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Calculation of Theoritical Values of Biogas
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04/06/2015 [Digestion]BiogasCOD/CH4yield
http://lists.bioenergylists.org/pipermail/digestion_lists.bioenergylists.org/2011February/000566.html 1/2
[Digestion]BiogasCOD/CH4yieldGasanOsojnikgasan.osojnikatgmail.comMonFeb1422:32:04PST2011
Previousmessage:[Digestion]NegativeBiogasPressNextmessage:[Digestion]DigestionofHoneyWasteMessagessortedby:[date][thread][subject][author]
Dearall,
IthinkthediscussedparametersregardingtheCOD/CH4yieldhavetobefurtherclarified.
Thereferencevalue0.35m3methane/kgofCODisatheoreticalvalueeveryonecancalculate,andisusedforengineeringpurposesinthedesigning&optimizationstageofthebiogasplant.AsMarcusalreadyexplained,itiscalculatedonthebasisofCOD*of*methane,therefore:
CH4+2xO2>CO2+2xH2O
m(CH4)=16gm(2xO2)=64gCOD(CH4)=16gCH4/64gO2=4gCOD
As1moleofgas=22,4dm3@stp,
(CH4)=16g/22,4dm3=0,71g/dm3
And1gofCH4occupies@stp
V(CH4)=22,4/16g=1,4dm3CH4
Tosummarize,1gofCH4is4gofCODandoccupies1,4dm3CH4@stp,
therefore,per1gofCOD
Y=1,4dm3CH4/4gCOD=0,35m3CH4/kgCOD
Anaerobicdegradationof1kgCODofsubstrate(whichis"transfered"totheCODofmethane)thereforetheoreticallyyields0,35m3ofmethane.Asexpected,thisvaluesarestronglyundermatchedinrealoperatingconditions.
ThevaluementionedbyMel,derivedfromexperimentalconditions,ismostlikelycoincidental,meaningthattheoperatingconditionsinthatparticularcase(0,35m3CH4/4kgCOD)meaning,thattheYi=(0,35/1)/(0,35/4)=25%oftheoreticalyield,orcanbederivedfrominappropriateinterpretationofthetheoreticalvalues,as1000molofCH4doindeedcorrespondto4kgofCOD(4gCOD/moleofCH4).
BRfromSI,Gasan
>>ThanksMarcusforyourresponsetomyquery:>>>>>>>All,>>>>>>Doyouknowof(have)awayto"translate"BODand/orCODtomethane>>>potential?ItwouldofcoursehavetobeintermsofBOD/CODremoved>>>givingrisetosomuchmethane.>>>>>>Mel>>>>>>HiMel,>>>>>>ifyouconsidertheremovedCODiscompletelytransferredtoCH4inthe>>>Biogas(CO2=0COD)youcancalculate:>>>>>>1gCODremoved>0,25gCH4>>>Or1gCODremoved>0,35LCH4(273K,1013mbar).>>>>>>Ifyouwanttoestimatemoreexactlyyoumayconsiderthatsomefothe>>>removedCODflowsintoH2andmicrobialbiomass.>>>>>>Markus>>>>Yourcalculation,however,isatoddswiththestatementinGradyetal.
04/06/2015 [Digestion]BiogasCOD/CH4yield
http://lists.bioenergylists.org/pipermail/digestion_lists.bioenergylists.org/2011February/000566.html 2/2
>>1999,page600in"BiologicalWastewaterTreatment2ndedition"Marcel>>Dekker.Thestatementisthat4kgCODremovedgenerates0.35m3of>>methane(0.35LCH4/4gCODremoved).Alsothatfigureornearaboutsis>>foundinotherdocuments.Apparentlyitwasderivedfromtheoretical>>calculation(notunderstoodbyme)andalsofromseriousobservationof>>realsystems.Ifrepetition=validity,thhanthfigureisusable.>>>>Perhapsotherscanweighinonthetheoreticalend,orreportother>>"sightingsofthetranslation.>>>>Mel>nextpartAnHTMLattachmentwasscrubbed...URL:
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