The Manufacturing Process of Portland Cement G4

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    The Manufacturing Process of

    Portland Cement

    Group members: No. Matriks

    1. TAN PEI YING A133043

    2. CHUA BOON YEN A133611

    3. YEU WEE CHEK A133533

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    1.

    RAWMATERIALS

    ACQUISITION

    2.

    RAWMATERIAL /KILN FEED

    PREPARATION

    3.PYROPROCESSI

    NG

    4.CEMENT

    GRINDING

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    Step 1: Raw Material Acquisition

    Highest concentration in portland cement

    Obtained from a variety of calcareous raw materialsCalcium

    Can significantly increase emissions of sulfur dioxide

    Found in deposits of limestone, clays, and shalesPockets of pyrite

    Forms of Calcium Sulfate

    Excavated from quarries or mines

    Gypsum/ NaturalAnhydrite

    Obtained from ores and minerals such as sand,shale, clay and iron ore

    Silicon,aluminium, iron

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    (left) obtain calcium from

    limestone (calcium

    carbonate)

    (right) pyrite, usually

    found in deposits oflimestone, clays and

    shales.

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    -Gypsum (or natural anhydrite) excavated

    from quarries or mines.

    -It will be added together with clinker inside grinding

    mill ( function to prevent flash setting of concrete)

    h l d

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    Step 2: The Raw Mix or Kiln Feed

    Preparation

    For Pyroprocess operation Variety of blending and sizing operations

    Wet and Dry process

    Raw materials are received

    with an initial moisturecontent varying from 1 tomore than 50 percent

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    Step 2: (I) Dry Process

    Moisture is reduced less than 1% before grinding

    Impact dryers, drum dryers, paddle-equipped rapid dryers, air

    separator, or autogenous mills

    During grinding in ball-and-tube mills or roller mills

    Thermal Energy for drying which is supplied by exhaust gassesfrom separate,direct fired coal, oil / gas burners

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    Material

    transportassociated withdry raw milling

    system

    Accomplished by a

    variety mechanismexp : screwconveyors, beltconveyors and drag

    conveyors

    Dry raw mix

    Pneumatically

    blended Stored in specially

    constructed silos

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    Wet Process

    Water is added to the rawmill, producing a pumpable

    slurry

    The slurry is agitated,blended

    Stored in various kinds andsizes of cylinder tanks or

    slurry basins

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    Step 3 : Pyroprocessing System

    Transforms the raw mix into clinkers

    The Chemical reations and physical processesthat constitute the transformation are quitecomplex

    Heart of manufacturing of cement

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    Chemical & Physical Processes

    Evaporation of water

    Evolution of combinedwater in the argillaceous

    components

    Calcination of thecalcium carbonate to

    calcium oxide

    Reaction of CaO withsilica to form dicalcium

    silicate

    Reaction of CaO withthe aluminium and iron-bearing constituents toform the liquid phase

    Formation of the clinkernodules

    Evaporation of volatileconstituents

    Reaction of Excess CaOwith dicalcium silicate toform tricalcium silicate

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    4 Stages

    Materials temperatures increased to 100C

    Evaporation of uncombined water from raw

    materials

    Materials temperature increases from 100C 430C to formoxides of silica, aluminium and iron

    Dehydration

    Carbon dioxide is evolved in the temperature of 900C to formCarbon Oxide in the temperature of 982C

    Calcination

    Occur in the burning zone of the rotary kiln

    Reaction of oxides ---T1510----> cement clinker

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    Rotary Kilns

    long cylinder rotating about its axis once

    every minute or two. The axis is inclined at aslight angle, the end with the burner beinglower.

    Mostcommonly

    used kiln fuels Coal, natural gas, and oil

    Used ofsupplementary

    fuels

    Waste solvents, scrap rubber, and petroleumcoke

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    Left: Cement Kiln That We Can

    Usually See Inside Laboratory.

    Right: High Efficiency

    Cement Kiln System InsideFactory. (where

    pyroprocessing can take

    place)

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    Five different

    processes toaccomplish thepyroprocessing

    step

    Wet process

    Long Dry process

    Semidry process Dry process with a

    preheater

    Dry Process with aprecalciner

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    Wet Process and Long Dry Process

    Occurs inrotary kiln

    rotary kiln are simple & shorter

    System ofChain

    Provided at the feed end of the kiln

    in the drying or preheat zones toimprove heat transfer from the hotgases to the solid materials

    KilnRotation

    Causes the hot chains to fall intothe cooler materials at the bottomof the kiln, then transfer the heatto the load

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    Dry Process Pyroprocessing System

    Preheater process

    Additional of one ormore cyclone-typepreheater vessels inthe gas streamexiting the rotary kiln

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    Hot exhaust gases from the rotary kiln pass countercurrently through the downward-moving raw materials in

    the preheater vessels.

    The hot gases are used as a source of heat for drying raw

    materials in the raw mill

    It is a production mechanics and pollution controldevices because the catch from the mechanicalcollectors, fabric filters, and electrostatic precipitators(ESP) will follow the raw mill returned to the process

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    Dry Process Pyroprocessing System

    Preheater / pre-cailciner process

    Additional thermal efficiency

    & productive gain is achievedby diverting some fuel to acailciner vessel at the base ofthe preheater tower

    Determined by the availability and source ofthe oxygen for combustion in the calciner

    Amountof the fuel

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    Preheater and Precalciner Kiln System

    Have analkali

    bypasssystem

    To remove the undesirablevolatile constituents(recirculate to the kiln)

    It can restrict process and gasflow

    The alkalicontent

    is limited

    Can cause deleteriousreactions in concrete

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    Semidry Process

    The water is added to the dry raw mix in apelletizer

    To form moist nodules or pellets

    Conveyed on a moving grate preheaterbefore being fed to the rotary kiln

    The pellets are dried and partially calcinedby hot kiln exhaust gases passing throughthe moving gate

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    Clinker Cooler

    Last component of the pyroprocessing system

    Recoups up to 30 percent of the heat input to the kiln system

    Locks in desirable product qualities by freezing mineralogy

    Makes it possible to handle the cooled clinker with conventionalconveying equipment

    It is cooled from about1100C to 93C (2000F to 200F) by ambient air

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    Commontypes

    Reciprocating grate

    Planetary Rotary

    Reciprocating

    grate cooler

    Lower clinker discharge temperature areachieved by passing an additional

    quantity of air through the clinker

    Additional air

    Cannot be utilized in the kiln for efficientcombustion

    Vented to the atmosphere Used for drying coal or raw materials or as

    combustion air source for precalciner

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    Clinker Storage

    Normally store 5-25% of its annual clinker productioncapacity

    Equipment used to transfer the clinker from coolers tostorage areas and to the finish mill are conveyors andbucket elevators

    Gravity drops and transfer points typically are vented todust collectors

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    Final Step: Finish Grinding Mill

    blending andgrinding

    operationsthat

    transformclinker tofinishedportlandcement

    Up to 5 percentgypsum ornaturalanhydrite isadded to theclinker during

    grinding To control the

    cementsetting time

    Other specialty

    chemicals areadded asneeded

    To impartspecificproductproperties

    Finish milling isaccomplished

    almostexclusively inball or tube

    mills.Typically,

    finishing isconducted in aclosed circuitsystem, with

    product sizingby air

    separation

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    `Grinding Mill

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    Packing and Loading

    Finished product is transferred usingbucket elevators and conveyors to large,

    storage silos on the shipping department

    The portland cement is transported in

    bulk by railway, truck, or barge, or in 43kg(94 pound) multiwalled paper bags

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    Packing & Despatch

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    Environmental Issues

    Air pollutants

    The combustion of fuel in rotary cementkilns generates nitrogen oxides from thenitrogen in the fuel or incomingcombustion air

    Sulfur dioxide is generated from thesulfur compounds in the ores

    Liquid andSolid wastes

    Overflow from slurry equipment

    Stripped overburden

    The combustion processes of cementkilns and rotary kilns have been used todispose of hazardous waste material

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    CONCLUSION:

    The manufacturing of Portland cementrequired a sequence of process.

    Roughly, we can convenient the process into 4

    main steps : raw material acquisition, rawmix/clink feed preparation, pyroprocessing, andgrinding mill.

    Comparing the wet process and dry process,dry process is more thermally efficient andsave cost.

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    THE END

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