Title Cover

Author(s)

Citation The Review of Physical Chemistry of Japan (1977), 47(2)

Issue Date 1977-12-25

URL http://hdl.handle.net/2433/47046

Right

Type Others

Textversion publisher

Kyoto University

Vol. 47, 1977

The Review of Physic

~~ __THE

.,

~LChe~~~'~'//)//q{{('''istry o J a~V I. 47 No. 2 (1977) ,~L- ~.

~~~

R~VI~VVo~OF JAPAN

C~E~ISTRY

Founded is 192b

CONTENTS

K[yoahl Hawataura X-Ray Emission Spectra Induced by Ion-Atom

Collisions I, Single and Double K-Shell Ionization .............................

Klyoahl Kawatanra : X-Ray Emission Spectra Induced by Ion-Atom

Collisions II, Effect of Chemical Bonding and Multiple Ionization on

X-Ray Spectra ..........................................................................

Kiyoahi Shhnizv, NorLki Tanehlhaehl and Yoshihtto Kondo: Effect of

Pressure on Dissociation of Ion Pairs, Mn50., CuSO~ and ZnSOe ..........,

Mssarn Hongo and Htrojl Iwasaki: The Viscosity of Nitrogen-Ammonia

53

69

System under Pressures

80

Izaml Iahihara :Electrical Conductance of Liar in Acetone at High Pressure

aad 25 °C ..................................................................

90

102

Hideki Aoml, Mmeo Saeaki aad Jiro Oaugi :Photochemical Hydrolysis of

m-Nitroanisole under Higb Pressure .........., ....................................

Masara Nakahara, Yasnhtro Uogkl, Muaeo Sasakl aad Jiro Oaugt:

"C and'H NMR Studies on the f, 4-Adduct Formed by the Reaction of

Tetracyaacethylene and Styreae

111

119

THE PHYSICO-CHEMICAL SOCIETY OF JAPAN

The Review of Physical Chemistry of Japan Vol. 47 No. 2 (1977)

THE REVIEWOF PHYSICALCHEMISTRYOF JAPAN

(Butsuri-Kagaku no Found in 1926

Shinpo)

President: Wasaburo Jono

Members. of Coundt

Michio Okamoto (Chief)

Jiro Osugi

Ryoao Goto

Renpei Goto

Eiji Suito

Hiroyuki Hetano

Board af -Fdltore:

J, Osugi (Chief) Kyoto Univessiy

R. Goto (Associate) Ryoto Sancyo Universiy

E, Suito ( n )Osaka Instituleoj Tecknalogy

Seeretan:

S. Shida

H. Teranishi

R. Susukf

K. Ruwa[a

S: Seki

R.. Fujishiro

T..Hayakawa

Y. Kubokawa

S. Tsuchshashi

T. Makita

S. Hasegawa

K. Shimiau

A. Tocawa

M. Sasaki

K, Hara

M. Nakahara.

S. Fukase

Yakotu<ma Uriiveristy Ryoso.Tecknical Univessity Rittumeikan Universily Uaiverrily of Osaka University aJ Oraks Osaka City Umusrsily PrtJedura! Univeaity of Osaka PreJeaaral University of Osaka Kobt University Xabe University Okayama University Dotkiska University Boika Nomex's Collect

The Review of Physical Chemistry of Japan Vol. 47 No. 2 (1977)

Deeemhe'25; 1977

Commnniestiom to the Editor should he addreued to`Board of Fditors, The Physico-Chemical Society

of ]apan, Facnlty of Science, Ryoto University, %yota,. Japan

Brtsineaa Coaeapondeneea should be addressed to :. Secretary. TLe Physico~Chemical Society of Japan,

Faculty of Science, Ryoto University, Ryoto, Japan.

Prurehase Order should be addressed ta: Maraaen l:o., Ltd, Nihoebashi, Chuo-ku, Tokyo,.-Japan

THE

Pu6liahed by

PHYSICOCHEMICAL SOCIfiTY OF JAPAN

(Nippou Butsuri-Ragaku- Reokyu Rai)

Faculty of Science, Ryoto University, Ryoto, Japan

--Printed by RAWARTTA PRINTING CO., LTD., Ryoto, Japan

The Review of Physical Chemistry of Japan Vol. 47 No 2 (1977)

Like the goos¢ thot loid the golden Asahi Kcasei is producing

mony things for your needs. To make life better for a"veryone,

Asahi Kasei produces all kinds of fibers and filaments to make the clothes you wear ...draperies, carpets, wall

coverings, blankets ...tire cords for your automobile. We're inthe Food business

with natirral food flavoring and - seasoning ...frozen foods likz ,_

=hamburgers andnt _eat balls. Sk~rapers _ use Asalrlautoclavedlightweight concrete,

^; We care for your health with medical

~, ,, - _- _ _r ~..

_- T.~~

_~°

tiY e.

{ '~

e99s.

equipment, medicines, artificial kidneys. Asahi ICasei products also include plastics of all kinds, synthetic rubber, fertilizers, starting materials and intermediates, ion exchange membranes for a non•polluting_ method of producing caustic soda, photosensitive renns for the printing industry. Our research engineers are working on more new products to make ~~; your lif_ _e easier audSta ;,,pier. LL _~~~

,`~~

~_,II

~, ~.p.6._ _~i,~-

--

_ _ 'ij~'

Asahi Chemical Industry Tokyo H ~ d Office: Hibiya~Mits~i Building, U2, Ywakucho 7-cbome, Ch

T (Q3)_543173p Tele>c; 222~351816EMBRG J) Cable: ASAHIKAS Oaks Hea Office€-Shin•Osaka$uilding, 25.7. Dojima Hamadori I~chome _K/~.•I

Tel: (061`32173711 Telex: 52&3811 (BEMBRG J) Cable: BEMBRfa-O$A

4e__

~_ a~iiu, ~_ ~~,

i

i~~ a

,.~.~„

The Review of Physical Chemistry of Japan Vol. 47 No. 2 (1977)

The Review of Physical Chemistry of Japanvoi. d7. Is~~

CONTENTS

No. 1

Maseru Nakahara and Jiro Osugi : Ionic Solutions under High Pressure

VII, Mobility of Hydrogen Ion in 1Vater at 15, 25 and 40 `C up to 5000 atm .......................................................................................

Yoshiyuki 'Panaka, Takeshi Yamamoto, Yoehlmasa Satomi, Hironobu

Kuhota and Tadashf Mak[ta : Specific Volume and Viscosity of Ethanol-Water Yfixtures under High Pressure .....................................

Masakntsu Ueno, Masaru Nakahara and Jiro Osugi: The Effect of Pressure on Micelle Formation and Solubility of Hexadecyltrimethyl-

ammonium Bromide in R'ater .......................................................... Masami Okamoto, Muneo Sasaki and Jiro Osugi : Kinetic Studies nn the

Cationic Polymerization of Tetrahydrofuran under High Pressure ............. Masatake Katayama, Kimihiko Hare and Jiro Osugl: Layer Growth of

Zn56 Phase in the Zn-Sb Di6usion Couple a[ High Pressure ...................

No. 2

Kiyoshi Kawatsura: X-Ray Emission Spectra Induced by Ion-Atom

Collisions I, Single and Double K-Shell Ionization ............................... Kiyoshi Kawatsura : X-Ray Emission Spectra Induced by Ion-Atom

Collisions II, Effect of Chemical Bonding and Muhiple Ionization on

12

33

42

X-Ray Spectra

Ki oshi Shimizu,

...53

ystem a ess res ..........

Izumi Ishihara: Electrical Conducta

and 2i°C ..............................

Hideki Aomi, Muneo Sasaki and

of m-Nitroanisole under High Pr

Maseru Nakahara, Yaeuhiro Uos "C and 'H NMR Studies on the

Tetracyanoethylene and Styren

y Noriaki Tsuchihashi and Yoshihito Kondo: Effect of Pressure on Dissociation of Ion Pairs, MnSOg, CuSO. and Zu50. .........

Maseru Hongo and Hiroji iwasaki: The Viscosity of Nitrogen-Ammonia S and r Pr u ........--------------------------- ..............

nce of Liar in Acetone at High Pressure

..........................................................

Jiro Oaugi: Photochemical Hydrolysis

essure .................................................

aki, Muneo Sasaki and Jiro Osugi

1, 4-Adduct Formed by the Reaction of

e .......................................................

...90

..........102

......119

THE Facult

Published by

PHYSICO-CHEMICAL SOCIETY

y of Science, Kyoto University,

OF JAPAN Kyoto, Japan

KAN~KA's

products and technologies shall be at your service

KANEKA has now firmly secured its leading position in Japan's chemical industry, and enjoys a high international reputation not only for its capability of offering unique, high-quality products in quick succession but also for its establishment of technical know-how in various field of technology. KANEKA's unique, high-quality products are as follows..." Kanekalon," a self-extinguish-ing modacrylic fiber and is booming for its suitability and nonflammability for carpets, curtains and wigs. "Kane-Ace B," PVC modifier, is now in brisk world-wide demand. "PVC Dispersion Resin ," "Heat Resistant PVC." "Expandable Polystyrene," and so on. A variety of epochal projects are now under way at our 10 laboratories far ahead in the same field both at home and abroad.

~~ ,i ;

t"~:

1~;

~~ Y ̀ ~'

k

f

e

.. 1

--~~: ,~ .

z;

,~ q-

q~ ^

'

~~ ~~ , ,

F

M

l

...,i

* KANEKA's per capita sales and profit are ranked as one of tha highest among all chemical manu- facturers in the world, thanks to our very high

productivity. * KANEKA's products have , for the most part.

originated in its own laboratories. * 55^/0 of~KANEKA's products have been devel-

oped on its hands for the first limo in Japan.

KANE~fA For tuNMy devils. pbess wdfs lo:

6ANE6AFUCNI CHEMICAL IND. CO., LTD. Neatl OMu: (AaaM 9hinbun skip./3, 3.NOme. Ne6mm~4na,

Rir.ku, Oaeka, Japan Phona:0aka 109)2021121

Tokyo OINpa: IOhUmxhl B/dp.)4, tehoma.Ohum.ehi, Ohiyode-ku, Tekyo, Jepen

Phone: TOkyo 1031218-1011 Nsw Yark 089ea: PANAM skip., 37th Fber. 200 Park Avenue,

Nsw Yerk, N.Y. 1001 J, Us.A. PhoM:(2121973d896

tiurops ONia: 4 OessUdod Bedkrar Alta. 2B. Wan Germmy Phm.e: 12739 <~

Ilk

r' I

~~~ '

~1

13~ .

y

~~

.m

'Y

r.i ~

mar,

f~ r

I

~,,

~-`~ ~r,.

~~

I

~~

i

' 1, ~'`

'~.,

i. -a ,~,; • '~

«, " r :=

~1~. , •~ , f" :. t _ ,.

~~' .

~!

~:

i '\

. ~,

The Review of Physical Chemistry of Japan Vol. 47 No. 2 (1977)

w U ~ ~

. ~ Z a ~

~ --

~ o ~ J ~ o ~ U

7 U U ~ " ,~ Y fd

~ 4] ~ ~ W ~

Z L O ~ U ~Ya

~ ESN r(nM

U

O Y O N ~ _ O `" ~ o

mF Z ~ ~ ~

N ~ - U ~_ Y ~ x ~ ~ ~

N U F-

~y ~ F--1-- Q

~~~

~~

e

Q~

U Z

~ N O Cn J J

a~ ~ ~ a 00 0

ZW U Q ~ 2 J Z

~U Q O_ J N ~ 1--U_Q~~~tnt~N H~NtLJW~Q =tqJ~

_UC_~F-~ Z~~yN,~~GZH ~?IWiOQ~V~

~ ~

°' ~ 3

L ~~~

The Review of Physical Chemistry of Japan Vol. 47 No. 2 (1977)

Tell us about how

you're using fluorine compounds.

(.r~ /YHaF 1, Fa CHF,CFgGoONa ~NFa l~~y GFS CQF2 ` Q~z cF3 ~ CHCQ:F cN :N Nz CaF$ N cP ~c2Fa)rv [F3

C~3~ ~CQ2Fz GC~F3 Ca~aFz Cz ~3 F3 C F

d Cp ~ CF3 LCksFz~G~NaF

~G2~F3~n ~ ~.gY~'' 3 Cft~F2 fC2(Qf5 f4. (CzF4~" ~~'~e)~ L'~z GZCf~FS GryBrzF4 CF3

Fluorine compounds have many unique qualities. But

their usages today are only the beginning; the best is yet to

come.

DAIKIN is a total maker of fluorine compounds .

Our series of them has been developed from Fluorspar as

its basic material. And we've learned a lot along the way.

So the next time you discuss fluorine compounds,

think of DAIKIN-the

DAIKIN Fluorochemicals

company with all the

answers. Answers

we're anxious to share.

~d DA/KIN KOGVO CO L7D Heatl Oflice ShimHankyu Bltlg., 6 Phone: Osaka (06) 946-7207 Telea:

Umeda. Krta-ku.

523-3644

Osaka. Japan.

The Review of Physical Chemistry of Japan Vol. 47 No. 2 (1977)

Example of Application with EMAX-,000+SEM

Simultaneous qualitative analysis of

multi-elements („Na- 92U ) ''®

$r.

~~~~~ Photo 1:700 fold enlargement

of an IC. The lower part shows the line analysis of AI. The

electron Beam is scanned over the line (scanning time: 00 sac.).

~:~'~

~sa

Photo 2: The plan analysis of Photo 1 showing AI distribution.

-~

~~ -

'

Photo 3: Background Is removed by contrast enhancer.

in a few tens of seconds.

X~flay Analyzer

E leetron Microswpe (SEM or TEM)

S it Lil Detector

~: ~

#;rA

~~I ~~

r~~ .

~~

X-ray Micro-Analysis System HORIBA MODEL EMAX-1000 SERIES

X-RAY ENERGY DISPERSIVE ANALYZERS

~;fos_~i xo~ u, .~~~ asoosec tnr ~ . /

Ot. ]skEV Il19~>~l1 lfAl VS=161: I'. hnl

i

Photo 4: The X-ray analysis of the area shown In Photo i.

The brighter peak is the window-set AI. The adjacent peak iz Si.

Each of HORIBA Model EXAM-1000 SERIES X-RAY ED ANALYZER for X-ray microanalysis is a system for simultaneously, speedily and easily analyzirg a multiple number of elements of a substance in a smallarea, by assembling it together with your electron microscope of SEM or TEM type. Extremely reliable. No personal error. Non-distructive. Consists of ahigh-resolution Si/Lil X-Ray Detector, a PulmHeight Analyzer and a Video Display.

MAIN APPLICATIONS Dualitative analysis in the fields of metal end minerel industrie; chemical industries and electronic industries Fixing the elements in biochemical and bio-assey studies.

Objects: Characteristic X-rays of elements from uNa (sodium) to uU (uraniuml.

System of Measurement: Energy-Dispersive Method by Si1Li) X~Ray Detector. Energy Resolution: Less than F.W.H.M. 162eV IMnWr Line 5.9keV, 1000 cps)

A group of specialists in HORIBA, Ltd. also offers an engineering service~encompessing an overall rystem in orderta maximize the performances of your X-rey analyzer system.

HORIBA, Ltd. Head Office: M'ryerrofigosht, Kluhoin, Minemi•ku, Kyoto, Japan Phone: 107b1313$121 Cable Add.: HORIBA KYOTO /Telex: 5972130