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    BALANCING

    CHEMICALEQUATIONS

    Name

    Rewrite

    and

    balance

    the

    equations

    below.

    . N

    2

    + H

    2

    NH,

    2. KCIO, KCI + C X

    3. NaCI + F

    2

    -* NaF +CI

    2

    4.

    H

    2

    + O

    2

    H

    2

    O

    5. AgNO

    3

    + MgCI

    2

    AgCI+ Mg(NO

    3

    )

    2

    6.

    AIBr

    3

    +

    KjSO,

    KBr + A I

    2

    (SO

    4

    )

    3

    7. CH,

    +

    O

    2

    -* CO

    2

    +

    H

    2

    O

    8.

    C

    3

    H

    8

    + O

    2

    -*

    CO

    2

    +

    H

    2

    O.

    9. C

    8

    H

    18 +

    0

    2

    10

    2

    +H

    2

    0

    10. FeCL

    + NaOH

    Fe(OH)

    3

    +

    NaCI.

    11.

    P+

    O,

    12. Na +

    H

    2

    O

    NaOH +

    13.

    Ag

    2

    O

    -

    Ag

    +

    O

    2

    14. S

    8

    +0

    2

    - S0

    3

    .

    O A. 0

    15. C0

    2

    +

    H

    2

    0

    0

    16. K

    + MgBr

    2

    17,

    HCI + CaCO,

    KBr + Mg

    CaCI

    2

    + H

    2

    O +CO

    2

    .

    Chemistry IF8766

    58

    Instructional

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    EQUATIONS

    Name

    theword

    equations

    belowaschemical equationsandbalance.

    zinc

    +

    lead(II) nitrate yield

    zinc

    nitrate

    +

    lead

    2

    aluminumbromide +chlorine yield aluminum chloride +bromine

    3 ,

    sodiumphosphate

    +

    calcium chlorideyieldcalcium phosphate

    +

    sodium

    chloride

    4. potassiumchloratewhenheatedyields potassiumchloride + oxygen gas

    5 . aluminum

    +

    hydrochloricacidyield aluminum chloride

    +

    hydrogen

    gas

    6 .

    calcium hydroxide

    +

    phosphoricacid yieldcalciumphosphate

    +

    water

    7 .

    copper

    + sulfuricacid

    yield copper (II)sulfate

    +

    water

    +

    sulfur dioxide

    8 .

    hydrogen +nitrogen monoxide yield water + nitrogen

    i

    nc

    Chemistry IF8766

    59 Instructional

    Fa i r ,

    in

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    TYPES OF REACTIONS

    Thereare 5main typesofreactions.

    1. Direct CombinationCompositionSynthesis:

    Two ormore elements orcompounds A and B)combine toforma

    more complex substance. ABoneproduct)

    A + B AB

    Examples:

    Write equationsshowing

    the

    direct combination

    of the

    elements below:

    a. Sodium

    and

    iodine

    b. calciumandoxygen

    c. hydrogen and chlorine

    d.

    hydrogen

    and

    carbon monoxide

    and

    oxygen

    to

    form carbonic

    acid

    e. nitrogenandhydrogentoform ammonia

    2. DecompositionAnalysis:

    ^ Reverse

    of

    direct combination.

    A

    complex compound

    ABone

    reactant)

    isbroken down intotwo ormore simpler substances.

    Aand B,elements and/or compounds)

    AB *

    A + B

    Examples: Write equations showing

    the

    decomposition

    of

    each

    of

    the

    following substances:

    a. Water

    b. silver chloride

    c.

    aluminum oxide

    d. lithium phosphate to form

    lithium,

    phosphorous and oxygen

    e.

    sulfuric acid to form hydrogen, sulfur and oxygen

    3. Single Replacement:

    Onesubstance isreplaced from-itscompound byanother

    substance.

    Element + compound -^ element + compound

    A + BC

    *

    B + AC

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    Note: Cationic single

    replacement: is

    when metals replace

    metals andhydrogen. +ion)

    AnionicSingle replacement: is when nonmetals replace

    nonmetals.

    -

    ion)

    To see if a

    reaction takes place

    use

    Table

    J. A

    more active

    metal replacesaless active metalor amore active nonmetal

    replaces

    a

    less active nonmetal.

    If

    this

    is not the

    case

    a

    reaction will not occur.

    Examples: Decideif thefollowing reactions will occur. If

    they

    dotake place determinetheproductsofeach reaction.

    a.

    zinc and nitric

    acid

    b. iron andcopper IIsulfate

    c. sodium and water

    d. magnesium chlorideandfluorine

    e. sodium chloride and bromine

    4. Double Replacement:

    Twocompounds combine toformtwo newcompounds.

    AB + CD

    *

    AD + CB

    Note: +

    ions switch places.

    These equations are also known as ionic equations. Ionic

    equations have

    two

    possibilities:

    a. Reactions go to completion stops): When ions in a solution

    combine to form a productthatleaves the scene of a

    reaction. There are three types of products that leave the

    scene of a

    reaction.

    1. Slightlyionizedwater

    2.

    Gases escape Cf)

    3. Precipitates settle

    to the

    bottom 4*)

    Precipitates are solid substances formed by a physical

    orchemical change in a liquid medium. It separates

    from the liquid by settling to thebottom.Precipitates

    are insoluble compounds see table F.

    b. If a reaction does not go to completion they are said to be

    Reversible. 5). Areversible reactionis one inwhichthe

    products can themselves react to form the reactants.

    Examples: For each reaction write themolecular,ionic and

    Netionic equations:

    a. silver nitrateandzinc chloride

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    b.

    copper

    IIhydroxideandacetic acid

    c.

    iron II

    sulfate

    andammonium sulfide

    5. Complete Combustion:

    When

    a

    hydrocarbon compound composed

    of

    onlycarbon

    and

    hydrogen) or acarbohydrate compound composed ofcarbon,

    hydrogen andoxygen) react with oxygentoform carbon dioxide

    andwater.

    Example: Write anequationfor thecomplete combustion ofeach

    ofthe

    following

    organic substances:

    a.

    b. CH

    4

    c

    C

    2

    H

    2

    d.

    C

    6

    Hi

    2

    0

    6

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    Name

    Date

    Class

    CHAPTERS REVIEW

    ACTIVITY

    TtxtReferenct:Section-13

    Chemical Changes

    Choose word*fromtrwlistto fill In the blanks in the paragraphs.

    WordUat

    analysis

    arrow

    chemical equation

    chemicalreaction

    coefficient

    delta

    doublereplacement

    electrolysis

    endothermic

    exothermic

    ionic equation

    precipitate

    product

    reactant

    single

    replacement

    spectator

    synthesis

    Another name for a chemical change is

    a(n)

    LD Such a change can

    be

    represented

    by means of a written statement called a(n)

    (

    2

    )

    . The

    symbol

    for the

    word yields

    in

    such

    a

    statement

    is

    a(n) GD

    Any

    substancewrittento the leftof thissymboliscalled

    a(n)

    .

    W

    _ .Any

    substancewritten to the right ofthis

    symbolis

    called

    a(n)

    GJ) A

    number written

    just

    to the

    left

    of a formula is called a(n)

    ()

    A

    chemjMf

    changeinwhich energy is absorbed is called a(n) (?)

    reaction.

    One in which energy is released iscalled a(n) (8) reaction.

    Some chemical

    changes

    involve charged particles. Anequation that

    showsthe

    reaction

    or

    production

    of

    such

    paniclesis

    called

    a(n)

    C O

    .

    Any

    charged

    particle

    that

    is

    present

    but that

    does

    not change or react

    during areaction isusually omitted from theequation; it iscalled

    a(n)

    (IP)

    A

    chemical change

    in

    which

    two or

    more substances combine

    to form

    a more complex substance is called a(n) (H) reaction. A change in

    which

    asubstanceisbroken down into

    simpler

    substancesiscalleda(n)

    (12) reaction.Any such change that is caused by the flow of anelectric

    current is called a(n) (13) . If the change iscausedby heat supplied to

    the reaction, the Greek symbol

    (H) isoften

    written above the yields

    symbol

    in the

    equation.

    A chemical change

    in

    which

    a

    free

    element replaces and releases

    another

    element

    in acompoundiscalleda(n) (15) reaction. Achemical

    change inwhich there isanexchangeofions betweentw ocompoundsis

    called

    a(n)

    (*6) reaction. Asolid substance producedbysucha reac-

    tion

    inaliquid

    medium

    is

    called a(n)

    (

    17

    ) .

    1.

    2.

    3.

    4.

    5.

    .

    7.

    g.

    9.

    10.

    11.

    12.

    13.

    14.

    IS.

    16.

    17.

    9 4 CHEMIST1Y:

    Th

    StudyofMattar

    COPYRIGHTbyPrtotic*Hall,Inc

    Reproductionofthil matter u

    rvttrkltd

    toduplicationfixd*uroomUM only.

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    Name

    Date

    Class

    CHAPTERS

    REVIEW ACTIVITY

    Text Reference:Section9-12

    Categories of Chemical Reactions

    State whether each of thefollowingequations represents a synthesis

    i),analysis a),single replacement sr),

    or

    doublereplacement dr)

    reaction.

    1.

    CO

    2

    -*

    C +

    O,

    1.

    2.

    NaCl

    + AgNOa

    -

    NaNO,+

    AgCl

    2.

    8. S + CU

    -+

    SCU 3.

    4.

    BaClt

    +

    2NaOH

    -*

    2NaCl

    +

    BaTOH),

    4.

    5.

    Zn

    +

    CuSO

    4

    -*ZnSO

    4

    + Cu 5.

    6.

    CH*

    -*

    C +

    2H

    2

    6.

    7.

    PbCNO,)s

    +

    Mg-*Pb

    +

    MgCNOsk

    7.

    8.

    Mg

    +

    2HC1- MgCU

    +

    Hi

    8.

    9. HjSO

    4

    -*

    H

    2

    +S +20

    2

    9.

    10.

    2Oj+

    N

    s

    -*N

    A 10.

    11.

    3CaBr

    2

    + 2Na

    s

    P-

    Ca

    s

    ft +

    6NaBr

    11.

    12. 2KI

    -l - Br

    2

    -2KBr

    +

    I

    2

    12.

    18.

    CflHtfO,,

    - 6C +

    6HzO

    13.

    14.

    2NaF

    - 2N a+ R 14.

    15.

    Si +

    O

    2

    -

    SiO

    2

    15.

    16. 2NaI -t -

    Pb(NO

    8

    )2

    -2NaNO

    3

    - f Pb I

    2

    16.

    17.

    N al+ Cs-*

    Csl

    + Na

    17.

    18. H

    2

    + CO

    +O

    2

    -

    H

    2

    CO

    3

    18.

    19. LJaPO

    4

    -3Li

    +

    P + 2O

    2

    19.

    20. CSz +

    2FJ

    -

    CF

    4

    + 2S 20.

    J

    COPYRIGHT

    by Prtntic*

    Hll.

    Inc.

    Rtproduction of

    thu

    mrtr

    (rttridd

    to duplication for

    eUwoom

    UM

    only.

    CHEMISTRY:ThStudyofMatter 9 3

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    CLASSIFICATIONOF

    Nome

    CHEMICAL REACTIONS

    Classify

    thereactions belowas

    synthesis,

    decomposition,singlereplacement

    (cationic

    anionic) or

    double

    replacement,

    2H

    2

    +

    O

    2

    - 2H

    2

    O

    2. 2H

    2

    O - 2H

    2

    + O

    2

    3.

    Zn +

    H,SO,

    ZnSO. + H

    2 4

    2

    4. 2CO

    O

    2

    - 2CO

    2

    5.

    2HgO -*

    2Hg

    O

    2

    6. 2KBr + CI

    2

    - 2KCI +

    Br

    2

    7.

    CaO + H

    2

    O

    -

    Ca(OH)

    2

    8. AgNO

    3

    + NaCI

    AgCI

    + NaNO

    3

    9. 2H

    2

    O

    2

    2H

    2

    O +

    O

    2

    10.

    Ca(OH),

    + H

    2

    SO

    4

    ~- CaSO,, 2H,O

    'H .

    :

    , t r, '8766

    50 Inotfjctionai

    f f j i f . m

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    Name

    predict

    theproductsof thereactions below. Then, writethe

    balanced

    equationand

    c l a s s i f y

    the reaction.

    ^

    magnesium

    bromide

    chlorine

    2 aluminum + iron (III) oxide

    3 .

    silvernitrate + zinc chloride

    PREDICTING

    PRODUCTS

    CHEMICAL REACTIONS

    4 hydrogen peroxide (catalyzed by manganese dioxide)

    5 zinc

    hydrochloricacid

    6

    sulfuricacid

    +

    sodium hydroxide

    sodium

    +

    hydrogen

    Qceticacid + copper

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    PROBLEMS

    INVOLVING EQUATIONS

    The

    coefficients used

    in

    balancing

    a

    chemical equation

    represent

    moles.

    Instoichiometric problems involving

    equations it isassumed thatthereactionis the single

    reaction

    with

    noside reactions),thatthereaction goes

    tocompletion

    and the

    reactants

    are

    completely reacted.

    Every stoichiometric problem involvesthefollowing

    three basic

    steps.

    Stepl: Find

    the

    moles

    of the

    substance

    you are

    given

    information

    about.

    Moles

    =

    g/gfm Moles=1/22.4 Moles

    = ftp/6.02 x

    10

    23

    Step 2: Set up amole ratio.

    Actual moles from step1) = Actual moles

    unknown)

    Theoretical moles fromcoefficients)Theoretical moles

    Step 3: Find

    the

    grams, liters

    or

    particles

    of

    your

    unknownusingone of thethree mole equations from step1.

    Type 1: Mass-Mass Problems:

    A

    balanced equationshows

    the

    moleproportions

    of

    products

    f toreactants. It ispossibletodeterminethemassof one

    substance that reacts withor isproduced fromagiven mass

    of

    another substance.

    Examples:

    1.

    How

    many grams

    of

    sodium chloride

    are

    needed

    to

    react

    toproduce 35.5 gramsofchlorinegas?

    2. How manygramsofhydrogenareproduced by theaction

    ofwateron 100.gramsofsodium?

    3.

    What massof

    oxygen

    will combinewith3. 0

    grams

    of

    hydrogen

    to

    produce water?

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    4.

    Given

    the

    reaction:

    N

    2

    +

    0

    2

    -

    2NO. What

    is the

    total

    number

    of

    grams

    of

    oxygen needed

    to

    react completely

    with

    2. 0

    moles

    of

    nitrogen?

    Type 2: Mass-Volume

    Problems:

    A

    mole 6.02

    X 10 ) of

    molecules

    of any gas

    occupies

    a

    volume

    of22.4 litersat STP. This numerical valueis

    called themolarvolume. It has amass equalto the

    molecular mass expressed in

    grams.

    In abalanced equation

    where

    the

    mole unit serves

    to

    relate

    the

    quantities

    of

    products andreactants,it ispossibletodetermine

    quantitative

    resultsindesired units, whichmay not

    necessarily

    be the

    same

    as the

    original units.

    Examples:

    1. Howmany gramsofzinc metalareneededtoreact with

    hydrochloric acidtoproduce 11.2 litersofhydrogen

    gas at

    STP.

    2. Howmany gramsofcarbon dioxideat STP are produced

    by the

    complete combustion

    of C

    2

    H

    e

    ?

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    Type 3: Volume- Volume Problems:

    Since

    one

    mole

    of any gas

    occupies

    the

    samevolume

    as one

    mole of any other gas, at the same temperature and

    pressure,

    the

    volumes

    of

    gases involved

    in a

    reaction

    are

    proportional to the number of moles indicated by the

    numerical coefficients in a balanced equation.

    Examples:

    1. In the

    reaction N

    2

    +

    H

    2

    ->

    2NH

    3;

    calculate

    the

    volume

    of

    hydrogen

    gasrequired toform100. litersofammonia?

    2. What volume of carbon dioxide will beformed fromthe

    complete combustion of 21.2 liters of camphene Ci

    0

    H

    6

    )?

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    STOICHIOMETRY:

    MOLE-MOLE

    PROBLEMS

    Name

    4.

    N

    2

    + 3H

    2

    -* 2NH

    3

    Howmany moles

    of

    hydrogen

    are

    needed

    to

    completely react with

    twomoles

    of

    nitrogen?

    2. 2KCIO,

    2 K C I +

    3O,

    Howmanymoles of oxygen areproducedbythe'decompositionof sixmoles

    ofpotassium chlorate?

    3. Zn + 2HCI -

    ZnCI

    2

    + H

    2

    Howmany molesofhydrogenareproducedfromthereactionofthree moles

    ofzincwithan

    excess

    ofhydrochloric acid?

    C

    3

    H

    5CL

    3C0

    4H

    2

    0

    . _ 2 2

    Howmany

    molesof

    oxygen

    are

    necessary

    to

    react completely with fourmoles

    of

    propane(C

    3

    H

    8

    )?

    5.

    K

    3

    P0

    4

    +

    AI(N0

    3

    )

    3

    -*

    3KN0

    3

    +

    AIPO

    4

    Howmanymolesofpotassium nitrateareproduced whentwomolesofpotassium

    phosphate

    react withtwomolesofaluminum nitrate?

    Chemistry IF8766

    62

    Instructional

    Fair,

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    STOICHIOMETRY:

    MASS-MASS PROBLEMS

    Name

    1 .

    2KCIO,

    2KCI

    + 3O

    0

    Howmany gramsofpotassium chlorideareproducedif 25 g ofpotassium chlorate

    decompose?

    2.

    N

    2

    +

    3H

    2

    - 2NH

    3

    Howmany

    grams

    ofhydrogenarenecessary toreact completelywith50.0g of

    nitrogenintheabove reaction?

    3.

    How

    manygrams

    of

    ammonia

    are

    produced

    in the

    reaction

    in

    Problem

    2?

    4. 2AgN0

    3

    + BaCI

    2

    - 2AgCI + Ba(NO

    3

    )

    2

    How

    many grams

    of

    silver chloride

    are

    produced

    from5.0 g ofsilver

    nitratereacting

    withanexcess ofbarium chloride?

    5. How much barium chlorideis necessary to reactwiththe silver nitratein Problem4?

    Chemistry

    IF8766

    64

    InstructionalFa ir,

    nc

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    5TOICHIOMETRY:

    VOLUME VOLUME PROBLEMS

    Name

    N, + 3 H

    2

    2NH,

    What

    volume

    ofhydrogenis

    necessary

    toreact with fiveliters ofnitrogentoproduce

    ammonia?

    (Assume

    constant temperatureandpressure.)

    2.

    What volume of ammonia is produced in the reactionin Problem1?

    3. C

    3

    H

    8

    +50

    2

    3CO

    4H

    2

    O

    If

    20

    liters

    o f oxygena re consumedin the above reaction,how many

    liters

    of carbon

    dioxide are produced?

    4. 2H

    2

    0 2H

    2

    +0

    2

    If

    30ml ofhydrogenareproducedin theabove reaction,howmanymilliliters of

    oxygen are

    produced?

    5.

    2CO + O

    2

    -* 2CO

    2

    How

    many liters of carbon dioxidea re produced if 75 liters of carbon monoxide

    a re

    burned

    in

    oxygen?

    How

    many

    liters

    of

    oxygen

    a re necessary?

    Chemistry IF8766

    63

    Instructional Fa i r , Inc.

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    I

    STOICHIOMETRY:

    MASS-MASS PROBLEMS

    Name

    \

    1. 2KCIO,

    2KCI + 3CX

    How

    many

    gramsofpotassium

    chloride

    are

    produced

    if 25 g of

    potassium chlorate

    decompose?

    2. N

    2

    +

    3H

    2

    - 2NH

    3

    How

    many

    gramsof

    hydrogen

    arenecessaryto

    react completelywith50.0

    g of

    nitrogen

    inthe

    above reaction?

    3.

    How

    manygrams

    of

    ammonia

    are

    produced

    in the

    reaction

    in

    Problem

    2?

    Ba(NO

    3

    )

    2

    .

    2AgNO

    3

    +

    BaCI

    2

    -

    2AgCI

    How

    many

    grams

    ofsilver

    chloride

    are

    produced

    from5.0 g ofsilvernitrate

    reacting

    with

    anexcessof

    barium chloride?

    5.

    How

    much barium chloride

    is

    necessary

    to

    react with

    the

    silvernitrate

    in

    Problem

    4?

    Chemistry

    IF8766

    64

    InstructionalFa ir, nc

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    STOICHIOMETRY:

    Name

    VOLUME VOLUME PROBLEMS

    1. N

    2

    + 3H

    2

    - 2NH

    3

    Whatvolume

    of

    hydrogen

    is

    necessa ry

    to

    react withfive liters

    of

    nitrogen

    to

    produce

    ammonia?

    (Assume

    constant temperatureandpressure.)

    2.

    What volume

    of

    ammonia

    is

    produced

    in the

    reaction

    in

    Problem1

    ?

    3.

    C

    3

    H

    8

    + 5O

    2

    - 3CO

    2

    + 4H

    2

    O

    If20liters ofoxygenareconsumedin theabovereaction,howmanyliters ofcarbon

    dioxide are produced?

    4. 2H

    2

    0

    2H

    2

    +0

    2

    If

    30

    mL

    of

    hydrogen

    are

    produced

    in the

    above reaction,

    how

    manymilliiiters

    of

    oxygen

    are

    produced?

    5.

    2CO + O

    2

    ->

    2CO

    2

    Howmany liters ofcarbon dioxideareproducedif 75

    liters

    ofcarbon monoxide

    are

    burned

    in

    oxygen?

    How

    many

    liters

    of

    oxygen

    arenecessary?

    Chemistry IF8766

    63 InstructionalFa ir, Inc.

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    llOICHIOMETRY:

    MIXED PROBLEMS

    Name

    N

    2

    + 3H

    2

    - 2NH

    3

    What

    volume

    of

    NH

    3

    at

    STP

    is

    produced

    if

    25.0

    g of

    N

    2

    is

    reacted with

    an

    excess

    ofH,?

    2.

    2KCIO

    3

    -* 2KCI

    +

    3O

    2

    If5.0 g ofKCIO

    3

    isdecomposed, what volumeof O

    2

    isproducedat STP?

    3, Howmany gramsof

    KCI

    areproducedinProblem2?

    4. Zn +

    2HCI -

    ZnCI

    2

    +

    H

    2

    What

    volumeofhydrogenat

    STP

    isproduced when2.5

    g

    of zincreact withan

    excessofhydrochloric acid?

    5.

    H

    2

    SO

    4

    + 2NaOH

    -* H

    2

    O

    +

    Na

    2

    SO

    4

    How

    many moleculesof water areproducedif 2.0 g ofsodiumsulfate are

    produced

    in the

    abovereaction?

    6.

    2AICI

    3

    -

    2AI +

    3CI2

    If

    10.0

    g ofaluminum chloridearedecomposed,howmany moleculesof CI

    2

    are

    produced?

    w

    Chemistry

    IF8766

    65

    Instructional Fa i r , Inc.

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    STOICHIOMETRY:

    LIMITING

    REAGENT

    Name

    f onaj -fopfc)

    . N

    2

    3 H

    2

    2NH,

    Howmany

    gramsofNH

    3

    can be

    produced

    fromthereactionof 28 g of

    N

    and

    25g ofH

    2

    ?

    2. Howmuchof the excess

    reagent

    in

    Problem

    1 s

    eft over?

    3.

    Mg +

    2HCI

    -

    MgCI

    2

    +

    H

    2

    What volume

    of

    hydrogen

    at STP isproduced

    from

    the

    reaction

    of

    50.0

    g of M

    theequivalentof 75 g of HCI?

    4. How much of the excess reagent in Problem3 is leftover?

    5. 3AgNO

    3

    +

    Na

    3

    PO

    4

    -

    Ag

    3

    P O

    4

    + 3NaNO

    3

    Silvernitrate and sodium phosphate arereactedinequalamounts of 200. g

    ea

    How

    manygrams

    of

    silver phosphate

    are

    produced?

    6.

    How

    much

    of the excess

    reagent

    in

    Problem

    5 is

    eft?

    ChemistryIF8766

    66

    Instructiona

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    N a m e

    IL

    Class

    Mass-Mass Problems

    Solving

    mass-mass

    p roblems usual ly involves these steps:

    1.

    Convertgiven masses in gramsto moles.

    2.

    U se coefficients in the balanc ed equ ation to establish mo le

    ratios

    between

    the substances involved in the problem.

    3.

    Calculate th e numb er of moles of the required substance.

    4. Convert

    that

    number of moles to mass in grams.

    Examples

    How many moles

    of

    F

    2

    are

    there

    in

    60.0s

    o fF,?

    (F

    = 19.0

    g/mole)

    mole

    mass

    of F

    2

    = 2 x 19.0

    g/mole

    = 38.0

    g/mole

    60.0 g

    38.0

    g/mole

    =

    1.58 moles

    In the

    followingreaction,

    ho w

    many moles

    of F

    2

    are

    needed

    to

    produce 1.5

    moles

    of HF?

    H

    2

    2HF

    mole ratio ofF

    2

    to HF = 12

    1:2= ?:1.5 ? = .75

    How many grams of HF is .75 moles of HF? (H = 1.0 g/mole)

    mole mass of HF = 1.0 g/mole + 19.0g/mole= 20g/mole

    .75 moles x 20g/mole= 15 g

    c

    o

    I Solve the

    following problems. Show

    your

    work.

    | 1.

    Given

    the

    equat ion

    N

    2

    (g)+

    3H

    2

    (g)-

    2N H

    3

    (g)

    answerthe

    fol-

    lowing questions.

    a. How many moles of N

    2

    are there in 200 g ofN,?

    (N

    = 14.0

    g/mole)

    la.

    Date

    o

    b.

    H ow

    many moles

    of

    NH

    3

    could

    be

    produced

    from the

    above amount

    of

    N

    2

    ?

    c.

    How many grams ofNH

    3

    would

    this

    be?

    (H =

    1.00 g/mole)

    c.

    11-3

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    Name

    Class

    Volume-Volumeand Mass-Volume Problems

    Date

    Volume-volume problems involve direct comparisonof the

    coef-

    ficients

    in abalanced

    equation.

    The

    reason

    is

    that equal volumes

    of gases at the same temperature and pressure contain equal

    numbers of moles and molecules. Also involved is thefactthat at

    STP the volumeof a gas isequalto22.4L /mole.Calculationof

    numbers

    of

    molecules involves

    the use of Avogadro's

    number,

    6.02 x

    10

    23

    molecules/mole.

    Examples

    Howmanylitersof HC1 gas can beproducedfrom 10 L ofC1

    2

    gas

    by the reaction H

    2

    +C1

    2

    -*2HC1?

    1:2=

    10L:?L

    ? = 20 L

    Howmany gramsofhydrogen gas (H

    2

    ) areneeded toproduce

    5.00

    L ofwater vapor, measuredatSTP, accordingto the reac-

    tion

    2H

    2

    +O

    2

    -2H

    2

    O? (H = 1.00 g/mole; O = 16.0g/mole)

    5.00

    L

    =.223 molesof

    H

    2

    O

    vapor

    22.4

    L/mole

    2:2

    = ?

    moles

    H

    2

    :.223

    molesH

    2

    0

    ? =

    .223 molesH

    2

    .223

    moles

    x

    2.00g/mole

    =

    .446

    g

    H

    2

    Howmany H

    2

    molecules aretherein .223 molesof H

    2

    atSTP?

    .223

    moles

    x

    6.02

    x

    10

    23

    molecules/mole

    = 1.34 x

    io

    23

    molecules H

    2

    Solve

    thefollowing problems. Show yourwork

    1. Howmany

    liters

    of

    CO

    2

    can beproduced

    from

    14.5L of C

    2

    H

    2

    by

    the reaction

    2C

    2

    H

    2

    (g)

    +

    50

    2

    (g)

    -

    4C0

    2

    (g) +

    2H

    2

    0(g)

    2. Howmanylitersofoxygenarereleased

    from

    thedecomposi-

    tionof 3.6 L of hydrogen peroxide gas

    (H

    2

    O

    2

    )

    to produce

    water vaporandoxygen? (Writethe

    balanced

    equation for

    the

    reaction

    as

    part

    of

    your work.)

    2H

    2

    0

    2

    (g)-+2H

    2

    0(g) +0

    2

    (g)

    2.

    < ~ H F M T S T R Y

    Review Activity

    11 5

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    Name

    Class

    Volume-Volumeand

    Mass-Volume

    Problems Continued)

    3. How many grams of zinc (Zn = 65.4g/mole) arerequired to

    produce

    67.2

    L of

    hydrogen

    gas at

    STP, according

    to the reac-

    tion

    2HCl-ZnCl

    2

    +

    H

    7

    3.

    Date

    4. a. How manyliters of

    C1

    2

    gas

    at STP can be produced by

    decomposing 70.0g of HC1

    gas?

    (H = 1.00 g/mole;

    Cl

    =

    35.5g/mole) (Includeabalanced equa tioninyour work.)

    4a.

    b. How many

    C1

    2

    molecules would be produced?

    5. How many liters of H

    2

    O vapor could be produced by the

    reaction

    of

    9.03

    x

    10

    23

    m olecules

    of

    O

    2

    ,according

    to the re-

    action

    2H

    2

    (g)

    +

    0

    2

    (g)

    -*

    2H

    2

    0(g)