4
Unlock Profits From Challenging Feeds ULTIMet™ High- Activity Catalyst Hydroprocessing SPM-UOP-00179 UltiMet Brochure_March 2018.indd 1 3/6/18 2:21 PM

Unlock Profits From Challenging Feeds - uop.com · Unlock Profits From Challenging Feeds ULTIMet™ High- Activity Catalyst Hydroprocessing SPM-UOP-00179 UltiMet Brochure_March 2018.indd

Embed Size (px)

Citation preview

Page 1: Unlock Profits From Challenging Feeds - uop.com · Unlock Profits From Challenging Feeds ULTIMet™ High- Activity Catalyst Hydroprocessing SPM-UOP-00179 UltiMet Brochure_March 2018.indd

Unlock Profits From Challenging Feeds

ULTIMet™ High- Activity Catalyst

Hydroprocessing

SPM-UOP-00179 UltiMet Brochure_March 2018.indd 1 3/6/18 2:21 PM

Page 2: Unlock Profits From Challenging Feeds - uop.com · Unlock Profits From Challenging Feeds ULTIMet™ High- Activity Catalyst Hydroprocessing SPM-UOP-00179 UltiMet Brochure_March 2018.indd

ULTIMet™ High-Activity Catalyst for HydrotreatingHigher activity for higher yields and higher profits

Meeting stringent clean fuel specifications is always challenging, and it can be even more

difficult when processing heavier feedstocks. The new ULTIMet™ hydrotreating catalyst from

Honeywell UOP changes that. Significantly more active than conventional choices, it processes

challenging feeds without the need for additional reactor space or higher pressure.

An Active Addition to the Unity LineupULTIMet is the latest addition to Honeywell UOP’s vast lineup of Unity catalysts. For more than 50 years, hydroprocessing

customers have relied on Honeywell UOP for complete solutions — equipment, licenses, technical expertise and catalysts.

Plus, UOP catalysts are universal and work with a range of equipment. That’s why the complete catalyst selection is called

Unity, and ULTIMet makes a great lineup even stronger.

Achieve MoreOpportunity crudes only provide an opportunity if you can efficiently process them. ULTIMet makes that happen. It’s

Honeywell UOP’s most active hydrotreating catalyst, used in diesel and VGO hydrotreating applications to produce a

higher-quality product while meeting tight environmental regulations.

• Get more profit from difficult feeds

• Go longer between catalyst change-outs

• Operate at higher feed rates to improve utilization

• Increased volume swell

• Works in existing units, so no capital investment is needed

UNITY HYDROTREATING

DEMETALLIZATION CLEAN FUELS PRETREAT

Si DEMET As DEMET Ni/V DEMET FCC GASOLINE NAPHTHA DISTILLATE FCC VGO PRETREAT

HYDROCRACKING PRETREAT

HYT-9110 UF-75 HYT-8109 HYT-2018 HYT-1118 HYT-4118 HYT-5119 HYT-6119

HYT-9119 UF-80 HYT-8119 HYT-2117 HYT-1119 HYT-6119 HYT-5219 HYT-6219

HYT-2118 HYT-9129 HYT-6219 ULTIMet™Now Available

HYT-2119 ULTIMet™Now Available

SPM-UOP-00179 UltiMet Brochure_March 2018.indd 2 3/6/18 2:21 PM

Page 3: Unlock Profits From Challenging Feeds - uop.com · Unlock Profits From Challenging Feeds ULTIMet™ High- Activity Catalyst Hydroprocessing SPM-UOP-00179 UltiMet Brochure_March 2018.indd

Light Cycle Oil (Sulfur = 0.7%, Nitrogen = 1000 ppm, Sp. Gr. = 0.937)

100% HYT-6219

60/40 HYT-6219/ULTIMet80/20 HYT-6219/ULTIMet

Hydr

ogen

Con

sum

mpt

ion,

Scf

/bbl

Product Sulfur, ppm

Light Cycle Oil (Sulfur = 0.7%, Nitrogen = 1000 ppm, Sp. Gr. = 0.937)

Time on Test (Days)

Polya

rom

atic

s, wt

%Ni

troge

n, p

pmSu

lfur, p

pm

4746454443424140393837363534

Test Phase 1 Test Phase 2 Test Phase 3

100% HYT-6219

80/20 HYT-6219/ULTIMet

60/40 HYT-6219/ULTIMet

Light Cycle Oil (Sulfur = 0.7%, Nitrogen = 1000 ppm, Sp. Gr. = 0.937)

100% HYT-6219

60/40 HYT-6219/ULTIMet80/20 HYT-6219/ULTIMet

Hydr

ogen

Con

sum

mpt

ion,

Scf

/bbl

Product Sulfur, ppm

Light Cycle Oil (Sulfur = 0.7%, Nitrogen = 1000 ppm, Sp. Gr. = 0.937)

Time on Test (Days)

Polya

rom

atic

s, wt

%Ni

troge

n, p

pmSu

lfur, p

pm

4746454443424140393837363534

Test Phase 1 Test Phase 2 Test Phase 3

100% HYT-6219

80/20 HYT-6219/ULTIMet

60/40 HYT-6219/ULTIMet

Light Cycle Oil (Sulfur = 0.7%, Nitrogen = 1000 ppm, Sp. Gr. = 0.937)

100% HYT-6219

60/40 HYT-6219/ULTIMet80/20 HYT-6219/ULTIMet

Hydr

ogen

Con

sum

mpt

ion,

Scf

/bbl

Product Sulfur, ppm

Light Cycle Oil (Sulfur = 0.7%, Nitrogen = 1000 ppm, Sp. Gr. = 0.937)

Time on Test (Days)

Polya

rom

atic

s, wt

%Ni

troge

n, p

pmSu

lfur, p

pm

4746454443424140393837363534

Test Phase 1 Test Phase 2 Test Phase 3

100% HYT-6219

80/20 HYT-6219/ULTIMet

60/40 HYT-6219/ULTIMet

Light Cycle Oil (Sulfur = 0.7%, Nitrogen = 1000 ppm, Sp. Gr. = 0.937)

100% HYT-6219

60/40 HYT-6219/ULTIMet80/20 HYT-6219/ULTIMet

Hydr

ogen

Con

sum

mpt

ion,

Scf

/bbl

Product Sulfur, ppm

Light Cycle Oil (Sulfur = 0.7%, Nitrogen = 1000 ppm, Sp. Gr. = 0.937)

Time on Test (Days)

Polya

rom

atic

s, wt

%Ni

troge

n, p

pmSu

lfur, p

pm

4746454443424140393837363534

Test Phase 1 Test Phase 2 Test Phase 3

100% HYT-6219

80/20 HYT-6219/ULTIMet

60/40 HYT-6219/ULTIMet

ULTIMet in ActionULTIMet is designed to work in conjunction with Honeywell UOP’s HYT-6219 hydrocracking pretreat catalyst.

A variety of configurations can be used to remove sulfur and nitrogen and retain cetane levels.

As this chart shows, ULTIMet thrives on

activity with hydrogen in a range of mixtures.

Feed Properties

- LCO

- S = 0.7%

- N = 1000 ppm

- Sp. Gr. = 0.937

During a study of light cycle oil

for hydrocracking, use of ULTIMet

dramatically improved sulfur

removal and API uplift in the

presence of nitrogen.

Feed Properties

- LCO

- S = 0.7%

- N = 1000 ppm

- Sp. Gr. = 0.937

SPM-UOP-00179 UltiMet Brochure_March 2018.indd 3 3/6/18 2:21 PM

Page 4: Unlock Profits From Challenging Feeds - uop.com · Unlock Profits From Challenging Feeds ULTIMet™ High- Activity Catalyst Hydroprocessing SPM-UOP-00179 UltiMet Brochure_March 2018.indd

March 2018

© 2018 UOP LLC. All rights reserved.

Learn MoreFor more information about increasing profits with the Honeywell UOP ULTIMet catalyst, contact your Honeywell representative or visit uop.com.

UOP LLC, A Honeywell Company25 East Algonquin RoadDes Plaines, IL 60017-5017, U.S.A.Tel: +1-847-391-2000

Customized SolutionTo discuss processing objectives for your next catalyst

reload as well as Honeywell UOP’s pilot plant testing

capabilities, reach out to your Honeywell representative.

Time on Test (Days)

API S

G 60

/60F

Der C

et N

oHy

drog

en C

onsu

mm

ptio

n, S

cf/b

bl

Product Sulfur, wt ppm

40

30

20

10

41.5

41.0

40.5

40.0

52

51

50

49

480 1 2 3 4 5 6

0

HYT-621929/31/40 HYT-6219/ULTIMet/HYT-621960/40 HYT-6219/ULTIMet

HYT-621980/20 HYT-6219/ULTIMet70/30 HYT-6219/ULTIMet60/40 HYT-6219/ULTIMet

500

450

400

350

300

250

100 150 200 250 300 350 400 450 500 550 600 650 700

API R

ise

Test Period

180160140120100

80604020

600

500

400

300

200

100

0

6.0

5.5

5.0

4.5

4.030 32 34 36 38 40 42 44 46 48

0

HYT-621980/20 HYT-6219/ULTIMet70/30 HYT-6219/ULTIMet60/40 HYT-6219/ULTIMet

Prod

uct N

itrog

en, w

t ppm

Prod

uct S

ulfu

r, wt p

pm

180160140120100

80604020

600

500

400

300

200

100

0

0

HYT-621980/20 HYT-6219/ULTIMet70/30 HYT-6219/ULTIMet60/40 HYT-6219/ULTIMet

VNRG Diesel (S=0.67%, N=972ppm, API=19.4)

HDN_

RVA

HDN_

RWA

HDS_

RVA

HDS_

RWA

Test Period

160150140130120110100140

130

120

110

100

180

160

140

120100160150140130120110100

30 32 34 36 38 40 42 44 46 48

Cat_IDR1 HYT-6219R2 80/20 HYT-6219/ULTIMetR4 70/30 HYT-6219/ULTIMetR3 60/40 HYT-6219/ULTIMet

Prod

uct S

ulfu

r, wt p

pm

40

30

20

10

0

HYT-621929/31/40 HYT-6219/ULTIMet/HYT-621960/40 HYT-6219/ULTIMet

Prod

uct N

itrog

en, w

t ppm

Prod

uct S

ulfu

r, wt p

pm

Prod

uct S

ulfu

r, wt p

pm

In this straight run diesel study, including

ULTIMet significantly improved sulfur

removal performance and cetane content.

The results were even better for the 60/40

loading of just HYT-6219 and ULTIMet.

Feed Properties

- Straight Run Diesel

- S = 2%

- API = 34.6

- Cetane = 45.8

Test Period

API S

G 60

/60F

Der C

et N

oHy

drog

en C

onsu

mm

ptio

n, S

cf/b

bl

Product Sulfur, wt ppm

40

30

20

10

41.5

41.0

40.5

40.0

52

51

50

49

480 1 2 3 4 5 6

0

HYT-621929/31/40 HYT-6219/ULTIMet/HYT-621960/40 HYT-6219/ULTIMet

HYT-621980/20 HYT-6219/ULTIMet70/30 HYT-6219/ULTIMet60/40 HYT-6219/ULTIMet

500

450

400

350

300

250

100 150 200 250 300 350 400 450 500 550 600 650 700

API R

ise

Test Period

180160140120100

80604020

600

500

400

300

200

100

0

6.0

5.5

5.0

4.5

4.030 32 34 36 38 40 42 44 46 48

0

HYT-621980/20 HYT-6219/ULTIMet70/30 HYT-6219/ULTIMet60/40 HYT-6219/ULTIMet

Prod

uct N

itrog

en, w

t ppm

Prod

uct S

ulfu

r, wt p

pm

180160140120100

80604020

600

500

400

300

200

100

0

0

HYT-621980/20 HYT-6219/ULTIMet70/30 HYT-6219/ULTIMet60/40 HYT-6219/ULTIMet

VNRG Diesel (S=0.67%, N=972ppm, API=19.4)

HDN_

RVA

HDN_

RWA

HDS_

RVA

HDS_

RWA

Test Period

160150140130120110100140

130

120

110

100

180

160

140

120100160150140130120110100

30 32 34 36 38 40 42 44 46 48

Cat_IDR1 HYT-6219R2 80/20 HYT-6219/ULTIMetR4 70/30 HYT-6219/ULTIMetR3 60/40 HYT-6219/ULTIMet

Prod

uct S

ulfu

r, wt p

pm

40

30

20

10

0

HYT-621929/31/40 HYT-6219/ULTIMet/HYT-621960/40 HYT-6219/ULTIMet

Prod

uct N

itrog

en, w

t ppm

Prod

uct S

ulfu

r, wt p

pm

Prod

uct S

ulfu

r, wt p

pm

SPM-UOP-00179 UltiMet Brochure_March 2018.indd 4 3/6/18 2:21 PM