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8/17/2019 Training Module 1 Updates 10.26.2012
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Aftertreatment Basics
Module 1
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2
Agenda
1. Emission Overview
2. PM Reduction Technology
a !iesel O"idation #atalysts
$ !iesel Particulate %ilters
&. 'O" Reduction Technology
a (elective #atalytic Reduction
$ Ammonia (li) #atalyst * AMO+
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,hat drives the need for aftertreatment-
Regulated Diesel Emissions
Particulate Matter (PM)
Made u) of #ar$on (oot /#0 Ash0 Organic material
sul)hates
,orsens )ree"isting res)iratory conditions such as
asthma and allergies
Hydrocarbons (HC)
(ome have irritating odor0 to"ic and*or carcinogenic
#ontri$ute to )hotochemical smog
Carbon Monoxide (CO)
#olorless0 odorless and tasteless gas
To"ic in high concentrations
&
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,hat drives the need for aftertreatment-
Oxides of Nitrogen (NOx)
Made u) of colorless nitric
o"ide /'O and reddish$rown0
very to"ic and reactive nitrogen
dio"ide /'O2
#ontri$ute to )hotochemical
smog and acid rain
3
Greenouse Gas (GHG)
#om)rised of #ar$on !io"ide
/#O20 Methane /#430 'itrous
O"ide /'2O0 %luorinated
5ases
5ases that tra) heat in the
atmos)here raisingtem)eratures
Original source6 e)a.gov
Smog
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5lo$al Emission Regulations E")anding
7
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Emissions Alignment
#ummins #onfidential8
On4ighwayOff4ighway
EPA 299:
EPA 2992
EPA 2919
EPA Tier & 2997
EPA Tier 3 ;nterim 2911
EPA Tier 3 %inal
2913
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PM RED!C"#ON "ECHNO$OG%
:
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!iesel O"idation #atalyst /!O#
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PM reduction )roduct
%lowthrough su$strate
Made of cordierite or metal
'o maintenance necessary
(u$strate is coated with )reciousmetals
Platinum /Pt and Palladium /Pd ascatalyst
Ena$les conversion at a lowertem)erature
;n general0 increasing Pt increases
conversion efficiency
#om)ati$le with >?(! and 17 PPM 799 PPM sulfur diesel fuels
,hat is a !O#-
Light seen through
substrate paths
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Provides @=9 reduction of #O0 4#
Provides 27 79 reduction of PM
Removes (olu$le Organic %raction of PM )article
Promotes )assive regen of !P% $y creating 'O2
Enhances com$ustion of diesel fuel in the e"haust stream togenerate heat for active regen of !P%
Enhances )erformance of (#R catalyst with creation of 'O2
,hat does a !O# do-
19
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!O# (u$strate Material #om)arison
Caracteristic Cordierite Metallic
Thermal #onductivity ?ower 4igher
(trength ?ower 4igher
,all Thicness 3 to 7 mil /199127 Cm &979 Cm
#ost ?ower 4igher
,eight ?ower 4igher
11
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!iesel Particulate %ilter /!P%
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,hat is a !P%-
PM reduction )roduct
,all flow filter
Every other channel is closed0 forcing e"haust gas
through walls of filter
Made of cordierite or silicon car$ide
(u$strate is ty)ically coated with
)recious metals
Platinum /Pt as a catalyst
Palladium /Pd as catalyst
ReDuires >?(! at 17 PPM
1&
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,hat does a !P% do-
Porous ceramic walls ca)ture
soot and ash from e"haust (oot is removed $y )eriodic
regeneration /active * )assive
Ash accumulates0 reDuiring !P%
removal and maintenance
Provides @=9 PM reduction
Tra)s #ar$on (oot0 Ash and
(olu$le Organic %raction of
)article
13
Clean
Exhaust
PM /
Ash
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,hat is Ash-
;ncom$usti$le material that can only $e removed $y cleaning
?ow density ash )lug near outlet of filter
4igh density ash layer on wall thicness increasing from inlet to
outlet
17Source: Corning
# n
l e t
O u
t l e t
%low
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,hat is Regeneration-
Process of removing accumulated soot $y conversion into
harmless #O2
Two ty)es of regeneration6
&cti'e regeneration
ReDuires tem)erature @799F#
Tem) achieved $y engine management0 dosing diesel fuel into e"hauststream or alternative heat source0 eg. $urner
Passi'e regeneration0 ena$led $y !O# ReDuires 1
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Active Regen
1:
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Passive Regen
1<
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!P% (u$strate Material #om)arison
97*9=*181=
Caracteristic Cordierite ilicon Carbide
Heat Caacity ?ower 4igher
"ermal Conducti'ity ?ower 4igher
Heat u * Cool Do+n Rate (lower %aster
"ermal Durability Moderate 4igher
,lo+ Restriction ?ower 4igher
oot Mass $imit ?ower 4igher
&s Caacity Moderate 4igher if asymmetric cellstructure used
Cost*liter ?ower 4igher
i-e (for same alicationand duty cycle)
?arger 17 &9 smaller
More
Ro$ust
(iGe
#ost
Benefits
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NO. RED!C"#ON "ECHNO$OG%
29
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21
(elective #atalytic Reduction /(#R%undamentals
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,hat is (#R-
#hemical )rocess in which to"ic 'O" is converted to
harmless '2 and 42O Reductant6 Ammonia /'4&
#atalyst6 #o))er Heolite /#uH or ;ron Heolite /%eH or Ianadia
%low through su$strate0 no cleaning necessary
ReDuires >?(! /J79PPM
Ammonia is generated $y the use of liDuid urea /nown as
!iesel E"haust %luid /!E% or AdBlue
22
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2&
4ow does (#R wor-
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'onto"ic solution of &2.7 >rea and 8:.7 ,ater
>sed to deliver Ammonia /to"ic to (#R catalyst
Known as AdBlue in Euro)e
#oncentration ratio with lowest freeGing )oint /11F#
Eutectic solution concentration does not change withfreeGing /)artial freeGing * thawing of vehicle tan
,hat is >rea or !iesel E"haust %luid-
23
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(#R #atalyst Material #om)arison
27
Caracteristic /anadia ,e01eolite Cu01eolite
$o+ "emeratureNOx Con'ersion
?ower ?ower 4igher
Hig "emeratureNOx Con'ersion
?ower 4igher Moderate
NH2 torage ?ower 4igher 4igher
Cost ?ower Moderate 4igher
3ere !sed4 (#Ronlysystems Euro ;I * I0
Tier 3%0EmergingMarets
4igh e"hausttem)eraturese")ected
ty)ically witha !P%
Both cool and hote"hausttem)eratures
e")ected EPA2919*&0 Tier 3%0Euro I;
Clic5 ere for more information
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,hat is a ,ashcoated (#R (u$strate-
#ordierite su$strate is coated with a thin layer called
washcoat
,ashcoat is made u) of catalyst
4igh mechanical strength
4igh melting )oint /@1&99#
28
#atalyst
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,hat is E"truded (#R-
(u$strate and catalyst are same material0 i.e. no
cordierite $ase Manufactured via the )rocess of e"trusion
#ontains more catalyst )er liter of su$strate
;ncreased (#R reaction L ;ncreased 'O" conversion
Ena$les better fuel economy
;ncreased de'O" efficiency ena$les u) to 79 length
reduction of (#R su$strate
2:
#atalyst
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(#R (u$strate #om)arison
2<
3ascoated Extruded
NOx Con'6 er liter ?ower 4igher ubstrate lengtfor gi'en DeNOx 7
+ inches +*2 inches
Heat u * CoolDo+n Rate
(lower %aster
Distribution ofCatalyst
'onuniform >niform
NH2 torage ?ower 4igher
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,hat is an Ammonia (li) #atalyst /A(#-
#a)tures '4& that sli)sN )ast the (#R catalyst during sudden
(#R catalyst tem)erature increases Active regen of !P%
;ncreased engine load
Also nown as Ammonia O"idation /AMO+ catalyst
%low through su$strate coated with o"idation catalyst0 Pt
2=
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,hat does an A(# do-
#onverts '4& gas into harmless '2
Reduces tail)i)e emission of '4& gas to J27 PPM
to )rotect against6
2779 ))m !etecta$le odor unliely to e")erience adverseeffects
79199 ))m Mild eye0 nose0 and throat irritation may develo)
tolerance in 12 wees with no adverse effects thereafter
139 ))m Moderate eye irritation no longterm secondary
effects.
&9
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>)coming Modules
ou have com)leted the first training module0
Aftertreatment Basics.
%uture Modules6
Module 26 Aftertreatment #om)onents (ystem %eatures
Module &6 (ystem ;ntegration Tradeoffs Benefits of
!ifferent Technologies
Module 36 Onhighway versus Offhighway
&1
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#E( Account Management #ontacts
Offhighway OEM Business6
Chris Calas
Dave Grimm
Paul Whittle
Sean Li
Virendra Mohite
#ummins !istri$utor
Business6
Terry RauppKevin Benson
Pat Campbell
Wendy Mayhe
Onhighway '.A. OEM
Business6!ohn B Carroll
Carlos Sustaita
!ane Beaman
Mario San"he# Miranda Cross
&2
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"H&N8 %O!
&&
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&PPEND#.
#ummins #onfidential&3
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(#R #atalyst Tem)erature Res)onse
97*9=*18 #ummins #onfidential&7
Clic5 ere to return
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,hy is '4& (torage ;m)ortant-
Ena$les some 'O" reduction without urea dosing
(tored '4& reacts with 'O" $etter than inQected '4&
4igh '4& storage at low tem)erature
(tored '4& will sli) with sudden increase in (#R
su$strate tem)erature Active Regeneration
;ncreased ?oad
Clic5 ere to return