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The New Coating Technologies for Plastics “NSC” NIPPON FINE CHEMICAL Co.,Ltd

The New Coating Technologies for Plastics “NSC” Protection glasses Developed coating resin, such as acrylic, polyurethane and inorganic materials. Variety of raw materials are

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The New Coating Technologies

for Plastics

“NSC”

NIPPON FINE CHEMICAL Co.,Ltd

Developed coatings agents for lens.

Served glass manufactures in Japan for more than 30years and

expanded glass business into the world.

Expanded coating business to other molded products such as Helmet

visor, Protection glasses

Developed coating resin, such as acrylic, polyurethane and inorganic

materials.

Variety of raw materials are selected carefully and then synthesized

for efficient functional coatings

Expanded coating business to film coatings for electronic materials

Various formulations are available to meet customer’s technical

requirements

NFC’s coating technologies history

Development of coatings and production and sales

Electronic industry materials

(Mobile phone, Smartphone, Computer display, TV, etc.)

Glasses

Sheets (a helmet visor, protective goggle, etc.)

Synthesis of functional materials, functional monomers,

functional development and manufacture of polymers

organic, inorganic, polymer synthesis and prescription

Key Business

1)Thermal curable coatings

・ For glazing

・ For films

・ For functional coatings

2)UV curable coatings

・ For films

・ For sheets

3)Hybrid type

Products offering

1. THERMAL CUREBLE HARD COATINGS

FOR LENS & SHEETS

CHARACTERISTICS OF NIIPPONFINE CHEMICAL

PRODUCTS

Stable performance: High abrasion resistance

Short Curing-time : 10~30minutes at 130℃

High adhesion

compatible with various plastics, metals, other substrate

Multiple functions

Capable of adding to coating layers some functions such

as antifogging, dyeing and so on

Substrate Product name Features

1.67 MR-7 ・NSC-5671 ①Disappearance of 1.60 interference fringes PU(MR-8) ・NSC-5601 insusceptible to Acryl product method 1.59 PC ・NSC-5506 ・NSC-5140/Primer ②Superior Adhesion ・NSC-5614 Boiling test 100/100 1.56 Polyurethane ・NSC-5616 Acryl ③Advanced Abrasion DAP more than 5 at 1.53 Trivex ・NSC-5613 Bayer test 1.49 CR-39 ・NSC-5150A Others ・NSC-5215 ④Excellent Weather Polarized lens ・NSC-5140 resistance ・NSC-AM-60 stable over 120hr at Stainable hard coating ・NSC-DY-106 QUV test Anti static hard coating

Functional thermal curable coatings

8

Disappearance of interference fringes

 adjustment index

Refractive index can be adjusted depending on the refractive index of substrate.

Adjustable range: ~1.67

Index

Substrate 1.60

Coating layer 1.50

Index

Substrate 1.60

Coating layer 1.60

Index adjustment

NSC-5601Q

REFRACTIVE INDEX: 1.60

PENCIL HARDNESS: 3H(Polyurethane)

ABRASION(SW): 4 (very good)

ADHESION: 5 (excellent)

Bayer test : 4↑

QUV test :120hr↑

SUBSTRATE: Polyurethane

Polyacrylate

CURING CONDITION:

120℃,30mins

NSC-5613

Product name NSC-5613

Refractive index 1.53

Thickness 3 - 5 mm

Transmittance > 98%

Falling ball impact test Excellent (127 cm, 300 g)

Taber abrasion test △haze 1 % ( CS-10F wheel, 500g load, 100 cycle)

Steel wool test 4 (very good) (#0000, 500 g load, 50 time)

Bayer test 5

Crosshatch adhesion 100 / 100

Boiling water resistance Stable (100 deg. C, 30 min)

Weather resistance

QUV test (7days) Stable 168hr

Sunshine-weather meter Stable 240hr

crosshatch adhesion 100 / 100

Applied to Trivex

Advanced Adhesion, Weather resistance

NSC-5506 Advanced abrasion resistance Hard Coat for

Polycarbonate

Features : Advanced abrasion resistance, flexibility

1) ASTM D1044 500g x 100 cycles, CS10F wheels

2) Steel wool abrasion test 1kg load×100 reciprocations

3) Soaked in 100℃ of water for 30 mins.

NSC-5506 NSC-1500

NSC-5000 series flexible

Bayer abrasion test 3.9

Taber Abrasion test

(△haze%) 1) < 0.9

Abrasion2) No scratch

Adhesion 100 / 100

Adhesion

boiling water test 3) 100 / 100

Adhesion

QUV test 96 hrs. 100 / 100

Feature : high hardness & advanced abrasion resistance

Haze (%) < 0.2

Total Light Transmittance (%) > 90

Pencil hardness 1) 2H

Taber Abrasion test(△haze%) 2) < 0.2

Adhesion 100 / 100

Adhesion

boiling water test 3) 100 / 100

1) 750g load, coated on PET film.

2) ASTM D1044 500g x 100 cycles, CS10F wheels

3) Dipped in boiling water for 30 mins.

NSC-5215 High hardness / thermal curing

Feature : No interference fringe with PC lenses

Interference fringe none

Bayer abrasion test 3.1

Adhesion 100 / 100

Adhesion

boiling water test 1) 100 / 100

Adhesion

QUV test 120 hrs. 100 / 100

1) Dipped in boiling water for 30 mins.

NSC-5614

Feature : Stable after QUV test (120 hrs.)

Bayer abrasion test 4.0

Adhesion 100 / 100

Adhesion

boiling water test 1) 100 / 100

Adhesion

QUV test 120 hrs. 100 / 100

1) Dipped in boiling water for 30 mins.

NSC-5150A Weather resistance coating for CR-39 / thermal curing

NSC-DY-106 Stainable hard coating

Product name NSC-DY-106

Curing system Thermal curing

NV 32 %

Viscosity 6.0 mPa・s

Falling sand test <4

Taber abrasion test <2

Adhesion 100 / 100

Features Stainable

Advanced anti-

abrasion

Stainable hard coating Standard hard coating

0 20 40 60 80 100

Afterstaining

DY-106

Transmittance

(%)

Weather resistance

1)Prevention of coating stripping

2)UV protection

Keep substrates from yellowing and damaged.

Wavelength (nm)

Spectral transmission range of UV

Perfect UV protection less than 380nm

Tra

nsm

itta

nce

Uncoated PC lens

Weather resistance

Yellowing resistance

NSC-1550 coated

QUV test / hour

Ye

llo

w

Ind

ex

(Y

I)

Weather resistance

:UV curable hard coating

UV irradiation 72hr

Base material(PET f ilm)

Coated f ilm(conventional UVcurable coating)

Coated f ilm(NFC's weather

resistance coating)

Since the coating contains our weather resistance formulation technologies, the cured

film shows much better anti-yellowing property after irradiation of UV compared with

those of conventional UV curable coatings.

*)Upper half is covered with aluminum foil to protect against UV rays.

Polarized lens needs to be cured at low temperature due to iodine series contained in the lens.

NSC-AM60 does not cause any damage to polarized lens because it can be cured at 90℃.

Coating for polarized lens

UV light

Natural light

Glare by reflection

Polarized light filter

0

5

10

15

20

25

30

35

40

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5

T hic knes s (µm)

⊿H

a

z

e

F

a

l

l

i

n

g

s

a

n

d

t

e

s

t

NSC-1520

NSC-5501

NSC-5140

NSC-5200

Substrate

F alling s and tes t-thic knes s

relation

Thermal curing types for PC

Abrasion resistance - Coating thickness F

alli

ng

sa

nd te

st /

D

ha

ze

Thickness / mm

NSC-5501 PC lens brief thermoset test

1.5

2

2.5

3

3.5

4

1 1.5 2 2.5 5 10 30 45 60 120

Time(min)

Steel

Wool

test

110℃120℃130℃135℃NSC-1520 110℃

Handling equipment:Automatic dehydrator WS(wind speed) 3,000L/min SW test :our evaluation method♯0000 SW

PC lens quick thermal curing

NSC-5501 PC lens quick thermal curing test

Ste

el-w

oo

l h

ard

ne

ss

Handling equipment : Automatic drying machine

WS(Wind Speed) : 3,000L/min

SW test : Our evaluation method #0000 SW

Product name Features Application Curing

condition NSC-1500 for sheet PC 120゚C,1hr

NSC-1600 Stable in high temp. humid. PC 120゚C,1hr

condition, interference fringes less

NSC-5506 Advanced abrasion resistance PC 120゚C,30mins

flexible index=1.5

NSC-2000 for sheet PMMA 80゚C,2hrs

Anti-scratch

NSC-5140 Advanced abrasion resistance SEVERAL 120゚C,1hr

index=1.5 SUBSTRATE

NSC-5200 Advanced abrasion resistance SEVERAL 120゚,30mins

flexible index=1.5 SUBSTRATE

Products for thermal curable coating

Coated Uncoated

Antifogging coating

Product name Features Applicable plastics

NSC-AF332 Conform to EN166/168 PC other materials

and ECE 22/05

NSC-AF301 PC other materials

Antifogging coatings

NSC-AF-332 Antifogging coating / thermal curing

One-coat type for polycarbonate

Pass the EN168 test (Antifogging and Abrasion)

Antifogging evaluation: measure with the defogging tester after the water immersion.

N-mark

K-mark (Resistance to surface damage by fine particle) : 2.7

Uncoated Coated

 Coating

Concealing performance by coating

Product

Name NSC-5140 NSC-5200

Substrate Nylon Nylon

%Solid 33% 33%

Viscosity 6.0mPa・s 10.0mPa・s

△%T(588nm) 83.0 94.3

To avoid color-dulling of dyed lenses

In the case of hard coating of dyed Nylon lenses, conventional coatings sometimes cause color-dulling

of lenses or elution of dye to the coating liquid. NFC developed an anti-color-dulling coating by our

intensive study.

Transmittance change before and after coarting

40

50

60

70

80

90

100

110

380 420 460 500 540 580 620 660 700 740 780

Wavelength/nm

TransmIttance

T%

NSC-5140コート

未コート基材

NSC-5200コート

NSC-5140

Substrate

NSC-5200

Tra

nsm

itta

nce

/

%

Wavelength / nm

Spectral reflectivity

4.5

5

5.5

6

6.5

7

7.5

8

8.5

400 450 500 550 600 650 700

Wavelength/nm

Reflectance

ratIo

%R

AR coated Uncoated

Characters aren'tclear becauselight reflects

Characters areclear

Anti-reflection coating

of

Re

fle

cta

nce

/ %

R

Wavelength / nm

Performances of

thermal curing type for PC

NSC-5000 series flexibilityTaber abrasion test piece(NSC-1520)

NSC-1520

coated

Uncoated

NSC-5501 NSC-1520 NSC-5506 NSC-1500

Water-repellentContact angle 95 Contact angle 75

Contact angle 60AntifoggingContact angle 25

Contact angle NFC can make layers that contain various types of contact angle.

High water-repellent coating can be made by using NFC’s special techniques.

Water repellent performance does not deteriorate because the water repellent

agent is incorporated into the coating layer.

Thiourethane DAP Nylon Urethane

Urethane polarized Modified Polyester

Coatings for other base materials

Antistatic coating

Containing antistatic materials, films having around 1 × 108Ω electrical surface

resistance can be obtained

1×109 Ω/cm2

more than 1×1014 Ω/cm2

Product name surface resistance Features

・NSC-AS-201 1011~12 Water resistance

・NSC-AS-202 1011~12 Water resistance

Solvent resistance

・NSC-AS-203 1011~12 Water resistance

・NSC-AS-204 109 Water resistance

Antistatic hard coatings

:Thermal curing

Product name surface resistance Features Pencil

hardness

・NSC-AS-101 1011~12 Water resistance 2H

・NSC-AS-102 1011~12 Water resistance 2H

Solvent resistance

・NSC-AS-103 1011~12 Water resistance 2H

・NSC-AS-104 109 Water resistance H

Antistatic hard coating: UV curing

For FILM

2. THERMAL CURABLE HARD

COATINGS FOR FILMS

Feature of thermal curable coatings

Very short curing time

Standard curing condition at 130゚C, for 2mins

Excellent anti-scratch property

Taber abrasion test less than 2%

Low curl property

High hardness with better anti bent crack property

Easy to add further functions

Good adhesion to metal surface such as ITO films

Product name Features Applicable Pencil hardness viscosity

plastics (% solid)

・NSC-3000 Abrasion PET,TAC,PC,ITO F 23

Adhesiveness (30%)

・NSC-3010 Abrasion PET,PC H 5

Anti-scratch (26%)

・NSC-3101 Abrasion PET,TAC,ITO 2H 4

Anti-scratch (30%)

Flexible

・NSC-1700 Water & Oil PET,PC Repellent

(permanent)

Thermal curable hard coating

NSC-5125 High hardness coatings / thermal curing

39

The hardest coating of all NFC’s thermal curable

products (Pencil hardness 2H on PET film)

Advanced abrasion resistance

Properties

Pencil hardness 2H (PET film)

Adhesion 100 / 100

Water soak

adhesion* 100 / 100

Solvent resistance good

* Soaked in water at 80℃ for 30 mins, dried for 30 mins

NES-3101 PET film brief thermoset test

1.6

2

2.4

2.8

3.2

3.6

4

10秒 30秒 1分 1分30秒 2分 4分

Curing time (sec)

Steel

Wool

hardnes

110℃

120℃

130℃

140℃

10 30 60 90 120 240

Handling equipment:Automatic drying machine

WS(wind speed) 3,000L/min

SW test :our evaluation method #0000 SW

PET film : quick thermal curing

NSC-3101 PET film quick thermal curing test

Ste

el-w

oo

l h

ard

ne

ss

Product name Features Applicable Pencil viscosity

plastics hardness (% solid)

・NSC-7113 Low curl property PET,TAC film 2H 51

(55%)

・NSC-7120 High Adhesion PET,TAC film 2H 4

(55%)

・NSC-7121 High Adhesion PET,TAC film H 200

(100%)

・ NSC-7100 Hardness Sheet, film 2H 38

(80%)

・ NSC-7318 Hardness Sheet, film 4H

(60%)

3. UV CURABLE HARD COATINGS

Relationship between

thickness and pencil-hardness

Relationship between thickness and pencil-hardness

0

1

2

3

4

5

6

0 5 10 15 20

thickness(μ m)

PencIlhardness

NSC-3402

NSC-3300

NSC-3101

9H

5H

4H

3H

2H

H

100

基材:100μ mPET film

F

U

Pe

ncil

ha

rdn

ess

Substrate : 100mm PET film Thickness / mm

Product name Features Pencil viscosity

hardness (% solid)

・NSC-7101 Antifouling (oil repellant) 2H 75

finger print can be wiped off easily (80%)

・NSC-7102 Antifouling (lipophilic) 2H 6

(60%)

・NSC-7103 Flexible 2H 25

no crack after 180゚ bent (55%)

・NSC-7120 Impact resistance 2H

Functional hard coating

UV curable functionalized coating

NSC-7101/antifouling

uncoated

Coated

Finger print After wiping off/right side

Signed by permanent marker After wiping off

Since the cured film surface has oil repellant property, finger print attached on the

surface is wiped off easily.

UV curable functionalized

coating NSC-7102/antifouling

UncoatedCoated with NSC-7102

コート

Since the cured film surface has lipophilic property, finger print attached on the

surface is barely recognized.

Product name R.I. Pencil viscosity

hardness (% solid)

・NSC-7600 1.59 H 135

(60%)

・NSC-7212 1.49 2H 45

(65%)

・NSC-7500 1.36

Reflective Index

Product name Features Pencil viscosity

hardness (% solid)

・NSC-7306 Advanced weather 2H 78

resistance (50%)

・NSC-7313 Advanced weather 2H 85

resistance (50%)

(Thermal curing)

・NSC-3600 Advanced weather

resistance

Weather resistance

Spectral transmission range of UV

NSC-7302 Spectral transmission

0

20

40

60

80

100

120

300 310 320 330 340 350 360 370 380 390 400

wave length/nm

Trancemission %T T

ran

sm

issio

n /

%T

wavelength / nm

FEATURES

SUPERFICIAL INJURY AND SCRATCHES REVERT IN AN INSTANT.

Product name NSC-7700

Curing system UV

Viscosity 43.4mPa・s

NV 56%

Pencil hardness 2B(PET)

Abrasion Crack restoration nature is good (1kg load)

Adhesion 100/100

Thickness 20μm

NSC-7700

Self-healing coating

NSC-7700 Usual hard coating

4. HYBRID TYPE

Feature of hybrid type

Advanced hardness

Pencil hardness 4H

Advanced abrasion

Taber abrasion less than 1%

Multifunction

Weather resistance etc.

Pencil hardness and abrasion resistance

1

2

3

4

5

6

7

8

9

10

111 2 3 4 5

Pencil hardness

Thrmo-curable

UV-curable

Hybrid

HARDNESS

NSC-7310

Pencil hardness and abrasionA

bra

sio

n

Standard Type of Hybrids

Product name Features Applicable Pencil

plastics hardness

・NSC-7310 Hardness PET,TAC 3H

Abrasion

・NSC-7311 High hardness PET,TAC 2~3H

Tack free after heating

NSC-7322 High hardness coatings / UV curing

53

Organic-inorganic hybrid type

High hardness

Advanced abrasion resistance (Taber abrasion test : Dhaze% = 2.1 / 500g Load X 100 rotations)

Film thickness

/ mm 10 15 30 45

PC/PMMA

composite* 6H 8H 9H -

PC - F 2H 5H

* thickness of PMMA layer is 120 mm

<Pencil hardness test>

FEATURES OF COATINGS OF NFC

NFC is a world’s leading manufactures of thermal curable hard coatings.

We have been keeping majority of market share for a long time in JAPAN as well as SE ASIAN nations.

We have great deal of skill in this field based on our advanced technical background.

NFC can supply various types of UV curable hard

coatings.

NFC can supply the two different types of coatings based on the hybridization technologies of organic materials.

NFC can develop various types of coating by the

state-of-art technologies.