in 7 to 10 gallons of spray mixture per acre.

;

UPI MErRIBUZIN 4Fapplied pre-emergence or postemergence to the sugarcane as a broadcast spray or spot. treatment . will effectively contiol the following when weeds are less than 3' inches in height. . '. " ..

, WEEDS CONTROLLED IN IRRIGATED AND NON·IRRIGATED SUGARCANE

Broadleilves Grasses ,Aruarimth, Spiny (Amaranth us ."PinosUs) Crabgrass (Digitaria spp.) ElIPh6tbia, Wild·(Eupl)qrbia spp:) CiIliiie!lgtass (PanicUlll ~imu!!l) .Firewhed.(Efechtites hleracijoliw;) Plushgrass (Chloris radiata) F1orafPai.nt.b~sh (E111iUa sonochijoUa) :RicegraSs (OryzqpsishY/1UJn6ideJ) Si:lUrge,Garden.{~~jJhorbia hirta) '. Wire grass (Eleusine indica) S{lUrge, Graceful (Euphorbia glomeriferti)

I

WEEDS CONTROLLED IN IRRIGATED SUGARCANE ONLY Broodleaves Grasses

.AmarfU1th, Spleen (Amaranthu.s duhius) Alexandergrass (Brachiaria pkmtaginea) Haole Koa (Leucaena leucocephala) BrisdyFoxtaii (Setaria llenicillata) Hialoa(Waitheriaamericana) Hilahila (Mimosa pudica) Pursl~ne, Common (Portulaca o/eracea) ,Rattlldpod (Crotalariaspectabilis)

j

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WEEDS CONTROLLED IN NON-IRRIGATEDSUGARCANE'ONLY Broadieaves .' Ager~ttim(Ageratum conyzoides) Richardia '(Richardiabrasiliensis) Tarw~d (Cuphea carihag~;iesi.f)

RECOMMENDED BROADCAST APPLlCA TIONS .... SUGARCANE - HAW All ONLY UPI METRIBUZIN REMARKS

, 4F(PtJA)

- ,

-'.'

4 to 8 (112 to 1 gal) (pon-irrigated)

PREEMERGENCE (irrigated and n(}n-irrigated sugarcane): Apply specified dosage per acre as a . broadcast spray to the soil surface. Applic~~()nsshouldbe made Within.two weeks after planting poor to cane emergence or shonly afteremer'g~ncc:::(spike stage),. .,'

; Stp p (1 tp 1-112 gal)

I (irrigated) '!

: 4t08 , pl2 to 1 gal)

5 toIO (J-1I8 to 1-114 gal)

'. . .. , . OR,. . , . EARLy POSTEMERGENCE (Irrigated and nO,n-irrigatedsugarcane): Apply specifieg,dosage .'. per acre as a broadcast spray over the cane. , Application may be delayed along as 4 to 6.we'eks.after plMitiiig proVIded weeds are less ihan Jinchesinhelght .' ,

OR POSTEMERGENCE: Apply specified dosage per acre as a broadcast spray to control weoos prior to "close.in" time when cane shades out the weed. grOwth. SPOT TREATMENT: Apply specified.dosage in 30 to 50 gallons offinished spray per acre, Spot treatments may be used to control weeds in missed· areas, comers of fields, or areas of hard .to control weeds,

NOTE: Do not apply more than 16pt. (2 gal) ofUPI MErRIBUZlN 4F (81b active ingredient) per,acre'per crop cycle regardless 'of the' method of application. The last application may be mooeup to 17 months of harvest. SPECIAL .PRECAUTIONS: Do notuse treated foliage for feed orforage.· .

.UPI lVi,etnbuzin 4F Master Label Page4T6f56

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SUGARCANE (Louisiana and Texas Only)

Pre-emergence and postemergence applications of UPI METRIBUZIN 4F with aerial or ground spray equipment are recommended for contr91 of the following weeds in sugarcane in Louisiana and Texas .

. Bioadleaves Grasses Ama~aiJ!h, Spiny (Amaranthus :~pinosus) BroadleafSignalgrass (Brachiariapiaryphjlla)' Bindwee~i, Field (Convolvulu,~ a"'l!nsis) CraQgrass.(Digitaria spp.) Chitkweed (Cerastium. vulgatuin) Foxtalls (Setaria spp.) . Henbit (LAmium ampl~ic.aule) . Johpsongrass. Seedling (Sorghum hale pense) Lambsquarters (Chenopodium album) Oats, Winter (Avena spp.)

I Londpn Rocket (Si,~mbrium irio) Marestail (Conyzacanadensi's) Mustard, Wild (Brassic:a /caber) Pigw~s (Amaranthus spp.) Purslane (Portulaca oleracea) Sowthistle (Sonchus SjJp.)

! RECOMMENDED APPLICATIONS..., SUGARCANE - LOtrrSIANAANDTEXAS ONLY UPlMETRIBUZIN ., .. ,REMARKS " ) 4FPtI Acre '! )to6 . BROAD.CAST: Apply specified dosage per acre using 20 to 30 gallons of water withgi"ound

equipment or 5 gallonS of w*r wi~ arrcraft equipment 'Apply as a brOlid~ast spr~yduting th~ Fall after planting or to the stubble after. harvest. Make.'a second applicationearlyin.theSpring.

1

1-112 to 3 BAND: Apply speci.fied <Iosage in 10 to 20~gallO. ns of w. ater per acre in a 30 to 36 inch .. band over the row during the Fall after planting or to the. stubble after harvest. Made a second application early in the Spring.

SPECIAL PRECAUTIONS (Louisiana and Texas Only): Do not use· treated foliage for feed or forage .. Use t:}le higher rate on heavy day soil and soil with a high percentage of organic matter. If.necessaty, a third application maY bemaqe in late 'Spring at layby. Do,nqt ~pply withinc;O days Ofhi:!I'vest. . For aer~al~Q ch~llligation applica,tioll J,netho9s on S\lglirc~~th.~ maximuIl1'applicationra~e i84 pts."\JPI METR:!aUZIN 4F per acre., '. . to aSsure thatsptaywlll no~ adversely affect ~djacent sensitive nontarget plantS, apply this prodticfbya'irCtaftat

.' a niiltiriuimupwirtddistanceof 400.fi. from se.nsltive plants.

SUGARCANE (Florida Only)

Postemetgence over-tile-top or directed spray applications of UPI METRIBUZIN 4F are recoinmended for the control ofthefolloWing weeds in sugarc<).Ile in Florida

.Broadleaves Grasses : Amatiirith, Spiny (seedling) (Ainaranthus spiilOsu.~) * Crabgrass, large (Digitiiris.sanguliuilis) Bunefweed (Cr:essle¢'gJ:oundscl)o.(Senecioglah~llus) foxtail, bristlegrass(Seiariamagna) , Cildweed (Gnaphalium spp)G60segrass (Eleuslndndica) PUrslahe(PottUlaca oie~dcea) Pailicum, broaclleif(panic,urrfi:lil.tper,runi)

, .. S~al"pass,Broadleaf(Br.achiariaJ}latyjJbyUa)

*Best control is achieved when applications are made when this weed,is less than 4" iri:dfameter. ~'

, RECOMMENDED APPLICATIONS - SUGARCANE- FLORIDA oNLy UP! METRlBUZ!N 4F (puAcre) REMARKS

2 t04 GROUND APPLICATION: UPIMETRIBUZIN 4F may be used.inone or two applications with a minimum of 14d;lYS between each application. Apj>lywhen weeds are less than 6 inches tall in 10 to 40 gallons of spray mixture per acre. . POSTEMERGENCEBROASCASTORBAND: Apply over th,e top otstub1:Jle oqilant cane while sugarcane is less than 14 inches talL . POSTEMERGENCE DIRECTEJ),§PRA Y: Apply to·sugarC¢'le th.\ltis a mlwmurn·of14 inches tail and before row~dosing. . .

2 t03 AERIAL APPLICA'rIOl'l: Apply when weeds areless than 4inchesuillin5 to 10 gallons of spray mixmreper acre. Apply to stubble or plant cane while tlie sugarcane.ls. less than 14 inches tall.

UP! Mctribuzin 4FMasterLabcl Page 48 of 56

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'UPI ~ETgmUZIN 4FPLUS Atrazine TANK MIX: UElMETRffiUZIN4F"maybeused withatraiine as a pre­,emergence orpostemergence (before row closing) application to sugarcane'. RatesforlJPlMETRffiUZIN4Farel-1/2 to 4 pVacre ,andatrwne 800/0,WP' (4L ) are 2-112 tQ ,5)b£acre (2 to 4 qtlacr~)~ For additional ,information 'on precautipns, instructions, limitations, application; and weeds controlled, refer to this label and the, atrazine label.

, i ' SP;ECIALPREC~UTIPNS (FlQrida OnJ,y): ,Do not use more than 4 pt per acrejn a single growing season. Do noi use on salld soils. Spray contact with sugar:canefoliage fuayresull in minOr leaf margin chlorosisandlor necrosis.

, Donptapply within 60 days of harvest. Do not use treated crop for feed or fOrage. Avoid spray overlaps or vat'iationsin application speed that may result in insufficient or excessive rates of application.

; .

To assure that spray will not adversely affect adjacent sensitive nont'arget piants, apply ,this prod'uct pyaircraft at a minimum upwinddisianceof400ft. from sensitive plants. ' ",

A,eriaIapplication is prohibited. TOl\1ATQES

Apply UPI METRffi UZIN 4F herbiCide with ground eqUipment to seeded and transplanledtomatoes as specified below' under "Recommended Applications". '"

For effective control of grasses and broadleaf weeds with post-emergence applications, apply UPI METRffiUZIN 4~ before weeds arel inch tall. Thorough spray coverage on weed foliage is essential for adequate control with post­emergence applications.

Do nptuse air bl~s( or other higbpresslll~spray equipment to makepost~emergenceapplications of UPI METRIBUZU't 4F., «efer to the ?ppropriate section of ti),is lab~l for ,ad.ditional int()~tionregarding spray ()quipmeIlt, ililiJtioiHates; illW~g, sprayefcleanilp, re~lIictio.ns, contaillet and disposal a.rid 'ca\ltions, ' ' , , ,

For specific application information see the,"General,Information'i sectioniu the front of thisiaheL

i WEEDS CONTROLLED • ~REPLANT'INCORPORATED APPLICATIONS TRANSPLANT TOMATOES ONLY

Broadcast Sprays - 1/2 to IPt UPI METRlBUZ1N4F1Acre Broadleaves Grasses GaIin~oga (Galinsoga spp.) *Goosegrass (Eleusine indica) Lamb'sqUarters (Chenopodium album) *PigWeed"Redroot (A/1Ulrant!ms retroflexus) "'Purs)ane, Common(Portulaca oleracea)

" PrepI~tincoipor!ltedapplicatio~ appli¢ as c1~ecI will suppress fO~tail$, panic;urns, and brunYardgr,ass. UPI l\f!i:TRIBUZIN 4FrtrUliIralin Tank Mix: ,This tank mix coIDi>ination 'applied preplant.incorporated asdirectedonJhis label tvilicorittol the weeds listed above plus those weedSlisterlon the TrlfluraliJi label., ' , ', '

; WEEDS CONTROI,LED;P~ST.EMERGENCE APPLICATIONS ESTABLISHED TOMATOES

For, effective control of weeds with post-emergence applications; apply UPlMETRffiUZIN 4F before weeds are 1 inch talL BtoadcastSprays-1I2 to 1 Pt UPI METRIBUZIN 4F/Acre, , Directed Sprays -1 to 2 Pl UPI METRffiUZIN 4F/Acre Broadleaves Grasses carp~tweed (Mollugo verticil/aui) *Foxtail, Yellow (Setaria glauca) Fumitory (Fumaria officinalis) Goosegrass (Eleusine indica), Galinsoga (Galinsoga spp.) , Plus Weeds Listed Under Broadcast Sprays *J:iIll$.onwe~d~(D(uura stralnonium) *Ladysthumb (Polygonwn persicaria) Lambsquarteis (Chenopodiuf1l album)

,Mustard, Wild (Brassica kabet)

"': .. '~~~,::;:~~J"~:'(

Pigw~eds (Amaranthus spp.) 'Purslane (Po,rtuiaca oleracea) *Ragweed, Common <Ambrosia artefllislijolia)

, *Smartweed, Pennsylvania (Prilygonum pensylvanicum) Toadflax,(Linaria spp.) "'Velvetieaf(Abutilontheophrasn)

... For optimum control ofthe$e weeds, usc the highest rate recOJ,nll1cndcd on the label for the type of app1.i!=aiio!l to be, made. Repeatpost"emergence applications may be neededfor best control.

Post"emergence applications as diIectedon Ulis label will SUWrC,ss barnyru:dgrass and crabgrasS when these weeds are less than 1 inch talL

, UPl Nietrihuzin 4F Ma~ter Lahel l' . ...... ..

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UPIMETRIBUZIN ~F PtlAcn'i*

; 1/2 to 1

112 to J

l,t02 ; ,

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RECOMMENDED BROADCAST APPLICATIONS REMARKS

PREPLANT INCORPORATED· TRANSPLANT TOMATOES ONLY: Apply specified dosage in 10 or more gallons of water per acre as a broadcaSt spray to the soil surface immediiltely before transplanting. Incorporate to a depth of 2 to 4 inches with equipment capable of unifonnly .mixing the chemical iiltothe soil. Thi~applicati6n may beinade alone.ot in a tank,miXcombination wIth , 'trifluralin.e.c; When.transplanting tomatoes, place the root system of the plants below the herbicide ,incorp6nltlOnZoneotinjuryinayoccur., Refer to the trifiuralin label for specific rate of application and for additional precautions and restrictions for tomatoes. ' ' POSTEMERGENCE BROADCAST SPRA Y~ESTABLISHED TOMATOES: Apply specified dosage:in 20 or more gallons of water per acre as a broadcast spray,. or apply in 1/4 to, 3/4 inCh of water (use li4 to il:2 inch of water on sandy soils) per acre as 'a continuous injection in center pivot and lateral move systems or apply in the last 15 to 30 minutes of set in pennanent soil set sprinkler . system.~. One or more applications ~y be applied per use season. Allow at least 14 days between, applications or severe crop injury may occur. For transplanted tomatoes, do not apply until transplants have recovered from transplant shock and new growthis evident. ,Do not apply to tomatOes within 24 hours of application of other pesticides. Do nonank mix with other pesticides. (See "Sp'ecial Precautions" beiow).. POSTEMERGENCE DIRECTEDSPRA Y~ESTABLISHED. TOMATOES: Apply specified , dosage J,n 20 or more gaIionsof\Vater PeI;i1ci:e as a directed spray; Oneot moreapj:>lications milybe applied per ,use seaSon. Allow alleast 14 ,~ys:between application~ or severe.crop injury may occur. Avoid contilctIDgtorilatofoiilige'wlth' spray. This methOd of treatmeiJt is recomil:lend,ed Cor use in " fields with a history of severe weed pressure or in fields.infested;with hard-to-control WeecIS. For transplanted tomatoes. do not appiy until, transplants have recovered from trilnspHuit shock and hew growth is evident.. Do,not apply to .tomatoes within 24 hours of application of other pesticides. (See "S pedal Precautions;' below). When banding, see the appropriate section in the front of this label.

·Use ,the higher rate in fields with a history of severe weed:pressure and for maximum residual weed control.

SPE~IAL PREC~UTIONS (Tomatoes): Do riot apply more than atotal of 2 pints UPI METRffiUZIN 4F per , crop reason.

, Do notapplY the total amount of 2 pt UP! METRIBUZIN4F within a time span ofless than 35 days; except ill the case Of. directed sprays.

I , ' '., Allow ~t least 14 days between applications, regardless of dosage or method of application or severe crop injury may OCCUL Do not apply within 7 days of harvest. Do oorapply within 3 days after periods of cool. wet or cloudy weather, or crop injury will occur.

Do not use bot caps on tomatoes within 7 days before or at any time after application of UPI METRlBUZIN 4F. Do not treat seeded totnatoes until plants have reached the 5 to 6 leaf stage or severe crop injury may occur.

Crop! injury or delay~ ~turitymayresult from pro~cast or directed spray !1.pplicatioos iftomatoes are growing under stress conditions such as periods of drought or cool, wet and cloudy weather preceding application, ' , I

~ '. ~ . . , '. . .. .. , .,,' ...'

For newly introduced to,inato varieties with uilkIlowntolerance to UP! ~TRIBUZIN. 4F, treat only a srilllliareato detertrune if UPI MET:RlBUZIN 4P'pao'!>e usf;!d wit!Wl!tinjury to the crop.' :;. "

; . .' J . . . ·'.='(,~~~·fr·~:;Cri· - -'

DO NOT USE UPI METRIBUZIN4F ON TOMATOES IN KERN COUNTY, CALIF:ORNIA. " ,·",'I<:p,X:::r;'

, CEREALS (Spring and Whiter Barley and Winter Wheat)

UP! ~ETRIBUZIN 4Fherbicide is recommended for control or suppression of certain grasses and broadleaf weeds when ' appli!-xlpost-emergenct! to spring and winter barley or winter wheat UPI METRIBUZIN 4F alone and severaLtank mixture treatments are recom'mended for use in the following states: AR, GA,ID, IL, IN, KS,KY,LA, MS; MO, MT,NV, ' OH, pK, OR. TN, rx, UT, WA.

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Mi~: See the "General Infonilation" s~ctionof this label for specifi~ mixing procedures. When tank mixing, car~iully . foliow the insti:Uctions on this label. Refer to t1ie other product labels registered' for use in barley and winter wheat for additional use directions, rates" weeds controlled. and restrictions.

upI Metribuzin 4FMaster Label Page 50 of 56 '

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, App~iqltl(Ul:' UPI MBTRIBUZIN 4F may b~ applied by aerial or ground applic~tion equipment. Use a ininimum spray volui,Ile of2gpa :byairapd 1 Q gpaby grqu1}d. Uniform spray coverag~ i~ necessary to obtain optimum weed controI~d to, ' minimize pqterttial for (;rop :injuty. Do not ~xceeQr:afus specified on ,this label. Do not' apply UPIMETRIB UZIN' 4F through any type of irrigation equipment "Apply uprMETRIBUZIN 4F when the crop is healthy and actively growing. UPI jVIETRrBUZIN 4F I)1ay be applied more man once per crop season. Allow a ininimulll.of 21 days betwe,en' , applications if wheat is actively growing or allow 45 dayS between applications if wheat is growing in adverse conditions, hasdntered oormancy or is ,stressed duelo frost damage, disease, drought or excessive moi~ture. Do not use on soils containing le~sthanO.75% orgllilic ma~ter. Do not apply inotethan a total Qf16 flpid ounces u:PlMETRIBUZIN 4F (8 ounc~s active ingredient) per,acre per year. On irriga:ted~e~~"dQnot apply more than 0.5 inches of water for the fIrst irrigation; the maximum amoiJnt for each additional irrigalion should riot exceed 1 inch. Allow:a minimumof14 days, between the fIrst irrigation and subsequent irrigations.

'Perf~rmanceF'actQrs: Weed controlniay not be observed for2t04 weeks under normal growth conditions and for 4'[06 weeks under very dry conditions. MoistUre (aUeast,Y2 inch) 'is required within 2 to '3 weeks after application to ,move UPI

, METRIBUZIN4F into the weedrootwne. Lack of adequate moisture after application may result in;poor, or erratic weed' , control. COIltrolor suppression of Its ted weeds is dependent on weed size at time of application: Control or suppression ,may be reduced if broadleaf weeds are taIler than 1 inch or grasses have m,ore than,?)eaves. ", I ' " ',' :; .~." '.:

, . Tan~ Mixtures: UPI MErRIBUZIN 4FIi1ay be tan~ inixed with Ally, Amber, Finese; Gle~ FC, Harinony Extra, 2,4-D, M(:pA, Igran, BanvellBanyel SGF, Bmnate or Buctril herbici,des. A non-ionic ,surfactant cOritaining at least 80% active ingredient may he used in UPI METRIBUZIN 4F tank,mixes with sulfunylurea herbicides (Ally, Amber, Finese, Glean FC and ~armony Extra). Do ,not use a crop oil concentratebr any adjuvant containing vegetable orpetrolenm'oilswith any UPl ,METRrn UZIN 4F mix as crop injury may result. Additional pesticides may also ,be tank mixed with UPI ' MIiTRIBUZIN4F uniess specificaliypmhibiled on~e inix products' labels. In some instances, combina:tions with

, orgahophosphate insecticides may causetemp6raryleafyellowing and/or crop injury, especially whenwidelyflucttiating day/nighttemperatures occur near, application,Alwaysrefer to the other product labeis registered for use on cerea1sfor' additional directions, rates and weed species cOntrolled. Observe, all precautions and liinitafions 00: labeling oiall prOducts usediin mixtures. ' , ' '

Fee4ing Restrictions: Do not graze wheat within 14 days of UPI METRIBUZIN 4Fapplication or harvest gritinwithin 21 days,afterlast application. Do not graze 9rharvest batley before crop maturity. ,For tank mix combihations, follow. the most' restrictive label. ' , '

Special Precautions: Cereal injury...; Crop injury may occur ifUPI METRIBUZIN 4Fis applied: 1. When the crop is under stress such as wint~r kil1;frost 4amage, disease, drought orexcessiye moisture, severe

grazing, or when these conditions follow the applicatJon. " '7. In combination wjth Dwd fertilizer especially with the addition of surfactant.

3. Prior to the growth stage specified on this label. ' , 4. To soils high in lime or sodium; a pRgreater tban 7.7, calcareous,gravelly, thinly covered. or exposed subsoil

'1 areas .. 5. 'To fields where cereal seeds have been planted less than 1 inch deep., 6. To a non-winter hardy wheat or barley variety. ' 7. To a sensitive wheat or barley variety as listed below. 8. To frozen soil or crop stilI in wimer dormancy.

Cereal Rotations Following Potatoes Treated.with UPIMETRIBUZIN 4F: If planting a sensitive cereal variety (listed under the wheat and barley variety tolerance pofil&ri of this label), following potatoes treated with UPI ME1'RIBUZIN 4F orMEI'RIBUZIN containing'products, refer lothe potato section of the UPI METRIBUZIN4F label for special cultural practices to follow.

APPLICA TI'ON RECOMMENDATIONS , ' <. • ".

,upI METRIBlJZIN 4F alo)1e or jn a tallk IIlix with labeled bro;ulIeaf herbicides may beapp}ied by a~rial PI g:rO)J./l4 spray eqlliptnent as.a brqadcasl post-emergence spray.

UPI Metribuzin4FMastetLabel ; ,

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iRECOMMENDED POSTEMERGENCE BROADCAST APPLlCATIONS OF UPI METRIBUZIN4F Crop Soil UPI METRmlJZIN 4F::Rate ,.

Growth Texture (n ozJA) Stage % ORGANIC MATTER REMARKS

0;75 to 2.0 Over 2;0 Coarse 1.5 to 3 1.5 to 4.5 Use these rates on crops with secondary roots smaller than I inch.

2 Leaf To, Medium 1.5 to 4.5 3. t94:.5 For drylaitcl winter wheat (nonirrigated), l!Pply the highest

2 Tiller . tecouunended rate to achieve maximum weed suppression/control. • .Fme 3 to 4.5 3to 6

t CoarSe, 4.5 to 6 6 to 7.5. D9not apply within' 2 weeks after gI'iizing otbrellkii1g ()fwinter 3 Tiller . dormancy .. Apply after the crop is at or'beyond the 3 tiller growth

to Mediurn 6 to 7.5 7.5 t09 . stage,butbeforejointing. Secondary roots should be developed 4 Tiller and'larger than 1 inchJong. Do not apply before 75 days after

Fine 7.5 to 9 7.5 to 9 planting. Over: 4 Coarse· ,6 to 9 7.5 to 12 For dryland winter wheat (nonirrigated),. apply the highest . Tillers recommended rate.to aehievemaximum weed suppressiontCoIitrol.

Medium 6 to 12 1.5 to 12 '. , ". : GEORGIA ONLY: Wheat must be planted before November i 5

Fine 7.5 to 12 12 to 16 in the Piedmont area and. Northern pan of the state, and before Deceniber 1 in the Coastal Plaih area.

WHEATAND Bi\RLEY VARIETAL TOLERA.NCE*

Wheat and barley varieties vary in their toleranCe to uPI METRlBUZIN 4F: Vari~ties below are tolerant to and are recommended for use with Uj:>rMETRIB UZlN 4R: .

WinierWheat: Abe, Arthur, AS 7846, AS 7853, Baker Seed 32, Barbie VI, Basin, Batum, Bayles, Becker, Bmtee V, Buchshot DS 2368, Caldwell, Cardinal, Cashup, Centurk, Cherokee, Cheyenne, Clark, Coker 747, Coker 762, Coker 797, Coker 68~15, Coker 9134, Coker 9543, Coker 9904, Coker 9907, Daws, DB 533W,DB 562W, DB 580W. Dixie 952, Doublecrop, Dusty, Dyna-gro426, Dynasty, ExC?l. Faro, FFR 525W, Florida 302, FS 432. FS 433, FS 435, Gams, Gar:st 64, Ge<,)rgia 100. Genie V, Hatton, Hawk., Hill 81, Howell, Hunter, Hyak, Hyslop, Katie VI, KY 16-2; Larned,Lewis 833, Lewj~in, Lisa, Longhorn, Luke, Madison, Magnum,MaJcom, McDermid, McNair 1003, McNair 1813,Molly;Moro, Ne.elY, Nelson, Newtoll; Norstar,.,Norwin, Nugaines, Oasis, Omega 78, Paha, Peck, Pike, Pipileer 2151, Pioneer 2180; Pion&et 251O,Pionee~ 2545, Pioneer 2548, Ploneer 2550, Pioneer 2552; }>ioneer2555,Pioneer, 2566;, Pioneer 2571, .PiOi),~er 2580;Pione¢t 2684, Qll.an.tui1;l 577, Redwin, Rpcky, Saluda, Sawyer, SC104,Sjouxland, Sprague, Southern Belie, Stilcy: Staili6n, ~tephei1s~ TAM W 101, TAM 105,TE877, TE 2548,TE SR204, Tiber, Tomahawk., Traveler, Tres; Tyee, Tyler;; Verne, Victory, Wakefield, Wanser, Weston, Winalta. Wrangler. . .

Barl~y:. Advance, Boyer, Clark, Compana, Hannchen, Hector; Hesk, Hudson, Lud. Luther, Kamiak,Klages, Olympic; Pirol¥te, Steptoe. and Triumph.

The following cereal varieties are sensitive to UPI METRIBUZIN 4F and are not recommended for use:

Winter Wheat: AT 90W, AT 91W, Arapaho, Baker Seed 33, Century, Cimarron, Coker 833, Coker 916, Coker 983, Coker 9024, Coker 9105, Coker 9323, Choker 9474,Choker 9835, Cboker 9766, choker 9817, FAR 555; Florida 304, Freedom,FS 417, FS 423, FS. 425, FS 430; Gore, Hazen,l-lickory,Jaclcson,)u,lieill, KY -49-'75, 'Linden,Madisbn;Mesa. Mustang, Pacer. Pioneer 2551,Pioneer 21~3, Princeton 733, PP:~;;;o/::?i~.; ~ER216, P~R278, Rose:n, SaYann,ab;Sierra, TAM, 107, TR 101, TR IOU. TR 8822, Tnumph 64.Vona, WlIlgS, WlOndge,Yamhili. . .

, SpriIlglDorum Wheat: Avoid use on Spring wheat and.Durum wheat varieties.

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Barley: Glenn, Morex, Moravian 3, Larker, 'Summit, Bracken, J\nhellser Busch B2tiOland varieties with Morex pare~tage.

Varieties Not Listed: To avoid possible crop injury on any variety not mentioned in this label. contact a UPI representative or herbicide expert for.a varietyTecommendation prior to treatment or treat a small strip ofthe unlisted variety with the. recommended uPlMETRIBUZIN 4F rate.to aspertiincrop tolerance before treating. an entire·field.

* Abbreviated names of vendors: AS (Agseco), AT (Agratechj, DB. (Diener Bros.), FS (GtoWtrlarJ<FS), PI (Pioneer), PER (Hybtitech), SC (I.M. Schultz),TE (Terra), andTR (Terral).' . . . .

UP! Metribuzin.4FMa.~ter Label Page 52 of 56

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Used at recommended rates,UPl METRIBUZIN 4F will control many annual broadleaf weeds. Controlls best when ,:. applied to young, actively growing weeds. Weeds controlled by UPIMETRIBUZIN 4F include:

B i ttercress datchfly, Conical (SaM) Calc}'rweed. (MadwOlt) Chickweed, Common Chickweed. Mousear 'Corncockle Dogferind (Mayweed) Evening Primrose. Cutleaf Falsetlax, Smallseed Fiddleneck, Tarweed Filaree, Redstem Geranium, Carolina Gron'I~ell, spp. Henbit

WEEDS CONTROLLED Knotweed.prostrale LambSquaner; Common Lettuce.~hlers Mustard. Blue Mustard, Wild Pennycress. Field Pepperweed. Virginia Pigweed. spp. Pineappleweed Polemonium, Annual (Jacob's Ladder) Radish. Wild Shepherdspurse Speedwell, lvyleaf Turnip. Wild

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•..•. ..tiPI~TRIBPZIN 4F control of the following weeds varies from poor to excellent depending on time of application, srageOfgro:\Vth at ,applidllioll,.temperaturesandsoil moistUre conditions following treatment. For maximum effect.on these weeds. apply the higheSt .. feeofJlllleridedrate at the earliest growth stage timing for each particular soil type and organic matter. Suppression is areduction in weed . size ~d growth a~ compared to a non-treated area in' the sarnefield.

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WEEDS SUPPRESSED BroadJeaves GraSses Buck\¥heat. Wild* Mustard. Tumble (Jim Barley, Hare (Wild) Brome. Downy* Oat, Wild* Buttercup, spp. Hill) * Barley, Little Brome, Japanese* Rescuegrass* CowcOckle Tansymustard Blackgrass Brome, Ripgut* Whitlowgrass. Spring Kochi;a* Thistle; Russian Bluegrass. Annual Cheat* (vernal) lettuCe,. Prickly Vetch. Winter , Bhiegrass, Bulbous Foxtail. spp:* Windgrass *Usethehighest recomrnendedUPI METRIBUZIN 4F rilte fotmaXimum weed suppression ...

. FOR WEED CONTROL IN A:WHEATIFALLOW/WHEAT ROTATION (Idaho;Oregoll. Utah. and WashIngton Only)

UPI METRIBUZIN 4F may be applie~ to provide weed control dUring the fallow period after wheat harvest or iIi the Spring before winter wheal is planted. Winter wheat can be seeded 4 months (120 days) after Spring application . Mechanicallillage or the application of a contact herbicide may be required to control weeds germinating prior to seeding of winter wheat. Best results will be obtained where straw and. chaff are evenly distributed across the field.

For specific iilformation see the "General Information" section in the fronl of this label.

Where weed growth is presental application time,UPI METRIBUZIN 4F should be applied with Gramoxoneorofu~F i, ' .. ' i

con~ct herbicide; Refer to the other product labelregistcred for. additional direCtions,rate~, and weed ~pecies ~o~irbne~i' , ~ " .,' \>"

WEEDS·CONTROLLED Broadleaves "

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Grasses "Chickweed. Conimon (Stellaria media) Mustard. Treacle (Eyrsimum. Cheaigross (Bromus secalinus) Henbit (IAmium ampiexicau[e) repalldum) Downy Brome (Bromus tectorul1i? *Kochia (Kocliia sCilparia) Mustard. Wild (Brassica kaher) *Wheat. Volunteer (Triticum .YPp.) Lambsquaners (Chenopodium album) Pennycress. Field (fanweed) (Thlaspi Mustard. Blue or Purple (ChorispoT{l arvense) tenella) Pigweeds (Amaranthus spp.) Mustard, Jim Hill (Sisymbrium airissimum) *Russian Thistle (Sa/sola iberica) Mustard. Tansy (Descurainia pinnClla) *Wild Sunflower (Heli'imthus spp.) >I< Note: Since control of these weeds may be varilibledepeIiaing on moistUrefollowiIig application. the higher JabelC4. rmeis recommended. ' " . , .. ,

After Harvest Application (Fall Fallow): . UPI METRIBUZIN '4F may be applied to wheat stubble lifter harv.est intlie Fall. : Apply Ito 1-114 pt per acre br6adcast before weeds emerge. Use higher rate for longer weed c.ontrol orfoy;·weeds desigiualed as requiring the higher rate for control. Rainfall (1/2 inch or more) is necessary for het~icideactivalioil.

UPI Metribuzin 4F Master Label PageS;! of 56

Do nqtplant crops in treated areador at least 10 months following Fall applications.

UPI METRIBUZ1N 4Pmay be applied at 1 to 1-1/4ptper acre as directed above for a Fall application. If other: vegetation is pre~ent at the time of application use a contact herbicide.

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Sprinh Application (Summer Fallow): UPLMETRIBUZIN 4F maybe applied to wheat stubble:in the Spring. Apply 3/4 to 1 pint pei' acre broadcast before weeds emerge in the Bpring .. Use higheuate for longer weed. control or weeds. ' designated as requiring higher rate for control. Rainfall (l/2 inch or more) is necessary for herbicide activation.

Pr~'utions and Restrictio~: Do not graze treated fields. Do not plant Spring seeded cerealsJollowing Fall fallow applications of UPI METRIBUZIN 4F.Where UPT METRffiUZIN 4Fwas applied in the Fall. do not apply UPI MET~UZIN 4F in the Spring. ' ' ,

FOR WEED CONTROL IN A FALLOW ROTATION WITH ,BARLEY AND WHEAT (Colorado. Kansas. Montana. Nebraska,and Wyomfug Only) . '

r,;"VPI ¥ETRmUZIN 4F may be applied to provide.weedcontrol during the fallow period arter wheat or barley harvest or m .• the Spring before'plantirig of Winter wheat or barley. Mechanical tillage or the 'application of a contact herbicide :may be

". 'requi~ed to control weeds germinating'prior to see(ungofWinter wheat or barlt:y.

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For specific application information see the "General Information" section in the front of this label.

Where weed growth is present at application time, UPI METRffiUZIN 4F should be applied with Gramoxone, Roundup, or other 'contact herbicide. Refer to the other product label registered for additional directions, rates, and weed species controlled. Do not plant crops in treated areas earlier than 10 months following Fall applications.

WEEDSCQNTROLLED Broadleaves Grasses, Chickweed, Common (Stel/aria media) Mustard, Tansy (Delcllrainia pimlata) Cheatgtass (BroIlius seCalinus) CoW<;9ckle( Vac<:aija pyr;amidata) Mustard, Treacle, (EYT§(mu.f1I r;epandllm) Downy BrQrne (BC0111us tecloruni) Heilbit (LamiUlilmilpiexicauie) Mustard, Wtld (Bt:assica kabeT) *Foxtail, Green (Setaria Viridis) *K9chia (Kochia scoparia) Pennycfes(Field (fanweed) (Thl!lspi *Whcat;.Volunteer (Triticum spp) Lambsquiu1ers (Chenopodium album) a11!ense) , *Wild Oats (Avena/atua) Mustfrd, Blue or Purple (Chorispora ' Pigweeds (AinaranthuilsjJp'.) tenclla) Russian lhi$de (Sa/sola iberica) Mustard, Jim Hill (Sisymbrium altissimufil) Sunflower (Herianthus spp.)

'" Note: Since control of these weeds may vary depending on moisture following application, use .the higher rate reCommended below

AFT~R HARVESJ' APPLICATION (Fall Fallow): UPI METRIBUZIN 4F may ·be applied to the stubble after harvest in the Fall. Apply 1-114 to 1-112 pt per acre broadcast before \Yeedsenierge. Use the higher rate for longer weed controi or· for weeds designated asrequirmg the :higher rate for controL Rainfall (112 inch or more ) is necessary for herbicide activ~tion. .

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SPRING APpLICATION (5ummerFaUow): UPI MEfRffiUZIN 4F may be applied to the sttibble in the Spring .. Apply 3/4 to 1 pt per acre broadcast before,weeds emerge in the Spring. Use the higherrate for longer weed control or weeds des~glJ'!J~d!as requiring.the higher rate for control. ' RainfaU(1I2 inch or more) is necessary fo,r;!>,«r;!>i,cideactivation. Wheat or barfeycan be seeded 120 days after Spring application.···"""·

Precautions and Restrictions: Do not graze treated fields. Do not plant Spring seeded cereals following Fall applications for fallow. Where UPI METRmUZIN 4F was applied in the Fall, do not apply UPI METRffiUZIN 4F in the spring. '

UP! Metribuzin 4F Master Uibcl Page 54 of 56

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CROP ROTATION RECOMMEND;\:TIONS

'" i 'Waitine Period After UPI METRIBUZIN 4F Herbicide Application· .-

4 Months Alfalfa Forage Grasses Sugarcane Barler Potatoes Tomatoes A~paragus ? Saini'oin Wheat2

Com SoYbeans 8 Months Bailey Lentils Rice

Cotton Peas Wheat 12 Months Other Crops Not Usted (except roOl crops)

18 Monihs Sugar Beets Onions Other. Root Crops 1 Cover crops for soil building or ,erosion control may be planted any time. but do not graze or harvest for food or feed. Stand reductions :mayoccudn some areas.' , 2 Following peas, leIitilsor soybeans.

STORAGE AND DISPOSAL

Do nol conlaIHi'nalewaler. food, orfced by storage or disposal .

Pesticide Storage: Slore in a cool. dry place and in such a manner as to prevent cross contamination with other pesticides, fertilizers. food, or feed. St()re in original container and out of the reach of children. prcferably in a locked storage area. ' . I ' . J '. . . . . . . . ' .

. Handle and. open container ina manner as to prevent spillage. If the container is leaking of material spilled forariy reason or cause, carefully sweep matenal into a pile. Referto Precautionary Statements on label for hazards associated with the. handling of this material. Do not walkthrough spiiled matenal. Dispose of . pesticide as directed .below. In. spill or leak incidents, keep unauthorized people away. For large spills. coiltact CHEMTREC at 1-800-424-9300. ' .

PestiCide Disposal: Wastes resulting from !be use of this product may be disposed of on site or at an approved waste disposal facility.

Container Disposal: Tr.iple rinse (Qr equivalent). Then offer for recycling or reconditioning. or puncture and dispose of in .a s~itary landfill, ()r incineration, or. if allowed by st~te and local authorities, bypUrhing, ,If burned, ~tay out of smoke .

IMPORTANT INFORMATION READ BEFORE USING PRODUCT

CONDmONS OF SALE AND LIMITA TIONOF WARRANTY AND UAB:u:,ITY

NOTICE: Read theentirc Dire.~ti(m~:for Use;and Conditions of Sale and Limitation of Warranty and LiabilHybeforebuY!J;ill!:t,,,:.;: " ,':" or using this product. If the ~'are'no( acceptable,'rerurn the product at once, unopened, and the purchase price,will be"'" .' . , refunded. ,

The Directions for Use of this product should be followed carefully. It is impossible to eliminate all risks inherently associated with the use of this px:oduct. Crop injury, ineffectiveness or other unintended c,:ons~uences may restill b~~use:of

, such factors as manner of use Or application, weather or crop conditions. presence of other materials or other influencing factors in the use of the product. which are beyond the control of United Phosphorous. Inc. or Seller. All such risks shall be assuriled by Buyer and User, and Buyer and User agree to hoid United Phosphorous Inc. and Seller harmless for any claims 'relating to such factors,

United Phosphorus, Inc. warrants that this product conforms to the chemical description on the label andis reasonably fit for . the. pl.Irposes stated in the Directions for U se,subject to the inherent risks referred to above, when used in accordance with· direc?c.msurtder nonnal use conditions. Thi$ warranty does not extend lothe use of this'produi;t conifaryto iabel instructions,

~IMeiribuzin4F Master.Label Page 55 of 56

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. or un~er abnormal conditions or under conditions notreasonably foreseeable to .or beyond the control of Seller or United Phosphorous, Inc., and Buyer and User assUlllethe risk of any such use: UNITED PHOSPHORUS. INC. MAKES NEITfIER . WARRANTIES OFMERCHANTABILITYOROFFlTNESS. FOR A P ARTIClJLAR PURPOSE NOR ANYOTHEK EXPRESS OR IMPLIEDW ARRANIT EXCEPT AS STATED ABOVE. .

To the.extent;aUowed by law. United Ehosphorous.'lnc.or Seller shall noib~.liabie for anyincidentai •. consequential ot: ~ped~' , ';' ,damages resulting from the use or han41ingofthis ·pr04uct. THE EXCLUSIVE REMEDY OF THE USER OR BUYER; AND'THEEXCLUSIVE'UABILITy OF'UNITED PHOSPHORUS, INC, AND SELLER FOR ANY.AND ALL CLAIMS •. LOSSES; INjuRIES OR DAMAGES (lNCLlJpING CLAlMSBASED ON BREACH OF WARRANTY, tONTRAC:f. NEGLIGENCE, TORT. STRICT LIABILITY OR OTHERWISE) RESULTING FROM THE USE. OR HANDLING OF nus PRODUCT SHALL BE, AT THE EI.ECTION OF UNITED PijOSPHOROUS, INC. OR SELLER, THE REPLACEMENT OF THE PRODUCT, OR COMEENSATION LIMITED TO DAMAGES NOT EXCEEDING THE FAIR MARKET PURCHASE PRICE, AND SHALL NOT INCLUDE INCIDENTAL OR CONSEQUENTIAL DAMAGES.

Unit~Phosphorous, Inc. and Seller offer this prO<illct,and Buyer and User accept it. subject to the foreg()il1g conditions of . ~e and limitations of w~ty@d of liability; whichniay not be modified ~x<:ept by written agre~nt. sjgned by the. dt,lly

.""auth~tiZed representative o{Urut¢cig~6Sl?hOrous,lric, ., ',!<" .

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Banv;elis a registered trademark of Velsicol Chemical Corp. Bron~te .and BllCtril are registered trademarks of Bayer Cominandand Conimence ate register~tiademru:ks ()fFMC CoW. Amber. Dual and Jgtanate registered trademarks OfCiba-Geigy. Ally,;Bladex, Canopy. Finesse, Glean and Harmony are registered trademarks ofE.I. duPont de Nemours and Co, Gran}oxone is a registered trademarkofICI Americas: Inc, Freegom, Lasso and Roundup are registered trademarks of Monsanto Co. . Purslfit,Prowl, and Scepter areregisteredtrademarksof~erican CyanaroidCo, Son3}an and Tteflanare registered irademltrks of DowElanco.Products' Co. X-77lis a'J,'egistered trademaikofVaJentUSACotp; .

02/26/04

UPI MetJibuzin 4F Master Label Page 56 of 56

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