THE VAPOR PRESSURE BEHAVIOR OF POLAR AND NONPOLAR SUBSTANCES

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Experimental report on tabulation of experimental vapor pressure data of polar and nonpolar substaances

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TT{E VAPOR PRESSURE BEHTryIOROF

POLAR AI\iD NO}IPOI-AR SUBSTA}ICES

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Technological ilnstitu*eNORTHWESTERN UNIVERSITYEVANSTON, ILLINOIS

?,*

a report

by

L

lvhteo Antoqrio Comez Nietoand

Christos G. Papadopoulos

Ctrenrical Engineering Departnent

Northwestern Univers

ity

Evanston,L976

Illinois

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------- --------------------------CRItlCALCOI-ISTANTS

TC= 528.b57 PG= 2?823.880 VC= 394.59$ ----------:::--- ---::::----------

--

-il;;;;;;;-

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;;;;;;;;;;; ---

ALFA= 3.93923 EETA=-{+.28425

GSI'lA= .26582 fl= 1.3957+ frl= 7.*80{,8rr-----r Jrrir rrrr:r i ririii-Jrir-ii 5|r r-r

PfRIPHERAL PARAI{ETEES

------.-

G3?S .6697 TR8 S -5.4976 XXXX TRINF 7.f5S0 AC R;S.8'C' t. #S8q lr . 2518354.---------------t---

T8

LITERATURT

CNLgULATED

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7t

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CRITICAL

CONSTANTS

TC= 551.958 PC= 18764.000 VC= 488.12G _--___-_--:::-___ _-_: :::-_ -__- _- -PARAilETERS

Fgn EAUATION{1}

ALFA= 4'336G? SETA=-4. l}776f GAIIA= .14158f,l= 1.43962 |.1= 7. S0380-------rrrrri-ii; ----;--;---

-i-

a;-

---------------

PRIPHfRAL

-- ---:-i-:---;-PARAHETERS

- --

TB 390.7970 TRB .6954 S -7.3?il8 TRINF XXXX AC 7.5880 RrS.B-.C. 0rtggg H .3776

LITTRATURE

CALCULATEO

390.7964 .6954 -7.32S 6 .9023714371

'?o34e4 .3514

-------;;;ffi;NUI-l8ER CF

r$rFoRr{A

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REF

23

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79.92

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38?.579 3E7.892 388.399 388.881 38 g. 356 38 9. 8Il9 390,325 390.7971. ?54 1. 726 39 2. 18I+ 392, 63539 39

376.5lt|

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---

CRlTICAL

CONS?ANTS

TC= 561+. il28 PC= 19319.880 YC: 477.918

---------------------

t----

PARA},ITERS FOfr EQUATION {1}

ALfA= q.1b425BE T A

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PERtrPHf RAL PARAI,lTTRS

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T8 39a. C 759 Tp"g . 6951 S '7.3778 XXXX TRINF AC 7.5888 R'S. B. C. S. SSSS t{ .3s94

LITERSTURT CALCULATf33q2.0737 ,5951

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HE PT A NE

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5

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{ 12r { 12} { 12} { t2) { 12} { 12) { 12} I 12t { 121 I L?l { 12f ( r?) { 1Zl { 121 { 12r ( 121 { 12} ( 12t I L?t I t?,

398.21+G 40 2. ZB8 48 9. 238

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3t5,922 3t9,8??

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(189) ( 189t t 1s9l{ 1891

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CR

ITICAL

C0l'lSTAr'lTS

PC= t925t.88GVC=

55U.8 13

tr75. 9?*

ZC=

.2i.

PARA},IETEFS FOF QUATION

{1I

ALfA= 4.16785

6fll.iA;

SETA=-4r 36156

frl= 7, 0 !0 t*

|{= 1,46t?2

.19378

PERI PHIRAL PARAI,!gTERS

LITERITURT8 TqB39

c TRIAC

,*955 -7.3888

8. I 59f

CALCULATEs 390 8575

NF

*. S .8. C.lf

0.80t{t,3587

xx xx 7.58G8

" .5955 -7 ' 38877

.9065 .7 ?9t

,

.t7 87

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- -- -- -- ----------------------FITTII{6 INTORHNTION

---

},IAX:ilUI't DTVIATICN AUfRAGE OEVlATIONSTANOARC DEVIATTON

NU}4BER

SF PCINTS

31

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4.HETHYLHEPTANE

97

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Ttx?85" 558297

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2t59.2227Lt+.76 337S.50

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| 433.1523. 148 15 3. 15S 45 3. 15? t+73.1118

15? 148 2 3. 15{i

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3362.8

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55

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CRITICAL CC}ISTANTS

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PARAI.ITERS FOR QUATION(1'

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