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2006 University of Jyväskylä at Present

University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

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Page 1: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

University of Jyväskyläat Present

Page 2: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

London

Paris

Berlin

MadridRome

Athens

University of Jyväskylä

HUMAN – NATURE –TECHNOLOGY

► founded in 1934

► one of the largestuniversities in Finland

► total income 176.9 million euros

► 7 faculties

► over 15 700 students

► staff about 2 500

Page 3: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

ORGANIZATION

INSTITUTE FOR ENVIRONMENTAL RESEARCH

SENATE RECTOR

ADMINISTRATIVE OFFICE

SEPARATE INSTITUTESFACULTIES

INSTITUTE FOR EDUCATIONAL RESEARCH

UNIVERSITY MUSEUM

UNIVERSITY LANGUAGE CENTRE

CONTINUING EDUCATION CENTRE

OPEN UNIVERSITY

UNIVERSITY LIBRARY

COMPUTING CENTRE

AGORA CENTERCentre for Applied LanguageStudies

5 departmentsFACULTY OF HUMANITIES

Teacher Training School4 departmentsFACULTY OF EDUCATION

FACULTY OF MATHEMATICS AND NATURAL SCIENCES

Konnevesi Research Station4 departments

SCHOOL OF BUSINESS AND ECONOMICS

FACULTY OF SOCIAL SCIENCES2 departments

3 departmentsFACULTY OF SPORT AND HEALTH SCIENCES

CHYDENIUS INSTITUTE –KOKKOLA UNIVERSITY CONSORTIUM

SECRETARIAT FOR THE FINNISHEDUCATION EVALUATION COUNCIL

FACULTY OF INFORMATION TECHNOLOGY 3 departments

Page 4: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

Licentiates and Doctorates 2001–2005

84

6675

6559

109

97106

113 109

0

20

40

60

80

100

120

2001 2002 2003 2004 2005 2004-06

Licentiates Doctorates119

Targeted no. of degrees/Dr.

Page 5: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

Total Funding 2005total 154.7 million €

Other external funding 5%

Budget funding 67%(based on resultsand objectives)

Other Ministry of Educationfunding 3%

Academy of Finland 7%

EU funding 7%Externally funded services 8%

Tekes-projects 2%

Available funding in 2005 176.9 million €(incl. Teacher Training School)

Page 6: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

FACULTIES (STUDENTS, %)1) FACULTY OF HUMANITIES (27)

2) FACULTY OF MATHEMATICS AND NATURALSCIENCES (18)

3) FACULTY OF EDUCATION (14)

4) FACULTY OF SOCIAL SCIENCES (12)

5) FACULTY OF INFORMATION TECHNOLOGY (12)

6) FACULTY OF SPORT AND HEALTH SCIENCES (9)

7) SCHOOL OF BUSINESS AND ECONOMICS (8)

Page 7: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

FACULTY OF MATHEMATICS AND NATURAL SCIENCES

g DEPARTMENT OF BIOLOGICAL AND ENVIRONMENTAL SCIENCES

g DEPARTMENT OF PHYSICSg DEPARTMENT OF CHEMISTRY

gLABORATORY OF APPLIED CHEMISTRYgLABORATORY OF INORGANIC AND ANALYTICAL

CHEMISTRYgLABORATORY OF ORGANIC CHEMISTRYgLABORATORY OF PHYSICAL CHEMISTRYgTEACHER EDUCATION

g DEPARTMENT OF MATHEMATICS AND STATISTICS

Page 8: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

APPLIED CHEMISTRYg WOOD PROCESSING CHEMISTRY

g ANALYTICAL CHEMISTRYg STRUCTURE CHEMISTRYg MECHANICAL PULPINGg CHEMICAL PULPINGg PULP BLEACHINGg PAPERMAKING CHEMISTRY

g OTHER RESEARCH AREASg ENVIRONMENTAL CHEMISTRYg THERMOCHEMISTRY OF BIOMASSg CLEANING CHEMISTRYg SPESIFIC TOPICS FROM INDUSTRY

Page 9: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

JYVÄSKYLÄN YLIOPISTO

DEGREES (Applied Chemistry)

Master’s Licentiate’s Doctor’s

1994-1996 17 3 -

1997-1999 40 10 4

2000-2002 52 11 4

2003-2005 44 7 4

Total 153 31 12

Page 10: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

Various degrees completed at the Dept. of Chemistryduring 1999-2005

Degree A IA O P TE Total

Master’s112

33.5%51 86 22 63 334

Postgraduate(licentiates + doctors)

3338.8%

18 23 10 1 85

A Applied ChemistryIA Inorganic and Analytical ChemistryO Organic ChemistryP Physical ChemistryTE Teachers Education

Page 11: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

g ANNUAL WORLD PRODUCTION OF KRAFT PULP 110 mill. t(about 80 % of the total amount of chemical pulps)

g ANNUAL WORLD PRODUCTION OF KRAFTBLACK LIQUOR ORGANICS 110 mill. t

(lignin 46 mill. t and aliphatic carboxylic acids 50 mill. t)

A HUGE AMOUNT OF A RENEWABLE BIOMASS SOURCE

(bioenergy vs. chemicals)

Page 12: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

g GLOBAL CONSUMPTION OF PAPER AND PAPERBOARD

IN 2005 360 mill. t

(chemical pulps 135, mechanical pulps 60, recycled fiber 125,and fillers etc. 40 mill. t)

IN 2015 450 mill. t

The growth rate in the global consumption per year 2.5 %

The total amount of kraft black liquor in 2015 about 130 mill. t

Page 13: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

TOPICS OF THIS COLLOQUIUM (9 SESSIONS)

g MILLS OF THE FUTURE AND INDUSTRIALPERSPECTIVE

g GASIFICATIONg MODELINGg CHEMISTRY AND REACTIONSg RECOVERY SYSTEM DESIGNg MATERIALS AND CORROSIONg DEPOSITION AND ASH BEHAVIOURg FIRING OF BLACK LIQUOR

Page 14: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

SciFinder ScholarTM 2006 (CAS) (July 28th, 2006)

The following references were found containing the concepts

g ”black liquor” 6298

g ”black liquor” and ”composition” 527

g ”black liquor” and ”utilization” 294

g ”black liquor” and ”chemicals” 1544

g ”black liquor” and ”byproducts” 84

Page 15: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

g ”kraft pulping” 17842(”pulping” 166136)

g ”kraft pulp” 22542(”pulp” 156206)

g ”turpentine” 12805(”kraft turpentine” 73)

g ”tall oil” 9823(”kraft tall oil” 157)

g ”black liquor” 6298(”kraft black liquor” 573)

Page 16: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

g ”black liquor” and ”combustion” 946

(”combustion” 257127)

g ”black liquor” and ”gasification” 343

(”gasification” 39557)

g ”black liquor” and ”biorefinery” 2

(”biorefinery” 160)

Page 17: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

g FAST ANALYSIS METHODS OF BLACK LIQUOR AND

ITS COMPONENTS

(chromatographic vs. spectroscopic methods)

g WOOD vs. NON-WOOD BLACK LIQUORS

g REACTIONS OF ORGANIC MATERIALS DURING

COMBUSTION AND GASIFICATION

g PRODUCTION POSSIBILITIES OF NEW BY-PRODUCTS

(e.g., the biorefinery concept)

Page 18: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

TYPICAL COMPOSITION (%) OF THE ORGANIC DRY MATTER OF WOOD KRAFT BLACK LIQUORS

COMPONENT AFTER PULPING

20 % RECOVERY OF LIGNIN

20 % RECOVERY OF ALIPHATIC ACIDS

LIGNIN 42 37 43

ALIPHATIC ACIDS 46 50 43

OTHER ORGANICS (extractives, carbohydrates, and miscellaneous)

12 13 14

LIGNIN/ALIPHATIC ACIDS 0.9 0.7 1.0

Page 19: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

TYPICAL MATERIAL BALANCE OF WOOD ORGANICS OVER THE KRAFT PROCESS

WOOD EXTRACTIVES UNBLEACHED PULP(100) (< 5) (45 - 55)

%Cellulose 40 -45Hemicelluloses 25 -35Lignin 20 -30Extractives < 5

%Cellulose 60 -75Hemicelluloses 20 -30Lignin < 5

BLACK LIQUOR(40 - 50)

OXYGEN DELIGNIFICATION

ORGANICS(5 - 10)

BLEACHING

%Aliphatic acids 40 - 45Lignin 35 - 45Other organics 10 - 15

Page 20: University of Jyväskylä at Presentwhitty/blackliquor/colloquium2006...UNIVERSITY OF JYVÄSKYLÄ Various degrees completed at the Dept. of Chemistry during 1999-2005 Degree A IA O

2006

UNIVERSITY OF JYVÄSKYLÄ

NUMBER OF PARTICIPANTS

AUSTRALIA 1CANADA 9FRANCE 1NETHERLANDS 1SWEDEN 10UNITED STATES 7FINLAND 63

92 (July 27th, 2006)

ACADEMIC DELEGATES 26INDUSTRIAL REPRESENTATIVES 57

(from mills and research institutes)STUDENTS 9