UMC - REAP - Aluminum_Ismail Khater_Ramon Osorio

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    HafenCity UniversityResource Efficiency in Architecture and Planning

    Urban Material CyclesProf. Kerstin KuchtaProf. Wolfgang Willkomm

    ALUMINIUMMaterial flow analysis of 70kg of a car

    By: Ismail Khater

    Ramn Osrio

    Summer Semester 2011

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    1.Abstract

    The economic and environmental reasons for recycling and reusing materials are vital to be able to

    effectively and efficiently meet the 21st centurys population demands. Aluminium is the third most

    abundant element on the earths crust. Today the use of aluminium is widely spread in countlessindustries. As complex a life cycle assessment could be, this paper describes the material cycle of the

    aluminium content of a car, which is estimated at around 70kg, from the early stages of extraction

    until the re-melting or recycling of the material.

    Table of Contents

    1. Abstract ........................................................ 1

    2. Introduction and Background ...................... 2

    2.1 Life Cycle Assessment ............................. 2

    2.2 History of Aluminium ............................. 3

    2.3 Physical and chemical properties ........... 5

    2.4 Mining and Production worldwide ......... 5

    2.5 Applications in the car ............................ 7

    3. Material Flow processes .............................. 8

    3.1 Mining and production processes .......... 8

    3.2 Use and Life span .................................. 10

    3.3 Disposal and Recycling ......................... 11

    3.4 Material Flow analysis .......................... 13

    4. Discussion ................................................... 14

    4.1 Additional environmental aspects ....... 14

    4.2 Conclusion ............................................ 16

    Bibliography ................................................... 17

    Listof figures

    FIGURE 1: LIFE CYCLE STAGES [5] ................................ ........... 3

    FIGURE 2: PHASES OF AN LCA[5] .......................................... 3

    FIGURE 3:WORLD PRIMARY ALUMINIUM PRODUCTION [7] ......... 4

    FIGURE 6: MINING AND PRODUCTION WORLDWIDE [11] ............. 6

    FIGURE 5: PRIMARY PRODUCTION WORLDWIDE [27] .................. 6

    FIGURE 4:MAIN END-USE MARKETS FOR ALUMINIUM PRODUCTS IN

    EUROPE [7] ................................. ............................. 6

    FIGURE 7:ALUMINIUM SHARE OVER TIME AS PERCENTAGE OF CURB

    WEIGHT [12] ............................................................ 7

    FIGURE 8: BAUXITE MINING [13] ................................ ........... 8

    FIGURE 9: ALUMINA TO ALUMINIUM, HALL-HROULT PROCESS [13]............................................................................. 9

    FIGURE 10: ALUMINIUM PRODUCTION STEPS [18] ................... 10

    FIGURE 11: ALUMINIUM USE AND LIFESPAN [3] ....................... 10

    FIGURE 12: END OF LIFE VEHICLE ALUMINIUM RECYCLING [3]...... 11

    FIGURE 13: ALUMINIUM FLOW CHART [3] .............................. 12

    FIGURE 14: MATERIAL FLOW DIAGRAM, OWN CALCULATION BASED

    ON [4] AND [9] ....................................................... 13

    FIGURE 15: CO2 EMISSION RELATED TO ALUMINIUM PRODUCTION

    WORLDWIDE [19] .................................................... 15

    FIGURE 16: ENERGY USE OF PRODUCTION PROCESSES AND

    THEORETICAL MINIMUM [18] ................................... .. 16

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    2. Introduction and Background

    Aluminium is an important material used in a diverse range of products. It is also known for being

    easily recycled and has many benefits over other metals, such as being lightweight, high strength,

    corrosion resistant and having a high thermal and electrical conductivity. [1] The aluminium industryis an immense part of the global economy of individual nations. Top market industries are

    transportation, packaging, building and construction. [2] Transportation accounts for about 30

    percent of the total aluminium output with a significant annual increase due to its characteristics.

    This paper is focused on the material cycle of the aluminium content of a car, as part of an overall

    material cycle study of a whole car, which is divided by materials and conducted by students of the

    master course resource efficiency in architecture and planning at the HafenCity University in

    Hamburg, as the program work for the course Urban Material Cycles. Through the overall study,

    one can have a comprehensive understanding on the materials required to build a car, and specificallyin this paper on the material flow of Aluminium. In order to have an example throughout this paper,

    the used weight of the aluminium content in a car is 70kg. [3] To be more specific, it is mostly referred

    to a German car, as the European Union is one of the largest aluminium end users worldwide. [4]

    As a lot of associations are dealing with material flow analysis in the form of a life cycle assessment, a

    short description of the concept of it will be explained. After that we will have a look into the

    materials history, physical and chemical properties, as well as its worldwide origins and its

    applications in a car. Next, a more in-depth material flow and its processes will be prescribed, from

    the early mining stages, use phase, to the disposal and recycling of the material. At the end, some

    additional aspects, such as the environmental impact will be discussed, followed by a conclusion.

    2.1 Life Cycle Assessment

    Industries and businesses have started evaluating their environmental impact as their ecological

    consciousness is rising. [4] Current concerns about the natural resource depletion and environmental

    degradation have caused a movement towards greener solutions through more efficient processes.

    Therefore, the environmental performance of these products and their manufacturing procedures

    have become a key issue, and finding ways to better optimize these ways is in focus for many

    companies to help minimize their effects on the environment. A currently known tool to do so is

    called Life Cycle Assessment (LCA), which comes across the entire life cycle of a product. Life Cycle

    Assessment approaches industrial systems to assess its cradle to grave practices. It requires detailed

    analyses of each and every step of a product, starting from its raw materials, material processing,

    manufacturing, distribution, use, repair, maintenance and disposal or recycling. All these stages are

    being evaluated, as they are configured mostly in a linear process and therefore interdependent. By

    counting the impacts during the product life cycle, life cycle assessment provides a complete view of

    the environmental aspects of the product or process and a more accurate image of the true

    environmental tradeoffs in product and process selection. [5]

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    A Life cycle assessments consist of four components, which are systematic and phased. First comes

    the goal definition and scoping, which describes the product and its process and activity. Then comes

    the inventory analysis, which identifies and quantifies the physical use of energy, water and materials

    and the environmental releases as well, such as air emissions and waste and water discharges. After

    that comes the impact assessment. This third phase assesses the environmental effects of the

    outcome of the inventory analysis. The fourth and last step is the interpretation. Here, an evaluationis done for the output results. The following figure is a diagram showing the whole process

    summarized. [5]

    The benefits of conducting a life cycle assessment are plenty. It helps decision makers to be able to

    identify and select the weak points of a product or process and use the outcome information to

    upgrade their businesses. By looking at the whole process, one can prevent or calculate the

    environmental impact transferred through any changes made (e.g., from air emissions to wastewater

    effluent). [5] In this paper the focus is only on the materials flow and quantity and it does not

    represent a comprehensive life cycle assessment, as such an analysis requires a lot of time and

    resources.

    2.2 History of Aluminium

    Despite being the third most abundant element of the Earths crust, the designation of aluminium and

    its identification as a chemical element only dates back to the early nineteenth century. A reason for

    its late discovery is the fact that aluminium never occurs naturally in metallic form. However, the

    history of use of aluminium compounds goes far back in time. Already around 5300 BC, ancient

    Persian potters are thought to have used clay consisting largely of aluminium silicates. Later, other

    ancient civilization such as Egypt and Babylon, but also Romans and Greeks used aluminium salts as

    mordents in fabric dyeing, as astringents for dressing wounds, as well as for cosmetic purposes. [6]

    It was not until 1808 that the metal was given its name by English chemist Sir Humphrey Davy, even

    though still describing an unknown metal at that time. First being named alumium, it was respelled by

    later scientists as the more pleasant sounding aluminium and later changed again to aluminium in

    order conform to the ending of most elements. The first to successfully isolate the metal was Danish

    scientist Hans Christian Oersted in 1825 by reacting aluminium chloride (AlCl3) with potassium

    amalgam, an alloy of potassium and mercury. A few years before, French scientist P. Berthier

    Figure 1: life cycle stages [5] Figure 2: phases of an LCA [5]

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    discovered a hard, reddish, clay-like material containing 52 percent aluminium oxide near the village

    of Les Baux in southern France. After the place of discovery he named it bauxite, todays most

    common ore of aluminium. [7]

    In 1827 Friedrich Wohler in Germany described a process for producing aluminium as a powder by

    reacting potassium with anhydrous aluminium chloride. Later, in 1845, he established many of the

    metal's properties, including its specific gravity (density). It was this discovery of its exceptional

    lightness that boosted scientific research and paved the way for commercial production. However, at

    that time the metals price still exceeds that of gold and platinum, bringing rulers such as Napoleon to

    serve their guests with plates made from aluminium rather than gold. Despite dropping by 90 percent

    in price over the following 10 years due to improved production processes, it was not until 1886 that

    considerable production begins to rise. In this year the two unknown young scientists, Paul Louis

    Toussaint Hroult (France) and Charles Martin Hall (USA) simultaneously invent a new electrolytic

    process, the Hall-Hroult process, which is the basis for all aluminium production today. Following

    that, the first aluminium companies were founded in France, Switzerland and the USA in 1888. In

    1889 Austrian scientist Karl Josef Bayer invented the Bayer Process for the large-scale production of

    alumina from bauxite, and thereby establishing the metals worldwide and multifarious use. [7]

    The real rise however only began after the Second World War. The aluminium industry expanded

    rapidly during the war to meet the need for military aircraft. This expanded production capacity made

    aluminium available for new and renewed markets, including automobiles.

    The use of aluminium in Automotive Industry began nevertheless earlier. Aluminium crankcases were

    used in the end of the nineteenth century in some car models. Even car with a full aluminium body

    was first developed in 1899. What may have been the first AIV (aluminium-intensive vehicle) was

    designed and built in 1923. In 1948, Land Rover started using aluminium outer skin sheets. By the

    time the aluminium content in cars increased rapidly, so that in 2005 the average volume of

    aluminium used in passenger cars was already 131kg and this trend keeps rising. [8]

    Figure 3:World Primary Aluminium Production [7]

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    2.3 Physical and chemical properties

    Aluminium is the most abundant metal in the Earths crust and, after oxygen and silicon, the third

    most abundant chemical element [9]. It constitutes about 8 percent by weight of the Earth's solid

    surface. However, it never occurs naturally in its pure metallic form, as it is chemically too reactive,

    but is found in mineral compounds (silicate and oxide) that are very stable. Aluminium is member of

    the boron group of chemical elements and its appearance ranges from silvery to dull gray, depending

    on the surface roughness. It is nonmagnetic, does not easily ignite and is not soluble in water under

    normal circumstances.

    One of the most important characteristics is its low specific density. Aluminium has about one-third

    the density and stiffness of steel. Due to its light weight, components made from aluminium and its

    alloys are vital to the aerospace industry and are important in other areas of transportation and

    lightweight construction. Another attribute constituting its widespread use is the metals ability to

    resist corrosion due to the phenomenon of passivation. When the metal is exposed to air, a thin

    surface layer of aluminium oxide is formed, effectively preventing further oxidation. The corrosionresistance of Aluminium alloys is however reduced due galvanic reactions with alloyed copper or the

    presence of dissimilar metals.

    Other industrial advantages are its durability with yield strengths of 711 MPa (aluminium alloys even

    range from 200 MPa to 600 MPa) and its softness, which makes it easily machined, cast, drawn and

    extruded. Beyond that, aluminium is highly reflective (approximately 92 percent of visible light and

    about 98 percent of medium and far infrared radiation), making it an important component of silver-

    colored paints and mirror finish. Aluminium is a good thermal and electrical conductor, having 59

    percent the conductivity of copper, both thermal and electrical. It is nontoxic, but nevertheless

    exposure of higher concentrations may lead to serious health effects, such as damage to the central

    nervous system and Dementia. [10]

    2.4 Mining and Production worldwide

    According to the European Aluminium Association, today more aluminium is produced each year than

    all other non-ferrous metals combined. The global production volume of 24,290 million tons of

    primary aluminium in 2010, including about 25 percent from recycled material, makes aluminium the

    second most used metal in the world and the most recycled material [2]. Global consumption of

    aluminium has increased rapidly in the past decades and estimations also predict an upward trend in

    the future. The growing demand especially of the emerging markets in countries such as China and

    India causes a further rise in production and at the same time leads to a geographical shift. Beyond

    that, fuel efficiency and hence lightweight vehicle design becomes an increasingly important factor,

    which leads to an increase of aluminium content in vehicles. [2]

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    How will this development affect the security of supply? Are the global reserves sufficient to meet the

    growing demand? As aluminium is among the most abundant elements of the Earths crust, the fear

    of supply shortage seems unreasonable. Estimations speak of Bauxite resources of about 55 to 75

    billion tons, located in Africa (33%), Oceania (24%), South America and the Caribbean (22%), Asia

    (15%), and elsewhere (6%). Reserves (considering also current economic and technical feasibility) are

    estimated at about 28mio tons, which would be sufficient to maintain supplies for at least the nexttwo hundred years. [11]

    Around 85 percent of all Bauxite mined worldwide goes towards production of aluminium metal. The

    remaining 15 percent is used in chemical and refractory products, as well as different aluminium

    compounds. The top markets for the aluminium industry include transportation, packaging, building,

    and construction. Transportation continues to be the largest market, accounting for 36 percent of the

    total aluminium output (see figure 4). [7] The global Bauxite output in 2010 was 211,000 tons [11].

    The majority of bauxite mining is done in the southern part of the world, largely in developing

    countries, whereas primary production is more focused in Europe and North America (figure 6).

    Figure 4: mining and production worldwide [11]

    Figure 5: primary production worldwide

    [27]

    Figure 6: Main end-use markets for

    aluminium products in Europe [7]

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    2.5 Applications in the car

    Since the oil crisis in the 1970s fuel-efficiency became an increasingly important factor in automotive

    industries. Particularly, the recent rise of energy prices boosts the demand for lightweight design. The

    amount of aluminium content in vehicles is steadily growing in order to keep vehicle weight under

    control, even though the total weight of passenger cars doubled in the past 30 years due to increased

    performance and number of appliances. [2]

    According to the Aluminium Association (2001), the use of automotive aluminium almost tripled

    between 1976 and 1999. The annual growth is expected to continue at a rate of approximately 3.64.5

    kg/vehicle, or about 3 percent, for the near future [12].Today European cars contain on average 130

    kilograms of aluminium castings, sheet and profiles and American cars some 150 kilograms.

    Aluminium has already been applied in a variety of parts, including the engine, body, hood, and front

    end. By far the most aluminium content of passenger cars and light trucks is found in castings for the

    components (61.9%), such as engine blocks, cylinder heads, and manifolds. Another 15.7 percent is

    used in wheels (mostly castings), followed by aluminium foil (12.9%), largely for heat exchangers suchas the radiator. The remaining aluminium applications include exterior trim and interiors (4.6%),

    chassis and suspensions (2.6%), closure panels (1.2%, mostly hoods), body structures (0.7%), and

    bumper systems (0.4%). [2]

    Figure 7: Aluminium share over time as percentage of curb weight [12]

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    3. Material Flow processes

    This section is about the material flow process from its initial stages of mining and production,

    throughout its use and life span, to its disposal and recycling stages. Found in bold letters are the

    main ingredient materials and processes in their order of production.

    3.1 Mining and production processes

    Bauxite As mentioned before, aluminium is the third most abundant metal on the earths crust. It is

    mostly mined from what is called bauxite, which is the reddish ore found right after usually a half

    meter topsoil layer, ranging from three to five meters deep. Since it is found so close to the ground it

    is extracted by a process called open-cast strip mining. [13]By doing this, small red pebbles called

    pisolites are mined. Their diameter has an average of about five millimeter.

    This process requires a lot of earth moving with heavy equipment, [13] which translates directly into

    environmental problems such as erosion and creating dust. Erosion is a major issue because most of

    the mining happens near rainforests. [3] How this is solved is mainly by returning the residues to their

    places and replanting the mined fields. As for the dust creation during the mining process, usually

    water is used on the floor, as well as covers for the transportation vehicles. [13]

    Figure 8: bauxite mining [13]

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    Alumina Through a process called the Bayer, which is a chemical refining process, bauxite is

    transformed into alumina or aluminium oxide (Al2O3). This is the feedstock for the aluminium smelting

    progression. To reduce the transportation costs usually it is done close to the mines. In this process

    caustic soda is used at high temperatures to haul out the alumina, which then is left to settle and

    crystallize. The residues of caustic soda is then recycled and reused for efficiency. Extracted alumina

    ranges from 31 to 59 percent by weight and has an average of 41 percent. Normally, every five tons ofbauxite yield two tons of alumina or one ton of aluminium. Some of the alumina is used not for

    aluminium production, but for other uses such as pharmaceutical, medical or other chemical

    industries. [13]

    Figure 9: alumina to aluminium, hall-Hroult process [13]

    Hall-Hroult Process As for the rest of the alumina, it is converted to aluminium using the Hall-

    Hroult electrolytic process. This is done by dissolving the alumina into molten cryolites (sodium

    aluminium fluoride) inside a large carbon container. Through the lowering of a carbon anode into a

    cryolite and the container lining acting as a cathode, a direct current passes through the electrolyte.

    The current has the characteristics of high ampere and low voltage. In this process the oxygen atoms

    are removed from the alumina through the electrolytic process, causing a reaction with the carbon

    producing carbon dioxide. The molten aluminium is left at the bottom of the container, which is

    regularly removed to a holding furnace to allow the repetition of the process. The aluminium is then

    cast into ingots, rolling slabs or extrusion billets, which are shipped to be processed into their final

    products. [13]

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    The following figure is an illustrative diagram, showing the steps of both new and recycled aluminium

    production.

    3.2 Use and Life span

    Every aluminium product purchased by its consumer has a range of life span, depending on the type

    of product. This lifetime ranges from a few weeks for packaging products like cans to decades such as

    building materials, for example aluminium window frames. Transportation has the most applications

    for aluminium, reaching 70 percent for casting alloys as shown in the diagram. [3] In western europealone, 3.6 million tons of wrought and casting alloys of aluminium were used only in transportation in

    2003. [3] This figure includes cars, aeroplanes, trains and ships. Since aluminium is continously

    replacing steel alloys because of its lighter weight, it is foreseen that the aluminium content in cars is

    rising every year.

    Figure 10: aluminium production steps [18]

    Figure 11: aluminium use and lifespan [3]

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    Putting an exact lifetime for the aluminium content in cars is very difficult. To give an example,

    German cars have an average lifespan within Germany of about 12 years, which is if they get

    dismantled after this use period. Often the case is different, where the cars are being shipped to less

    developed countries, where the cars are being used for a much longer period of time.

    However, aluminium scrap is of very high value compared to other materials as it doesnt lose any of

    its properties by recycling it over and over again. Therefore the incentive for recycling it exists, along

    with the much lower energy requirements than from mining it. About 90 to 95 percent of the

    aluminium in the cars goes back into the loop. [3]

    3.3 Disposal and Recycling

    The recycling of aluminium is of high economic, environmental and social importance. More than half

    of the aluminium used in the European Union is from recycled contents, and this figure is increasing

    constantly [3]. Since bauxite is not mined or easily found a lot in this region, it is of high importance to

    continuously try to reach higher levels of recycling, as well as finding better, more resource efficient

    scrap treatment and recycling processes. Along with that reason comes the high value of aluminium.

    This is not only for environmental and social responsibility reasons, but also for economic reasons,

    such as waste handling and energy preservation. As a rule of thumb, the energy required to recycle or

    remold the aluminium is about 5 percent of the initial energy demand to deal with mined bauxite.

    Collection The first step to be able to recycle aluminium is the collection. The industry tries to

    harvest as much as possible from the scrap metal available. However, with the help of the society and

    authorities, the amount of aluminium collected could increase further. The amount of aluminium

    scrap collected in Europe is 96 percent of the total aluminium used. This high percentage is also due

    to the high tech and efficient collection methods available and used. For vehicles, some aluminiumparts are first removed during the dismantling of the vehicle. Then, the car body is fed into a

    shredder. This results in having a mix of a lot of materials. The first separation process is removing the

    ferrous metals with a magnet, leaving plastics, glass, textiles, rubber and non-ferrous metals. In order

    to separate the aluminium a lot of processes are used. These include the sink-float process, as well as

    an electromagnetic separation. Other process uses laser and x-rays technology to identify the type of

    alloys. [3] Following diagram shows the process of extracting the aluminium content in a car.

    Figure 12: end of life vehicle aluminium recycling [3]

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    Treatment The quality of the scrap is monitored to be able to reduce the adherent materials as

    much as possible. The type of alloys is also of high importance, and therefore there is a separation by

    type as well. [3] Because of the types of melted materials and joints there are small aluminium losses

    during the separation of about 2 to 10 percent. [3]

    Residues There are also some residues from each process of the aluminium production and

    recycling phases. These remain are also reused, recycled or put back into the cycle. The aluminium

    salt slag, which is about 400 kilograms per ton of aluminium, is processed to reusable salt. The

    aluminium oxide is also used for various industries, such as for the production of cement. The filter

    dust, of about 25 kg/ton, as well as the skimmings (25 kg/ton) and furnace lining (2 kg/ton) are

    recycled within the aluminium recycling industry. [3]

    The following diagram shows the overall aluminium material processes.

    Figure 13: aluminium flow chart [3]

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    3.4 Material Flow analysis

    In order to quantify the material flow of aluminium in the automotive industry, a model car

    containing 70kg of aluminium was taken as a base. The following simplified diagram (figure 14)

    depicts the material cycle from mining to recycling stage, considering the main inputs and outputs of

    the different production processes. Although the Anode involved in the production process of primary

    aluminium does not directly contribute to the mass flow of the metal, it was still included as it is a

    main source of fossil fuel consumption. Other resource flows involved, such as water consumption,

    were not considered.

    The diagram shows that to produce 70kg of aluminium car parts, about double the mass of alumina is

    required and almost five times that much of bauxite. Without recycling these proportions would be

    even twice that high, as primary and secondary aluminium production contribute to almost the same

    parts of aluminium semis. The recycled fraction itself consists mainly of scrap derived from

    reprocessing car parts. The minimal loss of around 2,5kg during scrap melting indicates the high

    efficiency of the recycling process.

    The total waste output during all production stages is considerably high. Producing 70kg of aluminium

    car pieces generates almost 100kg of Bauxite residue, consisting of all the material that is not

    dissolved during the alumina extraction (Bayer process). Hereby, a toxic read mud remains that cannot

    directly be recycled nor easily be disposed. The environmental implications related to this and possible

    ways of treatment will be addressed in the following section.

    Furthermore, it is shown that about 37kg of carbon and fossil fuels, mostly derived from coal, is

    needed for anode production, representing half of the weight of the aluminium content in the car.

    Supplementary use of fossil fuels due to energy consumption during the production processes willalso be discussed in the following.

    Figure 14: material flow diagram, own calculation based on [4] and [9]

    STOCK

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    4. Discussion

    In this section the aluminium cycle presented in the previous section is discussed and evaluated. In addition,

    other important aspects that contribute to the overall environmental footprint of the metal are addressed.

    4.1 Additional environmental aspects

    Red mud As described in the previous chapter, by far the largest fraction of solid waste is the

    insoluble residue of the bauxite digestion (Bayer process). The resulting red mud is highly caustic and

    presents one of the aluminium industry's most important disposal problems. It is a mixture of solid

    and metallic oxide-bearing compounds originally present in the parent mineral, bauxite, and of

    compounds formed or introduced during the Bayer cycle. The sludge consists to 30 to 60 percent of

    oxidized iron, causing its red color. Other components include silica, unleashed residual aluminium,

    titanium oxide, as well as different organic compounds. It is a highly saline and alkaline mixture with a

    pH value ranging from 10 to 13 and high ionic strength. [14]

    Red mud cannot be disposed of easily. In most countries where red mud is produced it is pumped into

    open holding ponds, where it is stored for several years until the material is settled and can be

    recovered for future refining or be neutralized. This presents a problem as it takes up land area that

    can neither be built on nor farmed, even when dry. Another common practice of disposal is piping the

    mud into the deep sea, causing pollution of surface and underground water and contributing

    significantly to the overall cost of alumina production. [15]. Other reported environmental impacts of

    bauxite mining and processing include deforestation, increased erosion and disturbance of hydrology

    and natural habitats.

    A typical plant produces 0.3 to 2.5 tons of red mud with each ton of alumina, depending strongly onthe type of bauxite ore. [16] Considering the model car, about 100kg of bauxite residue would be

    generated from 70kg of aluminium content. It is estimated that around 70 million tons of red mud are

    produced worldwide every year [17]. Rapidly increasing aluminium production accentuates the

    rigorousness of the problem.

    Currently, scientific research is searching for new ways of treatment or industrial application of the

    material. Possible fields include metallurgical uses (iron and steel production, titania, alumina and

    alkali, minor constituents recovery), production of building materials (constructional brick, light

    weight aggregates, bricks roofing and flooring tiles, cements etc), catalysis, ceramics (pottery, sanitary

    ware, special tiles and glasses, glazes, ferrites) and other miscellaneous direct uses (in waste water

    treatment, as a filler, as a fertilizer, etc). However, practical application of those methods still remains

    on a very small scale as technical and economic feasibility are still lagging behind. [14]

    Energy consumption A major concern in terms of ecological footprint is the high energy intensity

    of Aluminium production.Electricity costs typically constitute about one-third of the total production

    costs.The worldwide average specific energy consumption is approximately 15kWh per kilogram of

    aluminium produced [18]. In the U.S, the aluminium industry consumes about 5 percent of the total

    electricity produced, in Australia with over 25000GWh even almost 15percent [19].

    http://umc%20-%20ikro%20-%20005.docx/#_Toc306480985http://umc%20-%20ikro%20-%20005.docx/#_Toc306480985http://umc%20-%20ikro%20-%20005.docx/#_Toc306480985http://umc%20-%20ikro%20-%20005.docx/#_Toc306480985http://umc%20-%20ikro%20-%20005.docx/#_Toc306480985http://umc%20-%20ikro%20-%20005.docx/#_Toc306480985http://umc%20-%20ikro%20-%20005.docx/#_Toc306480985http://umc%20-%20ikro%20-%20005.docx/#_Toc306480985http://umc%20-%20ikro%20-%20005.docx/#_Toc306480985http://en.wikipedia.org/wiki/Industryhttp://en.wikipedia.org/wiki/Metalhttp://en.wikipedia.org/wiki/Oxidisedhttp://en.wikipedia.org/wiki/Ironhttp://en.wikipedia.org/wiki/Silicahttp://en.wikipedia.org/wiki/Titanium_oxidehttp://en.wikipedia.org/wiki/PHhttp://en.wikipedia.org/wiki/Kilowatt-hourhttp://en.wikipedia.org/wiki/Kilowatt-hourhttp://en.wikipedia.org/wiki/PHhttp://en.wikipedia.org/wiki/Titanium_oxidehttp://en.wikipedia.org/wiki/Silicahttp://en.wikipedia.org/wiki/Ironhttp://en.wikipedia.org/wiki/Oxidisedhttp://en.wikipedia.org/wiki/Metalhttp://en.wikipedia.org/wiki/Industry
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    The high consumption is primarily related to the smelting process, as it is based on a constant electric

    current that is needed to reduce alumina to aluminium metal by electrolysis (Hall-Hroult Process). It

    requires 46 percent of the total energy consumed during all production stages. Smelters are therefore

    mostly located where electric power is both plentiful and inexpensive, such as the United Arab

    Emirates with excess natural gas supplies and Iceland and Norway with energy generated from

    renewable sources. In addition to consuming a large amount of electricity, this process directlyproduces carbon dioxide (CO2) and under certain conditions other highly potent greenhouse gases.

    Total greenhouse gas emissions can only be estimated considering the sources of energy, which vary

    widely on a global scale (figure 15). In Australia, one of the largest producers of alumina, electricity

    consumption is mostly covered by coal-fired power plants, causing about 2.5 times as much

    greenhouse gas per ton of aluminium as the world average. Internationally, however, coal accounts

    only for about 30 percent, whereas hydropower is the predominant energy source for aluminium

    production. [19]

    However, the potential to reduce the energy consumption is significant. The theoretical minimum

    energy required is three times lower than the energy consumed in current practice (figure 16).

    Current research states that technological improvements could for example reduce energy use for

    smelting by more than 30 percent [18]. Furthermore, it must be pointed out that the recycling process

    requires only 5 percent compared to the energy used for primary aluminium production. Therefore,

    increasing the collection and recycling rates may considerably contribute to reduce the overall energy

    consumption in the aluminium industry.

    In order evaluate the absolute energy balance of a material; the energy use during its entire life cycle

    needs to be considered. As aluminium is light compared to many other alternative materials, it may

    save a lot of energy during its life span. Although a holistic assessment of the total energy / carbon

    footprint was not feasible in the scope of this work, the following chapter will provide a conclusion of

    the aspects covered in this work, and give some recommendations for the future development.

    Figure 15: CO2 emission related to aluminium production worldwide [19]

    http://en.wikipedia.org/wiki/United_Arab_Emirateshttp://en.wikipedia.org/wiki/United_Arab_Emirateshttp://en.wikipedia.org/wiki/Icelandhttp://en.wikipedia.org/wiki/Norwayhttp://en.wikipedia.org/wiki/Renewable_resourcehttp://en.wikipedia.org/wiki/Renewable_resourcehttp://en.wikipedia.org/wiki/Norwayhttp://en.wikipedia.org/wiki/Icelandhttp://en.wikipedia.org/wiki/United_Arab_Emirateshttp://en.wikipedia.org/wiki/United_Arab_Emirates
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    4.2 ConclusionThis paper has highlighted the main features of the aluminium life cycle in relation to ecological and

    sustainable developments. It aims to summarize and give a brief understanding about the metal, in

    relation to the other studied materials, in an attempt to understand the urban material cycles and

    their impacts in a holistic manner, rather than just analyzing separate parts of it.

    Aluminum is seen today in almost every product in our lives and is related to what we eat, drink,

    consume and travel with. When one kilogram of aluminum is recycled 8 kg of Bauxite, 4 kg of

    chemical products and 14 kilowatt-hours of electricity are saved. With the aluminiums characteristics

    of not degrading and indefinite recycling capabilities, wasting it should be avoided as it createsunnecessary impact on the environment, the public health and increases production demands, as well

    as having an energy intensive production process [20]. Therefore, more effort into the recycling

    methodologies should be put more in focus, as well as paying more attention from the public to

    reduce and eliminate planned obsolescence, which means planning or designing a product with a

    limited useful life span, so it will become obsolete or nonfunctional after a certain period of time.

    One could argue that if the market finds better ways of recycling aluminum, certain environmental

    problems such as red mud and excessive energy use could be dramatically reduced when the market

    finds its equilibrium state. Hence, improvement is vital and only possible with the increase of public

    awareness of the realities behind aluminum consumption. This is being done best by the unequivocalmethod of making life cycle assessments, which takes all aspects into consideration, including

    environmental, economical, health and social. This method shows that for example replacing iron

    alloys with aluminum ones have a positive effect on the fossil fuels reduction through having light

    weight goods.

    By doing these analyses, regional and international regulations, as well as activists and the public

    could affect the current industries (production and recycling) with collective efforts, and change them

    into more sustainable operations.

    Figure 16: energy use of production processes and theoretical minimum [18]

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    aluminium.org/iai/stats_new/formServer.as

    p?form=1.

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