18
Contrib Mineral Petrol (1983) 83 :99-116 Contributions to Mineralogy and Petrology 0 Springer-Verlag 1983 The Granite Problem as Exposed in the Southern Snake Range, Nevada D.E. Lee' and E.H. Christiansen2 US Geological Survey, MS 912, Box 25046, Denver Federal Center, Denver, Colorado 80225, USA Department of Geology, University of Iowa, Iowa City, Iowa 52242, USA Abstract. A geochemically and mineralogically diverse group neous aspect can form as products of different pro- of granitoids is present within an area of 900 km2 in the cesses . . . " Within an area of 900 km2 in the southern Snake southern Snake Range of eastern Nevada. The granitoids Range, White Pine County, Nevada, six igneous masses exposed range in age from Jurassic through Cretaceous to are well exposed in discrete outcrops. These granitoids Oligocene and include two calcic intrusions, two different range in age from Jurassic to Oligocene, in SiO, content types of two-mica granites, and aplites. The younger intru- from 63 to 76 wt.%, in 6'80 from -2.6 to + 13.2 permil, sions appear to have been emplaced at progressively more and in initial 87Sr/86Sr from 0.7071 to 0.7157. The petro- shallow depths. All of these granitoid types are represented logic types exposed include two calcic (Peacock 1931) intru- elsewhere in the eastern Great Basin, but the southern sions, two different kinds of two-mica granites, and aplites. Snake Range is distinguished by the grouping of all these The purpose of this report is to summarize and integrate types within a relatively small area. the information in some 30 papers on the petrology, age The Jurassic calcic pluton of the Snake Creek-Williams relations, and systematic mineralogy of these rocks, and Canyon area displays large and systematic chemical and to speculate on the processes that may have been involved mineralogical zonation over a horizontal distance of five in their formation. km. Although major element variations in the pluton com- We first describe a well-studied pluton from the south- pare closely with Daly's average andesite-dacite-rhyolite ern Snake Range using models of its trace element and over an SiO, range of 63 to 76 percent, trace element (Rb, isotopic composition to demonstrate the role of fractional Sr, Ba) variations show that the zonation is the result of crystallization in developing its strong compositional zona- in situ fractional crystallization, with the formation of rela- tion. We then compare it with other plutons from the area tively mafic cumulates on at least one wall of the magma and attempt to explain their origins from Sr and 0 isotope chamber. Models of trace element and isotopic data indi- relationships. cate that relatively little assimilation took place at the level In this report we refer to a classification of granites of crystallization. Nonetheless, an initial 87Sr/86Sr value according to source materials (Chappell and White 1974). of 0.7071 and dS80 values of 10.2 to 12.2 permil suggest In the scheme, granites inferred to be derived from predomi- a lower crustal magma that was contaminated by upper nantly sedimentary protoliths are S-types, whereas those crustal clastic sedimentary rocks before crystallization. The derived from igneous source materials are I-types. The involvement of mantle-derived magmas in its genesis is diffi- chemical, mineralogical, and isotopic criteria used to distin- cult to rule out. Two other Jurassic plutons show isotopic guish between S- and I-type granites have been summarized and chemical similarities to the Snake Creek-Williams Can- by Chappell and White (1974), O'Neil and Chappell (1977), yon pluton. Beckinsale (1979), and Furgeson et al. (1980). As is appar- Cretaceous granites from eastern Nevada that contain ent in the discussion to follow, application of these criteria phenocrystic muscovite are strongly peraluminous, and to a particular pluton sometimes leads to ambiguous results. have high initial Sr-isotope ratios and other features charac- The central part of the area studied is about 60 km teristic of S-type granitoids. They were probably derived southeast of Ely, Nevada, in the southern part of the Snake from Proterozoic metasediments and granite gneisses that Range of eastern Nevada (Fig. 1). The granitoid rocks of comprise the middle crust of this region. this area intruded part of a lower Paleozoic miogeosynclinal Another group of granitoids (including the Tertiary ap- sequence of predominantly quartzite and carbonate rocks; lites) show chemical, mineralogic, and isotopic characteris- they are exposed east of the Mississippian Antler orogenic tics intermediate between the first two groups and may have belt (Gilluly 1963, pp 139, 140) and just west of the Creta- been derived by contamination of magmas from the lower ceous Sevier orogenic belt (Armstrong 1968, p 436). None crust by the midcrustal metasediments. of these plutons has been deeply unroofed. With the possi- ble exception of the Osceola intrusion, probably none of these granitoid masses has been eroded to a depth of more Introduction than 300 m. All of the plutons to be described (Fig. 2) are exposed beneath the Snake Range decollement. Parts or Faure and Powell (1 972, p 43) stated: "the crux of the gran- ite problem is that it is possible that granitic rocks of ig- all of the area studied have been mapped by Drewes (1958), Misch and Hazzard (1962), Whitebread (1969), and Hose Offprint requests to: D.E. Lee and Blake (1976).

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Page 1: The Granite Problem as Exposed in the Southern Snake Range ...geology.byu.edu/.../christiansen_83_snakerange.pdf · these granitoid masses has been eroded to a depth of more Introduction

Contrib Mineral Petrol (1983) 83 :99-116 Contributions to Mineralogy and Petrology 0 Springer-Verlag 1983

The Granite Problem as Exposed in the Southern Snake Range, Nevada D.E. Lee' and E.H. Christiansen2

US Geological Survey, MS 912, Box 25046, Denver Federal Center, Denver, Colorado 80225, USA Department of Geology, University of Iowa, Iowa City, Iowa 52242, USA

Abstract. A geochemically and mineralogically diverse group neous aspect can form as products of different pro- of granitoids is present within an area of 900 km2 in the cesses . . . " Within an area of 900 km2 in the southern Snake southern Snake Range of eastern Nevada. The granitoids Range, White Pine County, Nevada, six igneous masses exposed range in age from Jurassic through Cretaceous to are well exposed in discrete outcrops. These granitoids Oligocene and include two calcic intrusions, two different range in age from Jurassic to Oligocene, in SiO, content types of two-mica granites, and aplites. The younger intru- from 63 to 76 wt.%, in 6 '80 from -2.6 to + 13.2 permil, sions appear to have been emplaced at progressively more and in initial 87Sr/86Sr from 0.7071 to 0.7157. The petro- shallow depths. All of these granitoid types are represented logic types exposed include two calcic (Peacock 1931) intru- elsewhere in the eastern Great Basin, but the southern sions, two different kinds of two-mica granites, and aplites. Snake Range is distinguished by the grouping of all these The purpose of this report is to summarize and integrate types within a relatively small area. the information in some 30 papers on the petrology, age

The Jurassic calcic pluton of the Snake Creek-Williams relations, and systematic mineralogy of these rocks, and Canyon area displays large and systematic chemical and to speculate on the processes that may have been involved mineralogical zonation over a horizontal distance of five in their formation. km. Although major element variations in the pluton com- We first describe a well-studied pluton from the south- pare closely with Daly's average andesite-dacite-rhyolite ern Snake Range using models of its trace element and over an SiO, range of 63 to 76 percent, trace element (Rb, isotopic composition to demonstrate the role of fractional Sr, Ba) variations show that the zonation is the result of crystallization in developing its strong compositional zona- in situ fractional crystallization, with the formation of rela- tion. We then compare it with other plutons from the area tively mafic cumulates on at least one wall of the magma and attempt to explain their origins from Sr and 0 isotope chamber. Models of trace element and isotopic data indi- relationships. cate that relatively little assimilation took place at the level In this report we refer to a classification of granites of crystallization. Nonetheless, an initial 87Sr/86Sr value according to source materials (Chappell and White 1974). of 0.7071 and d S 8 0 values of 10.2 to 12.2 permil suggest In the scheme, granites inferred to be derived from predomi- a lower crustal magma that was contaminated by upper nantly sedimentary protoliths are S-types, whereas those crustal clastic sedimentary rocks before crystallization. The derived from igneous source materials are I-types. The involvement of mantle-derived magmas in its genesis is diffi- chemical, mineralogical, and isotopic criteria used to distin- cult to rule out. Two other Jurassic plutons show isotopic guish between S- and I-type granites have been summarized and chemical similarities to the Snake Creek-Williams Can- by Chappell and White (1974), O'Neil and Chappell (1977), yon pluton. Beckinsale (1979), and Furgeson et al. (1980). As is appar-

Cretaceous granites from eastern Nevada that contain ent in the discussion to follow, application of these criteria phenocrystic muscovite are strongly peraluminous, and to a particular pluton sometimes leads to ambiguous results. have high initial Sr-isotope ratios and other features charac- The central part of the area studied is about 60 km teristic of S-type granitoids. They were probably derived southeast of Ely, Nevada, in the southern part of the Snake from Proterozoic metasediments and granite gneisses that Range of eastern Nevada (Fig. 1). The granitoid rocks of comprise the middle crust of this region. this area intruded part of a lower Paleozoic miogeosynclinal

Another group of granitoids (including the Tertiary ap- sequence of predominantly quartzite and carbonate rocks; lites) show chemical, mineralogic, and isotopic characteris- they are exposed east of the Mississippian Antler orogenic tics intermediate between the first two groups and may have belt (Gilluly 1963, pp 139, 140) and just west of the Creta- been derived by contamination of magmas from the lower ceous Sevier orogenic belt (Armstrong 1968, p 436). None crust by the midcrustal metasediments. of these plutons has been deeply unroofed. With the possi-

ble exception of the Osceola intrusion, probably none of these granitoid masses has been eroded to a depth of more

Introduction than 300 m. All of the plutons to be described (Fig. 2) are exposed beneath the Snake Range decollement. Parts or

Faure and Powell (1 972, p 43) stated: "the crux of the gran- ite problem is that it is possible that granitic rocks of ig- all of the area studied have been mapped by Drewes (1958),

Misch and Hazzard (1962), Whitebread (1969), and Hose Offprint requests to: D.E. Lee and Blake (1976).

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100

41020"

38040'

cordance and the most notable discordance are well shown Fig. 1 . Northeastern Nevada and northwestern Utah, showing lo- where the pluton crops out at the of the range between cations of various intrusions mentioned in this report. The Ruby Mountains are a few km west of the northern part of the map Snake Creek and At the northern edge area of this outcrop, beneath Pyramid Peak, the intrusive contact

nearly parallels the flat bedding of the overlying quartzite, but at the southern edge of this outcrop, the intrusive con-

Intrusive Types Exposed tact cuts across about 300 m of quartzite bedding at a very high angle.

Snake Creek- Williams Canyon Intrusion Locally, along steep contacts, the host rock has been dragged upward and appears to have been shouldered aside

Geology. The Middle Jurassic (155k4 m.y.; Lee et al. 1983) (Drewes 1958, p 231). This is apparent in the extreme east- pluton of the Snake Creek-Williams Canyon area is the ern part of the intrusive outcrop, where Pioche Shale and oldest igneous mass present in the southern Snake Range. Pole Canyon Limestone have been folded into an over- Within a horizontal distance of 5 km this well-exposed plu- turned syncline. However, just north of this shale outcrop, ton grades from a tonalite (63% SiO,) where the host rock an apophysis of the intrusion has engulfed part of the lime- is limestone to granite (76% SiO,) where the host rock stone. This, as well as the discordant intrusive rock-quart- is quartzite. (The IUGS classification is used throughout zite contact at the crest of the range, indicates that some this paper; Streckeisen 1973). When the large and systemat- stoping took place. ic variation in the petrology of the pluton (Fig. 3) was re- The eastern half of the intrusive outcrop in Snake Creek cognized, it became apparent that this intrusive mass is drainage contains many xenoliths-fragments of Pioche ideal for a study of igneous processes. The intrusive rock Shale that are partly assimilated. The smallest of these is is well exposed in contact with chemically distinct host the size and shape of a walnut; the largest crops out over rocks, and the chemical and mineralogical trends are devel- an area of about 9,000 m2. In several places where the larger oped over large enough distances to be defined with assur- xenoliths are about a foot long, they comprise as much ance, yet the distances are still small enough to allow de- as 5% of the intrusion. These xenoliths tend to be ellipsoidal tailed field study of the concentration gradients. and to stand out on weathered surfaces. Strikes tend to

The eroded roof of this granitoid body probably was parallel the nearest intrusive contact, and dips usually are not much higher than the present outcrop. Thus the intru- within 20" of vertical. From this we infer that at least this sion probably has not been unroofed to a depth of much part of the intrusive must have undergone magmatic flow

3g007'

38"50'.

115000' 113000'

I I I

TOANARANGE BOX ELDER COUNTY

@ T O O E E COlJNTY GRANITE

i I

ELK0 COUNTY -------- WHITE PINE COUNTY

I TOOELE COUNTY C - - - - -

I JUAB COUNTY

KERN MOUNTAINS (TuNGSTONIA) QI I

INTRUSION

- JUAB COUNTY

MILLARD COUNTY I

NOTCH PEAK 1 Hg--"EuR";"N"dE a

SOUTHERN SNAKE i RANGE INTRUSIONS (See Fig. 2) 8@S

Qq,-yb

I I I

0 50 KILOMETERS U

114O25' 114O05'

gEr;: %

177-MW-60

W~llard Creek 295DL-W Intrusion

a Pole Canyon-

Snake Creek-W~lliarns Kious Basin Area Canyon Area

Lexington Creek Intrusion

3% GR 48

0 10 KILOMETERS u Fig. 2. Map showing locations of granitoid rocks of the southern Snake Range, Nevada. Outlines of intrusions modified from the map of Hose and Blake (1976). Shaded area shows intrusion that has been sheared and brecciated by stresses resulting from late movement on the Snake Range decollement. Only selected sample locations are shown

more than 300 m. This intrusion is essentially domelike (Drewes 1958, p 231) and roughly concordant with bedding in the overlying sedimentary rocks. Both the general con-

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101

114O15

I

-

38955 - 0 4 KILOMETERS

I EXPLANATION E] Alluv1m } PuArrRNARY El Pole Canyon Llrnestone 3 CAMBRIAN

Glacial depos~ts Pioche Shale

m ] ~ r a n ~ t o i d rocks )JURASSIC (1 Prospect Mountam Quartzite 1 CAMBRIAN AND PRECAMBRIAN

Osceola Argillite of Misch PRECAMBRIAN and Hazzard O B Z i 1

Fig. 3. Simplified geologic map of the Snake Creek-W~lliams Canyon pluton Solid lines are CaO ~sopleths. Many sample locations omitted for the sake of s ~ m p l ~ c ~ t y , but locations are shown for all samples ment~oned In the text and/or Included In the papers on the oxygen or strontium lsotope compositions of these rocks

before sohd~fication. West of the 2.0% CaO isopleth, the Llrnestone. Isopleths based on analyses of more than 80 intrusion is almost devold of xenoliths. rocks show CaO values increasing from less than 1.0%

There is little evldence of contact metasomatism around where the lntruslon is in contact wlth quartzite on the crest the Intrusion exposed in the Snake Creek-Williams Canyon of the range to more than 4.0% where the eastern part area. It is not uncommon for the limestone to be gnarled of the Intrusion IS In contact wlth limestone and shale and deformed withln a few meters of the intrusive contact, (Fig. 3). In the extreme western part of the same continuous but there IS v~rtually no skarn. Contact action on the Pioche igneous outcrop, where the granitoid rock (samples 27, 28, Shale is no more Impressive. Wlthin a few feet of the ig- 42 and 59) is In contact wlth Osceola Argill~te, CaO again neous rock, the shale may be baked and recrystallized, but increases and IS locally 2.0% or more, whereas SiO, con- there IS no indication of metasomatism. The intrusion's ef- tents decllne to about 71%. However, because most of the fect on the Prospect Mountain Quartzite is difficult to study intrusion in this area is altered, no attempt was made to because the quartz~te-intrusive contact IS exposed only in contour CaO values there. Almost all samples contain nor- a few places owing to the tendency of the quartzite to form mative corundum, but only four of the 86 analyzed speci- talus over the intrusion. However, micropegmatitic apo- mens contaln more than two percent normative corundum. physes were observed along bedding and jointing In the By comparing other chemical variables with CaO, it can quartzite. North of the mouth of W~lliams Canyon on the be shown (Lee and Van Loenen 1971, Fig. 4) that major west slde of the range contact effects on the Osceola Argil- element variations in this igneous mass compare closely lite are more pronounced. In places the rock is changed with Daly's average andeslte-dacite-rhyolite (Barth 1962, to a spotted hornfels (Whltebread et al. 1962), but this p 164) over an SiO, range of 63-76OI0. Lee and Van Loenen metamorph~sm apparently was c so chemical In terms of hand (1971, p 29-31) give petrographic descriptions of five repre- specimen-sized samples. sentative samples with SiO, contents ranging 63.5-74.9%.

Chemical petrology. The sedimentary rocks exposed in in- Mzneralogy. Pure fractions of most or all of the minerals trusive contact with the granitoid rocks (Fig. 3) are the Pre- (except quartz) present in each of 20 rocks were recovered cambnan Osceola Argillite (of Misch and Hazzard 1962), for study. The results of analytical work on these mineral the Precambrian and Cambrian Prospect Mountain Quart- fractions are summarized in the following discussion; de- zite, and the Cambrian Pioche Shale and Pole Canyon tailed information is given in the cited papers on the individ-

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102

100 I I I I I I I I the mass (63% SiO,) contain 2 wt.% epidote, 1% sphene, I- z 0.5% magnetite, and well developed allanite, apatite, and

so - Quartz zircon. This is an I-type assemblage. As SiO, increases, the amounts and types of accessory minerals change gradu-

- ally, until the most felsic parts of the intrusion (76% SiO,) contain only ilmenite, garnet, monazite, and trace amounts of apatite and zircon, a S-type assemblage. The entire suite - of accessory minerals comprises only about 0.1 wt.% of the most felsic parts of the intrusive. About 90% of the

I rare earths present in the pluton are contained in the acces- sory minerals.

0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 WEIGHT PERCENT CaO IN ROCK Trace Elements and Isotopic Variations

Fig. 4. General relations between CaO content and mineralogy for granitoid rocks of the Snake Creek-Williams Canyon area. (From General. Since the large and systematic variation in the Lee and Van Loenen 1971, Fig. 11) chemical petrology of this intrusion was first recognized,

the essential question has turned on the relative importance of assimilation and fractional crystallization in the develop-

ual mineral species. The mineralogy of the Snake Creek- ment of the pluton. Inasmuch as the most mafic parts of Williams Canyon pluton is outlined in Fig. 4, which has the intrusion are in contact with shale and limestone, the much in common with similar diagrams in the literature most felsic parts with quartzite, and because the Ca-rich that illustrate the variations and relative proportions of accessory minerals (epidote, sphene, apatite, and allanite) minerals composing major rock types as they result from are strongly concentrated in the mafic parts of the intrusion, magmatic differentiation (See Pirsson 1947, p. 117). General Lee and Van Loenen (1971) were led to the conclusion relations between amounts of CaO and accessory minerals that assimilation played a dominant role. However, a recon- in these rocks are diagrammed by Lee and Van Loenen sideration of this conclusion is presented here on the basis (1971, Fig. 10). of trace element and isotopic data obtained since 1971.

The biotites crystallizing from the magma followed an iron enrichment trend, because oxygen fugacity decreased Fractional crystallization. Elemental variations of Rb, Sr, with temperature. These biotites indicate that the most and Ba (Lee and Doering 1974, 1980) are shown in Figs. 5- mafic parts of the pluton began to crystallize at a tempera- 7, on which we will base our discussion of the various mod- ture of 780" C and 10-13 atm fo2, and that the most felsic els for the crystallization and possible contamination of parts finally crystallized at a temperature of about 735" C the pluton. First we will outline the major role of fractional and about lo-'' atm fo2 (Lee and Van Loenen 1970). The crystallization, and then we will show that neither assimila- magnetite and/or ilmenite coexisting with these biotites in- tion nor restite control had much influence on the distribu- dicate lower temperatures and lower fugacities of oxygen, tion of these elements. probably due to differences in degree of subsolidus equili- Recent petrogenic studies of granitic rocks have shown bration of different mineral phases (Lee and Van Loenen the importance of cumulate and "mixed" cumulate-melt 1979). compositions in plutonic settings (e.g. McCarthy and Hasty

Amounts and compositions of the feldspars present in 1976; McCarthy and Groves 1979; Bateman and Chappell these rocks vary with rock chemistry much as one would 1979). Thus the trace element models described here show expect in a series of differentiates. Plagioclase feldspars the variation in the compositions of the evolving liquid range from andesine to oligoclase as bulk rock composi- and of the instantaneous solids crystallized from the melt. tions become more silicic. Alkali feldspar is either absent Assuming that Rb, Sr, and Ba all obey Henry's law, or interstitial in trace amounts along the eastern margin their concentrations in a melt (C,) that is evolving by frac- of the intrusion. The alkali feldspars are maximum micro- tional crystallization can be described by the Rayleigh equa- cline microperthites, indicating temperatures perhaps below tion: 400" C (Lee et al. 1980). As with the opaque oxides. lack C L = C o F ~ ~ - l ~ of agreement between this temperature and those deduced (a)

from study of the coexisting biotites is probably to be ex- where Co is the original concentration of an element in plained by differences in degree of subsolidus equilibration. the liquid, F is the fraction of liquid remaining, and D

Accessory minerals present respond to rock chemistry, is the bulk partition coefficient. Since indicating that their development was controlled by liquid 2 crystal equilibria. Thus amount, crystal habit, and com- D = Cs/CL (b)

position of both zircon (Lee et al. 1968) and apatite (Lee where C, is the concentration of an element in the instanta- et al. 1973) change gradually from the mafic to the felsic neous solid precipitating from the melt parts of the exposure. The amount and composition of both Cs = D C,F(~-') allanite and monazite (Lee and Bastron 1967) and the (c)

amounts of sphene (Lee et al. 1969), epidote (Lee et al. As noted by McCarthy and Groves (1979), where signifi- 1971), and the opaque oxides also vary with rock composi- cant changes in the liquidus mineral assemblage occur (and tion. hence changes in D), the compositional trend of the solid

The gradual and systematic change of accessory mineral is discontinuous; however, the evolving liquid composition types precipitated during crystallization is one of the most shows only an inflection in its trend. In order to model striking features of this pluton. The most mafic parts of the trace element variation of the pluton, a variety of initial

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103

2WO

16W

1200

d

8W

400

0 '

A

Group 1 (x) Ca0>2.5 percent

Group 2 (A) CaO 2.0-2.5 percent

Group 3 (01 CaO< 2.0 percent

- -

- -

-

- -

- -

I I I I I 0 1W 2W 300 4W

Rb 20W / I I I I

- 'Prospect Mountain Quartzite - - Ba-330 ppm - - Rb= 68 pprn

Parent liquid 12W -

Simple Assimilation-

- \+crystallization

. r . o l r : r=.20>.. --- ---- -

Limestone , I , I , ----__ - I I I I I I I

Oo ' 1W ' 2W 300 4W 0 1W m 300 4000 100 m 303 4W Rb Rb Rb

Fig. 5A-D. Rubidium-barium variation diagrams (in ppm) for the Snake Creek-Williams Canyon intrusion. (A) Model for fractional crystallization of the pluton, showing composition of solid and liquid. Intervals marked on curves show fraction of melt remaining and range from 1.0 to 0.2 for liquids and from 1.0 to 0.1 for solids. Details of the model are given in Table 2. The line representing mixing between a hypothetical restite composition and a minimum melt is also shown. ( E D ) Models showing the effects of simple mixing and of combined assimilation - fractional crystallization for different values of "r". The simple mixing lines are based on contaminants having the compositions of the respective country rocks. Numbers on the simple mixing lines indicate fractions of wall rocks mixed with the magma. Samples of the Snake Creek-Williams Canyon pluton, omitted from B-D for the sake of simplicity, would plot as on A

conditions (C,, D) were chosen and iteratively varied until from these groups, defined simply on the basis of CaO computer-generated trends most closely approximated concentration, are shown with different symbols on all of those of the observed trends. Even though these models the diagrams. Their spatial disposition in the pluton is are fairly sensitive to changes in C, or D, they remain shown in Fig. 3. If the chemical variation is the result of approximate. Any composition that falls within the solid- fractional crystallization, the sharp discontinuity in Ba con- liquid envelope can be explained by the model - keeping centration at about 100 ppm Rb must reflect the introduc- in mind that the rock compositions may be the product tion of a new cumulate phase with a high D,,, and also of solid-melt mixtures. Compositions that result from the implies that samples from Group 1 and 2 are essentially entrapment of residual liquid would theoretically lie on tie cumulate in their nature. Modal data (Table 5, Lee and lines joining points of equal F on the liquid and solid evolu- Van Loenen 1971) suggest that the precipitation of K-feld- tion curves. spar (D,, - 6, Crecraft et al. 1981) concides with this dis-

Three discrete groups of samples from the Snake Creek- continuity. Many samples from the eastern margin of the Williams Canyon pluton appear on the Rb-Ba diagram pluton lack K-feldspar and others contain only small (Fig. 5). Group 1 has the lowest Rb concentration, moder- amounts of interstitial K-feldspar that may have crystal- ate Ba, and CaO between 2.6 and 4.5 wt. %. Group 2 has lized from trapped liquid. The trace element variation can high Ba (> 1,400 ppm), moderate Rb, and CaO between be approximated by increasing D,, to 2 at F z 0 . 8 (Table 1). 2.0 and 2.5%. Group 3 trends toward lower Ba at higher The relatively sudden appearance of K-feldspar in the cu- Rb concentrations and has CaO less than 2.0%. Samples mulate mineral assemblage is indicated by the sharp demar-

- - Pioche Shale -

Ba.750 ppm - Rb.225 ppm -

16W

B Pole Canyon Limestone -

- Baa00 pprn -

Rb; 20 ppm

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Table 1. Summary of trace element models

Ba 1,150 0.9 2.0 Sr 400 2.0 2.0 Rb 145 0.5 0.5

Li 27-30 2.1 1.1 CS 2-3 0.3-0.4 0.3-0.4 Zn 32-38 1.9-2.2 1.2

C, = Initial concentration in melt D =Bulk distribution coefficient F =Fraction of liquid remaining

cation of the high-Ba group. Although reaching this impor- tant phase boundary greatly ,affects the modeled trend of the liquid (Fig. 5), it is not readily apparent in the composi- tion of the samples in Group 3 which must be most like the liquid. The inflection may be obscured by mixed cumu- late-melt compositions, and because most variation in liq- uid compositions occurs when F <0.8. If the initial concen- trations used are approximately correct, samples 23 and 28

(Fig. 3) may be like the original liquid that intruded into the-upper crust.

The Blue Tier batholith, Tasmania, and the Loch Doon intrusion, Scotland, both show analogous Rb- Ba relations that can be interpreted as the result of the introduction of K-feldspar as a cumulus phase (McCarthy and Groves 1979; Tindle and Pearce 1981).

The Ba - Sr variation diagram (Fig. 6) shows groupings similar to those on the Rb- Ba projection. The variation can be approximated by a model that holds I),, constant at 2 and varies I),, from 0.9 to 2.0 at F=0.80. Again the appearance of K-feldspar and the consequent increase in D,, seems to have occurred over a short interval of crystalli- zation. The almost linear correlation of Ba and Sr in group 3 samples shows that D,,I.I),,; on this plot, samples with a pure liquid composition are indistinguishable from pure cumulates if formed at F 50.5. Apparently the observed de- crease in the proportions of plagioclase and epidote in the cumulates is approximately balanced by the increase in al- kali feldspar as no marked changes in I),, appear to be necessary to explain the observed trace element variation.

The Rb- Sr variation diagram (Fig. 7) does not show the pronounced groupings of the other two diagrams, pre- sumably because I),, and I),, remained fairly constant

Group 1 i x l Ca0>2.5 percent Group 2 (A) CaO 2.0-2.5 percent Group 3 (0) CaOc2.0 percent

X X X

IT" x x x

xX

I / X , x Sotid

/' /

/ /

/ " " 0 x Parent n lio~rid

Limestone Sr:lW ppm Quartzite Ba:750 ppm Sr=18 pprn

Ba= 300 ppm 80.330 ppm

Assimilation- 400 crystallization , Parent liquid - - -J - - -1 - ; Parent liquid crystallization

Parent liquid

m .OI

Be

Fig. 6A-D. Barium-strontium variation diagrams (in ppm) for the Snake Creek-Williams Canyon intrusion (Lee and Doering 1974, 1980). Explanations as for Fig. 5A-D. For clarity the liquid evolution curve is displaced upwards

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105

BW

WO

d5

4W

2W

Prospect Mountain

Simple Sr=1800 ppm Sr=lW ppm Rb=m pprn

mixing Rb= 20 ppm Sr=18 ppm

6i Assimilation fractional Assimilation- Fig. 7A-D. Rubidium-strontium variation

2W diagrams (in ppm) for the Snake Creek- Williams Canyon intrusion (Lee and Doering

O O im 2w m wo IW 2w 3w wo iw zw 3w 4~ 1980). Explanation as for Fig. 5A-D

Rb Rb Rb

throughout the crystallization sequence. The most promi- istries were sampled over a range of F from 1.0 to 0.25. nent feature of the diagram is the width of the variation Group 1 samples appear to be solids (with some trapped trend that results from the large difference between D,, liquid) formed between F = 1.0 to 0.8, when alkali feldspar (2) and D,, (0.5). The relative amounts of melt and cumu- was not a significant crystallizing phase. Group 2 appears late in each sample could be estimated from their positions to have formed when F was between 0.8 and 0.75, and on tie lines connecting points at equal F on the solid and there was cumulus alkali feldspar. Although dominated by liquid evolution curves. cumulate compositions, the scatter along a trend toward

The variations in our unpublished values for Li, Cs, liquids formed at the same F suggests that some samples and Zn can be modeled by means of the same method of this group contain as little as 50 percent cumulus materi- used for the Rb, Sr, and Ba data just discussed. Although al. Group 3 is a diverse assemblage with both melt and there is more scatter in the Li, Cs, and Zn variation dia- cumulate chemistries. It contains samples similar to every- grams, D's and initial concentrations can be estimated (Ta- thing from the original liquid ( F = 1.0) to the most evolved ble 1). Li and Zn are most enriched in Group 1 samples liquid (F-0.25). However, most samples of this group ap- (30-50 and 50-60 ppm, respectively), and their concentra- pear to contain a significant cumulate component, judging tions appear to decrease throughout the evolution of the from their displacement toward the cumulate trend in both liquid. Biotite and plagioclase are probably the most impor- the Rb- Sr and Rb- Ba diagrams. tant concentrators of Zn (Crecraft et al. 1981) and Li. Al- The evolving nature of the cumulus minerals is indicated though Cs is also concentrated in biotite relative to other by the modal data (Fig. 4). On the other hand the analysis minerals, it nonetheless collects during the evolution of the to follow assumes that the relative amounts of cumulus liquid and is found in concentrations as high as 6-7 ppm minerals remained constant over major periods of crystalli- in Group 3 samples. zation, and thus only gross averages of the mineral propor-

Neither U nor Th values lend themselves to simple mo- tions can be calculated from the trace element data. Using deling due to marked scatter. The concentrations of both the D's determined from the modeling of the latter portion of these elements generally increase from Groups 1 to 3. of the differentiation and mineral D's from Hanson (1978), Total variation, including the cumulates, is about 1-3 ppm equations of the form for U and 10-20 ppm for Th. The pronounced scatter is probably due to post-magmatic processes and to variations Di = Dq(X,) + @(Xp) + . . . in the concentrations of U- and/or Th-rich accessory miner- als (allanite, monazite, and zircon). Relatively high (4 to where a and /? are mineral phases, and X, and Xp are their 7) Th/U ratios are found in samples from Groups 1 and weight fractions, can be defined. For Sr, Ba, and Rb the 2, and, if magmatic, indicate that a decrease in the Th/U only important mineral phases are biotite and alkali and ratio of a melt is likely if it evolves by fractional crystalliza- plagioclase feldspar. Epidote is important to the Sr budget tion. of the mafic minerals, but its contribution to the bulk parti-

If these trace element models are correct, they imply tion coefficient is small and is ignored here, based on that samples with melt, cumulate, and melt/cumulate chem- D2-5 (Lee et al. 1971), and the fact that it comprises

I I I A

X

x Group 1 Ixl CaOr2.5 percent - Group 2 W CaO 2.0-2.5 percent

Group 3 (01 CaOc 2.0 percent

- 1 -

1

-

0

OO I 1 I 1W 2W 3W 4W

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106

1 .o

0.8

0.6

XpL

Table 2. Compositional variety in the Snake Creek-Williams Can- yon pluton"

Sample no. 1 23 48 84

SiO, 76.9 74.7 71.1 63.0 TiO, 0.08 0.21 0.39 0.78 A1,O, 13.6 13.8 15.1 18.2

0.59 1.8 2.5 5.4 MnO 0.02 0.06 0.06 0.05 MgO 0.17 0.39 1.2 2.1 CaO 0.48 1.8 2.4 4.4

-

-

I I

0 0.2 0.4 0.6 0.8 1

,I

I I I I - I I I I I I I

- I I I 1

K, I

Na20 3.7 3.4 3.7 3.8 K2O 4.5 3.7 3.3 2.3 PzO, 0.01 0.06 0.12 0.22

Total 100 100 100 100

1 =Evolved sample from Group 3 23 =Similar to parent liquid composition 48 =Sample from Group 2

.O 84 =Sample from Group 1

1 1 I I I I minus Rb; represents simultaneous

I solution of equations le) and ( f ) I I I - I I I I I I I - I I I I

XAF " From Lee and Van Loenen (1971, Table 5), recalculated volatile Fig. 8. Plot of weight fraction of alkali feldspar (X,,) versus weight - free to 100 percent, with total Fe as Fe20, fraction of plagioclase (X,,). The lines represent approximate solu- tion of equations d, e, and f, and their intersection gives the approx- imate proportion of these minerals in the fractionating mineral X,cc,s,o,I,,= 0.3 to 0.4. Again this solution is in reasonable assemblage. The equations assume that D's and proportions of the individual minerals remained constant. In the model described agreement with the of Group earlier, X,, = O until F <0.80 which appear to be early cumulates.

Composition of Original Liquid

a maximum of 2 wt.% of some samples. Thus three equa- The initial composition of the liquid used in the trace ele- tions of this type can be generated: ment models is shown in Table 1. If this composition is

b,, = 2 = 3.9(XAF) + 4.4(XPL) + 0.12(XBIOT) used as a criterion the initial liquid appears to have had (d) a CaO content of 1.8 to 2.0 wt.%. Inflections or discontinu-

bB,= 2 = 6.1 (XAF) + 0.3 (XPL) S 6.4(XBIoT) ities in several chemical (K20, Na20, P20, , Ba) and miner- bR, = 0.5 = 0.6(xAF) +0.04(XpL) + 3.3(xBIoT) (f) alogic (modal quartz and microcline) parameters occur at

where X,,, X,,, and XBloT are the weight fractions of alkali this point (Lee and Van Loenen 1971). These

feldspar, plag,oclase, and biotite. The individual mineral lend credence to the suggestion (Cain 1974) that the initial

D's have large uncertainties associated with them, further magma was tdicic. Thus sample 23 Lee and Van

complicating the exact solution of the equations. This prob- Loenen (I97l) appears be most like the parent liquid

lem can be visualized graphically. If the last in equa- of the intrusion. Its composition is shown in Table 2 and

tion (d) is allowed to go to zero, the equation can be repre- is compared with the com~ositions of from

sented as shown in Fig. 8, which plots the weight fraction and and with One of the most rocks

of plagioclase versus that of alkali feldspar. ~ h ~ ~ , if no in the intrusion. This comparison clearly shows the dangers

alkali feldspar were crystallizing from the melt, XpL - 0.45. of assuming that individual samples from granitic ~ l u t o n s

However, even moderate changes in D;; allow XpL are compositionally similar to the liquids from which they

to range from 0.4 to 0,5. such in D;; could occur crystallized. These considerations also show that it is totally over the course of crystallization and are certainly within to the plutonic as the range of measured D;; in various sil,cic rocks. Simulta- liquids, especially if the sample suite is small. The major

neous solutions of equations (e) and (0 with the element variations in this cumulate-dominated intrusion are

of the XBloT term produces another equation that can be similar to those in the classic andesite-dacite-rhyolite series,

plotted in this projection. Intersection of these curves yields but appear to have been produced by crystallization from

an area of approximate solution to the equations for the a liquid with greater than about 73% SiO,.

latter stages of crystallization ---XpL = 0.22 - (0.26) - 0.34, X,, = 0.16 - (0.20)- 0.24 (preferred solutions in parenthe- Restite Control

ses). From equations (d) and (f) X,loT-O.ll, and by differ- White and Chappell (1977) suggested that the geochemical ence XqUA,,, + XAcc,s,o,l,, - 0.40. This result is in agree- variation observed in some plutons results from the unmix- ment wlth the model data (Fig. 4) for samples with 2.0 ing of refractory phases residual from a partial melting to 2.5% CaO (Group 2), which appear to be cumulates event (restite) and a liquid. Simple mixing curves represent- formed while alkali feldspar was crystallizing. ing this process connect refractory marginal compositions

Estimates of the composition of the cumulate assem- of the pluton with a high-SiO, phase (representative of what blage from the early sequence can be obtained by setting could be a minimum melt) in Figs. 5-7. Strong deviations X,, = 0. In this case XpL = 0.4- (0.45) -0.5, XB,,,= 0.1 I to of the data away from these curves show that " restite" 0.20 (depending critically on DF:'), and XQuART,+ separation was not the dominant factor in the geochemical

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107

evolution of the Snake Creek-Williams Canyon pluton. 20 - o .

However, solid-liquid mixing was an important process as 19

the incomplete separation of liquids from crystallizing so- 18

lids appears to have been important.

Assimilation

- . ExPLANAnoN o Wall Rock

8 - - - f~ Intrusion o -

0

cn- ' 17-- E? x Xenolith ru 'R

16-g 9 1 - i - -

P d 1 5 - 9 - 8 8 8 - -

The composition (Ba, Rb, Sr) of the parent liquid was used 13 - - in an attempt to place limits on the amount and type of 12- , . . . . 0

- assimilation of country rock that may have occurred. De- . . . e O . . 1 1 - Paolo (1981) derived equations that describe the trace ele- 10 ment and isotopic evolution of liquids affected by simulta- neous assimilation and fractional crystallization in terms

. 0 0 . * ' .. . .- -

- 0 X *. - - LSNAKE CREEK-WILLIAMS CANYON INTRUSION ---I

of the parameter r, which is the ratio of the mass assimila- NORTHWEST SOUTHEAST

tion rate to the mass crystallization rate. Figs. 5-7 show Fig. 9. The oxygen isotope composition of the Snake Creek-Wil- the results of these calculations for both simple mixing and liams Canyon intrusion and its wall rocks projected to a NW-

combined assimilation-fractional crystallization, The liquid trending line that bisects the intrusion. The low- "0 eastern mar- and three compositions representative of the sedimentary gin of the pluton is adjacent to high- ''0 carbonates, suggesting section at the level of the intrusion were employed in the that simple mixing of wallrock and magma is not responsible for

the isotope variation of the pluton. This representation is highly calculations. Major and trace element analyses of these sedi- diagrammatic; only the relative positions of the samples are main- merits were presented by Lee and Van Loenen (197l) and tained, and no consistent horizontal scale is implied Lee and Doering (1974, 1980).

In the Rb- Ba diagram it is apparent that simple assimi- lation any the rocks the tion in 6180 (10.2-12.2 permil) accompanies the chemical spectrum of compositions observed. It is especially difficult to explain Group 2 by simple assimilation. However, if frac- and mineralogical trends described for this pluton. The Ca-

rich eastern margin of the intrusion is depleted in 180, and tional crystallization occurred simultaneously with assimila- the more evolved western portion is enriched in 1 8 0 tion the trace element trends are not markedly different (Fig. 9). As noted by Lee et al. (1982), the isotopic trends from those produced solely by fractional crystallization. are inconsistent with simple wall rock of The scatter of the data is such that it would be difficult the magma at the level of exposure, for high-61~0 carbon- to rule out assimilation rates that yield values of r 50 .2 . ates are the wall rocks along the eastern margin where the The effects of assimilation on the Ba-Sr evolution of intrusion has the lowest values of 6 ~ 8 0 . the pluton are analogous to those in Rb - Ba space. Consid- ered in isolation from the other trends, simple assimilation The rubidium and strontium isotope systematics also

of - 10% of the Pole Canyon Limestone could explain the tend to rule out substantial contamination of the magma

composition of Group 1 samples, but this mechanism does during fractional crystallization (e.g. Taylor 1980). Equa-

not explain the Rb - Ba variation. The amount of assimila- tions for quantifying these effects were presented by De

tion during fractional crystallization is not easily limited. Paolo (1981), and results of such calculations for the Snake

However, in the case of limestone assimilation, r50.05 to Creek-Williams Canyon intrusion are shown in Fig. 10. The assimilant was assumed to be similar to the Osceola Argil- eliminate "buffering" the Sr content of the melt to lite and the Prospect which are in- noticeably higher levels than are observed. truded by the western part of the pluton. The calculated The trend of the limestone mixing curves in the Sr- Rb curves show that large vanations of 87srj8Lsr accompany diagram is inconsistent with simple mixing to produce the

Group 1 samples. Assimilation of even 8 percent of the Pole modest changes in 6180. If the 0 isotope variation is con-

Canyon Limestone would raise the CaO content of the con- sidered to be caused solely by contamination, 30 to 50%

taminated melt to the amount observed in the marginal of the crystallized mass must have been assimilated. This would dramatically alter the Rb-Sr systematics of the in- portions of the pluton but would not provide sufficient trusion, producing ..ages.. of 30 to 40 m.y, at the time of strontium to explain the strontium abundance in the crystallization, along with slightly curved pseudoisochrons. Group 1 samples. However, assimilation during fractional

crystallization can only be limited to r's of less than 0.2. The isochronous nature of the Rb - Sr system of the intru- sion (Lee et al. 1983, Fig. 3), and its agreement with other Thus it appears that contamination did not play isotopic ages (zircon U -Th- Pb, Lee et al, 1968, and Lee an in producing the observed trace (Rb$ et al. 1981 ; hornblende K-Ar, Lee et al. 1970) apparently Sr, Ba) element variation in the Snake Creek-Williams Can- limit r to values of less than 0.05. Nevertheless, three sam-

yon intrusion. These observations do not rule out bulk con- ples from the extreme western margin of the exposure fall tamination and rehomogenization the magma before above the Rb- Sr isochron and appear to have been conta- crystallization commenced at the level of exposure. More- minated by the Osceola Argillite The 6180 vanation is over, it is difficult to rule out assimilation if it occurred limited to less than 1.0 permil by this value (0.05) of r during fractional crystallization. Possible values for the pa-

(Fig. for the values of cited earlier. results imply rame'er range 0'05 lor the "Ie Limestone that fractional crystallization of the intrusion may have pro- to 0.2 for the Pioche Shale or the Prospect Mountain Quart- duced much of the 'so variation. The fractions- zite. tion of oxygen isotopes follows a Rayleigh distillation law

A consideration of the isotopic variation across the plu- of the form ton provides a more rigorous test of the relative importance of assimilation and fractional crystallization. A large varia- R, = R,F("- ') (a)

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108

12

~ ~ - I I I I I I I I I I I I I

- -

- - r.0.50

Fz0.5 I-------'

GROUP 1 SAMPLES

-

r.0.05 - INITIAL

- MAGMA

- ASSUMED - 1 ' l ' l l " l " l g l l l ~

9 ' 1 I I I I I I I I 1 - l l l l l l ! l l l l l l ! l

0.706 0.708 0.710 0.712 0.714 0.716 0.718 0.720 GROUP 3 SAMPLES

8 7 ~ r / 8 6 ~ r

Fig. 10. S1'O and "Sr/"Sr shifts calculated for the case of com- 50- bined assimilation - fractional crystallization. The initial magma z was assumed to have 6180=10, 87Sr/86Sr=0.707, 400 ppm of Sr, and 150 ppm of Rb. The contaminant was assumed to be similar Y to a composite of the Pioche Shale and the Prospect Mountain 5 lo: -

~ - - O - - c - - - - - - , . - -0 - Quartzite, with 6180=13, 87Sr/s6Sr=0.750, 40ppm of Sr, and 5: - 225 ppm of Rb. I),, was assumed to be 2, I), was assumed to 3 be 1, and 0 concentrations were taken to be equal in the contami- nant and in the initial magma. The rapid change of 87Sr/86Sr with small changes in dl'O indicate that only small amounts of assimila- k d e i r d d ' ~ r k E : d d A d y A o ; r T m ' l b ~ u tion occurred during fractional crystallization. The tick marks indi- cate values of F. On the curve = 0.5, these tick marks Fig. 12. Chondrite-normalized REE patterns for rocks from the

are labeled, but most of the labels have been omitted from the Snake Creek-Williams Canyon intrusion. (A) c roup 1 samples,

other mixing curves for the sake of simplicity (B) Group 3 samples. Sample numbers are indicated

14 I I I I I I I I are shown in Fig. 11. A value of 11.0 permil was chosen

13

- - \ -\, -

\

for the initial dl'O of the liquid. This choice implies a-0.999 to produce the "0-depleted cumulates but seems reasonable based on the nature of the biotite-, magnetite-,

- epidote-, sphene-rich eastern margin and the 6180 values measured for these minerals (Lee et al. 1982). -

In the case where a = 0.999, dl'O of the cumulate varies from - 10 to 12.5 as the liquid varies from 11 to 13.5 per- mil. The curves clearly show that for a=0.999 the entire dl'O variation could occur in the cumulates with F ranging - from 1 to 0.1. But if, as shown earlier, the intrusion contains

10 - samples of "liquids" and "cumulates", the entire 6180

- range could be produced over the apparent range of F (1 to 0.25) derived from the trace element models.

8 - I I 1 I I I I I 0.1 0.3 0.5 0.7 0.9

In the case where a=0.999 only small changes in 6180 F occur and cumulates and liquids are only slightly different

Fig. 11. Plot of S1'O versus F (the fraction of liquid remaining in composition. Apparently a was closer to 0.999. in a crystallizing magma), showing the progressive change of dLsO for a=0.999 and u=0.9999. Curves for the liquid and instananeous cumulates are shown. The initial magma (F= 1) was assumed to Rare Earth Elements have a 6180 of 11

The rate earth element (REE) patterns for six samples (Cain 1974) from the pluton are shown in Fig. 12. Although some systematic variation of the patterns correlate with rock

where R, is the 180/160 ratio (B1'O+ 1,000) of the original chemistry, it is difficult to model the REE evolution of liquid, R, is this ratio in the evolving liquid, and a is the the crystallizing pluton. This is especially true because of fractionation factor (R,,,,,,/R,,,,,,). It follows that R of the high proportion of REE-rich accessory minerals in the the cumulates (R,) can be calculated from cumulate portions of the pluton; apatite, allanite, sphene,

and epidote constitute more than 3 wt.% of some rocks. R,= aR,F("-'I (b) Sphene contains a significant proportion (> 50%; Cain At magmatic temperatures a probably varies from 20.999 1974) of the total REE content of these samples. The rapid to 50.9999. Both values for a were used and the results change in the modal amounts of these accessories (Fig. 4;

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Lee and Van Loenen 1971, Fig. 10) and their high but gen- erally unknown partition coefficients for REE's make quan- titative interpretations difficult with this small set of sam- ples. All of the samples analyzed except number 15 appear to be cumulates, based on their Rb - Sr - Ba relationships.

Nonetheless, some inferences can be drawn from the variations in the REE patterns. From its position on the R b - Sr - Ba diagrams, sample 15 appears to be the closest (of those analyzed for REE) to the original composition of the parent liquid. The presence of a negative Eu anomaly suggests but does not demand equilibration with a feldspar- bearing or Eu-depleted source, indicative of an origin within the crust. Even though sample 6 also has a negative Eu anomaly, its position on the Rb - Ba - Sr diagrams suggests that it is a cumulate, albeit from a relatively evolved liquid. Sample 22, also a Group 3 cumulate, has a slight positive Eu anomaly, consistent with its cumulate nature. Sam- ples 66,78, and 86 all are Group 1 samples, early cumulates. Comparison of their patterns with that of sample 15 shows that the early cumulates were probably LREE-enriched and HREE-depleted compared to the magma from which they crystallized. Thus the evolving liquid must have become LREE-depleted and HREE-enriched. Sample 6, though it- self a cumulate, shows signs of having crystallized from such a melt. This type of REE variation is considered by some to be diagnostic of liquid-state differentiation (Hil- dreth 1979, and others), but it is seen here to be a natural consequence of crystal fractionation and the formation of cumulates along the margins of a pluton. The mineralogy of Group 1 samples is clearly consistent with this interpreta- tion, for these samples contain large amounts of the strongly LREE-enriched phases allanite (Lee and Bastron 1967) and epidote (Stuckless and Miesch 1981).

The REE pattern of sample 22 shows that by the time it crystallized the melt had been substantially depleted in LREE, or that the concentrations of LREE-rich phases in the cumulate had decreased. Both factors were probably important as a result of the liquid evolution described above and the disappearance of modal sphene and allanite and greatly reduced amounts of epidote (Fig. 4 ; Lee and Van Loenen 1971, Fig. 10). Sample 6 crystallized from a relative- ly evolved liquid after monazite had begun to crystallize from the magma and hence it may have elevated REE con- centrations because of the extremely high concentrations of REE in this phase (Lee and Bastron 1967).

In summary the trace element and isotopic data suggest that while there may have been bulk contamination and rehomogenization of the magma a t depth, there was little contamination during crystallization. This is apparent from the amounts of Rb, Sr, and Ba present in various parts of the pluton, and especially from the oxygen and strontium isotopic variations across the pluton. From a modeling of these parameters on variation diagrams it is clear that frac- tional crystallization played a major role, and that neither assimilation nor restite control had much effect on the trace element (Rb, Sr, Ba) distribution or on the oxygen and strontium isotope variations observed. However, it is diffi- cult to rule out assimilation completely if it occurred during fractional crystallization. The value of the parameter r may have been as large as 0.05 for the assimilation of sedimenta- ry rocks a t the level of exposure. In spite of relatively high 6180-values (> 10 permil), the mineralogy and chemistry of the pluton indicate that it was not derived solely from a metasedirnentary protolith.

Osceola Intrusion

The area of intrusive rock referred to as the Osceola stock by Armstrong (1966) is shown in Fig. 2. Preliminary study indicates that this granitoid rock is similar to the Snake Creek-Williams Canyon intrusion described above. Both plutons become more felsic from east to west. The Osceola stock has dl'O values (9.6-9.9 permil) somewhat lower than those (10.2-12.2 permil) determined for the Snake Creek-Williams Canyon intrusion (Lee et al. 1982), but ru- bidium-strontium isotopic results for the two plutons are very similar (Lee, Kistler and Robinson 1983). Data for the Osceola stock give an age of 145 m.y. with an initial 87Sr/86Sr ratio of about 0.7075. The results of U-Pb age work on zircon recovered from sample 177-MW-60 (Fig. 2) are complex but show signs of an inherited component and only an approximate age of 160-1 70 m.y. (Lee, Stacey and Fischer 1983).

Willard Creek Intrusion

The Willard Creek intrusion is one of the equigranular two- mica granites of northeastern Nevada discussed by Lee et al. (1981), who regarded it as a felsic phase of the Osceola intrusion (Fig. 2) just described. However, recent rubidium- strontium results for sample 295-DL-64 (Lee, Kistler and Robinson 1983) suggest that the Willard Creek mass may not be comagmatic with either the Osceola intrusion or the Snake Creek-Williams Canyon pluton, even though all three are Middle Jurassic in age. Muscovite recovered from sample 295-DL-64 gave a K-Ar age of 151 f 4 m.y. (Lee et al. 1970, Table I), very similar to the Rb-Sr ages deter- mined for the Osceola intrusion (- 145 m.y.) and the Snake Creek - Williams Canyon intrusion (1 55 + 4 m.y.). Sample 295-DL-64 gave an initial 87Sr/86Sr ratio of 0.7086 (f0.0002) for the Willard Creek mass at an age of 151 m.y. While this value is somewhat higher than the initial ratios determined for the plutons of the Osceola and Snake Creek- Williams Canyon areas, it is appreciably lower than the values (0.7111 to 0.7250) determined for four other two- mica granites in northeastern Nevada. This would indicate that the Willard Creek pluton was generated from less ra- diogenic source materials than the other two-mica granites in the area. On the other hand the S1'O value of sample 295-DL-64 was found to be 13.2 permil (Lee et al. 1981), and such a high value suggests that sedimentary materials were an important component in the generation of this two- mica granite.

In addition to its relatively low initial 87Sr/86Sr value of 0.7086, the Willard Creek mass differs from most other two-mica granites of northeastern Nevada in that it con- tains primary magnetite, usually regarded as characteristic of an I-type granite. Nonetheless, biotite from a single sam- ple has more than 3 AIToT ions per 22 anions (Lee et al. 1981), similar to those from strongly peraluminous granites from northeastern Nevada and elsewhere.

Pole Canyon-Cun Young Canyon Intrusion

The igneous mass exposed in the Pole Canyon-Can Young Canyon area is roughly elliptical in outline and domal in form. This intrusion consists of two phases that are sube- qua1 in outcrop area - a "host" intrusion and late aplitic and pegmatitic dikes as much as six feet wide. Where these

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110

I l l l l l l l l l i l t I I als present in these rocks are monazite, an allanite-like min- - eral, and equant apatite containing many tiny inclusions

- - of acicular zircon. - - - The d i 8 0 values for nine samples of this two-mica gran- -

K - - ite range from 10.6 to 12.1 permil and the minerals recov- z - -

ered from one of these samples appear to be in isotopic - equilibrium (Lee et al. 1982). Rubidium-strontium data for

- - - four whole-rock samples showed a scatter not unusual for - - muscovite granites. The 87Rb/86Sr and 87Sr/86Sr values for - - - - the whole rocks were therefore averaged to 1.44 and - - 0.71736, respectively. A regression (York 1969) of this value

for the whole-rock specimens, and data for a muscovite, A de A i d I dm 2" d d d y A :r Tm A :U - a microcline and a aplite-pegmatite gave an initial 87Sr/86Sr Fig. 13. Chondrite-normalized REE patterns for a samples from ratio of 0.71574$-0.0003 at an age of 79.1 f 0.5 m.y. (Lee, the Pole Canyon-Can Young Canyon intrusion (Cain 1974) and Kistler and Robinson 1983). from a two-mica granite of Cretaceous age from the Ruby Moun- The data summarized suggest that the muscovite-phen- tains, Nevada (Kistler et al. 1981) ocrystic two-mica granite of the Pole Canyon-Can Young

Canyon area is an S-type granite, derived from a metasedi- mentary protolith. Although this granite is unique among

dikes occur in swarms they all but obliterate any vestige the igneous types present in the southern Snake Range, of the host intrusion. The mineralogy of these aplites and its counterpart, the Tungstonia Granite of Best et al. (1974) pegmatites is simple. Except for quartz, muscovite, and al- is exposed in the Kern Mountains, about 83 km to the kali feldspars, garnet is virtually the only mineral seen in north, and a similar though not identical muscovite-phenoc- the field. Fluorite is a common but minor accessory miner- rystic granite is present in the Toana Range, about 225 km al. In addition, careful mineral separation work on a few to the north. Lee et al. (1981) concluded that all three of aplites has revealed the presence of exceedingly minute these muscovite-phenocrystic two-mica plutons resulted amounts of gahnite, columbite-tantalite, and two unidenti- from anatexis of Precambrian metasediments under condi- fied minerals. A few beryl crystals as much as one cm across tions of relatively low oxygen fugacity, and Lee, Stacey and appear to be confined to a single aplite. Fischer (1983) found that this anatexis probably took place

The host intrusion of the Pole Canyon-Can Young Can- during the Late Cretaceous, with an indicated source rock yon area is an unusual muscovite-phenocrystic (Lee et al. age of 1,970f 330 m.y. Such an origin would be consistent 1981) two-mica granite to granodiorite that was described with the locations and strongly S-type nature of these very in detail by Lee and Van Loenen (1971, pp 5, 38, 39). This unusual rocks. rock is distinguished in part by the presence of muscovite phenocrysts as large as two cm across, which contain small inclusions of euhedral biotite. It is not uncommon to find Lexington Creek Intrusion

as many as 20 biotite crystals included within a single large The map of Whitebread (1969) shows the Lexington Creek grain of muscovite. Petrographically, muscovite and biotite, intrusion truncated by a thrust fault; Lee et al. (1980) sug- both of which are very fresh looking, are seen to be asso- gest that the foliation noted by Whitebread and by Drewes ciated and often intergrown. They appear to have formed (1958) may have resulted from movement on the thrust in equilibrium. The muscovite contains no opaque inclu- before the pluton was completely crystallized. The original sions, nor does it present any other evidence that it is sec- mineralogy of this pluton has been somewhat obscured by ondary after biotite. Indeed the rocks are devoid of magne- deuteric alteration that may have accompanied develop- tite and ilmenite, these minerals being undetected not only ment of the foliation. However, it is apparent that the unal- in thin section but also during systematic mineral separation tered intrusion was a two-mica granite in which the biotite work. and muscovite were present as discrete crystals. Thus its

Chemical and modal analyses and norms of nine sam- texture contrasts with that of the Pole Canyon-Can Young ples of this muscovite-phenocrystic two-mica granite are Canyon pluton, which has biotite euhedra present within presented by Lee and Van Loenen (1971), who show that muscovite phenocrysts. the samples contain 2.8-3.4 percent normative corundum, A single analysis of zircon recovered from sample 378 and each is strongly peraluminous (molecular A120,4 suggests that the Lexington Creek pluton is Cretaceous in [CaO + N a 2 0 + K20]). The REE pattern (Fig. 13) of one age and was derived at least in part from a prexisting crustal sample from the Pole Canyon-Can Young Canyon intru- source (Lee, Stacey and Fischer 1983). The relatively high sion shows a relatively high (La/Yb ratio (-40) and only S i 8 0 values of 10.4 and 10.6 permil (Lee et al. 1982) deter- a small Eu anomaly (Cain 1974). A two-mica granite from mined for samples GR47 and GR48 (Fig. 2) are consistent the Ruby Mountains (Kistler et al. 1981) has about the with this idea. Three muscovites recovered from this pluton same amounts of HREE, but much lower LREE concentra- gave K-Ar ages of 77.9, 82.2, and 86.3 m.y. (Lee et al. tions (20X chondrite). 1980). The 86.3 m.y. age is assumed to be most nearly

The biotites present with muscovite in these rocks con- representative of the time of emplacement of this intrusion, tain only about 6.0 percent MgO, leading Lee and Van because there may have been partial degassing of the ana- Loenen (1970) to suggest that they may have initially equili- lyzed micas as a result of heat stress related to late move- brated with respect to a relatively low oxygen fugacity. This ment along the overlying thrust fault that truncates the inference is further substantiated by the complete absence intrusive mass. Using 86 m.y. as the emplacement age of of opaque oxides already noted. The only accessory miner- this pluton results in a calculated initial 87Sr/86Sr of 0.71 14

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(Lee, Kistler and Robinson 1983), another indication that this intrusive mass was derived from a crustal source with a high Rb/Sr ratio.

The Lexington Creek pluton contains apatite, zircon, fluorite, magnetite, and large amounts of epidote and zo- isite. However, the character of the accessory mineral suite originally present in this rock is problematical because of

The mineralogy of the Oligocene aplite is similar to that of the older aplites of the Pole Canyon-Can Young Canyon area, with muscovite, garnet, and fluorite in addition to quartz and feldspars. The aplites are also corundum norma- tive (1.5 to 3.0%), and two samples have 6"0 values (7.4 and 10.3 permil) similar to those found for samples of the undeformed mass in Young Canyon-Kious Basin.

the deuteric alteration noted earlier.

Summary

Young Canyon-Kious Basin Intrusion

Most of the granitoid rock exposed in the Young Canyon- Kious Basin area (Fig. 2) has been cataclastically deformed as a result of stresses related to late movement on the Snake Range decollement. The cataclastic part of this pluton is separated from the undeformed part by a fault that probab- ly represents the location of the Cambrian Pioche Shale before the pluton was emplaced (Lee and Van Loenen 1971, P1. 1). Biotites recovered from two samples from the unde- formed part of the pluton, and muscovite from spatially related aplite gave K - Ar ages of 29.9, 30.9, and 34.0 m.y., respectively. Concentrates of secondary muscovite recov- ered from the cataclastic or ti on of the intrusion gave K - " Ar ages of 17-18 m.y., presumably the time of deformation and thus of the most recent movement on the Snake Range decollement (Lee et al. 1970).

The 6180 values determined for three samples of the undeformed portion of the intrusion are 8.7, 9.8, and 10.0 permil, among the lowest of unaltered plutonic rocks from this area, but still relatively high. However, most sam- ples of the cataclastic portion have very low (to -2.6 per- mil) 6180 values. In general the most intensely deformed samples have the lowest 6180 values, leading Lee, Friedman and Gleason (1983) to the conclusion that this pluton un- derwent oxygen isotope exchange with meteoric water at the time of cataclasis.

The cataclasis of the pluton complicates interpretation of the Rb-Sr systematics. Lee, Kistler and Robinson (1983) report an age of 37.4k1.5 m.y. and an initial "Sr/ 86Sr ratio of 0.7120 (f 0.0001), using two cataclasized sam- ples and one undeformed sample. Including the analysis of a spatially associated aplite, the age is 28.3+ 1.5 m.y., with an initial 87Sr/86Sr ratio of 0.7126~(0.0004), in ap- proximate agreement with the K-Ar ages of the aplite and the undeformed parts of the intrusion. In either case the high intitial 87Sr/86Sr ratio of this Oligocene intrusion and the relativelv high 6180 values indicate that some meta-

d v

sedimentary materials were involved in its generation. The undeformed portion of the Young Canyon-Kious

Basin intrusion is an equigranular two-mica granite. Acces- sory minerals include allanite, monazite, magnetite, zircon, ilmenite, and very sparse sphene, apatite, and spessartine- almandine garnet. The biotites are similar in composition to those in the felsic part of the Middle Jurassic pluton of the Snake Creek-Williams Canyon area, with 2.9 to 3.0 AI'OT per 22 anions and Fez+ /Fez + + Mg of about 0.53 (Lee and Van Loenen 1970). The biotite compositions and the presence of sphene and magnetite suggest that the plu- ton crystallized under fairly oxidizing conditions. All of the samples analyzed are corundum normative. Unde- formed samples have 0.9 to 1.5% normative corundum, much less than the strongly peraluminous Pole Canyon-Can Young Canyon intrusion.

Some features of the granitic plutons in the southern Snake Range are summarized in Table 3. Magmatic activity began with the emplacement of three plutons of Middle Jurassic age in the western part of the study area (Fig. 2). These are the equigranular two-mica granite of the Willard Creek area and the calcic (Peacock 1931) intrusions of the Osceola and Snake Creek-Williams Canyon areas. The calcic plu- tons have initial 87Sr/'6Sr ratios of 0.7075 and 0.7071, re- spectively. These are the lowest initial ratios determined for any of the intrusive rocks of the southern Snake Range. The initial ratio of the Willard Creek pluton is somewhat higher at 0.70875, but this value is low compared with those of younger two-mica granites of the area.

After a period of quiescence lasting about 75 m.y., intru- sive activity resumed with the emplacement of the Late Cretaceous two-mica granites of the Pole Canyon-Can Young Canyon and Lexington Creek areas, somewhat to the east of the three Middle Jurassic plutons. Although these two-mica granites appear in outcrop only ten km apart and each crystallized from a relatively evolved (S- type) magma, they are very different rock types (Lee et al. 1981). For example, the Lexington Creek pluton contains discrete grains of both muscovite and biotite, whereas the biotite in the Pole Canyon-Can Young Canyon pluton only occurs as euhedra within large phenocrysts of muscovite.

The next period of quiescence lasted almost 50 m.y. and ended with the emplacement of the 37 m.y. (?) old equigran- ular two-mica granite of the Young Canyon-Kious Basin area, just to the east of the older plutons, and the penecon- temporaneous development of an aplite phase in the same general area. The granite has a relatively high initial s7Sr/ 86Sr of 0.7120.

Field studies indicate that the tops of the southern Snake Range plutons are present at about the same level, even though they range in age from Jurassic to Oligocene. Combined with the stratigraphic evidence that the region has been emergent since Late Jurassic, this indicates that the younger masses were emplaced at progressively more shallow depths. All of the plutons of the southern Snake Range appear at or below the level of the Snake Range decollement. Indeed, the Young Canyon-Kious Basin and the Lexington Creek intrusions were affected by late move- ment on this structure (Lee et al. 1970, 1980), and there is evidence to indicate that such spatial relationships be- tween intrusive rocks and thrust faults are not uncommon in the eastern Great Basin (Lee, Friedman and Gleason 1983).

There appears to be a confluence of regional igneous types in the southern Snake Range. We have noted the similarities between the distinctive muscovite-phenocrystic two-mica granite of the Pole Canyon-Can Young Canyon area and those of the Kern Mountains and the Toana Range, Nevada. The N - S trend defined by these distinctive granites is 225 km long (Lee et al. 1981). The Middle Jur-

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Table 3. Summary of data for intrusive rocks of the southern Snake Range, Nevada

Intrusion Rock typea Age Initial 6180 Accessory minerals 87Sr/86Sr permil

Snake Creek- Tonalite - 155 m.y. 0.7071 10.2-12.2 Felsic- garnet, monazite Williams granodiorite - (Rb - Sr) phase ilmenite, zircon Canyon granite Mafic epidote, magnetite sphene,

phase allanite apatite, zircon

Osceola Granodiorite - 145 m.y. 0.7075 9.6-9.9 Epidote, allanite, magnetite, sphene, (Rb - Sr) apatite zircon 160 m.y. (U - Pb)

Willard Equigranular 151 m.y. 0.7086 13.2 Monazite, ilmenite magnetite, apatite, Creek two-mica (Musc K - Ar) zircon, garnet

granite

Pole Canyon - Muscovite - 79 m.y. 0.7157 10.6-12.1 Allanite, monazite, acicular zircon in Can Young phenocrystic (Rb - Sr) equant apatite Canyon granodiorite -

granite

Lexington Equigranular 86 m.y. (?) 0.7114 10.4-10.6 Apatite, zircon, fluorite, apatite, Creek two-mica epidoteb, ziositeb

granite

Young Equigranular 37 m.y. (?) 0.7120 8.7-10.0 Allanite, monazite, magnetite, zircon, Canyon - two-mica (Rb - Sr) ilmenite: very sparse sphene, apatite, Kious Basin granite and garnet

Aplite Aplite 29 m.y. (?) 0.7120 (?) 7.4-10.3 Garnet, fluorite, trace amounts of gahnite, columbite-tantalite. Beryl found in one aplite

" According to the IUGS classification (Streckeisen 1973) May be deuteric

assic calcic plutons in the Osceola and the Snake Creek- the role of postmagmatic modification of single whole rock Williams Canyon areas are similar in age and petrology samples that represent entire plutons (e.g. those from Lee to the Notch Peak intrusion (169k3 m.y.) of the House et al. 1981). These samples are distinguished from others Range in western Utah (Lee, Stacey and Fischer 1983) and on Fig. 14. From the correlation of 0 and Sr isotopes two to the southern intrusion (152 m.y.) in the Gold Hill area groups of plutons can be distinguished. Those with 87Sr/ in Utah (Stacey and Zartman 1978). The middle Tertiary 86Sr less than 0.709 (all Jurassic in age) trend toward high igneous event apparent in the Young Canyon-Kious Basin 6180 (up to 13.2 permil). The other group diverges from area is represented by an Oligocene (38 m.y.) pluton that this trend and has much higher initial 87Sr/86Sr at compara- makes up the northern part of the intrusive outcrop of ble values of 6180. This latter trend is similar to the correla- the Gold Hill, Utah, area (Stacey and Zartman 1978). tion observed in the Maladeta igneous complex, Spain (Mi-

Finally, we note that the sequence of igneous events chard-Vitrac et al. 1980), and within granites of the inner described here is remarkable similar to that found in the Piedmont of the southwestern U.S.A. (Wenner 1981) - Ruby Mountains of Elko County, about 200 km northwest rocks that show S-type affinities in their chemistry and min- of the area of Fig. 1. Jurassic (160k2 m.y.), Cretaceous eralogy. The trend of the low 87Sr/s6Sr Jurassic plutons (83k1.3 m.y.), and Tertiary (31.9k1.2 m.y.) intrusive is similar to that observed for the eastern portion of the rocks all are present in the Ruby Mountains (Kistler et al. Peninsular Range batholith, California (Taylor and Silver, 1981). 1978), to the British Caledonides (Halliday et al. 1980), and

to the Sierra Nevada batholith (Masi et al. 1981) - rocks which appear to be chemically similar to the Snake Creek-

Discussion Williams Canyon pluton. The Sr and 0 isotope compositions of the granitoid rocks The covariation of Sr and 0 isotopic compositions is from this region may yield some clues to the origin of the usually attributed to the mixing of isotopically distinct res- contrasting magma suites. Lee et al. (1982) showed that ervoirs in the mantle and crust. The mixing may be accom- minerals from the Snake Creek-Williams Canyon and Pole plished through bulk contamination of a rising magma, Canyon-Can Young Canyon plutons appear to be in isotope exchange between magma and wall rock, or by isotopic equilibrium. Although not all whole rock samples physical mixing of the reservoirs within the source region. employed in the following analysis were studied in this man- It is very difficult to distinguish among these mechanisms ner, it seems probable that most are representative of the based simply on isotopic variations. magmas from which they crystallized. Samples of the catac- A schematic cross section of the crust and upper mantle lastic part of the Young Canyon-Kious Basin pluton show of this portion of the northern Great Basin is shown in marked depletion of "0 (Lee et al. 1982), and their 6180 Fig. 15. Approximate values of d'80 and are giv- values are not considered further here. It is dificult to assess en for each reservoir, based on the work of Kistler et al.

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17

15

13

@ 11 V)

9

EXPLANATION 7 @Values used in calculations. Stippled

areas indicate approximate ranges of compositions observed

5 0.70 0.71 0.72 0.73 0.74

87Sr 186Sr

Fig. 14. 6180 versus 87Sr/86Sr diagram showing the compositions of plutonic rocks from northeastern Nevada. 0 Osceola pluton; SC Snake Creek-Williams Canyon; W Willard Creek; L Lexington Creek; Y Young Canyon-Kious Basin; RK Cretaceous granite, Ruby Mountains; R J Jurassic granite, Ruby Mountains; P Pole Canyon-Can Young Canyon; K Kern Mountains; T Toana Range. Plutons represented by a single sample are shown (+) separate from the fields for other intrusions. Superimposed are curves showing simple mixing between a melt derived from the lower crust (400 ppm Sr, 87Sr/86Sr=0.706, 6180 =7), and two hypothetical metamorphic components of the middle crust. One of these is a granitic gneiss (200 ppm Sr, 87Sr/86Sr = 0.71 5, 6180 = 12), the other a schist (200 ppm Sr, 87Sr/86Sr=0.732, 6180= lo), both similar to rocks in the metamorphic terrane exposed in the Ruby Mountains (Kistler et al. 1981). Also shown is a curve denoting mixing between a lower crustal magma and a hypothetical quartzite (8 ppm Sr, 87Sr/86Sr=0.760, 6180= 15) representing clastic sedimentary rocks from the region (Lee and Doering 1980; Lee et al. 1982; Lee, Kistler and Robinson, 1983; and unpublished). The dashed lines show the effects of contaminating a mantle-derived magma (assumed to have 300 ppm Sr, 87Sr/86Sr= 0.704, and 6180 = 6) from two of the crustal reservoirs

(1981), Lee et al. (1981, 1982), and Lee, Kistler and Robin- composition of the crustal reservoirs it is unlikely that the son (1983). The stratigraphic reconstruction is from Stewart S-type magmas were generated by partial melting of the (1980) and ignores post-Cambrian sedimentation and tec- late Precambrian sedimentary rocks. During the Cretaceous tonism. (The stratigraphy summarized by Stewart implies these sedimentary rocks (mostly quartzites with minor that the Jurassic and Cretaceous plutons in the southern shale) had R7Sr/86Sr ratios of 0.760 to 0.780, much higher Snake Range were emplaced at a depth of about 10 km than those observed in the Cretaceous two-mica granites from the surface.) The compositions of these reservoirs are (0.71 1-0.732), and they were at depths of less than about shown in schematic fashion on Fig. 14. 16 km. An extremely high geothermal gradient would have

From the positions of the reservoirs relative to the com- been necessary to produce partial melting at this depth. position of the granitic rocks it is clear that the Pole Can- The lack of S-type plutons with high 87Sr/86Sr, (>0.71) yon-Can Young Canyon magma (and a few other strongly in western Utah suggests that the mid-crustal reservoir, in- peraluminous plutons like those in the Toana Range and terpreted to consist of Proterozoic metasediments (possibly in the Ruby and Kern Mountains) could have been formed derived from Archean parents; Farmer and DePaolo 1980) solely by anetexis of metasediments and granitic gneisses, and plutonic rocks like those described by Kistler et al. thought to have been at depth greater than 16 km during (1981), must not contribute substantially to magmatic pro- the Cretaceous. Indeed, Kistler et al. (1981) have suggested cesses there (Farmer and DePaolo 1981 ; Moore et al. 1979; that the Cretaceous and Jurassic granites in the Ruby Zartman 1974). This may be because the mid-crustal reser- Mountains have not moved significant distances from their voir does not occur at appropriate depths for contamina- sources. These granites intrude Precambrian metasediments tion or magma generation. This possibility is consistent with and granitic gneisses and are chemically similar to the Pole the regional stratigraphy and the tectonic reconstructions Canyon-Can Young Canyon pluton. The derivation of of Stewart (1980), which demonstrate that eastern Nevada these S-type granites from a mid-crustal reservoir of meta- was the site of subsidence and the accumulation of consider- sedimentary rocks is consistent with the presence of an in- able volumes of sediments (> 10 km thick) from the late herited component in the U -Pb systematics of their zircons Precambrian until at least the Triassic, depressing the base- (Lee, Stacey and Fischer 1983; Kistler et al. 1981, p 1448), ment there. In Utah, the mid-crustal reservoir occurs be- Nd model ages (Farmer and DePaolo 1980), their mineralo- neath a relatively thin sequence of Paleozoic sedimentary gy which implies crystallization at low fo2 (possibly as a rocks. Alternatively, Proterozoic sediments may have at- result of equilibration with graphite), and their strongly tained great thicknesses only off the western margin of the peraluminous chemistry which resulted in the crystallization Archean craton in the present site of eastern Nevada of muscovite and aluminous biotite. From the apparent (Fig. 15).

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this reservoir could be the clastic sedimentary rocks that make up the upper Precambrian-Lower Cambrian section in this region (Fig. 14). The data of Lee et al. (1 981, 1982,

BONATE SEDIMENTS and unpublished), and Lee, Kistler and Robinson (1983) shows that these sedimentary rocks have 6180 values of 11 to 15 permil and 87Sr/86Sr-0.760 (at 150 m.y.). A mixing parabola joining the high 6180 end of this range with a magma derived from the lower crustal reservoir is shown (Fig. 14). Large amounts of contaminar~on (up to about 70%) or isotopic exchange are required to produce the spectrum of compositions observed. Contamination by carbonates is deemed unlikely because of the covariation of 6180 and the increasing activity of A1,03 in the sequence of melts represented by the Osceola, Snake Creek-Williams Canyon, and Willard Creek intrusions. Nonetheless, it seems unlikely that this was accomplished by bulk contami- nation of a magma.

Fig. 15. Schematic diagram of the crustal structure of the northeas- In summary, the isotopic compositions of the southern tern Great Basin along an east-west transect that crosses the Ne- vada-Utah border at about 39" N. Post-Cambrian sedimentation Snake Range plutonic rocks define two trends - one toward

and tectonism have been ignored. The possible absence of a lower high 6180 at moderate 87Sr/86Sr, composed solely of Jur- crustal reservoir in eastern Nevada (Farmer and DePaolo 1981) assic plutons, the high 87Sr/86Sr at moderate is indicated by the dashed lower boundary for the metasedimentary 6180. These variations are consistent with the contamina- portion of the crustal section. Approximate values of 61s0 and tion of magmas derived from the lower crust by a compo- initial 87~r /86Sr (Sr,) are given for the five reservoirs discussed nent from upper crustal sedimentary rocks producing the in the text. The ruled area on the left represents the metasediment- first trend. The second trend may involve mixing a lower ary "source" of the highly peraluminous granites; the cross- crustal magma with a component from the middle crust hatched area represents the source of the calcic to calc-alkaline of metasedimentary and igneous rocks, The S- plutons of the area and may include the lower crust(?), mantle, and rnetasedimentary component. The vertical lines joining source type granites appear to have a large proportion of the mid-

and pluton cross the reservoirs which may have contributed to component. the isotopic composition of the plutons Other models could also explain the isotopic composi-

tions observed. For example, in terms of Sr and 0 isotopes it is extremely difficult to distinguish between the mixing

Other plutons (Lexington Creek and Young Canyon- of a mantle-derived basalt with a component from the lower Kious Basin) on the high 87Sr/86Sr trend could conceivably crust and the simple derivation of a melt from the lower be explained as a result of the mixing of a component from crust. However, we see little compelling evidence for the the mid-crustal reservoir with a component of another res- involvement of mantle-derived melts in producing the 0 ervoir having both lower 6180 and 87Sr/86~r, . Based on and Sr isotopic relations observed; an end member with the extrapolation of the trend to low 87Sr/86Sr,, the 6180 the appropriate isotopic composition (low 6180 and 87Sr/ of this primitive reservoir appears to have been in the range 86Sr) probably exists in the lower crust, for it can be dis- of 7-9 permil, values more consistent with the lower crust cerned in western Utah (E.H. Christiansen, unpublished than with the mantle. The chemistry and mineralogy of data). Certainly the aluminous nature of all of the granitoid the plutons are also consistent with a lower crustal source. rocks (high Al,03, with epidote or garnet and/or musco- Mixing parabolas join the composition of this hypothetical vite), their relatively silicic compositions, and the nature reservoir (6180 = 7 permil and 87Sr/86Sr, = 0.706) to por- of the liquidus phases (plagioclase, biotite, quartz) in even tions of the mid-crustal reservoir as approximated from the more primitive plutons suggests their ultimate deriva- Kistler et al. (1981). The isotopic compositions of the plu- tion from the crust. The apparent absence of mafic igneous tons from this group fall within this rather broad envelope. rocks of the appropriate age is permissive evidence against Those which we have termed S-types fall at the high 87Sr/ involvement of mantle-derived magmas in the generation 86Sr portion of the envelope. Contamination near the site of these granitic rocks. of emplacement would involve the carbonate or clastic res- Farmer and DePaolo (1981) have interpreted the Nd - ervoirs shown in Fig. 14, and may have further altered the Sr isotopic systematics of plutonic rocks from the northern position of the plutons in the 6180-87Sr/86Sr diagrams. Great Basin to indicate the absence of a lower crustal reser-

The low 87Sr/86Sr trend is more difficult to rationalize. voir in eastern Nevada. This inference is based on a appar- As noted earlier, this trend is similar to that encountered ent lack of low to moderate 87Sr/86Sr, (0.706-0.708) ratios in many plutonic and volcanic environments (generally in the region at appropriate Nd isotope ratios. We suggest thought to be related to the subduction process). The corre- that with the occurrence of plutons with 8 7 ~ r / 8 6 ~ r , lower lation is generally explained as the result of increasing than 0.708, a significant reservoir with isotopic characteris- amounts of contamination of a primitive mantle-derived tics of the lower crust (87Sr/86~r = 0.706- 709; d i 8 0 = 6 to magma by sedimentary materials, either at the source or 8 permil) may exist beneath the region. as the magma passes through the crust. If mixing with a noncarbonate sediment is important, then in order to pro- duce the marked 6180 variation with only small changes COnclUSions

in 87Sr/86~r , a reservoir with very low Sr concentration The chemical, mineralogical and isotopic diversity of the and high 6180 must be involved. A possible candidate for granitic plutons from the southern Snake Range, Nevada,

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and surrounding regions is largely a result of differences in the nature and composition of their sources. Strongly peraluminous Cretaceous granites with phenocrystic mus- covite were probably derived from a mid-crustal source composed of Proterozoic metasediments. They have high initial strontium-isotope ratios (over 0.715), moderately high 6180 (9 to 13 permil) and other characteristics of S- type granites. Metaluminous to peraluminous granites (Young Canyon-Kious Basin and Lexington Creek plutons) may have derived part of their character from a similar source but they have lower initial strontium-isotope ratios and in some cases bear magnetite and sphene, indicating crystallization under relatively oxidizing conditions. Thus we suggest that a component from the lower crust (or per- haps the mantle) was important in their source region. Three Jurassic plutons with accessory magnetite form a dis- tinct group that has initial Sr-isotope ratios less than 0.709 but with relatively high 6180 (up to 13 permil). We interpret these as originating from magmas that were contaminated as they passed through a thick Precambrian-Cambrian se- quence of quartzite-dominated clastic rocks. We suggest that their ultimate source lies in the lower crust but it is difficult to rule out the involvement of mantle-derived mafic magmas in their genesis. One of these plutons has been studied in detail and it appears that little assimilation took place during its crystallization. In situ fractional crystalliza- tion nonetheless drove residual liquids to higher dl'O (up to 12 permil) and led to the replacement of sphene and magnetite by ilmenite and garnet as crystallizing phases.

Acknowledgements. F.C.W. Dodge and R.W. Kistler of the U.S. Geological Survey provided helpful advice in the field and con- structive reviews of this manuscript. We have also benefited from the constructive reviews of Lang Farmer of U.C.L.A. and Craig Simmons of the Colorado School of Mines. Eric H. Christiansen was supported by a National Research Council - U.S. Geological Survey Postdoctoral Research Associateship while part of this work was performed.

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Received July 7, 1982; Accepted March 20, 1983