Upload
others
View
3
Download
0
Embed Size (px)
Citation preview
TM4/TM5 chemical mechanisms under the 1D
“microscope”
Nikos Daskalakis
Environmental Chemical Process Laboratory,Department of Chemistry, University of Crete.
Meteorology and Air Quality Group,Wageningen University.
April 25, 2013
Introduction
Different chemical schemes in the model
3 different in TM5, 2 different in TM4
Need for evaluation of different rates/schemes
Impact of the update of rates
Easy to use, fast, representative
Review chemistry over height
Use of single column model
WUSCM coupled with KPP for chemistry.
Introduction
Different chemical schemes in the model
3 different in TM5, 2 different in TM4
Need for evaluation of different rates/schemes
Impact of the update of rates
Easy to use, fast, representative
Review chemistry over height
Use of single column model
WUSCM coupled with KPP for chemistry.
Introduction
Different chemical schemes in the model
3 different in TM5, 2 different in TM4
Need for evaluation of different rates/schemes
Impact of the update of rates
Easy to use, fast, representative
Review chemistry over height
Use of single column model
WUSCM coupled with KPP for chemistry.
Introduction
Different chemical schemes in the model
3 different in TM5, 2 different in TM4
Need for evaluation of different rates/schemes
Impact of the update of rates
Easy to use, fast, representative
Review chemistry over height
Use of single column model
WUSCM coupled with KPP for chemistry.
Introduction
Different chemical schemes in the model
3 different in TM5, 2 different in TM4
Need for evaluation of different rates/schemes
Impact of the update of rates
Easy to use, fast, representative
Review chemistry over height
Use of single column model
WUSCM coupled with KPP for chemistry.
Introduction
Different chemical schemes in the model
3 different in TM5, 2 different in TM4
Need for evaluation of different rates/schemes
Impact of the update of rates
Easy to use, fast, representative
Review chemistry over height
Use of single column model
WUSCM coupled with KPP for chemistry.
Introduction
Different chemical schemes in the model
3 different in TM5, 2 different in TM4
Need for evaluation of different rates/schemes
Impact of the update of rates
Easy to use, fast, representative
Review chemistry over height
Use of single column model
WUSCM coupled with KPP for chemistry.
Introduction
Different chemical schemes in the model
3 different in TM5, 2 different in TM4
Need for evaluation of different rates/schemes
Impact of the update of rates
Easy to use, fast, representative
Review chemistry over height
Use of single column model
WUSCM coupled with KPP for chemistry.
TM4 IUPAC vs JPL — O3
TM4 IUPAC vs JPL — CO
TM4 IUPAC vs JPL — Isoprene
TM5 old vs new — O3
TM5 old vs new — CO
TM5 old vs new — Isoprene
TM5 vs CBM5 — O3
TM5 vs CBM5 — CO
TM5 vs CBM5 — Isoprene
All mechanisms — O3
All mechanisms — CO
All mechanisms — OH
All mechanisms — HO2
All mechanisms — NO
All mechanisms — NO2
All mechanisms — CH4
All mechanisms — Isoprene
Conclusions
Use of the single column model gives a good, fast validation
Easy to discover mistakes, correct them, re-evaluate
More information than the 0D model (height)
Thank you!!!