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The Periodic Table• A map of the building block of matter.
1IA
18VIIIA
11H
1.00797
2IIA
Periodic Table 13IIIA
14IVA
15VA
16VIA
17VIIA
2He
4.0026
23
Li6.939
4Be
9.0122
5B
10.811
6C
12.0112
7N
14.0067
8O
15.9994
9F
18.9984
10Ne
20.179
311
Na22.9898
12Mg24.305
3IIIB
4IVB
5VB
6VIB
7VIIB
8 9VIIIB
10 11IB
12IIB
13Al
26.9815
14Si
28.086
15P
30.9738
16S
32.064
17Cl
35.453
18Ar
39.948
419K
39.102
20Ca40.08
21Sc
44.956
22Ti
47.90
23V
50.942
24Cr
51.996
25Mn
54.9380
26Fe
55.847
27Co
58.9332
28Ni58.71
29Cu63.54
30Zn65.37
31Ga65.37
32Ge72.59
33As
74.9216
34Se78.96
35Br
79.909
36Kr83.80
537
Rb85.47
38Sr87.62
39Y
88.905
40Zr91.22
41Nb
92.906
42Mo95.94
43Tc[99]
44Ru
101.07
45Rh
102.905
46Pd106.4
47Ag
107.870
48Cd
112.40
49In
114.82
50Sn
118.69
51Sb
121.75
52Te
127.60
53I
126.904
54Xe
131.30
655Cs
132.905
56Ba
137.34
57La
138.91
72Hf
178.49
73Ta
180.948
74W
183.85
75Re186.2
76Os190.2
77Ir
192.2
78Pt
195.09
79Au
196.967
80Hg200.59
81Tl
204.37
82Pb
207.19
83Bi
208.980
84Po[210]
85At[210]
86Rn[222]
787Fr[223]
88Ra[226]
89Ac[227]
104Ku[260]
105 106 107 108 109http://www.chemsoc.org/viselements/pages/periodic_table.html
Periodic Law
• Periodic Law: –Physical and chemical
properties of the elements repeat in a regular pattern when they are arranged in order of increasing atomic number.
Families or Groups & Periods
• Families or groups go down columns of the periodic table.
• There are 18 columns that have similar characteristics and they have the following names.1 – alkaline earth metals 15 – nitrogen group2 – alkali metals 16 – chalcogens3-12 – transition metals 17 – halogens13 – boron group 18 – noble gases14 – carbon group
• Periods go across the periodic table.
Directions of trendsIncrease Across – Decrease Down
Electronegativity• Ability to attract
electrons • Most electronegative
atoms are in upper right corner of periodic table (fluorine)
• That’s why atoms on the right gain electrons; they pull electrons from the metals on the left.
Ionization Energy
• Energy required to remove an electron from an atom
• The nucleus’s hold on its valence electrons
Direction of trends increase-down a group & decrease across a period
Atomic Radius• Refers to size of an atom
• As you move across the period, the attraction between valence electrons and the nucleus is stronger; resulting in smaller size
Melting & Boiling Points• Temperature required to
melt or boil an element.
• Metals increase as you go down a group; decrease across a period.
• Nonmetals decrease down a group and increase across a period.
Periodic Table: Metallic arrangement• Layout of the Periodic Table: Metals vs. nonmetals
1IA
18VIIIA
12
IIA13
IIIA14
IVA15VA
16VIA
17VIIA
2
33
IIIB4
IVB5
VB6
VIB7
VIIB8 9
VIIIB10 11
IB12IIB
4
5
6
7
MetalsMetalsNonmetalsNonmetals
Reading the Periodic Table: Classification
Across the Periodic TablePeriods:Periods: Are arranged horizontally across the periodic table Are arranged horizontally across the periodic table
(rows 1-7)(rows 1-7)These elements have the same number of valence shells.These elements have the same number of valence shells.
1IA
18VIIIA
12
IIA13
IIIA14
IVA15VA
16VIA
17VIIA
2
33
IIIB4
IVB5
VB6
VIB7
VIIB8 9
VIIIB10 11
IB12IIB
4
5
6
7
2nd Period
6th Period
Down the Periodic Table•Family:Family: Are arranged vertically down the periodic table Are arranged vertically down the periodic table (columns or (columns or group, 1- 18 or 1-8 A,B)group, 1- 18 or 1-8 A,B)•These elements have the same number electrons in the outer most shells, the valence shell.These elements have the same number electrons in the outer most shells, the valence shell.
1IA
18VIIIA
12
IIA13
IIIA14
IVA15VA
16VIA
17VIIA
2
33
IIIB4
IVB5
VB6
VIB7
VIIB8 9
VIIIB10 11
IB12IIB
4
5
6
7
Alkali Family: 1 e- in the valence shell
Alkali Family: 1 e- in the valence shell
Halogen Family: 7 e- in the valence shell
Halogen Family: 7 e- in the valence shell
Infamous Families of the Periodic Table
• Notable families of the Periodic Table and some important members:
1IA
18VIIIA
12
IIA13
IIIA14
IVA15VA
16VIA
17VIIA
2
33
IIIB4
IVB5
VB6
VIB7
VIIB8 9
VIIIB10 11
IB12IIB
4
5
6
7
Alkali
Alkaline (earth)
Transition MetalsTransition Metals
Noble GasNoble GasHalogenHalogen
ChalcogensChalcogens
1IA
18VIIIA
12
IIA13
IIIA14
IVA15VA
16VIA
17VIIA
2
33
IIIB4
IVB5
VB6
VIB7
VIIB8 9
VIIIB10 11
IB12IIB
4
5
6
7
Important members - the Elements
• Individual members of selected Elements & their Individual members of selected Elements & their characteristics characteristics
H He
Li
Na
K Ca
Mg
Fe
I
Cl
F
P SSi
ONC
Al
ZnCu
Ag
Br
Periodic Table: Electron Behavior• The periodic table can be classified by the behavior of the electrons
1IA
18VIIIA
12
IIA13
IIIA14
IVA15VA
16VIA
17VIIA
2
33
IIIB4
IVB5
VB6
VIB7
VIIB8 9
VIIIB10 11
IB12IIB
4
5
6
7
---------- --------------- ----------------- METALS
Alkali Alkaline
Transition
METALLOID NON-METALS Noble gas Halogens
Chalcogens These elements tend to give up
e- and form CATIONS
These elements will give up e- or
accept e-
These elements tend to accept e- and form ANIONS
Trend in Atomic Radius•Atomic Radius: Atomic Radius:
•The size of an atom is decreases as you move across a period and increases as you move down a family.
Trend in Ionization PotentialIonization potential: Ionization potential:
The energy required to remove the valence electron from an atom. It is greatest in the upper right corner of the periodic table because these atoms hold on to their valence e- the tightest.
Trend in Electron Affinity
Electron Affinity: Electron Affinity:
The energy released when an electron is added to an atom. It is greatest in the upper right corner of the periodic table as these atoms have the greatest affinity for electrons.
Summary of Trends1. Electron Configuration
2. Atomic Radius
3. Ionization Energy3. Ionization Energy4. Electron Affinity4. Electron Affinity