Trend Presentation 2008: SUN CARE Ver. 1.1 Sun Care SUNJIN...Trend Presentation 2008: SUN CARE Ver. 1.1SUNJIN Since 1978 For more information, please visit our home page: or email:

Ver. 1.1Trend Presentation 2008: SUN CARE

SU

NJ

IN Sinc

e 19

78

For more information, please visit our home page: www.sunjinchem.comor email: [email protected] call office tel: 82-31-494-6322(300)or call mobile: 82-11-9920-1454

2008.7.1

SUNJIN CHEMICAL CO LTDMicro Beads, Nano MaterialsSurfactants For Cosmetics, Films, Paints, Plastics

Sun Care with elegant feel and transparency like skin care

SUNJINPage 1

EU regulation about UVA protection

UVB ProtectionSun Protection Factor minimum 6. Only 8 defined SPF values allowed

UVA ProtectionLevel of UVA protection (measured by in vivo or in vitro methods) at least 1/3 of labelled SPF. (UVA label can be used to highlight achievement of protection level)

Critical WavelengthAdditional criteria, minimum of 370nm to ensure broad band protection

All products need to comply by 2009, at which point it is expected to be treated as a law.

Products that do not comply with these requirements will not be regarded as ‘Sunscreen Products’

EU Commission Recommendation of 22 September 2006 on the efficacy of sunscreen products and the claims made relating thereto

SUNJINPage 2

Relative UVA parameters

SUNJINPage 3

Relative UVA parameters

SUNJINPage 4

Remarkable Sun Care Products in the market

SPF50PA+++

Water in Oil Oil in Water

SPF50PA+++

SPF40PA+++

SPF50PA+++

SPF50PA+++

SUNJINPage 5

Evaluation: SPF/PA by in vitro

All data hereafter measured at the same date in February, 2008 by the same operator at the same sample preparation condition to have the correct comparison SPF/PA of the

samples

SUNJINPage 6

Evaluation: Transparency

NIPPON DENSHOKUCOLOR METERZE 2000

W: White IndexHigher White index means less transparency

12.5㎛ draw down With applicator

Measure transparencyWith color meter

SUNJINPage 7

SHISEIDO Anessa SPF50 PA+++

SPF 33.4, Boots Star Rating 3Critical Wavelength 370.3

White Index=24.1:Very Transparent

Active Ingredients

1. Ethylhexyl methoxycinnamate

2. Octocrylene

3. Zinc oxide

4. BMDBM

5. Ethylhexyl TRIAZONE

W/O SPF 50 PA+++

SHISEIDO Anessa

W*=24.1

W*: White Index

SUNJINPage 8

Biotherm Homme SPF50, PA+++

Active Ingredients

1. Terephthalylidene dicamphorsulfonic Acid


3. Drometrizole trisiloxane

4. Titanium dioxide

5. Benzophenone-3

6. Phenylbenzimidazole sulfonic Acid

SPF 38.7 Boots Star Rating 3Critical Wavelength376.8

White Index=25.7Very Transparent

O/W SPF 50 PA+++

Biotherm Homme

W=25.7

SUNJINPage 9

THE FACE SHOP(KOREAN) Active White SPF50, PA+++

Active Ingredients


2. Ethylhexyl Salicylate

3. Methylbenzylidene camphor

4. Isoamyl p-methoxycinnamate

5. BMDBM

6. Titanium dioxide


White Index=32.4A bit White

O/W SPF 50 PA+++

더페이스샵 Active White

W=32.4

SUNJINPage 10

LÒREAL Solar Expertise SPF40, PA+++

Active Ingredients

1. Octocrylene

2. BMDBM

3. Titanium dioxide




White Index=34.6White

O/W SPF 40 PA+++

LÒREAL Solar Expertise

W=34.6

SUNJINPage 11

Biotherm Sun50, SPF50, PA+++

Active Ingredients

1. Octocrylene

2. Titanium dioxide


4. BMDBM



White Index=40.0Very White

O/W SPF 50 PA+++

Biotherm SUN50

W=40.0

SUNJINPage 12

Trend Presentation

High SPF, PA but should be transparent…

HOW?

SUNJINPage 13

KEY UV FILTERS

Grade Function UV FILTER Composition MATRIX

BMDBM (Avo Benzone) 31%

2-Ethylhexyl 4-methoxycinnamate 7%Hybrid ABOMC UVA + UVB PMMA 62%

2~712 nmTiO2 30~40% & Silica 60~70%SUNSIL-Tin40

Size of silica bead (㎛)

Crystal size of TiO2DescriptionsGrade

DisodiumSulfosuccinamate

water40nm / 45~50% / alkyl silaneSUNCLEAR Z50AQX

DispersantMediaZNO crystal size/content/surface treatment

Grade

40Alkyl SilaneZinc OxideSUNZNO-NAS

Crystal size(nm)Surface treatmentDescriptionsGrade

1. Hybrid ABOMC: Chemical UV filters inside PMMA bead

2. SUNSIL Tin40: TiO2 inside Silica bead

4. Z50AQX: Alkyl silane treated ZnO inside water

3. SUNZNO-NAS: Alkyl silane treated ZnO

SUNJINPage 14

W/O SPF 50 PA+++ SUN Cream

SUNJIN Formulation

Transparent Sun Cream, W/O type - 080111

Hybrid ABOMC provides excellent transparency and High protection of UVA

No Ingredients % INCI Name

Water 34.1 Aqua

Glycerin 98% 4.0 Glycerin

1,3 – BG 2.0 Butylene glycol

NaCl 0.5 Sodium chloride

Mehtyl paraben 0.2 Methyl paraben

Phenoxy ethanol 0.3 Phenoxy ethanol

KF-995 15.5 Cyclomethicone

Tegosoft DEC 5.0 Diethylhexyl carbonate

Finsolv-TN 4.0 C12-15 Alkyl benzoate

Abil EM-90 2.0 Cetyl PEG/PPG-10/1 dimethicone

Normcort HK-G 1.0 Clyceryl behenate/eicosadioate

Bentone 38 1.0 Quaternium-18 hectorite

SUNGEL D20 4.0 Dimethicone vinyldimethicone crosspolymer and dimethicone

Arlacel 83 0.5 Sorbitan sesquioleate

Parsol MCX 7.0 Ethylhexyl methoxycinnamate

Hybrid ABOMC50_31_7 6.0 PMMA/Avobenzone/Ethylhexyl

methoxycinnamate

Parsol EHS 3.0 Ethylhexyl Salicylate

Parsol 5000 2.0 4-methylbenzylidene camphor

SUNSIL-Tin40 5.0 Silica & Titanium dioxide

SUNZNO-NAS 3.5 Zinc oxide & alkyl silane

C

Tocopheryl acetate 0.1 Tocopheryl acetate

21 Fragrance 0.3 Fragrance

B

A

SUNJINPage 15

Active Ingredients


2. Hybrid ABOMC50_31_7

(BMDBM + Ethylhexyl methoxycinnamate)



5. SUNSIL-Tin40 (Silica & Titanium dioxide)

6. SUNZNO-NAS (Zinc oxide & alkyl silane)


White Index=19.7Truly Transparent

W=19.7

W/O SPF 50 PA+++

SUNJIN

W/O SPF 50 PA+++ SUN Cream

SUNJINPage 16

Summary: Water in Oil

W=19.7

W/O SPF 50 PA+++

SUNJIN

W/O SPF 50 PA+++

SHISEIDO Anessa

W=24.1

SPF 39.3 Boots Star Rating 3C.W. 378.7

White Index=19.7Truly Transparent

SPF 33.4, Boots Star Rating 3C.W. 370.3

White Index=24.1:Very Transparent

SUNJINPage 17

O/W SPF 50 PA+++ SUN Cream

SUNJIN Formulation


Transparent Sun Cream, O/W type - 080213

Procedure1. Mix all materials in Phase A at 75 ℃2. Mix all materials in Phase B at 75 ℃3. Slowly add Phase A into Phase B with

homogenizer(2500 RPM)4. Cool down5. Add phase C into 4 with homogenizer(2500 rpm)6. Add phase D into 5 4 with homogenizer(2500 rpm)7. Cool down

No Ingredients Contents INCI Name

Cetiol LC 1.5 Coco-Caprylate/Caprate

TSF 405 3 Cyclomethicone

Salacos 99 1 Isononyl Isononanoate

KALCOHL 6870 2 Cetyl alcohol

Aracel 165 2 Glyceryl monostearate/PEG-100 Stearate

Tween 60 1.7 Polysorbate 60

Emersol 7036NF 1 Stearic acid


Parsol EHS 4 Ethylhexyl Salicylate

Parsol 5000 3 4-methylbenzylidene camphor

Vegewax 70 1 dHydrogenated Vegetable oil

PP 0.1 Propyl Paraben

1,3-BG 6 Butylene glycol

5% Veegum 25 Magnesium aluminum silicate

Water 20 WATER

DC2501 WAX 1 Dimethicone copoyol

MP 0.1 Methyl paraben

Hybrid ABOMC50_31_7 9 PMMA/Avobenzone/Ethylhexyl methoxycinnamate

SUNSIL Tin 40 5 Silica & Titanium dioxide

Sunclear Z50AQS 7 zinc oxide

Sunclear T40AQS 0 Titanium dioxide

perfume 0.1 Perfume

extract 0D

A

B

C

In vivo proven

formula

SUNJINPage 18

Active Ingredients


2. Hybrid ABOMC50_31_7

(BMDBM + Ethylhexyl methoxycinnamate)



5. SUNSIL-Tin40 (Silica & Titanium dioxide)

6. SUNCLEAR-Z50AQS (Zinc oxide)


White Index=29.8Transparent

O/W SPF 50 PA+++

SUNJIN

W=29.8

O/W SPF 50 PA+++ SUN Cream

SUNJINPage 19

O/W SPF 50 PA+++

THE FACE SHOP Active White

W=32.4

O/W SPF 50 PA+++

Biotherm SUN50

W=40.0


SPF 39.8 Boots Star Rating 5C.W.385.1

Summary: Oil in Water

O/W SPF 50 PA+++

SUNJIN

W=29.8

O/W SPF50 PA+++

Biotherm Homme

W=25.7O/W SPF 40 PA+++

Lòreal Solar Expertise

W=34.6



SPF 36.1 Boots Star Rating 5C.W.383.4

SUNJINPage 20

W/O SUN LOTION: SPF 50, PA+++

SUNJIN Formulation

Transparent Sun Lotion, W/O type - 080707

Procedure1) Mix all materials in Phase A at 75 ℃2) Mix all materials in Phase B at 75 ℃3) Slowly add Phase A into Phase B with

homogenizer(2500 RPM) 4) Cool down5) Add phase C into 4 with homogenizer(2500rpm)6) Add phase D into 5 4 with homogenizer

(2500rpm)



Water 34.1 Aqua




A










B



methoxycinnamate



C


D Fragrance 0.3 Fragrance

ABOMC L/N : 08074001(6%)

SUNJINPage 21

Active Ingredients

1. Ethylhexyl methoxycinnamate : 7%

2. Ethylhexyl Salicylate : 5%

3. Hybrid ABOMC : 6%

4.Tin 40 : 3%

5. ZnO-NAS : 3.5%

W/O SPF50, PA+++ : SPF/PA Value Test Result

SPF 31.88UVA:UVB=0.956:1 = 1: 1.05 Boots Star Rating 5Critical Wavelength 383.4

SUNJINPage 22

W/O SUN LOTION: SPF 35 PA++

SUNJIN Formulation

Transparent Sun Lotion, W/O type – 080707-2


homogenizer(2500 RPM) 4) Cool down5) Add phase C into 4 with homogenizer(2500rpm)6) Add phase D into 5 4 with homogenizer

(2500rpm)



Water 36.1 Aqua




A










B



methoxycinnamate



C


D Fragrance 0.3 Fragrance

ABOMC L/N : 08074001 (3%)

SUNJINPage 23

Active Ingredients




4.Tin 40 : 3%

5. ZnO-NAS : 3.5%

W/O SPF 35 PA++ : SPF/PA Value Test Result

SPF 23.2UVA:UVB=0.834:1 = 1: 19Boots Star Rating 4Critical Wavelength 380.1

SUNJINPage 24

O/W SUN LOTION: SPF 50 PA+++

SUNJIN Formulation


Transparent Sun Lotion, O/W type – 080707-3







Tween 60 1 Polysorbate 60


Parsol MCX 7 Ethylhexyl methoxycinnamate


Vegewax 70 0.5 dHydrogenated Vegetable oil




Water 33.7 WATER


Phenoxy Ethanol 0.1 Methyl paraben

Hybrid ABOMC 6 PMMA/Avobenzone/Ethylhexyl methoxycinnamate

SUNCLEAR-Z50AQX 7 zinc oxide

Sunsil-Tin40 3 Titanium Dioxide

perfume 0.1 Perfume

A

B

C


homogenizer(2500 RPM) 4) Cool down5) Add phase C into 4 with homogenizer(2500rpm)

ABOMC L/N : 08074001 (6%)

SUNJINPage 25

Active Ingredients




4.Tin 40 : 3%

5. SUNClear-Z50AQX : 7%

O/W SUN LOTION: SPF 50 PA+++

SPF 32.26UVA:UVB=0.91:1 = 1: 1.09Boots Star Rating 5Critical Wavelength 382.7

SUNJINPage 26

O/W SUN LOTION: SPF 35 PA++

SUNJIN Formulation


Transparent Sun Lotion, O/W type – 080707-4







Tween 60 1 Polysorbate 60


Parsol MCX 7 Ethylhexyl methoxycinnamate


Vegewax 70 0.5 dHydrogenated Vegetable oil




Water 34.7 WATER


Phenoxy Ethanol 0.1 Methyl paraben

Hybrid ABOMC 3 PMMA/Avobenzone/Ethylhexyl methoxycinnamate

SUNCLEAR-Z50AQX 7 zinc oxide

Sunsil-Tin40 3 Titanium Dioxide

perfume 0.1 Perfume

A

B

C


homogenizer(2500 RPM) 4) Cool down5) Add phase C into 4 with homogenizer(2500rpm)

ABOMC L/N : 08074001 (3%)

SUNJINPage 27

Active Ingredients




4.Tin 40 : 3%

5. SUNClear-Z50AQX : 7%

O/W SPF 35 PA++ : SPF/PA Value Test Result

SPF 25.8UVA:UVB=0.8:1 = 1: 1.25Boots Star Rating 3Critical Wavelength 380

Documents

Trend Presentation 2008: SUN CARE Ver. 1.1 Sun Care SUNJIN...Trend Presentation 2008: SUN CARE Ver. 1.1SUNJIN Since 1978 For more information, please visit our home page: or email: