The Development of a National Master Plan for Hazardous ... · Dr Abdulelah Al Wadaee Regional Network Coordinator, Compliance Assistance Program (CAP), Bahreen UNEP office 21-10-2010

146

Part b: Appendices

Final Report on

The Development of a National Master Plan for Hazardous Waste Management for the Palestinian

National Authority (PNA)

By

Dr Amer EL-Hamouz

Department of Chemical Engineering

An-Najah National University

Nablus Palestine

[email protected]

Tel +970599 557056

Submitted to

Dr Abdulelah Al Wadaee

Regional Network Coordinator, Compliance Assistance Program (CAP),

Bahreen UNEP office

21-10-2010

147

Table of Contents 11: Appendices.................................................................................................................................... 148

Appendix 1a: Arabic summary of the first meeting........................................................................... 149

Appendix 1b: List of all Industrial enterprises in the West Bank and Gaza Strip [MoT, 2010] ............ 154

Appendix 2: Chemical uses by the Teaching and Research labs of Universities. ............................... 162

Appendix 3: List of all pesticides used in the POt during 2009 as reported by the agriculture AlSadeq 2010 ................................................................................................................................................ 168

Appendix 4: A sample Response ...................................................................................................... 190

Appendix 4b: Product Data Sheet .................................................................................................... 195

Appendix 5 B: Dumpsite location and size........................................................................................ 201

Appendix 6: Methodoligical method used in Analysing hazardous waste at ZF. ................................ 203

Appendix 7: Outcomes of one of committee’s meetings. ................................................................. 208

Appendix 8: Analytical sample result of Kufl Haris Waste. ................................................................ 212

Appendix 9: Special precautions for managing and storing hazardous waste ................................... 216

Appendix10: Harmful and Hazardous Waste Categories to be controlled in the POt according to Basel Convention...................................................................................................................................... 222

Appendix 11: Suggested forms for Notification of Hazardous waste activity and tansboundary movement. .................................................................................................................................. 225

Appendix 12: Arabic summary of the tanning wastewater treatment unit as reported by CH2M HILL........................................................................................................................................................ 228

Appendix 13: Hazardous materials in the Palestinian Enterprises..................................................... 232

Appendix 14: Periodical auditing and monitoring plan.........................................................................251

148

11: Appendices

149

Appendix 1a: Arabic summary of the first meeting.

ǅƑǀǄ ƣƑƾƴǆƐ ƅƑƾǂǁƐ .ǃƐƥ ŶƐ- ƒƗǀǄ ƒƏƑǆ ƧǐƏƥ ƕƯǂƨǁƐ.24/1/2010.

ƥǋƮƟǁƐ:ǃ.ǅƐǋƥǄ ǋƓƐ ƒǋƾƴǐ. ǃ.ƣƜǄƐ ǃǐǉƐƥǐƐ ǃ .ǃƑƬƳ ǃƨƑƾǁƐ ǃ.ƖƓƑƙ ƹƨǋǐ

ǃ.ƣƓƳ ǃƴǆǄǁƐ ƒƑǊƪ ƈ.ǃƪƑǉ ƝǘƬ.

ƣƑǄƳ ƑƓƑƓǁƐ.

ƒƑǐƸǁƐ :ǃ.Ǐƽǋƪ ƔƣƑƴƨ.

Ɗƥƕ ƇƓǀǄǃƒ ƗǆǄǂƕ ƢǕƒ ýǒǆƞ ƧǍƱǆǃƒ/ƔƑƓǈ ƩǒƑƧ ƗƱǄƪ ƖƥǍƞ ÜƗƑǒƕǃƒ ƚǒơ ƧƓƬƒ Ǐǃƒ Ǉƒ ƳǍƧƬǆǃƒ Ǎǋ ƥǍǌƞƕ Ɨƛǒƛơ ƗƱǄƪǃ ƖƥǍƞ ƗƑǒƕǃƒÛ Ɠǆǂ ƧƓƬƒǍ Ǐǃƒ ǎƥǆ Ɨǒǆǋƒ ƳǍƧƬǆǃƒ Ɠǆǃ Ǌǃ Ǉǆ ƝƑƓƙǈ ǑƕǄƙ ƘƓƞƓǒƙơƒ ƗƑǒƕǃƒ

ƗǒǈǒƱƪǄƽǃƒ .

ƾƧƱƙ ƢǕƒ ýǒǆƞ Ǐǃƒ ƖƧǍƧư ǅƒƨƙǃƒ ƇƓưƵƒ ƾǒƧƽǃƒ ǑǄƤƒƥǃƒ ƗƱǄƪǃ ƖƥǍƞ ƗƑǒƕǃƒ ƨǂƧǍ ǏǄƵ ƧǍƥǃƒ ǍơǆǃƒǐƧ ǅƓǌǃƒǍ ƖǍƤǘǃ ƇƒƧƥǆ ƔƙƓǂǆǃƒ ǇǒƶƕƓƙǃƒ ƖƧƒƥǘǃ ƗǆƓƶǃƒ ƗǒƓǆơǃ ƗƑǒƕǃƒ ýǂ ǑƼ ǊƶƿǍǆ ǁǃƦǍ ýǒǌƪƙǃ ýǆƵ ƢǕƒ ƧƓƬƙƪǆǃƒ ƩǒƑƧ ƾǒƧƽǃƒ ǑƼ ƗǒǄǆƵ ƴǆƞ ƘƓǈƓǒƕǃƒ ƥǂƋƙǃƒǍ Ǉǆ ƓǌƙƥǍƞ.

Ƈǚǆƨǃƒ ƇƒƨƵǕƒ

Ƙǈǂ ƔƹƧƒ ǑƼ ƟƧƬ ƱƓǀǈǃƒ ƗǒǃƓƙǃƒ ǅǂǃ ǑǋǍ ƭƤǄƙ ƖƧǂƼ ƳǍƧƬǆǃƒ ýǂƬƕ ǅƓƵ.

ƹƣǊǁƐ ƧǐƏƥǁƐ ƱǋƥƪǄǂǁ:

ƻƥǌǒ ƳǍƧƬǆǃƒ Ǐǃƒ ƾǒǀơƙ ƖƧƒƥƒ ƗǒƑǒƕ ƗǆƒƥƙƪǆǍ ƘƓǒƓƽǈǄǃ ƖƧƱƤǃƒ ǑƼ ǇǒƱƪǄƼ.

150

ƖƑǐǁƆ ƼǐƾƟƗ ƹƣǊǁƐ ǃƑƴǁƐ ƱǋƥƪǄǂǁ.

1. ýǒǂƬƙ ƾǒƧƼ ǑǄƤƒƥ Ǉǆ ƗƱǄƪ ƗƑǒƕǃƒ ƗƶƕƓƙǆǃ ƳǍƧƬǆǃƒ. 2. ýǒǂƬƙ ƾǒƧƼ ýǆƵ ǑǈƱǍ ǉƥǍǀǒ ƧǒƕƤǃƒ ƥ.ƧǆƓƵ ƨǍǆǌǃƒ. 3. ýǒǂƬƙ Ɨǈƞǃ ƗǒǌǒƞǍƙ ƳǍƧƬǆǄǃ. 4. ƥǀƵ ƗƬƧǍ ƾǚƱǗ ƳǍƧƬǆǃƒ. 5. ƥǀƵ ƗƬƧǍ/ƘƓƬƧǍ ƔǒƧƥƙǃ ƧƥƓǂǃƒ. 6. Ơƪǆ Ǒǈƒƥǒǆ ǐƧƲǈǍ.

ǁƐƞƨǄ ǁƐǏǆƐƣǐǄ ǋǁƐǎƥưǆ.

1. ƴǆƞ ƗƼƓǂ ƘƓǈƓǒƕǃƒ ƗǀǄƶƙǆǃƒ ƘƓǒƓƽǈǃƓƕ ƖƧƱƤǃƒ ƖƥǃǍƙǆǃƒ ƓǒǄơǆ Ǎƒ ƖƥƧǍƙƪǆǃƒ) ƧǒƧƓǀƙ ÜƗƑǒƕǃƒ ǅǂơǃƒ ǑǄơǆǃƒ Ü...... ƧƥƓƮǆ ǎƧƤƒ.(

2. ƾǀơƙǃƒ Ǉǆ ƖƥǍƞ ƗơƮǍ ƘƓǈƓǒƕǃƒ. 3. ƥǒƥơƙ ƿƒǍǆǃƒƴ ƗǈƤƓƪǃƒ/ƾƱƓǈǆǃƒ ƘƒƦ ƗǒǆǋǕƒ. 4. ƥǀƵ ƘƒƇƓǀǃ ƴǆ ƳƓǈƮ ƧƒƧǀǃƒ. 5. ƗƶƞƒƧǆ ǇǒǈƒǍǀǃƒ ƴưǍǍ ƧƓƱǗƒ ǑǈǍǈƓǀǃƒ ǅƲƓǈǃƒ ýǆƶǄǃ.

151

ƕƯƢǁƐ ƕǐǆƯǋǁƐ ƔƥƐƣǕ ƖƑǐƑƻǆǁƐ ƔƥƯƢǁƐ Ǐƺ ǅǐƯƨǂƺ

1. ƒƇƓǈƕ ǏǄƵ ƘƓǈƓǒƕǃƒ ƗƵǍǆƞǆǃƒ ǅƙǒƪ ƧǒǍƱƙ ƗƱƤǃƒ ǑƙǃƒǍ ýǆƙƬƙƪ ǏǄƵ ƗǄǆƞ ƘƓơƒƧƙƿƒ ƾǄƶƙƙ ƥƒǍǆǃƓƕ/ƘƒǍƥǕƒ Ǒƙǃƒ Ǉǂǆǒ ƖƥƓƽƙƪǗƒ Ɠǌǈǆ ǑƼ ƘƓǒǄǆƵ ǇǒƨƤƙ Ǎƒ ƗƞǃƓƶǆ Ǎƒ ƭǄƤƙǃƒ Ǉǆ ƘƓǒƓƽǈǃƒ ƖƧƱƤǃƒ.

2. ǅƹƓǈƙ ǅƓƙ Ǉǒƕ ƗƱƤ ƘƓǒƓƽǈǃƒ ƖƧƱƤǃƒ ƗǒƞǒƙƒƧƙƪǗƒǍ ƗǒǈƱǍǃƒ ƖƧƒƥǗ ƘƓǒƓƽǈǃƒ ƗƕǄƮǃƒ ƗǒƿƓƽƙƒǍ ýƨƓƕ Ǉǆ ýǚƤ ƥǒƱǍƙ Ɨƿǚƶǃƒ Ǉǒƕ ƘƓǌƞǃƒ ƗǃǍƌƪǆǃƒ ƗǒƧƓƙǒƧǂƪǍ ƗǒƿƓƽƙƒ ýƨƓƕ.

ƥǋƣ ƕƯǂƨ ƔƣǋƜ ƕƏǐƓǁƐ

1. ƥƒƥƵƒ ƱǍƱƤǃƒ ƗǒƶƞƧǆǃƒ ƗƱƤǄǃ. 2. ƴǆƞ ýǒǄơƙǍ ƘƓǈƓǒƕǃƒ. 3. ƘƒƧƓǒƨǃƒ Ɨǒǈƒƥǒǆǃƒ. 4. ƔƓƪƙơƒ ƘƓǒƓƽǈǃƒ ƖƧƱƤǃƒ ƖƥǃǍƙǆǃƒ ǑƼ ǇǒƱƪǄƼ. 5. ýǒǄơƙ ƘƓǈƓǒƕǃƒ Ǒƙǃƒ ǅƙ Ɠǌƶǆƞ Ưƶƕǃ ƘƓƲƼƓơǆǃƒ Ǉǆ ƚǒơ ƘƓǒǆǂ ÜƘƓǒƓƽǈǃƒ ƓǌƙƧƒƥƒ. 6. ƥǒƥơƙ ƴƿƒǍǆǃƒ ƗǈƤƓƪǃƒ/ƾƱƓǈǆǃƒ ƘƒƦ ƗǒǆǋǕƒ. 7. ƧǍƓƬƙǃƒ ƴǆ ƓǈƮƳ ƧƒƧǀǃƒ ǑƼ ƘƓƪƪƌǆǃƒ ƘƒƦ Ɨƿǚƶǃƒ. 8. ƇƒƧƞƒ ƘƓơǍƪǆ ƥƒǍǆǄǃ ƗǆƓƪǃƒ ƖƧƱƤǃƒǍ ǑƼ Ưƶƕ ƘƓƲƼƓơǆǃƒ. 9. ǀƙǅǒ ƘƒƧƥǀǃƒ ƗǒǄơǆǃƒ ƗƞǃƓƶǆǃ ƘƓǒƓƽǈǃƒ ÜƖƧƱƤǃƒ ƓǌǈǒƨƤƙ......ƣǃƒ.

10. ƥǒƥơƙ ƘƓƕƙƶǃƒ ƟǍǆƪǆǃƒ Ɠǌƕ Ɣƪơ ǇǒǈƒǍǀǃƒ Ǉƒ ƘƥƞǍ. 11. ǅǒǀƙ ƓǒƞǍǃǍǈǂƙǃƒ Ɨƛǒƥơǃƒ ƗƕƪƓǈǆǃƒ ƗƞǃƓƶǆǃ ƘƓǒƓƽǈǃƒ ƖƧƱƤǃƒ ƭǄƤƙǃƒǍ Ɠǌǈǆ. 12. ƧǒǍƱƙ ƘƓơƧƙǀǆ ƾƧƱǃ Ǎƒ ƗƱƬǈƒ ÜƗǒƙƓƪƪƌǆ ƗǒƶǒƧƬƙ Ǎƒ ƗǒǈƼ ýǆƓǂƙǄǃ ǑƼ ƖƧƒƥƒ ƗǒƑǒƕ Ɨǆƒƥƙƪǆ ƘƓǒƓƽǈǄǃ

ƖƧƱƤǃƒ. 13. ƗƿƥƓƮǆǃƒ ǏǄƵ ƗƱƤǃƒ. 14. ƥƒƥƵƒ ƘƓǀƼƧǆ ƗǒơǒưǍƙ ƗƱƤǄǃ. 15. ǅǒƥǀƙ ƗƱƤǃƒ ƧǒƧǀƙǃƒǍ ǑƑƓǌǈǃƒ ƳǍƧƬǆǄǃ.

152

153

154

Appendix 1b: List of all Industrial enterprises in the West Bank and Gaza Strip [MoT, 2010]

West Bank Gaza

ISIC Industry Number of enterprises

Number of Persons Engaged

Number of Enterprises

Number of Persons Engaged

1410 Quarrying of stone, sand & clay

230 1310 0 0

1511 Production & preserving of meat

7 110 6 25

1513 Preserving of fruit & vegetables

25 365

1514 Manufacture of vegetable & animal oil

7 103

14 87

1520 Manufacture of diary products

28 864 18 117

1531 Manufacture of grain mill products

88 288 44 219

1533 Manufacture of prepared animal feeds

21 165 7 46

1541 Manufacture of bakery products

919 3487 286 1405

1543 Manufacture of chocolate & sugar product

75 291 27 115

1544 Manufacture of macaroni, & similar products

6 44 6 44

1549 Manufacture of other food products n.e.c

317 1089 117 455

155

1551 Distilling & blending of alcohol

3 33

1554 Manufacture of soft drinks & mineral water

27 479 17 161

1600 Manufacture of tobacco products

21 190 0 0

1711 Spinning of textile fibbers 8 71

1712 Finishing of textiles 26 38

4 9

1721 Manufacture of made-up textile articles

193 785 59 170

1722 Manufacture of carpets & rugs

6 38

1723 Manufacture of rope,twine & netting

4 0

0 0

1729 Manufacture of other textiles n.e.c

9 30 5 25

1730 Manufacture of other textiles n.e.c

11 102 3 83

1810 Manufacture of wearing apparel

1287 9574

1820 Dressing and dyeing of fur; manufacture

9 52

1911 Tanning & dressing of leather

10 66

456

(1820) باستثناء

1815

)1820 (باستثناء

1912 Manufacture of luggage and handbags

20 172 8 23

1920 Manufacture of footwear 339 1878 23 71

2010 Sawmilling & plaining of wood

9 25

الخشب من الصفائح صنع 2021 0 0

8 19

156

2022 Manufacure of builders carpentery

269 422 141 373

2023 Manufacture of woooden containers

42 232 12 32

2029 Manufacture of other products of wood

202 739 42 87

2101 Manufacure of pulp,paper & paperboard

10 135

2102 Manufacture of paper containers

13 132

4 10

2109 Manufacture of the articles of paper

28 286 6 38

2212 Publishing of newspaper and journals

7 100 5 32

2221 Printing 187 863

2222 Sevice activities related to printing

11 55

2320 Manufacture of refined oils

3 24

68 297

2411 Manufacture of basic chemicals 30 78

2413 Manufacture of plastics

2421 Manufacture of fertilizer 16 124

2422 Manufacture of paints 14 123

5

excluding 2413

28

Excluding 2413

2423 Manufacture of medicinal products

7 421 4 48

2424 Manufacture of soap and detergent

76 491 42 419

2429 Manufacture of other chemical products

3 23 0 0

157

2519 Manufacture of the rubber products

5 35 6 28

2520 Manufacture of plastic products

101 1052 65 537

2610

Manufacture of glass & glass products

80 249 20 38

2691

Manufacture of non-refractory ceramic war

29 166 7 36

2692 Manufacture of refractory ceramic product

4 22 0 0

2693 Manufacture of structural non-refractory

22 98 0 0

2694 Manufacture of cement, lime & plaster

21 120 3 7

2695 Manufacture of articles of concrete, cement

267 1747 175 282

2696 Cutting, shaping & finishing of stone

995 6490 99 233

2699 Manufacture of other non-metallic

3 88 0 0

2710 Manufacture of basic iron & steel

13 54 5 9

2720 Manufacture of non ferrous metals.

32 206 0 0

2732 Casting of non ferrous metals

3 10 0 0

2811 Manufacture of structural metal products

2159 3686 617 1160

2812 Manufacture of tanks of metal

41 156 12 34

158

2891 Forging, pressing roll-forming of metal

62 128 35 107

2892 Treatment & coating of metals

136 322 57 120

2893 Manufacture of cutlery & hand tools

14 33 16 39

2899 Manufacture of other fabricated metal

26 217 21 70

2911 Manufacture of engines of turbines

9 23 3 13

2912 Manufacture of pumps 17 42

2914 Manufacture of ovens, furnaces and furnace burners

0 0

2915 Manufacture of handling equipment

10 12

4 11

2919 Manufacture of other purpose machinery

10 85 7 9

2921 Manufacture of agricultural machinery

22 60 19 37

2922 Manufacture of machine-tools

6 12 4 7

2924 Manufacture of const machinary & its rep

83 167 9 29

2925 Manufacture of machinery for food

12 56 0 0

2926 Manufacture of machinery for textile

8 13 11 20

2929 Manufacture of general purpose machinery

7 19 0 0

2930 Manufacture of general 14 54 20 145

159

purpose machinery

3110 Manufacture of electric motors.

26 43

3120 Manufacture of electricity

3130 Manufacture of insulated wire & cable

15 47

3140 Manufacture of batteries

11 65

4 21

3150 Manufacture of lighting equipment

6 36 7 43

3190 Manufacture of other electrical equipment

14 23 0 0

3220 Manufacture of T.V & radio transmitters

3 3

او التلفزیوني االستقبال جھزة 3230 عرض او تسجیل واجھزة االذاعي

الصوت

0 0

13 26

3311 Manufacture of medical equipments

71 152 14 49

3320 Manufacture of optical instruments

4 5 3 8

3420 Manufacture of bodies for vehicles

3 9

3430 Manufacture of parts for motor vehicles

النزھة قوارب وإصالح بناء 3512 والریاضة

7 26

3592 Manufacture of bicycles

4

Excluding 3512

19

Excluding 3512

0 0

األخرى النقل معدات صنع 3599 0 0 6 8

3610 Manufacture of furniture 1945 5029 472 1327

160

3691 Manufacture of jewellery 11 103

3692 Manufacture of music machine

4 4

الریاضة أدوات صنع 3693 0 0

4

Excluding 3692

14

Excluding 3692

3694 Manufacture of games & toys

4 13

3699 Other manufacturing n.e.c 5 8

5 102

3710 Recycling of metal waste & scrap

0 0

3720 Recycling of non- metal waste & scrap

12 36

3 19

4010 Production of electricity 6 371 3 312

4100 Collection & distribution of water

176 653 196 528

161

162

Appendix 2: Chemical uses by the Teaching and Research labs of Universities.

163

164

165

166

167

168

Appendix 3: List of all pesticides used in the POt during 2009 as reported by

the agriculture AlSadeq 2010

169

INSECTICIDES, ACARICIDES & NEMATICIDES

Brand Name صورة المبید

المادة تركیز الفعالة

Contant a.i.

الشائع األسم

Generic Name

X mite SC 150g/L Acequinocyl

Alsystin WP 25% Triflumuron

Aplord SC 250g/L Buprofezin

Apollo SC 50g/L Clofentezine

Agremic EC 18g/L Abamectin

Evisect S SP 50% Thiocyclam hydrogen oxalate

Afent SC 150g/L Indoxacarb

Acremakten EC 18g/L Abamectin

Akrimite EC 550g/L Fenbutatin Oxide

Akterah SC 240g/L Thiamethoxam

Oberon SC 240 g/L SPIROMESIFEN

Insegar WP 25% Fenoxycarb

Annivers CS 50g/L Halfenprox

Attabron EC 50g/L Chlorfluazuron

Orthene SP 75% Acephate

Ipon SG 20% DINOTEFURAN

Baythroid EC 50g/L Cyfluthrin

Pegasus 25 SC 250g/L Diafenthiuron

170

Polo 25 SC 250g/L Diafenthiuron

Pegasus 50 SC 500g/L Diafenthiuron

Polo 50 SC 500g/L Diafenthiuron

Pride SC 200g/L Fenazaquin

Peropal WP 25% Azocyclotin

Becis EC 25g/L Deltamethrin

Bektosfen SC 8400 Iu/mg Bacillus Thuringinsis

Bakten EC 18g/L Abamectin

BONANZA SC 500g/L Diafenthiuron

Bio . TION. RB 8000 Iu/mg Bacillus Thuringinsis

Pyrtlin SAC 1% Chlorpyrifos

Pyrinex 48 EC 479g/L Chlorpyrifos

Pyrinex GR 5% Chlorpyrifos

Bio . BIT. SC 8400 Iu/mg Bacillus Thuringinsis

Bio . T. SL 8000 Iu/mg Bacillus Thuringinsis

Bio . T.+ SC 16000 Iu/mg Bacillus Thuringinsis

Bionem DP 3-3.5 % Bacillus Firmus

Bionem WP 5 % Bacillus Firmus

Tiger EC 100g/L Pyriproxyfen

Tracer super SC 240g/L Spinosad

Tarsip EC 200g/L Cypermethrin

Neroopaz OL 80% Summer oil

171

Trigard WP 75% Cyromazine

Chess WG 50% Pymetrozine

Tokuthion EC 500g/L Prothiofos

Tlon 2 L 94% Dichloropropene

Titan 20 EC 200g/L Cypermethrin

Tedion EC 80g/L Tetradifon

Gusation WP 25% Azinphos-methyl

Dalfen WG 32000 Iu/mg Bacillus Thuringinsis

Dorbas EC 480g/L Chlorpyrifos

Dorsan DP 5% Chlorpyrifos

Dorsan 4 EC 479g/L Chlorpyrifos

Dorsban GR 5% Chlorpyrifos

Dorsban 4 EC 479g/L Chlorpyrifos

Dybs EC 1000g/L Dichlorvos

Decis EC 25g/L Deltamethrin

Dafel WP 16000 Iu/mg Bacillus Thuringinsis

Divipan 100 EC 1000g/L Dichlorvos

Divipan 5% DP 5% Dichlorvos

Divipan Laido KN 1000g/L Dichlorvos

Dimethoate EC 400g/L Dimethoate

Demol OL 98% Parffinic oil

Dimilin WP 25% Diflbenzuron

Runer SC 240g/L Methoxyfenozide

172

Ragby CS 200g/L Cadusafos

Rmsen GB 1% Chlorpyrifos

Rogor 40 EC 400g/L Dimethoate

Rufast EW 75% Acrinathrin

Romacten EC 18g/L Abamectin

Rimon EC 100g/L Novaluron

Zohar PT-50 SL 500g/L Detergent (soap soluation)

Zohar LQ-215 SL 17% Detergent (soap soluation)

Zoharnet SL 470g/L Detergent (soap soluation)

J M S oil OL 97.2% Mineral Oil

Sitol oil E 80% Petroleum Oil

SAF-T-Side E 80% Petroleum Oil

Sbidar SC 110g/L Ethoxazol

Safsan 1015 GB 15% Sodium fluosilicate

Safsan 515 GB 15% Sodium fluosilicate

Cymbush 10 EC 100g/L Cypermethrin

Cmshofr EC 200g/L Cypermethrin

Sensor EC 300g/L Etofenprox

Siperin 10 EC 100g/L Cypermethrin

Siperin 20 EC 200g/L Cypermethrin

Citrona OL OL 82% Summer oil

Sesamin EC 70% Sesame oil

173

Sufa SC 520g/L Sulphur

Sherpaz EC 100g/L Cypermethrin

Frcotyl EC 18g/L Abamectin

Verto - M EC 18g/L Abamectin

Frobit WG 25000 Iu/mg Bacillus Thuringinsis

Florbak SC 8500 Iu/mg Bacillus Thuringinsis Varaizawai

Flormait SC 240g/L Bifenazate

Vitol OL OL 80% Summer oil

Vertimec EC 18g/L Abamectin

Vertigo EC 18g/L Abamectin

Virotar OL OL 80% Summer oil

Virol OL OL 80% Summer oil

Cotnion 20 EC 200g/L Azinphos-methyl

Cotnion 20 SC 200g/L Azinphos-methyl

Cotnion 25 WP 25% Azinphos-methyl

Cotnion 8 DP 8% Azinphos-methyl

Karate EC 50g/L Lambda Cyhalothrin

kung fu EC 50g/L Lambda Cyhalothrin

King Bo EC (0.2% + 0.4%)w/w

Oxymatrine + Prosuler

Kaskid SL 50g/L Flufenoxuron

Keshet EC 25g/L Deltamethrin

calybso SC 480g/L Thiacloprid

174

Kandor EC 91.7% Dichloropropene

Confidor SC 350g/L Imidacloprid

Copra EC 100g/L Pyriproxyfen

CONFIDENCE SC 350g/L Imidacloprid

KOHINOR SC 350g/L Imidacloprid

Lamdex EC 50g/L Lambda Cyhalothrin

Levanola OL 82% Summer oil

Match EC 50g/L Lufenuron

Magister SC 200g/L Fenazaquin

Marshal 25 250g/L EC Carbosulfan

Miteclean SC 100g/L Pyrimidifen

Meteor SC 50g/L Fenpyroximate

California Mixture SC 250 g/l Calcium Polysulphid

Mesurol SC 500g/L Methiocarb

Mesurol WP 50% Methiocarb

Masai WP 20% Tebufenpyrad

Mosblan SP 20% Acetamiprid

Mosblan SL 200g/L Acetamiprid

Molit SC 150g/L Teflubenzuron

Melpnok EC 9.3g/L Milbemectin

Metasystox EC 250g/L Oxydemethon methyl

Mitac EC 200g/L Amitraz

Neemacor 10 GR 10% Fenamiphos

175

Neemacor 400 EC 400g/L Fenamiphos

Neropaz 80 OL 80% Summer oil

Nerola OL 99.25% Summer oil

Neron 250 EC 250g/L Bromopropylate

Nimgard OL 97% Neem Oil

Nimtol OL 97% Neem Oil

Neemix 45 EC 45g/L Azadirachtin

Ezidor

EC 30g/L Azadirachtin

Botanigard L ---- Beauveria Bassiana

Biosafe DP ---- Bacillus Firmus

Biophytos SB DP ---- Rotenone, Pyrethrum natural

Ganim 1500 EC ---- Azadirachtin

Deritenone OL

---- Rotenone

Vintrazol EC ---- Mineral oil

Root Shield GR ---- Trichoderma Harzianum

Azgan WP ---- Azadirachtin

Thuricide SL ---- Bacillus thuringiensis

Totach EC ---- Neem Oil

Pyrethrum Natural

176

Stop ants RB ---- Ortho Boric Acid

Sodium Tetraborate Pentahydrate

ECOGAN BARAK EC ---- Neem Oil

Pkant Oil

Pyrethrum

ECOGANE EMFAR EC ---- Neem Oil

Pkant Oil

Pyrethrum

Shom Herk SL 15g/L + 0.5

g/L

Garlic extract+ Pyrethrum natural

FUNGICIDES & BACTERICIDE


Generic name

الفعالة المادة تركیز

Contant a.i.

صورة المبید

Brand Name

Azoxystrobin + Difenoconazole (200+125) g/L SC ORTIVA TOP

FOSETHYL ALUMINIUM 80% WP ALIETTE

Azoxystrobin 250g/L SC Amistar

Thiophanate methyl 70% WP Amco - M

Quinoxyfen 250g/L SC Abeir

Fenbuconazole 50g/L EC Indar

Hexaconazole 50g/L SC Anvil

Tolylfluanid 50% WP Aoperin Molti

177

Propineb 70% WP Antracol

Dimetomorph + Mancozeb 9% + 60% WP Acrobat

Tebuconazole 250 g/l EW Orios

Penconazole 100 g/l EC Ofir

Penconazole 200g/L EW Ofir 2000

Prochloraz manganese 50% WP Octav

Fluazinam 500g/L SC Ohaio

Ampelomyces Quisqualis 5*109 WG AQ 10

Triadimenol 250g/L EC Bayfidan

Bitertanol 25% WP Baycor

Copper hydroxide 77% WP Parasol

Mepanipyrim 50% WP Prupica

Dazomet 98% GR Bazamid

Propanocarp HCL 722g/L SL previcur

Metiram 80% WG Poliram DF

Oxycarpoxin 75% WP Plantax

Copper hydroxide 77% WP Blu shild

Iminoctadine tris 40 % WP Blekiot

Flusilazole 400g/L EC Punch 40

Difenozonazole 250 g/l EC Bogard

Copper Sulphate 80% WP Bordozol

TCMTB 300g/L EC Busan

Tebuconazole 250 g/l EC Polyron

178

Carbendazim 50% WG Bavistin

Quintozene (PCNB) 75% WP Terachlor

Mancozeb 80% WP Triziman

Fenhexamid 500g/l SC Teldor

Flutolanil 410g/l SC Telem

Thiophanate methyl 70% WP Topaz

Penconazole 100 g/l EC Topnex

Penconazole 100 g/l EC Topenko

Tebuconazole 45 % WG Tebax

Sulphur 70% DP Gafribk

Sulphur 80% WP Gafritp

Sulphur 825g/L SC Gafritr

Benalaxyl + Mancozeb 8% +65% WP Galben M

Metalaxyl M + Chlorothalonil (37.5+500) g/L SC Folio Gold

Flutriafol 125g/L SC Hosan

Propanocarp HCL 722g/L SL Dynone

Chlorothalonil 82.5% WG Daconil

Carbendazim 50% WP Delsene

Dithianon 500g/L SC Delan

Propamocarp HCL 722g/L SL Dotan - proplant

Pyrifenox 200g/L EC Dorado 200

Myclobutanil 200g/L EW Rally

Carbendazim + diethofencarb 250+250g/L SC Resec

179

Fenarimol 120g/L EC Rubigan

Trichoderma harzianum Cful5*107 DP Rot pro

Iprodione 500g/L SC Rodion

Iprodione 500g/L SC Rovral nozel

Iprodione 50% WP Rovral 50

Zoxamide + Mancozeb 8.3% + 66.7% WG Roxam

Copper oxychloride + Mefenoxam 40 + 2.5 % WP Ridomil gold – CU

plus

Mefenoxam 480g/l WP Ridomil gold nozl

Mefenoxam + Mancozeb 4 + 64% WP Ridomil gold M.Z

Tolclofos methyl 50% WP Risolex 50

Metominostrobin 202 g/L SC Ringo

Mancozeb 80% WP Sancozeb

Oxolinic acid 20% WP Sterner

Kresoxim methyl 50% WG Stroby

Triforine 190g/L EC Saparol

Difenoconazole 250g/L EC Score

Fludioxonil 100g/L SC Celest

Dichlofluanid+Tebuconazole 40 +10 % WP Silvacur

Sulphur 720g/L SC Salfo Ron

Sulpher 650g/L SC Salfo le

Cyprodinil + fludioxonil 37.5 + 25 % WG Switch

Pyraclostrobin + Boscalid (6.7 + 26.7) % WG Signum

Copper hydroxide 77% WP Champion

180

Triadimenol 250g/L EC Shavit

Bromuconazole 100g/L SC Vectra

Trifloxystrobin 50% WG Flant

Polyoxin-AL 50% WG Polar

Tebuconazole 250g/L EC Folicur

Copper hydroxide 77% WP Funguran

Cymoxanil 45% WG Fyten

Pyrimethanil 300g/L SL Firos

Sulpher 99.9 % DP Sulpher

Sulpher 99.9 % DP Sulpher

Sulpher 90% WP Sulphur

Sulpher 70% DP Sulphur

Sulpher 99% DP Sulphur

Sulpher 99.97% DP Sulphur

Copper Sulphate 98 % GR Copper Sulphate

Copper Sulphate 98% WP Copper Sulphate

Copper Sulphate 98% GR Copper Sulphate

POtassium bicarbonate 80% SP Kaligren

POtassium phosphite 500g/L SL Canon

Propineb + Copper oxychlorde 17.5+37% WP Cupro Antracol

Copper hydroxide + mancozeb 3.88 + 66.7 % WP Copman

POtassium phosphite 850g/L SL Cordon

181

Copper hydroxide 77% WP Kocide 101

Copper hydroxide 53.8 % WG Kocide 2000

Copper hydroxide 61.4 % WG Kocide DF

Sulphur 80% WG Comolus

Propamocarb HCL + Fenamidone 375g/l + 75g/l SC Konsento

Mancozeb 80% WP Mancotal

Polyoxin B 10% WP Milvan

Mancozeb 80% WP Manzidan

Mancozeb 80% WP Mancozan

Diniconazole 12.5% WP Marit

Iprovalicarb+ Propineb 5.5% + 61.25% WP Melody Duo

Pencycuron 25g/L SC Monceren

Pencycuron 250g/L SC Momento

Pyrimethanil 300 g/l SC Mithos

Prochloraz zinci 50% WP Mirage

Prochloraz 450 g/l EC Mirage 45

Sulphur 80% WG Microtail

Cymoxanyl 50% WG Saymon

Bupirimate 250 g/l EC Namrod

Sulphur 700g/L SC Halogafrit

Sulphur 80% WG Thaiovit

Mineral Oil 99% OL EOS

182

Tea Tree Oil ---- EC Timorex Gold

POtassium hydrogen carbonate + Copper sulfate

---- WP More

POtassium salt Fatty acid

---- SC Nat 35

Sulphur 720g/L SC Sufa

Bacillus Subtilis ---- SC Serenade ASO

Mineral Oil 97% EC Citrole

Trichoderma Harzianum 5*107 DP Root Pro

Metschnikowia Fructicola 56% WG Shemer

HERBICIDES & DEFOLIANTS


Generic name


Contant a.i.


Brand Name

Terbutryne 500 g/L SC Agrein 500

Tribenuron methyl 75% WG Express

Triasulfuron 75% WG Amber

Terbutryne + Ametryne 25+40% WP Amign 65

Oxyfluorfen 240g/L EC Amcogol

183

Sulfometuron methyl 75% WG Oust 75

Ethidimuron 70% WP Ustilan

Linuron 500g/L SC Aflon

2,4-D salt 96.9% SP Aminbar

Carfetrazone ethyl 40% WG Aurora

Pendimethalin 330 g/L EC Pendel

Phenmedipham 157g/L EC Betanal

2,4-D (Tri-ethanol amine salt) 500g/L SL Alber 40

2,4-D 335g/L EC Albur super

Imazethapyr 100g/L SL Persut

Prometryne 500g/L SC Prometrex

Prometryne 500g/L SC Prometron

Prometryne 500g/L SC Promegard

Glyphosate isopropy amine salt 480g/L SL Pilaround

Glufosinate ammonium 200g/L SL Basta 20

Glufosinate ammonium 200g/L SL Baster

Benfluralin 180g/L EC Benefex 18

Sulfentrazone 75% WG Boral

Fenoxaprop -P- ethyl +

MefenpyrDiethyl

69+18.8 g/L EW Puma super

Ammonoium thiocyanate +

Aminotriazole

220 + 250 g/L SL Bedozol TL

Chloridazon (Pyrazon) 65% WG Pyramin

184

Quizalofop-p- ethyl 100g/L EC Bilot soper

Glyphosate Trimesium (sulfate) 480g/L SL Touchdown

Terbutryne 500g/L SC Terbutrex

Trifluralin 480g/L EC Treflan

Trifluralin 480g/L EC Triflurex

Triclopyr BUTOTYL 480g/L EC Trable

Cloquintocet + Clodinafop Propargyl

25g/L + 100g/L EC Topik

Aclonifen 600g/L SC Challenge

Picloram + 2,4-D 102g/L + 396g/L EC Tordon 101

Sulfometuron methyl 75% WG Tostar

Fluroxypyr 200g/L EC Tomahawk

Flufenacet 60% WG Tiara

Rimsulfuron Methyl 25% WG Titus

Glyphosate Isopropy Amine Salt 480g/L SL Taifun

Glyphosate Isopropyl Amine Salt 480G/L SL Galoop

Triclopyr BUTOTYL 480g/L EC Garlon

HaloxyfopR Methyl Ester 104g/L EC Gallant Super

Oxyfluorfen 240g/L EC Galon

Oxyfluorfen 240g/L EC Galigan

Glyphosate Isopropy Amine Salt 480g/L SL Glyphogan

Glyphosate Isopropy Amine Salt 480g/L SL Glyphos

Glyphosate Isopropy Amine Salt 480g/L SL Glefon

185

Oxyfluorfen 2% GR Goal GR

Oxyfluorfen 238g/L EC Goal FN

Fluazifop -P- butyl 150 g/L EC Deganol F

Florasulam+Flumetsulam 75+100g/L SC Derby

Benoxacor + Metolachlor-S 45+915g/L EC Dual S. gold

Metoxuron 80% WP Dosanex 80

Oxadiargyl 400g/L SC Raft

Glyphosate isopropy amine salt 480g/L SL Roundup

Glyphosate isopropy amine salt 480g/L SL Roundmor

Glyphosate isopropy amine salt 480g/L SL Roundpaz

Oxadiazon 250g/L EC Ronstar

Flurochloridone 250g/L EC Racer

Anionics&nonionics 500g/L SL Zohar OC-6

Diuron+Thidiazuron 60+120g/L SC Dropp ultra

2,4-D Iso Octyl Ester 350g/L EC Sanafen Super

Imazaquin 150g/L SL Septer

Fluroxypyr 200g/L EC Starane

Flumioxazin 50% WP Strike

Diuron+Thidiazuron 60+120g/L SC Striptease

Pendimethalin 500g/L EC Stomp

Pyrithiobac Sodium 85% SP Staple

Carfetrazone ethyl 60g/L EW Sfotalit

186

Clethodim 116g/L EC Select Supr

Isoxaben + Trifluralin 0.5% + 2% GR Senpshot

Metribuzin 70% WG Sencor 70

Oryzalin 480g/L SL Surflan

Ethalfluralin 333g/L EC Sonalan

Propaquizafop 100g/L EC Shugn

Fomesafen 250g/L SL Flex

Trifluralin 480g/L EC Floren or Eflurin

Quizalofop-p- tefuryl 40g/L EC Fantrh

Cycloxydim 100g/L EC Focus Ultra

Fluazifop -P- butyl 150 g/L EC Fuzilade froty

Imazapic 240g/L SL Cadre

Fluometuron 500g/L SC Cottogan

Fluometuron 500g/L SC Cottolint

Diflufenican 500g/L SC Quartz

Clomazone 360g/L CS komnd

Pyridate 600g/L EC Lentagran

2,4-D Iso Octylester 480g/L EW Lentmol D

Quizalofop-p- ethyl 100g/L EC Loabord 10

Cinidon Ethyl 200g/L EC Lotuse

Clopyralid 100g/L EC Lontrle

Linuron 410g/L SC Linor

187

Linuron 500g/L SC Linurex

Magnesium chlorate 230g/L SL Mag 18

Ametryne 500g/L SC Amitrex

Iodosulfuron methyl sodium +

Mefenpyr diethyl

5% +15% WG Hosar

Bromacil 80% WP Hybar X

Pendimethalin 330 g/L EC Weed Stop

MOLLUSCIDES الحلزونیة المبیدات


Generic Name


Contant a.i.


Brand Name

Metaldehyde 6% GB Eskar GO

Metaldehyde 5% GB Metazon

Metaldehyde 5% GB Metazon 200

القوارض مبیدات RODENTICIDES


Generic Name


Contant a.i.


Brand Name

Bromadiolone 0.25% SL Ratimon

Bromadiolone 0.005% GB Ratimon G

188

Bromadiolone 2.5% CB Ratimon L

Coumatetralyl 0.0357% GB Racumin

Coumatetralyl 0.75% CB Racumin 57

FUMIGANTS المدخنات

Pesticides


Generic Name


Contant a.i.


Brand Name

Aluminium Phosphide 56% GE Phostoxin

Chloropicrin + Methyl Bromide 30% + 70% GA Bromobec 70

Chloropicrin + Methyl Bromide 2% + 98% GA Mtbrom 980

Chloropicrin + Methyl Bromide 34.7% + 61.1% GA Talobek

Chloropicrin + Methyl Bromide 2% + 98% GA Metfume 98

Magnesium Phosphide 66% TB Magtoxin

Metham Sodium 370g/L SL Adukim

Metham Sodium 370g/L SL Adegan

Metham Sodium 510g/L SL Metmor

Methyl Bromide 100% GA Mtbrom 100

Metham Sodium 370g/L SL Nemasol

189

المبیدات تجھیز صور

AE=Aerosol dispenser أیرسوالت AB= Grain bait حبوب طعم

E=Emulsion مستحلب DP=Sustable powder رطب مسحوق

GA=Gas غاز EO=Emulsion, water in oil زیت في ماء مستحلب

L=Liquid سائل GR=Granule محببات

SG=Water soluble الماء في تذوب محبباتgranules

EC=Emulsifiable concentrate مركز مستجلب

SL=Soluble concentrae ذائب زمرك CB=Bait concentrae مركز طعم

معلقة كبسوالت GB=Granular bait محبب طعم CS=Capsule suspension

EW=Emulsion,oil in water ماء في زیت مستحلب SE= Suspo emulsion معلق مستحلب

RB=Ready bait جاھز طعم OL=Oil miscible liquid زیت

SC=Suspension مركز معلقconcentrate

PA=Paste معجون

SP=Water soluble الماء في یذوب مسحوقpowder

GE=Gas generating product غازیة مادة

WP= Wettable powder مسحوق للبلل قابل

معلقة كبسوالت CS=Capsule suspension

TB = Tablet أقراص Wg= Water Dispersible granules متمیئة غیر محببات

190

Appendix 4: A sample Response

191

192

نابلس كھرباء مشروع في العاملة لمحوالتا

المستخدم الزیت ووزن نوعیة الى إضافة المشروع في العاملة الكھربائیة المحوالت بعدد متزویدك طلبكم الى باإلشارة

- : المطلوب الجدول أدناه

ǃƽƥǁƐ üǋƟǄǁƐ ƕƴƨ ) ƈ ƹ ƿ( ƣƣƴǁƐ

ǅƦǋ ƖǐƦǁƐ ǏǂǀǁƐ ǅƦǋǁƐ / ǃƸǀ

1 160 9

250 2,250

2 250 65

420 27,300

3 400 126

450 56,700

4 630 145

510 73,950

5 1000 8

780 6,240

6 1500 5

1,200 6,000

7 2000 3

1,500 4,500

8 10 MVA 9

6,900 62,100

9 5 MVA 1

3,500 3,500

193

ƱǋǄƜǄǁƐ 371 242,540

: المستخدم الزیت نوع

1. Diala – Ax – IEC 296 2. NYTRO 10XT – NYNAS OIL – IEC 296

السیارات زیوت مع العطاءات شعبة طریق عن المزاد بطریق بیعھ طریق عن الزیت من التخلص یتم

بالعلم التفضل یرجى

Tel: 09 2388568 ; Fax : 09 2388569 ; [email protected]

194

195

Appendix 4b: Product Data Sheet

196

197

198

199

Appendix 5

a) Generated solid waste quantity from Beitlahm and Hebron dumpsites.

200

201

Appendix 5 B: Dumpsite location and size

NO LOCATION / NAME

POINT_X

(PAL SYSTEM)

POINT_Y

(PAL SYSTEM)

Approximate Area (m2)

Bethlehem Governorate

1 Nahhalin 160581.425 120580.879 1000.0

2 Battir 163925.529 126256.444 1000.0

3 Al 'Ubeidiya 180679.068 124450.187 7000.0

4 Dar Salah 181358.502 124364.699 7000.0

5 Husan 161902.385 123906.534 1000.0

6 Zaatara 178518.013 118116.873 3500.0

7 Tquo' 2 – Shuirat current 179598.913 111614.900 1500.0

8 Tqou' old 174736.244 114940.669 1500.0

Hebron Governorate

9 Yatta Current 166785.717 96010.982 150000.0

10 Al Dahriya 150156.660 91157.822 3000.0

11 Idhna 145073.729 105581.018 4000.0

12 Beit Ula 150500.242 112386.760 2000.0

13 Nuba 155209.827 112525.110 3000.0

14 Beit Ummar - soreef 157255.398 115168.498 4000.0

15 Al Shoyokh 168878.914 108592.782 3000.0

16 Bani Na'im 168304.296 104510.103 3000.0

17 Sa'ir 169656.577 108286.557 3000.0

18 Dura 152303.912 105028.385 5000.0

202

203

Appendix 6: Methodoligical method used in Analysing hazardous waste at ZF.

204

1- Pilot Separation of Solid Waste:

An equivalent of 1% of solid waste arrived from each zone (will be called later as pilot sample)

was subjected to separation to identify the presence of Hazardous waste of each different zone

shown in Figure AP1 and was recorded in Table similar to Table AP1.

The segregated hazardous solid waste weight and composition was identified according to Basel

convention.

Determination of the percentage of hazardous waste for each zone was calculated and

recorded.

Table AP1: Average weights of the pilot samples.

Average daily waste

ton/day

Weight of samples

Kg

%

Zone 1

Zone 2

Zone 3

Zone 4

Zone 5

2- Sampling Frequency:

The samples program was as follows:

1. Sampling was conducted over a 2 weeks period. Three days was considered for the pilot

separation in each week.

205

2. During each week samples was taken from the solid waste of the 5 zones. Zone 1 and 2 were

mixed together. Also zone 3 and 4 were also mixed together while zone 5 was sampled alone.

3. Three samples (1 and 2; 3 and 4; and 5) was taken in each of the 3 days differently. This means

that 3 sets of samples was collected during the 3 weeks period, see the schedule shown in Table

AP2

22/1 to 6/2/2010

Fri S S M T W T Fri S S M T W T Fri S M Zones 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31

Z 1&2

Z 3&4

Z5

Z 3&4

Z5

Z 1&2

Z5

Z 3&4

Z 1&2

Table AP2: Sampling Schedule

Apparatus:

The following apparatus shown in Figure AP1 was used in sampling.

Separation table of 1.8 * 1 * 0.8 m covered by steel mesh of 2 * 2 cm

Waste baskets that are labeled with each component.

balance

206

gloves, masks, and hats

brooms and labels

Figure AP2: Apparatus of waste separation

Separation of solid waste was carried out according to the following procedure:

207

1. The samples was selected randomly by the loader

2. Removing the sharps wastes such as needles, broken glass, and etc, to avoid injury for the

laborers.

3. Solid waste items were separated by the laborers into labeled baskets.

4. The weights of samples was recorded in Table 3 and include date, zone number; waste items

name; samples weights.

208

Appendix 7: Outcomes of one of committee’s meetings.

ƥƮƟǄ ƱƑǄƗƜǗƐ ƘǁƑƙǁƐ ƕǆƜǂǁ ǃƑưǆ ƖƑǄǋǂƴǄ ƔƥƐƣƋ ƣƐǋǄǁƐ ƔƥƯƢǁƐ ǋ ƕǄǘƨǁƐ ƕƟƬǁƐǋ ƕǐǆǊǄǁƐ

ƘƥǀƵ Ɨǈƞǃ ƗǈƞǄǃ ǅƓƲǈ ƘƓǆǍǄƶǆ ƖƧƒƥƍ ƥƒǍǆǃƒ ƖƧƱƤǃƒ Ǎ Ɨǆǚƪǃƒ ƗơƮǃƒǍ ǒǈǌǆǃƒƗ ƓǌƵƓǆƙƞƒ ƚǃƓƛǃƒ ƣǒƧƓƙƕ 18/4/2010 Ƨǀǆƕ Ɨƪƪƌǆ ƘƓƽƮƒǍǆǃƒ ƩǒǒƓǀǆǃƒǍ Ĳ ǅƒƧ Ÿƒ ĲƳƧƓƬ Ʃƥǀǃƒ ƧǍươƕ ýǂ Ǉǆ ƘƓǌƞǃƒ ƗǒǃƓƙǃƒ:

1-ǦȝǟǿȂȱǟ ǥǿǟȁȿ ǠȾȲǮȵȿ ȳ .ȧǻǠȎȱǟ ǼȶƮ 2-ǦɅȿǠȶɆȮȱǟ ǧǠȝǠȺȎȲȱ ƗɆȖȆȲȦȱǟ ǻǠƠɍǟ ǠȾȲǮȵȿ ȳ .ɄȭȀǩ ǢɅǽ Ǽǝǟǿ 3- Ɨƪƪƌǆ ƘƓƽƮƒǍǆǃƒ ƩǒǒƓǀǆǃƒǍ ǄƛǆǍƓǌ ǅ .ýǚƕ ǍƕƊ ƔƧǃƒ

ƥƿǍ Ɣǒƺƙ ǇƵ ƧǍươǃƒ ýǂ Ǉǆ ƘƓǌƞǃƒ ƗǒǃƓƙǃƒ:

1- ƗƱǄƪ ƖƥǍƞ ƗƑǒƕǃƒ ƓǌǄƛǆǒǍ ǅ .ǇƒǍƧǆ ǍƕƊ ƔǍǀƶǒ Ǎ ǅ .ƘƕƓƛ ƻƪǍǒ

2-Ɨȕɀȱǟ ǻǠȎǪȩɋǟ ǥǿǟȁȿ ǠȾȲǮƹȿ ȳ . ǧǠǵȀȥ ȯǠȺȵ )ǿɀȒƩǟ ȸȝ ǧǿǾǪȝǟ( 3- ǦɆȹǠƫɉǟ ǦȱǠȭɀȱǟ)GTZ( ȿƹǠȾȲǮ ƆɎƭ ɃǼȹ 4-ȻǠɆƫǟ ǦȖȲȅ ǦɆȺɆȖȆȲȦȱǟ ȿƹǠȾȲǮ ȳ .ȀɅǼǣ ȷǟȿȀȵ

ǿɀȒƩǟ ȸȝ ǿǟǾǪȝɍǟ Ž ǧǠȑȿǠȦƫǟ ȷȿǘȉ ǥȀǝǟǻ ǦȲǮư ǨȵǠȩ Ǽȩȿ

جدول األعمال1- ƗƬƿƓǈǆ ƘƓǒƮǍƙǃƒ Ǒƙǃƒ ǅƓƿ ƩǒƑƧ ƗǈƞǄǃƒ ƓǌưƧƶƕ ǏǄƵ ƇƓưƵǕƒ

1- ƕƪƽƑǆǄ ƖƑǐƬǋƗǁƐ ǏƗǁƐ ǃƑƽ ƧǐƏƥ ƕǆƜǂǁƐ ƑǊƮƥƴƓ ǍǂƳ ƅƑƮƳǓƐ

ƘƬƿƓǈ ƗǈƞǄǃƒ ƘƓǒƮǍƙǃƒ ƘƧƧƿǍ Ɠǆ ǑǄǒ:

1- ƴƼƧ ƘƓǒƮǍƙǃƒ ƧƓƬƙƪǆǄǃ ƥ .ƧǆƓƵ ƨǍǆǌǃƒ

ƧǐƏƥ ƕǆƜǂǁƐ

ǃ .üǘƓ ǋƓƈ ƒƥǁƐ

ƘƓǀƼƧǆ

- ƘƓǒƮǍƙǃƒ

209

ƖƥƓƪǃƒ ƇƓưƵƊ Ɨǈƞǃ ǅƓƲǈ ƘƓǆǍǄƶǆ ƖƧƒƥƍ ƥƒǍǆǃƒ ƖƧƱƤǃƒ ƗǈƞǃǍ Ɨǆǚƪǃƒ ƗơƮǃƒǍ Ɨǒǈǌǆǃƒ

Ɨǒơƙ ƗƕǒƱ ƥƶƕǍ

ƖƑǐƬǋƗǁƐ

1- ýƮƼ ƗǒƞǒƙƒƧƙƪǗƒ ƗǒǈƱǍǃƒ ƗƮƓƤǃƒ ǆǃƓƕƥƒǍ ƖƧƱƤǃƒ Ǐǃƍ ǇǒǒƑƨƞ ƓǆǋǍ

Ɗ- ƘƓǒƓƽǈǃƒ ƖƧƱƤǃƒ

Ɣ- ƥƒǍǆǃƒ ƖƧƱƤǃƒ

ƒƦǋǍ ýƮƽǃƒ Ǉǆ ýƞƊ ǇƊ ǇǍǂǒ ǁǃƓǈǋ ýƮƼ ƘƓǒơǚƮǄǃ ǑƼ ƒƦǋ ƳǍưǍǆǃƒ

ƗƕƪǈǃƓƕ ƳǍưǍǆǃ ƘƓǒƓƽǈǃƒ ƖƧƱƤǃƒ

1- ýƮƼ ƘƓǒƓƽǈǃƒ ƖƧƱƤǃƒ ƗƞƧƓƤǃƒ Ǉǆ ýƨƓǈǆǃƒ ǇƵ ǁǄƙ ƗƞƧƓƤǃƒ Ǉǆ ƗƵƓǈƮǃƒ ƓǈǋǍ Ǉǂǆǒ Ɠǌǆǒƪǀƙ Ǐǃƍ Ǉǒǆƪƿ ǆǋǍƓ

ƘƓǒƓƽǈǃƒ ƖƧƱƤǃƒ Ɨǒǃƨǈǆǃƒ ) ǁǃƦǂǍ ƘƒƧƓƱƍ ÜƘƒƧƓǒƪǃƒ ÜƘƓǒƧƓƱƕǃƒ.......ƣǃƒ (ƓǈǋǍ ǅƙǒ ƇƓǈƛƙùƪƒ ƘƓùǒƓƽǈǃƒ - أƗǒǃƨǈǆǃƒ ǇƵ ǐƊ ƗǒƞǒƙƒƧƙƪƍ ƓǌǈǕ ƻǍƪ ǅƙǒ ƓǌǃƓƪƧƍ Ǐǃƍ ƘƓƕƓǂǆ ƘƓǒƓƽǈǃƒ ǅƙǒǍ ýǆƓƶƙǃƒ Ɠǌƶǆ.

ƘƓǒƓƽǈǃƒ ƗǒƵƓǈƮǃƒ ƓǈǋǍ ƓưǒƊ ǅƙǒ ƇƓǈƛƙƪƒ ƘƓǒƓƽǈǃƒ ƗƞƧƓƤǃƒ Ǉǆ ƘƓǂƧƬ ǕƒƗǒǍƥ ƚǒơ ǊùǈƊ ƥùƞǍǒ ƠƑƒǍùǃ - بƗǒƦǒƽǈƙ ǐƥǃ ƖƧƒƨǍ ƗơƮǃƒ ƭƤƙ ƳǍưǍǆ ƘƓǒƓƽǈǃƒ ƗǒƕƱǃƒ ǉƦǋǍ ƠƑƒǍǄǃƒ ýǆƬƙ ƘƓǂƧƬ ƗǒǍƥǕƒ.

2- ƘƓǒƓƽǈǃƒ ƗǒƵƓǈƮǃƒ ƓǈǋǍ ƓưǒƊ ǅǒ ƥƓƞǒƍ ƠƑƒǍǄǃƒ Ɨǒǈƽǃƒ ƗƮƓƤǃƒ ýǂƕ Ǉǆ ƖƧƒƨǍ ƥƓƮùƙƿǙƒ ǑǈƱǍùǃƒ ƗƱǄùƪǍ ƖƥǍƞ ƗƑǒƕǃƒ ƚǒơƕ ǅƙǒ ƓǌƶưǍ ƾƓƽƙǙǍ ǏǄƵ Ɨǒǃƈ ƫǒƙƽƙǃƒ ƚǒơ ǊǈƊ ƓǒǃƓơ Ǚ ƥƞǍǒ ýƛǆ ƒƦǋ ƾǒƿƥùƙǃƒ ǍƊ ƫǒùƙƽƙǃƒ ƓǆǂǍ ƲơǍǃ ǊǈƊ ǅƙǒ ǅƒƥƤƙƪƒ ƘǍǒƨ ƘƒƧƓǒƪǃƒ ǑƼ Ưƶƕ ƘƓƵƓǈƮǃƒ.

3- ƔǄƱǃƒ Ǉǆ ƘƓǌƞǃƒ ƗƮƙƤǆǃƒ ) ƖƧƑƒƥ ƘƓưǍƓƽǆǃƒ (ǇƊ ǇǍǂƙ ƗơưƒǍ ǑƼ ƘƓƿƓƽƙƒ ƴǆ ƘƓǌƞǃƒ ƗǒƞƧƓƤǃƒ ǊùǈƊ ǑƼ ƥǈƕ ƾǄƶƙǆǃƒ ǑƼ ƘƓǒƓƽǈǃƒ ƖƧƱƤǃƒ ƗƶƞƒƧǆ ǉƦǋ ƠƑƒǍǄǃƒ ƕƿý ƴùǒƿǍƙǃƒ ǏùǄƵ ǐƊ ƗùǒƿƓƽƙƒ ƗǒǄƕǀƙƪùǆ ŹƒƧùƲǈ ǇƊ

ƳǍưǍǆ ƗƑǒƕǃƒ Ǚ ýƒƨǒ ƫƿƓǈǒ ýǂƬƕ ǅƓƵ ƴǆ ƔǈƓƞǃƒ ǑǄǒƑƒƧƪǗƒ.

Ɣ- ƥƒǍǆǃƒ ƖƧƱƤǃƒ

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1- ƔǄƱǃƒ Ǉǆ Ɨƪƪƌǆ ƘƓƽƮƒǍǆǃƒ ƩǒǒƓǀǆǃƒǍ ýǆƵ ƠƑƒǍǄǃƒ ƗǒƦǒƽǈƙǃƒ ƗƮƓƤǃƒ ƥƒǍǆǃƓƕ ƖƧƱƤǃƒ.

2- ƔǄƱǃƒ Ǉǆ Ɨƪƪƌǆ ƘƓƽƮƒǍǆǃƒ ƩǒǒƓǀǆǃƒǍ ýǆƵ ƘƓƽùƮƒǍǆǃƒ ǆǃƒ ƗùǄǀƶƙ ǑùƼ ƥƒǍùǆǃƒ ƖƧùƱƤǃƒ ) Üýùǀǈ ÜǇǒƨƤƙ.....ƣǃƒ (ƴǆ ǅǄƶǃƒ ǊǈƊ ƓǒǃƓơ ǅƙǒ ƗƬƿƓǈǆ ƗƽƮƒǍǆ ƗǒǈǒƱƪǄƼ ƾǄƶƙƙ ƝǒƧƓǌƮ ýǀǈ ƥƒǍǆǃƒ ƖƧƱƤǃƒ.

3- ƔǄƱǃƒ Ǉǆ ýǂ ƘƒƧƒƨǍǃƒ Ɨǒǈƶǆǃƒ ƥƒǍǆǃƓƕ ƖƧƱƤǃƒ ƥƓƞǒƍ ƘƒƧƕƙƤǆǃƒ Ɨǆƨǚǃƒ ƭơƽǃ ǉƦǋ ƥƒǍǆǃƒ ǍƊ ƥƓƞǒƍ Ǌǒǃƈ ƭơƽǃ ǉƦǋ ƥƒǍǆǃƒ.

4- ƥƓǆƙƵƒ ǅƓƲǈ) GIS (ƘƓǒƓƽǈǄǃ ƖƧƱƤǃƒ Ǉǂǆǆ ǁǃƦǍ ƥƶƕ ƾƓƽƙǙƒ ƴǆ ƘƒƧƒƨǍǃƒ Ɨùǒǈƶǆǃƒ ƳǍùưǍǆƕ ƘƓùǒƓƽǈǃƒ ƖƧƱƤǃƒ.

5- ƗƶƞƒƧǆ ƖƧƒƨǍ ƗơƮǃƒ ƭǍƮƤƕ ƳǍưǍǆ Ɨǆǚƪǃƒ ƗǆƓƶǃƒ ƚǒơ ǊǈƊ ƥƞǍǒ ƖƧƒƥƍ Ɨǒǈƶǆ ǑƼ Ɨǆǚƪǃƒ ƗùǆƓƶǃƒ ǁǃƦǂǍ ƖƧƒƨǍ ýǆƶǃƒ.

6- ƔǄƱǃƒ Ǉǆ Ɨƪƪƌǆ ƘƓƽƮƒǍǆǃƒ ƩǒǒƓǀǆǃƒǍ ýǆƵ ƘƓƽƮƒǍǆǃƒ ƱǆǃƒƗƕǍǄ ƭǍƮƤƕ Ɨǆǚƪǃƒ ƗǆƓƶǃƒ.

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212

Appendix 8: Analytical sample result of Kufl Haris Waste.

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214

215

216

Appendix 9: Special precautions for managing and storing hazardous waste

Here you can find a list that intended to indicate the need for special precautions when managing

these incompatible HW:

Oxidizers waste should be kept separate from organics, flammables and combustibles Segregate from other materials like cyanides, sulfides, and isocyanates Separate halogenated from non-halogenated used solvents and store them in appropriate containers away

from heat and ignition sources

Material exhibiting unstable, highly reactive, explosive or extremely toxic properties should be kept separate from other waste and

stored in an isolated area prior to disposal pick up

The following are examples of incompatible hazardous materials:

Hazardous Material Symbols or example

Flammables and oxidizers

Elemental metals and hydrides

Mercury (Hg) & Sodium Borohydride (NaBH4)

Cyanides and acids Sodium Cyanide (NaCN) & Hydrochloric Acid (HCl)

Sulfides and acids Sodium Sulfide (Na2S) & Hydrochloric Acid (HCl)

Bases and acids Sodium Hydroxide (NaOH) & Sulfuric Acid (H2SO4)

Flammables and acids

Chlorine compounds and Calcium Hypochloride (Ca (OCl)2 & Sulfuric Acid

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To stor the Hazardous materials in safe conditions, the following regulations can be used.

You have to differential HZW from non as in the following flow diagram.

acids (H2SO4)

Chlorine compounds and amines

Sodium Hypochloride & Aniline

Air or water reactive and anything

Calcium carbide (CaC2) and Water (H2O)

Organic peroxides and anything

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Yes

Hazardous Waste

Is the material a waste?(can not be reused, recycled)

Is your waste within the categories in appendix 9

Does the waste contain hazardous substances?

CHECK

Labels of substances

Yes

No

Yes

Non-Hazardous Waste

No

Not sure

Contact EQA / or other resource institutions for advice

Continue to use No

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Segregate liquid HZW from solid HZW Store the HZW and hazardous materials separately in compatible groups to avoid the possibility that their

vapors or gas react together (e.g. of incompatible materials: oxidizers and flammables) Store all compatible hazardous materials in one place to monitor closely their use and limit and control the

access to this area (do the same with HZW) Respect the stocking conditions recommended on MSDS available from suppliers Use containers made of, or lined with, material that is compatible with HZW to be stored Maintain the containers in good condition and change the leaking ones Keep the containers closed all the time except when removing wastes Never completely fill any container containing liquid hazardous waste, allow at least two inches of air space

near the top Label correctly the HW containers by using the words “Hazardous Waste” or according to the hazard class

in order to prevent mistakes on the part of the employees Put in the storage area warning signs describing

precautionary and preventive measures

Storage of HW in fume hoods or under sinks is not recommended

Provide sufficient ventilation to keep humidity, temperature and concentration of fumes and

vapors at a low level

Make sure that the floor of the storage area is made of non-permeable material to prevent contamination of soil and groundwater and keep the area clean

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[Source: Hazardous Waste Management Training Kit of UNEP, David Wilson, Fritz Balkau, Maggie Thurgood]

Ensure that storage sections are provided with containment area to contain any spillage. The floor of the containment area shall be lined with a material compatible with the stored material

Pay attention that the floor of the storage area is flat to allow easy handling of hazardous materials or HZW containers to prevent spills

Equip the storage area with portable fire extinguishers and alarm system Leave enough space between containers to facilitate the inspection and the handling Make sure that the storage area there has at least 2 clearly marked exits (e.g. doors, windows) that are

always accessible (not blocked by materials or locked) Containers must be inspected weekly for signs of leaks, corrosion, or deterioration Inspect regularly (at least weekly) the storage areas of HZW and hazardous materials Mark the containers with the starting date when the HZW were generated Ensure that flammable substances are not exposed to direct sunlight in order to avoid self-inflammation Do not place ignitable or reactive waste in tanks unless certain precautions are taken Carry out regular checks and keep written records

An appropriate storage requires a labeling system. The Hazardous Waste labeling must clearly identify the following information:

The content of the container The hazard symbol of the contents The degree of the hazard of the contents Initial date of the collection and the closure

date Initial date of the collection and the closure

date The name and the address of the waste

generator

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In addition, the label must contain the following statement

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Appendix10: Harmful and Hazardous Waste Categories to be controlled in the POt according to Basel Convention

Code Categories of hazardous waste to be controlled In the POt

Y1 Clinical wastes from medical care in hospitals, medical centers and clinics

Y2 Wastes from the production and preparation of pharmaceutical products

Y3 Waste pharmaceuticals, drugs and medicines

Y4 Wastes from the production, formulation and use of biocides and phytopharmaceuticals

Y5 Wastes from the manufacture, formulation and use of wood preserving chemicals

Y6 Wastes from the production, formulation and use of organic solvents

Y7 Wastes from heat treatment and tempering operations containing cyanides

Y8 Waste mineral oils unfit for their originally intended use

Y9 Waste oils/water, hydrocarbons/water mixtures, emulsions

Y10 Waste substances and articles containing or contaminated with polychlorinated biphenyls (PCBs) and/or polychlorinated terphenyls (PCTs) and/or polybrominated biphenyls (PBBs)

Y11 Waste tarry residues arising from charcoal plants

Y12 Wastes from production, formulation and use of inks, dyes, pigments, paints, lacquers, varnish

Y13 Wastes from production, formulation and use of resins, latex, plasticizers, glues/adhesives

Y14 Waste chemical substances arising from research and development or teaching activities which are not identified and/or are new and whose effects on man and/or the environment are not known

Y15 Wastes of an explosive nature not subject to other legislation

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Y16 Wastes from production, formulation and use of photographic chemicals and processing materials

Y17 Wastes resulting from surface treatment of metals and plastics

Y18 Residues arising from industrial waste disposal operations

Y21 Hexavalent chromium compounds

Y22 Copper compounds

Y23 Zinc compounds

Y24 Arsenic; arsenic compounds

Y26 Cadmium; cadmium compounds

Y28 Tellurium; tellurium compounds

Y29 Mercury; mercury compounds

Y30 Thallium; thallium compounds

Y31 Lead; lead compounds

Y32 Inorganic fluorine compounds excluding calcium fluoride

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Code Categories of hazardous waste to be controlled

Y33 Inorganic cyanides

Y34 Acidic solutions or acids in solid form

Y35 Basic solutions or bases in solid form

Y36 Asbestos (dust and fibers)

Y37 Organic phosphorus compounds

Y38 Organic cyanides

Y39 Phenols; phenol compounds including chlorophenols

Y40 Ethers

Y41 Halogenated organic solvents

Y42 Organic solvents excluding halogenated solvents

Y43 Any congenor of polychlorinated dibenzo-furan

Y44 Any congenor of polychlorinated dibenzo-P-dioxin

Y45 Organohalogen compounds other than substances referred to in this Annex (e.g. Y39, Y41, Y42, Y43, Y44)

For detailed subcategories, consult Basel Convention classification document

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Appendix 11: Suggested forms for Notification of Hazardous waste activity and tansboundary movement.

Evident for Transportation and Disposal of Hazardous Waste

Manifest for Transportation and Disposal of Hazardous Waste

Copy To EQA Environment Quality Authority, EQA

Copy To Waste Generator Ramalla

Copy To The Treatment, Storage and Disposal Facility Tel: 02 240 3498

Copy To Transporter Fax:

P.O. Box

Ramalla West Bank

1. Generator Information

The Listed Material In Paragraph 2 Has Been Collected From (Generator Facility Name) ………………………………………………………………………..

And Transported To …………………………………………………………..

Based On The Recommendation Of .

Generator Name …………………. Title …………. Signature ……………

Time (Hrs: Min) ………:…………. Date / /

Address ………………………. Tel. No. …….………. Fax ………………….

Carrier Company Name ……………………….. Tel. No. ……………

Address ………………………..……..……………….. Fax No. ……………

2. Hazardous Waste Description

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a- General Waste Description ………………………………………………

b- Waste Physical State

Solid Semi Solid Sludge Liquid

Other (Describe) ……………………………………………………

c- Hazard Class

Toxic Flammable Corrosive

Explosive Poisons other (describe) …………

d- Waste Class

Waste Oil Chemical Materials Inorganic

Halogens Solvents Pesticides

e- Waste Information

Waste Weight/ Volume …………… No. Of Transport Vehicles………….

Vehicle Capacity ……………………………….

f- Specify Activities That Generated The Waste

3. Transporter

a- I Certify That I Collected The Wastes Listed In Paragraph 2 Above And The Declared Materials Are Accurate.

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b- The Above-Mentioned Wastes Were Transported From ………………………..

Time (Hrs : Min) ………:…………. Date …………………………….

Name : ……..……… Signature: ……….. Vehicle License No. ……….

4. Treatment Storage And Disposal Facility (TSDF)

a- The Waste Listed In Paragraph 2 Above Was Treated/ Disposed Of Let Location …………………………………………………….

b- Method Of Treatment/ Disposal ……………………………………………...

Landfill Treatment Incineration Chemical Treat.

Detonation Other (Specify) ………………………….………

5. Environment Quality Authority (EQA)

a- The EQA certifies that the waste listed in paragraph 2 above have been received / treated / disposed of on date …………….. The Waste Belongs To: Generator Name ………………………………….

b- Environment Quality Authority Representative ………………………………..

c- Title……………………………..…..d- signature………………..……..………

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Appendix 12: Arabic summary of the tanning wastewater treatment unit as reported by CH2M HILL

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230

231

232

Appendix 13: Hazardous materials in the Palestinian Enterprises

Data taken from References 100 and 101 listed in the references.

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Chemical Name

Formula CAS Route Hazardous LD50 LC50 Toxic dose

Barium peroxide Ba-O2 1304-29-6

mucous membranes, throat, & nose

Corrosive LD50 Mouse sc 50 mg/kg

1-Naphthylamine C10-H9-N 134-32-7

eyes and the skin

Toxic LD50 Rat oral 680 mg/kg bw

LC50 Rat inhalation >0.056 mg/L/4 hr

Calcium carbonate CaCO3 471-34-1

Oral Toxic LD50 Mouse oral 6450 mg/kg bw

LC50 Gambusia affinis (Western mosquitofish) >56,000 mg/L/24-96 hr

Benzole C6-H6 71-43-2

eye and moderate skin

Flammable 50 Rat oral 3306 mg/kg

LC50 Rat ihl 10,000 ppm/7 hr

50-500 mg/kg

Methanol C-H4-O 67-56-1

eye and skin Flammable LD50 Rat oral 5628 mg/kg

LC50 Cat inhalation 85.41 mg/L/4.5 hr

is between 0.3 and 1 g/kg.

ferrous oxide FeO2 1345-25-1

lung and gastrointestinal

spontaneously flammable

LD50 Rat oral >15 g/kg /Iron oxide

LC50 Gambusia affinis (Western mosquitofish) >10,000 mg/L/24

Iron(III) oxide Fe2O3 1309-37-1

Noncombustible

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carbon tetrachloride Ccl4 56-23-5

inhalation probable human carcinogen

LD50 Rat oral 2920 mg/kg

LC50 Lepomis macrochirus (Bluegill) 125,000 ug/l/96 hr

Tetrachlorethylene (C2CL4)

C2-Cl4 127-18-4

Skin Corrosion LD50 Oral Mouse 6000-8571 mg/kg

LC50 Rat inhalation 4100 ppm/6 hr

tetrachloroethane (C2H2CL4) C2-H2-Cl4 25322-20-7 Oral Skin

Toxic LD50 Rat oral 317 mg/kg

LC50; Species: Oryzias latipes freshwater, static, 30 deg C; Concentration: 39000 ug/L for 24 hr

Ethyl methyl ether C3-H8-O 540-67-0 through inhalation

HIGHLY FLAMMABLE

Pentachlorophenol C6-H-Cl5-O 87-86-5 Skin, Eye and Respiratory

probable human carcinogen

LD50 Rat male oral 146 mg/kg

LC50 Tubifex tubifex 286, 619, and 1294 ug/l/24 hr

Acrylonitrile C3-H3-N 107-13-1 eye, mucous membrane, and skin

Corrosive LD50 Rat sc 80 mg/kg


Glycol ether C4-H10-O3 111-46-6 eye and human skin

Combustable LD50 Rat oral 15.6 g

LC50; Species: Xenopus laevis

1 mL/kg.

235

/kg 3065000 ug/L for 48 hr

Dimethyl sulfate C2-H6-O4-S 77-78-1 eye and skin Corrosive LD50 Mouse ip 61 mg/kg bw

LC50 Mouse inhalation 280 mg/cu m/4 hr

exceeding approx 5 mg/cu m (1 ppm)

Dinitrobenzene (all isomers) C6-H4-N2-O4

25154-54-5 Resp tract Toxic

Dinitro-o-cresol C7-H6-N2- 534-52-1 eye and skin Explosive LD50 Rat oral 26 LC50 GAMMARUS oral lethal dose 5-

Lemeon peel oil UNKNOWN 8008-56-8 Polyurethane Acrylamide C3-H5-N-O 79-06-1 Skin Toxic LD50 Rat male

oral 565 mg/kg LC50 Pimephales promelas (fathead minnow) 109 mg/l/96 hr

Ethyl acrylate C5-H8-O2 140-88-5 Skin, Eye and Respiratory

Flammable LD50 Rat oral 760-1020 mg/kg

LC50 Rat inhalation 1000-2000 ppm/4 hr

Ethylamine C2-H7-N 75-04-7 skin, mucous membranes, and respiratory tract

F LD50 Rat oral 530 mg/kg bw

LC50 Rat inhalation 12.6 mg/L/4 hr

Ethyl benzene C8-H10 100-41-4 eye F LD50 Rat oral 5.46 g/kg

LC50 Lepomis macrochirus 32 mg/l/96 hr

Ethyl bromide

C2-H5-Br 74-96-4 eyes and respiratory

Confirmed animal carcinogen Corrosive

LD50 Rat ip 1750 mg/kg

LC50 Rat inhalation 27,000 ppm/1 hr

236

O5 to 65 mg/kg FASCIATUS (SCUD) 1,100 UG/L/96 HR

50 mg/kg

Dinitrotoluene C7-H6-N2-O4

25321-14-6 Eye Combustible

Dioxane (Diethylene dioxide)

123-91-1 eye, skin, and respiratory system

probable human carcinogen


LC50 Rat inhalation 46 g/cu m/2 hr

470 ppm

Diphenylmethane diisocyanate

C15-H10-N2-O2

101-68-8 A skin and eye flammable LC50 Rat (male) inhalation 369 mg/cu m/4 hr

Dipropylene glycol methyl ether

C7-H16-O3 34590-94-8 Skin and eye F LD50 Rat oral 5.35 g/kg

Endrin C12-H8-Cl6-O

72-20-8 Oral Corrosive LD50 Rat female dermal 15 mg/kg

LC50 ASELLUS BREVICAUDUS (SOWBUG) 1.5 UG/L/96 HR

Epichlorohydrin C3-H5-Cl-O 106-89-8 nose & eye probable human carcinogen Flammable



EPN C14-H14-N-O4-P-S

2104-64-5 skin and eyes Toxic LD50 Rat (female) oral 8 mg/kg

LC50 Rat inhalation 160 mg/cu m/1 hr

1,2-Epoxypropane C3-H6-O 75-56-9 skin, eyes, and respiratory system

probable human carcinogen FLAMMABLE

LD50 Rabbit skin 1245 mg/kg

LC50 Mouse inhalation 1740 ppm/4 hr

2,3-Epoxy-1-propanol C3-H6-O2 556-52-5 eyes and upper respiratory tract, & a skin

human carcinogen


Ethanethiol C2-H6-S 75-08-1 eyes and skin Extremely flammable



Ethanolamine C2-H7-N-O 141-43-5 skin, eyes, respiratory system

Combustible LD50 Rats oral 10.2 g/kg

LC50 Carassius auratus (Goldfish) 190 mg/L/24 hr

237

2-Ethoxyethanol (Cellosolve)

C4-H10-O2 110-80-5 Eyes Flammable LD50 Rat oral 3.46 g/kg


approximately 100 ml for a 70 kg person

2-Ethoxyethyl acetate (Cellosolve acetate)

C6-H12-O3 111-15-9 Skin F LD50 RAT MALE ORAL 3900 MG/KG


approximately 100 mL for a 70 kg

Dimethylformamide C3-H7-N-O 68-12-2 skin F LD50 Mouse oral 6.8 ml/kg

LC50 Salmo gairdneri (rainbow trout) 12,000 mg/l/96 hr

3500 ppm is considered immediately dangerous to life or health (IDLH

1,1-Dimethylhydrazine C2-H8-N2 57-14-7 skin, eyes, Corrosive LD50 Mouse ip 113-290 mg/kg


Chlorine trifluoride Cl-F3 7790-91-2 eyes, respiratory system

Corrosive LC50 Mouse inhalation 178 ppm/1 hr

Chloroacetaldehyde C2-H3-Cl-O 107-20-0 EYES, NOSE, & THROAT

F

a-Chloroacetophenone (Phenacyl chloride)

C8-H7-Cl-O 532-27-4 respiratory tract and the skin

Toxic LD50 Rat oral 127 mg/kg

10 MINUTE EXPOSURE TO 0.85 MG/L

Chlorobenzene C6-H5-Cl 108-90-7 eyes and nose Corrosive LD50 Rat oral 2.29 g/kg

LC50 Mouse (female) inhalation 1886 ppm (8.8 mg/L) for 6 hr

Chlorobromomethane C-H2-Br-Cl 74-97-5 Skin Corrosive LD50 Mouse oral 4300 mg/kg


2-Chloro-1,3-butadiene C4-H5-CL 126-99-8 Eye and Respiratory

F LD50 Rat oral 450 mg/kg

LC50 Rat inhalation 11,800 mg/cu m/4 hr

238

1-Chloro-2,3-epoxypropane C3-H5-Cl-O 106-89-8 nose & eye irritation

probable human carcinogen F



2-Chloroethanol C2-H5-Cl-O 107-07-3 eyes and respiratory


LC50 Pimephales promelas (fathead minnow) 83.7 mg/l/96 hr

50-500 MG/KG

bis(Chloromethyl) ether C2-H4-Cl2-O 542-88-1 EYES, RESPIRATORY TRACT

human carcinogen

LC50 Rat /ihl/ 5-7 ppm/6-7 hr

Chloromethyl methyl ether C2-H5-Cl-O 107-30-2 Skin Corrosive LD50 Rat oral 0.5 g/kg

LC50 Rat /ihl/ 5-7 ppm/6-7 hr

1-Chloro-1-nitropropane C3-H6-Cl-N-O2

600-25-9 Skin, Eye and Respiratory

F LD50 Rabbit oral between 50 and 100 mg/kg

50-500 MG/KG;

Dicyclopentadienyl iron C10-H10-Fe 102-54-5 eye, skin, and respiratory

F LD50 Mouse oral approx 600 mg/kg

Dieldrin C12-H8-Cl6-O

60-57-1 probable human carcinogen Slightly corrosive

LD50 Rat oral 38.3 mg/kg

LC50 Tubifex & Limnodrilus (mixed cultures) 6700 ug/l/96 hr

Diethylamine C4-H11-N 109-89-7 eyes, nose, and throat

Corrosive LD50 Mouse oral 649 mg/kg bw

LC50 Rat inhalation 17.3 mg/L/4 hr

20 g

2-Diethylaminoethanol C6-H15-N-O 100-37-8 skin, eye, and respiratory

F LD50 Rat oral 1,300 mg/kg

LC50 Pimephales promelas (fathead minnow) 1780 mg/l/96 hr

Difluorodibromomethane C-Br2-F2 75-61-6 Nose Toxic Diglycidyl ether (DGE) C6-H10-O3 2238-07-5 skin, eyes, and

respiratory Combustible LD50 Mouse iv

100 mg/kg LC50 Mouse inhalation 86 ppm/4 hr

239

Dihydroxybenzene C6-H6-O2 123-31-9 eyes, skin, and resp system


LC50; Species: Daphnia magna 90 ug/L for 24 hr

5 to 12 g.

Diisopropylamine C6-H15-N 108-18-9 A skin and severe eye

Corrosive LD50 Rat oral 770 mg/kg

LC50 Rat ihl 4800 mg/cu m/2 hr

Che mi cal N ame FORMU LA CAS ROUTE HAZ ARDOUS LD50 LC50 TOXIC DOSE

240

Acetaldehyde volatile liquid C2-H4-O

75-07-0 skin, eye and respiratory

Flammable LD50 Rat oral 1930 mg/kg The 4-h LC50 of

acetaldehyde in rats was

determined and found to

be 13,300 ppm (24.0 g/m3

air

Acetic acid liquid C2-H4-O2


Flammable LD50 Rat oral 3.53 g/kg

LC50 Fathead minnows >315 mg/L/1 hr; 122 mg/L/24 hr; 92 mg/L/48 hr; 88 mg/L/72 hr; 88 mg/L/96 hr (static bioassay in Lake Superior water at 18-22 deg C)

workers exposed for 7-12 yr at concentrations

of 60 ppm, plus 1 hr daily at 100-200 ppm

Acetone liquid C3-H6-O

67-64-1 eyes and nose Flammable Explosion

LD50 Rat oral 10.7 mL/kg

LC50 Coturnix japonica (Japanese quail, age 14 days) oral >40,000 ppm

In children 2 to 3 mL/kg is considered to

be toxic Zinc oxide Powder

ZnO

1314-13-2 oral eye dermal inhalation

contact with water liberates highly flammable gases


LC50 Lepomis macrochirus (Bluegill sunfish, weight 0.38 g) >320 ppm/96 hr

Lead

Solid Pb

7439-92-1 oral flammable in the form of dust

>5,000 ppm 10-30 grams

Allyl alcohol mobile liquid C3-H6-O

107-18-6 eye, skin, or resp irritation

flammable LD50 Rabbit percutaneous 89 mg/kg

LC50 Goldfish 1 mg/l/24 hr

Aluminum Solid AL

7429-90-5 lungs & eyes violently explosive

LC50 Pisidium casertanum >1.0 mg/L/96 hr

mouth is about 30 g.

Ammonia gas NH3

7664-41-7 the vapor even in low concn is

corrosive, alkaline gas


LC50 Daphnia magna 24 mg/L/48 hr

LCLo Human inhalation 7,000 mg/cu m/3 hr

241

extremely irritating to skin, eyes and respiratory

Ammonium sulfamate

crystalline solid H3-N-O3-S.H3-N


corrosive LD50 Mouse oral 3100 mg/kg

LC50 Carp (young) 1,000-2,000 mg/L/48 hr

Sodium sulfate

Solid H2-O4-S.2Na


nonflammable noncombustible solid

LD50 Rabbit percutaneous > 4.0 g/kg

LC50 Aspergillus 80 ppm/40 hr at 32 deg C

500 mg/l

Arsenic, inorganic compounds

As 7440-38-2 skin eye

corrosive LD50 wild Norway rat oral 104 mg/kg

LC50 Penaeus seliferus (white shrimp, juvenile) 24,700 ug/l/96 hr

Skin 17 ppm Eye 3ppm

Arsine colorless gas As-H3

7784-42-1 inhalation flammable

LD50 Mouse ip 2.5 mg/kg

LC50 Mouse inhalation 0.67 mg/kg/2.4 min

500 ppm

Asbestos fine, slender, flaxy fibers UVCB

1332-21-4 respiratory carcinogenic

Benzyl chloride to slightly yellow liquid. C7-H7-Cl

100-44-7 eyes and respiratory skin


LC50 Penaeus setiferus (white shrimp) 7.1 mg/L/24 hr

Biphenyl crystalline solid C12-H10

92-52-4 eyes, skin, and mucous membrane and upper respiratory tract

flammable LD50 Rat oral 3280 mg/kg

LC50 Cyprinodon variegatus (Sheepshead minnow) 4.6 mg/L/96 hr

Bromine Liquid Br2

7726-95-6 skin corrosive material

LD50 Rat ip 85.2 ppm

1000 ug/L for 48 hr

Bromoform colorless heavy liquid C-H-Br3

75-25-2 eyes and nose corrosive LD50 Rat male oral 1388 mg/kg

1 mg/L for 48 hr

Copper malleable metal Cu

7440-50-8 eyes, nose and throat

Cresol pinkish liquid C7-H8-O

1319-77-3 eyes, nose, and throat

flammable LD50 Rat oral 1454 mg/kg

LC50 Gammarus fasciatus /(Scud/, immature stage)

242

7.0 mg/L/48 hr Cyclohexanone oily liquid

C6-H10-O 108-94-1 mucous

membranes corrosive flammable

LC50 Pimephales promelas (fathead minnow) 527 mg/l 96 hr

Cyclohexene colorless liquid C6-H10

110-83-8 eyes, the skin and the respiratory tract.

highly flammable

LD50 Rat oral 2.4 mL (1946 mg)/kg

LC50; Species: Daphnia magna (Water flea); Conditions: freshwater; static; Concentration: 9400 ug/L for 48 hr

Cyclopentadiene colorless liquid C5-H6

542-92-7 eyes and nose flammable LC50 Rat inhalation 39 mg/L/1 hr

1,2-Dibromo-3-chloropropane (DBCP)

colorless liquid C3-H5-Br2-Cl

96-12-8 skin, mucous membranes

combustible

LD50 Rabbit (male) oral 100 mg/kg

PHASIANUS COLCHICUS (RING-NECKED PHEASANT) 3-4 MO FEMALES ORAL 156 MG/KG

Dibutyl phthalate oily liquid C16-H22-O4


explosive flammable


LC50 Anas platyrhynchos (Mallard duck, age 10 days) oral >5000 ppm/8 days

Dichlorobenzene C6-H4-Cl2 25321-22-6 skin, eyes, and respiratory system

flammable 10000 ug/L for 48 hr

Dichloromethane colorless liquid C-H2-Cl2

75-09-2 eyes and respiratory tract

flammable LD50 Mouse inhalation 16000 ppm/7 hr plus 1 hr observation

LC50 Pimephales promelas Rafinesque (fathead minnows) 193 mg/l/96 hr

exposure to 100 ppm

diethyl ether mobile liquid C4-H10-O

60-29-7 oral eye nose

toxic flammable

LD50 Mouse iv 996 mg/kg bw

LC50 Poecilia reticulata (guppy) 2134 mg/L for 14 days

Fluorine gas or liquid F2

7782-41-4 eye, mucous membrane, & skin irritant

corrosive gas

LC50 values for these animals ranged from 150 ppm for mice

500 mg/kg has been fatal to humans

Formaldehyde colorless gas liquid C-H2-O

50-00-0 eye, skin and respiratory system

corrosive flammable liquid

LD50 Rat oral 100 mg/kg /SRP

LC50 /Morone saxatilis/ (Striped bass, larvae) 10 mg/L/48-96 hr

523 mg/kg based on ingestion

243

Formic acid fuming liquid C-H2-O2

64-18-6 skin and severe eye irritant


LC50 Daphnia magna 34 mg/L/24 hr

Glycerin (mist) clear, colorless syrupy liquid C3-H8-O3

56-81-5

human eye explosion LC50 Goldfish >5000 mg/l/24 hr

n-Hexane very volatile liquid C6-H14

110-54-3 eyes and nose skin

flammable LD50 Rat (14-day-old) oral 24.0 mgl/kg bw

LC50 Daphnia magna >50 mg/l/24 hr

Hydrazine colorless oily liquid H4-N2

302-01-2 mucous membranes, nose, throat, and upper respiratory tract.

flammable liquid


LC50 Lepomis macrochirus (Bluegill sunfish) 1.08 mg/L/96 hr

Hydrogen bromide colorless gas HBr

10035-10-6 eyes, skin, mucous membranes, respiratory tract

corrosive LC50 Rat inhalation 2858 ppm/1 hr

Hydrogen chloride liquid HCL

7647-01-0 skin corrosive explosive

LD50 Mouse ip 1449 mg/kg


Hydrogen cyanide colorless gas or liquid C-H-N

74-90-8 skin and eyes respiratory

flammable LD50 Rat sc 3700 ug/kg

LC50 Rat inhalation 3778 mg/cu m (10 sec)

Lethal adult dose of hydrogen cyanide is 50

mg Hydrogen peroxide colorless liquid

H2O2 7722-84-1 eye, nose,

throat, skin powerful oxidizer

Iodine violet solid. I2

7553-56-2 nose ... skin rash , eye

vapor is corrosive

LD50 Rat oral 14 g/kg

2 and 4 g of free iodine

Methyl propyl ketone

colorless liquid C5-H10-O

107-87-9 irritates the eyes, skin, and respiratory

flammable LD50 Rat oral 3.73 g/kg

LC50 Pimephales promelas (Fathead minnow, age 32 days, mean length 18.4 mm, mean weight 0.095 g) 1240 mg/L/96 hr

Morpholine Liquid C4-H9-N-O

110-91-8 eyes, nose, throat, lungs and skin

corrosive LD50 Rat oral 1.05 g/kg

Naphtha (Coal tar) Liquid UVCB

8030-30-6 respiratory tract highly flammable

LD50 Rat oral >25 ml/kg bw

LC50 Rat inhalation 73,680 ppm for 4 hr

244

Naphthalene Solid C10-H8

91-20-3 skin eye oral

corrosive flammable

LD50 Sprague Dawley rat oral 2.6 g/kg

LC50 Oncorhynchus gorbuscha (pink salmon) 1.4 mg/L/96 hr

approximately 2 g.

Nickel carbonyl colorless liquid C4-Ni-O4


carcinogenicity corrosive

LC50 RAT INHALATION 35 PPM/30 MIN

Nickel silvery solid Ni

7440-02-0 oral carcinogen flammable

Nitric acid fuming liquid H-N-O3

7697-37-2 skin, eyes, and mucous membranes

corrosive LC50 Mouse inhalation 67 ppm/4hr

Oxalic acid colorless powder or granular solid C2-H2-O4

144-62-7 eyes and upper respiratory tract

toxic gases LDLo Dog oral 1000 mg/kg

Sodium hydroxide colorless to white ... solid H-Na-O

1310-73-2 skin, eyes, and mucous membranes

corrosive LD50 Mouse ip 40 mg/kg

LC100 CYPRINUS CARPIO 180 PPM/24 HR

Tetrachloroethylene colorless liquid C2-Cl4


corrosion LD50 Oral Mouse 6000-8571 mg/kg


Tetrachloroethane C2-H2-Cl4 25322-20-7 LD50 Rabbit dermal 6330 mg/kg

LC50; Species: Oryzias latipes (Medaka, high-eyes); Conditions: freshwater, static, 30 deg C; Concentration: 39000 ug/L for 24 hr

Titanium dioxide O2-Ti 13463-67-7 respiratory skin

not combustible

Toluene colorless liquid C7-H8

108-88-3 skin and severe eye

flammable LD50 Rat oral 2.6 to 7.5 g/kg

LC50 FOR BLUEGILL WAS 17 MG/L/24 HR & 13 MG/L/96 HR

60 ml (625 mg/kg)

2-Butanone (Methyl ethyl ketone)

colorless liquid C4-H8-O


highly flammable liquid

2-Butoxyethanol liquid C6-H14-O2

111-76-2 eyes, the skin and the

flammable LD50 Rat oral 1.48 g/kg

LC50 Menidia beryllina (Inland silverside) 1250

LD50 is 0.5 mL/kg bw /orally

245

respiratory tract, nose

mg/L/96 hr

tert-Butyl acetate C6-H12-O2 540-88-5 eyes and nose flammable n-Butyl alcohol colorless liquid

C4-H10-O 71-36-3 irritating to

eyes, nose and throat

corrosive LD50 Rat oral 790 mg/kg


3 TO 7 OZ REPRESENTS REASONABLE EST OF SINGLE ORAL MEAN

LETHAL DOSE OF ANY BUTYL ALCOHOL IN

MAN tert-Butyl alcohol colorless liquid

C4-H10-O 75-65-0 eyes, nose and

throat flammable LD50 Rats oral

3.5 g/kg bw LC50 Poecilia reticulata (guppy) 3550 ppm/7 days

Cadmium lustrous metal Cd

7440-43-9 nose and throat probable human carcinogen powdered cadmium is flammable


LC50 Rat ihl 25 mg/cu m/30 mos

Calcium oxide colorless cubic crystals CaCO3

1305-78-8 skin, eyes, and respiratory system

toxic

Calcium silicate white powder Ca-Si-O3

1344-95-2 respiratory tract.

Calcium sulfate natural anhydrite crystals Ca.H2-O4-S

7778-18-9

Carbon black fine black powder C

1333-86-4 skin and respiratory irritation

explosion LD50 Rat oral /greater than/ 8000 mg/kg bw

Carbon dioxide gas CO2

124-38-9 skin toxic explosion

LC50; Species: Trout Concentration: 240 mg/L/1 hour

2-Pentanone (Methyl propyl ketone)

C5-H10-O LD50 Rat oral 3.73 g/kg

1240 mg/L/96 hr

Perchloroethylene (Tetrachloroethylen

colorless liquid C2-Cl4

127-18-4 skin eye

explode LD50 Oral Mouse 6000-


246

e) 8571 mg/kg Phenol Crystals

C6-H6-O 108-95-2 skin, eyes, and

respiratory system

caustic LD50 Rat oral 530 mg/kg

5 mg phenol/l for 8 days estimated 140 mg/kg to be the minimal

human oral dose at which death occurs.

Phosphoric acid syrupy liquid H3-O4-P

7664-38-2 eye and skin irritation

corrosive LD50 Rat oral 1530 mg/kg

138 mg/l/24-96 hr TCLo inhalation human 100 mg/cu m

Phosphorus pentasulfide

greenish-gray to yellow, crystalline solid

1314-80-3 eyes combustible solid

Propane colorless gas 74-98-6 inhalation, skin and eye contact by liquid

flammable LC50 Rat inhalation >800,000 ppm (1,442,847 mg/cu m)/15 min

n-Propyl acetate colorless liquid 109-60-4 eyes flammable LD50 Rabbit oral 6.64 g/kg


n-Propyl alcohol colorless liquid 71-23-8 eyes, throat, & mucous membranes

corrosive

LD50 Rat oral 1.87 g/kg

LC50 Pimephales promelas (fathead minnows) 4.48 g/l/96 hr

Propylene oxide liquid 75-56-9 skin, eyes and respiratory system

flammable LD50 Rat ip 150 mg/kg

LC50 Rat inhalation 4000 ppm/ 4 hr

Silica, amorphous amorphous powder

NO CAS RN irritating to the eye

explosion LD50 Rat oral >22,500 mg/kg

LC50 Carp >10,000 mg/l/72 hr

Vinyl chloride colorless gas or liquid

75-01-4 skin carcinogen flammable

Xylenes (o-, m-, p-isomers)

... liquid 1330-20-7 eyes and mucous membranes

corrosive carcinogenic

LD50 Rat oral 10 mL/kg

LC50 Rat inhalation 6,350 ppm/4 hr

Chromium sulfate

peach-colored solid


non-combustible

LD50 Rabbit percutaneous > 4.0 g/kg

LC50 Coturnix (Japanese quail) > 5000 ppm/ 5 days

Carbon disulfide mobile ... liquid 75-15-0 eyes, skin and mucous membranes

explosive LD50 Rat oral 3188 mg/kg

LC50 Rat inhalation 25 g/cu m/2 hr

15 ml may be fatal to an adult.

Carbon monoxide colorless gas 630-08-0 respiratory toxic flammable gas


247

Carbon tetrachloride

heavy liquid 56-23-5 Skin, Eye and Respiratory

probable human carcinogen Corrosive


LC50 Lepomis macrochirus (Bluegill) 125,000 ug/l/96 hr

Chlorobromomethane

colorless liquid 74-97-5 Inhalation, ingestion, eye and skin contact

Corrosive LD50 Mouse oral 4300 mg/kg


Chloroethylene Colorless gas or liquid C2-H3-Cl

75-01-4 Inhalation carcinogen

Chloroform (Trichloromethane)

Clear, colorless liquid C-H-Cl3

67-66-3 Skin and eye probable human carcinogen

LD50 Rat intragastric 2000 mg/kg

Eisenia fetida (Earthworm, adult, weight 300-500 mg) dermal (using filter paper) 111 ug/sq cm for 48 hr

lethal dose for an adult is estimated to be

about 45 g

2-Diethylaminoethanol

COLORLESS LIQUID C6-H15-N-O

100-37-8 skin, eye, and respiratory irritant

Flammable LD50 Rat oral 1,300 mg/kg


Diethyl ether Colorless, volatile, mobile liquid C4-H10-O

60-29-7 Nasal ,, eye Flammable LD50 Mouse iv 996 mg/kg bw

LC50 Mouse inhalation 186 mg/L/90 min

Lethal= 1400-1890 ug/mL

Diisobutyl ketone WATER CLEAR LIQUID C9-H18-O

108-83-8 Eye and skin flammable LD50 Rat dermal >2000 mg/kg bw

LC50 Rat inhalation (male & female) >5 mg/L/4 hr

Dimethyl sulfate Colorless oily liquid C2-H6-O4-S

77-78-1 eye and skin burns

animal carcinogen

LD50 Mouse oral 140 mg/kg bw

LC50 Guinea pig inhalation 167 mg/cu m (32 ppm)/60 min

Dioxane (Diethylene dioxide)

Colorless liquid or solid C4-H8-O2

123-91-1 probable human carcinogen

Explosion LD50 Mouse ip 790 mg/kg

LC50 Mouse inhalation 37 g/cu m/2 hr

Lethal concentrations for humans can occur

at 470 ppm

Diphenyl (Biphenyl)

Solid C12-H10

92-52-4 eye and skin Flammable LD50 Rat oral 3280 mg/kg

LD50 Mouse oral 1900 mg/kg bw

248

Ethyl acetate CLEAR LIQUID C4-H8-O2

141-78-6 Eye and Respiratory

Flammable LD50 Rat oral 5.6 g/kg

LC50 Rat inhalation 16,000 ppm/6hr

Ethyl alcohol (Ethanol)

very mobile liquid C2-H6-O

64-17-5 eye and skin irritant

Flammable LD50 Mouse iv 1973 mg/kg

LC50 Mouse inhalation 39 mg/cu m/4 hr

Isobutyl acetate C6-H12-O2 110-19-0 resp tract F Rabbit oral 4.8 gm/kg

TLm Brine shrimp 1200 ppm/24 hr

Isobutyl alcohol C4-H10-O 78-83-1 eyes, nose and throat

C Mouse intraperitoneal 544 mg/kg

Rat inhalation 8000 ppm/4 hr

Isopropyl alcohol C3-H8-O 67-63-0 eyes, nose and throat

C Rat oral 5045 mg/kg

LC50 Poecilia reticulata (guppies) 7060 ppm/7 day

PROBABLE LETHAL ORAL DOSE FOR ADULT

IS 8 OZ (240 ML Limestone 1317-65-3

2-Methoxyethanol (Methyl cellosolve)

C3-H8-O2 109-86-4 inhalation and dermal

Corrosive LD50 Rat ip 2500 mg/kg

LC50 Lepomis macrochirus >10,000 ppm/96 hr

Methyl ethyl ketone (MEK)

C4-H8-O 78-93-3 eyes, nose, and throat

F LD50 Rat oral 3400 mg/kg bw

LC50 Rat inhalation >5000 ppm/6 hr

Pentachlorophenol C6-H-Cl5-O 87-86-5 Skin, Eye and Respiratory

Confirmed animal carcinogen

Rat male oral 146 mg/kg

LC50 Tubifex tubifex 286, 619, and 1294 ug/l/24

Chromium (III) sulfate

Cr.3/2H2-O4-S 10101-53-8 Skin Toxic LC50 Coturnix (Japanese quail) > 5000 ppm/ 5 days

Cyanide 57-12-5

hexanol C6-H14-O 111-27-3 eye burns and skin

Flammable LD50 Mouse oral 1950 mg/kg

LC50 Mouse inhalation >21 mg/L/1 hr

methylene chloride C-H2-Cl2 75-09-2 Corrosivity Confirmed animal carcinogen


LC50 Rat ihl 88,000 mg/cu m/30 mos

sodium hypochlorite

Cl-H-O.Na 7681-52-9 skin and eyes oxidizer LD50 Rat oral 8.91 g/kg

Sodium sulphate anhydrous

H2-O4-S.2Na 7757-82-6 Toxic LD50 Rabbit percutaneous >

LC50 Mosquito fish 17,500 mg/l/48 hrs

249

4.0 g/kg

Sodium silicate UVCB 1344-09-8 skin and mucous membranes

F LD50 Rat oral 1.1 - 1.6 g/kg

sodium chloride NaCl 7647-14-5 Eye Corrosive LD50 Rat oral 3000 mg/kg

LC50; Species: Ceriodaphnia dubia 280000 ug/L for 7 day /total/

0.75 to 3.00 g/kg.

olive oil UNKNOWN 8001-25-0

butyl glycol C6-H14-O2 111-76-2 eyes, nose and throat

F LD50 is 0.5 mL/kg bw /orally/ in humans


1.4 mL/kg

phosphoric acid H3-O4-P 7664-38-2 eye and skin Corrosive LD50 Rat oral 1530 mg/kg

mosquito fish 138 mg/l/24-96 hr

100 mg/cu m

peppermint oil UVCB 8006-90-4 LD50 Rat oral 2426 mg/kg

250

251

Appendix 14: Periodical auditing and monitoring plan

252

The following flow charts and tables forms describe the information needed to be supplied by the enterprises deal with hazardous materials and hazardous wastes whenever apply for authorization permission to deal with hazardous materials and wastes. All information are needed for issuing or renewing permissions by relevant stakeholders, e.g. EQA, MoNTE…etc ).

253

General Information Company Profile

Please complete the table to describe your company profile Name of the company

Address

Telephone number

Fax number

E-mail

Contact person

Number of employees and working hours scheme

Main raw materials

Main product(s)

Departments

Available Environmental Features / Facilities

254

Other Important Information

Date

Hazardous Materials and Hazardous Waste Management Team

Please list the persons in charge of handling and managing HM and HZW at your company, their positions, responsibilities, and qualifications.

Name and Position Responsibility Qualifications

Name: Position:

1. 2. 3.

Name: Position:

1. 2. 3.

Name: Position:

1. 2. 3.

255

PRODUCTION OVERVIEW

To provide a general understanding of the production activities of your enterprise, an overview is useful. This is

prepared in brief to inform the HM and HZW team and any external concerned party such as EQA, MoLG,

MoH..etc of the general scope of the activities. This brief description is also intended to help identifying issues

related to HM and HZW management.

Then, to be able to identify quantitatively /qualitatively where HM is used in the production process as well as

identification of the sources of HZW and its quantity, a rough material flow diagram should be prepared and

included by the production staff and the HM and HZW team. The flow diagram should include inputs, process

step, and outputs including wastes and emissions.

An example for a well known / simple process is given below. You can prepare your own description and material

flow diagram by copying this example..

256

Production process of XYZ Electroplating Company

General description of the production process

The company is specialized in electroplating of brass fittings for taps and mixers. Brass electroplating line is used

and the process is as follows:

1. Forged brass parts are cleaned by ultrasonic degreasing, followed by electrocleaning (anodic and cathodic

baths) and water rinsing. Cleansers and cyanide salts solutions are used in the baths.

2. The parts are then transferred to a nickel plating bath containing nickel sulphate (NiSO4), nickel chloride

(NiCl2), boric acid (H3BO4) solution, and then rinsed consecutively in two baths.

3. The parts are then plated in a chrome bath with a chromic acid (CrO3) solution, followed by rinsing.

4. Finally, the pieces are transferred to a chromium treatment bath. The bath contains sodium metabisulphite

(NaHSO3) to reduce the dragged – out hexavalent chromium (Cr+6) ions to trivalent chromium (Cr+3). The

Cr+3 ions are washed off in two consecutive rinse baths.

The rinsing and spent solutions are sent to the wastewater treatment unit, which comprises cyanide (CN)

treatment unit and physiochemical treatment for the heavy metals.

257

Input Quantity Process Step Output Brass pieces

Almuclean 50 kg 1. Degreaser A

Wastewater, used bath

Water 2. Rinse

A Wastewater to Tank 2

Almuclean 100 kg 3. Cathodic A


Almuclean 100 kg 4. Anodic A


Water 5. Rinse


H2SO4 0.50% 6. Acidic B


Water 7. Rinse

B Wastewater to Tank 1

NiSO4 270 - 290 g/L NiCl2 60 - 70 g/L H3BO4 40 - 45 g/L Wastewater, used bath (every

14 days)

Additives 16 - 39 mL/L Sodium Saccharine 2.4 g/L

8. Nickel bath C

Water 9. Rinse


Water 10. Rinse


Chromic acid 165 – 195 g/L Wastewater, used bath (every 3 weeks)

H2SO4 0.9 – 1.2% Ital chrome D 10 – 12 g/L

11. Chrome bath D

Water 12. Rinse

A

NaHSO3 5% 13. Chrome treatment A


Water 14. Rinse


Water 15. Rinse


258

Plated pieces to quality check section

Figure:: Material Flow Diagram

Legend:

A: 1200 L, B: 1525 L, C: 4000 L, D: 1500 L, Tank 1: Acidic wastewater storage tank, Tank 2: Alkali wastewater storage tank

High priority areas at XYZ Electroplating Company

Ni and Cr baths (if to be discharged), since they contain Ni and Cr ions in addition to other pollutants such as Cl and SO4

The wastewater from the rinsing baths together with the treatment system

The sludge generated from the treatment system, since it contains high concentrations of Ni and Cr hydroxides that have to be completely stabilized before being disposed in a landfill

And chemical spillage on the floor of the electroplating area

259

Labeling Issue:

The following flowchart gives some guidelines for labeling:

Figure: Flowchart Illustrates the Labeling Process Adapted from California Institute of Technology

Yes

Was a hazardous waste label attached to the container when the first drop went inside?

Are the names of all chemicals stored in the container listed in full, with no abbreviations or formulas?

Yes

Are the physical state and hazard class listed on the label?

Yes

Segregate and place HW container in designated storage or pickup area

No

No

No

Attach hazardous waste label (see attached symbols)

List the names of all chemicals stored in the container with no

Consult the MSDS of the material used in the process and list physical state and hazardous class of the raw material

Yes

260

Example of Hazardous symboles

Characteristic Symbols Examples

Explosives

ammunitions, powdered charcoal, ammonium nitrate

Compressed gases and cryogenic liquids

Liquefied petroleum gas (LPG), acetylene, carbon dioxide, nitrogen, argon, oxygen

Flammable liquids

Methanol, acetone, benzene, fuel oil, diesel fuel, gasoline, jet fuel, kerosene

Flammable solids, spontaneously combustible, and water reactive generating flammable gases

Calcium carbide, calcium phosphide, metal powders and organic material powders

Characteristic Symbols Examples

Oxidizers

Oxygen, nitrous oxide

Toxic substances

Chlorine, ammonia, calcium phosphide, all pesticides, insecticides, chromium, cadmium, selenium, nickel, lead and mercury compounds

Radioactive

Uranium 238, cesium, cobalt

Corrosives

Sulfuric and nitric acids, hydroxides such as sodium hydroxide

261

Miscellaneous hazardous materials

Hot asphalt, liquid surfactants

To label your HZW containers you have to use the following label that could only be used for non-mixed chemicals

Hazardous Waste Contents Description Percentage, %

1- ………………………………………………………………………………………………………………………….. 2- …………………………………………………………………………………………………………………………… 3- ……………………………………………………………………………………………………………………………. 4- …………………………………………………………………………………………………………………………… 5- …………………………………………………………………………………………………………………………… 6- …………………………………………………………………………………………………………………………… 7- ……………………………………………………………………………………………………………………………

Hazards: □ ignitable □ corrosive □ reactive □ toxic amount Kg/ liter…….. Date of Accumulation ……/……./ ….. Generator name……………………….. Address …………………………….…. This label should be disposed off in an authorized manner only. If found in an unauthorized area, call 02 240 3498 Example of Labeling of Hazardous Waste

262

The following flowchart illustrates the procedure to be followed by the hazardous waste generators for treatment and final disposal

No

?

No

?

Not sure

Refer to Hazardous Waste Management and Handling Regulation for the year 2010

Is the hazardous waste treated on site in order to be reused

Yes

Continue to use

Yes

No

Arrange special treatment of this waste.

Contact EQA

Tel : 02 240 3498

Is the recycled material Safe for use?

Yes

Is the hazardous waste used oil?

263

Figure Procedure to be followed for Hazardous Waste Disposal

264

Storage of Hazardous Raw Materials for the Period …………………………………….

Please complete the table for the hazardous raw materials storage. You can use this table as much as you need.

Area Store

No.

Material Name / Concentration

Physical State (Liquid, Solid, Gas, Sludge)

Input Quantity

Output Quantity

Material on Hand

Wastes during storage

Storage Structure /

Area

Storage Environmenta

l Controls

Container Size / Type

Storage Environment

Storage Safety and Emergency

Response Features

265

266

Available On Site Hazardous Waste Treatment Facilities

Please fill the table regarding all waste streams generated at your company, the applied treatment technology and final disposal for each hazardous waste stream.

Hazardous Waste Treatment Technology Capacity Output Final Disposal

Way

267

Action Plan

Please fill the table to establish the outline of the HM and HZW action plan at your company.

Situation / Problem Measures Responsible Person(s)

Time Frame

Investment and Running Cost

Expected Environmental

Benefits

268

Follow-up

For continual improvement and to ensure sustainability of the system, the company

should always have follow up actions. These may include periodical auditing on the HM

and HZW, establishing unit dedicated to HM and HZW management, training and

awareness raising of the staff concerned. In the following form, the company can fill in

the envisaged follow up actions noting that these actions shall be revised and updated

on a continuous basis and shall be approved by the enterprise’s management.

Example

Table: Envisaged Follow up Actions by the Company at XYZ Electroplating Company

Envisaged follow up actions by the company:

During year one of the implementation, perform at least 3 audits to check

proper adaptation / implementation of the system

On a yearly basis, revisit the action plan and add necessary modifications

(upgrading)

Look always for cleaner production potentials opportunities

Keep employees up to date with new information / resources for HM and

HZW management through access to web sites or related training

If you have still open questions or problems with the management of your

hazardous material or waste, please do not hesitate to contact the EQA or

other organizations such as Universities

269

List of Technical Resource Institutions in POt

Name Telephone Fax Web Site

EQA

MoH

M oLG

MoNE

MoT

PWA

In addition to Palestinian Universities

270

Annual Hazardous Waste Management Report (AR Form)

(To be submitted by Enterprise to EQA by 31 January every year).

1. Particulars of the applicant:

(i) Name of the authorized person (occupier/operator):………………………..

(ii) Name of the Enterprise:………………………………Sector Type..………

Address…………………………………………………………………..

Tel. No ………………………………………………………………………

Fax No………………………………………………………………………

2. Categories of waste generated and quantity on a monthly average basis:…………..

3. Brief details of the on-site treatment facility:………………………………………..

In case of off-site facility: ………………………………………………………….

(i) Name of the operator ………………………………………………………

(ii) Name and address of the facility:……………………………………………..

Tel. No. Fax No.

271

4. Category-wise quantity of waste treated:……………………………………………….

5. Mode of treatment with details:………………………………………………………….

6. Any other information:……………………………………………………………………

I Certified that the above report is for the period from …………….…………………………….

………………………………………………………………………………...

Name…………………………………………….Title ……………………………………..

Signature …………………….. Date

272

Hazardous Waste Management Application

(To be submitted in duplicate)

To:

The EQA/ application authority branch…………………………………………………….

(city name: ……………………………….)

Address. …………………………………………………………………………….

1. Particulars of Applicant …………….………………………………………………

(i) Name of the Applicant ……………………………………………………………..

(in block letters & in full)

(ii) Name of the Enterprise: …………………………Sector Type……………………

Address: …………………………………………………………………………….

Tele No: ………………….…… Fax. No: ………………………………….

2. Activity for which authorization is sought:

Generation

Collection

Reception

Storage

Transportation

Treatment

Disposal

Any other form of handling

3. Please state whether applying for First time authorization or for renewal:

( in case of renewal previous authorization, write number………. and date……………

273

4. (i) Address of the institution handling Hazardous wastes: …………………..

(ii) Address of the place of the treatment facility:…………………………….

(iii) Address of the place of disposal of the waste: …………………………..

5. (i) Mode of transportation (if any) of Hazardous Waste …………………….

(ii) Mode(s) of treatment: ……………………………………………………..

6. Brief description of method of treatment and disposal (attach details):

7. (i) Category of Hazardous waste to be handled: ………………………………………….

Solid semi solid sludge Liquid others

(ii) Quantity of waste (category-wise) to be handled per month…………………

…..Continue

8. Declaration

I do hereby declare that the statements made and information given above is true to the best of my

knowledge and belief and that I have not concealed any information.

I do also hereby undertake to provide any further information sought by the prescribed authority in

relation to these rules and to fulfill any conditions stipulated by the prescribed authority.

Name : Title:

Signature of the applicant Date :

274

275

Emergency Inspection Procedure

EQA inspectors have to be trained to carry out an emergency or abnormal inspection in case there is a

report of illegal hazardous waste out of the enterprise or there is an accident occurs inside or outside the

enterprise during the Hazardous waste chain process. Figure x, is a schematic flowchart explaining the

procedure to be taken in such cases with all inspection files to be filed.

Figure x: Emergency/abnormal inspection procedure

276

Sometimes the needs for an emergency checks are decided during results during normal inspection.

Other cases may rise from received complain to EQA or any other HZW stakeholder. Such problems

might be related to on- site HZW management chain steps or off-site enterprise management chain

step. On-site accidents could be related to “collection and segregation”, “Initial HZW treatment”,

“internal transportation” or “internal storage” stages.

Whenever an environmental violation is observed due to any accident occurs at any enterprise, during

transportation of such HZW or any other off-site where HZW is handled, the authorized person (EQA

inspection team) shall report the accident in accordance to inspection form in Figure x to the prescribed

authority without delay.

EQA inspection teams should communicate the safety officer of the enterprise. The inspection teams

should, where necessary, raise the subject of violation with the EQA, MoLG, MoH and other related

stakeholder where necessary.

Periodic communication (recommended to be annually) should also be maintained between EQA

inspection teams and the enterprise safety officer in order to check up on general management within the

enterprise as shown in the Hazardous Waste Chain Management Process (HWCMP) form.

Direct and continuous communication between the safety officer in the enterprise and the collection

agency should be established and maintained in order to solve minor problems that may arise during

the HZW collection activities.

277

Hazardous Waste Chain Management Process (HWCMP)

This form is designed to be filled by enterprise safety officer for parts 1 to 8. A copy of this form must be send to EQA which in turn send a copy of this form to MoLG. Both EQA and MoLG double check sections (1-6) and (7-8) respectively.

Enterprise name: …………………………………………………………….. Address: …………………………………………………….

Prepared by: ………………………………………………………………… Date: …………………………………………………..

Sector type: Public Private Military Educational

Emergency Other

Processing area (m2): ………..…. Existence of storage raw materials area Yes size m2 No Specialties / services at the facility: manufacturing teaching lab others………. Who is in-charge of Hazardous waste activities at your facility under current legislation? Has he /she received training in HZW Management? Yes when …../…../ No What specific compliance requirements have been specified by the HZW advisory committee for your facility? …………. Have you received all the necessary clearances for operations? Yes No Specify ………

278

Hazardous Waste Chain Management Process Form Source and segregation of Hazardous Waste: production area main store laboratory others

Hazardous Waste needs initial treatment: Yes No

Part 1: The following information are according to the Palestinian Hazardous Waste Regulation Rule of the year 1999, Section Exist Does not

exist

Needs further

investigation

[S1] Special committee for HZW management

[S2] Regular meetings of the HZW management committee

[S3] Instructions available for HZW segregation?

[S4] Clear HZW signs are distributed

[S5] Coding for HZW waste

[S6] HZW collection bags volume is adequate and is proportional to generated waste

[S7] HZW is segregated according to its type in special containers.

[S8] Biohazard bags or taped to prevent leakage or explosion of contents

[S9] all containers are marked as "Hazardous waste" with appropriate signs

[S10] A filing record is available for the amount generated and type of the segregated Hazardous waste

Infectious medial waste: Yellow Solid plastic, non permeable

1- H

azar

dous

Was

te C

olle

ctio

n an

d S

egre

gati

on

at s

ourc

e (S

)

Pathological medical waste: Red bags or Red plastic containers

279

Sharp Medical Waste: Yellow Solid Plastic containers, non permeable

Pharmaceutical/Chemical Waste: Brown Solid Plastic containers, non permeable

Radioactive Waste: non color lead container with a radioactive sign

Mixed Medical Waste: Solid plastic, non permeable colored of the most dangerous hazardous waste with a sign for mixed medical waste

Toxic waste:

Flammable waste:

Ignitable waste:

Explosive waste:

Corrosive waste:

Poisonous waste:

Comments:

280

Part 2: The following information are according to the Palestinian Hazardous Waste regulation Rule of the year 1999, Exist Does not exist

Needs further Investigation

[HZWT1] For medical waste

The infectious medical waste are treated at generation source

Autoclave treatment

Formalin, concentration of not less than 10% for 24 hours

Needle destruction

Discharge to sewer (liquids only)

2- H

azar

dous

Was

te T

reat

men

t (H

ZWT)

[HZWT2] Other type of HZW:

physical treatment

Manual separation - removes selected wastes by visual inspection

Sieving and screening - removes coarse material

Sedimentation - settles solids to separate liquid

Decanting - removes water content

281

Centrifuging - removes water content

Filtration

Solvent extraction

Adsorption

Soil washing - extracts soluble contaminants

Sludge drying

Autoclaving - sterilises waste by heat & pressure

Microwave irradiation - sterilisation

Chemical Treatment

Chemical reduction and oxidation - uses oxidising and reducing agents to transform

constituents

Neutralisation - adjusts pH to neutral

Precipitation - separates hazardous constituents from solution

Dechlorination - removes chlorine from organic materials

Hydrolysis - breaks down constituents by adding water

Electrolysis - breaks down chemical compounds with electrical charge

282

Physiochemical treatment

Solvent extraction - uses immiscible solvent to dissolve organic material in aqueous solution

Flocculation & coagulation - aggregates fine constituents

Stripping / Desorption - separates volatile components from liquid by passing through gas stream

Membrane-separation - uses semi-permeable membrane

Leaching - removes soluble components from solid material

Scrubbing - removes constituents from gas or liquid stream by contact with washing liquid/slurry or powder

UV Irradiation / Ozonolysis - breaks down hazardous constituents by ozone/energy

Ion exchange - exchange with dissolved ionic species through contact with resin

Biological treatment:

Biodegradation of organic into simple inorganic species with suitable microbes

Activated sludge treatment - biodegrades organic species with bio-active sludge in aqueous phase

Rotating biological contactor - breaks down aqueous organic species in contact with bacterial rich filter

283

Aerated lagoons and stabilisation ponds - break down organic wastes in shallow pools with oxygen

Anaerobic digestion - degrades organic waste in absence of oxygen

Land application - biodegrades organic matter through action with soil microbes

Comments

Part 3: The following information are according to the Palestinian Hazardous Waste regulation Rule of the year 1999, Article Exist Does not exist


[IT1] There is a specific program for the collection and transfer of Hazardous waste to the storage area

[IT2] Bio hazardous waste do not remain in the waste generated bags/containers by more than one day

[IT3] Clear and sufficient content label containers

[IT4] Immediate new container after transferring the filled one

3- C

olle

ctio

n an

d tr

ansp

ort

wit

hin

the

ente

rpri

se p

roce

ssin

g

area

(IT)

[IT5] Containers or transport vehicles are

284

Easy loaded and unloaded

has smooth surfaces

Be washed and disinfected every day

[IT6] Specialized workers assigned to transport hazardous waste

[IT7] Workers are equipped with appropriate personal protective equipment PPE

Comments

Part 4: The following information are according to the Palestinian Hazardous Waste regulation Rule of the year 1999, Article Exist Does not exist


[OS1] Appropriate space area

[OS2] The storage area has an impermeable, hard-standing floor with good drainage; it is easy to clean and disinfect

4- O

n si

te

stor

age

(OS)

[OS3] The storage area should afford easy access for staff in charge of handling the Hazardous waste.

285

[OS4] Has the possibility to be locked to prevent access by unauthorized persons.

[OS5] Easy access for Hazardous waste-collection vehicles.

[OS6] Protection from the sun.

[OS7] Inaccessible for animals, insects, and birds.

[OS8] Good lighting and at least passive ventilation.

[OS9] Not situated in the proximity of fresh food stores or food preparation area

[OS10] A supply of cleaning equipment, protective clothing, and waste bags or containers is not located conveniently close to the storage area

[OS11] Separated from sections of the enterprise’s canteen and places of household wastes

[OS12] Available cleaning tools and source of clean water and sewer sink

[OS13] Appropriate method of storage

[OS14] Biohazards bags and packages are places on ground or in containers

[OS15] General cleaning is: -very good - good - acceptable bad - very bad

Comments

286

Part 5: The following information are according to the Palestinian Hazardous Waste regulation Rule of the year 1999, Article…. Exist Does not exist


[TOFF1] A designed Hazardous waste vehicle is available and licensed by MoT and has a temporary permit from the MoLG

[TOFF2] Risk wastes and non risk waste are transported separately for disposal

[TOFF3] Filled off site transportation form

5- O

ff S

ite

Tran

spor

tati

on

(OFF

)

Comments

Part 6: The following information are according to the Palestinian Hazardous Waste regulation Rule of the year 1999, Article… Exist Does not exist


For medical hazardous waste where Autoclave Treatment is used:

[TFD1] There is a responsible agency for operating the autoclave

[TFD2] is there any monitoring program for the medical waste autoclave.

[TFD3] Medical load number is identified

[TFD4] Temperature of not less than 121oC and pressure of Less than 15psi for a period of continuous 45minutes

6- T

reat

men

t an

d fi

nal d

ispo

sal

(TFD

)

[TFD5] Temperature of not less than 130oC and pressure of Less than 31psi for a period of continuous 30minutes

287

[TFD6] Temperature reaches its setting point

[TFD7] Pressure reaches its setting point

[TFD8] Data is computerized logged

Comments

saline solution out of dialysis is send:

[TFD9] Directly to the sewage network [TFD10] to sewage system after sterilization

[TFD11] to special hospital's treatment plant

[TFD12] to non permeable massive concrete tank

[TFD13] adequate and safe disposal of broken thermometer and pressure measuring devices

[TFD14] Liquid Waste characteristics PARAMETERS PERMISSIBLE LIMITS

pH 6.5-9.0

288

Suspended solids 100 mg/1

Oil and grease 10 mg/1

BOD 30 mg/1

COD 250 mg/1

Phenol compounds Other Solvents Silver Nitrite Heavy metals

[TFD15] Recovery

[TFD16] Incineration

[TFD17] Immobilization

[TFD18] Deposit into Land

[TFD19] Deep injection

[TFD20] Physiochemical treatment

[TFD21] Send to Rammat Hovave (needs special form to be filled)

Comments

289

special register form for dealing with Hazardous Materials and HZW

special form for HZW transportation (importance of Hazardous Materials and exporting Hazardous waste)

7- Records

a record for HZW management committee's meeting

290

Maintenance of Records

(1) Environmental Safety Officer of the enterprise shall maintain records related to the generation,

collection, reception, storage, transportation, treatment, disposal and/or any form of handling of HZW in

accordance with rules and guidelines presented in the inspection forms. These forms are in line with the HWCMP form.

(2) All records shall be subject to inspection and verification by the prescribed authority (EQA, MoH

and MoLG) at any time.

291

292

Off Site Transportation form (OST Form)

GENERAL

Enterprise Facility Name…………………………………………………………………

Address:……………………………… Tel…………….. Fax ………………..

City ………………………………….

E-Mail …………………………………

Individual Responsible for Management of Hazardous Waste (Safety Officer) name,

……………………………..

Public Private Military Educational

Emergency Other

Storage area Size m2………………………. Annual HZW generation ………kg/year……….

Type of Hazardous Waste waste …………..kg/day or ………..kg/year

Category of Hazardous waste to be transported ………………………………………….

Solid semi solid sludge Liquid others

Quantity of waste (category-wise) to be handled per month…………………

Do You Import Hazardous Materials Yes No

If Yes what is your licence number ……. Issue date

LEGISLATION ON HZW MANAGEMENT

Do you have National Guidelines on HZW management Yes No

Does your establishment has internal guidelines on HZW management Yes No

Is there a designed HZW vehicle with a permit from the MoT Yes No

Hazardous and non hazardous wastes are transported separately Yes No

Filled off site transportation form Yes No

Further information / Remarks about any recent off site transportation accident

Accident Date…./ …../

293

Off site transportation form (OST Form)… continue

Transportation Date: Copy to

Serial No Name of HZW regulation authority

Address : Tel

Originator's reference:

CONSIGNMENT NOTE FOR THE CARRIGAE AND DISPOSAL OF HAZARDOUS WASTE

Producer's Certificate

A

(1) The material described in B is to be collected from ………………………..………………………………………………….. ……………………………………………………………………………………………………………………………………… (2) taken to …………………………………………………………………………………………………………………………. signed …………………………………………………………………………… Name………………………………………… on behalf of ……………………………………………………………………….…Position ……………………………………..

Address ……………………………………………………………………………..Telephone no……………………………….

……………………………………………………………………………………….Date………………………………………

Estimated date of collection………………………………………

Description of the Waste

(1) General description and physical nature of waste liquid semi solid solid sludge other (specify)

(2) Relevant chemical and biological components and maximum concentrations

(3) Quantity of HZW and size, type and number of containers

294

B

(4) Process(es) from which waste originated

Carrier's collection certificate

C

I certify that I collected the consignment of HZW and that the information given in A(1) and (2) and B(1) and (3) is correct subject to any amendment listed in this space:

I collected this consignment on ……………………………..at ………………………… .hours: …………….

Name: ………………………………………….Signed …………………………………. .Date: …………….

On behalf of …………………………………..Vehicle reg. no: ………………………..

Address: …………………………………………………………………………………….Tel: …………

Producer's Collection Certificate

D

I certify that the information in B and C is correct and that the carrier was advised of appropriate precautions measures.

Signed: ……………………………… Name: ……………………………………Date: …………..Tel……..

Disposer's certificate

I certify that waste disposal licence no ………………….. issued by ……………………….. authorizes the treatment /disposal at this facility of the waste described in B (and as amended where necessary at C).

295

E

Name and address of HZW treatment facility manager ………………………………………………………………………………………………………..

This waste was delivered in vehicle ……………… (reg no) at …………………..hours on …………………………(date)…… and the carrier gave his name as ……………………………………..on behalf of …………………………………………….. Proper instructions were given that the HZW should be taken to ……………………………………………..

Signed …………………..Name ……………………………Position

Date …………………………on behalf of…………………………………..

Any comments:

Did you find the disposed HZW treated or untreated? treated untreated

Carrier's Signature………………..….. Producer's Signature …………………………….. Disposer's Signature………………………….

To be filled by EQA inspector:

Write any shortages found and recommend solutions ………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………….. Inspected By …………………Date …./ …../

296

Documents

The Development of a National Master Plan for Hazardous ... · Dr Abdulelah Al Wadaee Regional Network Coordinator, Compliance Assistance Program (CAP), Bahreen UNEP office 21-10-2010