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Two Technical Advances in Wet Chemical Scrubbing Technology. Richard Hanson MA MEng CEng MIChemE ERG (Air Pollution Control) Ltd. Introduction | Two Technical Advances. V-tex TM technology Development Process Description Applications and Case studies Zero-effluent scrubbers - PowerPoint PPT Presentation
ERG (Air Pollution Control) Ltd
Two Technical Advances in Wet Two Technical Advances in Wet Chemical Scrubbing TechnologyChemical Scrubbing Technology
Richard HansonRichard Hanson MA MEng CEng MIChemE MA MEng CEng MIChemEERG (Air Pollution Control) LtdERG (Air Pollution Control) Ltd
ERG (Air Pollution Control) Ltd www.ergapc.com
IntroductionIntroduction | Two Technical | Two Technical AdvancesAdvances
V-texV-texTMTM technology technology DevelopmentDevelopment Process DescriptionProcess Description Applications and Case studies Applications and Case studies
Zero-effluent scrubbersZero-effluent scrubbers Process Description Process Description Applications and Case StudyApplications and Case Study
SummarySummary
ERG (Air Pollution Control) Ltd www.ergapc.com
V-texV-texTMTM | Development| Development
Developed in UK by AEA Technology Developed in UK by AEA Technology
Used in difficult applications Used in difficult applications reliability and performancereliability and performance Eg. nuclear industryEg. nuclear industry
V-texV-texTM TM technology used in technology used in ScrubbingScrubbing StrippingStripping Distillation Distillation Mixing Mixing
ERG (Air Pollution Control) Ltd www.ergapc.com
V-texV-texTMTM | Development| Development
V-texV-texTMTM Scrubbing Scrubbing Since early 1990s in UK and Since early 1990s in UK and
Ireland Ireland Mid-late 1990s in USAMid-late 1990s in USA More than 400 systems installedMore than 400 systems installed
Technology is now owned by ERGTechnology is now owned by ERG
What is it…?What is it…?
ERG (Air Pollution Control) Ltd www.ergapc.com
V-texV-texTM TM | Process Description| Process Description
Key features Key features V-texV-texTMTM chamber chamber Tangential gas inletTangential gas inlet Opposed jet spray nozzleOpposed jet spray nozzle Intense mixingIntense mixing Central gas outletCentral gas outlet
ERG (Air Pollution Control) Ltd www.ergapc.com
V-texV-texTM TM | Process Description| Process Description
Opposed jet self-cleaning spray Opposed jet self-cleaning spray nozzle nozzle
Fine droplet spray patternFine droplet spray pattern Induced swirl from tangential gas Induced swirl from tangential gas
flowflow Typical droplet size 100-200 Typical droplet size 100-200 μμmm Large surface area for mass Large surface area for mass
transfer transfer
ERG (Air Pollution Control) Ltd www.ergapc.com
V-texV-texTM TM | Process Description| Process Description
Mass transfer modelsMass transfer models
Traditional packed towersTraditional packed towers Tower diameter = Tower diameter = ff (gas rate) (gas rate) Efficiency = Efficiency = ff (packed height) = (packed height) = ff (HTU) (HTU) HTU = HTU = ff (packing type, liquor rate, gas rate) (packing type, liquor rate, gas rate)
V-texV-texTMTM Chamber diameter = Chamber diameter = ff (gas rate) (gas rate) Efficiency = Efficiency = ff (liquor rate, liquor pressure) (liquor rate, liquor pressure)
ERG (Air Pollution Control) Ltd www.ergapc.com
V-texV-texTM TM | Implications of transfer | Implications of transfer modelmodel(1) Non-clogging(1) Non-clogging No packing to foulNo packing to foul Applications for dirty gas/liquorApplications for dirty gas/liquor Scrubbing with slurriesScrubbing with slurries Reliable performance, lower Reliable performance, lower
maintenance, guaranteed efficiencymaintenance, guaranteed efficiency
ERG (Air Pollution Control) Ltd www.ergapc.com
V-texV-texTM TM | Implications of transfer | Implications of transfer modelmodel(2) Significantly reduced vessel height(2) Significantly reduced vessel height High pseudo-KHigh pseudo-Kgga valuesa values Intense mixing, high turbulenceIntense mixing, high turbulence Gas residence time reduced approx x10 for same scrubbing efficiencyGas residence time reduced approx x10 for same scrubbing efficiency
ERG (Air Pollution Control) Ltd www.ergapc.com
V-texV-texTM TM | Implications of transfer | Implications of transfer modelmodel
ERG Packed Tower Scrubber
V-texTM
Scrubber
Example: Example: 1000 m1000 m33/hr air/hr air HCl removal efficiency HCl removal efficiency
99.5% 99.5%
7.4 m
2.2 m
ERG (Air Pollution Control) Ltd www.ergapc.com
V-texV-texTM TM | Case studies| Case studies
ClCl22 scrubbing scrubbing Chemical industryChemical industry Chlorine scrubbing from process Chlorine scrubbing from process
air streamair stream NaOCl by-product for saleNaOCl by-product for sale
ERG (Air Pollution Control) Ltd www.ergapc.com
V-texV-texTM TM | Case studies| Case studies
HCl scrubbingHCl scrubbing Pharmaceutical industryPharmaceutical industry Hastelloy C276 and ECTFE/PTFEHastelloy C276 and ECTFE/PTFE Pressure and explosion rating Pressure and explosion rating
certifiedcertified >99.5% HCl removal efficiency, >99.5% HCl removal efficiency,
batch scrubbingbatch scrubbing
ERG (Air Pollution Control) Ltd www.ergapc.com
Reactive gas scrubbing + particulate Reactive gas scrubbing + particulate removalremoval Optical Fibre ManufacturerOptical Fibre Manufacturer Removal of HCl and SiORemoval of HCl and SiO22 Scrub liquor contained up to 5% weight Scrub liquor contained up to 5% weight
SiOSiO22 with no blockage with no blockage Constant back pressure improved Constant back pressure improved
optical fibre qualityoptical fibre quality
V-texV-texTM TM | Case studies| Case studies
ERG (Air Pollution Control) Ltd www.ergapc.com
V-texV-texTM TM | Case studies| Case studies Multi-component contaminants Multi-component contaminants
Tobacco ManufacturerTobacco Manufacturer Steam quench/sub-cooling with NHSteam quench/sub-cooling with NH33, VOC and dust scrubbing , VOC and dust scrubbing Scrub liquor contained entrained dust – unsuitable for packed towerScrub liquor contained entrained dust – unsuitable for packed tower
SOSO22 scrubbing ex-incinerator scrubbing ex-incinerator 12,000Am12,000Am33/hr with 5,000mg/m/hr with 5,000mg/m33 SO SO22 Lime slurry scrubbing Lime slurry scrubbing >99.8% removal SO>99.8% removal SO2 2
ERG (Air Pollution Control) Ltd www.ergapc.com
Zero-EffluentZero-Effluent | Process | Process Description Description Vacuum evaporation: application to scrubbingVacuum evaporation: application to scrubbing
Established technologyEstablished technology Process application innovationProcess application innovation System integration – optimisation of capital and operating costsSystem integration – optimisation of capital and operating costs Minimises water usage and effluent disposalMinimises water usage and effluent disposal
Simplified flowsheetSimplified flowsheet Evaporator/condenser circuit, heat pump circuit, effluent circuitEvaporator/condenser circuit, heat pump circuit, effluent circuit
ERG (Air Pollution Control) Ltd www.ergapc.com
Zero-EffluentZero-Effluent | Process | Process DescriptionDescription
Schematic courtesy of H2O GmbH
ERG (Air Pollution Control) Ltd www.ergapc.com
Zero-EffluentZero-Effluent | Process | Process DescriptionDescription Typical Scrubber blowdown 500 litre/hr Typical Scrubber blowdown 500 litre/hr < 40 litre/hr concentrated < 40 litre/hr concentrated
sludge waste + recovery of > 460 litre/hr process water to systemsludge waste + recovery of > 460 litre/hr process water to system Operation at 5kPa and 40Operation at 5kPa and 40ooC C Typically 0.15kW per litre water evaporatedTypically 0.15kW per litre water evaporated
ERG (Air Pollution Control) Ltd www.ergapc.com
Zero-EffluentZero-Effluent | Case study | Case study
Aerospace industryAerospace industry Chromic acid scrubberChromic acid scrubber 200 litre/hr treatment rate200 litre/hr treatment rate 200 g/litre CrO200 g/litre CrO33 commodity recovery commodity recovery Return on investment = 9 monthsReturn on investment = 9 months
ERG (Air Pollution Control) Ltd www.ergapc.com
Zero-EffluentZero-Effluent | Applications | Applications
High water/effluent costs and low energy costsHigh water/effluent costs and low energy costs Feedstock, product and by-product recoveryFeedstock, product and by-product recovery Minimised loading for RO and ion-exchange treatment plantsMinimised loading for RO and ion-exchange treatment plants
ERG (Air Pollution Control) Ltd www.ergapc.com
SummarySummary
Innovations in Scrubbing technologyInnovations in Scrubbing technology
V-texV-texTMTM Solid-laden gas/liquor applicationsSolid-laden gas/liquor applications Space limitationsSpace limitations
Zero-effluentZero-effluent Feedstock/product recoveryFeedstock/product recovery Utility optimisation Utility optimisation