Toxic-Chemical-Leakage-Outside-Waste-Depot

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    1997 REPORT SHOWSTOXIC CHEMICAL

    LEAKAGEOUTSIDE TOXICDEPOT

    ByMurrayS.Thompson (BAppSciEnvironmentalHealthwithDistinction1998,HonsISocialEcology1999,UniversityofWesternSydney)Copyright1998,2010

    http://poisonedpeople.comhttp://poisoningandlegalaction.com.au/mcs.htm

    EMAIL: [email protected](toJune1997)Reportonthegroundwater

    monitoringprogramattheCastlereaghWasteDepotclearly

    showsthatthedepotisleaking.

    Boresalongtheperimeterofthedepot,alongwithboreslocatedmore

    thanhalfakilometeroutsidethedepotindicateadisturbingarrayoftoxiccontaminants.

    WhichContaminantsandWhere?SeveralorganiccompoundshavebeenfoundinBore943a(seeFigure1,page4),whichislocatedonthesoutheastperimeter,onLlandiloRoadandjustovertheroadfrom

    FifthRdinBerkshirePark. VolumeIoftheReportspecificallynotesthatBore943a

    containedseveralorganiccompoundssimilartothosefoundinonsitebores(ADI

    1997a:52).

    Volatilehalogenatedcompounds(VHCs)(including1,1dichloroethane,chloroform,

    methylenechloride(dichloromethane)andtrichloroethene),totalpetroleum

    hydrocarbons(TPH)(ADI1997a:20;1997b:AppendixB),andthesemivolatileorganic

    isophorone(detectedbeforeJanuary1997[1997b:AppendixB])werefound.

    Toluene,methylethylketone,andmethylisobutylketonearelistedamongthe

    contaminantsfoundingroundwateratthisboresite(ADI1997a:2021).

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    ThestoryofchemicalleakagecontinueswithBores942C,locatedjustinsidethenorth

    eastperimeter,and941(ontheperimeter,southoftheJohnMoronyCorrectional

    Centre). 942CshowedmoderateconcentrationsofTPHs(0.856mg/L)andlow

    concentration[s]offormaldehyde(1.3mg/L). 941alsodemonstratedthepresenceof

    TPHsinthegroundwater,includingtoluene(ADI1997a:22). Itisimportanttonotehere

    thattheADIReportoftennotesthatcontaminantswerenotdetectedbeforethistest

    period. Thisclearlyshowscontaminantmovement. However,theobvioussourceof

    thesetoxicwastescannotbeestablishedwithcertainty,accordingtotheseexperts.

    Proposedsourcesaregivenasalocalsourceorcrosscontaminationoftheboresduring

    drillingandinstallation(ADI1997a:22).

    Withwastesindicatedalongtwosidesofthedepot,weshouldthenaskifchemicalsare

    indicatedasleakingbeyondtheperimeter. Yestheyare. Thesouthandthewesternperimeters

    have

    offsite

    bores

    that

    clearly

    contain

    indicators

    of

    toxic

    chemical

    wastes.

    First,Bore317A,locatedonthesouthernperimetershowsupwardtrendsinthechlorinatedhydrocarbons1,1dichloroethaneand ethene,cis1,2 dichloroetheneand

    trichloroethene(ADI1997a:42).

    Next,Bores904,905,906,969andOSMB5,locatedfrom200to500metersoutsidethisperimeter,havevaryingindicationsofthefollowingchemicals:chloroform,

    trichloroflouromethaneandvinylchloride.

    What

    are

    these

    chemicals

    doing

    outsidethe

    depot

    in

    the

    groundwater?

    Probably

    the

    sameastheTPHs,tolueneandVHCsintheperimeterbores941and943A:migrating!

    BoreOSMB2,locatedoffsiteandacrossTheNorthernRoadfromthedepot,indicates

    0.083mg/LofTPHsinJune1997(ADI1997a:Table12F1),alongwithtracesofarsenic,

    cobalt,phenol,dinbutylpthalate,andbutylbenzylpthalate(ADI1997a:Table12F2).

    Upgradients,perchedgroundwatersandchemicaldiffusionItwasnotedintheReportthatBores905andOSMB5arelocatedupgradienttothe

    WMC (ADI1997a:27). Thewordingimpliesthatthechloroformingroundwaterin

    thesetwoborescouldnotbesourcedfromthedepot. Furthertothis,thepresenceof

    thechloroform,

    as

    with

    other

    chemicals

    found

    in

    bores

    along

    the

    depot

    perimeter,

    is

    consideredtorepresentananomaly(ADI1997a:27). Ananomalyiswhatyoucalla

    situationwhenyoudontwanttocallitwhatitreallyis: chemicalleakagefromasource

    containingonemilliontonnesofliquidwaste...dumpedatCastlereaghoverthepast20

    years(Kerr,1995:3).

    Perchedgroundwaters:thistermhasdevelopedamythicalqualityoverthepastfewyearswithregardtoWasteServiceNSW(WSNSW)andotherauthoritiesusageofit. It

    isatermthatmagicallyexplains,withouteverprovidingrationalandphysicalproof,

    whythegroundwatersbeneaththedepotaresomehowtotallyisolatedfromallother

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    geologicalstructures. AccordingtoWSNSWtheory,chemicalscannotcrossthisbarrier

    andescapeintogroundwatersadjacenttothedepot.

    Modernresearchintolandfilltechnology,however,contradictsADIupgradient

    insinuationsandexoticperchedgroundwatertheories. Note:

    Theobjectiveofcontrollingthehydraulicconductivityisclearlyoneoflimiting

    advectivecontaminanttransport(iethemovementofcontaminantswithmoving

    water)throughtheliner. However,despitemorethanadecadeofresearchand

    theexistenceofgoodsupportingfielddata,itisonlyrecentlythatithasbeen

    generallyrecognizedthatthereisasecondcontaminanttransportprocesswhich

    willoccureventhroughaverylowhydraulicconductivityclayliner:thatprocess

    ischemicaldiffusion. ...diffusionmaybethedominantcontaminanttransport

    mechanisminawellconstructedclayliner. Furthermore,contaminantscan

    escapefrom

    awaste

    disposal

    site,

    by

    diffusion

    through

    aliner,

    even

    ifwater

    flow

    inthelinerisintothelandfill(Rowe1994:219)(emphasisadded).

    WhenoneaddsanEPAadmissionofchemicalleakagefromwastecellsinto

    groundwaterbeneaththedepot(EPAofficial1995,pers.comm.,26April[recordedat

    theCommunityMonitoringCommitteemeetingatthePenrithCityCouncilChambers])

    totheabovescientificresearch,itbecomesalltooclearthatTHEWASTEDEPOTIS

    LEAKING.

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    Figure1 SitePlanandLocationofMonitoringBoreholes(additional bore locations added as large diamond

    shapes)(WasteServiceNSW1996:Appendix1)

    317A

    OSMB2

    312A

    904

    OSMB59

    05

    CASTLEREAGH

    STATEFOREST

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    Surfaceand

    bore

    water

    tests

    on

    aproperty

    2km

    south

    west

    of

    the

    Castlereagh

    Waste

    Depotconfirmthepresenceoflargeamountsofsodiumchloride,phosphorusand

    cadmium.

    Althoughnotactinginaprofessionalcapacity,UniversityofWesternSydney

    Hawkesburystudentsduring1995/96foundevidenceoftheabovechemicalsonafarm

    propertylocatedjust2kmfromthedepot. Inthecaseofthetoxicheavymetal

    cadmiumfoundinthepropertysborewater,thelaboratorydeterminationofasignificantlevelof1.2084ppm(1,208ppb)wasmadebyTechnicalOfficersatthe

    University. Thislevel,accordingtofiguressetbyAlloway(1990:31)is604.2%greater

    than

    the

    normal

    lithosphere

    (rocky

    crust)

    concentration

    and

    2014%

    beyond

    normal

    soil

    levels.

    Variousstudieshavebeenaccessedforthissectioninordertodeterminethetoxicities

    ofsomeBoreandpropertychemicals.

    Cadmium,andotherheavymetalsaretoxicatquitelowconcentrations(Cresser,

    Killham&Edwards1993:152). Cadmiumisimplicatedinbonedeformations(Rowland

    &Cooper

    1983:170),

    the

    longterm

    development

    of

    obstructive

    pulmonary

    disease

    and

    emphysema(Philp1995:141), carcenogenicityinanimalsandhumans(ONeill&Dodet

    1985:10),andnephrotoxicity(WHO1989:168).

    Vinylchloride(Bores904,905,906,969andOSMB5)causesliver,brain,lungand

    lymphoidtissuecancer(Siemiatycki1995:103104)andisaskinirritant(Rowland&

    Cooper1983:176).Italsoinducestumoursofthebloodintheoccupationallyexposed

    andisasuspectedmutagen(Alloway&Ayres1993:216).Chloroform(fouroftheaboveBores)isimplicatedincancer(Philp1995:81;Alloway&

    Ayers1993:216)

    and

    hepato

    (liver)

    and

    nephro

    (kidneys)

    toxicity

    (Philp

    1995:152).

    Toluene(Bores941and943A),anorganicsolvent,isamucousmembraneandskin

    irritant(Rowland&Cooper1983:174).Moredisturbingly,tolueneisdescribedasa

    neurotoxinwhichisabsorbedthroughthelungsInthisrespect,itcaninducemild

    abnormalitiesoftheCNS[and]deathduetoitsinhalationhasoccurredasaresultof

    solventabuse(Alloway&Ayres1993:44;216). Methylethylketone(Bore943A)can

    causedermatitisandhasanirritantactionontheeyesandrespiratorysystem

    (Rowland&Cooper1983:175).

    Student Research Confirms Chemicals on Property

    How Toxic Are These Chemicals?

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    Formaldehyde(Bore942C)isarespiratoryirritantandasuspectedcarcinogen(Rowland

    &Cooper1983:173).

    Arsenic(BoreOSMB2)causesliverandlungcancer(Rowland&Cooper1983:58),aswell

    asskincancer(Sunderman1985:17).

    Phenol(BoreOSMB2)iscorrosiveandpoisonous(Aviado1976:1068)andcancause

    vomiting,eyeandrespiratoryproblems (Bender1991). Further,phenolcauses

    changestoenzymeswithintheendoplasmicreticulum(incells),particularlyintheliver,

    butalsothekidneys,lungsandintestines(Alloway&Ayers1993:210).

    Chlorinatedhydrocarbons(Bore317A)promoteallergicreactionssuchasdermatitisand

    arealsonarcotizingagents(Rowland&Cooper1983:1767). Theseverypersistent

    contaminantshave

    ahigh

    potential

    for

    human

    toxicity

    indicated

    by

    reproductive

    defectsinphytoplanktonand,inmammalsandbirds,microsomalenzymeinduction[a

    modificationimposedongermcells(Kellogg1976:702)],tumorpromotion,estrogenic

    effectsandimmunosuppression(Philp1995:77).

    Trichloroethene(Bores317Aand943A)isanorganicsolventthatpromotesdermatitis

    andhasnarcotizingeffects(Rowland&Cooper1983:1767). Itshouldbenotedhere

    that1,1,1trichloroethane hasproduceddeathsinacuteoccupationalexposureand

    heartfailurethroughsolventabuse(Alloway&Ayres1993:217).

    Dichloromethane

    (Bore

    943A)

    converts

    to

    carbon

    monoxide

    which

    forms

    carboxyhemoglobinintheredbloodcells(Philp1995:153),thusreducingoxygenation

    andimpairingrespiration.

    ItmustbepointedoutherethatresidentsaroundtheCastlereaghWasteDepotcanbe

    exposedtofumesandliquidleachates24hoursaday,thisbeingafarmorecritical

    situationthanmonitoredoccupationalexposurestochemicals. Itisnowonder,then,thatteratogenicimpactsonlivestockandhumanshavebeennotedbythelandholders

    onadisturbinglyregularbasis.

    Theabovelistedconvergenceofchemicalanalytesfoundintestboresontheperimeter

    andoutsidetheCastlereaghWasteDepotandthesymptomatologyalsolisted,critically

    synchronizeswiththeillnessesexperiencedbyLondonderryresidentslivingclosetothe

    depot.

    Itmaybethesadtruththattoxicchemicals,disposedofbywayofacruelpartnership

    betweenanaberranttechnologysintractableanddangerouswastesandagenerally

    Requiem

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    negativegovernmentalviewofworkingclass/ruralareas,arecripplingtheproductive

    potentialoftheLondonderryregion. Andsincetheliquidwastesburiedatthedepot

    havepermeatedextensively,itmaybeveryreasonablyconcludedthatthesustainability

    oftheselands hasbeenandwillbe,foralongtimeintothefuture,severely

    compromised.

    REFERENCESADILimited1997a,HalfYearlyReporttoJune1997:GroundwaterMonitoringProgramCastlereaghWasteManagementCentre Volume1,ADILimtedEnvironmentalConsulting,SilverwaterNSWAustralia.

    ADILimited1997b,HalfYearlyReporttoJune1997:GroundwaterMonitoringProgramCastlereaghWasteManagementCentre Volume2,ADILimtedEnvironmentalConsulting,Silverwater

    NSW

    Australia.

    Alloway,B.J.andAyres,D.C.1993,ChemicalPrinciplesofEnvironmentalPollution,BlackieAcademic&Professional(AnImprintofChapman&Hall),Glascow,UK.

    Aviado,D.M.1976,Phenol,inStedmansMedicalDictionary,23rdEdn,TheWilliams&WilkinsCompany,BaltimoreMdUSA.

    Bender,J.1991,Govtsays:dontworry,behappy,PenrithPress,4June.Cresser,M.,Killham,K.,andEdwards,T.1993,SoilChemistryanditsApplications,PressSyndicate

    of

    the

    University

    of

    Cambridge,

    Cambridge

    England.

    Kellogg,R.H.Induction,inStedmansMedicalDictionary,23rdEdn,TheWilliams&WilkinsCompany,BaltimoreMdUSA.

    Kerr,P.1995,Toxictiptoclose,PenrithPress,April25.ONeill,I.K.andDodet,B.1985,Considerationsofsampling,interactionsandIARCevaluations

    forthisgroupofelements,inEnvironmentalCarcinogens:SelectedMethodsofAnalysis,edsI.K.ONeill,P.Schuller&L.Fishbein,InternationalAgencyforResearchonCancer,LyonCedex

    08,France.

    Philp,R.B.1995,EnvironmentalHazards&HumanHealth,LewisPublishers(CRCPress,Inc.)FL,USA.Rowe,R.K.1994,Diffusivetransportofpollutantsthroughclayliners,inLandfillingofWaste:Barriers,eds,T.H.Christensen,R.CossuandR.Stagmann,E.&F.N.Spon,London,UK.

    Rowland,A.JandCooper,P.1983,EnvironmentandHealth,EdwardArnold(Publishers)LtdLondon.

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    Siemiatycki,J. 1995,RiskFactorsforCancerintheOccupationalEnvironmentandRelevant

    EpidemiologicStudyMethods,inIntroductiontoEnvironmentalEpidemiology,EdsE.O.Talbott&G.F.Craun,CRCPress,Inc.BocaRaton,FL,USA.

    Sunderman,F.W.1985,CarcinogenicityandMutagenicityofSomeMetalsandtheir

    Compounds,inEnvironmentalCarcinogens:SelectedMethodsofAnalysis,edsI.K.ONeill,P.Schuller&L.Fishbein,InternationalAgencyforResearchonCancer,LyonCedex08,France.

    WasteServiceNSW1996,CastlereaghWasteManagementCentreClosurePlan(Revision2),WasteServiceNSW,ChatswoodNSWAustralia.

    WHO1989,ToxicologicalEvaluationofCertainFoodAdditivesandContaminants,CambridgeUniversityPress,CambridgeUK.

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