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7/25/2019 The Atom and Its History
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The Atom and its History
7/25/2019 The Atom and Its History
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Democritus (465
BC) Ancient Greeks came to
believe all matter consisted of differing
amounts of only 4 basic substances eart!" fire"#ater" and et!er
$euci%%us" teac!er of Democritus" %ro%osed
matter #as made of small %articles D& #as first to use t!e #ord atomos:
the smallest, indivisible part of matter
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Back in t!e 'ron Age&
ome elements are found in nature in a
relatively %ure form&
ulfur" co%%er" gold"
silver" and iron #ere
made into decorative
and useful ob*ects&
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+!e Alc!emists (Dark Ages till
t!e ,enaissance) $ooked for t!e
%!iloso%!ers stone
t!oug!t t!ey #ouldfind a #ay to turn -b
into Au
.e#ton dabbled in
alc!emy
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+!e modern age begins
/enning Brand of Germany discovered
%!os%!orusin 0661&
/e collected 52
buckets of urine"
fermented it" and
t!en boiled off t!e
#ater&
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3ose%! -riestley
Discovers oygen 04
(at t!e same time as
$avoisier 7 c!eel)
A 8natural %!iloso%!er9
Also credited #it!
inventing soda #ater:
(0;;0
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Antoine $avoisier $a# of conservation of
mass
Discovers nitrogen gas"and t!at oygen can be
c!emically se%arated
from certain com%ounds
confirms la# of definite
%ro%ortions
fat!er of modern
c!emistry loses !is !ead to t!e
=renc! ,evolution
04;014
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3o!n Dalton
=at!er of modern
Atomic +!eory
t!oug!t atoms of anelement #ere all
identical and
indivisible
com%ounds are formed
from atoms of
different elements
0660
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Dalton>s model
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William Prout
$a# of Definite
-ro%ortions
0
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Dimitri ?endeleev (0
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?endeleev>s original table
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C!emistry and -!ysics 3oin
=orces+!e late 01t! century t!roug! t!e 2t!century
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3 3 +!omson Discovers t!e electron
-lum -udding ?odelof t!e atom&
All t!e c!arged
%articles #ererandomly scattered
like 8%lums in
%udding9
did not kno# aboutneutrons
.obel -rie 0126&
+!om%sons e%eriment to discoverelectrons (0
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+!omson>s model
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il!elm ,oentgen
0
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BecFuerel(0
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+!e Curies
-ierre ?arie
?arie (0
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.ikola +esla0
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Irnest ,ut!erford (0
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,ut!erford>s 8%lanetary9 model
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/enry ?osley (0
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J0
J +;
$os Alamos .ational $ab
,elations!i%s on t!e -eriodic
http://periodic.lanl.gov/default.htmhttp://periodic.lanl.gov/default.htm7/25/2019 The Atom and Its History
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,elations!i%s on t!e -eriodic
+able
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Max Planck
t!e energy of an
orbiting electron isdetermined by t!e
freFuency of its #ave
0
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.eils Bo!r (0
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Bo!r>s energy level model
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Ir#in c!rLdinger
it! /eisenberg"
calculated %robable
locations of electrons
Kuantum mec!anics
and c!rLdinger >s cat
0
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$ouis de Broglie
Ilectrons orbiting t!e
nucleus e!ibit #ave
%ro%erties ?oving matter !as a
#avelengt! related to
its momentum
$eads to develo%ment
of t!e cloud model of
t!e atom
0
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Ilectron cloud model
Com%arisonof t!e t#o models
http://dwb4.unl.edu/ChemAnime/BOHRQD/BOHRQD.htmlhttp://dwb4.unl.edu/ChemAnime/BOHRQD/BOHRQD.html7/25/2019 The Atom and Its History
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+!e 01 olvay Conference
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erner /eisenberg
?at!ematical models
#it! c!rodinger
+!e Mncertainty-rinci%le
you can not kno# bot!
t!e %osition and s%eed
of an electron
simultaneously
0120016
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/eisenberg #as a !ydrogen filled nai e%%elin t!at came to t!is
disastrous end in t!e 01;2>s&
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erner /eisenberg #as a German %!ysicist #!o" in !is late
t#enties" introduced #!at is kno#n as t!eHeisenberg
Uncertainty Principle. +!is discovery s!ook t!e very
foundation of subatomic %!ysics&
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/eisenberg>s %rinci%le states
=or any moment in time" it is
im%ossible to kno# t!e %osition and
t!e momentum of a moving %article&
im%ly because t!e act of observing affects t!e be!avior of t!e observed&
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'>m sure you>re a#are of some t!ings t!at c!ange t!eir be!avior
de%ending on !o# t!ey are being observed" for eam%le
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'n t!e case of %articles" t!e observer also affects t!e be!avior of
t!e observed& +!ere are limits to !o# muc! #e can kno# about a
%article at any given moment& +ake t!is %icture for eam%le
/o#ever" if #e moved t!e magnifying glass"
,ig!t no# #e can see t!e left side clearly&
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.o# #e can see t!e rig!t side clearly but can no longer see t!e left&
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'magine t!isA microsco%e t!at can see electrons in orbit around t!e nucleus
e s!oot ordinary lig!t #aves at t!e electron to find its
%osition"
e try gamma rays (s!orter #avelengt!)&
+!e %roblem #it! t!is is t!at gamma rays !ave so muc!
energy (!ig! freFuency)" t!at u%on contact" t!e electron
is knocked out of orbit making im%ossible to kno# itsmomentum&
but t!e #avelengt! is too long to be obstructed by
t!e electron"so&&&
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Albert Iinstein
0
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Iinstein didn>t like Kuantum
?ec!anics Iinstein to Bo!r" 8God
does not %lay dice
#it! t!e universe9 Bo!r" in res%onse"
8!o are you to be
telling God #!at to
doO9
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-aul Dirac
=urt!er develo%ed Fuantum t!eory
from #ork of
/eisenberg and c!rodinger
!ared a .obel -rie 01;;
orked on Mranium
enric!ment during ''
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3ames C!ad#ick
01; discovers t!e
neutron
I%lains isoto%es
!tt%PP###&nobel&seP%!ysicsPlaureatesP01;5Pc!ad#ickbio&!tml
0
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$ise ?eitner
,ealied t!at some
#eig!t #as lost during
nuclear fission INmcB
as %art of t!e team
t!at discoverednuclear fission in late
01;2s
0
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Inrico =ermi
(01200154)
Imigrated from =ascist 'taly in 01;< after#inning .obel -rie
Built first nuclear reactor underneat! t!e
stadium at t!e Mniversity of C!icago 014
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Art!ur Com%ton
orked #it! =ermi on first reactor
Demonstrated t!e %article as%ect of
electromagnetic radiation
+!e Com%ton cattering Iffect
0
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Glenn +& eaborg
0100111
,es%onsible for t!e
Actinide conce%t
Discovered ten elements
plutonium, americium,
curium, berkelium,
californium, einsteinium,
fermium, mendelevium,nobelium,and 106 named
after him!
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Radioactivity
+!ree ty%es
Al%!a Q a /e nucleus (%Jn)
Beta R an electron
Gamma S %ure energy I? #aves
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Penetration of Matter
+!oug! t!e most massive and most energetic ofradioactive emissions" t!e al%!a %article is t!es!ortest in range because of its strong interaction#it! matter& +!e electromagnetic gamma ray is
etremely %enetrating" even %enetratingconsiderable t!icknesses of concrete& +!e electronof beta radioactivity strongly interacts #it! matterand !as a s!ort range&
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