Upload
others
View
4
Download
0
Embed Size (px)
Citation preview
Traditional FR Products today use
halogenated (bromine/chlorine) based
polymers and FR fillers (i.e. Antimony, ATH,
etc.)
However, TOXICITY and SMOKE are of a
concern when using traditional fire
retardants.
New standards are emerging: One example
is the railway industry.
Market requirements:
Conventional Polyester Systems don’t meet the strict Standards
required for compliance in Railway, Aviation, Marine &
Construction applications (smoke, toxicity).
Regulations are changing, the Railway is one example of
standardising across Europe. This brings new standards, new
challenges and tighter controls of all Raw materials used in Fire
Resistant products.
Because of these changes, CCP Composites saw an
opportunity to develop a Fire Resistant system that meets these
changes.
CCP Solutions: Why an intumescent system?
Intumescent materials work by forming a char layer at the
interface of the fire source and the composite laminate, which
cuts off the oxygen from the organic fuel source.
The intumescent solution brings many advantages: first of all,
there is no halogen, lowering the toxicity and the opacity of the
fumes.
CCP Solutions: What is an intumescent system?
What is EN 45545?
New European Standard for Rolling Stock effective in 2013.
Rolling Stock for Railways - EN 45545
1991 2009 2012 2013
Development started to ensure no
trade barriers between EU
countries TS 45545
issued CEN countries
voted - March EN 45545 issue
National standards
Country Standard EUROPEAN UNION CEN TS 45545 / LOI, ISO 4589 / EN 13501
UNITED KINGDOM BS 476, Part 6, 7 ; BS 6853
FRANCE NF P 92-507 ; NF F 16-101
SPAIN UNE 23727
GERMANY DIN 5510
USA ASTM E 84, 662, SMP 800, UL 94
Relations between Categories and Fire Hazard Levels (=HL)
N
Standard
Vehicles
A
Automatic
Vehicles,
having no
emergency exit
D
Double
decked
Vehicles
S
Sleeping and
Couchette
Relations between Categories and Fire Hazard Levels (=HL)
N
Standard
Vehicles
A
Automatic
Vehicles,
having no
emergency exit
D
Double
decked
Vehicles
S
Sleeping and
Couchette
Relations between Categories and Fire Hazard Levels (=HL)
N
Standard
Vehicles
A
Automatic
Vehicles,
having no
emergency exit
D
Double
decked
Vehicles
S
Sleeping and
Couchette
FIREBLOCK™ performances: Flame spread, Smoke, heat release, effluents toxicity
According to EN 45545 Railway standard
FIREBLOCK resin + gel coat: HL3 level
CFE (kW/m²) 20 HL 1, 2 and 3
MAHRE (kW/m²) 60 HL 1 90 HL 3 HL 2
Ds (4) 150 HL 1 300 HL 2 600
ITC @ 8 min. 0.75 HL 1 0.9 HL 3 HL 2 1.2
VOF4 300 HL 1 600 HL 2 1200
Effluents
Toxicity
Smoke
density
Smoke
density
Heat
release
Flame
Spread
HL 3
HL 3
29,5
62
115
178
0.01
HL3
HL2
HL3
HL3
HL3
FIREBLOCK resin
FIREBLOCK gelcoat
22,7
32,5
76,5
184
0.31
FIREBLOCK™ PERFORMANCES EU standards
Country Standard FIREBLOCK
performances
EUROPEAN UNION
CEN TS 45545 HL 3
LOI, ISO 4589 > 60
EN 13501 B s2 d0
UNITED KINGDOM
BS 476, Part 6 Class 0
BS 476, Part 7 Class 1
BS 6853 Category 2
FRANCE NF P 92-507 M1
NF F 16-101 F1
SPAIN UNE 23727 M1 F1
GERMANY DIN 5510 S4 SR2 ST2
USA
ASTM E 84 Class 1
ASTM E 662 conforms
ASTM E 162 FSI = 10
SMP 800 conforms
UL 94 V-0
Fireblock is the Brand name for our award winning
“Intumescent Composite System” comprising of
an Intumescent Gelcoat (Brush or Spray Grade) and
an Intumescent Resin (HLU Brush or Spray, Light RTM and
Pultrusion Grade)
to make composite parts for the Railway, Aerospace
and Building Sector.
FIREBLOCK ™
An opportunity for “High Temp Fire Resistant” parts
Test at 2000 °C using oxy-acetylene torch
Standard Fire Retardant composite panel of the same thickness failed
after 30 seconds
A Metal panel of the same thickness failed after 20 seconds
CCP Composites FireBlock Technology:
1 minute without any damage
You have to be very close to the laminate, for the flame to go through!
FIREBLOCK™ performances: High temperature resistance
FIREBLOCK™ PERFORMANCES Environmental performances
0
100000
200000
300000
400000
500000
600000
700000
800000
900000
1000000
STANDARD FIREBLOCK
g e
q C
O2 /
Pan
el
IPCC-Greenhouse effect 2008 (direct, 100 years)
Green houses gases emissions
Pannel USE PHASE
Glass MANUFACTURING
Resin MANUFACTURING (CCPComposites+upstream)
-13%
Environmental performance is improved by three major factors:
The Total Ecosolutions product uses raw materials that are less toxic.
When exposed to fire, the Total Ecosolutions product does not emit
halogen.
Because the Total Ecosolutions product has a lower density than the
reference product, the train is lighter and, as a result, uses less energy
and emits less carbon.
Our Life Cycle Analysis tells us that
we gain a 13% reduction in CO2
emissions when compared to
Standard Fire Retardant Systems
CMR Free (Carcinogenic, Mutagenic and Toxic for Reproduction)
Halogen Free
Low Density : about 1.39 kg/L as compared to more than 1.6 for heavy
filled UPR
Very High Fire Protection and High Workability
Room temperature curing
Formaldehyde free
No acid catalyst needed (Standard MEKP catalyst)
Ambient curing
Long shelf life
Good cosmetics with the Gel coat
Good Mechanical Properties
Cost competitive
What are the Benefits of FIREBLOCK ™
Norsodyne H81381TFA - Pre-accelerated
Norsodyne H81269TF – Non-accelerated
FIREBLOCK ™
Norsodyne I81268F – Filled RTM
Light Injection Resin
60 Minute Fire door using Polycor
2330 BR & Norsodyne H81269TF
FIREBLOCK ™application
FIRE door in construction
Furness & Probe
temperatures
FIREBLOCK ™application
Railway
The CCP Composites FIREBLOCK™ product
has been chosen by Bombardier transportation
for the manufacture of parts of the new
BOMBARDIER INNOVIA Monorail 300 system
in São Paulo, Brazil.
What products can we offer?
POLYCOR ® 2335BR – White Brush Gel coat
POLYCOR ® 2335PA – White Spray Gel coat
NORSODYNE® H81269TF – Thixotropic, Filled, Hand Lay up or Spray
Lay up resin, Non-accelerated.
NORSODYNE® H81381TFA - Thixotropic, Filled, Hand Lay up or
Spray Lay up resin, Pre-accelerated.
NORSODYNE® I81268F – Filled RTM Injection Resin, Non-
accelerated.
NORSODYNE® P81091TF – Thixotropic, Filled Pultrusion Resin
FIREBLOCK ™product range
CONCLUSION
FIREBLOCK ™ is your solution for Fire Resistance
products.
FIREBLOCK™ allows you to reach the highest level of
Fire safety.
FIREBLOCK ™ enables users to consume less natural
resources and / or reduce their environmental impact.
FIREBLOCK ™ is a complete “Fire System” offering
Resin and Gelcoat products.