Title Cover

Author(s)

Citation The Review of Physical Chemistry of Japan (1967), 36(2)

Issue Date 1967-04-30

URL http://hdl.handle.net/2433/46880

Right

Type Others

Textversion publisher

Kyoto University

Vol. 36. 1966

The Review of Physical Chemis~.rr~^~~~~ ~~''Ja 301. 3_ 6J~lo. 2 (1966)

No. 2

THE

RMVI~Wof ra~siuA~CN~~ISTkYOF JAPAN

Fo.ekd is jS26

CONTENTS

Jiro Osugi, Kiyoshl Shimizn, Tokio Nakamura and Akifvmi Onodera: High

Pressure Transition in Cadmium Sulfide ...................................................... 59

Jiro Osugi, Klyoshl Shimizu, Tokio Nskemura and Akifuml Onodera : Electrical

Conductivity of Cadmium Sulfide under High Pressuteand High Temperature...... 74

Jiro Osugi and Kimihiko Han: E6ect of Pressure on the Electrical Conductivity

of Organic Substances (II) a, a'-DiphenYl-~-Picryl Hydrazyl,,,,,,,,,,,,,,,,,,,,,,,, 8l

J(ro Osugi and Yoiehi Kitamnra : Optical Studies of Pressure E6ects (IID Pressure

effect on the Aqueous Solution of Amylose-Iodine Complea .............................. 88

Jlro Osugl, Sigern Knsnhan and Satoehi Hirayama : I?;iaetic Studies on Fast Reac-

tions in Solution (I) Photoreductian of 1-Aretonaphthone .............................. 93

Jiro Osagi, Muveo Sasaki and Ithvo Ovishi : The Effect of Pressure on the Rate

of the Benzidine Rearrangement (II) o, o'-Hydrazotoluene ..............................100

Kolchiro Aokl, Mitevrv Tavaka, Koichi Hiramatan and Shoji Kaneahlne : Ag-

gregation of Bovine Serum Albumin under High Pressure ..............................111

THB PHYSICO•CHBMICAL SOCIBTY OF JAPAN

The Review of Physical Chemistry of Japan Vol. 36 No. 2 (1966)

THE REVIEWOF PHYSICALCHEMISTRYOF JAPAN(Butsuri-Kagaku no Shinpo)

Prea[dent: Shinkichi Horiha, professor Emeritus, M. ]. A.

Mcrnhere of Cortnell :

Asuma Otuda.(Chiei)

J. Osugi R. Rodera R. Goto T. Yamamoto T Fujinaga S. Tanaka

Hoard of Edltore:

J. Osugi (Chief)

Seeretsry

S. gachi

H. Takagi

H. Hatano

W. Jono

R. Coto

E. Suito

Rywo Uniarsily

Unibe(tily ¢J Xobe

Xgoto Univerrily

R oto University

I. Tsujikawa

A. %aji

A. Saika

W. Jam (Associate

R. Goto ( n

E..Suito ( n ) y

S. Shlda

T. Ritagawa

M. Tamura

H. Matsayema

T. Makila

K_ Suzuki

R. Hirola

S. Seki

T. Ishioo

T. Imoto

R. Fujiahiro

0. Toyama

S. Ono

S. Tsuchihashi

S. Huegawa

H. Togawa

R.:Shimizu

T. Fujiware

Tokyo tns/itrts of Tuknolaq

Yokokama Universily

Ky¢lo Univatity

Doskiska University Ryola TuknicaJ University

Rifsumtikan University

Universdy of Osaka

Univertiry of O.r¢k¢

Rinreji. Institute of Tuknoto;y

bluniiiyal Universily afOroka

Municifal University of Osaka

Prefulur¢t UAiverrky of Otaka

PreJatural Univeriry of Osaka

Uaiveni/y of Robs

Okayonw Univntily

Dosbish¢ UniversUy

M. Saty

The Review of Physical Chemistry of Japan Vol. 36 No. 2 (1966)

April - 30,: 1967

Commanfeatione to tbe. Editor should be addressed to sl3sard of Editors, The Pbysito-Chemical Society

of Japan, College of Science, Kyoto University,. Kyoto, Japaa

Bnainees Corceapbndencee sbould bt addressed. to.; $ec;etary, The Physics-Chemical Society of Japan;

College sf Science, Ryots University, Kyoto, Japan:

Pnrehaee Order should be addressed to: Efaruzen Co.,-Ltd., Nibonbastii, Chvs•ku, Tokyo, Japan.

THE

Published by

PHYSICO•CHfiMICAL SOCIETY OF JAPAN

(Nippon Butattri-Ragaku Bealcyu Rai)

College. of -Science, Kyoto University, Kyoto, Japaa

Pcinted by RAWARITA INSATSU. CO., Kyoto; Japan

The Review of Physical Chemistry of Japan Vol. 36 No 2 (1966)

Single crystals of HORIBA INSTRUMENTS, INC., offered as complete products ready to use which arefree from impurity absorption, have aquired worldwide reputations.

Our xintillators, sucb as NaI (Tl), CsI (Tl) or CaIr are also credited and used internationally by the nuclear scientists, for the established qualities.

Limit of transparancy (microns)

ReGactive index:

Solubility ^•

tilic gravity: gr/cml

Melting point: 'C

Maximum diameter-i mm

Maximum height-. mm

NaCI KCI KBr KI LiF AgCI RRS-5• P.RS-fi' Csl

^-15 X21 X27 X31 ~fi X30 X40 -34 X70

t.335 1.498 L539 L66] 1.394 2.071 2,629 2.336 1.987

35.7 18.5 53.5 117.5 0.17 g.9 x IO's 0.02 032 44

z.lfi 1.59 2.75 3.13 1.64 S.Sfi 7.2 ].l9 4.53

801

110

100

776 730

170 120

100 t00

680

110

843

700

455 0.l3 424 621

60 fi0 60 60

10 60 I00 60 100 t00

KRS-5 is a compound single crystal of TII and TIBr, and KRS-6 is a compound single crystal of TICI aad'flHr. g/100 gr water at normal temperature.

HORIBAI INSTRUMENTS , I N C .

Hesd office & Faelory: Nakagawara Dliyaaohigashi-machi,

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The Review of Physical Chemistry of Japan Vol. 36 No. 2 (1966)

The Review of Physical Chemistry of Japan

Vol. 36, 1966

CONTENTS

No 1

Jiro Osugi, Kiyoshi Shimizu and Hideto Takizawa: Effect of Pressure on the Dissociation of Electrolytic Solution (III) Electrical Conductivity of Hexam-

mine Cobalt (III) Sulphate at Hight Pressures ........................................••••• 1 Jiro Osugi, Tetuo Mizokami and Tadafumi Tachibana : The EGett of Pressure on

the Keto-enol Equilibria of Acetone and Cyclohexanone ................................. 8 Jiro Osugi and Kimihiko Hara : Effect of Pressure on the Electrical Conductivity

of Organic Substances (I) Pyrolyzed Polyatrylonitrile ...............................•• 20 Jiro Osugi and Kimihiko Hara : High-pressure Dlelting in Polyethylene .................. 2S Jiro Osugi, Ryosuke Namikawa and Yoshiyaki Tanaka : Chemical Reaction at

High Temperature (III) Reaction of Silicon and Phosphorus at High Tempera- ture and High Pressure ........................................................................... 35

Kiyoshi Kitamura : Inactivation of Enzymes under High Pressure (II) Inactivation of Bacterial Al-Proteinase and Q-Amylase of Barley under High Pressure ......... 44

Jiro Osugi, Kiyoshi Shimizu, Yoshiyuki Tanaka and Kosaku Kadono: Prepara- tion and Chemical Properties of Cubic Boron Arsenide, BAs ........................... 54

No. 3

Jiro Osugi, Kiyoshi Simizu, Tokio Nakamura and Akititmi Onodera: High Pres- sure Transition in Cadmium Sulfide ......................................................... 59

Jiro Osugi, Kiyoshi Shimizu, Tokio Nakamura end Akifumi Onodera: Electrical Conducity of Cadmium Sulfider High Temperature ....................................... i4

Jlro Osugi and Kimihiko Hara: Effect of Pressure on the Electrical Conductivity of Organic Substances (II) a, a~-biphenyl-S-Picryl Hydrazyl ........................... 81

Jiro Osugl and Yoichi Kitamura: Optical Studies of Pressure Effectr (III) Pressure effect on the Aqueous Solution of .4mplose-Iodine Complex ........................... 88

Jiro Osngi, Sigeru Kasahara and Satoshi Hirayam: Kinetic Studies on Fast Reac- tions in Solution of 2-Acetonopbone ......................................................... 93

Jiro Osagi, Muneo Sasaki and Ichiro Onishi: The Effect of Pressure oa the Rate of the Benzidine Rearrangement (II) o, o =Hydrazotoluene ..............................100

Koichiro Aoki, MItsaru Tanaka, Koichi Hiramatsu and Shoji Kaneshna: Aggre- gation of Bovine Serum Albumin under High Pressure .................................I11

Published by

THE PHYSICO-CHEMICAL SOCIETY OF JAPAN College of Science, Kyoto University, Kyoto, Japan

The Review of Physical Chemistry of Japan Vol.

~_ _

36 No. 2(1966)

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The Review of Physical Chemistry of Japan Vol. 36 No 2 (1966)

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The Review of Physical Chemistry of Japan Vol. 36 No. 2 (1966)

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The Review of Physical Chemistry of Japan Vol. 36 No. 2 (1966)

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The Review of Physical Chemistry of Japan Vol. 36 No. 2 (1966)

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