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The following list contains the Material Safety Data Sheets you requested. Please scoll down to view the requested MSDS(s). Product MSDS Distributor Format Language Quantity 2122326 N/A Hach Company ROWGHS English 1 1457799 N/A Hach Company ROWGHS English 1 2122426 N/A Hach Company ROWGHS English 1 27242 N/A Hach Company ROWGHS English 1 __________________________________________________________________________________________________________ Total Enclosures: 4

The following list contains the Material Safety Data ...guidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only persons properly

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Page 1: The following list contains the Material Safety Data ...guidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only persons properly

The following list contains the Material Safety Data Sheets you requested. Please scoll down to view the requested MSDS(s).

Product MSDS Distributor Format Language Quantity

2122326 N/A Hach Company ROWGHS English 11457799 N/A Hach Company ROWGHS English 12122426 N/A Hach Company ROWGHS English 127242 N/A Hach Company ROWGHS English 1__________________________________________________________________________________________________________Total Enclosures: 4

Page 2: The following list contains the Material Safety Data ...guidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only persons properly

World HeadquartersHach CompanyP.O.Box 389 MSDS No: M00379Loveland, CO USA 80539(970) 669-3050

SAFETY DATA SHEET_____________________________________________________________________________1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Alkaline Cyanide ReagentCatalog Number: 2122326

Hach Company Emergency Telephone Numbers:P.O.Box 389 (Medical and Transportation)Loveland, CO USA 80539 (303) 623-5716 24 Hour Service(970) 669-3050 (515)232-2533 8am - 4pm CST

MSDS Number: M00379Chemical Name: Not applicableCAS Number: Not applicableAdditional CAS No. (for hydrated forms): Not applicableChemical Formula: Not applicableChemical Family: Not applicableIntended Use: Laboratory Reagent Determination of manganese

_____________________________________________________________________________2. HAZARDS IDENTIFICATION

GHS Classification:Hazard categories: Acute Toxicity: Acute Tox. 3-Orl Acute Toxicity: Acute Tox. 2-Derm Acute Toxicity: Acute Tox.3-Inh Skin Corrosion/Irritation: Skin Corr. 1A Hazardous to the Aquatic Environment: Aquatic Chronic 1

GHS Label Elements:DANGER

Hazard statements: Toxic if swallowed. Fatal in contact with skin. Toxic if inhaled. Causes severe skin burns and eyedamage. Very toxic to aquatic life with long lasting effects.

Contact with acids liberates very toxic gas.Precautionary statements: Do not breathe dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilatedarea. Do not get in eyes, on skin, or on clothing. Do no eat, drink or smoke when using this product. Wear protectivegloves / protective clothing / eye protection / face protection. IF ON SKIN (or hair): Remove/Take off immediately allcontaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove victim/person to fresh airand keep at rest in a position comfortable for breathing. IF SWALLOWED: rinse mouth. Do NOT induce vomiting.Immediately call a POISON CENTER or doctor/physician.

HMIS:Health: 3Flammability: 0Reactivity: 0Protective Equipment: X - See protective equipment, Section 8.

NFPA:Health: 3Flammability: 0Reactivity: 0Symbol: Not applicable

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WHMIS Hazard Classification: Class E - Corrosive material Class D, Division 1, Subdivision B - Toxic material(immediate effects)WHMIS Symbols: Corrosive Acute Poison

_____________________________________________________________________________3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Components according to GHS:Sodium Cyanide

CAS Number: 143-33-9 Chemical Formula: NaCNGHS Classification: Acute Tox. 1 –Orl, H300; Acute Tox. 1 – Derm, H310; Acute Tox. 2 - Inh, H330; Aquatic acute 1,H400; Aquatic Chronic 1, H410;EUH032Percent Range (Trade Secret): 5.0 - 15.0Percent Range Units: weight / weightPEL: 5 mg/m3 (skin)TLV: 5 mg/m3 (skin)

WHMIS Symbols: Acute PoisonSodium Hydroxide

CAS Number: 1310-73-2 Chemical Formula: NaOHGHS Classification: Met. Corr.1, H290; Skin Corr. 1A, H314; Aquatic Acute 3, H402Percent Range (Trade Secret): 1.0 - 5.0Percent Range Units: weight / weightPEL: 2 mg/m³TLV: Not established

WHMIS Symbols: Acute PoisonCorrosiveHazardous Components according to GHS: No

Demineralized Water

CAS Number: 7732-18-5 Chemical Formula: H2OGHS Classification: Not a dangerous substance according to GHS.Percent Range (Trade Secret): > 90.0Percent Range Units: weight / weightPEL: Not establishedTLV: Not established

WHMIS Symbols: Not applicable_____________________________________________________________________________4. FIRST AID MEASURES

General Information: In the event of exposure, show this Material Safety Data Sheet and label (where possible) to adoctor. Have a cyanide first aid kit available. Emergency response to cyanide exposure should be planned and practicedprior to work with cyanides. First responders should start treatment and get medical attention immediately.Advice to doctor: Break an amyl nitrite pearl in cloth and hold lightly under nose for 15 seconds. Repeat 5 times at 15second intervals. Transport to hospital immediately. If patient has not responded to amyl nitrite, inject intraveneously 10mL of a 3% solution of sodium nitrite at a rate not greater than 2.5 - 5 mL/min. Follow directly with 50 mL of a 25 %solution of sodium thiosulfate at the same rate by the same route. Keep patient under observation. If signs of poisoningpersist or reappear, repeat nitrite and thiosulfate injections 1 hour later in one-half the original doses.

Emergency response to cyanide exposure should be planned and practiced prior to work with cyanides. First respondersshould start treatment and get medical attention immediately. Antidote: break an amyl nitrite pearl in cloth and hold lightlyunder nose for 15 seconds. Repeat 5 times at 15 second intervals. Transport to hospital immediately. Note to Physician:Have a cyanide first aid kit available. If patient has not responded to amyl nitrite, inject intraveneously 10 mL of a 3%solution of sodium nitrite at a rate not greater than 2.5 - 5 mL/min. Follow directly with 50 mL of a 25 % solution ofsodium thiosulfate at the same rate by the same route. Keep patient under observation. If signs of poisoning persist orreappear, repeat nitrite and thiosulfate injections 1 hour later in one-half the original doses.Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.

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Skin Contact (First Aid): Remove contaminated clothing. Wash skin with plenty of water for 15 minutes. Call physicianimmediately.Inhalation: Remove to fresh air. Call physician.Ingestion (First Aid): Never give anything by mouth to an unconscious person. Call physician immediately.

_____________________________________________________________________________5. FIRE FIGHTING MEASURES

Flammable Properties: During a fire, irritating and highly toxic gases may be generated by thermal decomposition.Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear.Extinguishing Media: Use media appropriate to surrounding fire conditionsExtinguishing Media NOT To Be Used: Not applicableFire / Explosion Hazards: May react violently with: strong acidsHazardous Combustion Products: Toxic fumes of: cyanide compounds sodium monoxide

_____________________________________________________________________________6. ACCIDENTAL RELEASE MEASURES

Spill Response Notice:Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill

according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only personsproperly qualified according to state or local regulations should respond to a spill involving chemicals.Containment Technique: Releases of this material may contaminate the environment. Stop spilled material from beingreleased to the environment. Absorb spilled liquid with non-reactive sorbent material.Clean-up Technique: If permitted by regulation, Cover spilled material with an alkali, such as soda ash or sodiumbicarbonate. Carefully mist spill with bleach until saturated. Scoop up slurry into a large beaker. Oxidize spilled materialwith a 50% excess of bleach containing at least 5% sodium hypochlorite. Allow to react for 24 hours in a fume hood.Flush reacted material to the drain with a large excess of water. Decontaminate area with bleach solution. Otherwise, Pickup spill for disposal and place in a closed container Dispose of in accordance with local, state and federal regulations orlaws.Evacuation Procedure: Evacuate general area (50 foot radius or as directed by your facility's emergency response plan)when: any quantity is spilled. Deny access to unnecessary and unprotected personnel. If conditions warrant, increase thesize of the evacuation.DOT Emergency Response Guide Number: 154

_____________________________________________________________________________7. HANDLING AND STORAGE

Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling.Maintain general industrial hygiene practices when using this product.Storage: Keep away from: acids / acid fumes. Protect from: heat freezingFlammability Class: Not applicable

_____________________________________________________________________________8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls: Use a fume hood to avoid exposure to dust, mist or vapor. Maintain general industrial hygienepractices when using this product.Personal Protective Equipment:

Eye Protection: chemical splash gogglesSkin Protection: neoprene latex gloves In the EU, the selected gloves must satisfy the specifications of EU Directive89/686/EEC and standard EN 374 derived from it. lab coatInhalation Protection: laboratory fume hood

Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly afterhandling. Keep away from: acids/acid fumes Protect from: heat freezingTLV: Cyanide 5 mg/m3 (skin)PEL: Cyanide 5 mg/m3 (skin)For Occupational Exposure Limits (OEL) for ingredients, see section 3 - Composition/Information on Ingredients.:

_____________________________________________________________________________9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Clear, colorless liquid

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Physical State: LiquidMolecular Weight: Not applicableOdor: NoneOdor Threshold: OdorlesspH: 12.3Metal Corrosivity:

Corrosivity Classification: Not classified as corrosive to metals according to GHS criteria.Steel: Not determinedAluminum: Not determined

Specific Gravity/ Relative Density (water = 1; air =1): 1.112Viscosity: Not determinedSolubility:

Water: MiscibleAcid: Produces HCNOther: Not determined

Partition Coefficient (n-octanol / water): Not applicableCoefficient of Water / Oil: Not applicableMelting Point: Not availableDecomposition Temperature: Not determinedBoiling Point: 92 CVapor Pressure: Not availableVapor Density (air = 1): Not availableEvaporation Rate (water = 1): 0.57Volatile Organic Compounds Content: Not applicableFlammable Properties: During a fire, irritating and highly toxic gases may be generated by thermal decomposition.Flash Point: Not applicable

Method: Not applicableFlammability Limits:

Lower Explosion Limits: Not applicableUpper Explosion Limits: Not applicable

Autoignition Temperature: Not availableExplosive Properties:

Not classified according to GHS criteria.Oxidizing Properties:

Not classified according to GHS criteria.Reactivity Properties:

Not classifed as self-reactive, pyrophoric, self-heating or emitting flammable gases in contact with water according toGHS criteria.Gas under Pressure:Not classified according to GHS criteria.Not determined

_____________________________________________________________________________10. STABILITY AND REACTIVITY

Chemical Stability: Stable when stored under proper conditions.Mechanical Impact: None reportedStatic Discharge: None reported.Reactivity / Incompatibility: Incompatible with: acidsHazardous Decomposition: Contact with acids/acid fumes releases toxic cyanide gas.Conditions to Avoid: Extreme temperatures

_____________________________________________________________________________11. TOXICOLOGICAL INFORMATION

Toxicokinetics, Metabolism and Distribution: No information available for mixture.Toxicologically Synergistic Products: None reportedAcute Toxicity: Toxicological Testing and/or Acute Toxicity Estimate (ATE) - Calculated from Ingredient Toxicity DataTesting data Oral Rat LD50 = 69 mg/kg; ATE oral LD50 = 64 mg/kgTesting data Dermal rabbit LD50 Between 200 mg/kg and 500 mg/kg; ATE dermal LD50 = 103 mg/kg;ATE inhalation Rat LC50 = 2.4 mg/l

Specific Target Organ Toxicity - Single Exposure (STOT-SE): Based on classification principles, the classificationcriteria are not met.

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Specific Target Organ Toxicity - Repeat Exposure (STOT-RE): Based on classification principles, the classificationcriteria are not met.Skin Corrosion/Irritation: Corrosive to skin.Testing data: 1 Hour exposure - Severe erythema 1 hour after exposure. Slight edema 1 hour after exposure. Moderate

eschar with pale areas 1 hour after exposure.Eye Damage: Corrosive to eyes.Sensitization: Based on classification principles, the classification criteria are not met.CMR Effects/Properties (carcinogenic, mutagenic or toxic to reproduction): No germ cell mutagenicity, carcinogenicityor reproductive toxicity data found.

This product does NOT contain any IARC listed chemicals.This product does NOT contain any NTP listed chemicals.This product does NOT contain any OSHA listed carcinogens.

Symptoms/Effects:Ingestion: Toxic May be rapidly fatal. Causes: cyanosis ( a reduction of the blood's ability to carry oxygen, giving abluish discoloration) burns of the mouth and esophagus May cause: anxiety headache confusion irregular heartbeatconvulsions coma deathInhalation: Toxic Effects similar to those of ingestion.Skin Absorption: Toxic Will be absorbed through the skin. Effects similar to those of ingestionChronic Effects: Chronic overexposure may cause central nervous system effects irritation skin irritation

Medical Conditions Aggravated: Pre-existing: Skin conditions_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: --No ecological data available for this product.

Ingredient Ecological Information: sodium cyanide: Lepomis macrochirus 96hr LC50 = 0.083 mg/l; Asellus communis96hr EC50 = 2.33 mg/lCEPA statement: Sodium Hydroxide: Persistent, Not bioaccumulative or inherently toxic to aquatic organisms; Sodium

Cyanide: Persistent, Inherently toxic to aquatic organisms, Not bioaccumulative._____________________________________________________________________________13. DISPOSAL CONSIDERATIONS

EPA Waste ID Number: D003Special Instructions (Disposal): Dispose of material in an E.P.A. approved hazardous waste facility.Empty Containers: Rinse three times with an appropriate solvent. In the US, rinsate from empty containers is classified ashazardous waste and should be disposed of at an E.P. A. approved facility.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemicaland analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging mustbe disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.

_____________________________________________________________________________14. TRANSPORT INFORMATION

D.O.T.:D.O.T. Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S.(Sodium Hydroxide/Sodium Cyanide Solution)

Hazard Class: 8Subsidiary Risk: 6.1ID Number: UN2922Packing Group: II

T.D.G.:Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S.(Sodium Hydroxide/Sodium Cyanide Solution)

Hazard Class: 8Subsidiary Risk: 6.1UN Number/PIN: 2922Packing Group: II

I.C.A.O.:I.C.A.O. Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S.(Sodium Hydroxide/Sodium Cyanide Solution)

Hazard Class: 8

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Subsidiary Risk: 6.1ID Number: UN2922Packing Group: II

I.M.O.:Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S.(Sodium Hydroxide/Sodium Cyanide Solution)

Hazard Class: 8Subsidiary Risk: 6.1ID Number: UN2922Packing Group: II

Additional Information: There is a possibility that this product could be contained in a reagent set or kit composed ofvarious compatible dangerous goods. If the item is NOT in a set or kit, the classification given above applies. If the item ISpart of a set or kit, the classification would change to the following: UN3316 Chemical Kit, Class 9, PG II or III. If the itemis not regulated, the Chemical Kit classification does not apply.

_____________________________________________________________________________15. REGULATORY INFORMATION

U.S. Federal Regulations:O.S.H.A.: This product meets the criteria for a hazardous substance as defined in the Hazard Communication Standard.(29 CFR 1910.1200)E.P.A.:

S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): Immediate (Acute) Health HazardS.A.R.A. Title III Section 313 (40 CFR 372): This product contains a chemical(s) subject to the reportingrequirements of Section 313 of Title III of SARA.Cyanide compounds

302 (EHS) TPQ (40 CFR 355): Sodium Cyanide 100 lbs.304 CERCLA RQ (40 CFR 302.4): Sodium Hydroxide 1000 lbs. Sodium Cyanide 10 lbs.304 EHS RQ (40 CFR 355): Sodium Cyanide - RQ 10 lbsClean Water Act (40 CFR 116.4): Sodium Hydroxide - RQ = 1000 lbs. (454 kgs.) Sodium cyanide - RQ 10 lbs.RCRA: Contains RCRA regulated substances. See Section 13, EPA Waste ID Number.

State Regulations:California Prop. 65: No Prop. 65 listed chemicals are present in this product.Identification of Prop. 65 Ingredient(s): NoneCalifornia Perchlorate Rule CCR Title 22 Chap 33: Not applicableTrade Secret Registry: Not applicable

National Inventories:U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).

CAS Number: Not applicableCanadian Inventory Status: All ingredients of this product are DSL Listed.EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.Australian Inventory (AICS) Status: All ingredients are listed.New Zealand Inventory (NZIoC) Status: All components either listed or exempt.Korean Inventory (KECI) Status: All components of this product are either listed, listed as the anhydrous compound orexempt.Japan (ENCS) Inventory Status: All components either listed or exempt.China (PRC) Inventory (MEP) Status: All components either listed or exempt.

_____________________________________________________________________________16. OTHER INFORMATION

References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for1992-1993. American Conference of Governmental Industrial Hygienists, 1992. CCINFO RTECS. Canadian Centre forOccupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. Gosselin, R. E. et al. Clinical Toxicology ofCommercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. Outside Testing. In-house information.Technical Judgment. List of Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification,Packaging and Labeling of Dangerous Substances, Amended July 1992.Complete Text of H phrases referred to in Section 3: H290 May be corrosive to metals. H300 Fatal if swallowed. H310Fatal in contact with skin. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H330 Fatalif inhaled. H400 Very toxic to aquatic life. . H410 Very toxic to aquatic life with long lasting effects.Revision Summary: . . Substantial revision to comply with EU Reg 1272/2008, Reg 1907/2006 and UN GHS (ST/SG/AC.10/36/Add.3).

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Date of MSDS Preparation:Day: 30Month: JulyYear: 2014

MSDS Prepared: MSDS prepared by Product Compliance Department extension 3350CCOHS Evaluation Note: It is offered under exemption from WHMIS labeling as specified in the Controlled ProductsRegulation (CPR) Section 17. It is offered under the interim policy that was established by Health Canada permitting useof GHS-formatted safety data sheets in Canada prior to revision of CPR to GHS. This product has been classified andlabeled in accordance with the requirements of GHS (ST/SG/AC.10/36/Add.3). This SDS has been prepared in accordancewith the requirements of GHS (ST/SG/AC.10/36/Add.3).

_____________________________________________________________________________

Legend:NA - Not Applicable w/w - weight/weightND - Not Determined w/v - weight/volumeNV - Not Available v/v - volume/volume

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safetyprograms in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATAOR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.

HACH COMPANY ©2015

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World HeadquartersHach CompanyP.O.Box 389 MSDS No: M00075Loveland, CO USA 80539(970) 669-3050

SAFETY DATA SHEET_____________________________________________________________________________1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Ascorbic AcidCatalog Number: 1457799

Hach Company Emergency Telephone Numbers:P.O.Box 389 (Medical and Transportation)Loveland, CO USA 80539 (303) 623-5716 24 Hour Service(970) 669-3050 (515)232-2533 8am - 4pm CST

MSDS Number: M00075Chemical Name: Not applicableCAS Number: Not applicableAdditional CAS No. (for hydrated forms): Not applicableNot applicable

Chemical Formula: Not applicableChemical Family: Not applicableIntended Use: Laboratory Reagent

_____________________________________________________________________________2. HAZARDS IDENTIFICATION

This mixture is not classified as hazardous per GHS (UN publication ST/SG/AC.10/36/Add.3)GHS Classification:

Hazard categories: Not applicableGHS Label Elements:Not applicable

Hazard statements: Not applicablePrecautionary statements: Not applicable

HMIS:Health: 0Flammability: 1Reactivity: 0Protective Equipment: X - See protective equipment, Section 8.

NFPA:Health: 0Flammability: 1Reactivity: 0Symbol: Not applicable

WHMIS Hazard Classification: Not applicableWHMIS Symbols: Not applicable

_____________________________________________________________________________3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Components according to GHS: NoAscorbic Acid

CAS Number: 50-81-7 Chemical Formula: C6H8O6

GHS Classification: Not applicablePercent Range (Trade Secret): > 99.0

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Percent Range Units: weight / weightPEL: 15 mg/m3 as total dust; 5 mg/m3 as respirable dustTLV: 10 mg/m3 as inhalable dust; 3 mg/m3 as respirable dust

WHMIS Symbols: Not applicableOther component

CAS Number: Not applicableChemical Formula: Not applicable.GHS Classification: Not applicablePercent Range (Trade Secret): < 1.0Percent Range Units: weight / weightPEL: Not establishedTLV: Not established

WHMIS Symbols: Not applicable_____________________________________________________________________________4. FIRST AID MEASURES

General Information: In the event of exposure, show this Material Safety Data Sheet and label (where possible) to adoctor.Advice to doctor: Treat symptomatically.Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician if irritation develops.Skin Contact (First Aid): Remove contaminated clothing. Wash skin with soap and plenty of water. Call physician ifirritation develops.Inhalation: Remove to fresh air.Ingestion (First Aid): Give large quantities of water. Never give anything by mouth to an unconscious person. Callphysician immediately.

_____________________________________________________________________________5. FIRE FIGHTING MEASURES

Flammable Properties: Can burn in fire, releasing toxic vapors. Material is not classified as flammable according to GHScriteria.Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear.Extinguishing Media: Carbon dioxide Dry chemical. Water.Extinguishing Media NOT To Be Used: Not applicableFire / Explosion Hazards: May react violently with: strong oxidizersHazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide.

_____________________________________________________________________________6. ACCIDENTAL RELEASE MEASURES

Spill Response Notice:Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill

according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance.Containment Technique: Stop spilled material from being released to the environment.Clean-up Technique: If permitted by regulation, Scoop up spilled material into a large beaker and dissolve with water.Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drainwith a large excess of water. Decontaminate the area of the spill with a soap solution. Otherwise, Pick up spill for disposaland place in a closed container Dispose of in accordance with local, state and federal regulations or laws.Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of theevacuation.DOT Emergency Response Guide Number: Not applicable

_____________________________________________________________________________7. HANDLING AND STORAGE

Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain general industrialhygiene practices when using this product.Storage: Keep away from: oxidizers

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Flammability Class: Not applicable_____________________________________________________________________________8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls: Maintain general industrial hygiene practices when using this product.Personal Protective Equipment:

Eye Protection: safety glasses with top and side shieldsSkin Protection: disposable latex gloves lab coatInhalation Protection: adequate ventilation

Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Wash thoroughly after handling. Keep awayfrom: oxidizersTLV: Not establishedPEL: Not establishedFor Occupational Exposure Limits (OEL) for ingredients, see section 3 - Composition/Information on Ingredients.:

_____________________________________________________________________________9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: White to light yellow crystalsPhysical State: SolidMolecular Weight: Not applicableOdor: SweetOdor Threshold: Not availablepH: 5% solution = 2.3Metal Corrosivity:

Corrosivity Classification: Not classified as corrosive to metals according to GHS criteria.Steel: Not determinedAluminum: Not determined

Specific Gravity/ Relative Density (water = 1; air =1): 1.65Viscosity: Not determinedSolubility:

Water: SolubleAcid: Not determinedOther: Soluble in alcohol, glycerol

Partition Coefficient (n-octanol / water): Not applicableCoefficient of Water / Oil: Not applicableMelting Point: 192 °C (378 °F)Decomposition Temperature: Not determinedBoiling Point: Not applicableVapor Pressure: Not applicableVapor Density (air = 1): Not applicableEvaporation Rate (water = 1): Not applicableVolatile Organic Compounds Content: Not applicableFlammable Properties: Can burn in fire, releasing toxic vapors. Material is not classified as flammable according to GHScriteria.Flash Point: Not applicable

Method: Not applicableFlammability Limits:

Lower Explosion Limits: Not applicableUpper Explosion Limits: Not applicable

Autoignition Temperature: Not availableExplosive Properties:

Not classified according to GHS criteria.Oxidizing Properties:

Not classified according to GHS criteria.Reactivity Properties:

Not classifed as self-reactive, pyrophoric, self-heating or emitting flammable gases in contact with water according toGHS criteria.Gas under Pressure:Not classified according to GHS criteria.Not applicable

_____________________________________________________________________________

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10. STABILITY AND REACTIVITY

Chemical Stability: Stable when stored under proper conditions.Mechanical Impact: None reportedStatic Discharge: None reported.Reactivity / Incompatibility: Incompatible with: oxidizers alkalies copper ironHazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.Conditions to Avoid: Excess moisture

_____________________________________________________________________________11. TOXICOLOGICAL INFORMATION

Toxicokinetics, Metabolism and Distribution: No information available for mixture.Toxicologically Synergistic Products: None reportedAcute Toxicity: Acute Toxicity Estimate (ATE) - Calculated from Ingredient Toxicity DataATE Oral Rat LD50 = 11901 mg/kg

Specific Target Organ Toxicity - Single Exposure (STOT-SE): Based on classification principles, the classificationcriteria are not met.Specific Target Organ Toxicity - Repeat Exposure (STOT-RE): Based on classification principles, the classificationcriteria are not met.Skin Corrosion/Irritation: Based on classification principles, the classification criteria are not met.Eye Damage: Based on classification principles, the classification criteria are not met.Sensitization: Based on classification principles, the classification criteria are not met.CMR Effects/Properties (carcinogenic, mutagenic or toxic to reproduction): No germ cell mutagenicity, carcinogenicityor reproductive toxicity data found.

IARC Listed: NoNTP Listed: NoO.S.H.A. Listed: No

Symptoms/Effects:Ingestion: Very large doses may cause: gastrointestinal tract irritation diarrheaInhalation: No effects anticipatedSkin Absorption: No effects anticipatedChronic Effects: No effects anticipated

Medical Conditions Aggravated: None reported_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: No information available on this product.Ingredient Ecological Information: No ingredient information available.CEPA statement: Ascorbic Acid: Not Persistent, bioaccumulative or inherently toxic to aquatic organisms.CEPA statement: Magnesium Sulfate: Persistent, not bioaccumulative or inherently toxic to aquatic organisms.

_____________________________________________________________________________13. DISPOSAL CONSIDERATIONS

EPA Waste ID Number: Not applicableSpecial Instructions (Disposal): Work in an approved fume hood. Dilute to 3 to 5 times the volume with cold water.Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Open cold water tap completely,slowly pour the reacted material to the drain. Allow cold water to run for 5 minutes to completely flush the system.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normal trash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemicaland analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging mustbe disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.

_____________________________________________________________________________14. TRANSPORT INFORMATION

D.O.T.:D.O.T. Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NA

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ID Number: NAPacking Group: NA

T.D.G.:Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NAUN Number/PIN: NAPacking Group: NA

I.C.A.O.:I.C.A.O. Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NAID Number: NAPacking Group: NA

I.M.O.:Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NAID Number: NAPacking Group: NA

Additional Information: There is a possibility that this product could be contained in a reagent set or kit composed ofvarious compatible dangerous goods. If the item is NOT in a set or kit, the classification given above applies. If the item ISpart of a set or kit, the classification would change to the following: UN3316 Chemical Kit, Class 9, PG II or III. If the itemis not regulated, the Chemical Kit classification does not apply.

_____________________________________________________________________________15. REGULATORY INFORMATION

U.S. Federal Regulations:O.S.H.A.: This product does not meet the criteria for a hazardous substance as defined in the Hazard CommunicationStandard. (29 CFR 1910.1200)E.P.A.:

S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): This product is not hazardous under 29CFR.1910.1200 and therefore is not covered by Title III under SARA.S.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject to the reportingrequirements of Section 313 of Title III of SARA.--

302 (EHS) TPQ (40 CFR 355): Not applicable304 CERCLA RQ (40 CFR 302.4): Not applicable304 EHS RQ (40 CFR 355): Not applicableClean Water Act (40 CFR 116.4): Not applicableRCRA: Contains no RCRA regulated substances.

State Regulations:California Prop. 65: No Prop. 65 listed chemicals are present in this product.Identification of Prop. 65 Ingredient(s): NoneCalifornia Perchlorate Rule CCR Title 22 Chap 33: Not applicableTrade Secret Registry: Not applicable

National Inventories:U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).

CAS Number: Not applicableCanadian Inventory Status: All ingredients of this product are DSL Listed.EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.Australian Inventory (AICS) Status: All ingredients are listed.New Zealand Inventory (NZIoC) Status: All components either listed or exempt.Korean Inventory (KECI) Status: All components of this product are either listed, listed as the anhydrous compound orexempt.Japan (ENCS) Inventory Status: Some ingredients are not listed or exempt.China (PRC) Inventory (MEP) Status: All components either listed or exempt.

_____________________________________________________________________________

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16. OTHER INFORMATION

References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for1992-1993. American Conference of Governmental Industrial Hygienists, 1992. The Merck Index, 11th Ed. Rahway,New Jersey: Merck and Co., Inc., 1989. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York:Van Nostrand Reinhold Co., 1989. Gosselin, R. E. et al. Clinical Toxicology of Commercial Products, 5th Ed. Baltimore:The Williams and Wilkins Co., 1984. Vendor Information. In-house information. Technical Judgment.Complete Text of H phrases referred to in Section 3: Not applicableRevision Summary: . . Substantial revision to comply with EU Reg 1272/2008, Reg 1907/2006 and UN GHS (ST/SG/AC.10/36/Add.3).Date of MSDS Preparation:

Day: 24Month: JuneYear: 2014

MSDS Prepared: MSDS prepared by Product Compliance Department extension 3350CCOHS Evaluation Note: It is offered under exemption from WHMIS labeling as specified in the Controlled ProductsRegulation (CPR) Section 17. It is offered under the interim policy that was established by Health Canada permitting useof GHS-formatted safety data sheets in Canada prior to revision of CPR to GHS. This product has been classified andlabeled in accordance with the requirements of GHS (ST/SG/AC.10/36/Add.3). This SDS has been prepared in accordancewith the requirements of GHS (ST/SG/AC.10/36/Add.3).

_____________________________________________________________________________

Legend:NA - Not Applicable w/w - weight/weightND - Not Determined w/v - weight/volumeNV - Not Available v/v - volume/volume

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safetyprograms in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATAOR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.

HACH COMPANY ©2015

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World HeadquartersHach CompanyP.O.Box 389 MSDS No: M00388Loveland, CO USA 80539(970) 669-3050

SAFETY DATA SHEET_____________________________________________________________________________1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: PAN Indicator Solution 0.1%Catalog Number: 2122426

Hach Company Emergency Telephone Numbers:P.O.Box 389 (Medical and Transportation)Loveland, CO USA 80539 (303) 623-5716 24 Hour Service(970) 669-3050 (515)232-2533 8am - 4pm CST

MSDS Number: M00388Chemical Name: Not applicableCAS Number: Not applicableAdditional CAS No. (for hydrated forms): Not applicableChemical Formula: Not applicableChemical Family: Not applicableIntended Use: Laboratory Reagent Determination of manganese

_____________________________________________________________________________2. HAZARDS IDENTIFICATION

GHS Classification:Hazard categories: . Reproductive Toxicity: Repr. 1B Serious Eye Damage/Eye Irritation: Eye Dam. 1 .

GHS Label Elements:DANGER

Hazard statements: May damage the unborn child. . Causes serious eye damage. May damage the unborn child.Suspected of damaging fertility. .Precautionary statements: Wear protective gloves / protective clothing / eye protection / face protection. IF ON SKIN:Wash with plenty of soap and water. Immediately call a POISON CENTER or doctor/physician. Obtain specialinstructions before use. Wear eye protection. IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention.Dispose of contents/container according to state, local, federal or national regulations.

HMIS:Health: 1*

Flammability: 1Reactivity: 0Protective Equipment: X - See protective equipment, Section 8.

NFPA:Health: 2Flammability: 1Reactivity: 0Symbol: Not applicable

WHMIS Hazard Classification: Class D, Division 2, Subdivision A - Very toxic materials (other toxic effects)WHMIS Symbols: Other Toxic Effects

_____________________________________________________________________________3. COMPOSITION / INFORMATION ON INGREDIENTS

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Hazardous Components according to GHS:N,N-Dimethylformamide

CAS Number: 68-12-2 Chemical Formula: C3H7NOGHS Classification: Flam. Liq. 3, H226; Acute Tox. 5 -Orl, H303; Acute Tox. 4 -Derm, H312; Acute Tox. 4 -Inh,H332; Eye Irrit. 2, H319; Repr. 1B, H360D;Percent Range (Trade Secret): 25.0 - 30.0Percent Range Units: weight / weightPEL: 10 ppm (skin)TLV: 10 ppm (skin)

WHMIS Symbols: Flammable / CombustibleOther Toxic EffectsOctylphenoxypolyethoxyethanol

CAS Number: 9036-19-5 Chemical Formula: (C2H4O)nC14H22OGHS Classification: Acute tox. 5 - Orl, H303; Eye Dam. 1, H318Percent Range (Trade Secret): 5.0 - 15.0Percent Range Units: weight / volumePEL: Not establishedTLV: Not established

WHMIS Symbols: Other Toxic EffectsHazardous Components according to GHS: No

Demineralized Water

CAS Number: 7732-18-5 Chemical Formula: H2OGHS Classification: Not a dangerous substance according to GHS.Percent Range (Trade Secret): 35.0 - 45.0Percent Range Units: volume / volumePEL: Not establishedTLV: Not established

WHMIS Symbols: Not applicableAmmonium Acetate

CAS Number: 631-61-8 Chemical Formula: CH3COONH4

GHS Classification: Not a dangerous substance according to GHS.Percent Range (Trade Secret): 15.0 - 25.0Percent Range Units: weight / weightPEL: Not establishedTLV: Not established

WHMIS Symbols: Not applicablePyridylazo Naphthol

CAS Number: 85-85-8 Chemical Formula: C15H11N3OGHS Classification: Not a dangerous substance according to GHSPercent Range (Trade Secret): < 0.1Percent Range Units: weight / weightPEL: Not establishedTLV: Not established

WHMIS Symbols: Not applicable_____________________________________________________________________________4. FIRST AID MEASURES

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General Information: In the event of exposure, show this Material Safety Data Sheet and label (where possible) to adoctor.Advice to doctor: Treat symptomatically.Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.Skin Contact (First Aid): Remove contaminated clothing. Wash skin with plenty of water for 15 minutes. Call physicianimmediately.Inhalation: Remove to fresh air. Give artificial respiration if necessary. If breathing is difficult, give oxygen. Callphysician.Ingestion (First Aid): Give a slurry of powdered activated charcoal. Induce vomiting using syrup of ipecac or by stickingfinger down throat. Never give anything by mouth to an unconscious person. Call physician immediately.

_____________________________________________________________________________5. FIRE FIGHTING MEASURES

Flammable Properties: Can burn in fire, releasing toxic vapors.Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear.Extinguishing Media: Water. Alcohol foam. Dry chemical. Carbon dioxideExtinguishing Media NOT To Be Used: Not determinedFire / Explosion Hazards: May react violently with: nitric acid metal nitrates strong oxidizers alkali metalsHazardous Combustion Products: Toxic fumes of: dimethylamine nitrogen oxides. carbon monoxide, carbon dioxide.

_____________________________________________________________________________6. ACCIDENTAL RELEASE MEASURES

Spill Response Notice:Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill

according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only personsproperly qualified according to state or local regulations should respond to a spill involving chemicals.Containment Technique: Releases of this material may contaminate the environment. Dike the material to create a barrierto combustibles.Clean-up Technique: Do not breathe the fumes. If permitted by regulation, Absorb spilled liquid with non-reactivesorbent material. Incinerate material at a government approved hazardous waste facility. Decontaminate the area of thespill with a soap solution. Otherwise, Pick up spill for disposal and place in a closed container Dispose of in accordancewith local, state and federal regulations or laws.Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan) when:any quantity is spilled.DOT Emergency Response Guide Number: Not applicable

_____________________________________________________________________________7. HANDLING AND STORAGE

Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling.Maintain general industrial hygiene practices when using this product.Storage: Keep away from: acids oxidizers alkali metals halogens Store between 10° and 25°C. Protect from: heatFlammability Class: Not applicable

_____________________________________________________________________________8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls: Maintain adequate ventilation to keep vapor level below TWA for chemicals in this product.Maintain general industrial hygiene practices when using this product.Personal Protective Equipment:

Eye Protection: chemical splash gogglesSkin Protection: lab coat neoprene latex gloves In the EU, the selected gloves must satisfy the specifications of EUDirective 89/686/EEC and standard EN 374 derived from it.Inhalation Protection: laboratory fume hood

Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly afterhandling. Protect from: heat Keep away from: acids/acid fumes alkali metals oxidizersTLV: Not establishedPEL: Not establishedFor Occupational Exposure Limits (OEL) for ingredients, see section 3 - Composition/Information on Ingredients.:

_____________________________________________________________________________

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9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Clear, red-orange liquidPhysical State: LiquidMolecular Weight: Not applicableOdor: AmmoniaOdor Threshold: Not availablepH: 8.0Metal Corrosivity:

Corrosivity Classification: Not classified as corrosive to metals according to GHS criteria.Steel: Not determinedAluminum: Not determined

Specific Gravity/ Relative Density (water = 1; air =1): 1.044Viscosity: Not determinedSolubility:

Water: MiscibleAcid: MiscibleOther: Not determined

Partition Coefficient (n-octanol / water): Not applicableCoefficient of Water / Oil: Not applicableMelting Point: Not determinedDecomposition Temperature: Not determinedBoiling Point: 101°C; 214°FVapor Pressure: Not availableVapor Density (air = 1): Not availableEvaporation Rate (water = 1): 0.25Volatile Organic Compounds Content: Not availableFlammable Properties: Can burn in fire, releasing toxic vapors.Flash Point: >93°C; >200°F

Method: Closed cupFlammability Limits:

Lower Explosion Limits: Not availableUpper Explosion Limits: Not available

Autoignition Temperature: Not availableExplosive Properties:Not classified according to GHS criteria.

Oxidizing Properties:Not classified according to GHS criteria.

Reactivity Properties:Not classifed as self-reactive, pyrophoric, self-heating or emitting flammable gases in contact with water according to GHS

criteria.Gas under Pressure:Not classified according to GHS criteria.Not applicable

_____________________________________________________________________________10. STABILITY AND REACTIVITY

Chemical Stability: Stable when stored under proper conditions.Mechanical Impact: None reportedStatic Discharge: None reported.Reactivity / Incompatibility: Incompatible with: nitric acid metal nitrates halogens alkali metals oxidizersHazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: nitrogen oxides carbondioxide carbon monoxideConditions to Avoid: Heat Heating to decomposition.

_____________________________________________________________________________11. TOXICOLOGICAL INFORMATION

Toxicokinetics, Metabolism and Distribution: No information available for mixture.Toxicologically Synergistic Products: Exposure to and/or consumption of alcohol may increase toxic effects of thisproduct.Acute Toxicity: Acute Toxicity Estimate (ATE) - Calculated from Ingredient Toxicity Data

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ATE Oral Rat LD50 = 8277 mg/kgATE Dermal Rat LD50 = 3577 mg/kgATE inhalation Rat LC50 = 21.8 mg/l

Specific Target Organ Toxicity - Single Exposure (STOT-SE): Based on classification principles, the classification criteriaare not met.Specific Target Organ Toxicity - Repeat Exposure (STOT-RE): Based on classification principles, the classificationcriteria are not met.Skin Corrosion/Irritation: Based on classification principles, the classification criteria are not met.DMF: Skin human 100%/24H - Standard Draize Test - MILD

Eye Damage: Corrosive to eyes.DMF: Eye rabbit 100 mg - Rinsed Draize Test - SEVERE; Octylphenoxypolyethoxyethanol: Eye rabbit 1% SEVERE

Sensitization: Based on classification principles, the classification criteria are not met.CMR Effects/Properties (carcinogenic, mutagenic or toxic to reproduction): Contains a reproductive toxin.DMF: Cytogenetic analysis-hmn-inh-12300 µg/m3/Y; Cytogenetic analysis-hmn lymphocytes-100nmol/l;

Octylphenoxypolyethoxyethanol: DNA inhibition-hmn lymphocytes 5 ppmDMF: Inh rat TCLo=4mg/m3/4H 1-19d post-conception-Pre-implantation mortality, fetotoxicity, embryo death; Skin rat

TDLo=7552mg/kg 6-15d post-conception-fetotoxicity; oral mouse TDLo = 1820mg/kg 6-15d post-conception-fetotoxicityAn ingredient of this mixture is: IARC Group 3: Non-classifiableDimethylformamideThis product does NOT contain any NTP listed chemicals.This product does NOT contain any OSHA listed carcinogens.

Symptoms/Effects:Ingestion: May cause: abdominal pain nausea vomiting diarrhea blood pressure problems kidney damage liverdamageInhalation: Harmful Effects similar to those of ingestion. May cause: respiratory tract irritationSkin Absorption: Harmful if absorbed through the skin May cause kidney damage May cause liver damage May causenausea May cause vomitingChronic Effects: Dimethylformamide is capable of producing cumulative systemic injury when repeatedly inhaled orabsorbed through the skin. Chronic overexposure may cause kidney damage liver damage

Medical Conditions Aggravated: Pre-existing: Liver conditions Kidney conditions_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: No product ecological information available.Mobility in soil: No data available

Ingredient Ecological Information: Octylphenoxypolyethoxyethanol - Bluegill sunfish (Lepomis macrochirus), 96 hourdynamic: > 10 mg/lCEPA statement: Octylphenoxypolyethoxyethanol: Inherently toxic to aquatic organisms, not persistent or

bioaccumulative; N,N-Dimethylformamide: Persistent, not inherently toxic to aquatic organisms or bioaccumulative._____________________________________________________________________________13. DISPOSAL CONSIDERATIONS

EPA Waste ID Number: Not applicableSpecial Instructions (Disposal): Dispose of material in an E.P.A. approved hazardous waste facility.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normal trash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemicaland analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging mustbe disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.

_____________________________________________________________________________14. TRANSPORT INFORMATION

D.O.T.:D.O.T. Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NAID Number: NAPacking Group: NA

T.D.G.:Proper Shipping Name: Not Currently Regulated

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--Hazard Class: NASubsidiary Risk: NAUN Number/PIN: NAPacking Group: NA

I.C.A.O.:I.C.A.O. Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NAID Number: NAPacking Group: NA

I.M.O.:Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NAID Number: NAPacking Group: NA

Additional Information: There is a possibility that this product could be contained in a reagent set or kit composed ofvarious compatible dangerous goods. If the item is NOT in a set or kit, the classification given above applies. If the item ISpart of a set or kit, the classification would change to the following: UN3316 Chemical Kit, Class 9, PG II or III. If the itemis not regulated, the Chemical Kit classification does not apply.

_____________________________________________________________________________15. REGULATORY INFORMATION

U.S. Federal Regulations:O.S.H.A.: This product meets the criteria for a hazardous substance as defined in the Hazard Communication Standard.(29 CFR 1910.1200)E.P.A.:

S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): Immediate (Acute) Health Hazard Delayed(Chronic) Health HazardS.A.R.A. Title III Section 313 (40 CFR 372): This product contains a chemical(s) subject to the reportingrequirements of Section 313 of Title III of SARA.302 (EHS) TPQ (40 CFR 355): Not applicable304 CERCLA RQ (40 CFR 302.4): Ammonium acetate 5000 lbs. Dimethylformamide 1 lb.304 EHS RQ (40 CFR 355): Not applicableClean Water Act (40 CFR 116.4): Ammonium acetate - RQ 5000 lbs.RCRA: Contains no RCRA regulated substances.

State Regulations:California Prop. 65: No Prop. 65 listed chemicals are present in this product.Identification of Prop. 65 Ingredient(s): NoneCalifornia Perchlorate Rule CCR Title 22 Chap 33: Not applicableTrade Secret Registry: Not applicable

National Inventories:U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).

CAS Number: Not applicableCanadian Inventory Status: All ingredients of this product are DSL Listed.EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.Australian Inventory (AICS) Status: All ingredients are listed.New Zealand Inventory (NZIoC) Status: All components either listed or exempt.Korean Inventory (KECI) Status: All components of this product are either listed, listed as the anhydrous compound orexempt.Japan (ENCS) Inventory Status: All components either listed or exempt.China (PRC) Inventory (MEP) Status: All components either listed or exempt.

_____________________________________________________________________________16. OTHER INFORMATION

References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). TLV's Threshold Limit Values and BiologicalExposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992. Air Contaminants,Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. CCINFO RTECS. Canadian Centre for

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Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. Gosselin, R. E. et al. Clinical Toxicology ofCommercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. IARC Monographs on the Evaluation ofthe Carcinogenic Risks to Humans. World Health Organization (Volumes 1-42) Supplement 7. France: 1987. List ofDangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling ofDangerous Substances, Amended July 1992. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. NewYork: Van Nostrand Reinhold Co., 1989. Vendor Information. In-house information. Technical Judgment.Complete Text of H phrases referred to in Section 3: H226 Flammable liquid and vapour. Not applicable H312 Harmfulin contact with skin. H332 Harmful if inhaled. H318 Causes serious eye damage. H319 Causes serious eye irritation.H360D May damage the unborn child.Revision Summary: . Updates in Section(s) 6, 13,Date of MSDS Preparation:

Day: 22Month: JulyYear: 2015

MSDS Prepared: MSDS prepared by Product Compliance Department extension 3350CCOHS Evaluation Note: It is offered under exemption from WHMIS labeling as specified in the Controlled ProductsRegulation (CPR) Section 17. It is offered under the interim policy that was established by Health Canada permitting useof GHS-formatted safety data sheets in Canada prior to revision of CPR to GHS. This product has been classified andlabeled in accordance with the requirements of GHS (ST/SG/AC.10/36/Add.3). This SDS has been prepared in accordancewith the requirements of GHS (ST/SG/AC.10/36/Add.3).

_____________________________________________________________________________

Legend:NA - Not Applicable w/w - weight/weightND - Not Determined w/v - weight/volumeNV - Not Available v/v - volume/volume

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safetyprograms in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATAOR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.

HACH COMPANY ©2015

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World HeadquartersHach CompanyP.O.Box 389 MSDS No: M00350Loveland, CO USA 80539(970) 669-3050

SAFETY DATA SHEET_____________________________________________________________________________1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Deionized (Demineralized) WaterCatalog Number: 27242

Hach Company Emergency Telephone Numbers:P.O.Box 389 (Medical and Transportation)Loveland, CO USA 80539 (303) 623-5716 24 Hour Service(970) 669-3050 (515)232-2533 8am - 4pm CST

MSDS Number: M00350Chemical Name: Deionized (Demineralized) WaterCAS Number: 7732-18-5Additional CAS No. (for hydrated forms): Not applicableChemical Formula: H2OChemical Family: Not applicableIntended Use: Laboratory reagent Analytical reagent Standard solution Solvent

_____________________________________________________________________________2. HAZARDS IDENTIFICATION

This substance is not classified as hazardous per GHS (UN publication ST/SG/AC.10/36/Add.3)GHS Classification:

Hazard categories: Not applicableGHS Label Elements:Not applicable

Hazard statements: Not applicablePrecautionary statements: Not applicable

HMIS:Health: 0Flammability: 0Reactivity: 0Protective Equipment: X - See protective equipment, Section 8.

NFPA:Health: 0Flammability: 0Reactivity: 0Symbol: Not applicable

WHMIS Hazard Classification: Not applicableWHMIS Symbols: Not applicable

_____________________________________________________________________________3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Components according to GHS: NoDemineralized Water

CAS Number: 7732-18-5 Chemical Formula: H2OGHS Classification: Not a dangerous substance according to GHS.Percent Range (Trade Secret): 100.0Percent Range Units: weight / weight

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PEL: Not establishedTLV: Not established

WHMIS Symbols: Not applicable_____________________________________________________________________________4. FIRST AID MEASURES

General Information: Not applicableAdvice to doctor: Not applicableEye Contact: Not applicableSkin Contact (First Aid): Not applicableInhalation: Not applicableIngestion (First Aid): Not applicable

_____________________________________________________________________________5. FIRE FIGHTING MEASURES

Flammable Properties: Material will not burn.Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear. Evacuate area and fight fire from a safe distance.Extinguishing Media: Use media appropriate to surrounding fire conditionsExtinguishing Media NOT To Be Used: Not applicableFire / Explosion Hazards: None reportedHazardous Combustion Products: This material will not burn.

_____________________________________________________________________________6. ACCIDENTAL RELEASE MEASURES

Spill Response Notice:Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill

according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only personsproperly qualified according to state or local regulations should respond to a spill involving chemicals.Containment Technique: Not applicableClean-up Technique: Not applicableEvacuation Procedure: Not applicableDOT Emergency Response Guide Number: Not applicable

_____________________________________________________________________________7. HANDLING AND STORAGE

Handling: Maintain general industrial hygiene practices when using this product.Storage: Not applicableFlammability Class: Not applicable

_____________________________________________________________________________8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls: Maintain general industrial hygiene practices when using this product.Personal Protective Equipment:

Eye Protection: Not applicableSkin Protection: Not applicableInhalation Protection: Not applicable

Precautionary Measures: Not applicableTLV: Not establishedPEL: Not establishedFor Occupational Exposure Limits (OEL) for ingredients, see section 3 - Composition/Information on Ingredients.:

_____________________________________________________________________________9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Colorless liquid Aerosol can Amber yellow liquidPhysical State: LiquidMolecular Weight: 18.02

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Odor: OdorlessOdor Threshold: Not applicablepH: 7Metal Corrosivity:

Corrosivity Classification: Not classified as corrosive to metals according to GHS criteria.Steel: NONEAluminum: None

Specific Gravity/ Relative Density (water = 1; air =1): 1Viscosity: Dynamic = 1.0 mPa*s at 20 °C (68 °F); Kinematic = 1.0 mm2/s at 20 °C (68 °F)Solubility:

Water: MiscibleAcid: MiscibleOther: Soluble in most polar solvents.

Partition Coefficient (n-octanol / water): Not applicableCoefficient of Water / Oil: Not applicableMelting Point: 0 ºC (32 ºF)Decomposition Temperature: > 2000 °C (> 3632 °F)Boiling Point: 100 ºC (212 ºF)Vapor Pressure: 23.8 mm Hg @ 25 °C (77 °F)Vapor Density (air = 1): 0.62Evaporation Rate (water = 1): 1Volatile Organic Compounds Content: Not applicableFlammable Properties: Material will not burn.Flash Point: Not applicable

Method: Not applicableFlammability Limits:

Lower Explosion Limits: Not applicableUpper Explosion Limits: Not applicable

Autoignition Temperature: Not applicableExplosive Properties:

Not classified according to GHS criteria.Oxidizing Properties:

Not classified according to GHS criteria.Reactivity Properties:

Not classifed as self-reactive, pyrophoric, self-heating or emitting flammable gases in contact with water according toGHS criteria.Gas under Pressure:Not classified according to GHS criteria.

_____________________________________________________________________________10. STABILITY AND REACTIVITY

Chemical Stability: Stable when stored under proper conditions.Mechanical Impact: None reportedStatic Discharge: None reported.Reactivity / Incompatibility: None reportedHazardous Decomposition: None reportedConditions to Avoid: Not applicable

_____________________________________________________________________________11. TOXICOLOGICAL INFORMATION

Toxicokinetics, Metabolism and Distribution: Not applicableToxicologically Synergistic Products: None reportedAcute Toxicity: Based on classification principles, the classification criteria are not met.Specific Target Organ Toxicity - Single Exposure (STOT-SE): Based on classification principles, the classificationcriteria are not met.Specific Target Organ Toxicity - Repeat Exposure (STOT-RE): Based on classification principles, the classificationcriteria are not met.Skin Corrosion/Irritation: Based on classification principles, the classification criteria are not met.Eye Damage: Based on classification principles, the classification criteria are not met.Sensitization: Based on classification principles, the classification criteria are not met.

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CMR Effects/Properties (carcinogenic, mutagenic or toxic to reproduction): No germ cell mutagenicity, carcinogenicityor reproductive toxicity data found.

IARC Listed: NoNTP Listed: NoO.S.H.A. Listed: No

Symptoms/Effects:Ingestion: No Effects AnticipatedInhalation: No effects anticipatedSkin Absorption: No effects anticipatedChronic Effects: No effects anticipated None reported

Medical Conditions Aggravated: None reported_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: --No ecological data available for this product. Mobility in soil: Highly mobile Based on classification principles, not

classified as hazardous to the environment.CEPA Categorization: Persistent, not bioaccumulative or inherently toxic to aquatic organisms.

Ingredient Ecological Information: --Not applicable

_____________________________________________________________________________13. DISPOSAL CONSIDERATIONS

EPA Waste ID Number: Not applicableSpecial Instructions (Disposal): Not applicableEmpty Containers: Dispose of empty container as normal trash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemicaland analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging mustbe disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.

_____________________________________________________________________________14. TRANSPORT INFORMATION

D.O.T.:D.O.T. Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: Not applicableID Number: NAPacking Group: Not applicable

T.D.G.:Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: Not applicableUN Number/PIN: Not applicablePacking Group: NA

I.C.A.O.:I.C.A.O. Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: Not applicableID Number: Not applicablePacking Group: NA

I.M.O.:Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: Not applicableID Number: Not applicablePacking Group: NA

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Additional Information: There is a possibility that this product could be contained in a reagent set or kit composed ofvarious compatible dangerous goods. If the item is NOT in a set or kit, the classification given above applies.

_____________________________________________________________________________15. REGULATORY INFORMATION

U.S. Federal Regulations:O.S.H.A.: This product does not meet the criteria for a hazardous substance as defined in the Hazard CommunicationStandard. (29 CFR 1910.1200)E.P.A.:

S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): This product is not hazardous under 29CFR.1910.1200 and therefore is not covered by Title III under SARA.S.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject to the reportingrequirements of Section 313 of Title III of SARA.--

302 (EHS) TPQ (40 CFR 355): Not applicable304 CERCLA RQ (40 CFR 302.4): Not applicable304 EHS RQ (40 CFR 355): Not applicableClean Water Act (40 CFR 116.4): Not applicableRCRA: Not applicable

State Regulations:California Prop. 65: Not applicableIdentification of Prop. 65 Ingredient(s): Not applicableCalifornia Perchlorate Rule CCR Title 22 Chap 33: Not applicableTrade Secret Registry: Not applicable

National Inventories:U.S. Inventory Status: TSCA Listed: Yes

CAS Number: 7732-18-5Canadian Inventory Status: DSL Listed: YesEEC Inventory Status: EINECS Listed: YesAustralian Inventory (AICS) Status: ListedNew Zealand Inventory (NZIoC) Status: ListedKorean Inventory (KECI) Status: ListedJapan (ENCS) Inventory Status: ListedChina (PRC) Inventory (MEP) Status: Listed

_____________________________________________________________________________16. OTHER INFORMATION

References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,No. 12. Thursday, January 19, 1989. pp. 2332-2983. Technical Judgment.Complete Text of H phrases referred to in Section 3: Not applicableRevision Summary: Substantial revision to comply with EU Reg 1272/2008, Reg 1907/2006 and UN GHS (ST/SG/AC.10/36/Add.3).Date of MSDS Preparation:

Day: 28Month: JanuaryYear: 2015

MSDS Prepared: MSDS prepared by Product Compliance Department extension 3350CCOHS Evaluation Note: It is offered under exemption from WHMIS labeling as specified in the Controlled ProductsRegulation (CPR) Section 17. It is offered under the interim policy that was established by Health Canada permitting useof GHS-formatted safety data sheets in Canada prior to revision of CPR to GHS. This product has been classified andlabeled in accordance with the requirements of GHS (ST/SG/AC.10/36/Add.3). This SDS has been prepared in accordancewith the requirements of GHS (ST/SG/AC.10/36/Add.3).

_____________________________________________________________________________

Legend:NA - Not Applicable w/w - weight/weightND - Not Determined w/v - weight/volumeNV - Not Available v/v - volume/volume

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safetyprograms in accordance with applicable hazard communication standards and regulations.

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THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATAOR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.

HACH COMPANY ©2015