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Thermodynamics & Phase Change

Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

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Page 1: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Thermodynamics

amp Phase Change

Heat can only do one thing at a time either change the temperature OR change the state

Changes of state ndash seen in phase change diagram

tem

pera

ture

heat added

Diagonal regions where thermal energy is added and particles increase in motion (temperature changes)

Flat regions where changes in state occur All added thermal energy goes to overcome the forces holding the particles together

Heat of fusion ndash The amount of energy required to melt one kilogram of a substance

Heat of vaporization ndash the amount of energy required to vaporize one kilogram of a substance

Heat of Fusion amp Vaporization for Water

Heat of fusion for waterbull Hf = 334x105 Jkg

bull positive when melting negative when freezing

Heat of vaporization for waterbull Hv = 226x106 Jkg

bull positive when evaporating negative when condensing

Heat required to melt

Q = mHf

use for melting amp freezing

Heat required to vaporize

Q = mHv

use for evaporating amp condensing

Specific Heat Values

Cice = 2060 Jkg˚C

Cwater = 4180 Jkg˚C

Csteam = 2020 Jkg˚C

Use these values for temps in Celsius or Kelvin

Example 1

You are asked to melt 0100 kg of ice at its melting point and warm the resulting water to 200 ordmC How much heat is needed

Calculate heat needed to melt the ice

Q1 = mHf

Calculate heat needed to raise water temperature

Q2 = mCΔT Add all heats together to get the total heat

needed

Q = Q1 + Q2

Example 1 Strategy

Example 1 Solution

Q1 = 33400 J

Q2 = 8360 J

Q = 41760 J

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 2: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Heat can only do one thing at a time either change the temperature OR change the state

Changes of state ndash seen in phase change diagram

tem

pera

ture

heat added

Diagonal regions where thermal energy is added and particles increase in motion (temperature changes)

Flat regions where changes in state occur All added thermal energy goes to overcome the forces holding the particles together

Heat of fusion ndash The amount of energy required to melt one kilogram of a substance

Heat of vaporization ndash the amount of energy required to vaporize one kilogram of a substance

Heat of Fusion amp Vaporization for Water

Heat of fusion for waterbull Hf = 334x105 Jkg

bull positive when melting negative when freezing

Heat of vaporization for waterbull Hv = 226x106 Jkg

bull positive when evaporating negative when condensing

Heat required to melt

Q = mHf

use for melting amp freezing

Heat required to vaporize

Q = mHv

use for evaporating amp condensing

Specific Heat Values

Cice = 2060 Jkg˚C

Cwater = 4180 Jkg˚C

Csteam = 2020 Jkg˚C

Use these values for temps in Celsius or Kelvin

Example 1

You are asked to melt 0100 kg of ice at its melting point and warm the resulting water to 200 ordmC How much heat is needed

Calculate heat needed to melt the ice

Q1 = mHf

Calculate heat needed to raise water temperature

Q2 = mCΔT Add all heats together to get the total heat

needed

Q = Q1 + Q2

Example 1 Strategy

Example 1 Solution

Q1 = 33400 J

Q2 = 8360 J

Q = 41760 J

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 3: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Changes of state ndash seen in phase change diagram

tem

pera

ture

heat added

Diagonal regions where thermal energy is added and particles increase in motion (temperature changes)

Flat regions where changes in state occur All added thermal energy goes to overcome the forces holding the particles together

Heat of fusion ndash The amount of energy required to melt one kilogram of a substance

Heat of vaporization ndash the amount of energy required to vaporize one kilogram of a substance

Heat of Fusion amp Vaporization for Water

Heat of fusion for waterbull Hf = 334x105 Jkg

bull positive when melting negative when freezing

Heat of vaporization for waterbull Hv = 226x106 Jkg

bull positive when evaporating negative when condensing

Heat required to melt

Q = mHf

use for melting amp freezing

Heat required to vaporize

Q = mHv

use for evaporating amp condensing

Specific Heat Values

Cice = 2060 Jkg˚C

Cwater = 4180 Jkg˚C

Csteam = 2020 Jkg˚C

Use these values for temps in Celsius or Kelvin

Example 1

You are asked to melt 0100 kg of ice at its melting point and warm the resulting water to 200 ordmC How much heat is needed

Calculate heat needed to melt the ice

Q1 = mHf

Calculate heat needed to raise water temperature

Q2 = mCΔT Add all heats together to get the total heat

needed

Q = Q1 + Q2

Example 1 Strategy

Example 1 Solution

Q1 = 33400 J

Q2 = 8360 J

Q = 41760 J

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 4: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Diagonal regions where thermal energy is added and particles increase in motion (temperature changes)

Flat regions where changes in state occur All added thermal energy goes to overcome the forces holding the particles together

Heat of fusion ndash The amount of energy required to melt one kilogram of a substance

Heat of vaporization ndash the amount of energy required to vaporize one kilogram of a substance

Heat of Fusion amp Vaporization for Water

Heat of fusion for waterbull Hf = 334x105 Jkg

bull positive when melting negative when freezing

Heat of vaporization for waterbull Hv = 226x106 Jkg

bull positive when evaporating negative when condensing

Heat required to melt

Q = mHf

use for melting amp freezing

Heat required to vaporize

Q = mHv

use for evaporating amp condensing

Specific Heat Values

Cice = 2060 Jkg˚C

Cwater = 4180 Jkg˚C

Csteam = 2020 Jkg˚C

Use these values for temps in Celsius or Kelvin

Example 1

You are asked to melt 0100 kg of ice at its melting point and warm the resulting water to 200 ordmC How much heat is needed

Calculate heat needed to melt the ice

Q1 = mHf

Calculate heat needed to raise water temperature

Q2 = mCΔT Add all heats together to get the total heat

needed

Q = Q1 + Q2

Example 1 Strategy

Example 1 Solution

Q1 = 33400 J

Q2 = 8360 J

Q = 41760 J

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 5: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Heat of fusion ndash The amount of energy required to melt one kilogram of a substance

Heat of vaporization ndash the amount of energy required to vaporize one kilogram of a substance

Heat of Fusion amp Vaporization for Water

Heat of fusion for waterbull Hf = 334x105 Jkg

bull positive when melting negative when freezing

Heat of vaporization for waterbull Hv = 226x106 Jkg

bull positive when evaporating negative when condensing

Heat required to melt

Q = mHf

use for melting amp freezing

Heat required to vaporize

Q = mHv

use for evaporating amp condensing

Specific Heat Values

Cice = 2060 Jkg˚C

Cwater = 4180 Jkg˚C

Csteam = 2020 Jkg˚C

Use these values for temps in Celsius or Kelvin

Example 1

You are asked to melt 0100 kg of ice at its melting point and warm the resulting water to 200 ordmC How much heat is needed

Calculate heat needed to melt the ice

Q1 = mHf

Calculate heat needed to raise water temperature

Q2 = mCΔT Add all heats together to get the total heat

needed

Q = Q1 + Q2

Example 1 Strategy

Example 1 Solution

Q1 = 33400 J

Q2 = 8360 J

Q = 41760 J

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 6: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Heat of Fusion amp Vaporization for Water

Heat of fusion for waterbull Hf = 334x105 Jkg

bull positive when melting negative when freezing

Heat of vaporization for waterbull Hv = 226x106 Jkg

bull positive when evaporating negative when condensing

Heat required to melt

Q = mHf

use for melting amp freezing

Heat required to vaporize

Q = mHv

use for evaporating amp condensing

Specific Heat Values

Cice = 2060 Jkg˚C

Cwater = 4180 Jkg˚C

Csteam = 2020 Jkg˚C

Use these values for temps in Celsius or Kelvin

Example 1

You are asked to melt 0100 kg of ice at its melting point and warm the resulting water to 200 ordmC How much heat is needed

Calculate heat needed to melt the ice

Q1 = mHf

Calculate heat needed to raise water temperature

Q2 = mCΔT Add all heats together to get the total heat

needed

Q = Q1 + Q2

Example 1 Strategy

Example 1 Solution

Q1 = 33400 J

Q2 = 8360 J

Q = 41760 J

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 7: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Heat required to melt

Q = mHf

use for melting amp freezing

Heat required to vaporize

Q = mHv

use for evaporating amp condensing

Specific Heat Values

Cice = 2060 Jkg˚C

Cwater = 4180 Jkg˚C

Csteam = 2020 Jkg˚C

Use these values for temps in Celsius or Kelvin

Example 1

You are asked to melt 0100 kg of ice at its melting point and warm the resulting water to 200 ordmC How much heat is needed

Calculate heat needed to melt the ice

Q1 = mHf

Calculate heat needed to raise water temperature

Q2 = mCΔT Add all heats together to get the total heat

needed

Q = Q1 + Q2

Example 1 Strategy

Example 1 Solution

Q1 = 33400 J

Q2 = 8360 J

Q = 41760 J

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 8: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Specific Heat Values

Cice = 2060 Jkg˚C

Cwater = 4180 Jkg˚C

Csteam = 2020 Jkg˚C

Use these values for temps in Celsius or Kelvin

Example 1

You are asked to melt 0100 kg of ice at its melting point and warm the resulting water to 200 ordmC How much heat is needed

Calculate heat needed to melt the ice

Q1 = mHf

Calculate heat needed to raise water temperature

Q2 = mCΔT Add all heats together to get the total heat

needed

Q = Q1 + Q2

Example 1 Strategy

Example 1 Solution

Q1 = 33400 J

Q2 = 8360 J

Q = 41760 J

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 9: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Example 1

You are asked to melt 0100 kg of ice at its melting point and warm the resulting water to 200 ordmC How much heat is needed

Calculate heat needed to melt the ice

Q1 = mHf

Calculate heat needed to raise water temperature

Q2 = mCΔT Add all heats together to get the total heat

needed

Q = Q1 + Q2

Example 1 Strategy

Example 1 Solution

Q1 = 33400 J

Q2 = 8360 J

Q = 41760 J

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 10: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Calculate heat needed to melt the ice

Q1 = mHf

Calculate heat needed to raise water temperature

Q2 = mCΔT Add all heats together to get the total heat

needed

Q = Q1 + Q2

Example 1 Strategy

Example 1 Solution

Q1 = 33400 J

Q2 = 8360 J

Q = 41760 J

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 11: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Example 1 Solution

Q1 = 33400 J

Q2 = 8360 J

Q = 41760 J

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 12: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Example 2

A 400-g sample of chloroform is condensed from a vapor at 616 ordmC It liberates 9870 J of heat What is the heat of vaporization of chloroform

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 13: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Example 2 Solution

Q = mHv

-9870 = (040)(Hv)

Hv = -246750 Jkg

(negative because itrsquos cooling)

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 14: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Law of Conservation of Energy

Energy cannot be destroyed or created only transferred

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 15: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

1st Law of ThermodynamicsThe total increase in the

thermal energy of a system is the sum of the heat added to it and the work done on it

Heat engines are devices which convert thermal energy to mechanical energy continuously along with some waste heat

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 16: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

2nd Law of Thermodynamics

Entropy of the universe is always maintained or increased All things will become more and more disordered unless some action is taken

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 17: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Entropy is a measure of the disorder in a system

Entropy increases when heat is added and decreases when heat is removed

2nd Law of Thermodynamics

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage

Page 18: Thermodynamics & Phase Change. Heat can only do one thing at a time: either change the temperature OR change the state!

Thermal Engine efficiency

Called Carnot efficiency or the ideal efficiency of a heat engine

(Thot-Tcold)Thot = Ideal efficiency

Temperatures must be in Kelvin

Result is a percentage