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Teoria do Campo Cristalino Aula 1

Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

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Page 1: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Teoria do Campo

Cristalino Aula 1

Page 2: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Page 3: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Page 4: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Ex.:Cd

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 4d10

Ex.:Cd2+

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10

Por exemplo, considere o cádmio, que no estado fundamental possui 48 elétrons

Page 5: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Page 6: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Forma dos orbitais d:

Page 7: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

dz2 é o somatório da combinação linear entre:

Page 8: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Campo Cristalino octaédrico

Page 9: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Page 10: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Page 11: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Page 12: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Page 13: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

Page 14: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado

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