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Your Clear Advantage

TOPAS Advanced Polymers

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Page 1: TOPAS Advanced Polymers

Your Clear Advantage

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Page 2: TOPAS Advanced Polymers

TOPAS Advanced Polymers produces an innovative line of polyolefin materials used for a wide range of applications in the automotive, appliance, medical, information tech-nology, communications, consumer and industrial sectors. TOPAS Advanced Polymers believes that a key element in marketing these materials is to provide application devel-opment and technical support to its customers on a global basis.

TOPAS® COC

The company’s most important product is its family of TOPAS® COC resins. These amorphous polymers allow in-novative application development not feasible with other materials. TOPAS® COC offers high transparency, outstand-ing moisture barrier, high rigidity and strength, excel-lent biocompatibility and good electrical properties. This unique combination of properties has opened up TOPAS® COC applications in such diverse areas as medical devices, food and pharmaceutical packaging, optics and toners.

NORBORNENE

Another important product of TOPAS Advanced Polymers is norbornene, a bicyclic olefin, which is the main build-ing block in the polymerization of TOPAS® COC. It has many other uses, such as in pharmaceutical intermediates, pesticide compounds, specialty fragrances and high-damp-ing rubber. With an annual production capacity of 21,000 metric tons of high-purity norbornene, the company is the largest supplier of this useful chemical intermediate.

PRODUCTSPRODUCTS

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Page 3: TOPAS Advanced Polymers

TOPAS® COC exhibits a unique combination of properties, which can be customized by varying the chemical structure of the copolymer. Performance benefits include:

• Low density

• High transparency

• Low birefringence

• Extremely low water absorption

• Excellent water vapor barrier properties

• Adjustable heat deflection temperature up to 170 °C

• High rigidity, strength and hardness

• Excellent biocompatibility

• Very good melt processability/flowability

• High resistance to acids and alkalis

• Very good electrical insulating properties

Grade Description

8007 Clear grade with a heat deflection temperature (HDT/B) of 75 °C. It is especially suitable for packaging moisture-sensitive products because of its low water absorption and very good bar-rier properties. Grade 8007 has a lower elastic modulus and higher elongation than other TOPAS® COC grades.

5013 Clear grade with a heat deflection temperature (HDT/B) of 130 °C. This grade is characterized by high flowability and excellent optical proper-ties. Recommended for applications such as optical parts, e.g. lenses, and optical storage media, where low birefringence and high mold-ing accuracy (pit replication) are essential, as well as for medical and diagnostic applications.

6013 Clear grade with a heat deflection temperature (HDT/B) of 130 °C. Its combination of high pu-rity, chemical resistance, high transparency and high HDT/B makes this material useful for prod-ucts such as labware. Parts made from 6013 can be gamma- and steam-sterilized.

6015 Clear grade similar to 6013, with a heat deflec-tion temperature (HDT/B) of 150 °C, a value which cannot be attained by many amorphous polymers.

6017

Clear grade with a heat deflection temperature (HDT/B) of 170 °C. For parts requiring resis-tance to short-term, high-temperature exposure.

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Page 4: TOPAS Advanced Polymers

COMPANYCOMPANY

COMPANY PROFILE

TOPAS Advanced Polymers manufactures and markets TOPAS® COC (cyclic olefin copolymer) for advanced pack-aging, medical, optical and other applications worldwide. In addition TOPAS Advanced Polymers manufactures and markets norbornene, a valuable building block for complex organic molecules.

TOPAS Advanced Polymers is a joint venture between Daicel Chemical Industries Ltd., and Polyplastics Co., Ltd. It is headquartered in Frankfurt, Germany, with a US sub- sidiary in Florence, KY. It operates a 30,000 metric tons/year COC plant, the world’s largest, in Oberhausen, Germany. It employs about 100 people working in research and de-velopment, marketing and sales, production and adminis-tration. TOPAS Advanced Polymers was launched on Janu-

ary 1, 2006 following the purchase of the TOPAS business from Ticona, a subsidiary of Celanese Corporation. TOPAS® COC was developed in the early 1990s by Hoechst AG. Hoechst created a new COC process in which norbornene is synthesized from dicyclopentadiene and ethylene. A second step copolymerizes norbornene with ethylene by metallocene catalysis to generate cyclic olefin copolymer.

QUALITY MANAGEMENT

TOPAS Advanced Polymers is committed to meeting the highest quality, environmental, health and safety require-ments worldwide. This commitment means that the com-pany constantly updates its management system certifica-tions. Important certifications obtained by the company include: ISO 9001:2000.

LOCATIONS

TOPAS Advanced Polymers Inc. Florence (Kentucky, US): M&S North America, film laboratory

TOPAS Advanced Polymers GmbH Frankfurt (Germany): Headquarters; R&D, M&S EuropeOberhausen (Germany): Production site

PolyplasticsTokyo (Japan):M&S Sales Asia/Pacific, R&D

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Page 5: TOPAS Advanced Polymers

HISTORY

1990 Project in Central Polymer Research Hoechst AG

1996Pilot plant at Hoechst – develop-ment of metallocene-COC process

Hoechst AG

2000Production plant on stream,market development for segments

Ticona (Celanese)

2006Business acquired by DAICEL and POLYPLASTICS

Daicel Ltd.Polyplastics, Co., Ltd.

TOPAS Advanced Polymers GmbH

COMPANY OWNERSHIP DATA

Polyplastics

TOPAS Advanced Polymers GmbH

TOPAS Advanced Polymers, Inc.

Daicel

55%45%

100%

55%

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Page 6: TOPAS Advanced Polymers

APPLICATIONSAPPLICATIONS

M E D I C A LCyclic Olefin Copolymer (COC)

Medizin_E_270206.indd 2 18.01.2007 14:53:07 Uhr

TOPAS Medical brochure

Cyclic Olefin Copolymer (COC)

DIAGNOSTIC

TOPAS Diagnostic brochure

O P T I C A LCycloolefin Copolymer (COC)

TOPAS Optical brochure

MEDICAL

The dynamic and innovative medical technology sector calls for high-performance materials. TOPAS® COC offers:

• Superior moisture barrier and low moisture absorption

• Easy thermoformability

• High rigidity and strength

• Dimensional stability

• Excellent purity and low extractables

• Resistance to hydrolysis and many acids, bases and polar organic solvents

• High light transmission, even into the near UV range

• Compatibility with common sterilization methods

• Compliance with appropriate USP Class VI, ISO 10993 compatibility tests and FDA regulations. It also has active US FDA Drug and Device Master Files

OPTICAL

For advanced optical applications, including flat panel dis-plays and lenses, TOPAS Advanced Polymers offers several specially engineered optical grades of its TOPAS® cyclic olefin copolymer.• Low water uptake

• Low birefringence

• Very good metallizability

• High surface replication

• High-temperature resistance

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Page 7: TOPAS Advanced Polymers

PACKAGING

The packaging market imposes a broad range of demands on product designers. Criteria such as package appeal, durability and function are all critical, and recyclability is playing an increasingly important role. TOPAS® COC ethyl-

ene copolymers represent a major step forward in polymer technology, enabling package developments and enhance-ments that were simply not feasible before the arrival of this new resin on the packaging scene.

TOPAS Packaging brochure

TOPAS Blister forming brochure

TOPAS® can enhance packaging materials in numerous areas, including:

• Moisture barrier (WVTR) • Controlled tear

• Downgaging • Stiffness

• Thermoformability • Heat resistance

• Sealing layer • COF and blocking

• Transparency • Controlled shrinkage

• Film density • Dimensional stability

• Metallization

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Page 8: TOPAS Advanced Polymers

BLENDS AND COMPOUNDS WITH POLYOLEFINS

The addition of TOPAS® COC grades during the production process offers an opportunity to significantly broaden the property spectrum of polyolefins. This approach is widely used in film manufacture.

High-Tg COC grades can also be blended with polypropyl-ene homo- and copolymers to produce new compounds with a property profile, extending into the engineering polymer range.

The effects of compounding TOPAS® COC grades with a Tg above 100 °C into PE or PP include:

• Significant increase in tensile modulus

• Less tendency to creep under load at elevated temperatures

• Higher heat deflection temperature

• Improved water vapor barrier

• Lower warpage

• Reduced impact strength

3500

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0

E-M

odul

us [M

Pa]

Content Topas [%]Grades0 10 20 30 40 50 60 70 80 90 100

E-Modulus vs diverse PP/COC with diff. COC content HDT-B, vs diff PP/COC Grades with 20% COC

140

120

100

80

60

40

20

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[°C

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PP-Homo/TOPAS 6013Linear (PP-Homo/TOPAS 6013)

(PP-Homo)/20% TOPASLogarithmically (PP-Homo/20% TOPAS)

3500

3000

2500

2000

1500

1000

500

0

E-M

odul

us [M

Pa]

Content Topas [%]Grades0 10 20 30 40 50 60 70 80 90 100

E-Modulus vs diverse PP/COC with diff. COC content HDT-B, vs diff PP/COC Grades with 20% COC

140

120

100

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60

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[°C

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7PP-Homo/TOPAS 6013Linear (PP-Homo/TOPAS 6013)

(PP-Homo)/20% TOPASLogarithmically (PP-Homo/20% TOPAS)

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Page 10: TOPAS Advanced Polymers

NAFTA TOPAS Advanced Polymers, Inc.

EUROPE & South America TOPAS Advanced Polymers GmbH

ASIA Polyplastics Co., Ltd.

E M E R G I N G M A R K E T S

Timothy Kneale Ph. +1-859-746-6447 ext [email protected]

Wilfried HatkePh. +49 (0)[email protected]

Hirozumi ShimomuraPh. +81-3-6711-8615

[email protected]

M E D I C A L

Barbara Canale Ph. +1-859-746-6447 ext [email protected]

Michael Grimm Ph. +49 (0)69-305-46757

[email protected]

Shigeki Shinogi Ph. +81-3-6711-8615

[email protected]

O P T I C A L

Ronald LamontePh. +1-859-746-6447 ext [email protected]

Joerg Strack Ph. +49 (0)[email protected]

Yoshihito TsukamotoPh. +81-3-6711-8615

[email protected]

P A C K A G I N G

Randy JesterPh. +1-859-746-6447 ext 4409

[email protected]

Wolfram Goerlitz Ph. +49 (0)69-305-46760

[email protected]

Naohiro KatoPh. +81-3-6711-8615

[email protected]

CONTACT OUR SPECIALISTS!

TOPAS Advanced Polymers GmbHIndustriepark Höchst · Gebäude F821 65926 Frankfurt · Germany Phone: +49 (0)1805-1-86727 Email: [email protected]

www.topas.com

TOPAS Advanced Polymers, Inc.8040 Dixie Highway Florence, KY 41042 · USA Phone: +1-859-746-6447 Email: [email protected]

www.topas.com

Polyplastics Co., Ltd.JR Shinagawa East Building, 13F 18-1 Konan 2 - Chome, Minato-Ku Tokyo, 108-8280 · Japan Phone: +81-3-6711-8615 Email: [email protected]

www.polyplastics.com

CONTACTSCONTACTS

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