TORRES-VERDIN Salt Saturation in-Sut

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    March-April 2004 PETROPHYSICS 141

    Assessment of In-Situ Hydrocarbon Saturation in the Presence of Deep

    Invasion and Highly Saline Connate Water1

    Carlos Torres-Verdn2, Bovan K. George

    2, Mojdeh Delshad

    2, Richard Sigal

    3,

    Farid Zouioueche3, and Barbara Anderson

    4

    INTRODUCTION

    The drilling of wells with heavy mud causes large over-

    balance pressures, resulting in deep invasion of mud filtrate

    into porous and permeable layers. In the past, the effect of

    mud-filtrate invasion on induction logs has been studied

    using simplified models of radial invasion. The simplest

    invasion model is the step invasion profile, which assumes

    a completely flushed zone of resistivityRxo and diameterDi,

    beyond which lies the undisturbed (virgin) formation of

    resistivity Rt. Such a model embodies three unknowns (Rt,

    Rxo,andDi) that, in theory, can be resolved using three resis-

    tivity logs exhibiting complementary depths of investiga-

    tion. This is a useful but idealistic approach because a sharp

    boundary seldom exists between the completely flushed

    PETROPHYSICS, VOL. 45, NO. 2 (MARCH-APRIL 2004); P. 141156; 22 FIGURES, 5 TABLES

    ABSTRACT

    This paper describes a field study undertaken to quan-

    tify the effects of mud-filtrate invasion on resistivity

    induction logs. The objective is to assess in-situ gas satu-

    ration in a low-porosity carbonate formation. A large dis-crepancy between the salinity of connate water and drill-

    ing mud is responsible for the presence of a substantial

    low-resistivity annulus in the near-wellbore region. This

    annulus suppresses the sensitivity of electromagnetic

    induction currents to detecting gas saturation in the virgin

    zone. A quantitative explanation for the presence of the

    low-resistivity annulus is presented based on the physics of

    mud-filtrate invasion.

    The process of mud-filtrate invasion is modeled with a

    two-dimensional chemical flood simulator that includes

    the effect of salt mixing between mud filtrate and connate

    water. Radial resistivity profiles are obtained from the

    simulated spatial distributions of water saturation and salt

    concentration using Archies law. These profiles confirm

    the presence of the low-resistivity annulus in the transi-

    tion region between the flushed and virgin zones. Numeri-

    cal simulation of induction logs validates the agreement

    between the mud-filtrate invasion model and the available

    wireline induction logs.

    An extensive sensitivity analysis is performed to quan-tify the effect of several petrophysical parameters on the

    spatial distributions of water saturation and salt concen-

    tration. Results from this study show that the pre-annulus

    and annulus segments of the radial resistivity profile

    remain insensitive to initial water saturation, thereby

    impeding the estimation of in-situ gas saturation from

    resistivity induction logs alone. Modeling of the process

    of mud-filtrate invasion is the only possible way to esti-

    mate in-situ hydrocarbon saturation from induction logs.

    It is also found that laterolog measurements are only mar-

    ginally affected by the presence of a low-resistivity annu-

    lus.

    The sensitivity analysis described in this paper pro-

    vides a rigorous quantitative method to assess the effects

    of different types of muds on the invaded zone prior to

    drilling.

    Manuscript received by the Editor July 4, 2003; revised manuscript received February 4, 2004.1Originally presented at the SPWLA 44th Annual Logging Symposium, June 22-25, 2003, Galveston, Texas, paper K.2The University of Texas at Austin, Austin, Texas USA.

    3Anadarko Petroleum Corporation4Schlumberger-Doll Research, Ridgefield, CT

    2004 Society of Petrophysicists and Well Log Analysts. All rights reserved.

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    zone of resistivity Rxo and the undisturbed formation of

    resistivity Rt. In the past, slightly more sophisticated radial

    parametric models of mud-filtrate invasion have been used

    for interpretation, including three-stage ramp and annulus

    resistivity profiles. Actual radial fluid saturation and resis-

    tivity profiles can be quite complex and largely depend on

    specific petrophysical properties of the rock as well as on

    the properties of the fluids involved. A specific radial para-

    metric model of electrical resistivity cannot be uniquely

    interpreted from resistivity induction data alone without

    prior knowledge of the fluid and rock-fluid formation prop-erties.

    The study presented in this paper is focused on a

    gas-bearing carbonate formation. This formation was pene-

    trated by well X-2 using a heavy freshwater base mud,

    thereby causing an overbalance pressure in excess of 1000

    psi. Table 1 describes the properties of the mud used to drill

    well X-2. Lithology in the gas-bearing zone consists of

    inter-layered carbonates along with fine-grained clastics

    and shales. Porosity of the gas-bearing formation is low,

    usually less than 15%, hence contributing to deep invasion.A major challenge faced in theevaluation of this reservoiris

    the deep invasion of mud filtrate adversely affecting the

    response of resistivity measurements. Gas saturation of the

    formation is about 80-85% with the remaining pore space

    occupied by irreducible connate water. Salinity of the mud

    filtrate is about 2,000 ppm whereas the salinity of connate

    water is about 200,000 ppm. Dual Induction Logs (DIL*)

    acquired in well X-2 (shown in Figure 1) exhibit a reverse

    resistivity profile where deep dual-induction (ILD) read-

    ings (20-22 ohm-m) are lower than the medium dual-induc-

    tion readings (ILM, 25-30 ohm-m). Both ILD and ILM

    readings are lower than the shallow, Rxo readings (90-100ohm-m) indicated by MSFL and SFL.

    A nearby well, here identified as X-1, was drilled a few

    hundred feet away from well X-2. This well was drilled

    with a light mud resulting in very shallow invasion. Table 2

    describes the properties of the mud used to drill well X-1.

    Resistivity logs acquired in well X-1 exhibit a normally

    ordered resistivity profile across the same carbonate forma-

    tion (shown in Figure 2) with the following array induction

    (AIT*) readings: AIT90 = 50-60 ohm-m, AIT60 = 40-50

    ohm-m and AIT10 = 30-35 ohm-m. In addition to Array

    Induction data, Dual Laterolog (DLL*) data were acquired

    in well X-1 (shown in Figure 3). Well X-1 is considered a

    key well in the present study due to both negligible invasionand the availability of extensive log and core data. Rock

    core and well-log data acquired in well X-1 are used as a

    benchmark in the present work. This well provides a unique

    reference to quantify the effect of mud-filtrate invasion on

    142 PETROPHYSICS March-April 2004

    Torres-Verdn et al.

    *Mark of Schumberger

    TABLE 1 Summary of measured mud properties for Well X-2 (the well that exhibits deep invasion).

    Depth Mud Weight Viscosity Loss Control Chloride W/L Solids

    (ft) (ppg) (cp) Material (lb/gal) Ph (ppm) (cc/30 min.) (%)

    X215 NativeX920 8.8 35 6 8.5

    X500 9 33 6 8

    X080 8.9 36 6 8 1200

    X540 9 38 6 8.8 1000 14 5.2

    X015 9 38 8 8 900 13 5

    X375 9.1 38 8 8.5 900 11

    X730 9.1 37 8 8.5 900 11 Bit Trip

    X200 9.1 50 8 9.9 800 9.2

    X300 9.1 50 8 10 950 9.6 5.7

    TABLE 2 Summary of measured mud properties for WellX-1 (the well that exhibits negligible invasion).

    Depth Mud Weight Viscosity Chloride

    (ft) (ppg) (cp) Ph (ppm)

    X444 1.2 81 8.1 1250

    X497 1.1 81 8 400

    X552 0.96 82 8.1 280

    X559 1.1 82 8.02 260

    X592 1.2 82 8.02 240

    X608 1.2 82 8 230

    X608 9 82 8.03 320

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    March-April 2004 PETROPHYSICS 143

    Assessment of In-Situ Hydrocarbon Saturation in the Presence of Deep Invasion and Highly Saline Connate Water

    FIG. 1 Plot of the basic suite of measured wireline logs in Well X-2, including dual induction readings.

    FIG. 2 Plot of the basic suite of measured wireline logs in Well X-1, including array induction readings.

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    the resistivity logs acquired along the same carbonate for-

    mation in well X-2.

    Lower-than-normal deep resistivity readings cause over-

    estimation of connate-water saturation, which results in

    underestimated hydrocarbon reserves. The study reported

    in this paper was undertaken to quantify the effect ofmud-filtrate invasion on resistivity logs. It was anticipated

    that proper modeling of the mud-filtrate invasion profile

    would help to correct deep resistivity readings and hence to

    improve estimates of in-situ water saturation using existing

    well-log data. Preliminary studies performed prior to the

    work reported in this paper had suggested the presence of a

    substantial low-resistivity annulus as the cause of the low

    resistivity readings in well X-2.

    In the past, presence of low-resistivity annuli has been

    discussed by several authors, including Dumanoir et al.,

    1957, Gondouin et al., 1964, Ramakrishnan and Wilkinson,

    1999, and Zhang et al., 1999. However, a consistent andsystematic petrophysical explanation for the origin and

    properties of such an annulus has not been presented before

    in light of actual field data. This paper develops a consistent

    explanation for the presence of a low resistivity annulus

    based on the physics of mud-filtrate invasion and salt mix-

    ing between mud filtrate and irreducible connate water. The

    model of mud-filtrate invasion is benchmarked against

    measured borehole induction resistivity data and conclu-

    sions are drawn concerning the interpretation of in-situ

    hydrocarbon saturation in the virgin zone.

    Invasion of mud filtrate into the formation is modeled asa two-dimensional (2D) axisymmetric chemical flood pro-

    cess. Filtrate invasion is simulated to obtain cross-sections

    of water saturation as a function of depth and radial distance

    away from the borehole wall. Cross-sections of salt concen-

    trations are also obtained by modeling the mixing of salt

    between the invading fresh mud filtrate and the highly

    saline connate water. As shown below, the radial variation

    of salt concentration within the invasion zone is responsible

    for the presence of a low resistivity annulus around the

    borehole.

    NUMERICAL SIMULATION

    OF MUD-FILTRATE INVASION

    Mud-filtrate invasion is treated in an equivalent manner

    to the process of water injection into a gas reservoir.

    Accordingly, two-phase immiscible fluid flow is assumed

    144 PETROPHYSICS March-April 2004

    Torres-Verdn et al.

    FIG. 3 Plot of the basic suite of the measured wireline logs in Well X-1, including dual laterolog readings (compare to the inductionlogs shown in Figure 2).

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    in the simulations of mud-filtrate invasion (Dewan and

    Chenevert, 2001, and Semmelbeck et al., 1995). Rate of

    invasion of mud filtrate across the borehole wall is calcu-

    lated as a flow rate function resulting from mudcake

    buildup (Wu et al., 2001). The flow of mud filtrate through

    mudcake can be described by Darcys law, i.e.,

    QkA P

    hf

    mc

    =m

    D, (1)

    where Qfis the flow rate of mud filtrate across the borehole

    wall, kis the mud cake permeability, A is the cross-sectional

    area through which the filtrate flows,m is the viscosity of fil-trate, hmc is the thickness of mud cake, and DP is the pressuredrop across the mud cake.

    In this paper, flow of mud filtrate across the mudcake is

    modeled using an axisymmetric version of the 3D

    multi-phase, multi-component compositional simulator

    UTCHEM, developed by The University of Texas at Austin(Saad, 1989, and Delshad et al., 1996). Both dynamic

    growth of mudcake thickness and dynamic decrease of

    mudcake permeability are coupled to formation properties

    (Wu et al., 2001). This process results in a dynamic

    monotonic decrease of flow rate across the borehole wall.

    After a short initial spurtof mud-filtrate invasion, the rate of

    flow is found to reach a steady-state value specific to a par-

    ticular layer. In the present work, the layer-dependent rate

    of mud-filtrate invasion is assumed to be the steady-state

    value yielded by the simulations of invasion. The simula-

    tion of mud-filtrate invasion can also take into account sev-

    eral cycles of mudcake rub-off and buildup.Assumptions made by the reservoir simulation model are

    those of multi-component immiscible fluid displacement

    governed by Darcys law and mass balance. The general

    form of the mass balance equation for the k-th component

    can be written as

    f r r

    tC C u D Rk k k k l l kl

    l

    n

    k

    p

    ( ) (~

    ) ,+ -

    =

    =

    1

    (2)

    where f is porosity, Ck is the overall concentration of com-ponent k per unit pore volume, Ckl is the concentration of

    component k in phase l, rk is fluid density, ul is the Darcyflux for phase l, Rk is the total source/sink term for compo-nent, kand

    ~Dkl the dispersive flux, defined as

    ~, D S K C k l l k l k l = f (3)

    where Sl is the saturation for phase l, and Kkl is a dispersion

    tensor. The latter tensor includes contributions from molec-

    ular diffusion and hydrodynamic dispersion (Bear, 1979). A

    more detailed discussion of both model formulation and

    solution algorithm used by UTCHEM may be found in Saad

    (1989) and Delshad et al. (1996).

    Salt mixing between mud filtrate and connate water is

    modeled as part of the fluid-flow simulations performed

    with UTCHEM. The three most important mechanisms

    causing the transport of salt in permeable media are viscousforces, gravity forces, and dispersion (diffusion) forces

    where the driving mechanisms are pressure, density, and

    salt concentration gradients, respectively. The transport of

    salt is described by the convection-diffusion equation.

    As the invading mud filtrate moves radially into the for-

    mation, it mixes the uneven concentrations of salt in mud

    filtrate and connate water. There are two mechanisms for

    dispersive transport that take place in the mixing of fresh

    and salt water, i.e., convective and molecular dispersion.

    Convective dispersion is the mixing due to variations in

    local velocity both in magnitude and direction. Molecular

    diffusion is mixing resulting from variations in salt concen-

    tration, and takes place in the absence of flow. The disper-

    sion tensorKkl contained in equation (3) includes the effect

    of molecular diffusion, and can be written as (for the i and j

    directions)

    KD

    Su

    S

    u u

    uklij

    kl

    ij

    Tl

    l

    l ij

    L l Tl

    l

    li lj

    l

    = + +-

    td

    a

    fd

    a a

    f

    ( ), (4)

    where Dkl is the molecular diffusion coefficient, t is atortuosity factor, aL and aT are the longitudinal and trans-verse dispersivities, respectively, dij is the Kronecker deltafunction, and uli and ulj are the components of Darcys

    velocity of the phase lin the i andj directions, respectively.The first term in the right-hand side of equation (4) is due

    to diffusive transport and the second term in the same equa-

    tion represents dispersion due to convective transport. For

    very small flow rates of mud filtration, the convective term

    becomes negligible and the total mixing is caused mainly

    by diffusion. For higher flow rates where the interstitial

    velocity is greater than about 3 cm/day (Lake, 1989), con-

    vective mixing dominates diffusive mixing. This is because

    for large fluid velocities in the pores, time available for dif-

    fusion will not be sufficient for complete mixing. In the

    present work, the flow rate of mud filtration taking place

    across a layer of thickness 2 ft is about 8 ft

    3

    /day. This corre-sponds to an interstitial velocity of about 320 cm/day near

    the borehole wall assuming a porosity of 0.14. At such large

    interstitial fluid velocities, mixing is predominantly gov-

    erned by convective transport.

    Two-dimensional cylindrical flow is assumed for the

    numerical simulation of mud-filtrate invasion near the

    borehole (i.e. 3D flow with no spatial variations in the azi-

    muthal direction). A finite-difference scheme is used to

    discretize and numerically solve equations (2) and (3).

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    Two-dimensional cross-sections of water saturation and

    salt concentration are obtained directly from the simulation

    results. In turn, salt concentration is transformed into an

    equivalent value of connate water resistivity, Rw, using the

    conversion formula (Dresser Atlas Inc., 1982)

    RC T

    w

    w

    = +

    +

    0012336475 82

    18 390 955.

    .

    .,

    .(5)

    where Tis temperature measured in degrees Centigrade, and

    Cw is salt concentration measured in ppm.

    WATER SATURATION AND ELECTRICAL

    RESISTIVITY IN THE INVADED ZONE

    As described in the preceding section, cross-sections of

    water saturation and salt concentration are obtained as the

    output of the numerical simulation of mud-filtrate invasion.

    In turn, values of water salinity and salt concentration are

    transformed into an equivalent value of water resistivity

    using equation (5). The final step is to compute the corre-sponding spatial distribution of electrical resistivity. This is

    accomplished using Archies equation, namely,

    SR

    R

    awn w

    tm

    =f

    , (6)

    where Sw is water saturation, a is the tortuosity/cementation

    factor, n is the saturation exponent, f is porosity, and m isthe cementation exponent. The use of Archies law in the

    present study is justified given the clastic nature of the car-

    bonate sequence under consideration. In addition, the high

    salinity of connate water makes it unnecessary to apply cor-

    rections for the presence of clay to Archies equation. Tables

    3a and 3b describe the specific values used in this study for

    the various parameters included in equation (6).

    Simulation of mud-filtrate invasion was performed on a

    5-layer synthetic model reconstructed from the depth inter-

    val X493-X551 ft of Well X-2 shown in Figure 1. As illus-

    trated in Figure 4, two of these five layers were placed on

    the upper and lower boundaries of the model and consisted

    of impermeable shale barriers. The remaining three layers

    146 PETROPHYSICS March-April 2004

    Torres-Verdn et al.

    TABLE 3a Summary of rock properties for well X-2.

    Horiz. Perm. Vertical Perm. Tortuosity-Cementation Cementation Exponent Saturation Exponent

    Porosity (md) (md) Factor, a m n

    0.14 6.83 0.93 1 2 2

    Table 3b Summary of mud, formation, and fluid properties for well X-2.

    Invasion Initial Formation Formation Salinity of Salinity of

    Time Water Temperature Pressure Mud Filtrate Connate Water

    (Days) Saturation (Swi) (deg F) (psi) (ppm) (ppm)

    4 0.14 98 96 2,000 200, 000

    FIG . 4 Graphical description of the geometrical andpetrophysical properties of the reservoir model considered inthis paper. There are three reservoir layers (flow units) and twoimpermeable shale barriers. Porosity, vertical permeability, andthickness for the three reservoir layers are indicated on the fig-ure. The three reservoir layers exhibit a vertical permeability of0.93 md.

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    in the interval X506-X536 ft, correspond to separate flow

    units within the actual reservoir formation. The finite-dif-

    ference grid used in the numerical simulation of mud-fil-

    trate invasion consisted of 60 grid steps in the radial direc-

    tion and 4 grid steps per layer in the vertical direction.

    Radial grid steps were increased in geometrical progressionfrom the borehole wall into the formation in order to prop-

    erly reproduce the rapid spatial variations of fluid satura-

    tion and salt concentration in the near-borehole region. This

    grid was also the result of a refinement study undertaken to

    assess the internal consistency and numerical accuracy of

    the simulated cross-sections of water saturation and salt

    concentration.

    Capillary pressure data (shown in Figure 5) from labora-

    tory measurements for the drainage cycle is available for

    the permeable reservoir layers described in Figure 4.

    Because of the lack of laboratory capillary pressure for the

    imbibition cycle, the available drainage-cycle data were

    used in the numerical simulations for the imbibition cycle

    of capillary pressure. The water-gas relative permeability

    data used for the numerical simulation of mud-filtrate inva-

    sion is shown in Figure 6 (henceforth referred to as Type-A

    water-gas relative permeability curves). Capillary pressure

    and relative permeability curves were assumed the same for

    the three reservoir layers shown in Figure 4.

    Figure 7 shows a radial profile of the numerically simu-

    lated cross-sections of water saturation and water resistivity

    taken through the center of the upper (and thicker) reservoir

    layer graphically described in Figure 4. Petrophysical prop-

    erties of this layer are given in Tables 3a and 3b as well as in

    Figure 4. Simulation of mud-filtrate invasion was per-

    formed assuming an invasion time of four days. The inva-

    sion profile shows a radial length of invasion of about 7

    feet, whereas the salinity profile, represented as Rw, shows

    that salt concentration near the borehole is very low, equal

    March-April 2004 PETROPHYSICS 147

    Assessment of In-Situ Hydrocarbon Saturation in the Presence of Deep Invasion and Highly Saline Connate Water

    FIG. 6 Plot of the original (TYPE A) water-gas relative perme-ability curves. The dark and light lines represent relative perme-ability curves as a function of water saturation for water and gasfluid fractions, respectively.

    FIG. 7 Plots of water resistivity (Rw) and water saturation (Sw)as a function of radial distance away from the borehole wall. Thetwo curves were obtained from the 2D numerical simulation ofthe process of mud-filtrate invasion assuming an invasion timeof four days. The radial profile is taken through the upper reser-voir layer shown in Figure 4.

    FIG. 5 Plot of capillary pressure as a function of water satura-tion measured on rock core samples. Only the drainage cycle ofthe capillary pressure curve was available for the studydescribed in this paper. The imbibition cycle of capillary pres-sure was assumed equal to the drainage cycle.

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    to that of mud filtrate. Salt concentration begins to increase

    at a radial distance of about 4 feet from the borehole wall

    and it attains a maximum value (equal to that of the salinity

    of connate water) at a radial distance of about 6 feet from

    the borehole wall.

    It becomes evident from Figure 7 that, as the invasion ofmud-filtrate progresses, the salt concentration front trails

    the saturation front. This behavior results in a high-salinity,

    high water saturation region at the front face of the advanc-

    ing mud-filtrate column. Intuitively, it is the dephasing

    and distortion of the water concentration front with

    respect to the salt saturation front that causes the pres-

    ence of the low-resistivity annulus. The electrical resistiv-

    ity profile (Rt) calculated with the use of equation (6) shows

    a low-resistivity annulus at a distance of about 5 feet from

    the borehole wall (Figure 8). The deep resistivity log, with a

    depth of investigation of about 5-6 feet, is for the most part

    sensing an average of the electrical conductivity of the

    invaded zone and the annulus region. On the other hand, the

    shallow resistivity log senses the higher resistivity of about

    110 ohm-m closer to the borehole wall. This model agrees

    with the observed deep (ILD = 20-22 ohm-m), medium

    (ILM = 25-30 ohm-m) and shallow (MSFL = 90-100

    ohm-m) resistivity readings reported by the field log shown

    in Figure 1. The true resistivity of the formation is about 90

    ohm-m, which is much higher than the measured deep

    induction resistivity (20-22 ohm-m). Water saturation cal-

    culated using the true formation resistivity is about 15%

    whereas that calculated using the deep induction measure-

    ments is about 28-30%. Therefore, a nave reservoir evalua-

    tion performed with the deep induction measurements will

    result in underestimation of in-place hydrocarbon reserves

    if the low resistivity annulus is not taken into account.

    SENSITIVITY OF THE SPATIAL DISTRIBUTION OF

    MUD-FILTRATE INVASION TO VARIOUS

    PETROPHYSICAL PARAMETERS

    A detailed sensitivity analysis was performed to assess

    the effects of various invasion, rock, and fluid parameters

    on the simulated two-dimensional cross-sections of electri-

    cal resistivity. Reference formation and fluid properties

    used in the simulations are summarized in Tables 3a and 3b

    as well as in Figure 4. Moreover, the capillary pressure and

    relative permeability curves used as reference are the ones

    described in Figures 5 and 6, respectively.

    The sensitivity analysis described below consisted of

    making slight changes to the benchmark parameters and of

    assessing the influence of such changes on the calculatedcross-sections of electrical resistivity. Results from this

    sensitivity analysis are summarized in Table 4. For conve-

    nience, we choose to describe the two-dimensional

    cross-sections in the form of radial profiles of electrical

    resistivity. Only one such radial profile is analyzed and is

    taken through the center of the upper (and thicker) reservoir

    layer shown in Figure 4. The radial profile is described in

    terms of the following parameters: (a) Rxo, (b) Rt, (c) resis-

    tivity of the annulus, Rann, (d) radial location of the resistiv-

    ity annulus measured away from the borehole wall, and (c)

    radial width of the resistivity annulus.

    148 PETROPHYSICS March-April 2004

    Torres-Verdn et al.

    FIG. 8 Plot of electrical resistivity as a function of radial dis-tance away from the borehole wall calculated from the waterand salt concentration profiles shown in Figure 7. The radial pro-file is taken through the upper reservoir layer shown in Figure 4.

    FIG. 9 Plot of electrical resistivity as a function of radial dis-tance away from the borehole wall calculated for five times ofinvasion (measured in hours or days). The radial profile is takenthrough the upper reservoir layer shown in Figure 4.

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    Figure 9 illustrates the sensitivity of electrical resistivity

    to time of invasion. The low resistivity annulus is located at

    a radial distance of 2.5 feet after 1 day of invasion. As the

    invasion progresses, the annulus moves radially away from

    the borehole wall. Width of the annulus also increases with

    time of invasion. Hence, the resistivity measured by induc-

    tion logging tools will vary depending on the time of log-

    ging. The acquired resistivity readings will be erroneously

    low when the spatial region of investigation of a particular

    measurement comprises the annulus. An unbiased resistiv-

    ity measurement can only be obtained if the logs are

    acquired a short time after the onset of invasion.

    Sensitivity of electrical resistivity to formation porosity

    is described in Figure 10. Porosities of 0.07, 0.14 and 0.28

    were considered for the analysis. When the porosity is

    reduced to half (0.07) of its reference value, the annulus

    moves farther away from the borehole and its width

    increases. For higher porosities, the annulus remains closer

    to the borehole wall and its width becomes smaller. As sug-

    gested by equation (6), the electrical resistivity increases as

    porosity decreases from 0.28 to 0.07.

    Figure 11 shows radial profiles of electrical resistivity

    simulated for different values of connate water salinity.

    Connate water salinity affects the resistivity of the annulus

    as well as the resistivity of the virgin formation. By con-

    trast, the flushed zone resistivity remains unaffected by the

    March-April 2004 PETROPHYSICS 149

    Assessment of In-Situ Hydrocarbon Saturation in the Presence of Deep Invasion and Highly Saline Connate Water

    TABLE 4 Summary of the calculated sensitivity of radial variations of electrical resistivity to specific perturbations of invasion,petrophysical, and fluid parameters.

    Sensitivity Value of Rxo, Rann, Rt, Distance of Width of

    Parameter Parameter ohm-m ohm-m ohm-m Annulus, ft Annulus, ft

    Days of 6 Hrs 105 5 90 1 1

    Invasion 1 Day 105 5 90 2 2

    2 Days 105 5 90 3 2.5

    4 Days 105 5 90 4.5 3.25

    6 Days 105 5 90 5.5 3.5

    Porosity Porosity/2 435 20 370 6 3

    Porosity 105 5 90 4 2.5

    2*Porosity 25 3 22 3 1.5

    Initial Water Swi/2 105 5 360 4.5 2.5

    Saturation, Swi Swi 105 5 90 4.5 2.5

    2*Swi

    105 5 23 4.5 3.5

    Salinity of Mud Salinity 105 5 90 4.5 2.5

    Filtrate 2*Salinity 54 5 90 4.5 2.5

    5*Salinity 23 5 90 4.5 2.5

    10*Salinity 12 5 90 4.5 2.5

    Salinity of Salinity 105 5 90 4.5 2.5

    Connate Water Salinity/4 105 22 270 5 2.5

    Salinity/8 105 32 490 5.5 2.5

    Saturation 1.5 105 5 35 4.5 2.5

    Exponent, n 2 105 5 90 4.5 2.5

    2.5 105 5 240 4.5 2.5

    Cementation 1.5 40 2 37 4.5 2.5

    Exponent, m 2 105 5 90 4.5 2.5

    2.5 280 12 240 4.5 2.5

    Mixing 100% 105 5 90 4.5 2.5

    Efficiency 50% 55 5 90 3.5 3.5

    25% 28 7 90 2.5 4.5

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    presence of an annulus as it is almost entirely saturated with

    mud filtrate. Figures 12 and 13 describe the sensitivity of

    the radial resistivity profile to the saturation exponent, n,

    and to the cementation exponent, m, respectively. A varia-

    tion ofn affects mainly the undisturbed formation resistiv-

    ity, whereas changes in m affect the resistivities of theflushed zone, of the annulus, and of the virgin formation.

    Figure 14 describes the effect of changing the mud-fil-

    trate salinity on electrical resistivity. The radial profile of

    electrical resistivity across the flushed zone varies for dif-

    ferent values of mud-filtrate resistivity. However, both the

    resistivity of the annulus and the resistivity of the undis-

    turbed formation remain unchanged.Resistivity profiles calculated for different values of ini-

    150 PETROPHYSICS March-April 2004

    Torres-Verdn et al.

    FIG. 11 Plots of electrical resistivity as a function of radial dis-tance away from the borehole wall calculated for three differentvalues of connate water salinity (measured in ppm). The radialprofile is taken through the upper reservoir layer shown in Figure4 and the assumed invasion time is four days.

    FIG. 12 Plots of electrical resistivity as a function of radial dis-tance away from the borehole wall calculated for three differentvalues of Archies saturation exponent, n. The radial profile istaken through the central reservoir layer shown in Figure 4 andthe assumed invasion time is four days.

    FIG. 10 Plots of electrical resistivity as a function of radial dis-tance away from the borehole wall calculated for three values offormation porosity. The radial profile is taken through the upperreservoir layer shown in Figure 4 and the assumed invasion timeis four days.

    FIG. 13 Plots of electrical resistivity as a function of radial dis-tance away from the borehole wall calculated for three differentvalues of Archies cementation exponent, m. The radial profileis taken through the upper reservoir layer shown in Figure 4 andthe assumed invasion time is four days.

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    tial water saturation (Swi) are shown in Figure 15. Capillary

    pressure and relative permeability curves were adjusted to

    conform to the various values of initial water saturation

    considered by this sensitivity analysis. The initial water sat-

    uration affects both the undisturbed formation resistivity

    and the width of the annulus, but has no effect on either theannulus resistivity or the flushed-zone resistivity. This is a

    significant result for the present work. It means that the

    pre-annulus and annulus segments of the resistivity profile

    remain highly insensitive to initial water saturation. If bore-

    hole resistivity measurements are only sensitive to the

    pre-annulus and annulus segments of the resistivity profile,

    then the same result indicates that estimation of in-situ gas

    saturation is not possible from resistivity measurements

    alone.

    The convective and dispersive term for the salt species

    contained in equation (2) can be further multiplied by a

    coefficient to control the efficiency of salt mixing. A value

    of one corresponds to complete mixing while a value of

    zero for the same coefficient corresponds to no mixing.

    Efficiency of salt mixing was of interest as there was some

    preliminary indication that salt mixing could be condi-

    tioned by the dual pore-size distribution exhibited by reser-

    voir rocks (micro and macro porosity). The effect of salt

    mixing efficiency between mud filtrate and connate water is

    graphically illustrated in Figure 16. Mixing efficiency

    affects the width of the annulus as well as the resistivity of

    the flushed zone. However, it has no significant effect on

    the resistivity of the annulus.

    Sensitivity analysis was also performed to assess the role

    played by relative permeability on the spatial distributions

    of water saturation and salt concentration. To this end, the

    Type-A water-gas relative permeability curves shown in

    Figure 6 were modified to construct the Type-B relative

    permeability curves shown in Figure 17. It is emphasizedthat the Type-B relative permeability curves exhibit a much

    lower value of critical water saturation than the Type-A

    March-April 2004 PETROPHYSICS 151

    Assessment of In-Situ Hydrocarbon Saturation in the Presence of Deep Invasion and Highly Saline Connate Water

    FIG. 15 Plots of electrical resistivity as a function of radial dis-tance away from the borehole wall calculated for three values ofinitial water saturation,Swi. The radial profile is taken through theupper reservoir layer shown in Figure 4 and the assumed inva-sion time is four days.

    FIG. 14 Plots of electrical resistivity as a function of radial dis-tance away from the borehole wall calculated for four values ofmud-filtrate salinity (measured in ppm). The radial profile istaken through the upper reservoir layer shown in Figure 4 andthe assumed invasion time is four days.

    FIG. 16 Plots of electrical resistivity as a function of radial dis-tance away from the borehole wall calculated for three values ofsalt mixing efficiency. The radial profile is taken through theupper reservoir layer shown in Figure 4 and the assumed inva-sion time is four days.

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    curves. Simulation results for Sw and Rw, as well as for the

    computed resistivity profile, Rt, using the Type-B relative

    permeability curves are shown in Figures 18 and 19, respec-

    tively. The water saturation front is less sharp compared to

    that of the reference model (shown in Figure 7). Radial

    resistivities monotonically increase in the flushed zoneregion, rising to a maximum of 155 ohm-m, then steeply

    falling into the annulus region to finally reach the true for-

    mation resistivity. Resistivity logs acquired in such an envi-

    ronment will yield medium resistivity values (ILM) and Rxoresistivity values higher than the deep resistivity reading

    (ILD). A visual comparison of Figures 8 and 19 conveys the

    important message that the shape of the electrical resistivity

    profile can be drastically changed with a perturbation in the

    relative permeability curves. This is so because, in additionto capillary pressure, relative permeability curves control

    the shape, location, and radial extent of the water saturation

    front. The salt concentration front, on the other hand, is

    mainly controlled by fluid transport.

    Results from the above sensitivity analysis are summa-

    rized in Table 4. It can be concluded that the radial location

    of the low-resistivity annulus is primarily influenced by

    porosity and time of invasion. The lower the porosity and

    the longer the time of invasion, the longer the radial dis -

    tance between the wellbore and the low-resistivity annulus.

    On the other hand, the size and width of the low-resistivity

    annulus are primarily controlled by (a) the difference in

    salinity between connate water and mud filtrate, (b) the ini-

    tial water saturation, and (c) porosity and the cementation

    and saturation exponents contained in Archies formulas. It

    is also found that a variation in the end points and curvature

    of the relative permeability curves can drastically distort

    the shape of the radial profile of electrical resistivity. Quan-

    tification of the sensitivity of radial profiles of electrical

    resistivity to additional mud and petrophysical parameters

    can be found in George (2003).

    152 PETROPHYSICS March-April 2004

    Torres-Verdn et al.

    FIG. 19 Plot of electrical resistivity as a function of radial dis-tance away from the borehole wall calculated from the watersaturation and salt concentration profiles shown in Figure 18 (inturn calculated assuming the TYPE-B relative permeabilitycurves shown in Figure 17).

    FIG. 18 Plots of water resistivity (Rw) and water saturation (Sw)as a function of radial distance away from the borehole wall andthrough the upper reservoir layer shown in Figure 4. The twocurves were obtained from the 2D numerical simulation of theprocess of mud-filtrate invasion using the TYPE-B relative per-meability curves shown in Figure 17 and assuming an invasiontime of four days.

    FIG. 17 Plots of the TYPE B relative permeability curves. Thedark and light lines represent relative permeability curves as afunction of water saturation for gas and water fluid fractions,respectively (compare to Figure 6).

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    NUMERICAL SIMULATION OF BOREHOLE

    RESISTIVITY MEASUREMENTS

    Readings of various borehole resistivity tools were sim-

    ulated numerically using as input the computed cross-sec-

    tions of electrical resistivity. Figure 20 shows apparent

    resistivity values simulated for dual induction, array induc-tion, and dual laterolog tools as a function of the time of

    invasion, from 2 to 6 days. The shallow array induction

    reading, AIT10, provides a good indication ofRxo asit isnot

    affected by the presence of the annulus. This is because

    after 2 days of invasion the annulus has moved away into

    the formation, beyond the depth of investigation of the

    AIT10 reading. Measurements performed with shallow

    laterolog (LLS) and other shallow resistivity (SFL) tools

    yield apparent resistivity values slightly lower than Rxo,

    although gradually approach to the latter value as the annu-

    lus recedes away from the borehole wall. The deep

    laterolog reading, LLD, provides resistivity values closer toRt since it is only slightly affected by the presence of the

    annulus. This behavior is due to basic operating principles

    of resistivity logging tools, which indicate that laterolog

    tools respond to resistive anomalies whereas induction

    tools respond to conductive anomalies. Induction tool read-

    ings AIT20, AIT30-ILM are close to 34 ohm-m and 26

    ohm-m, respectively, after 2 days of invasion; the same val-

    ues monotonically increase as the invasion progresses.

    Induction resistivity readings, AIT60-ILD increase very

    slowly, from about 24 ohm-m, whereas the deep array induc-

    tion reading, AIT90, first decreases below the AIT60-ILD

    value and then gradually increases from 4 days onward.

    Fi gure 21 shows t he si m ul a t ed dua l -i nduct i on(DIL-SFL) tool readings assuming a cross-section of elec-

    trical resistivity corresponding to an invasion time of 4 days

    (Figure 8). Values of Rt and Rxo used in the simulation are

    varied slightly as a function of depth based on the field logs.

    The simulated log readings for ILD are about 18-25 ohm-m,

    for ILM are about 28-35 ohm-m, and those for SFL are

    about 70-80 ohm-m. As shown in Figure 21, the simulation

    results are in close agreement with those of the measured

    log data. Resistivity values fall steeply at the lower part of

    the formation mainly due to increased shale content. Simu-

    lated log responses for various perturbations of invasion,

    petrophysical, and fluid properties are summarized in Table

    5. For the reservoir model considered in this paper, it was

    found that dual-induction measurements were not sensitive

    to a perturbation of the value of in-situ water saturation.

    This exercise provided further confirmation that the length

    of penetration of borehole induction measurements was

    seriously compromised by the presence of the low-resistiv-

    ity annulus.

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    Assessment of In-Situ Hydrocarbon Saturation in the Presence of Deep Invasion and Highly Saline Connate Water

    FIG. 21 Numerically simulated wireline logs of shallow anddeep dual induction (ILD and ILM, respectively), and shallowresistivity (SFL) as a function of depth across the formation ofinterest in Well X-2. The numerically simulated logs are shownas black lines. For comparison, the corresponding measuredfield logs are shown with red lines on the same plot. Theassumed invasion time is four days.

    FIG. 20 Numerically simulated apparent resistivity readings ofdual induction (ILM and ILD), shallow resistivity (SFL), duallaterolog (LLS and LLD), and array induction (AIT10, AIT20,AIT30, AIT60, and AIT90) measurements. The figure showssimulated apparent resistivity readings as a function of time ofmud-filtrate invasion. For comparison, the figure also shows thecorresponding values of flushed-zone resistivity (Rxo), annu-lus-zone resistivity (Rann), and virgin-zone resistivity (Rt). Themeasurement point is taken in the middle of the upper reservoirlayer shown in Figure 4.

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    It is important to remark that the relatively good agree-

    ment between measured and simulated induction measure-

    ments shown in Figure 21 was only possible when the inva-

    sion time was set to four days. This time of invasion is con-

    sistent with the drilling record of Well X-2. Such an exer-

    cise indicates that, in principle, when interpreting borehole

    resistivity measurements with a quantitative model of

    mud-filtrate invasion, time of invasion could be inferred

    from the global match of numerically simulated and mea-

    sured borehole resistivity logs, assuming that porosity is

    inferred from ancillary information (e.g. density logs).

    However, additional petrophysical information will be

    needed to properly match all the vertical fluctuations exhib-

    ited by the shallow and deep reading borehole resistivity

    logs, including initial water saturation, permeability, capil-lary pressure, and relative permeability, among others.

    For completeness, Figure 22 shows the dual laterolog

    response simulated in the presence of the electrical resistiv-

    ity annulus shown in Figure 8. Simulated LLD and LLS

    readings yield resistivity values of 70-80 ohm-m and 55-65

    ohm-m, respectively. Such values are much closer to the

    actual virgin-zone resistivity values (80-90 ohm-m) than

    those yielded by the deep induction measurements. This

    exercise clearly suggests that laterolog measurements are

    much less affected by the presence of a low resistivity annu-

    lus than induction measurements, and hence do remain sen-

    sitive to a perturbation of in-situ water saturation in the vir-gin zone.

    DISCUSSION AND CONCLUSIONS

    Differences in salt concentration between mud filtrate

    and connate water can result in salt mixing within porous

    formations. Because of this, the electrical resistivity of con-

    nate water will experience substantial spatial variations

    radially away from the borehole wall that cannot be

    154 PETROPHYSICS March-April 2004

    Torres-Verdn et al.

    FIG. 22 Numerically simulated shallow and deep dual laterologreadings (LLS and LLD, respectively) as a function of depthacross the formation of interest in Well X-2. The assumed inva-sion time is four days.

    TABLE 5 Numerically simulated Dual Induction-SFL (DIL-SFL) log readings for various perturbations of invasion,petrophysical, and fluid parameters.

    SFL ILM ILD

    (ohm-m) (ohm-m) (ohm-m) Petrophysical/Fluid Parameter

    83.0 27.0 23.6 2 days of invasion

    90.5 36.1 25.0 4 days of invasion

    94.0 45.0 27.5 6 days of invasion

    21.7 20.2 20.1 Mud-filtrate salinity = 10,000 ppm

    94.1 51.4 37.1 Connate water salinity = 50,000 ppm

    124.6 31.4 19.8 Type B relative permeability

    85.9 19.4 13.5 Initial water saturation = 0.28

    92.1 34.8 23.9 Capillary Pressure is Half

    34.4 19.5 14.7 Cementation Exponent m = 1.5

    91.6 28.7 18.8 Saturation Exponent n = 1.5

    49.6 27.9 23.0 Mixing Efficiency is Half

    96.7 55.9 40.1 Mud Cake Permeability is 0.15 md

    392.7 222.7 155.1 Porosity is Half (0.07)

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    explained from the distribution of water saturation alone.

    Estimation of in-situ water saturation from resistivity mea-

    surements via, for instance, Archies law, requires that the

    resistivity of formation water be known as a function of

    radial distance away from the borehole wall.

    Large differences in salt concentration between mud fil-trate and connate water can cause the presence of a promi-

    nent low resistivity annulus some distance away from the

    borehole wall. This phenomenon has been considered in a

    number of previous publications dealing with the interpre-

    tation of wireline resistivity logs. However, a consistent and

    systematic petrophysical explanation for the origin and

    properties of such an annulus has not been presented before

    in light of actual field data. The origin and geometrical

    characteristics of such an annulus are governed by the par-

    ticular combination of petrophysical and fluid parameters,

    including mud properties, time of invasion, porosity, abso-

    lute permeability, relative permeability curves, capillary

    pressure, initial water saturation, connate water salinity,

    mud salinity, and cementation factor, among others. In turn,

    the presence of a low-resistivity annulus seriously compro-

    mises the radial length of penetration of borehole induction

    tools thereby impairing an accurate assessment of in-situ

    hydrocarbon saturation.

    The above phenomena were successfully recognized and

    described from well-log data acquired in an active gas-pro-

    ducing field. In this particular case, a low resistivity annu-

    lus was formed because of both usage of fresh water mud

    and presence of extremely salty connate water. Two-dimen-

    sional simulations of mud-filtrate invasion and salt mixing

    yielded radial profiles of electrical resistivity consistentwith actual borehole induction data. Further sensitivity

    analysis provided valuable insight into the role played by

    formation and fluid properties in the creation and character-

    istics of the low-resistivity annulus.

    Simulation results presented in this paper indicate that

    there is not a simple procedure to correct previously acquired

    borehole induction measurements for the presence of a

    low-resistivity annulus. Such a correction would require a

    reliable extrapolation of the profile of electrical resistivity

    beyond the annulus region. Given (a) the lack of sensitivity

    of the pre-annulus and annulus regions of the resistivity pro-

    file to the value of initial water saturation, and (b) the largevariability of the resistivity annulus properties, namely,

    width, height, and distance from the borehole wall, an

    extrapolation of resistivity beyond the annulus region is

    highly non-unique. Because of the same reasons, inversion

    of borehole induction logs in terms of parametric radial pro-

    files of electrical resistivity (e.g. ramp and annulus profiles)

    in general will not yield the radial asymptote required for the

    unbiased estimation of water saturation in the virgin zone.

    Despite the above complications, it is here remarked that

    one of the by-products of the simulation of mud-filtrate

    invasion is a cross-section of the spatial distribution of

    water saturation and salt concentration in the near-borehole

    region. This cross-section is consistent with the measured

    borehole induction logs and is largely controlled by the

    mud and petrophysical parameters assumed in the simula-tion of the phenomenon of mud-filtrate invasion. The long

    radial-distance asymptote of such a cross-section becomes

    a good estimate of water saturation in the virgin zone. It is

    therefore concluded that, in the presence of a prominent

    low-resistivity annulus and/or deep invasion, simulation of

    mud-filtrate invasion to match existing borehole induction

    logs is perhaps the only possible way to calculate reliable

    estimates of in-situ hydrocarbon saturation.

    Another significant result stemming from this paper is

    that laterolog measurements could provide a practical tech-

    nical alternative to overcoming the limited depth of investi-

    gation experienced by induction tools in the presence of alow-resistivity annulus and deep invasion.

    Finally, the simulation results described in this paper

    indicate that numerical simulation of mud-filtrate invasion

    can be usedto assess the influence of a given typeof mud on

    the response of induction and laterolog resistivity measure-

    ments. It is also possible to make use of such a simulator to

    design chemical properties of muds in order to minimize

    formation damage. Chemical properties of muds could also

    be designed to optimize the sensitivity of borehole logging

    tools and therefore to improve the accuracy of log interpre-

    tation techniques used to estimate in-situ rock formation

    properties.

    ACKNOWLEDGEMENTS

    We are obliged to Anadarko Petroleum Corporation for

    permission to publish these results. UT Austins Research

    Consortium on Formation Evaluation, jointly sponsored by

    Baker Atlas, Halliburton, Schlumberger, and Anadarko

    Petroleum Corporation, provided partial funding for the

    work reported in this paper. The authors would like to thank

    Ian Zhang, Hal Meyer, and two anonymous reviewers for

    their constructive technical comments and editorial sugges-

    tions.

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    ABOUT THE AUTHORS

    Carlos Torres-Verdn received a PhD degree in Engineering

    Geoscience from the University of California, Berkeley, in 1991.

    During 19911997, he held the position of Research Scientist with

    Schlumberger-Doll Research. From 19971999, he was Reservoir

    Specialist and Technology Champion with YPF (Buenos Aires,

    Argentina). And since 1999, he is an Assistant Professor with the

    Department of Petroleum and Geosystems Engineering of The

    University of Texas at Austin, where he conducts research in for-

    mation evaluation and integrated reservoir characterization. He

    has served as Guest Editor for Radio Science, and is currently a

    member of the Editorial Board of the Journal of Electromagnetic

    Waves and Applications, and an associate editor for Petrophysics

    (SPWLA) and the SPE Journal.

    Bovan K. George was a graduate research assistant while pur-suing a MSc degree in Petroleum Engineering at The University of

    Texas at Austin between 2001 and 2003. He currently works as a

    log analyst with Oil and Natural Gas Corporation (ONGC), in

    India. Bovan received a Master of Science degree in Physics from

    the University of Kerala and a Master of Technology in Industrial

    Physics from IIT Kharagpur, India.

    Mojdeh Delshad is a research engineer with the Center for

    Petroleum and Geosystems Engineering at The University of

    Texas at Austin. She holds MSc and PhD degrees in Petroleum

    Engineering from The University of Texas at Austin. Her research

    interests are in petrophysical property modeling, enhanced oil

    recovery, reservoir engineering, simulation, and groundwater

    modeling and remediation. She is a member of the SPE Editorial

    Review Committee.

    Richard Sigal is currently a Reserach Professor at the Univer-

    sity of Oklahoma with a joint appointment in the Petroleum Engi-neering and Geoscience Departments. He is also the Director of

    the Mobile Core Analysis Laboratory at Oklahoma University.

    Previously, Richard worked for Anadarko as part of the

    engineering technology group. Before joining Anadarko he spent

    21 years with Amoco mostly in their Tulsa Technology Center.

    After retiring from Amoco, he worked for two years for

    Halliburton in Houston. During the last 15 years, much of Rich-

    ards time has been spent on understanding permeability and the

    technologies used to characterize and estimate it. He worked in

    Petrophysics and core measurements at Amoco and supervised the

    development of Petrophysical applications at Halliburton. Among

    his areas of special expertise are NMR and mercury capillary pres-

    sure measurements. Richard was trained in mathematics and phys-

    ics. His PhD thesis fromYeshiva University was in general relativ-

    ity.

    Farid R. Zouioueche is a reservoir engineer formerly with

    Anadarko Petroleum Corporation. He graduated with a MSc

    degree in Petroleum Engineering from The University of Texas in

    Austin in 2000. His research interests cover near wellbore

    remediation processes, capillary flow theory, and phase behavior.

    Barbara Anderson is a principal research scientist at

    Schlumberger-Doll Research in Ridgefield, CT. She joined SDRin

    1966, and since that time she has worked on developing computer

    codes for modeling resistivity tool response. Her ongoing goal is to

    minimize uncertainty in log interpretation by integrating forward

    modeling directly into the interpretation process. She is presently

    working in the areas of anisotropy interpretation and inversion.Barbara is a past-president of SPWLA, and in 1996 she received

    the SPWLA Distinguished Technical Achievement Award. She

    received a PhD degree from Delft University in 2001.

    156 PETROPHYSICS March-April 2004

    Torres-Verdn et al.