Training Module 1 Updates 10.26.2012

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     Aftertreatment Basics

    Module 1

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    2

     Agenda

    1. Emission Overview

    2. PM Reduction Technology

    a !iesel O"idation #atalysts

    $ !iesel Particulate %ilters

    &. 'O" Reduction Technology

    a (elective #atalytic Reduction

    $  Ammonia (li) #atalyst * AMO+

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    ,hat drives the need for aftertreatment-

    Regulated Diesel Emissions

    Particulate Matter (PM)

      Made u) of #ar$on (oot /#0 Ash0 Organic material

    sul)hates

      ,orsens )ree"isting res)iratory conditions such as

    asthma and allergies

    Hydrocarbons (HC)

      (ome have irritating odor0 to"ic and*or carcinogenic

      #ontri$ute to )hotochemical smog

    Carbon Monoxide (CO)

      #olorless0 odorless and tasteless gas

      To"ic in high concentrations

    &

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    ,hat drives the need for aftertreatment-

    Oxides of Nitrogen (NOx)

      Made u) of colorless nitric

    o"ide /'O and reddish$rown0

    very to"ic and reactive nitrogen

    dio"ide /'O2

      #ontri$ute to )hotochemical

    smog and acid rain

    3

    Greenouse Gas (GHG)

      #om)rised of #ar$on !io"ide

    /#O20 Methane /#430 'itrous

    O"ide /'2O0 %luorinated

    5ases

      5ases that tra) heat in the

    atmos)here raisingtem)eratures

    Original source6 e)a.gov

    Smog

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    5lo$al Emission Regulations E")anding

    7

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    Emissions Alignment

    #ummins #onfidential8

    On4ighwayOff4ighway

    EPA 299:

    EPA 2992

    EPA 2919

    EPA Tier & 2997

    EPA Tier 3 ;nterim 2911

    EPA Tier 3 %inal

    2913

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    PM RED!C"#ON "ECHNO$OG%

    :

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    !iesel O"idation #atalyst /!O#

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    PM reduction )roduct

    %lowthrough su$strate

      Made of cordierite or metal

      'o maintenance necessary

    (u$strate is coated with )reciousmetals

      Platinum /Pt and Palladium /Pd ascatalyst

      Ena$les conversion at a lowertem)erature

      ;n general0 increasing Pt increases

    conversion efficiency

    #om)ati$le with >?(! and 17 PPM 799 PPM sulfur diesel fuels

    ,hat is a !O#-

    Light seen through

    substrate paths

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    Provides @=9 reduction of #O0 4#

    Provides 27 79 reduction of PM

    Removes (olu$le Organic %raction of PM )article

    Promotes )assive regen of !P% $y creating 'O2

    Enhances com$ustion of diesel fuel in the e"haust stream togenerate heat for active regen of !P%

    Enhances )erformance of (#R catalyst with creation of 'O2

    ,hat does a !O# do-

    19

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    !O# (u$strate Material #om)arison

    Caracteristic Cordierite Metallic

    Thermal #onductivity ?ower 4igher  

    (trength ?ower 4igher  

    ,all Thicness 3 to 7 mil /199127 Cm &979 Cm

    #ost ?ower 4igher  

    ,eight ?ower 4igher  

    11

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    !iesel Particulate %ilter /!P%

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    ,hat is a !P%-

    PM reduction )roduct

    ,all flow filter

      Every other channel is closed0 forcing e"haust gas

    through walls of filter

      Made of cordierite or silicon car$ide

    (u$strate is ty)ically coated with

    )recious metals

      Platinum /Pt as a catalyst

      Palladium /Pd as catalyst

    ReDuires >?(! at 17 PPM

    1&

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    ,hat does a !P% do-

    Porous ceramic walls ca)ture

    soot and ash from e"haust  (oot is removed $y )eriodic

    regeneration /active * )assive

      Ash accumulates0 reDuiring !P%

    removal and maintenance

    Provides @=9 PM reduction

    Tra)s #ar$on (oot0 Ash and

    (olu$le Organic %raction of

    )article

    13

    Clean

    Exhaust

    PM /

    Ash

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    ,hat is Ash-

    ;ncom$usti$le material that can only $e removed $y cleaning

    ?ow density ash )lug near outlet of filter 

    4igh density ash layer on wall thicness increasing from inlet to

    outlet

    17Source: Corning 

        #  n

       l  e   t

       O  u

       t   l  e   t

    %low

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    ,hat is Regeneration-

    Process of removing accumulated soot $y conversion into

    harmless #O2

    Two ty)es of regeneration6

      &cti'e regeneration

    ReDuires tem)erature @799F#

    Tem) achieved $y engine management0 dosing diesel fuel into e"hauststream or alternative heat source0 eg. $urner 

      Passi'e regeneration0 ena$led $y !O# ReDuires 1

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     Active Regen

    1:

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    Passive Regen

    1<

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    !P% (u$strate Material #om)arison

    97*9=*181=

    Caracteristic Cordierite ilicon Carbide

    Heat Caacity ?ower 4igher  

    "ermal Conducti'ity ?ower 4igher  

    Heat u * Cool Do+n Rate (lower %aster  

    "ermal Durability Moderate 4igher  

    ,lo+ Restriction ?ower 4igher  

    oot Mass $imit ?ower 4igher  

    &s Caacity Moderate 4igher if asymmetric cellstructure used

    Cost*liter  ?ower 4igher  

    i-e (for same alicationand duty cycle)

    ?arger 17 &9 smaller  

    More

    Ro$ust

    (iGe

    #ost

    Benefits

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    NO. RED!C"#ON "ECHNO$OG%

    29

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    21

    (elective #atalytic Reduction /(#R%undamentals

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    ,hat is (#R-

    #hemical )rocess in which to"ic 'O" is converted to

    harmless '2 and 42O  Reductant6 Ammonia /'4&

      #atalyst6 #o))er Heolite /#uH or ;ron Heolite /%eH or Ianadia

    %low through su$strate0 no cleaning necessary

    ReDuires >?(! /J79PPM

     Ammonia is generated $y the use of liDuid urea /nown as

    !iesel E"haust %luid /!E% or AdBlue

    22

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    2&

    4ow does (#R wor-

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    'onto"ic solution of &2.7 >rea and 8:.7 ,ater 

    >sed to deliver Ammonia /to"ic to (#R catalyst

    Known as AdBlue in Euro)e

    #oncentration ratio with lowest freeGing )oint /11F#

    Eutectic solution concentration does not change withfreeGing /)artial freeGing * thawing of vehicle tan

    ,hat is >rea or !iesel E"haust %luid-

    23

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    (#R #atalyst Material #om)arison

    27

    Caracteristic /anadia ,e01eolite Cu01eolite

    $o+ "emeratureNOx Con'ersion

    ?ower ?ower 4igher  

    Hig "emeratureNOx Con'ersion

    ?ower 4igher Moderate

    NH2 torage ?ower 4igher 4igher  

    Cost ?ower Moderate 4igher  

    3ere !sed4 (#Ronlysystems Euro ;I * I0

    Tier 3%0EmergingMarets

    4igh e"hausttem)eraturese")ected

    ty)ically witha !P%

    Both cool and hote"hausttem)eratures

    e")ected EPA2919*&0 Tier 3%0Euro I;

    Clic5 ere for more information

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    ,hat is a ,ashcoated (#R (u$strate-

    #ordierite su$strate is coated with a thin layer called

    washcoat

    ,ashcoat is made u) of catalyst

    4igh mechanical strength

    4igh melting )oint /@1&99#

    28

    #atalyst

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    ,hat is E"truded (#R-

    (u$strate and catalyst are same material0 i.e. no

    cordierite $ase Manufactured via the )rocess of e"trusion

    #ontains more catalyst )er liter of su$strate

      ;ncreased (#R reaction L ;ncreased 'O" conversion

      Ena$les better fuel economy

    ;ncreased de'O" efficiency ena$les u) to 79 length

    reduction of (#R su$strate

    2:

    #atalyst

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    (#R (u$strate #om)arison

    2<

    3ascoated Extruded

    NOx Con'6 er liter  ?ower 4igher  ubstrate lengtfor gi'en DeNOx 7

    + inches +*2 inches

    Heat u * CoolDo+n Rate

    (lower %aster  

    Distribution ofCatalyst

    'onuniform >niform

    NH2 torage ?ower 4igher  

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    ,hat is an Ammonia (li) #atalyst /A(#-

    #a)tures '4& that sli)sN )ast the (#R catalyst during sudden

    (#R catalyst tem)erature increases   Active regen of !P%

      ;ncreased engine load

     Also nown as Ammonia O"idation /AMO+ catalyst

    %low through su$strate coated with o"idation catalyst0 Pt

    2=

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    ,hat does an A(# do-

    #onverts '4& gas into harmless '2

    Reduces tail)i)e emission of '4& gas to J27 PPM

    to )rotect against6

      2779 ))m !etecta$le odor unliely to e")erience adverseeffects

      79199 ))m Mild eye0 nose0 and throat irritation may develo)

    tolerance in 12 wees with no adverse effects thereafter

      139 ))m Moderate eye irritation no longterm secondary

    effects.

    &9

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    >)coming Modules

    ou have com)leted the first training module0

     Aftertreatment Basics.

    %uture Modules6

    Module 26 Aftertreatment #om)onents (ystem %eatures

    Module &6 (ystem ;ntegration Tradeoffs Benefits of

    !ifferent Technologies

    Module 36 Onhighway versus Offhighway

    &1

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    #E( Account Management #ontacts

    Offhighway OEM Business6

    Chris Calas

    Dave Grimm

    Paul Whittle

    Sean Li 

    Virendra Mohite

    #ummins !istri$utor

    Business6

    Terry RauppKevin Benson

    Pat Campbell 

    Wendy Mayhe 

    Onhighway '.A. OEM

    Business6!ohn B Carroll 

    Carlos Sustaita

    !ane Beaman

    Mario San"he# Miranda Cross

    &2

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    "H&N8 %O!

    &&

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    &PPEND#.

    #ummins #onfidential&3

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    (#R #atalyst Tem)erature Res)onse

    97*9=*18 #ummins #onfidential&7

    Clic5 ere to return

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    ,hy is '4& (torage ;m)ortant-

    Ena$les some 'O" reduction without urea dosing

    (tored '4& reacts with 'O" $etter than inQected '4&

    4igh '4& storage at low tem)erature

    (tored '4& will sli) with sudden increase in (#R

    su$strate tem)erature  Active Regeneration

      ;ncreased ?oad

    Clic5 ere to return