, (Mukai, Tomohiro) Publisher
Publication year 2014 Jtitle . (The Hiyoshi review of natural
science). No.56 (2014. 9) ,p.21- 34 Abstract 1 ,
66 2000 , 1 , ATR ()2008 , , , , , , , 66 , , 66 ,
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66 ATR

An Experiment with Infrared Absorption Spectra Measurement of Nylon-66 by ATR method.
Shigeru OHBA and Tomohiro MUKAI

1 66 2000 1 ATR 2008 66 66
Hiyoshi Review of Natural Science Keio University No. 56, 21-342014
223-8521 4-1-1Research and Education Center for Natural Sciences, Keio University, Hiyoshi 4-1-1, Kohoku-ku, Yokohama 223-8521, Japan. 102-8160 2-17-1Present Address, Science Research Center, Hosei University, Fujimi 2-17-1, Chiyoda- ku, Tokyo 102-8160, Japan. [Received Feb. 1, 2014]
22
1
2
2-1 66
66 H2NCH26NH2 HOOCCH24COOH 11 1 12 X
66X P1 2 C12H22N2O2 1 Z13α23 a4.87b5.26c17.15α50.5β76γ63.5° 4 c N-H…O ac 2 a 2 b
23
66 ATR
4 66 265200 Brill Brill α5 6 7
230 66 8 220 2509
1 66
O
C
O
2 ) 6
NH 3
2 66 3[C12H22N2O2]n P1Z1 c N-H…O ac 2 b
24
2-2 66 Morgan
1959 101112 ClOCCH24 COCl 2 66 3
10
610 1 1 6 ClOCCH28COCl 10
3 66 NaOH
H 2 N
H H
C Cl

a
182 50 35 14 5.6 0.70
17 8 6.5 3.4 2.3 1.7
0.86 1.47 1.75 1.11 1.76 2.75
a
2 1 1 610 m- ηη0 ηsp η-η0/η0 cηsp/c0 η ηKMaMKaa 0.5 2.013 η
3
3-1
66 ATR 4 FT/IR- 4100 4000 650 cm1 0.9 cm1 7800 350 cm1 ATR ZnSe 625 cm1
4 FT/IR-4100 ab ATR b
a b
5
ATR ATR 2 R-CO-NH-R 6a 3400 cm1 7
5 2368 cm1
CO2 668 cm1 CO2
2cm115
C-O O-H C=O N-H
R-OH 1350 1260 3400 3200
R-C=OH 1740 1720
R-C=OR 1725 1705
R-C=OOR 1210 1163 1750 1735
R-C=OOH 1320 1210 3300 2500 1725 1700
R-C=ONH-R 1680 1630 3320 3140
R-NH-R 3500 3310
66 ATR
66 IR 6b 66 1500 6ab
6ATR 66 ab
7 66
28

3-2
66 265 280 300 66 300 14 66
4
4-1 116.21 25 g
0.5 M NaOH 430 ml 183.03 25 g 480 ml / 1.76 2 3 11
4-2 215
C=O 1700 cm1 C=O 100 cm1 8 C=O 2 66 3 16 66
1718 IR SDBSWeb19 Gaussian 09 20
1420 1470 cm1 CH2 scissoring CH2
29
21 66
IR 40 240 30 1.090 1.240 g/cm3 66 3 EtC=ONH-CH26-NH-C=O-CH24-C=ONH-Pr IR 936 cm1 C-CO C-C trans 1144 cm1 C-C gauche 22IR 1 2324 3 11 3 1742 cm1
1633 cm1 6 66 IR 25 3 IR 66 26 66 1730 cm1 C=O 66 1501713 cm1 27
8C=O 2
R
C
N
H
O
R
R
C
N+
H
O-
R
30
No. 562014
27 C=O1725 1700 cm1 2 3 1742 cm1 28 IR 1694 1742 cm1 C=O29
5
66 ,
3 66
cm1a
cm119
3301s 3081w 2930s 2857m 1742w 1633vs 1536vs 1473m 1464m 1416m 1372w 1275m 1200m 1180w 1146w 1041w 935m 686s
N-H21
N-H 21
2 N-HC-N 21
CH2 scissoringnext to NH22
not adjacent to amide22
next to CO22
CH2 twist-wagging 21
CH2 wagging 21
C-C skeletal22
3307vs 3072m 2961s 2853s
1672vs 1563vs 1474m 1467m 1435s 1328w 1369m 1276m 1285m 1206m1229m 1164s 1119w 1053w1070w 950w 692s
avs: very strong, s: strong, m: middle, w: weak.
31
ε- 6 1114 260
5-2
1111214 adipoyl chloride → chloride
301 1 ec chlorid
acetate 30
acetatechloride 31
5-3
CO2
H2O CH2NH2COOH3 H2SO4
32
4 CO2
2368 cm1668 cm1


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