No Tc (° R) Pc (psi) Tc (°K) Pc (atm) Pc (Kpa)

1 271.20 705.4 150.67 48.00 4863.58

2 1051.50 1499 584.17 102.00 10335.28

3 1001.50 661.3 556.39 45.00 4559.52

4 239.30 507.4 132.94 34.53 3498.41

5 819.30 823 455.17 56.00 5674.40

6 547.60 1070.5 304.22 72.84 7380.86

7 993.60 1146.3 552.00 78.00 7903.49

8 1061.40 594.6 589.67 40.46 4099.64

9 584.20 1198.5 324.56 81.55 8263.39

10 750.90 1118.4 417.17 76.10 7711.12

11 761.70 1190.4 423.17 81.00 8207.55

12 59.70 190.8 33.17 12.98 1315.52

13 1165.10 3206.7 647.28 218.20 22109.49

14 672.40 1306.5 373.56 88.90 9008.03

15 730.20 1653.7 405.67 112.53 11401.90

16 80.10 395.3 44.50 26.90 2725.51

17 324.00 940.5 180.00 64.00 6484.54

18 775.80 1469.6 431.00 100.00 10132.57

19 221.30 492.9 122.94 33.54 3398.44

20 557.50 1053.7 309.72 71.70 7265.03

21 278.60 736.9 154.78 50.14 5080.76

22 775.20 1144.8 430.67 77.90 7893.14

23 883.60 1196.8 490.89 81.44 8251.67

24 965.80 793.6 536.56 54.00 5471.70

25 822.00 718.6 456.67 48.90 4954.59

26 747.30 984.6 415.17 67.00 6788.60

27 749.30 968.5 416.28 65.90 6677.59

28 950.70 1061.1 528.17 72.20 7316.05

29 343.90 673.1 191.06 45.80 4640.88

30 923.70 1153.6 513.17 78.50 7953.82

31 774.10 1081.6 430.06 73.60 7457.39

32 979.50 727.5 544.17 49.50 5015.95

33 1039.10 668.5 577.28 45.49 4609.16

34 555.00 890.3 308.33 60.58 6138.42

35 1054.30 740.7 585.72 50.40 5106.96

36 776.30 714.5 431.28 48.62 4926.32

37 914.30 832.7 507.94 56.66 5741.28

38 1101.90 701.2 612.17 47.71 4834.62

39 936.20 701 520.11 47.70 4833.24

40 509.50 742.2 283.06 50.50 5117.31

41 941.70 784.8 523.17 53.40 5411.02

42 1010.30 778.9 561.28 53.00 5370.34

43 830.10 805.3 461.17 54.80 5552.37

44 842.70 1048.4 468.17 71.34 7228.49

45 1070.60 839.1 594.78 57.10 5785.41

46 876.90 870.7 487.17 59.25 6003.29

47 828.70 764.2 460.39 52.00 5268.99

48 550.00 709.8 305.56 48.30 4893.91

49 720.10 764.2 400.06 52.00 5268.99

50 929.30 925.3 516.28 62.96 6379.74

51 1164.40 1091.9 646.89 74.30 7528.41

52 905.50 802.4 503.06 54.60 5532.37

53 898.50 796.5 499.17 54.20 5491.69

54 821.10 815.6 456.17 55.50 5623.38

55 934.50 512.9 519.17 34.90 3536.33

56 724.30 816.2 402.39 55.54 5627.52

57 721.70 747.2 400.94 50.84 5151.78

58 657.20 667 365.11 45.39 4598.82

59 917.00 693.7 509.44 47.20 4782.91

60 915.30 680.4 508.50 46.30 4691.21

61 912.40 680.9 506.89 46.33 4694.66

62 1102.30 178.9 612.39 12.17 1233.48

63 1074.40 683.1 596.89 46.48 4709.82

64 665.90 617.4 369.94 42.01 4256.84

65 915.00 691 508.33 47.02 4764.29

66 966.40 737.1 536.89 50.16 5082.14

67 779.90 590.8 433.28 40.20 4073.44

68 821.30 704.8 456.28 47.96 4859.44

69 1062.30 705.4 590.17 48.00 4863.58

70 998.20 563.3 554.56 38.33 3883.83

71 819.70 737.4 455.39 50.18 5084.21

72 834.70 683.2 463.72 46.49 4710.51

73 834.70 578.1 463.72 39.34 3985.87

74 765.00 628 425.00 42.73 4329.92

75 755.30 583 419.61 39.67 4019.66

76 779.70 610 433.17 41.51 4205.82

77 752.20 580 417.89 39.47 3998.97

78 770.70 595 428.17 40.49 4102.39

79 909.70 609 505.39 41.44 4198.92

80 964.20 603 535.67 41.03 4157.55

81 1130.70 648.1 628.17 44.10 4468.51

82 941.90 556 523.28 37.83 3833.50

83 955.10 578 530.61 39.33 3985.18

84 968.60 589.3 538.11 40.10 4063.09

85 1182.00 583.7 656.67 39.72 4024.48

86 734.70 529.1 408.17 36.00 3648.03

87 765.30 550.7 425.17 37.47 3796.96

88 985.90 623 547.72 42.39 4295.45

89 1013.20 640.5 562.89 43.58 4416.11

90 912.00 576.1 506.67 39.20 3972.08

91 840.20 523.2 466.78 35.60 3607.35

92 1225.90 668 681.06 45.45 4605.71

93 1182.80 714.2 657.11 48.60 4924.25

94 850.00 514.4 472.22 35.00 3546.67

95 870.00 527.6 483.33 35.90 3637.69

96 831.00 507 461.67 34.50 3495.65

97 921.20 655 511.78 44.57 4516.08

98 853.00 586 473.89 39.88 4040.34

99 860.60 512 478.11 34.84 3530.13

100 857.00 508.4 476.11 34.59 3505.31

101 1009.70 542.3 560.94 36.90 3739.04

102 988.90 483.6 549.39 32.91 3334.32

103 829.80 483 461.00 32.87 3330.18

104 845.60 489.5 469.78 33.31 3374.99

105 780.80 464 433.78 31.57 3199.18

106 1322.90 578.2 734.94 39.34 3986.56

107 1231.10 562.9 683.94 38.30 3881.07

108 1255.10 595.3 697.28 40.51 4104.46

109 1232.60 566.5 684.78 38.55 3905.89

110 1206.30 655.4 670.17 44.60 4518.84

111 1138.30 656 632.39 44.64 4522.98

112 1298.10 655.8 721.17 44.62 4521.60

113 1012.70 714.2 562.61 48.60 4924.25

114 1251.10 889.1 695.06 60.50 6130.15

115 1257.80 768.6 698.78 52.30 5299.33

116 995.30 591.5 552.94 40.25 4078.26

117 959.00 549 532.78 37.36 3785.23

118 920.00 471.7 511.11 32.10 3252.27

119 880.90 450.5 489.39 30.65 3106.10

120 900.50 455.4 500.28 30.99 3139.88

121 914.20 440 507.89 29.94 3033.70

122 896.50 440.1 498.06 29.95 3034.39

123 907.80 453.1 504.33 30.83 3124.02

124 1282.20 481 712.33 32.73 3316.39

125 1069.10 587.8 593.94 40.00 4052.75

126 1255.60 726 697.56 49.40 5005.61

127 1030.20 504.4 572.33 34.32 3477.73

128 1025.00 492.8 569.44 33.53 3397.75

129 963.90 412.2 535.50 28.05 2842.03

130 972.30 396.9 540.17 27.01 2736.54

131 1146.40 559 636.89 38.04 3854.18

132 1115.50 540 619.72 36.74 3723.18

133 1114.60 114.6 619.22 7.80 790.14

134 1138.00 530 632.22 36.06 3654.23

135 1112.80 500 618.22 34.02 3447.39

136 1084.70 453.9 602.61 30.89 3129.54

137 1062.50 406.5 590.28 27.66 2802.73

138 1024.90 362.1 569.39 24.64 2496.60

139 1432.40 304.4 795.78 20.71 2098.77

140 1245.50 553.6 691.94 37.67 3816.95

141 1225.90 526.6 681.06 35.83 3630.79

142 1192.60 500 662.56 34.02 3447.39

143 1172.00 441 651.11 30.01 3040.60

144 1149.00 149 638.33 10.14 1027.32

145 1114.50 369.2 619.17 25.12 2545.55

146 1071.00 331 595.00 22.52 2282.17

147 1347.00 576.1 748.33 39.20 3972.08

148 1266.20 483 703.44 32.87 3330.18

149 1286.20 486.5 714.56 33.10 3354.31

150 1188.70 773.9 660.39 52.66 5335.87

151 1188.80 418.7 660.44 28.49 2886.84

152 1224.10 453.6 680.06 30.87 3127.47

153 1162.40 353.9 645.78 24.08 2440.06

154 1114.00 14 618.89 0.95 96.53

155 1384.50 517.6 769.17 35.22 3568.74

156 1371.40 508.1 761.89 34.57 3503.24

157 1152.00 282 640.00 19.19 1944.33

158 1434.50 467.2 796.94 31.79 3221.24

159 1420.00 557 788.89 37.90 3840.39

160 1400.70 467.4 778.17 31.80 3222.62

161 1296.40 384.1 720.22 26.14 2648.29

162 1188.30 261.6 660.17 17.80 1803.67

163 1480.10 434.2 822.28 29.55 2993.71

164 1393.40 408.6 774.11 27.80 2817.21

165 1418.90 408.6 788.28 27.80 2817.21

166 1219.00 250 677.22 17.01 1723.70

167 1581.80 420.4 878.78 28.61 2898.57

168 1251.00 230 695.00 15.65 1585.80

169 1518.60 391 843.67 26.61 2695.86

170 1459.90 357.5 811.06 24.33 2464.88

171 1278.00 220 710.00 14.97 1516.85

172 1685.90 378.1 936.61 25.73 2606.92

173 1605.70 378.1 892.06 25.73 2606.92

174 1512.20 381.8 840.11 25.98 2632.43

175 1305.00 206 725.00 14.02 1420.32

176 1788.50 346.4 993.61 23.57 2388.35

Vc (pies3/lbs) Vc (m3/kg) Vc (m3/kg)1 0.0988 0.0062 0.0062

2 0.0783 0.0049 0.0049

3 0.0727 0.0045 0.0045

4 0.0714 0.0045 0.0045

5 0.0703 0.0044 0.0044

6 0.0679 0.0042 0.0042

7 0.0675 0.0042 0.0042

8 0.0673 0.0042 0.0042

9 0.0688 0.0043 0.0043

10 0.0682 0.0043 0.0043

11 0.0682 0.0043 0.0043

12 0.0667 0.0042 0.0042

13 0.0665 0.0041 0.0042

14 0.0691 0.0043 0.0043

15 0.0673 0.0042 0.0042

16 0.0646 0.0040 0.0040

17 0.0665 0.0041 0.0042

18 0.0665 0.0041 0.0042

19 0.0668 0.0042 0.0042

20 0.0662 0.0041 0.0041

21 0.0636 0.0040 0.0040

22 0.069 0.0043 0.0043

23 0.0676 0.0042 0.0042

24 0.0656 0.0041 0.0041

25 0.0684 0.0043 0.0043

26 0.0679 0.0042 0.0042

27 0.0594 0.0037 0.0037

28 0.0607 0.0038 0.0038

29 0.0586 0.0037 0.0037

30 0.06 0.0037 0.0037

31 0.0746 0.0047 0.0047

32 0.0689 0.0043 0.0043

33 0.0685 0.0043 0.0043

34 0.0668 0.0042 0.0042

35 0.0679 0.0042 0.0042

36 0.0682 0.0043 0.0043

37 0.0676 0.0042 0.0042

38 0.065 0.0041 0.0041

39 0.0654 0.0041 0.0041

40 0.065 0.0041 0.0041

41 0.0695 0.0043 0.0043

42 0.0531 0.0033 0.0033

43 0.055 0.0034 0.0034

44 0.0565 0.0035 0.0035

45 0.0557 0.0035 0.0035

46 0.0567 0.0035 0.0035

47 0.057 0.0036 0.0036

48 0.0534 0.0033 0.0033

49 0.0572 0.0036 0.0036

50 0.059 0.0037 0.0037

51 0.0581 0.0036 0.0036

52 0.0532 0.0033 0.0033

53 0.0344 0.0021 0.0021

54 0.0461 0.0029 0.0029

55 0.0305 0.0019 0.0019

56 0.0681 0.0042 0.0043

57 0.0517 0.0032 0.0032

58 0.5165 0.0322 0.0322

59 0.0367 0.0023 0.0023

60 0.051 0.0032 0.0032

61 0.028 0.0017 0.0017

62 0.0497 0.0031 0.0031

63 0.23 0.0143 0.0144

64 0.0356 0.0022 0.0022

DATOS PROBLEMABUTANO

P= 300 atmT= 393.15 °K 200 °Cm= 30V= #VALUE!

SISTEMA INTERNACIONAL SISTEMA INGLÉS

Tc 191.06 °K Tc 343.908 °RPc 45.80 atm Pa Pc 673.26 PsiR 0.08 atm*m3/kmol*°K R 10.731 psia*pie3/lbmol*°R

atm*L/mol°K

a b a b

2.26 0.04 8534.3 0.7

atm*m6/kmol2 m3/kmol psi*pie6/lbmol2 pie3/lbmolatm*L2/mol2 L/mol

CARDANOCARDANO

P= 1.440414E-005

q= -0.0001963874

9.642004E-009

x= #VALUE!

a= -0.150

b= 0.008

c= -0.0003

PARA SABER EL VOLUMEN QUE CORRESPONDEN A 25G DE BUTANO

1mol de Butano = 58 g/moln=25g/58g/moln=0.4310 mol ENTONCES

X=n=

1 mol de la sustancia X= 16.014 g/mol V=m= 30 gramos Vm=n= 1.87336081 mol

Volumen Molar o Específico=

Δ=

P=(3b-a^2)/3

q=(2a^3-9(ab)+27 c)/27

∆= (q/2)^2+ (P/3)^3

x= √(3&(-q/2)+ " " √∆ ) + √(3&(-q/2)- " " √∆ ) - a/3

Van der Waals

psia*pie3/lbmol*°R

- a= 0.15032448 Negativo

b= 0.00754689 Positivo

- c= 0.00032292 Negativo

#VALUE!1.87336081 mol

#VALUE! m3 o L#VALUE!

Volumen Molar o Específico= 0.17237

b=(R ∗Tc)/8Pc

a= Pc 27 b^2

x= √(3&(-q/2)+ " " √∆ ) + √(3&(-q/2)- " " √∆ ) - a/3

V^3 - (V^2 (Pb+RT)+V∗a -ab)/P

FORMA ESTÁNDAR

OJOPARA SACAR LA PRESIÓN SE OCUPA EL Vm

P= #VALUE! atm

P=RT/((V-b)) - a/V^2

DATOS PROBLEMABUTANO

P= 230 atmT= 473.15 °K 200 °Cm= 25 grV= 0.2439902489

SISTEMA INTERNACIONAL SISTEMA INGLÉS

Tc 425.16 °K Tc 765.288 °RPc 37.50 atm Pa Pc 551.25 PsiR 0.08 atm*m3/kmol*°K R 10.731 psia*pie3/lbmol*°R

atm*L/mol°K

a b a b

0.02 0.08 51613.7 1.9

atm*m6/kmol2 m3/kmol psi*pie6/lbmol2 pie3/lbmolatm*L2/mol2 L/mol

CARDANOCARDANO

P= -0.0832985633

q= -0.009848866

2.843387E-006

x= 0.5660573774

a= -0.691

b= 0.076

c= -0.003

PARA SABER EL VOLUMEN QUE CORRESPONDEN A 25G DE BUTANO

1mol de Butano = 58 g/moln=25g/58g/moln=0.4310 mol ENTONCES

X=n=

1 mol de la sustancia X= 58 g/mol V=m= 25 gramos Vm=n= 0.43103448 mol

Volumen Molar o Específico=

Δ=

P=(3b-a^2)/3

q=(2a^3-9(ab)+27 c)/27

∆= (q/2)^2+ (P/3)^3

x= √(3&(-q/2)+ " " √∆ ) + √(3&(-q/2)- " " √∆ ) - a/3

Redlich Kwong

psia*pie3/lbmol*°R

.

- a= 0.1688055198 Negativo

b= -4.6237603628 Positivo

- c= 0.0001243841 Negativo

0.566057380.43103448 mol0.24399025 m3 o L0.56605738

Volumen Molar o Específico= 0.17237

x= √(3&(-q/2)+ " " √∆ ) + √(3&(-q/2)- " " √∆ ) - a/3

FORMA ESTÁNDAR

OJOPARA SACAR LA PRESIÓN SE OCUPA EL Vm

P= 79.926374 atm

P=RT/((V-b)) - a/V^2

PARA SACAR LA PRESIÓN SE OCUPA EL Vm

DATOS PROBLEMABUTANO

P= 120 atmT= 150.00 °K 200 °Cm= 50V= #VALUE!

SISTEMA INTERNACIONAL SISTEMA INGLÉS

Tc 590.28 °K Tc 1062.504 °RPc 27.65 atm Pa Pc 406.455 PsiR 0.08 atm*m3/kmol*°K R 10.731 psia*pie3/lbmol*°R

atm*L/mol°K

a b a b

35.80 0.22 134931.3 3.5

atm*m6/kmol2 m3/kmol psi*pie6/lbmol2 pie3/lbmolatm*L2/mol2 L/mol

CARDANOCARDANO

P= 0.2638377199

q= -0.0358098964

0.0010008032

x= #VALUE!

a= -0.322

b= 0.298

c= -0.065

PARA SABER EL VOLUMEN QUE CORRESPONDEN A 25G DE BUTANO

1mol de Butano = 58 g/moln=25g/58g/moln=0.4310 mol ENTONCES

X=n=

1 mol de la sustancia X= 114.232 g/mol V=m= 50 gramos Vm=n= 0.43770572 mol

Volumen Molar o Específico=

Δ=

P=(3b-a^2)/3

q=(2a^3-9(ab)+27 c)/27

∆= (q/2)^2+ (P/3)^3

x= √(3&(-q/2)+ " " √∆ ) + √(3&(-q/2)- " " √∆ ) - a/3

Van der Waals

psia*pie3/lbmol*°R

- a= 0.32154325 Negativo

b= 0.29830107 Positivo

- c= 0.06531958 Negativo

#VALUE!0.43770572 mol

#VALUE! m3 o L#VALUE!

Volumen Molar o Específico= 0.17237

b=(R ∗Tc)/8Pc

a= Pc 27 b^2

x= √(3&(-q/2)+ " " √∆ ) + √(3&(-q/2)- " " √∆ ) - a/3

V^3 - (V^2 (Pb+RT)+V∗a -ab)/P

FORMA ESTÁNDAR

OJOPARA SACAR LA PRESIÓN SE OCUPA EL Vm

P= #VALUE! atm

P=RT/((V-b)) - a/V^2