Upload
duongdung
View
221
Download
1
Embed Size (px)
Citation preview
MATERIAL SAFETY DATA SHEET
January, 2009
TOWELETTE, PRE-MOISTENED, LEMON-SCENTED --------------------------------------------------------------------------------------
Section I: Identification
Identity (As used on Label and List): MOIST TOWELETTE WITH LEMON FRAGRANCE
Ingredients: 98.8% water 1% lemon fragrance
.2% soap Physical Description: A pre-moistened towelette made with virgin paper,
individually packaged in a moisture-proof pouch.
Manufacturer's Name: SANFACON VIRGINIA, INC.
Address: PO Box 600
18097 US Hwy 501 Brookneal, VA 24528
-------------------------------------------------------------------------------------- Section II: Hazardous Ingredients
Hazardous components: N/A
--------------------------------------------------------------------------------------
…2
Section III: Physical/Chemical Characteristics
Boiling Point: N/A Specific Gravity: +/- 1.0 Vapour Pressure: N/A Melting Point: N/A Vapour Density: N/A Evaporation Rate: N/A
Solubility in Water: Complete
Appearance and Colour: Clear liquid with lemon scent --------------------------------------------------------------------------------------
Section IV: Fire and Explosion Hazard Data
Flash Point: N/A Flammable Limits: N/A
Extinguishing Media: N/A Special Fire Fighting Procedures: NONE
Unusual Fire & Explosion Hazards: NONE
-------------------------------------------------------------------------------------- Section V: Health Hazard Data
Routes of Entry: Inhalation: N/A Skin: Topically applied
Ingestion: N/A Health Hazards: N/A
Carcinogenicity: N/A
Information/Emergency: Monday through Friday, 8 a.m. to 5 p.m., (800) 463-5591 or contact the local Poison Control Centre.
Caution: If accidentally splashed in eyes, rinse thoroughly with cold water; may cause discomfort. No need for first aid if swallowed or inhaled.
Signs and Symptoms of Exposure:
SAFE AS A TOPICAL SKIN CLEANSER
--------------------------------------------------------------------------------------
…3
Disclaimer: Sanfacon acknowledges that the information contained herein is assumed accurate
and complete, and illustrates the product to the best of their knowledge. No warranty, expressed or implied, is made and Sanfacon assumes no legal
responsibility or liability resulting from its use.
fusee backfire sar camp Page 1 of 4 May 2012
SAFETY DATA SHEET
1. Product and Company Identification
Emergency Road Flare / Fusee / Railway Flare NSN#: 1370-01-009-2593
Backfire Torches NSN#: 1370-00-294-1279
SAR Signal Flare / Campfire Starter
Use:
Emergency signal
Forest fire control
Emergency signal / campfire starter
Orion Safety Products 28320 St. Michaels Rd Easton, MD 21601
Phone Number:
EMERGENCY
US 1-800-637-7807 Intl (11) 1-410-822-0318 CHEMTREC 1-800-424-9300
2. Hazards Identification
Emergency Overview Hazard Statements: Fire or projection hazard May be harmful if swallowed Causes severe skin burns and eye damage Causes skin irritation Causes serious eye damage Causes eye irritation May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause damage to thyroid through ingestion after prolonged or repeated exposure
Precautionary Statements: Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep/Store away from combustible materials. Protect from moisture. Use only non-sparking tools Avoid breathing dust/smoke Use only outdoors or in a well-ventilated area. Avoid release to the environment.(contents) Use personal protective equipment as required. In case of fire: use water deluge. Do not use dry powder or foam extinguishers!
NFPA Rating
Flammability 2
Health 2
Reactivity 1
HMIS Rating
Flammability 1
Health 3
Physical Hazard 1
3. Composition / Information on Ingredients Component CAS # EINCS # %age
Strontium Nitrate 10042-76-9 233-131-9 <75%
Potassium Perchlorate 7778-74-7 231-912-9 <50%
Potassium Chlorate 3811-04-9 231-100-4 <25%
Sulfur 7704-34-9 231-722-6 <25%
Shellac mixture none <25%
Paraffinic Oil 64742-54-7 232-384-2 <25%
Sawdust / Wood Flour 9004-34-6 232-674-9 <10%
4. First Aid Measures Inhalation If fumes from ignition or contents are inhaled, remove to fresh air. Watch for signs of allergic reaction. If other symptoms
develop, get medical aid immediately.
Skin For burns, cool with water and bandage appropriately. If contents are contacted, wash with area with soap and water for 15 minutes. Remove contaminated clothing and wash before reuse. Get medical aid if burned or irritation occurs.
Eyes If burned, cover eye and get medical help immediately. If contents get into eye, flush with plenty of water for at least 15 minutes, occasionally lifting the up and lower lids. Remove contact lenses if easily possible. Do not use boric acid to rinse with; sulfur is an acid irritant. Get medical aid immediately.
Ingestion Get medical aid immediately.
5. Firefighting Measures
Extinguishing Media Water deluge Unsuitable Extinguishing Media Foam and dry chemical extinguishers and suffocation are ineffective.
Protective Equipment and Precautions for Firefighters
Wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Prevent further propagation of fire by spraying unburnt nearby product with water. Combat fire from a sheltered position.
Specific Hazards Arising from the Chemical
Flame and sparks are ejected out the open end of the flare when it functions. Do not point flare at any part of the body or flammable material. Only use outdoors – smoke is harmful. Contents may ignite and burn explosively when suspended in air and exposed to open flame or spark.
Flashpoint Not Applicable Flammability Limits Not Applicable Ignition Temperature >167F
Warning Danger Warning Danger
GHS Classifications Explosive Division 1.4 Acute Toxicity Category 5 Skin Corrosion / Irritation Product- Category 1A Contents - Category 2 Serious Eye Damage / Irritation Product-Category 1 Contents - Category 2B
Respiratory or Skin Sensitization Contents - Category 1 STOT - Repeated Exposure Contents - Category 2
fusee backfire sar camp Page 2 of 4 May 2012
6. Accidental Release Measures Personal Precautions Environmental Precautions
Do not breathe contents and avoid contact with skin and eyes. Wear flame retardant clothing with long sleeves, dust mask, rubber or nitrile gloves, safety goggles, safety shoes. Avoid friction on the released product. Keep away from ignition sources.
Prevent dispersion of contents on soil and in water. Prevent contents from spreading or entering into drains, ditches, groundwater or rivers by using appropriate barriers.
Methods for Containment and Clean-up Use caution when cleaning up spilled product contents. Remove heat, flames, sparks and other sources of ignition. Use non-sparking tools and equipment. Prevent buildup of electrostatic charges by grounding. Clean spills in a manner that does not disperse dust into the air. Do not absorb in sawdust or other combustible absorbents. Pick up spill for recovery or disposal and place in an approved container. Wash away remainder with plenty of water. Collect wash water for approved disposal.
7. Handling and Storage
Handling Hold and point flare away from body when igniting. Exercise caution when using this product since molten flecks may be emitted. Avoid contact with clothing and other combustible materials. Wear eye protection during use. Follow instructions on package. Use outdoors only! Do not ignite or burn product inside a vehicle or building. Flares should be allowed to burn to completion. Unburned and partially burned flares contain potassium perchlorate which should not be allowed to come into contact with surface and ground water. Perchlorate Material – special handling may apply. See www.dtsc.ca.gov/hazardouswaste/perchlorate. Avoid ingestion and inhalation of smoke and contents. Do not dismantle. Do not allow contents to touch eyes, skin or clothing. Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with skin and eyes. Avoid contact with heat sparks, and flame. Do not ingest contents as they may be harmful if swallowed.
Storage Store in a dry place away from direct sunlight, heat and incompatible materials. Store away from food and beverages. Store away from flammable materials, sources of heat, flame and sparks. Store at ambient temperature. Do not store partially burned flares in a vehicle, closed container, warehouse, or any other building.
8. Exposure Controls / Personal Protection Exposure Limits OSHA PEL ACGIH TLV
Strontium Nitrate Not Established Not Established
Potassium Perchlorate nuisance dust 15 mg/m³. nuisance dust 15 mg/m³.
Potassium Chlorate Not Established Not Established
Sulfur Not Established Not Established
Shellac Not Established Not Established
Paraffinic Oil TWA: 5 mg/m3 8 hour(s). Form: All forms STEL: 10 mg/m3 15 minute(s). Form: All forms; TWA:
5 mg/m3 8 hour(s). Form: All forms
Sawdust / Wood Flour wood dust 5.0 mg/m3 (respirable fraction) Western red cedar: TWA – 2.5 mg/m3
TWA-5.0 mg/m3; STEL (15 min.) – 10 mg/m3 (softwood) TWA – 1.0 mg/m3 (certain hardwoods such
as beech or oak)
Engineering Controls Use product outdoors only! When cleaning up powder, use local and/or general exhaust. Eye / Face Protection Safety glasses or goggles Skin Protection None under normal conditions when using product unless prolonged handling is anticipated. Impervious protective clothing,
including gloves, boots, and a lab coat, apron or coveralls, as appropriate, when cleaning up spilled product. Wash hands and face before eating, drinking or using tobacco products.
Respiratory Protection None under normal conditions when using product. A particulate respirator (NIOSH t N95 or better filters) may be worn during the cleanup of spilled materials.
General Hygiene Use product outdoors away from combustible products. For cleanup of spilled materials, emergency showers and eye wash stations should be available. Educate and train employees in the safe use and handling of hazardous materials.
9. Physical and Chemical Properties Appearance (color, physical form, shape): Red or yellow paper tube with plastic or cardboard cap on one end
pH: Not available Melting Point: Not available Solubility: >300 g/l powder Boiling Point Not applicable Freezing Point: Not applicable Evaporation Rate: Not applicable
Vapor Pressure: Not applicable Specific Gravity Not applicable Vapor Density: Not applicable
10. Stability and Reactivity Chemical Stability Stable Possibility of Hazardous Reactions Hazardous polymerization will not occur.
Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Combustible materials, heat, flames, sparks and other sources of ignition. Moisture.
Strong acids, strong fuels, ammonia salts, and strong bases. Strong oxidizers; chlorate salts,
Carbon monoxide, carbon dioxide, sulfur oxides, and nitrogen oxides.
11. Toxicology Information Toxicology Oral LD50 skin LD50 LC50
Strontium Nitrate Rat: 2750 mg/kg No information found No information found
Potassium Perchlorate Rat: 2100 mg/kg No information found No information found
Potassium Chlorate Rat: 1870 mg/kg (CAT 4) No information found No information found
Sulfur Rat:>5050 mg/kg body weight Rat:>2020 mg/kg body weight Rat:>5.49 mg/L air concentration
Shellac No information found No information found No information found
Paraffinic Oil Rat: >2000 mg/kg Rat: >2000 mg/kg No information found
Sawdust / Wood Flour No information found No information found No information found
fusee backfire sar camp Page 3 of 4 May 2012
Acute Dose Effects Repeated Dose Effects Burning flare can cause severe burns if in contact with body. Contents may cause moderate eye irritation or burns. Contact with skin causes irritation and possible burns, especially if skin is wet or moist. Ingestion of contents may cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation of smoke or
contents will cause irritation to the lungs and mucus membrane. Individuals with known allergies to sulfide drugs may also have allergic reactions to elemental sulfur.
Prolonged or repeated skin contact with contents may cause dermatitis.
Irritation Irritating to the skin and eyes on contact. Inhalation will cause irritation to the lungs and mucus membrane.
Corrosivity Burning flare can cause severe burns if in contact with body
Carcinogenicity None of the ingredients are listed by NTP, IARC or regulated as a Carcinogen by OSHA
Reproductive Effects No information found
Genetic Effects No information found Neurological Effects No information found
Developmental Effects
Perchlorate exposure at certain levels can disrupt the function of the thyroid gland by interfering with the iodide uptake and thyroid hormone production. This interference may lead to developmental defects. Scientists consider pregnant women, children, infants, and individuals with thyroid disorders to be the populations most at risk of harm from being exposed to perchlorate.
Sensitization No information found
Target Organ Effects
Eye, skin, liver, kidney, and thyroid.
12. Ecological Information
Aquatic Toxicity Persistence / Degradability
Bioaccumulation / Accumulation
Mobility in Environmental Media
Potassium Chlorate: fish: LC50 oncorhynchus mykiss (rainbow trout) 1750 mg/l – 96 hr, EC50 daphnia magna (water flea) 1093 mg/l 24 hr Strontium Nitrate: Acute toxicity - Fishes, Carassius auratus, LC100, 9,615 mg/l; Chronic toxicity - Fishes, Gasterosteus aculeatus, LC100, 2.912 mg/l Sulfur: Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - > 180 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - > 5,000 mg/l - 48 h Paraffinic Oil: Oil Mist, Mineral Lepomis macrochirus (LC50) 96 hour(s) >100 mg/l Oncorhynchus mykiss (LC50) 96 hour(s) >100 mg/l
No information found No information found No information found
13. Disposal Considerations Finished product is considered reactive and could ignite. Burning is the preferred method of disposal of pyrotechnic materials; product is considered inert after ignition. If quantities are too large to destroy by test firing, consult factory. Flares should be allowed to burn to completion. Partially burned, unburned flares, spilled contents, and ash from burned flares should be disposed of in accordance with federal, state, and local requirements. Do not store partially burned flares in a vehicle, closed container, warehouse, or any other building. Refer to California Code of Regulations, Title 33, Sections 67384.1-67384.10 for additional information on handling and disposal of potassium perchlorate containing materials.
14. Transportation Information
Part Number
Description shipping name hazard class
ID Number
packing group
EX Number
Reportable Quantities
Shipping method
United States
Bulk flares Fusee 4.1 NA1325 II Not
applicable none Ground only
3153-08 3-15 min flares ORM-D / Limited
Quantity Not
applicable UN3178
Not applicable
Not applicable
none Ground only
3153-63 3-15 min flare display ORM-D / Limited
Quantity Not
applicable UN3178
Not applicable
Not applicable
none Ground only
6020 20 min flare 6 pack ORM-D / Limited
Quantity Not
applicable UN3178
Not applicable
Not applicable
none Ground only
6030 30 min flare 6 pack ORM-D / Limited
Quantity Not
applicable UN3178
Not applicable
Not applicable
none Ground only
8900 Roadside Emergency
Kit ORM-D / Limited
Quantity Not
applicable UN3178
Not applicable
Not applicable
none Ground only
8905 Flare Kit Plus Emergency Kit
ORM-D / Limited Quantity
Not applicable
UN3178 Not
applicable Not
applicable none Ground only
8901 Deluxe Roadside Emergency Kit
ORM-D / Limited Quantity
Not applicable
UN3178 Not
applicable Not
applicable none Ground only
8902 Extreme Weather Roadside Kit
ORM-D / Limited Quantity
Not applicable
UN3178 Not
applicable Not
applicable none Ground only
fusee backfire sar camp Page 4 of 4 May 2012
8902-5 Deluxe “5” Flare Roadside Kit
ORM-D / Limited Quantity
Not applicable
UN3178 Not
applicable Not
applicable none Ground only
750 Signal Flare / Fire
Starter ORM-D / Limited
Quantity Not
applicable UN3178
Not applicable
Not applicable
none Ground only
International / Air
Bulk flares Signal Devices,
Hand 1.4S UN0373 II EX-9209001 none Air / ground
15. Regulatory Information
US Regulations TSCA CERCLA CWA CAA SARA 313
SARA 302
Acute Chronic Fire Reactivity Pressure
Strontium Nitrate yes no no no no no no no no no no
Potassium Perchlorate yes no no no no no no no no no no
Potassium Chlorate yes no no no no no yes no no yes no
Sulfur yes no no no no no no yes no no no
Shellac mixture mixture mixture mixture mixture mixture not stated not stated not stated
not stated
not stated
Paraffinic Oil yes no no no no no no no no no no
Sawdust / Wood Flour yes no no no no no not stated not stated not stated
not stated
not stated
US States Prop 65 NJ PA Canada WHMIS DSL Europe wgk
Strontium Nitrate no 1743 no No results yes 2
Potassium Perchlorate no 1577 no C yes 1
Potassium Chlorate no 1560 no No results yes 2
Sulfur no 1757 yes No results yes 1 / nwg
Shellac mixture mixture mixture mixture mixture not listed
Paraffinic Oil no 1437 no No results yes not listed
Sawdust / Wood Flour yes 3227 yes No results yes not listed
16. Other Information Revision Information: May, 2012
Risk and Safety Phrases: R10 Flammable R38, Irritating to skin R20 Harmful by inhalation. R21 Harmful in contact with skin. R22 Harmful if swallowed. R34 Causes burns R36 Irritating to eyes. R37 Irritating to respiratory system. S17 Keep away from combustible material S16 Keep away from sources of ignition S2 Keep out of the reach of children.
S8 Keep container dry. S13 Keep away from food, drink and animal foodstuffs. S24 Avoid contact with skin. S25 Avoid contact with eyes. S29 Do not empty into drains. S41, In case of fire and / or explosion do not breathe fumes S43 In case of fire use water S51 Use only in well ventilated areas
Key / Legend: HMIS: hazardous material identification system NFPA: national fire protection association CAS: Chemical Abstracts Service number EINECS: European inventory of existing chemical substances OSHA PEL: occupational safety and health administration permissible exposure limit NIOSH TLV: national institute of occupational safety and health Threshold Limit Value NTP: National Toxicology Program IARC: International Agency for Research on Cancer
TSCA: toxic substance control act - US CERCLA: comprehensive environmental response, compensation and liability act – US CWA: clean water act - US CAA: clean air act - US SARA: superfund amendments and reauthorization act – US PROP 65:California’s Proposition 65 list WHMIS: workplace hazardous materials information system - Canada DSL: Domestic Substances List - Canada WGK: water hazard classes - Germany
Legal Statement: This information is accurate to the best knowledge Orion Safety Products. Orion Safety Products makes no representations or warranties, either express or implied, including without limitation any warranties of merchantability or fitness for a particular purpose, with respect to the information set forth herein or the product to which the information refers. Accordingly, Orion Safety Products will not be responsible for damages resulting from use of or reliance upon this information. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this
information to their particular situation.
Page 1/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
DR
1 Identification of the substance/preparation and of the company/undertaking
· Product details
· Trade name: liquid in glow stick and glow cup· Registration number: Not available
· Application of the substance / the preparation: Chemiluminescer
· Manufacturer/Supplier:XIAMEN LONG AFTERGLOW CO., LTD
NO.1043, TONG JI ZHONG ROAD, TONG AN AREA, XIAMEN, FUJIAN PROVINCE, CHINA
TEL :+86-592-3675699
FAX: +86-592-3675400
· Further information obtainable from: XIAMEN LONG AFTERGLOW CO., LTD
· Information in case of emergency:Tina
MP: +86-13600951446
· Email: [email protected]
· Reference Number: GZHGR2010004483; GZ1003017899/CHEM
2 Hazards identification
· Hazard description: Not Applicable
· Information concerning particular hazards for human and environment:The product does not have to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
· Classification system:The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
3 Composition/information on ingredients
· Chemical characterization· Description:
Mixture of the substances listed below with nonhazardous additions.
For the wording of listed risk phrases refer to section 16.
· Dangerous components:
CAS: 10075-85-1
EINECS: 233-210-8
9,10-bis(phenylvinyl)anthracene Xi; R 36/37/38 0,3%
· Non-dangerous components:
CAS: 136-60-7
EINECS: 205-252-7
butyl benzoate 85,6%
CAS: 75203-51-9
EINECS: 278-124-1
Bis(2,3,5-trichloro-6-((pentyloxy)carbonyl)phenyl) oxalate 14,1%
· Remark:Bis(2,3,5-trichloro-6-((pentyloxy)carbonyl)phenyl) oxalate (CAS No.: 75203-51-9)
Synonym: CPPO
9,10-bis(phenylvinyl)anthracene (CAS No.: 10075-85-1)
Note: Fluorescer
4 First aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Rinse with water.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor. EU
(Contd. on page 2)
Page 2/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
Trade name: liquid in glow stick and glow cup
(Contd. of page 1)
DR
5 Fire-fighting measures
· Suitable extinguishing agents:CO₂, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Protective equipment: Wear fully protective suit.
6 Accidental release measures
· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
· Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
· Measures for cleaning/collecting:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
· Additional information: See Section 7 for information on safe handling.
7 Handling and storage
· Handling· Information for safe handling: Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection: Keep ignition sources away - Do not smoke.
· Storage· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility: Store away from foodstuffs.
8 Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· Ingredients with limit values that require monitoring at the workplace:The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· DNELs: Not available
· PNECs: Not available
· Additional information: The lists valid during the making were used as basis.
· Personal protective equipment· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
· Respiratory protection: Suitable respiratory protective device recommended.
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves:The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material:The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection: Goggles recommended during refilling EU
(Contd. on page 3)
Page 3/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
Trade name: liquid in glow stick and glow cup
(Contd. of page 2)
DR
9 Physical and chemical properties
· General Information
Form: Liquid
Colour: Transparent
Odour: Odourless
· Change in conditionMelting point/Melting range: Not available
Boiling point/Boiling range: Not available
· Flash point: Not available
· Flammability (solid, gaseous): Not available
· Ignition temperature: Not available
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation of explosive air/
vapour mixtures are possible.
· Explosion limits:Lower: Not available
Upper: Not available
· Oxidizing properties Not available
· Vapour pressure: Not available
· Density: Not available
· Relative density Not available
· Vapour density Not available
· Evaporation rate Not available
· Solubility in / Miscibility withwater: Not available
· pH-value: Not available
· Segregation coefficient (n-octanol/water): Not available.
· Viscosity:Dynamic: Not available.
10 Stability and reactivity
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Materials to be avoided: Not available
· Dangerous reactions: No dangerous reactions known.
· Dangerous decomposition products: No dangerous decomposition products known.
11 Toxicological information
· Acute toxicity
· LD/LC50 values relevant for classification:
136-60-7 butyl benzoate
Oral LD50 5140 mg/kg (rat)
Dermal LD50 4000 mg/kg (rabbit)
· Primary irritant effect· on the skin: Irritating effect possible.
· on the eye: Irritating effect possible.
· Sensitization: Sensitization possible.(Contd. on page 4)
EU
Page 4/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
Trade name: liquid in glow stick and glow cup
(Contd. of page 3)
DR
· Additional toxicological information:The product is not subject to classification according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version.
When used and handled according to specifications, the product does not have any harmful effects to our
experience and the information provided to us.
· Toxicokinetics, metabolism and distribution: Not available
· Acute effects (acute toxicity, irritation and corrosivity): Not available
· Repeated dose toxicity: Not available
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): Not available
12 Ecological information
· Information about elimination (persistence and degradability): Not available
· Behaviour in environmental systems· Mobility and bioaccumulation potential: Not available
· Ecotoxical effects· Aquatic toxicity: Not available
· Additional ecological information:· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· PBT assessments: Not available
13 Disposal considerations
· Product· Recommendation: Smaller quantities can be disposed of with household waste.
· Uncleaned packaging· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· Land transport ADR/RID (cross-border)· ADR/RID class: -
· Danger code (Kemler): -
· UN-Number: -
· Packaging group: -
· Hazard label: -
· Description of goods: -
· Limited quantities (LQ): -
· Transport category: -
· Maritime transport IMDG· IMDG Class: -
· UN Number: -
· Label: -
· Packaging group: -
· EMS Number: -
· Marine pollutant: Yes
· Proper shipping name: -
· Air transport ICAO-TI and IATA-DGR· ICAO/IATA Class: -
· UN/ID Number: -
· Label: -
(Contd. on page 5)
EU
Page 5/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
Trade name: liquid in glow stick and glow cup
(Contd. of page 4)
DR
· Packaging group: -
· Proper shipping name: -
15 Regulatory information
· Sara
· Section 335(extremely hazadous substances):
None of the ingredients is listed.
· Section 313(specific toxic chemical listings):
None of the ingredients is listed.
· TSCA(Toxic Substances Control Act):
136-60-7 butyl benzoate
10075-85-1 9,10-bis(phenylvinyl)anthracene
· Proposition 65
· Chemical known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity foe males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Cancerogenity categories
· EPA(Environmental Protection Agency)
None of the ingredients is listed.
· IARC(International Agency for Research on Cancer)
None of the ingredients is listed.
· NTP(National toxicology Program)
None of the ingredients is listed.
· TLV(Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
· NIOSH-Ca(National Institution for Occupational Safety & Health )
None of the ingredients is listed.
· OSHA-Ca(Occupational Safety & Health Administration)
None of the ingredients is listed.
· Labelling according to EU guidelines:Observe the general safety regulations when handling chemicals.
The product is not classified as dangerous according to Directive 67/548/EEC, 1999/45/EC and 1272/2008/
EC.
16 Other information
· Relevant R-phrases36/37/38 Irritating to eyes, respiratory system and skin.
· ***************************************************************************************The contents and format of this MSDS/SDS are in according with REGULATION(EC) No. 1907/2006, EU
Commission Directive 1999/45/EC, 67/548/EEC.
DISCLAIMER OF LIABILITY
The information in this MSDS/SDS was obtained from sources which we believe are reliable. However, the(Contd. on page 6)
EU
Page 6/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
Trade name: liquid in glow stick and glow cup
(Contd. of page 5)
DR
information is provided without any warranty, express or implied, regarding its correctness. The conditions
or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond
our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability
for loss, damage or expense arising out of or in anyway connected with the handling, storage, use or disposal
of the product. This MSDS/SDS was prepared and is to be used only for this product. If the product is used as
a component in another product, this MSDS/SDS information may not be applicable.
· ***************************************************************************************End of document
EU
Page 1/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
DR
1 Identification of the substance/preparation and of the company/undertaking
· Product details
· Trade name: liquid in glow stick and glow cup· Registration number: Not available
· Application of the substance / the preparation: Activator
· Manufacturer/Supplier:XIAMEN LONG AFTERGLOW CO., LTD
NO.1043, TONG JI ZHONG ROAD, TONG AN AREA, XIAMEN, FUJIAN PROVINCE, CHINA
TEL :+86-592-3675699
FAX: +86-592-3675400
· Further information obtainable from: XIAMEN LONG AFTERGLOW CO., LTD
· Information in case of emergency:Tina
MP: +86-13600951446
· Email: [email protected]
· Reference Number: GZHGR2010004482; GZ1003017898/CHEM
2 Hazards identification
· Hazard description: Not Applicable
· Information concerning particular hazards for human and environment:The product does not have to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
· Classification system:The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
3 Composition/information on ingredients
· Chemical characterization· Description:
Mixture of the substances listed below with nonhazardous additions.
For the wording of listed risk phrases refer to section 16.
· Dangerous components:
CAS: 7722-84-1
EINECS: 231-765-0
EU number: 008-003-00-9
hydrogen peroxide solution C, Xn, O; R 5-8-20/22-35 3,3%
· Non-dangerous components:
CAS: 7732-18-5
EINECS: 231-791-2
pure water 9,2%
CAS: 131-11-3
EINECS: 205-011-6
dimethyl phthalate 87,5%
4 First aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Rinse with water.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
5 Fire-fighting measures
· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.(Contd. on page 2)
EU
Page 2/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
Trade name: liquid in glow stick and glow cup
(Contd. of page 1)
DR
· Protective equipment: Wear fully protective suit.
6 Accidental release measures
· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
· Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
· Measures for cleaning/collecting:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
· Additional information: See Section 7 for information on safe handling.
7 Handling and storage
· Handling· Information for safe handling: Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection: Keep ignition sources away - Do not smoke.
· Storage· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility: Store away from foodstuffs.
8 Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· Ingredients with limit values that require monitoring at the workplace:
131-11-3 dimethyl phthalate
PEL (USA)
REL (USA)
TLV (USA)
5 mg/m³
5 mg/m³
5 mg/m³
7722-84-1 hydrogen peroxide solution
PEL (USA)
REL (USA)
TLV (USA)
MAK (Germany)
1,4 mg/m³, 1 ppm
1,4 mg/m³, 1 ppm
1,4 mg/m³, 1 ppm
0,71 mg/m³, 0,5 ppm
· DNELs: Not available
· PNECs: Not available
· Additional information: The lists valid during the making were used as basis.
· Personal protective equipment· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
· Respiratory protection: Suitable respiratory protective device recommended.
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves:The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material:The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.(Contd. on page 3)
EU
Page 3/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
Trade name: liquid in glow stick and glow cup
(Contd. of page 2)
DR
· Eye protection: Goggles recommended during refilling
9 Physical and chemical properties
· General Information
Form: Liquid
Colour: Transparent
Odour: Odourless
· Change in conditionMelting point/Melting range: Not available
Boiling point/Boiling range: Not available
· Flash point: Not available
· Flammability (solid, gaseous): Not available
· Ignition temperature: Not available
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation of explosive air/
vapour mixtures are possible.
· Explosion limits:Lower: Not available
Upper: Not available
· Oxidizing properties Not available
· Vapour pressure: Not available
· Density: Not available
· Relative density Not available
· Vapour density Not available
· Evaporation rate Not available
· Solubility in / Miscibility withwater: Not available
· pH-value: Not available
· Segregation coefficient (n-octanol/water): Not available.
· Viscosity:Dynamic: Not available.
10 Stability and reactivity
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Materials to be avoided: Not available
· Dangerous reactions: No dangerous reactions known.
· Dangerous decomposition products: No dangerous decomposition products known.
11 Toxicological information
· Acute toxicity
· LD/LC50 values relevant for classification:
131-11-3 dimethyl phthalate
Oral LD50 6800 mg/kg (rat)
Dermal LD50 >10 mg/kg (rabbit)
(Contd. on page 4)
EU
Page 4/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
Trade name: liquid in glow stick and glow cup
(Contd. of page 3)
DR
· Primary irritant effect· on the skin: Irritating effect possible.
· on the eye: Irritating effect possible.
· Sensitization: Sensitization possible.
· Additional toxicological information:The product is not subject to classification according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version.
When used and handled according to specifications, the product does not have any harmful effects to our
experience and the information provided to us.
· Toxicokinetics, metabolism and distribution: Not available
· Acute effects (acute toxicity, irritation and corrosivity): Not available
· Repeated dose toxicity: Not available
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): Not available
12 Ecological information
· Information about elimination (persistence and degradability): Not available
· Behaviour in environmental systems· Mobility and bioaccumulation potential: Not available
· Ecotoxical effects· Aquatic toxicity: Not available
· Additional ecological information:· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
· PBT assessments: Not available
13 Disposal considerations
· Product· Recommendation: Smaller quantities can be disposed of with household waste.
· Uncleaned packaging· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· Land transport ADR/RID (cross-border)· ADR/RID class: -
· Danger code (Kemler): -
· UN-Number: -
· Packaging group: -
· Hazard label: -
· Description of goods: -
· Limited quantities (LQ): -
· Transport category: -
· Maritime transport IMDG· IMDG Class: -
· UN Number: -
· Label: -
· Packaging group: -
· EMS Number: -
· Marine pollutant: Yes
· Proper shipping name: -
(Contd. on page 5)
EU
Page 5/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
Trade name: liquid in glow stick and glow cup
(Contd. of page 4)
DR
· Air transport ICAO-TI and IATA-DGR· ICAO/IATA Class: -
· UN/ID Number: -
· Label: -
· Packaging group: -
· Proper shipping name: -
15 Regulatory information
· Sara
· Section 335(extremely hazadous substances):
7722-84-1 hydrogen peroxide solution
· Section 313(specific toxic chemical listings):
131-11-3 dimethyl phthalate
· TSCA(Toxic Substances Control Act):
All ingredients are listed.
· Proposition 65
· Chemical known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity foe males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Cancerogenity categories
· EPA(Environmental Protection Agency)
131-11-3 dimethyl phthalate D
· IARC(International Agency for Research on Cancer)
7722-84-1 hydrogen peroxide solution 3
· NTP(National toxicology Program)
None of the ingredients is listed.
· TLV(Threshold Limit Value established by ACGIH)
7722-84-1 hydrogen peroxide solution A3
· NIOSH-Ca(National Institution for Occupational Safety & Health )
None of the ingredients is listed.
· OSHA-Ca(Occupational Safety & Health Administration)
None of the ingredients is listed.
· Labelling according to EU guidelines:Observe the general safety regulations when handling chemicals.
The product is not classified as dangerous according to Directive 67/548/EEC, 1999/45/EC and 1272/2008/
EC.
· Special labelling of certain preparations:Safety data sheet available for professional user on request.
EU
(Contd. on page 6)
Page 6/6
Safety Data Sheet
Printing date 12.03.2010 Revision: 12.03.2010
Trade name: liquid in glow stick and glow cup
(Contd. of page 5)
DR
16 Other information
· Relevant R-phrases20/22 Harmful by inhalation and if swallowed.
35 Causes severe burns.
5 Heating may cause an explosion.
8 Contact with combustible material may cause fire.
· ***************************************************************************************The contents and format of this MSDS/SDS are in according with REGULATION(EC) No. 1907/2006, EU
Commission Directive 1999/45/EC, 67/548/EEC.
DISCLAIMER OF LIABILITY
The information in this MSDS/SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions
or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond
our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability
for loss, damage or expense arising out of or in anyway connected with the handling, storage, use or disposal
of the product. This MSDS/SDS was prepared and is to be used only for this product. If the product is used as
a component in another product, this MSDS/SDS information may not be applicable.
· ***************************************************************************************End of document
EU
Corporation Telephone: (845) 365-8200 * Website: www.dynarex.com
Toll Free: (888) DYNAREX * Website: www.thcnet.com
Fax: (845) 365-8201
Executive Headquarters: Ten Glenshaw Street, Orangeburg, NY 10962
Reviewed on 4/11/13 Page 1 of 2 MATERIAL SAFETY DATA SHEET
Reorder # 1303 / 1331 (BZK Antiseptic Towelettes)
Emergency or Information Phone No.: 845-365-8200 (M-F Daytime) At other times, contact the local Poison Control Center.
Corporation Telephone: (845) 365-8200 * Website: www.dynarex.com
Toll Free: (888) DYNAREX * Website: www.thcnet.com
Fax: (845) 365-8201
Executive Headquarters: Ten Glenshaw Street, Orangeburg, NY 10962
Page 2 of 2
The information furnished herein is believed to be accurate and represents the best data currently available to us. No warranty, expressed or implied, is made and Dynarex Corp. assumes no legal responsibility or liability resulting from its use.
This MSDS has been compiled in accordance with - EC Directive 91/155/EC - OSHA's Hazcom Standard (29 CFR 1910.1200)
Corporation Telephone: (845) 365-8200 * Website: www.dynarex.com
Toll Free: (888) DYNAREX * Website: www.thcnet.com
Fax: (845) 365-8201
Executive Headquarters: Ten Glenshaw Street, Orangeburg, NY 10962
MATERIAL SAFETY DATA SHEET Page 1 of 2
Dtd. 4/4/13
I. PRODUCT IDENTIFICATION PRODUCT/TRADE NAME: ALCOHOL PREP/SWAB – Reorder #’s AM-20200, 1103, 1104, 1106, 1113, 1114, 1116
1203, 1204. HAZARD RATING (NFPA) HEALTH: 1 FLAMMABILITY: 3 REACTIVITY: 0 SPECIFIC: NONE EMERGENCY OR INFORMATION TELEPHONE NO: 845-365-8200 (M-F DAYTIME) AT OTHER TIMES, CONTACT THE LOCAL POISON CONTROL CENTER CHEMICAL NAME: ISOPROPYL ALCOHOL II. HAZARDOUS INGREDIENTS PER 29 CFR 1910.1200 Hazardous Ingredients % ACGIH TLV CAS NUMBER ISOPROPYL ALCOHOL 70 400 ppm 67-63-0 III. PHYSICAL/CHEMICAL CHARACTERISTICS COLOR/ODOR/APPEARANCE: TOWELETTE/PAD/SWAB SATURATED WITH CLEAR LIQUID WITH ALCOHOL ODOR.. BOILING POINT: N/A
FLASH POINT: 78°F VAPOR DENSITY N/A EVAPORATION RATE: N/A SOLUBILITY IN WATER: COMPLETE
SPECIFIC GRAVITY (H2O = 1):N/A IV. FIRE & EXPLOSION HAZARD DATA
FLASH POINT (Method Used): 78°F TAG CLOSED CUP : LEL: 2.0 UEL: 12.0
EXTINGUISHING MEDIA: DRY CHEMICAL OR ALCOHOL TYPE FOAM, CARBON DIOXIDE SPECIAL FIRE FIGHTING PROCEDURES: HANDLE AS FLAMMABLE LIQUID. USE RESPIRATORY PROTECTION FOR FIRE FIGHTING PERSONNEL UNUSUAL FIRE AND EXPLOSION HAZARDS: CLASS 3 FLAMMABILITY V. REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOID NONE INCOMPATIBILITY: NONE HAZARDOUS DECOMPOSITION OR BYPRODUCT: NONE POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: NONE
Corporation Telephone: (845) 365-8200 * Website: www.dynarex.com
Toll Free: (888) DYNAREX * Website: www.thcnet.com
Fax: (845) 365-8201
Executive Headquarters: Ten Glenshaw Street, Orangeburg, NY 10962
ALCOHOL PREP/SWAB
Page 2 of 2
VI. HEALTH HAZARD DATA EFFECTS OF OVER EXPOSURE: SKIN: IF RASH APPEARS, DISCONTINUE USE EYES: WILL CAUSE EYE STING IF SPLASHED INHALATION: NONE INGESTION NOT A NORMAL ROUTE OF ENTRY EMERGENCY AND FIRST AID PROCEDURES: SKIN CONTACT: DISCONTINUE USE IF RASH OR IRRITATION OCCURS EYE CONTACT: FLUSH WITH COLD WATER FOR 15 MINUTES INHALATION: REMOVE TO FRESH AIR INGESTION: INDUCE VOMITING. CALL PHYSICIAN TARGET ORGANS: N/A VII. SPILL AND DISPOSAL PROCEDURE SPILL CONTROL: ELIMINATE ALL SOURCES OF IGNITION WASTE DISPOSAL METHOD: FLUSH SPILLS WITH WATER. HANDLE AS FLAMMABLE LIQUID. FOLLOW LOCAL, STATE AND FEDERAL REGULATIONS. HANDLING AND STORAGE: STORE AWAY FROM HEAT AND SOURCES OF IGNITION VIII. CONTROL MEASURES/PROTECTION RESPIRATION: USE IF PERMISSABLE EXPOSURE LEVEL IS EXCEEDED WHEN HANDLING BULK LIQUID VENTILATION: RECOMMENDED PROTECTIVE GLOVES: NONE REQUIRED EYE PROTECTION: ONLY IF SPLASHING IS EXPECTED HYGIENIC PRACTICES: GOOD HOUSEKEEPING PRACTICES SHOULD BE FOLLOWED. OTHER: DON'T ALLOW LARGE QUANTITIES OF WASTE TO ACCUMULATE IX. TRANSPORT/SHIPPING DOT SHIPPING NAME: N/A TECHNICAL SHIPPING NAME: N/A DOT SHIPPING CLASSIFICATION: DOT-NOT REGULATED DOT ID NO.: N/A DOT LABEL REQUIREMENTS: N/A UN/NA NUMBER REGULATIONS: N/A REPORTABLE QUANTITY: N/A X. DISCLAIMER THE INFORMATION FURNISHED HEREIN IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST DATA CURRENTLY AVAILABLE TO US. NO WARRANTY, EXPRESSED OR IMPLIED IS MADE AND DYNAREX CORPORATION ASSUMES NO LEGAL RESPONSIBILITY OR LIABILITY RESULTING FROM ITS USE.
Page 1 of 4
Corporation Telephone: (845) 365-8200 * Website: www.dynarex.com
Toll Free: (888) DYNAREX * Website: www.thcnet.com
Fax: (845) 365-8201
Reorder # 1408 Reviewed on 4/11/13
Material Safety Data Sheet
SECTION 1. Product and Company Identification
Product/Trade Name: Sting & Bite Pad
Manufacturer's Name: Dynarex Corporation
Manufacturer's Address: 10 Glenshaw Street Orangeburg, NY 10941
Emergency or Information Phone No.:
888-DYNAREX or 845-365-8201 At other times, contact the local Poison Control Center
Page 2 of 4
Corporation Telephone: (845) 365-8200 * Website: www.dynarex.com
Toll Free: (888) DYNAREX * Website: www.thcnet.com
Fax: (845) 365-8201
Page 3 of 4
Corporation Telephone: (845) 365-8200 * Website: www.dynarex.com
Toll Free: (888) DYNAREX * Website: www.thcnet.com
Fax: (845) 365-8201
Page 4 of 4
Corporation Telephone: (845) 365-8200 * Website: www.dynarex.com
Toll Free: (888) DYNAREX * Website: www.thcnet.com
Fax: (845) 365-8201
SECTION 16. Other Information Disclaimer: The information furnished herein is believed to be accurate and represents the best data currently available to us. No warranty, expressed or implied, is made and Dynarex Corp. assumes no legal responsibility or liability resulting from its use. This MSDS has been compiled in accordance with - EC Directive 91/155/EC - OSHA's Hazcom Standard (29 CFR 1910.1200)
Date Prepared: March 2011