17
Copyright is owned by the Author of the thesis. Permission is given for a copy to be downloaded by an individual for the purpose of research and private study only. The thesis may not be reproduced elsewhere without the permission of the Author.

The effect of land disposal of dairy factory wastes on

  • Upload
    others

  • View
    2

  • Download
    0

Embed Size (px)

Citation preview

Page 1: The effect of land disposal of dairy factory wastes on

Copyright is owned by the Author of the thesis. Permission is given for a copy to be downloaded by an individual for the purpose of research and private study only. The thesis may not be reproduced elsewhere without the permission of the Author.

Page 2: The effect of land disposal of dairy factory wastes on

THE EFFECT OF LAND DISPOSAL OF DAIRY FACTORY

WASTES ON SOIL PROPERTIES

A thesis presen ted in partial fulfilment of

the requirements f or t he degree of

Master of Agricultural Science in Soil Science

Massey Univer sity

Keith William NcAuliffe

19 78

Page 3: The effect of land disposal of dairy factory wastes on

(i)

ABSTRACT

Many New Zealand dairy factories dispose of their wastewater by spray

irrigating onto pasture. Little is known , however, about the effects of

this disposal on soil properties. Research was undertaken at three pasture

disposal sites in order t o determine whether certain soil property changes

may have occurred as a result of t he wastewater treatment.

interest were those properties related to water movement.

Of pa,rticular

Laboratory studies using ' undisturbed ' soil cor es indicated that dairy

factory wastewate r can i mpede soil water movement. A single application

of simulated whey effluent resulted in approxima tely a 50% decrea se in

saturated hydraulic conductivity (K) within two days . This r eduction was

observed to be caused by a combina tion of both phys i cal and biological block-

age processes. With r epetitive doses of effluent a K decrease of over 99%

was induced in some cores . Sever al cores, particularly those containing

earthworms, showed signs of recovery, and in some co r es the fina l hydraulic

conductivity value was gr eater than the initial val ue.

Analyses of soil samples f r om the disposal and cont r ol sites at

Te Rehunga and Tokomaru suggest that fifteen years of wastewater irrigation

have resulted in marked c hanges in soil physical , chemical and biological

properties. Total carbon and nitrogen levels were found to be significantly

higher at the disposal site ; for the Te Rehunga s i te, the differences in

the organic matter l evel down to 600mrn represented an increase of 250 000

kg ha-l

Water balances for the Te Rehunga and Longburn sites indicate that,

in the absence of wastewater, pasture is likely t o be water stressed on

average for approximately forty days per year. The water balance also

shows that deep percolation will be gre~tly increa~ed by the wastewater

application. The period of maximum deep percolation loss is likely to

be September to October at both the Te Rehunga and Longburn disposal sites .

Page 4: The effect of land disposal of dairy factory wastes on

(ii)

The major site management problems encountered at the disposal sites

examined occurred as a result of poor soil drainage, pasture burning and

pasture pulling. An infiltration problem was observed at the Longburn

site and the recently established disposal site at Tokomaru, with two

major causes of the low infiltration rate appea ring to be blockage from

the effluent and pugging; these observations illustrate the need for

controlling the effluent application rate, the suspended solids level in the

wastewater, and the stock grazing pattern, in order to minimise site

drainage problems. A drainage problem over the winter-spring period at

Te Rehunga was due to a high groundwater table. Pasture burning was

observed at all three disposal sites. The pasture pulling problem at

Te Rehunga is the only cited example of such a problem occurring at a

dairy factory disposal site.

Observations made at the established Te Rehunga and Tokomaru disposal

sites show that long term spray irrigation of dairy factory wastewater can

occur without inducing undesirable soil property changes. It appears as

though considerable benefit can be gained ~ram the wastewater irrigation,

particularly in reducing the incidenc e of water stress in the pasture and

decreasing the requirement for fertilizer.

Page 5: The effect of land disposal of dairy factory wastes on

ACKNOWLEDGEMENTS

I wish to express my thanks to my supervisors, Dr Dave Scatter,

Dr Neil Macgregor and Kevin Earl for their guidance and friendship

during all stages of my wo rk . I would a lso like to thank the Dairy

(iii)

Research Institute for finan c ia l a ssistance throughout my work. Thanks

also to Mr Lindsay Jamieson for assistanc e and advice with the illus trations.

To my wife Amanda, thanks for the encourag emen t given throughout my

masterate.

For the typing I wish t o thank Jud y McKegg .

Page 6: The effect of land disposal of dairy factory wastes on

TABLE OF CONTENTS

ABSTRACT ....

ACKNOWLEDGEMENTS

TABLE OF CONTENTS

LIST OF FIGURES

LIST OF TABLES .

CHAPTER ONE

INTRODUCTION . . . . . . . .

CHAPTER mo

SITE DESCRIPTIONS

2.1 The Te Rehunga Dispos a l Site

2.2 The Long burn Disposa l Sit e

2.3 The Tokomaru DisposaJ Sit e

2 .4 The Tokomaru Silt Loam

2.5 The Manawa tu Silt Loam

CHAPTER TH REE

METHODS OF SOIL ANALYSIS .

3.1 Detennina t ion of Soil Phy s i ca l Properties

3.1.1 Bulk density .

3.1.2 Particle densit y

3.1.3 Water retention properties of th e soil

3.1.4 Laboratory measurement of hydraulic conductivity

3.1.5 Field measurement of infiltration

3.1.6 Dye tracing of soil macropor es ..

3.2 Determination of Soil Chemical Properties

3.2.1 Organic carbon

3.2.2 Total nitrogen

3.2.3 Ammonium and nitrate

3.2.4 Mineralisable nitrogen

(iv)

Page ( i)

. (iii)

• (iv)

(x)

.. (x iv )

l

6

6

6

6

7

7

8

8

8

8

8

9

11

11

11

11

12

12

12

Page 7: The effect of land disposal of dairy factory wastes on

3.2 . 5 Plant-available phosphorus

3. 2. 6 Soil pH

3. 3 Determination of Soil Biological aw.l Microbiological

Proper t itos

3. 3 . l

3.3.2

Soil microbial respiration

Earthworm numbers

3.4 Determination of Effluent P ropert ie~

3 . 4 . 1 Total and suspended sol id s

3.4.2 Electrica l c0 nduc tivi t y

3.4. 3 Carbohydrate ...

3.4.4 Simulation of whey ~ff]uent

CHAPTER FOUR

SOIL WATER BALANCE STUDIES

4.1 Introduction

4.2 Procedure for the Construction of the Basi.c Suil

Water Balance

4 . 3 Results and Discussion

CHAPTER Fl VE

THE EFFECTS OF DAIRY FACTORY EFFLUENT ON SOI L HYDRAULIC

CONDUCTIVITY .

5.1 Introduction

5.1.1 Reduction in soil saturated hydraulic conduct ivity

following effluent applicalion .

5.1.2 A review of observations made on pore clogging and

of the mechanisms involved ..

5.1.3 The relevanc e of previous work to c l ogging from

dairy factory cff luent . . . .

5.1 . 4 Increases in soil hydrc.1uli- \Onductiv itv

(v)

Page

13

13

13

13

16

16

16

16

16

17

l8

l 'J

21

2 (i

'17

30

33

Page 8: The effect of land disposal of dairy factory wastes on

(vi)

page

5.2 Aims of Permeabilit y Studies . . . . . . . . . . . . . . . . 3L1

5.3 Experimental Design

5.4 Results and Discussion

5.4.l "Undisturbed" soil core reaction to repetitive

applications of simulated whey effluent ..

5.4.2 Changes in saturated hydraulic co nduct i vity following

a single applicat Lon of simulated whey effluent to

5.4.3

5.4.4

"undisturbed cores".

Isolating

Isola ting

the biological blockage mechanism

the physical blockage mechanism .

5.4.5 The extent of blockage as a funct i on of effluent

quality

5.4.6 A study of the increa se in saturated hydraulic

conductivity of "undisturbed" cores .. .

5.4. 7 Use of the "Double Staining Technique" t o study

blockage and recovery of channels in "undisturbed"

cores

5.4.8 Information obtained from field studies

5.4.9 Relevance of the "undisturbed" core studies to the

field situation

5.5 Summary of Results ..

CHAPTER SIX

LONG TERM CHANGES IN SOIL PROPERTIES RESULTING FROM THE APPLICATION

34

35

36

44

49

53

56

60

61

67

68

CF DAIRY FACTORY EFFLUENT . . . . . . . . . . . 70

6.1 Introduction . . . . . . . . . . 70

6.1.l Scope of the study

6.1.2 Plant nutrient effects

6.1.3 Effects on groundwater quality

70

70

72

Page 9: The effect of land disposal of dairy factory wastes on

6.1.4 Gaseous losses to the atruosphere

6.1.5 The nutrient balance

6.1. 6 Soil pH

6.1.7 Soil physical property ~ ha nges

6.1.8 Soil biological prope rt y changes

6.1.9 Conclusion .

6.2 Experimental Design

6.3 Resul ts and Discuss i on

6.3.1 Bulk densit y

6.3.2 Depth of the su rface horizon

6. 3. 3 Soil pH

6.3.4 Soil nitra t e and ammonium

6.3.5 Plant-availabl e phospha t e

6.3.6 Potentially rnin erali sabl e nit r ogen

6.3. 7 Total nitrogen

6.3.8 Organic matter

6.3.9 Earthworm numbers

6 .3. 10 Soil respiration

6. 4 Summary of Results

CHAPTER SEVEN

MANAGEMENT PROBLEMS AT DAIRY FACTORY DISPOS AL SITES

7.1 Introduction

7.2 Soil Drainage

7.2.1 Te Rehunga - A high groundwate r table drainage

problem

(vii)

page

73

74

76

76

76

78

79

79

80

81

82

83

85

86

87

89

91

93

%

98

• 98

98

• 98

7.2.2 Longburn - An infiltration prob] em . 99

7.2.3 Integration of stock managemen t with the disposal

system . . . . .104

Page 10: The effect of land disposal of dairy factory wastes on

(viii)

page

7.3 Pasture Burning 106

7.4 Pasture Pulling 107

7.5 Stock Health 111

7.6 Summary . 112

Page 11: The effect of land disposal of dairy factory wastes on

APPENDIX I

PROFILE DESCRIPTIONS . . . .

APPENDIX II

BASIC DATA AND CALCULATIONS RELATING TO THE WATER BALANCE

STUDIES

A2. 1 Rainfall

A2.2 Evapotranspiration

A2.3 Effluent Application

A2.4 Soil Information ...

APPENDIX III

DERIVATION OF THE RESPIROMETER EQUATION

APPENDIX IV

ADDITIONAL RESPIROMETRY STUDIES AND CARBOHYDRATE ANALYSIS DATA

A4.1 Respirometry Studies

A4.2 Carbohydrate Analysis

APPENDIX V

ANALYSIS OF EFFLUENT SAMPLES

BIBLIOGRAPHY . . . .

(ix)

page

113

115

115

115

11 5

117

12 2

12 3

12J

12 5

128

129

Page 12: The effect of land disposal of dairy factory wastes on

(x)

page

FIG. 3. 1

3.2

4. 1

4.2

The apparatus used to study saturated hydraulic conductivity in the laboratory . . . . . .

The respirometry apparatus ..

Average seasonal runoff for the Te Rehunga site in the presence and absence of the irrigation component

Average season runoff fo r the Longburn site in the presenc e and absence of the irri ga tion component .

4.3 The average number of days per month on which the Te Rehunga site is likely t o be water-st ressed (at the -15 bar and -1 bar l evel) in the absence of irrigation . . .

4.4 The average number of da ys per mo nth on whic h the Longburn sit e is likely t o be water-stressed (at the

10

14

22

23

-15 bar level) in the a bsence of irrigation 23

5.1 Changes of K with time following rep e titive applica­tions of simulat e d effluent to two Tokomaru silt loam (0-lOOmm) cores, with <i wate r only treatment cor e for comparison . . . . . . . . . . . 38

5.2 Changes of K wi th time followin g repe titive applic a tions of simu]at c d ef fJuent to two To koma ru si l t loam (0-100mm ) cores , with il w<.1ter only treatment core for comparison 38

5.3 Changes of K with time folJo win g r epe titive applications of simula ted eff luen t to a Tokomaru silt loam (100-200mm) core, with a water on l y tr eatment core for comparison 39

5.4 Chang es of K with time follow i ng repetitive applications of simulat ed effluent to two Tokomaru silt loam (100-200mm) c or e s, with two wa t er on ly treatment cores for comparison

5.5 Changes of K with time fo llowin g repetitive appli­cations of simulated eff l uent t o two Kopua silt loams (0-lOOmm) co res, with a water only treatment core for

39

comparison . 40

5.6

5.7

5.8

Changes of K with time following repetitive applica­tions of simulated effluent t o two Kopua silt loams (0-lOOmm) cores, with two water only treatment cores for comparison . . ,. . . . . . . . . . . . . . . . •

Changes of K with time following repetitive appli­cations of simulated effluent to two Kopua silt loam (100-200mm) cores, with a water only treatment core for comparison . . . . . . . . . . . . . • . .

Changes of K with time following repetitive appli­ca tions of simulated effluent t o a Kopua silt loam (100-200mm) core, with a water only treatment core for comparison . . . . . . . . . . . . . . . . .

40

4 l

41

Page 13: The effect of land disposal of dairy factory wastes on

FIGURE 5. 9 Changes of K with time following repetitive applications of s i mulated effluent to two Manawatu silt loam (O-lOOmm) cores, with a water only

(xi)

page

treatment core for comparison . . . . . . . . . . . 42

5.10 Changes of K with time following repetitive applications of simulated effluent to a Manawatu silt loam (0-lOOmm) core, with a water only treatment core for comparison . . . ...

5.11 Changes of K with time foll owing a singl e application of simulated effluent to a Tokomaru silt loam (100-200mm) core, with a water only treatment core for comparison

5.12 Changes of K with time following a s ingle application of simulated e ffluent to two Tokomaru silt loam (100-200mm) cores, with a water only treatment core for comparison

5.13 Changes of K with time following a single application

42

45

45

of simulated effluent to three Tokomaru silt loam (O-lOOmm) cores . . . . . . . . . . . . . . . . . . . 46

5.14 Changes of K with time following a single application of simulated effluent to two Kopua silt loam (O-lOOmm) core s, with a water only treatment core for comparison

5. 15 Changes of K with time following two applications of simulated effluent (on days 'O' and '14') to three Tokomaru silt loam (100-200mm) cores, with a water only treatment core for comparison

5.16 Changes of K with time following repetitive applications of simulated effluent and effluent plus inhibitor treatments to Tokomaru silt loam (0-lOOmm) cores .

5.17 Changes of K with time following repetitive applications of simulated effluent plus inhibitor

46

47

so

treatments to Tokomaru silt loam (0-lOOmm) cores 50

5.18 Changes of K with time following repetitive applications of simulated effluent and effluent plus inhibitor treat­ments to Tokomaru silt loam (100-200mm) cores . . . . 51

5.19 Changes of K with time following repetitive applications of simulated effluent and effluent plus inhibitor treatments to Tokomaru silt loam (100-200mm) cores .

5.20 Changes of K with time followin g repetitive applications of simulated effluent and effluent plus inhibitor treatments to Manawa tu silt loam (0-1 OOmm) cores . . . . . . . . . . . . . . . . . . . . . . ..

51

52

Page 14: The effect of land disposal of dairy factory wastes on

(xii)

page

FIGURE 5. 21 Changes of K with time following repetitive applications of simulated effluent and effluent plus inhibitor treatments to Manawatu silt loam (O-lOOrnm) cores . . 52

5.22 Changes in K during ponding and over the two day period following application of simulated effluent to Tokomaru silt loam (0-lOOmm) cores, with a water only treatment core for comparison . . 54

5.23 Changes in K during ponding and over the two day period following application of simulated effluent to Tokomaru silt loam ( 100-200mm) cores , with a water only tr ea tment core for comparison . • 5<';

5.24

5.25

Changes in K during the ponding period and o~er the two day period following app]ic~tion of simulated eftJ uent t o ti;,..'o Karapoti brown sandy loam (0-lOOmm) cores, with a water on l y treatment core for compar L;on

Changes in K during the ponding period and over the two day period followir.g application of simulated effluent to t wc, Karapoti silt loam (0-lOOmm) cores, with a water only treatment ~or~ fur compar ison

5. 26 Changes c;f K with time fo 1 lnwing a sj ngle appJ ka tion of high suspi:!ndeJ sol i,Js ef[ luc-nt to L1w Tokomaru silt loam (0-lOOr:im) L'o r es, with a water only treatment core ...

5.27 Changes of K wHh time folhnving appl ication of high suspended solius effl 1ent. to D TokomDru silt loam (0-lOOmm) cor..:, \·Ji th d water on] :t treatment core for

55

57

compar Lson • '.i 7

5.28 Changes of K with time l0ll0wln~ applica tion of high suspended solids t~ fflui:!nt to four Tokomaru silt loam (100-200mm) cor(;'s, with ci \vater on1v treatment core

5.29

for comparison . . . . . . . . . 58

Changes in K during ponding and o er the two day period following an application of high suspended solids effluent to three Tokomaru silt loam (O-lOOmm) cores, 59 with a water only treatment .._'.ore for comparison.

5.30 Changes in K during ponding and over the two day period following an application of high suspended solids effluent to thr ee Karapoti silt loam (O-lOOmm) cores , with a water only tr ea tment 1·ore for comparison 59

5.31 A section through a Tokomaru silt- loam (100-200nun) core following staining with Methylene Blue 62

5 .32 A section through a Tokomaru silt loam (O-lOOmm) core following staining with Rhoclnmine-B . . . . . 62

5.33 Successive sections through a Tokomaru silt loam (0-lOOnun) core following "do ible staining" ...... 63

Page 15: The effect of land disposal of dairy factory wastes on

1 •

(xiii) page

FIGURE 5.34 A section through a Manawatu silt loam (0-lOOmm) core following "double staining" . . . . . . . . 63

5.35 An enlarged section of a .Manawatu silt loam (0-lOOmm) core following "double staining" ..... 64

6.1 Changes in soil oxygen consumption with time fol lowing effluent or water applications tu soil samples from the Te Rehunga disposal site . . . 95

6.2 Changes in soil oxygen consumption with time following effluent or water applications to soil samples from the Te Rehunga con trol site . . . . 95

7. 1 A ponded depression area at the Long burn disposal site . . l 0 l

7.2 Effluent solids material coating the soil surface following spray irrigation . . 101

7.3 Changes of K with time in so il cores from the depression and elevated area of the Longburn disposal site with core surfaces removed on days 4 and 8 103

7.4 Pasture burning at the Tokomaru disposal site. . 108

7. 5

A2.l

A2.2

A2.3

A2.4

A2.5

A4.l

A4.2

A4.3

A4.4

Pasture pulling at the Te Rehun ga disposal site . . 110

Seasonal dairy production in New Zealand (averaged over the ten year period 1965-1975)

Bulk density of the Te Rehunga disposal site profile

Water retentivity characteristics of the Te Rehunga disposal site profile . . . . . ...

Bulk density of th e Longburn disposal site profile

Water retentivity characteris tics 0[ the Longburn disposal site profile . . . . . .

Changes in soil oxygen consumption with time following the application of simulated effluent, effluent plus inhibitor and water treatments to soil samples from the Te Rehunga control site . . ..

Changes in soil oxygen consumption with time followin g either the sectioning or sieving of soil cores collected from the depression area of the Longburn disposal site

l l ()

11 ~

12()

120

124

124

Changes in soil oxygen consumption with time following application of simulated effluent or water a t time ' O' to surface layer soil from the Tokomaru rlisposal Site . . 126

Changes in soil oxygen co nsumption with time followin g an application of simulated effluent or water at time 'O' to surface layer soil from the Longburn di sposal si te ........... . ............ . 126

Page 16: The effect of land disposal of dairy factory wastes on

TABLE 5 .1

5 . 2

5 .3

5.4

6. 1

LIST OF TABLES

Comparison of the c hanges in K between a two- or four-day spelling interval fo l l c)1,r Ln g appl Lcation of simulated effluent to Tokomaru silt loam (100-200mm) cores .

Forty-five minute infiltralion rates recorded prior to a nd two days after spray irrigation at the Longburn disposal site

Mid-s eason and end of oeHson in(iJLration r~tes for th e Te Rehunga disposal and cont rol sites .

Pre-season and mid -season infilcr.Jtion i-:1tes at the recently established Tokomaru disposal site

Bulk density c; i the surL:ice JOOmm ~if soil from two disposal sites and their ~orresp0nJing control sites.

6.2 The depth of tile i\p horLrnn 3t. tlk Te Rehunga disp.~sal

and control sites

6.3 Soil pH value; f11r the :~ Reh1.rng;·, disposal and control sitL'S

6 . 4 Nitr..itc and dmmonium IL·\' t ' L .. ;!! Llw T.-. Rt.=:hunga disposal

(xiv)

page

49

65

66

67

80

81

and control sites . 8~

6 . 5

6 .6

6.7

6 . 8

6.9

Nitrate and anrnwtiium level :-, dl rhc Tok,1maru disposal and control sit~s .

Nitratl, <.ind arnrnon Lum Lt"V<~ l.s .iL t·ih ' Longburn disposal and control sites .. . .

"Plant-available" µhosplic..t L ic'. Vc' h ; for the disposal and control slt2s Cit. Tt: R,,hunga '1nd Tokomaru

Potentially mineral isab le n i. tr,)ge11 values for the disposal and control sites ~r TP Rehunga, Tokomaru and Lon gb urn

Total nitrogen levels at th~ Te Rehunga disposal and control sites .

8'i

<., :. ...... _.

86

87

6 . 10 Total nitrogen levels nt Lhe Tokomaru disposal and control sites . 88

6. 1 1 Organic matter levels at th0 Te Rehunga disposal and control sites 90

6 .1 2 Organic matter levels at th~ Tokomaru disposal and control sites . 90

6.13 Earthworm numbers in the surface lOOmm of soil at t he Te Rehunga . Tokomaru and Lnngburn disposal and control sites . 92

Page 17: The effect of land disposal of dairy factory wastes on

(xv)

page

TABLE 6.14 Oxygen consumption rates in soil samples taken from the Te Rehun ga disposal and control sites at seven

7. 1

Al. l

Al. 2

Al. 3

Al. 7

A2.l

A2.2

A2.3

A2.4

A2.5

A4 .1

AS.I

and fourteen days after waste application . . . . . 93

Infiltration rates at a rotationally grazed disposal site (Field l) and at a set stocked dipsosal site (Field 2) . . . . . . . . .

Profile description of the Kopua sLJt l oam

Profile desc ription of the Karapoti brown sandy loam at the Longburn disposal site .. ,

Profile descrip tion of the Kairanga fi ne sandy loam at the Tokomaru disposal site ....... .

Profile description of the Munawatu silt loam

Mean monthly ra inf alJ data (in mm) for Te Rehunga, Tokomaru and Palmerston North over the period 1941 -19 70 . . . . . . . . . . . .....

Average potential eva potranspiration values for pasture at Palmerston North (mm month--1) ..

Calculation of the "available water holding capacity" and readily avai l able water . . ...

An example of the working procedure involved in the cons truct i on of a daily water balance (from the Te Rehunga water balance) . . . . . . . . .

Maximum daily rainfall figur12s (in mm) for Te Rehunga (over the 10 year period 1967-1977) and for Palmerston

105

llJ

l l 3

l 14

116

l 1 7

l 18

12 l

North (over the 42 year per1od 1928-1970) . . . . . 121

The percentage of applied carbohvdrate collected in the leachate following addition of a 35 l1lill dose of 127 simulated effluent to "undisturbed" soil cores

Composition analysis of effl11ent samples from Longburn dairy factory . . . . . . . . . . . . . . . l 28