t ANALYTICAL CATA REPORT PACKAGE FOR.' EARTH … · m ^^i'l industrial corrosion management incorporated ttstmnenkmnoukikwxihetertm 10«-«m41n data summary report; e^th technology

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SDMS Document

68215

t ANALYTICAL CATA REPORT PACKAGE FOR.' •y^r*^'.-•^^•^*-*:•*•|y*•i^•fr•^r*-fr•^!-k•k•**•fr-A * * * * * * * * • ^ • * - k * - k * * * * * * * * * * * * * * * * * * - f , - k * * * * * * * * * * * * * - ' t - A * - k * * - ^ - i , - » r 4 r *

EARTH TtrCHNOLOGY CORf'ORATION

Stapling Machine

August 1. 1989 I

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£.aae_*. O.-jti M;3n33c->Tri£nt Sarrinsiry i Lab/Client ID Cross Reference 2 Q'? 1 i V»? r. i b 1 c s C h e c; k i i'-, t 3 Field Chain-of-Custody 4 - 5 LjbOiVjtory Cha i n--of-Castod ie-s 6 - 15 Laboratory Chronicles 16 No nco nf or:T:3nce Summary 23 - 25 Methodology Summaries 26 - 29 S3n;plf? Results: SMC-MU-1-2 Lab #103438 30 SMC-MU-2-2 Lab #103439 46 SMC-MU-3-2 Lab #103440 54 SMC-MU-4-2 Lab #103441 64 SMC-MU-5-2 Lab #103442 74 SMC-F8-2 Lab #103443 34 SMC-TB-2 Lab #103444 94

Q'jality Assurance Oata; Volatiles Aqueous 9 7 - 1 1 2

Quality Assurance 03ta: Semivolatiles Aqueous 113 - 124

Quality Assurance Data; Petroleum Hydrocarbons Aqueous 125 - 126

Quality Assurance Data: General Analytical Aqueous 53

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INDUSTRIAL CORROSION MANAGEMENT INCORPORATED

t t S t m n E N k M N O U K I K W X I H E T e r t M 10«-«M41N

DATA SUMMARY REPORT; E^TH TECHNOLOGY CORPORATION - STAPLING MACHINE

The following sutniarises those parameters and their corresponding concentrations found in the aamples submitted.

SAMPLE ID

PARAMETERS i WLWItES: 'dt0-yi^ 1,1-Dlchloroethene (ppb) '*'* f V;

•• .''-H y ' i / i . .

Trlchloroethene (ppb) '•

Bencene (ppb) • ' • .y,- ' \ 'gÂ

Toluene (ppb)

Chlorobentene (ppb)

pH (standard units)

t m TOO iMH

' S H C -MM-1-2

22

19

15

2.1

16

13

7.27

SMC-MW-2-2

6.51

SMC-MW-3-2

6.42

SMC-MW-4-2

7.35

'.'.f.-.i

SMC-MW-5-2

6.85

•^4Hy

Srtt-FB-2

6.74

SMfc-TB-2

NA

B-Analyte found in blank J*Identtfled at value 1 than detection limit; value is estimated

. •. • »

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1 i ; :i >• g u 113 1 0

Pando l(r!> , NJ 07869 .::-M-'53-1-v?:?0 AMGUSr 1, 1989

•M^mp NJ OEP Certifie.i Drink in<J Ua t er/U ast r-.-j t,--Laboratory ID* i'l U 6 3 US EPA Contrii.it Laboratorv

AK'ALVriCA-L '.'ATA REPORT PACKAGE FGHi

C 1 i i - r . t :

•? i::t.;> 1 >? ':; ;) U T'C e

I'^ciirif ] c d \ i y :

EARTH T E C H K ' O L O G Y CORPORATION

STAPLING nACHIN!-;: CUSTOMIf.R

SAMPLE. ID:

SMC-MU-1-2 SMC-?';U!-2-2 SMC-KU-3-2 Si'(C-KU~4-2 SMC-MU-^.-2 SMC-F.'5-2 SMC-TB-:>

MATRIX

U-^TER UATER UATER WATER UATER UATER UATER

LAB NUMBER

103438 103439 103440 103441 103442 103443 103444

DATE *. TIME

COLLECTED

06/23/89 0 6 / 2 3 / 3 9 06/23/89 06/23/99 06/23/89 06/23/99 06/23/89

13: 14 12; 14 15i 12i

; 10 •y30

;45 ;50 !l0 ;30

AT LAS DATE

06/23/89 06/23/89 06/23/S9 06/23/39 06/23/39 06/23/S? 06/23/89

S u p e r v i s o r / M a n a g e r S i g n a t u r e :

C o p y r i g h t ICM, I r i c , 19S6. A l l r i s h t s r e s e r v e d . TS

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,' • ' ^ ' ' • ^ . " • ' ' • ^ • T ^ ' ^ ^ ^ - ^

INDUSTRIAL CORROSION NANACENENT 1152 Route 10 Randolpii, New Jersey 07869 210-584-0330

The Earth Technology Corporation 53 Haddonfield Road. Suite 316 Cherry Hill, Nev Jersey 08002

Re: Stapling Machine - Base/Neutral Surrogate Recovery

To Whoa it Nay Concern:

Two of the Three BN surrogates added to SHC-MW 5-2 saaple (our lab • 103442) for the Base/Neutral analysis did not recover to within QC liaits. The recoveries were as follows:

Nitrohenxene-ds 2 33 - 141 2-Piuorobiphenyl 25 43 - 116

As the saaple appeared to have only ainiaal aatrix interference, it iSf suspected that the poor surrogate recoveries are due to laboratory |. error. Possible causes are technician error in adding the surrogates^' or error when concentrating the extract.

I hope that this error will not cause yon any difficulties. If you have any further questions, please do not hesitate to call.

Sincere ly , ICM Laboratories

Edwina B. Cariat i Quali ty Assurance Supervisor

EBC/ks

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LABORATORY DELIVERABLES

THIS FORM MUST BE COMPLETED BY THE LABORATORY OR ENVIRONMENTAL CONSULTANT AND ACCOMPANY ALL DATA SUBMISSIONS

The following laboratory deliverables shall be included in the data submission. All'deviations from the accepted methodology and procedures, or performance values outside acceptable ranges shall be summarized in - the Non-Conformance Summary. Attachment 2 of the Draft ECRA Sampling Plan Guide (ESPG) provides further details to be followed. The document shall be bound and paginated, contain a table of contents, and all pages shall be legible. Incomplete packages will be returned or held without review until the data package is completed.

Check if Complete

I.

II.

III.

IV.

V.

VI.

VII.

VIII.

IX.

X.

Cover Page, Format, and Laboratory Certlflcatiea (Include Cross Reference Table cf Field I.D. # and Laboratory I.D. #)

Chain of Custody

Summary Sheets Listing Analytical Results Including QA Data Information (see Attached Fora and ESPG Attachment 2.B.2.C.)

Laboratory Chronicle and Hethodolofy

Suonary including Sampling Holding Tiae Check

Initlal Calibration and Continuing Calibration

Tuna Suanary (MS)

Blanks (Mathod, Fiald. Trip)

SurrogAt* Kacovazy Suaaazy

Chroaatofra^w Laballad/Coopound Identification

(flidiiai Oiti^t^ Liaits (Lower thaa Action Level If CifiBtiZdiM:<8iiiipl« - and consistent vith aethod l iidUiiliUiM)'.", ,....

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SAMPLE MATERIAL

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Gbebreyesus, Habteab

Harvey, Sarab

Heller, Sbaron

Hof, Philip

Holt, Sodica

Jercsyaski, Hallns

Kadakla. Geeta

Koleno, Paals

Kusterer, Jeaaac

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Norton, Kiaberly

Peters, Catbsrine

Pies, Sangeeta

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Bei, Aaabela

Biccio, Mark

Bicbardsoa, Snsaa

Bldlngs, Audrey

Biagwelski, Eva

Boberts, S. David

Santana, Illnaiaada

Sarsony, Kenneth

Strojnovska, Isshella

Thorp, Carla

Wachal, Btati

Oboh* Aaroit-w V

Selengut t' Jeffrey

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SIGNATURE IDENTIFICATION FOR IN-HOUSE CHAIN-OF-CUSTODIES

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NAME ^ SIGNATURE INITIALS

Maedel, Lynne > A ^ 1 U U L / ( - J y C M ^ ^ ' ^ ry^fgC---

Tesfaghiorghls, Teoane_

Otey, Margo Mann. Dudley ^ ^ ^ ^ " T h ^ Q ^/^

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:tii'i NJ DEP Certified Drinking Wacer/WasCftwater ""Prî^

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Laboratory 1D# 14116

LABORATORY CHRONICLE

DATE RECEIPT/REFRIGERATION

DATE SAMPLED

" m i^/;?-^/y\

GC/MS:

Extractions: Acids

Base/Neutrals taj.xn ^ \

Analysis Volatiles

Acids

Base/Neutrals "1 ( I 3^[<^

GC: Extractions:

Pesticide>PCB Analysis:

Pesticide/PCB

Volatiles

rETROLEDM HYDROCARBONS;

Extractions: L,! M l ^

Analysis: j » h^

ATOMIC ABSORPTION:

Metals:

Mercury: ____

GENERAL ANALYTICAL;!'-'

Cyanide:

Phenol:

OTHER ANALYSIS:

fit^ •'''hh

LAB # io'a.«43>y

PRESERVATIVE Uâ^j^j^fiflliiiii^ SO*f

Section Supervisor Review & Approval:

(Signature)

1 Section Supervisor Review & i^proval:

(Signature)


(Signature) ''Ôi^.


(Signature)


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(Signature)

F ina l Approval: CJjuLJUf^ J S . Û>vautL

Quality Assurance Coordinator 1 6

Si'i "yiMjiM

NJ DEP Certified Drinking Water/Wastewater •"t^* Laboratory ID# 14116


DATE SAMPLED


^Hh LAB #__L0ii3l. PRI-SERVATIVE i^^Y^jtô^j^,^! f>l^\Ci^

GC/MS:

Extractions; Acids

Base/Neutrals .l alsL Analysis: . .

Volatiles U)(X^/^

Acids

Base/Neutrals ll |->-(^

GC:

Section Supervisor Review &

Extractions: Pesticlde7PCB

Analysis: Pesticide/PCB

Volatiles

PETROLEUM HYDROCARBONS:

Extractions: Loi 1 !

Analysis: (//

ATOMIC ABSORPTION:

Metals:

Mercury:

' $ • - • •

GENERAL ANALYTICAL: : -

Cyanide:

Phenol:

OTHER ANALYSIS:

r/ri ^/ft


Section Supervisor Review & Approval: _



Final Approval: ^ ^

1 7 Quel:

(Signature)

(Signature)

(Signature)

(Signature)

Lty Assurance Co

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Sl'i NJ DEP C e r t i f i e d Dr ink ing Water/Wastewater L a b o r a t o r y ID# 14116



DATE SAMPLED

'/>3/gA LAB # lO^'tO

GC/MS:

/ ^ / p - ^ / r l PRESERVATIVE J t f ^ ^ i a ^ j g w i i i S o ^

Extractions; Acids

Base/Neutrals U [--l [^

Analysis: Volatiles

Acids

Base/Neutrals "7 ( /^/S^ Section Supervisor Review & Approval

^'SigiSure") GC:

Extractions: Pesticide7PCB


Volatiles


Extractions:

Analysis:

ATOMIC ABSORPTION:

Metals:

Mercury:

Jj^rfet Jî l^

' / • • - •


Section Supervisor Review & Approval: __

(Signature)

(Signature) ""•

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(Signature)

GENERAL ANALYTICAL:'

Cyanide:

Phenol: Section Supervisor Review & Approval:

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(Signature)

OTHER ANALYSIS:

H-V^l^^l^

18

Final Approval: Fjûcn^Mi^ J^_ Gc-iIlX^

Quality Aasurance Coordinator

:î ' i NJ DEP Certified Drinking Water/Wastewater " 9 1 Laboratory ID# 14116 •'':!;'


DATE SAMPLED


U l ^ - ^ l ^ L.\B # <^/>^/A

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GC/MS:

Extractions: Acids

Base/Neutrals la 1 > n [ ^

Analysis: Volatiles Acids

U>(d^fa?l*S^

Base/Neutrals "{ |i " ^ j ^

GC: Extractions:

Pestlcide7PCB Analysis:

Pesticide/PCB

Volatiles

PETROLEUM HYDROCARBONS;

Extractions: L/|a<{|S^

Analysis: U |j.V[Vt

ATOMIC ABSORPTION:

Metals:

Mercury: .

GENERAL ANALYTlOa.?

C y a n i d e :

P h e n o l ;

OTHER ANALYSIS:

PRZSERVATIVE _0±^ i iS - - s>u i£<J jW^^^^

Section Supervisor Review & Approval

(Signature)



(Signature)

^ ' t ^ < ^ (Signature)


(Signature)


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(Signature)

Quality Assurance Coordinator

u NJ DEP C e r t i f i e d Dr inking Water /Wastewate i L a b o r a t o r y ID# 14116


DATE SAMPLED


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GC/MS;

Extractions: Acids

Base/Neutrals

Analys i s : V o l a t i l e s

J alM •lûi-ISft

Acids

Base/Neutrals -aU^H

GC; Extractions:

PesticideyPCB Analysis:

Pesticide/PCB

Volatiles


Extractions:

Analysis:

uUt^ J J ^

k. < 4 ^ Y ( < ^

ATOMIC ABSORPTION:

Metals:

Mercury:

GENERAL ANALYTICAL:

Cyanide:

Phenol:

OTHER ANALYSIS: .

PRESERVATIVE ^ ^ ^ O t f ' \ J - t J fJ S0«


(Slgnaturfe)


(Signature)

(Signature)

Section Supervisor Review & Approval;

(Signature) C3 O


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20

(Signature 1

(^lallcy Aaauranee Coordinator:

M :iii'j

NJ DEP C e r t i f i e d Dr ink ing Water/Wastewater L a b o r a t o r y ID# 14116



DATE SAMPLED

M [ T>M

LAB #__iVbHH3^ PRESERVATIVE

GC/MS:

Extractions; Acids

Base/Neutrals Vj\x.'llV\

Analysis: Volatiles

Acids

Base/Neutrals IHJE

GC: Extractions:

Pcsticide7PCB Analysis:

Pesticide/PCB

Volatiles


Extractions;

Analysis:

"u^Mlja Mu

ATOMIC ABSORPTION:

Metals:

Mercury:

GENERAL ANALYTICAL;

Cyanide:

Phenol:

OTHER ANALYSIS:



\*,iA^tf^^r<l. , (J^ÔY

(Signature)




(Signature) ^ ^

(Signature)

(Signature)

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Final Approval: c j^JL^niULJD, C^^^tcaA


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'Mi NJ DEP Certified Drinking Water/Waste^/ater"" Laboratory ID#, 14116 "-^'y^


DATE RECEIPT/REFftlGERAIION

DATE SAMPLED

u( 3,:> fa u I ^ m

LAB / /b'S« < *<'

PRESERVATIVE

GC/MS:

Extractions: Acids

Base/Neutrals

Analysis: Volatiles «Ul^ Acids

Base/Neutrals

GC: Extractions:

Pestlcide>PCB Analysis:

Pesticide/PCB

Volatiles


Extractions:

Analysis:

AT(»aC ABSORPTION:




Metals:

Mercury: -.;

fPT0^y-

GENERAL AHALYTiCAl^^

Cyanide:

1

1

Phenol:

OTHER ANALYSIS:

• . . . . . . '

]

22



£ t< Vy N «»a*4xJi,

(Signature gnature)

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(Signature)

(Signature)

(Signature)

(Signature)

Final Approval: Odt^tiViL A . Q u ^ '

Quality Aasurance Coordlnatoi

^ y ^ ! ^

11S2 Boute 10 NJ DEP Certified Drinking Hater/ ^ ^ . # ^ Randoipb, NJ 07869 Wastewater Laboratory I0I14116 201-584-0330 USEPA Contract Laboratory

NOWCOWPQRMANCE SUMMARY CHECKLIST

Lab Nu.h«r., lO^H-b^ - (&!>^^H

Volatile Organics: Anaiyied -y Not Analysed

A H tunes were run in required frequency. Yes -^ No

Ail tune a/x ratios aet criteria. Yes -^ No

Ail iaitial and/or continuing calibrations were run in required frequency. Yes j^ No

All calibration SPCCs and CCCs aet criteria. Yes No

Surrogate recoveries aet QC criteria. Yes -^ No

All aethod blanks aet contaaination criteria. Yes N o _

All saaples were analysed witbin the required holding tiaes, Yes / No

Other nonconforsanccs.

Coaaents!

Seal-volatile Organics: Analysed J Not Analysed

All tunes were run in required frequency. Yes ^ No

All tune a/i ratios aet criteria. Yes ^ No »

All initial and/or continuing calibrations were run in required

frcgaoncy. Yes / No o o

A U c a l l b r i t i O B SPCCs and CCCs aet c r i t e r i a . Yes y No

Saritogate recover ies aet QC c r i t e r i a . Yes No_/

All •ethdd'^blanks net contaainat ion c r i t e r i a . Yes • No.

-J o

All saaples wece extracted and analysed within the required holding tiaes. Yes No

Other nonconf oraances. AlXM^^-^Ly^^^^-eig « w A J ^ - f l h U 7 i ^ - ( n ^ C f ^

Coaaents:

_ 2 ^

1152 Route 10 NJ DEP Certified Drinking Water'/ 1 1 - ^ ^ 3 Randolph, NJ 07869 Wastewater Laboratory IDtl4H6 ti. ii 201-584-0330 USEPA Contract Laboratory #S/I

NONCONFORMANCE SUMMARY CHECKLIST

Lab Nunbers: I lii^^H 3 ^ - / 0 1 ^ 4 ^

Pesticides/PCBs: Analysed Not Analysed ^

All aetbod blanks aet contaaination criteria. Yes No

All saaples were extracted and analysed within the required bolding tiaes. Yes No

Other nonconforaances.

Coaaents:

Metals: Analysed Not Analysed ^

All aethod blanks net contaaination criteria. Yes No_

All saaples were analysed within the required holding tiaes. Yes No

Other nonconforaances..

Coaaentsi

Petroleaa Hydrocarbons: Analysed_^^ Not Analysed

All saaales were analysed within the required holding tiaes,

Othe^râoneoaf oraances.

y-i.

w

o Coaaents: o

24

fl. , — 1152 Route 10 NJ DEP Certified Drinking Water/ -'IrfS ife' >; ." Randolph, NJ 07869 Wastewater Laboratory IDtl4116 - - •">

201-584-0330 USEPA Contract Laboratory


Lab- M a . h c r s : ( D ^ ^ 1>^ ~ ( 0 :^ H <4 ^

General Chcaistry: Analysed Not Analysed

All saaples were analysed within the required holding tiaes. Yes_ji_ No

Other nonconforaances..

Coaaents:.

General:

All saaples were properly preserved in the field, ^ e s j , No.

Coaaents:

Additional Coaaents;

<\

^ -

25

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Puracablcs (CC/MS)

MATRIX: Water

y i i

METHOD REFERENCE: Code of Federal Regulations 40, Part 136, Appendix A, Metbod 624.

METHOD SUMMARY: Heliun is bubbled through a S nl water saaple contained in specially designed purging chanber for 11 nin. at aabient teaperature. The purgeables are transferred froa the aqueous to the vapor phase and passed through a 3 coaponent trap (OV-1, Tenax and silica gel) where they are absorbed. After purging is conplete, the trap is heated and backflushed with heliua to desorb the purgeables onto a gas chroaato-graphic coluan. The chroaatograph is teaperature prograaaed (3 ain. at 4S degrees C, then ranp to 220 degrees C at 8 degreos/ain.; final hold 12ain.) to separate the purgeables which are then detected with the aass spectroaeter. The aass spectroaeter data I systea (RTE-6) identifies target coapounds that aeet the criteria of retention tiae (-*30 s e c ) , relative abundance of characteristic aasses (-*20X), and aaxiaisation of characteristic aasses within 1 scan of each other. Other coapounds detected can be searched by the data systea in its EPA/NIH library of 42000* coapounds.

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26

:• .-•. ' i iy- i^

33je_Ncmr.U jmJ Aciii^

MATRIX: Wjtct

METHOD REFERENCE: Code of Federal Regulations 40, Method 625.

Pjrt 136, Appendix A,

METHOD SUMMARY: A Bcasured voluae of saaple, approxiaatel is serially extracted with acthylene chlo pH greater than 11 and again at pH less t a separatory funnel. The nethylene chlor is dried, concentrated to a voluae of 1.0 analysed by CC/MS. The gas chroaatograph SPB-5 capillary coluan, is prograaaed at C (1 Bin.) to 60 degrees C at 30 degrees then to 300 degrees C at 8 degrees C/ain, final hold of 24 ain. The aass spectroae systea (RTE-6) identifies target coapound the criteria of retention tiae (-•30 sec. abundance of 3 characteristic aasses (-•2 standard spectra), and aaxiaisation of characteristic aasses within 1 scan of ea Other coapounds detected can be searched systcB in its EPA/NIH library of 42000* c Quantitative analysis is perforaed using internal standard techniques with a singl characteristic a/s.

y 1 liter, ride at a ban 2 using ide extract al and with 30 a .

30 degrees C / a i n . ,

with a , :, t e rvda tac ;., s t ha t , a e e t ) ,_ r e l a t ^ e v ; OX - - o t y •••.•Wi'^''pi

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•-.mr-

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27

PETROLEUM HYDROCARBON

MATRIX: Water

'mm '•ysyi

METHOD REFERENCE: U.S. EPA Methods for cheaical Analysis of Water and Wastes, 1983 Spectropbotoaetric Infrared Method 418.1

METHOD SUMMARY: The saaple bottle is aarked at the water aeniscus for later deteraination of voluae. The saaple is poured into a 2000 al separatory funnel. The saaple bottle is rinsed with 30 al of fluorocarbon-113 which is then added to the saaple in the separatory funnel. The funnel is shaken for 10 ainutes and the solvent layer filtered through a funnel containing solvent-aoistened filter paper into a 100 al voluaetric flask. The saaple is' extracted twice aore with 30 al of fresh solvent coabin-ing all extracts in the voluaetric flask. The extract is diluted to 100 Bl. 3 g. of silica gel is added and stirred for S ninutes. Quantitation is perforaed using an infrared, spectrophotoaeter. Appropriate dilutions are aade if the extract concentration is greater than 4ag/100al.

W

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28

tK

MATRIX: Water

METHOD REFERENCE: Standard Methods 16th Edition, Method 423

• - ^ l • • • > ^ i r

ym

METHOD SUMMARY: Following standardisation of the pH neter, the electrode is rinsed with deionised water and blotted dry. Saaples are brought to rooa teaperature, the electrode is iaaersed in the solution, and when equilibriua is established, the pH is read.

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11 "5 2 R c u t e 10 R a n d ) I p h , NJ C78A9 : C - l - ' ? : 3 4 - 0 3 3 0 AMGUST ] , 1 9 8 9

N.J D£P C e r t i f i i ^ d D r i n k i n g L a b o r a t o r y ID l 1411.6 US EPA C o n t r a c t L a b o r a t o r y

U a t e r / U a r, t €' u a t e^^ • '•y-' ' j5,i

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GC/MS VOLATILES - TIEf? I I DEL IVfrABLES

l.<.>b ^ . ' l ; ^ l h e ^ : CI L.:- r» t : S;?>:iple i i o u r c e : S i 11: P 11? I D : S3»riF> ] e d a t e ; £an;p l a i by ; A t l a b d a t e ; M a t r i x :

103^38 EARTH TECHMOLO-Gr STAPLING MACHINE SMC-H(J-l--:2 06/23/8' CUSTOMER 06/23/89 UATER

CQRFGRATICN

Par am«?ter Result ug/1

Chl Bro Win Chl Met 1 ,1 1 . 1 tot Chl 1 ,2 1 ,1 Ccir Bro 1 ,2 t-1 Tri Dib 1 , 1 Ben c-1 2-C Bro Tet 1 ,1 Tol Chl Eth Tot

0 r

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0 »?t len i<:h ich --1 , of 0 i r. !i --Tr •n T die ich -Di lor mo c -Tr ne -Oi 0 ro f o r chl / »-ne ob<? ben Xy

thane hane loride hane e Chlor ide lo roethylene loroethane 2-Oichloroethene

lore cv thane ichlo ro ethane etrachlo ride hlo romethane loropropane chlo ropropene 0 ethiy lene hlo romethane ichloroethane

19

chlo ropropene ethylvinyl Ether m 0 roethylene Tetrachloroethane

nzeno z ene lenes

16 13

U U U U U

U U U u u u u u u

u u

u u u J u

u u

UJ/I micrograms/liter or ppb

Method Slank ug/1

Min imum Detect io n Limit ug/1

U U U U U U U U U U U U U U U U U U U U U U U U U U U

u

S

5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5

ll: Indicates a compound uas analyzed for but not detected. Ji [ndicate-s an e<>timated value. It is utilized when a reported value

meets the identification criteria but the result is less than ihe -ipecified detection limit but greater than zero.

B: Indicates that the analyte was found in the blank as well as the sample. It indicates possible/probable blank contamination.

Copyright ICM, I-nc. ;'1986. All rights reserved, TS

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35

1 i-:i2 Riu t.e 10 Piindjlph, N.J 07S69 2 0 1 -•:•>• A - 0 3 3 0 AUGUST J, 1989

' " ' ' ' ' • - • ' ^^^ f /M NJ DEP C e r t i f i e d O r i n k i n s Uater /Uartet jJ j i^ t L a b o r a t o r y I D * 14116 ' ^ 0 US EPA C o n t r a c t L a b o r a t o r y

LAEOPATORY ANALYSIS A ] ] r e s u l t t i a r e r e p o r t e d i n m g / l (ppm) u n l e s ' i o t h e r y i s e s t a t e d

C l i e n t ! Soiirpli? Soa;~ce: ;;>3t!ipic ID! S.jii!pl'? Dale; Sampled By: At Lab Date!

103A'iO EAtUH TECHNOLOGY CORPORATION STAPLING MACHINE SMC-MU-3-2 06/23/9? CUSTOMER 06/23/S9

.PARAMETER TESTED RESULT DUPLICATE SPIKE

RECOVERY X

pH (units) 6.42

<- Less than >= Grea t f? r t h a n

INDUSTRIAL CORROSION MANAGEMENT, I n c , R i c h a r d L e v i n e , P r e s i d e n t

C o p y r i g h t ICM, I n c , TS

1986 . A l l r i g h t s r e s e r v e d ,

PAGE * 63

5

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Randolph, NJ 07869 NJ DEP Certified Drinking Uater . 201-••}:? 4-0330 Laboratory ID* 14116 • ' • ' " M ^ ! ^ AUGUST ] , 1989 US EPA Contract Laboratory ' ;it^

LAPOKATORr ANALYSIS — '.'OLATILE POLLUTANTS Note: Oich lo ro benz ene'i- analv:jed as semi-vo lati les.

GC/r»3 '.'0LATILE3 - TIER II OELIVERASLES

LvJb Number: 103441 Clt.:-.Tt; EARTH TECHNOLOGY CORPOPAT-'GN Sair.Dle source: STAPLIW(5 MACHINE 3::i:i:pli7 ID: SMC-«'J-4-2 Siample date: 06/23/89 Sampl.id by: CUSTOMER At lab date: 06/23/89 M.atrix; UATER

Min imum Method Detection

Parjm>?>.er Result Slank Limit ug/1 ug/1 ug/1

Chloromethane U U BrcT.c:nethane U U

5 Vinyl Chloride U U 5 Chloroethane U U Methylene Chloride U U 1 , l-Oi.::hlo roethy lene U U 1,1-Dichloroethane U U

5 5 5

total-1,2-Oichloroethene U U 5 5 5 5

Chloroform U U 1,2-0ichloroethare U U 1,1,1-Trichloroethane U U Carboi Tetrachloride U U 5 Bromodichloromethane U U 5 i 1 ,2-Oich lo ropropane U U 5 |J t-1 ,3-0 ich loro pro pene U U 5 .|-Trichloroethylene U U 5 ^ D ibromochloromethane U U 5 i / • . 1,1,2-Trichloroethane U U 5 Benz€?ne U U 5 c-1,3-Oichloropropene U U 5 2-ChloroethyIviny1 Ether U U 5 Bromoform U U 5 Tetrachloroethylene U U 5 1,1,2,2-Tetrachloroethane U U 5 Toluene U U 5 Chlorobenzene U LJ 5 Ethylbenzene U U 5 Total Xylenes U U 5

ug/1 " microsrams/liter or ppb

U: Indicates a compound uas analyzed for but not detected. J: Indicates an estimated value. It is utilized when a reported v-iluc

meets the identification criteria but the result is less than the specified detection limit but greater than zero.

B: Indicates that the analyte uas found in the blank as uell as the sample, .sl't. indicates possible/probable blank contamination.

''tB:.y ••;»••:

Copyright l C H , l i i . n c . , 1986. All rights reserved

»

PAGE • 64 o o

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li' a t e> >U a%ffiâ;^]

LAEORAT^r-RY ANALYSIS-GC/MS BA-SE/NEUTRALS -

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103441 EARTH TECHNOLOGY CORPORATION STAFLIrIG MACHINE SMC-MU-4-2 0.*/23/'3? CUSTOMER 0.^/23/3? UATER

W>

Acenaphthene Acen-ajihthy lene Anthracene Benzidine Benzo(a)anthracene Benzo( i> pyrene Benzo<b)fluoranthcn2-Benz 0 < gh i > perylene Benzo(k)fluoranthene 8 i i ( 2~ <: h 10 r 0 e t hy 0 xy ) me t h a n e B i s ( 2 - ch 10 r 0 e t hy 1) e t h e r 8 i s ( 2 - c h l o r o i s o p r o p y 1 ) e t h e r B i s ( 2 - e t h y l h e x y l ) p h t h a l a t e 4-BrorD0?heny 1 p h e n y l e t h e r B u t y l b e n z y l p h t h a l a t e 2 - C h l o r o n a p h t h a l e n e 4 - C h l o r o p h e n y 1 pheny l e t h e r C h r y s « n e Dib.enz<a,h)anthracene 1 ,2-Di':hlorobenzene 1,3-Dichlorobenzene 1,4-Oichlorobenzene 3,3-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate Oi-n-butyl phthalate 2,4-Dinitrotoluene 2,6-Oinitrotoluene Di-n-octyl phthalate 1,2-DiphonyIhydrazine Flîo rarthene FlJO rene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene, Isophorone Naphthalene ..i .,., -^yriiSî' ' Nitrob»?nze. i ie •,IJCM?:f\ . m-N - N i t r 0 so d ime.tl1ly4iamine^.^-^'Ît N - N i t r 0 so d i - n-R.roIp'yiami ne-s P ' N - N i t r 0 so d iphenyj'lamine.'^''^^*',» Phc.13 nthrene i'-* Mg^<^y' f-^'-t'''^'' . Pyrene 'Z »-^'4'î'>f:~>^'^s^- 1 , 2 , 4 - T r i c h l o r ' b b e n z"en'et; - •» y

Result u g / 1

U U U U U U U U U U U U U U U U U U U U U U U U U U u u u u u u u u u u u u u u u u u u u u

M e t h o d Slank u g / 1

u U U U U U U U U U U U U U U U u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u

M i n i m u m D e t e c t i o n L i m i t u g / 1

5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5

• " . »

O-'

o

00

U9/1 micrograms/liter or ppb

U: Indicates a compound uas analyzed for but not detected. ^___i J: Indicates an estimated value. It is utilized uhen a reported value

meets the identification criteria but the result is less than the spt»cified detection limit but greater than zero. . •• '

B: Indicates that the analyte uas found in the.blank as uell as the sample.

j /

C o p y r i g h t TS

ICM, I n c . , 1986 . A l l r i g h t s r e s e r v e d ,

.1 m

PAGE t 67

I t ?

X i J i r 0 t t ' : e i •-'

Pando I p h . NJ 07869 2 0 1 - : i 3 A ~ 0 3 3 0 7 ' 1 9 / 8 9

NJ DEP C e r t i f i e d D r i n k i n g U a t e r / U a s t p u a t , t 3 Li ibo r.3to ry I D * 1411.s / - f i l

LIBRARY SEARCH RESULTS OF NONTARGETED PEAKS U I I H ESTIMATED CONCENTf'ATIGN OF Tt.NTATl'.'ELY I DENTIFI tO COhPUUNUS

D a t y f i l e n a m e : L :•:'.•) .n.'irnber; F r a c t i o n :

>C3831 1034-11 Ba!ie./Neu t r a l

b c a r K';i;t:bi?r

'349

CAS No Rete-n t ion

Time Compo u nd h'-.aiDe

2 8 . i: Unk nown

Mo lecuIar U e i g h t

Est imated C 0 n c e n t r a t i 'J n

u g / 1

77 B

A: Indicates that the compound is an acetone based aldol-type condensation produi:t formed by concentrating the extraction solvent (1:1 acetone/methylene chloride).

3: Indicates that the analyte tjas found in the blank as well as the sample. It. furthsr indicate'.* possible/probable blank contamination,

Copyright ICM, Inc., 1996. All rights reserved.

• '•.?•*•« i,''

• • ' •• i i ' j ih^/yAy' . -Ty, .,•;•"

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TOTAL ION CHROnATOSRAn F i l « >C3ddl 39.a-5ee.a M U . INST 59703,SAtlPLE I5544l f f7SCl5 l27r331

TIC 4ee

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48eaa»

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1608 J_ >L

I • I ' I ' I • I ' 18 12 14

' I ' I • I ' 16 10

I ' l * 28 22

Data F i l e : > C 3 8 8 1 : : C 1 Name: INST 59703,SAMPLE M i s c : 1 0 3 4 4 1 B , Q C 1 2 1 2 , L , 9 8 0 , I , 3 0 M SPB- f CAP COLUMN

I d F i l e : ABNC::SC Title: CLP BNA IDFILE Last Calibration: 890712 17:56

Quant Q i j t p u t F i l e : ^ C 3 8 8 1 : : Q T

BTL#13

Operator ID: MB1874 Quant Times 890713 01:55 Injected at: 890713 01:11

TIC page 1 of 2

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6 9 00

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m

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TOTAL ION CMROnHTOSRAfl F i l * >C36ai 39 .8 -588 .a M U . INST 89783,SAIIFLE 13344157^151171755?

1888880:

988888^

888880:

7888e»

eaoaao:

588880^

48888^

388889:

288880:

188880^

20.00 , • - • • -- ' - '

TIC 24.88 2880 3288

J9

J • I ' I ' I ' J ' I ' I ' I ' I ' I ' I ' I ' J ' I ' I ' I • I ' I ' r' 22 24 26 28 38 32 34 36 38 48

m.

Data File: >C3881::C1 Name: INST 59703,SAMPLE Misc: 103441B,QC1212,L,980,1,30M SPB-5 CAP COLUMN

Id File: ABNC::SC Title: CLP BNA IDFILE Last Calibration; 890712 17:56

Quant Output File: ^03881::QT

BTL#13

•' M • ? ^ ^

Operator ID: MB1874 Quant Time: 890713 01:59 Injected at: 890713 OtMl

TIC page 2 of 2

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- ' • \ • - — • • ' ' * > 1 • • • I I I I I i ' l ' I • • ' ! • — ' ' . ' • • T • — ' 1 ' ' • 1 • ' ' I ' • • ' I I ' • '. ' I M • ' . 1 " ' 1 ' ' ' I."' ' r ' ' 1C3 ISO

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£ 9 0

9 9 116 1 4 5 l.- ' l?2e9 2 2 3

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C H S C O S 3 C 8 3 e «

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1. lH-Pyrrole-2>5-dionc, I-£4-(2-benzoxasoly1iphenylJ-tyci)

2. Pndrosterone (801)

230 C1VH10N203

2y0 C1'^H3U02

Sarriplc f i l e : >P3aa i > , S p e c t r a r n • : S e a r c h spaed'M^:;lS^%.v-'f".^M!t'ing o p t i o n : N

-• • :'f.r:?fe?¥:«w'feHi':^.'.54::% Prob . J | 2$ i l ^Sg i&^ ' JebN t

• y i m y > ^ ? > y ^ ^ : . . ' ^ ' • ' • • • ^ m m B f i ^ - P ^ - y.. - • - -

1 . ^ 2 0 * JU65^tiC?M8;..>3S974 53418 3 2 3 t 2

ROOT

2349 No. oi- i o n r a n g e s s e a r c h e d : 4'.,

"BIGDB 23 •'Bir.-JB 1-4

DK IFLG TIi.T tl CON r.-_I « _ !

68 SS

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KdndolF!--. NJ 078.69 NJ DEP Cert i f i e J Drink in>3 Ua t er/Uostef i^^l ;:':i-5;i'1--0330 L a b o r a t o r y ID# 14J. Is '¥<^4 Ai.iGUST 1, 1989 US EPA Contra;:t Laboratory 'vsj ij

' "•";??#•-

LAEORATORY AKftLYSIS-PETRGLEUM HYDRDCAReONS "§1

Client: EARTH TECHNOLOGY CORPORATION S-ainpl.? •:curc:e.' STAPLING MACHINE Samp liny Date: 06/23/89 SjinplC'i by: CUSTOMER At Lai) t^te: 06/23/89

MINIMUM LA8 DUPL. DETECTION METHOD SPIKE NO. ID. RESULT RESULT RPD LIMIT BLANK RECO'VER

';U3t«>r matrix) m- /1 mg/l mg/l X

1C34'11 SMC-!«U-4-2 U 0.99 U

U== Not detected NC= N':i n-calcu lable RPO due to valueCs) less than the detection limit

INDUSTRIAL CORROSION MANAGEMENT,•Inc, Richard Levine, President f

Copyright ICM, Inc., 1986. All ri'Shts reserved. TS

yisa^-.ai •'-. -,A?*fei,-.

• - ' ^ [ y . : " ^ y ^ y ^ i ^ /

y^ylh'ry^^^-'."^ ''l

PAGE #72 3 1

i

^ j

*• i

i" ' ' Randolph 11.•52 R-3:ite 1'3

NJ 07869 201-?i:-3'1-0330 AUOUST 1, 1989

• • ' ^ m ^ ' i NJ DEP Certified Drinking Uater/Uasteilia'ee*! Laboratory rO# 14116 "^-y^""'' US EPA Contract Laboratory

LABORATORY ANALYSIS Al] results are reported in my/1 <ppm) unless otheruiise stated.

L:ib N'lffiil'C-T ; C l i e n t : Sjinpl*? So'Jree: Samp 1e ID; Samp I*? Date: Sampled By: At Lab Date:

103441 EARTH TECHNOLOGY CORPORATION STAPLING MACHINE SHC-MU-4-2 06/23/89 CUSTOMER 06/23/89

*. PARAMETER TESTED RESULT DUPLICATE SPIKE

RECOVERY

pH (units) 7.3;

4

•~ L e a s t h a n ' = G r e a t e r t h a n

I N D U S T R I A L CORROSION MANAGEMENT ,^Vi;n:^ff:f-R i c h a r d L e v i n e , P r e s i d e n t " ' ' ' ' " ' • - y ^ ' ^

C o p y r i g h t ICM, I n c , TS

1 9 8 6 . A l l r i g h t s r e s e r v e d .

it y s . y

PAGE 0 7 3

5

1 „-o.-

-- -.- -- '•'•y^^SW Randolph, NJ 07869 NJ DEP Certified Orinl<ing Uater/UasteiJa;t'er ;:01-'J.^M-0330 Lafcor-atory ID# 14116 =-,<?£§! AUGUST 1, 1989 US EPA Contract Laboratory - ;%?2

LABORArnftr ANALYSIS—VOLATILE POLLUTANTS i Note: Dich 1 0 robi?nz enes analyzed as sem i-vo 1 at i le'i .

C-C/M3 VOLATILES - TIER II DELIVERABLES

L;.>b Number: " 103442 C l i e n t : EARTH TECHK'OLOGY CORPCRATrON S;?iTip]e r.ource; STAPLING MACHINE S jinp 1 e ID: E.îC-hU-.5-2 Snîple d a t e : 06/23/89 S.!ii,pl.;"i by: CUSTOMER At lab date: 06/23/89 .'i.dtrix: UATER

Min imum Method Detection

Param»?t«:'r Result Slank Limit ug/1 ug/1 ug/1

Chloromethane U U 5 Bron;oin«?thane U U 5 Vinyl Chloride U U 5 Chloroethane U U b Methylene Chloride U U 5 1 , l-Dichloroethylene U U 5 1 ,1-Dichloroethane U U 5 total--l ,2-Dichloroethene U U 5 Chloroform U U 5 1 ,2-D ii:h lo roethane , U U 5 1,1,1-Trichloroethane U U ;3rbon Tetrachloride U U 5 Bromodichloromethane U U 5 l,2-Di<:hloroprcp3ne U U 5 t-1,3-Dichloropropene U - U 5 Trichloroethylene U U 5 Dibromochloromethane U U 5 i,1,2-Trichloroethane U U 5 Benzene U U 5 c-1,3-0ichloroprapene U U 5 2-ChloroethyIvinyl Ether U U 5 Bromoform U U 5 Tetrachloroethylene U U 5 1 , 1 ,2,2-Tetrachloroeth3ne U U 5 Toluene U U 5 Chlorobenzene U U 5 Ethylbenzene U U 5 Total .Xylenes U U 5

ug/1 - micrograms/liter or ppb

U; Indicates a compound uas analyzed for but not detected. J: Indicates an estimated value. It is utilized when a reported value

neets the identification criteria but the result is less than the sp<?cified detection limit but greater than zero,

6: Indicates that the analyte was found in the blank as uell as the sample. It,., indicates possible/probable blank contamination.

Copyright ICM, Inc., •1986. All rights reserved, TO • ! • : • -

o o M

PAGE * 74 1

T.ITCL ION :HRQMaTQi5(iCiri r i l e >ftOS3? ' • 5 . 0 - 2 ( > 0 . 0 » i j i . VQO ON l i , Si i r lPLE 1 0 3 4 4 2 . a V 0 6 7 2 . 5 . L

T I C 100 200 ?C0 400 500

' I . . . . 1 . . . 1 . . . . 1 . . . . I . . . . I .

i4000(>-

12000CH

'10000'>

oCCOO"

bOuOO-

40000-1

•t'ffftl^^.f^yM

-•; y . ) i

D a t a F i l e ' > G 0 8 2 5 « « G 1 Q u a n t O u t p u t F i l e * * G 0 8 2 5 ! ! Q T Names UOA ON G, SAMPLE M i s c « 1 0 5 4 4 2 , Q V 0 6 7 2 , 5 , L , 6'X2mrr. IX SP 1 0 0 0 ON CARBOPKB

I d F i l e ! GyOALs sSC T i t l e ' GENERAL I D F I L E FOR INSTRUMENT G L a s t C a l i b r a t i o n ' 8 9 0 6 2 8 0 8 > 5 0

O p e r a t o r I D ' SP5680 Q u a n t T i m e ' 8 9 0 6 2 8 1 0 « 5 7 I n j e c t e d a t < 8 9 0 6 2 8 1 0 ( 1 6

T I C p a g e 1 o f 2

59

o o

75 VD VJ1

5'fj

TOTAL ION CHROMOTOGROM F i l « f-0325 ?5.0-2<J0.

1 i

500 bOO 1 , . . . , . . . . 1 .

1 1

1 J

i 1 ; i- ' :-:- j '>i 2 1

1 1 1 •• ; r i i - i l1 i -»-

L'

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i ] 1 • - • ' - - • V - • '

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i ^ 1

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i II II « n II )i I 1 1 1

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1 . 1 . .

' I ' l £3

800

u u

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11 \

_ • d n » « « . « J ^ * _ ^ , - . ^

' 1 ' 1 ' 1 • 1

30 32

103442 , dvO^T-S. S. L

?00 1000 . 1 . . . . * \ .

, • 1 • 1 • 1 • 1 • 1 ' 1 • 1

34 i i 33 40

Data F i l e s >G0825««G1 Quant O u t p u t F i l e ' * G 0 8 2 5 ! ' Q T Name' UOA ON G, SAMPLE M i s c 1 0 3 4 4 2 , QU0672, 5 , L, 6'X2mm IX SP 1000 ON CARBOPKB 0-Id File' GUOALs'SC litle' GENERAL IDFILE FOR INSTRÛMENT G Last Calibration' 890628 08'50*

Operator I0« SP5680 Uuant Time' 890628 10'57 Injected at' 890628 10*16

IC page 2 o f 2

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7 6

115? Route 1'3 Rando Iph , NJ 0736? 2.-. 1 -•=,; .1 -03 30 AUOUSf 1 , 1989

N.J DEP Certified Drin!<ing Laboratory ID# 14116 US EPA Contract Laboratory

LAEC'!?A7GRY Al^ÂLYSIS-GC/HS e.'^.Se/NEUTRALS -

•-PRIGRITY POLLUTANT BASE/NEUTRALS TIER II DELIVERABLES PLUS 15 PEAKS

U a t e r / U a s t;eua:'%e;tJ

-yy?

• : , .%?:

ijk^

L.îb N'.;rr;ber : C I : i e n t : 3;.--.I-;-•!»? ' - o a r c e : S: . . i ; ip le I D : •Sir:i;f>l>? ' J a t e : Si imp l e d by : A t l a b d 2 t e ! M a t r i x :

103442 EARTH TECHNOLOGI' STAPLING MACHINE SMC-MIJ-5-2 06/23/39 CUSTOMER 0 6 / 2 3 / 3 9 UATER

CORPORATION

P3r-3w.f.;*er Re- i iu l t u g / 1

A.r en aph t h e n e U Aoi'Tâph t h y 1 t r i e U A n t h r a c e n e U B e .1;: i d i r! e U B e n z o ( a ) a n t h r a c e n e U S e n ^ 0 ( i ) p y r e n e U B e n z o ( b > f l u o r a n t h e n e U 9 e n z 0 < j h i > p e r y l e n e U B<£>iTi 0 ( k ) f l u o r a n t h e n e U B i i i < 2 - ( : h l o r o e t h y 0 xy) methane U Bir i< 2 - c h l o r o e t h y 1) e t h e r U S i i , ( 2 - f : h l o r 0 i i ' . t p r o p y l ) e t h e r U B i s < 2 - e t h y l h e x y l ) p h t h a l a t e U 1 -S ro :eopheny 1 p h e n y l et.her U B u t y l b e n z y l p h t h a l a t e U 2 - C h l o r o n a p h t h a l e n e U " ^ - C h l o r o p h e n y l p h e n y l e t h e r U ChrysGrna U D i b e n z ( a , h ) a n t h r a c e n e U 1 , 2 - D i c h l o r o b e n z e n e U 1 . 3 - D i c h l o r o b S ' n z e n e U 1 . 4 - 0 i i : h l o r obenzene U 3 , 3 - D i c h l o r o b e n z i d i n e U O i . ? t h y l p h t h a l a t e U O in / / ? t hy l p h t h a l a t e U D i - n - b u t y l p h t h a l a t e U 2 , - 4 - D i n i t r o t o l u e n e U 2 , 6 - O i n i t r o t o l i i e n e U D i - n - o c t y l p h t h a l a t e U 1 . 2 - O i p h e n y I h y d r a z i n e U F l u o r a n t h e n e U F l x o r t i n f i U H e x a c h l o r o b e n z e n e U H e x a c h l o r o b u t a d i e n e U H e x a c h l o r o c y c l o p e n t a d i e n e U H e x . a c h l o r o e t h a n e U I n d e n o < 1 , 2 , 3 - c d ) p y r e n e U I s o p h o r o n e U N a p h t h a l e n e U N i t r o b e . i z e n e . -.^ , U N - N i t r o s o d i m e t h y l a m i ' n e U N - N i t r o s o d i - n - p r . o ? y , l a i n i n 8 U N - N i t r o s o d i p h e n y ' l a m i n © U Phen.-anthrfene v f * , ( - . ^ U P y r e n e — v-t^C"-.4^' - -' , U 1 , 2 , ' 4 - T r i c h l o r o b e n z e n e - U

•d-^/l - m i c r c s r a m s / l i t e r o r ppb

U: I n d i c a t e s a compound uas a n a l y z e d f o r J : I ' u l i c a t e s an e s t i m a t e d v a l u e . I t i s u

Method Blank u g / 1

U U U U U U U U U U U U U U U U u u u U u u u u u U u U u u u U u u u u u u u u u u u u u u

b u t n o t d e t t i l i z e d uhen

Min imum D e t e c t i o n L i m i t u g / 1

5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5

e c t e d .

' t . 1 ^

'€••

S-

a r e p o r t e d v a l u e

RWY

1 o i 2- !

^ !

i • meets the identification criteria but the result is less than __ . the -ipecified detection limit but greater than zero. Indicates that the analyte uas found in the blank as uell as the sample.

Copyright TS

ICM, Inc., 1986, All rights reserved.

PAGE # 77

... i - - r. y u L e I '-' PcMtfJo ] ph . NJ 07869 2'"1 - ' v34 - : ' 330 7 / 1 9 / 8 9

;. ^•i^<^C?.5s'^:.,'",,-,

MJ DEP Certified Drinking Uater/Uaste<^ât'y Laboratory lOt 14116 <yn

•yi^y

LIBRARY SEARCH RESULTS OF NOWTARGETED PEAKS UITH ESTIMATED CGNCENTRATION OF TENTATIVELY IDENTIFIED CUMPOUNL»S,

D;rt;i f i l e n a m e : i.. .30 n^trnbcr; F r a c t i o n :

>C3882 1 0 3 4 4 2 Ba l i e / N e u t r a l

S c a n • u ;r! b >2 r CAS No

2357

R e t e n t i o n T i m e

Compo und N.3me

28.09 Unk no un

MolecuIar Ueight

Est imated Concentration

ug/1

120 B

A: I n d i c a t e s t h a t t h e c o m p o u n d i s an a c e t o n e b a s e d a l d o l - t y p e c o n d e n s a t i o n p r o d u c t f o r m e d by co n c e n t r a t i : :g t h e e x t r a c t i o n s o l v e n t ( 1 : 1 a c e t o n e / m e t h y l e n e c h l o r i d e ) .

B: I r ^ l i c a t e s t h a t t h e a n a l y t e was f o u n d i n t h e b l a n k a s u e l l a s t h e s a m p l e , I t . f u r t h e r i n d i c a t e s p o s s i b l e / p r o b a b l e b l a n k c o n t a m i n a t i o n .

C o p y r i g h t ICM, I n c . , 1 9 8 6 , A l l r i g h t s r e s e r v e d .

^

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vo 00

78

TOTWI. ION CHROflBTOeRWn __ F i l a >C3e8£ 3 5 . 8 - 9 6 8 . 6 u u . IMST 59793,Sf inPLE 1834428 ,001212 ,L ,98<

780888-

fiseeee'

680888-

558880-

580880-

450000-

400000-

380000-

3O000»

250000-

200000'

190009-

100000-

50000-

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Id File: ABNC::SC Title: CLP BNA IDFILE Last Calibration: 890712 17:56

Quant Output File: ^C3882::QT

BTL*14

Operator ID: MB1874 Quant Time: 890713 02:48 Injected at: 690713 02:04

TIC page 1 of 2

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TOTAL ION CHROnnTOORnn Til. >C3882

7eo0e»'

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688800-

558000-

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Sample file: >C38'i'2 Spectrum •: Search speed: 1- - . Til-tinq option: N

•-. ;iv-•5%^.'' •-•'' • ' - - y y • •:-

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1 1 3 2 R o u t . 3 l O ' "'ÎC^jVisf.' F i u i J o l p h , NJ 0 7 3 6 9 NJ DEP C e r t i f i ( ? d D r i n k i n g U a t e r / U a s t e u d . t e i : 201-'^3A-0330 L 3 b o ^ a t ( ) r ^ y I D * 1 4 1 1 6 r-iUGUsiir 1 , 1 9 8 9 US EPA Con t r. i c t L a b o r a t o r y

I.APQRrtTORY ANALYSIS-PETROLEUM HYOPOCARBQNS

C l i r n t ! EARTH TECHNOLOGY CORPORATION' S::urpl'.y Sour- ' -*?; .STAPLING MACHINE .5r:iiriplin<.:: D a t e ; 0< :^ /23 /89 S.?>;i:pls?tJ b y : CUSTOMER A t L a b D a t e ; 0 6 / 2 3 / 8 9

MINIMUM LA.S DUPL. DETECTION METHOD SP IKE NO. I D . RESULT RESULT RPD L I M I T BLANK RECOVERY

(W3 t (? r r n s t r i x ) m g / l m g / l m g / l %

1 Q 3 A A 2 S M C - M U - 5 - 2 U 0 . 3 9 U

U:= Not i i f i t e c t e d K'C- No n-calcu Isblc RPD due to V3lue'(s) less than the detection limit,

INCUSTi?IAL CORROSION MANAGEMENT, Inc, Richard Levine, President £•

C'.-,':?yr isht ICM, Ire,, 19SA. All rights reserved, TS

PAGE * 82

o

.. .. .i <. r . J u '- t? J. 'w'

F d n d o l F h . NJ 078A9 2 0 1 - ; ; ; J ' 1 - J 3 . 3 0 AUGUST 1 , 1989

NJ DEP C e r t i f i e d D r i n k i n g U a t e r / U a 5t eua't'e.; L ; 2 b o r a t o r y I D * 1411.6 ' ^ ^ ' US EPA C o n t r a c t L a b o r a t o r y p*;;

LABORATORY ANALYSIS A I ] r e s u l t s a r e rci--o r t c d i n m g / l (ppm) u n l e s s o t h e r w i s e s t a t e d .

L.v;b N'Jniter! C l i e n t : S.-y.nplo S o u r c e : S;3niple I D : Sani!:jl»? D a t e : Samp led Ey: A(. Lab O a t c !

103442 EARTH TECHNOLOGY CORPORATION STAPLING MACHINE SMC-MU-5-2 0 6 / 2 3 / 3 9 CUSTOMER 0 6 / 2 3 / 8 9

PARAMETER TESTED

pH (units)

•= Les^ than " G r e 3 t e r thiin

RESULT DUPLICATE SPIKE

RECO'.;ERY X

6.&1

INDUSTRIAL CORROSION MANAGEMENT, Inc, Richard Levine, President

Capyriijht ICM, Inc., 19S4. All rights reserved, TS

PAGE * 83

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Randolph, N i 07969 201-:v3 4—:'3 30 AUGUST ] . 1939

NJ DEP Certified Drinking Uater/Uastruatt Laboratory ID* 1411A -US EPA Contract Laboratory

LAeOPATQRY ANALYSI3--V0LATTLE POLLUTANTS Note; Dichlo robenz enes an3lY.ied as 'j.emi-vo lat i les .

L-C/M3 '.'0LATILE3 - TIER II DELIVERABLES

L i.>l> Number : C I i -3 -i * : Sa.rip ] G so ij r c e ; S - J ) l : p l > 7 I D ; S a Triple d a t e : c a in ;:> I'? d b y : At lab date: d 3 t r i X !

1034^3 EARTH TECHNOLOGY STAPLING MACHINE SMC-FS-2 06/23/89 CUSTOMER 06/23/89 UATER

COrPORAriCN

P a r . a m a t e r Re?<>ult u g / 1

Method Slank ug/1

Minimum Detectio n Limit ug/1

h lo r ." 0 m w-iny 1 hlo r ethy ,1-0 ,1-D ctal h 1 o r .2-0 , 1 .. 1 arbo r 0 mo .2-0 -1 ,3 rich ibr 0 1 ''

enz c -1,3 -Chl romo etra .1.2 clue h lo r thyl otal

0 metha jnethan Chlor

0 G t l a n lene C i c /T 10 r i c h 10 r -1,2-0 0 f 0 rifi i': h 10 r - T r i c: h r. T o t r d i c h 10 i c h 10 r - D i c h 1 1 0 r 0 e t mo chlo - T r i c h ne - 0 i c h 1 0 r0 eth f o r m c h l o r o ... 1 c; %.

ne c b e n z e benz en Xy len

ne e ide e h 10 r i d e oethylene 0 e t h a n e i c h l o r o e l h e n e

0 e t !•( 3 n e loro ethane •jchlori-de romethane opropane 0 ropropene hylene romethane loroethane

0 ropropene ylvinyl Ether

ethylene rachlo roethane

ne e es

U U U U U U U U U U u u u u u u u u u u u u u u u u u u

u g / 1 " m i c r o g r i i T s / l i t e r or ppb

U U U U U U U U U U U u u u u u u u u u u u u u u u u u

5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5

U t

a compound u a s a n a l y z e d f o r b u t n o t d e t e c t e d , n e s t i m a t e d v a l u e . I t i s u t i l i z e d uhen a r e p o r t e d v a l u e

Indicates Indicates an e&iimaiea vaxue. i x I'S uiixizea unen a reporiea meets the identification criteria but the result is less than

as the

niF.-tTL:? Liiif A U i f n L . i i j i . d L J . u i i u i J L f c - i J d u u L \ . n a r e ^ u j i J 5 j e s s i r t h e 'Specified d e t e c t i o n l i m i t b u t g r e a t e r t h a n z e r o . I n d i c a t e s t h a t t h e a n a l y t e u a s f o u n d in t h e b l a n k a s u e l l ; s a m p l e . It i n d i c a t e s p o s s i b l e / p r o b a b l e b l a n k c o n t a m i n a t i o n ,

Copyright ICM, Inc., 1986. All rights reserved, TC

55

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PAGE * 84

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TOTOL t r iN CHPnMOTf,i;?Qn r , \ . r . n s i O !"•. . O - i ' ^ O . 0 i o u . V0i3 l lN S . S O n f L r 1 0 ' S 4 4 3 . .1V0672 . ? , <:

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D a t a Files >G0810'«G1 Qudr.t Output F i l e ' *G0810ssQT Names UOA ON G, SftMPLE M i s c 1 0 5 4 4 3 , Q 0 0 6 7 2 . 5, S, 6->.Zmfr. IV. p lOOO ON CftRBOPKB

Id riles GUOftLs sSC Tit l e s GtHERftL IDFILE FOR INSTRUHENT G Last Calibrations 8 9 0 6 2 7 13«22

O p e r a t o r ID» SP5680 G u a n t T i m e * 890627 16'25 In j s c t e d at» 890627 15s41

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O p e r a t o r I D s S P 5 6 8 0 I j u a n t T i m e s 8 9 0 6 2 7 168 25 I n j e c t e d a t « 8 9 0 6 2 7 16i»41


- » ' ..---^:;

' ^ ^ y ^ : ^ y .':'

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R a n d o l p h , NJ 07869 NJ DEP C e r t i f i e d D r i n k i n g Uater/UWst%îiiijt*€ 201- : i3 '1 -0330 L a b o r a t o r y 10* 14116 -".; *^?>a AUGUST 1 . 1989 US EPA C o n t r a c t L a b o r a t o r y ' ' "^^

LASOPATriRY A N A L Y S I S — P R I O R I T Y POLLUTANT KASE/NEUTPALS '-'.': GC/M? BA.'SE/NEUTRALS - T I E R I I DELIVERABLES PLUS 15 PEAKS

Lab N;ic!ber: 103443 Client! • EARTH TECHNOLOGY CORPORATION SD;'.i:>le source: STAPLING MACHINE Sirnii 'le ID; SMC-FB-2 Gain?. I,? date; 06/23/89 Sampled by: CUSTOMER At Lib 'iate; 06/23/39 Matrix: UATER

P-ar ameter ResuIt ug/1

U U U U U U U U U U U U U U U U U U U U U U U U U U U u u u u u u u u u u u u u u u u u u u

Method Blank ug/1

U U U U U U U U U U U U U U U U U U U u u u u u u u u u u u u u u u u u u u u u u u u u u u

Minimum Detection Limit ug/1

5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5

Acenaphthene Acenaphthylene Anthracene Benz idine B e n z o ( a ) a n t h r a c e n e B e n . : o ( a > p y r e n o B e n ; o ( b ) f l u o r a n t h e n e Be:TZ 3 ( sh i ) p e r y l e n e B e n z o < k ) f l u o r a n t h e n e B i i ' ' 2-(:h lo r 0 e t h y 0 xy ) i i e t h a n e B i s ( 2 - c h l o r o e t h y l ) e t h e r B i i > ( 2 ~ i : h l o r o i s c p r 3 p y l ) e t h e r B i 5 ( 2 - e t h y l h e x y l ) p h t h a l a t e 4 - 3 r o re o p h e n y l p h e n y l e t h e r B u t y l b e n z y l p h t h a l a t e 2 - C h l o r-3 n .aphtha l e n e 4- (Jh lo ro p h e n y l pheny l e t h e r C h r y s e n o Dibenz(3,h)anthracene 1 ,2-Oic,'iiorobenzene 1,3-Dichlorobenzene 1,4-Oichlorcbenzene 3,3-Dichlorobenzidine Oiothyl phthalate Dimethyl phthalate Di-n-butyl phthalate 2,'4-Oinitrotoluene 2,6-Dinitrotoluene Di-n-octyl phthalate 1,2-0iphenylhydra2ine Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene U U 5 ^ Hexachloroethane ~ Indeno(l,2,3-cd)pyrene Isopho rone N a p h t h a l e n e U U 5 ^ N i t r o b e n z e n e U U 5 o N - N i t r o s o d i m e t h y l a m i n e N-Ni t r o ' i o d i - n - p r o p ' y l a a i i n e N-Ni t r o sod iphenylvaminer. U U 5 ^ Fhe.'Ian t h r o n e •yi. ;'*-' • .• - U U 5 oi P y r e n e i , r " v ' U U 5 o 1 , 2 , 4 - T r i ch lo - rdbenzene» - U U 5 -J

._.„__ _ inTcf r^ i^ rams/ l i t e r or~p^"b

U: I n d i c a t e s a compound u a s a n a l y z e d f o r b u t no t d e t e c t e d . J ; I n d i c a t e s an e s t i n a t e d v a l u e . I t i s u t i l i z e d when a r e p o r t e d v a l u e

m e e t s t h e i d e n t i f i c a t i o n c r i t e r i a b u t t h e r e s u l t i s l e s s t h a n t h e - i p t j c i f i e d d e t e c t i o n l i m i t b u t g r e a t e r t h a n z e r o .

B: I n d i c a t e ' . ^ t h a t t h e a n a l y t e u a s f o u n d in t h e b l a n k a s u e l l a s t h e sample

C o p y r i g h t ICM, I n c . , 1986 . A l l r i g h t s r e s e r v e d . TS

PAGE * 87

1

. - • . - . • . , , n .1.1-11- ^ _ w . ' n i , ' ^ . ' J . i . ' i* ( u - i i v t - j i j ' : . n i r . f V I y i T>C . '^M$yM

l l ' ! ; 2 R o u t e 10 'SgUi| R a n d o l p h , NJ 0 7 8 6 9 NJ DEP C e r t i f i e d D r i n k i n g U a t e r / U a s t e u S t i | > 2 0 1 - r : ' 3 4 - 0 3 3 0 L a b o r a t o r y I D * 14116 y'' ' 7 / 1 9 / 8 9 i ^

• LIBRARY SEARCH RESULTS OF NONTARGETED PEAKS U I T H ESTIMATED CONCENTRATION OF TENTAT IVELY I D t : W T I F I E D COMPOUNDS.

D a t a f i l e name: >C3883 L a b Ti'^rBber; 1 0 3 4 4 3 F r a c t i o n : Ba !ie./N eu t r a 1

3 c i ? r R e t e n t i o n Compound M o l e c u l a r E s t i m a t e d N u m b e r CAS No, T ime Name U e i g h t C o n c e n t r a t i o n

u g / 1

>357 2 8 . 0 8 U n k n o u n 5 7 B

A: I n d i c a t e s t h a t t h e c o m p o u n d i s an a c e t o n e b a s e d a l d o l - t y p e c o n d e n s a t i o n p r o d u c t f o r m e d by c o n c e n t r a t i n g t h e e x t r a c t i o n s o l v e n t ( 1 : 1 a c e t o n e / m e t h y l e n e c h l o r i d e ) ,

B; I n d i c a t e - 3 t h a t t h e a n a l y t e was f o u n d i n t h e b l a n k a s u e l l a s t h e s a m p l e , I t , f u r t h e r i n d i c a t e s p o s s i b l e / p r o b a b l e b l a n k c o n t a m i n a t i o n .

i

Copyri'jht ICM, Inc., 1996. All rights reserved.

O O

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88 S

TOTAL ION CHROnATOGRRn n i * >c3ee3 39.a-5ee.a M U . INST 59793,snnPLE i A U 4 i b . { i t i i i i , L , i 7 i

70eee9-

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1680

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Quant O u t p u t F i l e : ^C3883:sQT

8TL#15

Data File: >C3883::C1 Name: INST 59703,SAMPLE Misc: 103443B,QC1212,L,970,1,30M SPB-5 CAP COLUMN


Operator ID: M61874 Quant Time: 990713 03:41 Injected at: 890713 02:57

TIC page 1 of 2

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TOTAL ION CHROMATOeRRn Fil* >C3ee3 35.e-5ee.e M U . INST s^res.snnPLC 1034438,001212,L,97(

TIC 2098" 2488 28,88 3288

780088-

600808-

588088-

488888-

308888-

208888-

188888-

22 24 26 1 ' I ' 1 ' I ' I • I ' I ' I '

38 32 34 36 •! ' 1 ' T ' 1 '• I

38 48

Quant Output File: ^C3883::QT

BTLtl5

Data File: >C3883::C1 Name: INST 59703,SAMPLE Misc: 1Q3443B,QC1212,L,970,1,30M SPB-5 CAP COLUMN



TIC page 2 of 2

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90

r ' i i e - 'C i . iSJ If i iT S j i ' i j i .ii'<f:.*-£ l o - - » 4 3 c . u C - i i i .L . r r e . 1 , j j i i i P S c a n H i ' S p i flb 3 5 " , : i SI 10 flOn OVC 2 C . 0 S m i n .

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Sample f i l e : >crjS3'3 Spectrum I : ^ . J - J /^

9 1

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istet<b#e:t NJ DEP Certified Drinking Uater/Uas Laboratory ID# 14116 '- ' US EPA Contract Laboratory .-"

LABORATORY ANALYSIS-PETROLEUM HYOROCAReONS

C :i icnt : 3 •:i;'i ?' 11? S o 11 r c e : Siiirip l i n y D a t e : S.7i:i;p I •;-i.l b y :

At Lab Date:

EARTH TECHNOLOGY CORPORATION STAPLING MACHINE 06/23/89 CUSTOMER 06/23/89

LAS DUPL. NO, ID, RESULT RESULT

CUate.'" matrix) ms/l mg/l

1031'13 SMC-F3-2 U

RPD

MINIMUM DETECTION

LIMIT mg/l

METHOD BLANK

0 . 3 3 U

SPIKE RECOVERS

U-- N o t d e t e c t e d NC ~ N o n - c a l c u l a b l e RPO d u e t o v a l u e ( s ) l e s s t h a n t h e d e t e c t i o n l i m i t

I N D U S T R I A L CORROSION MANAGEMENT, I n c R i c h a r d L e v i n e , P r e s i d e n t I

L'j py;

TS yht ICM, Inc., 1936, All rights reserved.

•vi'" .,-"7" ••.. .jpî^j-

PAGE * 92 ^

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to

J. . - ^ p. J l l I. e i V

F s i i d o l p h , NJ 0 7 8 6 9 201- ' v :3<1-0330 AUGUST 1 , 1 9 3 9

NJ DEP Certified Drinking UatE' /Uas-.tCp'ObSle Laboratory ID* 14116 US EPA Contract Laboratory

LAPOPATORY ANALYSIS All reriults are reported in mg.''l (ppm) unless otheruise sts'.ed.

L^b .'v'lrnber : C1 tent ; Swir-pl*? Source Sample ID: 3i:i:ple ijate: SaTiipled By; At Lab Date:

103443 EARTH TECHNOLOGY CORPORATION STAPLING MACHINE SMC-FB-2 06/23/S9 CUSTOMER 06/23/39

.•PARAMETER TESTED RESULT DUPLICATE S P I K E

RECOUERY X

K- H ( u n i t s ) 6 . 7 4

< •-'• L e s s thicui .'•- Greater than

INDUSTRIAL CORROSION MANAGEMENT, Inc Richard Levine, Frs'Siident

Co.--yri3ht ICM, Inc., 1996. All rights reserved, TS

PAGE # 93

• . • y : y ? - S . } / y •';.•.

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1. i. o .L-. K 0 'i t e I '-• Randolph, NJ 07369 201 -•-" .3-1-03 30 AUGUST 1, 1989

Note

t 'iAyy,t!j^2 m N J DEP C e r t i f i e d Drinking Water/Uasteua";t''erf Laboratory ID* 14116 .-•%iiil US EPA JDortract Laboratory ;i|3&!

.ABOPATORY ANALY.SIS—".'OLATILE POLLUTANTS Dichlorobenz fncjs analy:zed a^ i=emi-vo 1 at i le-o , GC/MS VOLATILES - TIER II OELIVEf-ASLES

'¥

l . i i ib NunibC'?r :

S : j m p l e s o u r c e : 5.;,;i^;.le I D ; S a m p l e d a t e : b . j ; n p A t l a b .M 31 r i X

(?d by da t<

P a r -iJrKjter

hlo r romo iny 1 hlor ethy ,1-0 ,1-D otal hlor ,2-D ,1,1 arbo romo ,2-D -1 .3 rich ibro 1 ''

enz e -1 ,3 -Chl romo etra 1 "

o lue hlor thyl otal

omet meth Chl

oeth lene ichl ichl -1,2 of or ichl -Tri 1 Te dich i.:hl -Die loro mo ch -Tri ne -Die 0 ro e form chlo ,2-T ne oben benz Xyl

hane ane 0 r ide ane Chlor i

0 roethy oroetha -Dichlo m 0 raetha chlo roe trach lo lo romet 0 roprop hlo r0 pr ethyilen lo romet chlo ro e

h 10 r 0 p r thy 1vin

roethyl etrachl

zene ene enes

de lene ne roethene

ne thane ride hane ane opene e hane thane

opene yl Ether

ene oroethane

103444 EARTH TECH." STAPLING H,' SMC-T3-2 06/23/39 CUSTOMER 06/23/89 UATER

Result ug/1

U U U U U U U U u u u u u u u u u u u u u u u u u u u u

'GLOGY CORP ^CHINE

Method Slank ug/1

U U U U U U U u u u u u u u u u u u u u u u u u u u u u

OPATI

M D L

CN

in imum etect io n imit

ug/1

5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5

ug/1 •- micrograms/liter or ppb

U: Indicates a compound was analyzed for but not detected. J: Iniiicates an estimated value. It is utilized uhen a reported value

meets the identification criteria but the result is less than the •jp<?cified detection limit but greater than zero.

B: IndicateS'that the analyte was found in the blank as well as the sample. '.Ife'vindic'atfta possible/probable blank contamination.

• & y i / i ' ' "• "

C o p y r i g h t ICM ,^!T»k't ,V4^86fv- A-11 r i g h t s r e s e r v e d .

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• . ' • • \ - . . ^

TOTOL ION CMROflQTOGRQtl V i W eoe2«> 3 5 . 0 - 2 1 5 0 . 0 a « u . VOfl OM S , S&nPLE

TIC 100 200 300

*—^ 1 - 1 - - A fl i ^ 1 I 1 . • ; 1 . 1 . 1 t . • 1 1 - i - . 1 - j _ - i 1 . • . . 1

103444 , a v o t r a , 5 . L

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' I ' l 16 13 20

Data File' >G0829«sGl Quant Output File» *G0829i:QT Name« UOA ON G, SAMPLE ni5c« 103444, QU0672, 5, L, 6'X2mm DC SP 1000 ON CftRBOPKB

Id File". GUOAL'sSC Title* GENERAL IDFILE FOR INSTRUMENT G Last Calibration' 890628 08«50

Operator ID« SP5680 Quant Timet 890628 14«52 Injected at' 890628 la»ll

TIC page 1 of 2

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Data File: >G0329««G1 Quant Output File« *G0829!sQT Names U O H ON G, SAMPLE liisc: 103444, QU0672, 5, L, 6-X2mni IV. SP 1000 ON CARBOPKB

Id h I le= GUUAL!sSC litle: GENERAL lOFILE FOR INSTRUMENT G Last Calibrations 890628 08:50

Operator ID: SP5680 U'jant rime: 890«>28 l4s5>2 Injected at: 890628 1-4:11

j i L page 2 or .::

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^-^'•y?m NJ OEP C<?v f i f iec! D r i n k i n g U a t e r / U a ? . t e u a ' l % L.abo r I ' . ' j ; y I'D* 1-4116 US EPA Cor i t r ib i r t L a b o r a t o r y

SURFjrGATE RflCO'.-E KY SUf^r'rARi' A •} 0 (? o u s V ii 1 a 11 1 e S 'a T• r : ci vi t e 'y

T '1 ri;l;'er 0V0.572

.''. R e c o v e r y 2-D i c h lo r o e t b a n e - d 4

% Reco'.'ery Toluere-dS

% Recovery Bromofluorobenzene

• Outside QC Limit-3

BLANK 103441 1034 4 0 •034.39 BLANK 103443 BLANK 103412 J 034 39 1034123 1034 42SD

lO'i 114 114 112 104 105 104 104 103 105 lOS

.

101 101 100 100 107 107 103 103 107 110 106

99 101 104 101 103 106

9 7 101

9 9 1 0 0 1 0 4

0 0 0 0 0 0 0 0 0 0 0

QC L i i i i i t y ; 1 , 2 - D i c h l o r o e t h a n e - d 4 To I ' l e n e - d S Bromofluorobenzene

76-114 83-110 86-115

> V^l-.tes outside QC Limits. 3~ Spike sample 30- Spike duplicate savrple

Copyright ICM, Inc., 1987. All rights reserved, TS

• • ' % m ^ r y r n ^ ' y . •• »>imm/- .

PAGE * 97

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•fM 1152 Fo^le I'D Rardo Iph , NJ 0 78*9 ;:oi-'^>M--o ;•::•:) "Miyur.t 1 . 19^9

NJ OEP Certified Drinking Ua t er/Ua.sfe,^ L-J bo rater y ID* 14116 US EPA Contract Lat. era to ry . ,.,„

QUAL.ITY ASSURANCE DATA MATRIX SPIKE/MATPIx; SPIKE DUPLICATE RECOVERY

Vrjlatiles - Uater

2 M W ,

S j i i i p l e i i ' i ; i i be r ; 1 0 3 4 4 2 OC P a t c h nuipber ; 0 V 0 6 7 2

F o r -i. rr;;; l e s : 103441 103440 103439 103443 103442 10343S 103444

Coirpo 'ind

1 , 1 - 0 i c h 10 r 0 e t h e II e 1 r i c h l o r o c t h e n e ;.' I'! 1;) r 0 .b c- It z e n e T o l u c M i e 3 G 'r; z. *-~ . *?

Cone Samp Added Cone ug/L ug/L

50 50 50 50 50

U U U U U

Core M,S U3/L

73. 4 67.6 64.6 67.1 59.9

% Rec

157* 135* 129 134* 120

Cone MSD ug/L

57.6 59,4 53,3 56.4 55.1

% Rec

115 119 117 113 110

RPD

31* 13 . 10 17*-9 •;.;

QC RPD

14 14 13 13

..11 M

Limits Recovery

•il--l,'»5 71-120 75-'l;30' 76-125^

i 74rl'27 I f

* '.'ali>:--i are outside QC Limits

RPD: 2 out of 5 are outside QC limits. Recovery: 3 out of 10 are outside QC limits.

Comments:

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173 Less than^ 2/i <of' inass 174 0.00 l/«* Greater thanV OJt- of mass 95 93.10 175 5 -9 '4 o f jiiasVi74^ - Q . 7 - * i 7 u yb-lul/. of mass i / * * 91,85 I// 5-9>; ot mass 17o 6 . 5o

19.21 54.71 100.00

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SC/MS PERFORMANCE STANDARD

Bronof luorobenzene <BFB>

•" • ' ; " . ' - . 'y .^ i

« / : Ion Abundance

Criteria

X Relative Abundance Base Appropriate Peak Peak Status

50 75 35 5£

173. 174 175 17S 177

J5-40S of nas s 95 30-Mr';of wass.a?; 3ase .peak,' 10OS-relative abundance

Lesllfthan 2S'ofl n a s s 174 Scea|ervtKan„.53S-'c.f mass 95 3-95:df mass 174 , 35-101X of nass 174 5-3X of nass 176

Injection Date: 0S/':7/aS Injection Time: 12s03

Data File: ^60507 Scan: 68

ASSOCIATED SAMPLE NUMBERS: /03M3

1 01

24 .53 SS.S-t

100.00 B.02 0.£)Q

73 .£9 4 .33

70 .77 3 .53

a t u r e :

24.53 55.94

1'3^.30 6.02 3.00

73 .53 5.52

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10.442 103.030

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Initial Calibration Data HSL Coapounds

Cafe No>

Contractor* IHOUSTRiflL CORRBSIOH

Contract No: riAhflGEnENT

Instruaent ID> IA

Calibration Date: 0e/T$/89

7 0 3 4 4 O

niniauB RF for SPCC is ,3

t o344<. ^ r'

103-444-naxiniw I RSO for CCC is 301

Laboratory

Coapound

Chlor oMthtne

BroMMthane Vinyl Chloride

Chloroethane nethylene Chloride

Acetone Carbon Disulf ide 1,1-Oichloroethene 1,1-DichIoroethane 1,2-Oichloroethene ( to ta l )

Chlerofore l,2-0ichloroethane-d4

1,2-Oichloroethane

2-Butanofte 1.1,1-Trlcbioroethane Carbon Tetrachloride Vinyl Acetate BroMdichloroMthane 1,2-DichlBropropane traos-l,3-0ich1oropropene Trichloroethene

OibroMchloroMthane

1,1,2-Tricbloroethane

Benzene cis-l,3-0iebloropropene

BrMMfora

2-Heianone 4-llBthyl-2-Pentanoi« Tetrach Uraethene

ID> >60743 RF

20.00

.67437

>S0742 >S0741

RF RF 50.00 100.00

.70059 .65927

X0740 RF

150.C0

.71783 1.51439 1.62452 1.68056 1.61821

>G0757 RF

200.00

.66303 1.56285

1.07605 1.13771 1.22616 1.30860 1.40675

.66308 .74682 .74395 .78372 .77273 1.20084 1.22870 1.225C5 1.21785 1.17742

.36526 .21706 .20500 .18036 .14142 2.57354 2.73586 2.77656 3.01230 3.07038 1.22277 1.23224 1.24041 1.23742 1.21060 2.17766 2.16720 2.24751 2.21761 2.15027

1.25037 1.26427 1.30722 1.29775 1.23332

3.18704 3.07811 3.21677 3.07752 3.03337 2.01111 1.89907 1.88567 1.81755 1.73169 2.11471 2.02267 2.04631 2.01578 1.91673

.03045

.79663

.80655

.32957

.72903

.28285

.31362

.45754

.61099

.32027

.73522

.62456

.47312

.23411

. - ' ^ ^ ^

.02285 .02301

.79199 .79718

.78635 .76810

.29659 .32100

.73721 .73722

.29313 .28092

.31899 .31896

.462B1 .4M06

.60953 .60639

.30869 .29878

.7K69 .72402

.65019 .64366

.50536 .50239

.22713 .22205

.2056i .19953 • t e ; 5 5 7 1 ® 5 5 | l 6 V X 5 4 < 8 5

l . l , 2 , 2 - T e t r a c h l o r o e t h a n e : ^ f f v 5 4 « 3 | i^wfmîfm

.02132

.75487

.74206

.32629

.72001

.28430

.32145

.43656

.58511

.28415

.69907

.63578

.50032

.20506

.18955

.53327

.46449

.01725

.73761

.76917

.32156

.70954

.26400

.30105

.42918

.54992

.25932

.68292

.60429

.45226

.17571

.16480

.54450

.42262

RRT

.152

.241

RF

.68342 1.60015

.308 1.23509

.411 .74606

.646 1.21441

.731 .22182

.804 2.88173

.944 1.22913 1.077 2.19645

1.149 1.27099 1.214 3.12297

1.271 1.86942 1.282 2.02324

.642

.709

.727

.735

.756

.818

.893

.856

.890

.894

.877

.831

1.020

.899

.839

.911

.914

.02298

.77606

.77444

.31901

.72660

.28104

.31481

.45003

.59239

.29425

.71538

.63170

.48669

.21295

.19507

.54803

.48036

i RSO CCC SPCC

3.802 • • 3.964

10.228 » 6.863 1.183

38.427 7.564

1.016 • 1.782 • • 2.497

2.454 • 5.525 3.521

20.806 3.469 3.089

4.081 1.637 3.776 • 2.607

3.570 4.379

8.021 3.279

2.858 4.764 • •

11.016 9.960

1.875 9.318 • •

tF - Response Factor' (Sul iscnlpt^ ls l imtntr to UCA)

RRT Rwerage Relative Retention T i w (RT Std/8T Istd)

RF - Ruerage Response Factor

U S D - Percent Relatiue Standard Deviation

CCC - Calibration Check Coapounds (•) SPCC - Systea Perforaance Check Coapounds (••)

Fora VI Page 1 of 2

1 05

• • » . • •

Initial Cahoration Data " - i^M HbL Coapounds

iaie hoi InjtruMnt ID: IH

iontractjr: INDUSTRltiL CGRSDSlilK Calibration Date: 1)6/15/87

Contract No< HHMEhENT

HiniBoa i f fo r SPCC is .3 naxiaua I RSO for CCC is 30}

Laboratorv ID: >go743 >60742 >£0741 >60740 >G0737 RF RF RF RF RF _

Coapound ZO.OO 50.00 100.00 150.00 200.00 RRT RF X RSD CCC SPCC

Toluene-d8 1.152711.14026 1.117711.112611.13276 .7511.13165 1.417 Toluene .t«052 .63008 .64264 .60050 .58673 .757 .62413 4.836 * Chlorobenzene .88773 .88531 .93655 .90372 .90819 1.005 .70430 2.274 ti ethylbenzene .44882 .43531 .44613 .43385 .42477 1.081 .43782 2.217 • Styrene .71277 .87077 .72251 .87646 .87840 1.233 .87222 2.656 Xylene (total) .53371 .51741 .53077 .51024 .51540 1.281 .52195 1.732 Broaofluorobenzene .80170 .76874 .77208 .74035 .73860 1.179 .76827 3.764

RF - Response Factor'(ûbMriptîsâMuhV is.OCA)

RRT - rtuerage Re la t i ue Retent ion Tiae (RT StdiDT I s t d )

RF - Auerage Response Factor

U S D - Percent Relatiue Standard Deviation

CCC - Calibration Check Coapounds (•) SPCC - Systea Perforaance Check Coapounds (••)

' y 0

o 1 o f

Ul

Fora VI Page 2 of 2 10

1 oe ^ a\

C o n t i m t i n g U l i D r a t i o n Check ' - • ' • f M ^

- K : '-mi

m e MO:

loritractor-- iiiUUiixiriL LUK4iU lUii

Lontract Ho: PHrtHbthtNl

Instruaent lus IH

la i iDrat ion tlat?' v.]/2»/8y

Tiae: 11141

Laboratory ID: ,ii,[);9i)

I n i t i a l i a i i b ra t i on Date: vo/l5/{

to3«fl

I l i n i a u a Rf f o r SPCC i s .5

Coapound RF

rtaxiaua i O i f f f o r CCC i s 15X

i f t i ' i f f CCC SPCC

Ihloroaeti'iane sroaoMtnane

iJinyl Chloride ihtoroethar>e Methylene i h l o n d e

Hceione Carbon Disul f ide i . l -uicnioroethene

l. l-Oichloroetnane l.^-Uichioroethene ( t o t a l i Ih lorofora l. i*utcnioroetnane-o4

l. i-Otchloroethane ^-ttutanone

l . l . l -Tnct i io roethane laroon Tetrachloride tfinvl Acetate broaodienloroaethane 1.2-Oichloropropane trans-l.)-0ich1oropropene Trichloroethene Dibroaochloroaethane

l . l ,2-Trich)oroethane

benzene

eis-l,3-&ichloropropene Broaofora

2-Heianoite

4-rlethy 1 -2-Pentanone

Tetrachloroethene

1,1,2,2-Tetrachloroetnane To1ueoe-d8 loiuene

.08342 l.otul?

.78042

1./45U 1.2J5<)» l.ZiOAy

./4tt;ft

1.Z1441

. 'u i i i 2.H8173

1.2^*13

./«58<> 1.180dl

.345>i

3.yuy5') 1.25055

Z . l 7 « 4 j 2 .12738

l . i m i 3.12277 1.8«y4i 2.ili:3i4

.\tUU

.7740«

.77444

.31901

,7 ioo0 .28104 .31481 .45003 .59239

.29425

.71538

.63170

.48»69

,21295

.19517

•^laiiMj'^ .IÎ^H,

1./U487 3.21870 i.OJJu^ 2.05510

. v i t l i

.84485

.»ou73

.32844

.7«26l

.29098

.335^6

.47012

.61213

.29299

.71245

.66512

.49676

.20975

.19892s Ji5595|^^ ^.43524?'

• j ^ ;K i3 l65 t l v i49B i^ •• ;6457i;

14.19 7.07

.44 •

2.A5 2.78

54.77

4.45 1.74 •

3.05 i.oy

3.0/ • 9.82 1.57

18.in 7.12 3.37

2.96 4.74 3,54 • 6.49

4.46 3.53

.43

.41 5.29 2.47

1.50 1.97

2.11 9.59

1.61 3.46 •

••

I t

I t

I I

f

.s:y

Kf - Response Factor froa dai ly standard f i l e at 50.00 UG/L

RF - Hverage Response Factor froa I n i t i a l Cal ibrat ion Fora Vi

tO i t r - i Utrference froa or ig inal average or curve

ILL - i a i i b r a t i o n Check Coapounds (* | SPLC - Systea Perforaance Check Coapounds (*•)

Fora VI1 Page 1 ef 2

2' O- 1

Ul to

1 07

•i : i Contiriujng Cal ib ra t ion Check HSL Coapoumii

lase No:

Contractor I IHDiiSTRlHl lORROSIOH

Contract Ho: HHtiHGENEHT

Instrut tent l b : I H

Ca l ib ra t ion Date' Oo/io/67

Tiae> 11:41

Laboratorv ID> /G0790

In i t i a l Calibration Date: 0o/13-87

n in iaua i(F for SPCC is .3 naxiaua 1; O i f f for CCC is 25'<i

Coapoiind t f RF i D i f f CCC SfCC

Lnlorooenzene tinyloenzene i turene Atfiene i t o t a i i broiiof luorocenzene

.70430 .71534 1.28 •«

.45?b2 .'*4830 i.}'' •

.WuL .y?2i5 4.47

. ? i l /5 .54»77 5.14

.76927 .79737 5.85 iConc«50.00i

'-•SM •i-:yym

•' ' ' y % . •• y / s : -

m

T

.•y""

k f - ife2pon;e Factor f roa da i l v standard f i l e a t 50.00 l)G/L

RF - Huerage Response Factar f roa I n i t i a l Ca l ib ra t ion Fora VI

4Ui r r - i [ f i r ferer ice f roa o r i g i na i auerage or curue

CCC * C a l i b r a t i o n Check Coapounds l * i SPCC - Svstea Per foramce Check Coapounds t*«)

Fora V l i Page 2 of 2

1 0 8

w

Cofltifiuug Cahbra t i jn CVsck Ca±>*- 103 44-3

Cass .Ho:

Cur,trac;a-: 1105181*. CCiERCSIJIi

CaliCrj l lci Oale: Ot.'ZT.'S?

!:««: !2:-5

U0er.2l.wv 13: itCc'jS

I c i t i a l uhi.-ati . jf . Cats: i;t.'l:/.35

1^-1%^ if for GPrC is .3

•rartpijund Bf

f.ir.msn I iliff fa- CCC i s 2^*

Rf :C':ff cccspcr

Chicrc-.t-J'aM 3.'S!iciwtrif.i

!J:r.','l a-.ljr;d4 Lr!iiirget.Tane "rftri'.'ljf* 'iRioridt ftceti)r,t Carior, J l julf ide I .^ - i ich iora t thsnt l,!-!iiciii).-«tiv3n< !,2-D;wii)r5eth«r.« a a t a l ) Chiorofan i ,2-Djc-icroetMiis-d') 1,2-0iw-,i;rss'lhai!« 2-3i)tani)M l . l . l - l r i o i l a r a e l h a r e Carbon Istrachloriite Uinyl Acttate Broiwdidilsrcfttthanc 1 .i-OiLhlorcpropane t rans- i .j-ihcbiaropropent Tr ich ls ra theae Si t 'oradi iaromthant 1,1,2-ir ichhroethane Bcnreu c i s - I .Mhc.'iloroprapene Brgnoforn 14itxaKnt 1-fl«thi;i-2-P«ntanont I etrachlorotthtne 1,1,2,2-i«tract!ioro«thai« Toli;e«-i8 ToluiflC

.ta31Z .82322 2).19 ',.50515 i . i s l i i 1.95

! .23iW 1.2Sii9 2.^5 . - ' M i .76i?£

l . - m i 1.25:07 ..~;82 .iiili 61.72

2.Sal "J2.»J« 3,77 1.22515 1.25s8' 2.Zo • 2.15515 2.5fi5Sa U\ 1.27Q?: 1.270?9 .00 3.12297 3.52572 !2.3fl • 1.3^512 2 .5M31 2S.53 2.C232* 2.10359 18.80

.02215 .!)2i2b M . J O

.77506 .SflSSa 3.92 .77111 .74992 .58 .31901 .3£27i 13.71 .72560 .30372 10.51 .281M .26630 5.:«. • .31181 .31S35 9.70 .151103 .HS33 .38 .592S . i i m S.22 .29425 .27829 5.12 .71528 .71692 .21 .63)70 .56610 S.K . 1 8 M ) . t tS i i 1.38 .2129S .21962 Z.66 .17507 .1)621 .58 .51IK13 .S IW 6.20 .18035 .*263» 11.21

1.131651.fl9M1 3.29 .62113 .6176) !.il3 •

Bf - lespcflM fac t j r fron i a i l v Jtamtorc f i l e a t 55.00 liS/L

fa" - Hvtraje Rtspciw f a c t x frsa I n i t i a i Calibraticn Fom 1)1

Sliff - : Olffersncc fran c r i j i n a l avKragt ar curve

CCC - i a i ib ra t ion Cheek Catip«ur.es ' » SPCC - Svstan PeHomance Checii tanfounii >•>

f s m WI Past 1 of 2

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1 09

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ior.tiDji.i.j Coh!iiit;or. Cl>,ict

HSl Cjncc:-'.::

C3££ lo : _ Caiitraticn Sate: Oi/:?. i9

i :- ' . '3:>3r: [((aSfxIRL C U m i l i Jms: : : : : 6

y y r : z : No: nftisii^tEHI Lii~r3*:rv iD: ;GiiSe2

lr , i : ru: tni IC: !il I.iifiji ial-ibrsi-.i?, C'.jt;: 'Dt/!5,8'J

t l iPin* iif tor SFCC i i ,3 llcvirion : Oiff for Cii u 111

ConMu.id «f !«• : i i i f f CCC i?CC

ChloroMniene .90130 . i m 2.OS «

ithyiben-iiie .13762 .1i542 1.38 '

i ; : ; r iM .39222 .SS-;2 l.Gl

jiyisne uctai) .52195 .5ibi2 .58

srarofluorocMieM .75529 .sCKfl 5.17 iCjnciG'.OO)

Rf - Suspense factor fron daily sta.'hjard f i le al 50.3C Lt/L

55

8f - .I'vera^ iJesponse factor fron I.iiiiai Calibration fern !/I g

lEiff - I Difference fron original auerage or curve (-• Ul

CCC - CalibratiM ChecJi Csnpcuuis (•) SPCC • Syitoi farforsanee tîtck Carpounds i**) t o

1 1 0 fom UII faae 2 a f 2

rontinutni) Calibration Checli HSL Coapoundf

Case Ho'

Contractors IrtDljilklML C0i>i(D51ON

Contract No-' DHNHGtHtHl

InstndBenc lu : iH

Calibration Date: Uo'28/8''

Tine! 06:0."

laboratorv ID: >i,iiiil'?

I n i t i a l Caiibrdtion bate"- Oo/l=>'()'i'

10 3<(-<W-

lliniaim kt ror SrCC is .3 (laxinua i Dirr for CCC i< 25*

LOhpournl

Ciiloromec'iane srotoomeiriane Uinyl Ihioruie

Lftioroechflfte

iietnwlef.e chionde Hcerone Carbon uisuit ide I . t - l j i en loroethene

1,1-0 ich loroethane i.2-U)chioroetnene ( to ta l )

Chlororora 1.2-0ichioroeiharie-o4

1.2-Oichloroethane 2-butanone 1,1.1-Trichloroethane Carbon Tetrachiorine Omul Hcetate iSroaodichlorocetnane

1.2-Oichloropropane trani-l,3-0icnloropropene Trichloroethene Oibroaochioroaethane 1,1,2-Trich loroethane

'benzene cis-l,;-Oichlorepropene Sroaofora

Z-hexanone

4-nethyi-i-Pentanone letracnloroetnene i.l.2.2-ietracAioroethane

roluene-d8 loiuene

kF

.odJ42 l.OUUlil i.a5\iy .'/•ii'io

i./144i . 'uiSi

Rf

.y3739 i . l iy j ' i 1.26632

.b5o5/

1.17453 .h3474

2.68173 l . m i o

1.2i*l3 l.lo8?7

2.17645 2.08755 I.i7uy7 1.2U183

3.12277 2.86572 1.8*742 2.00*75

2.02524 .02278 .77604 .77444 .51701 .72660 .28104 .31481 .45003 .57237

.27425

.71558

.43170

.48067

.21275

.17507

.54U05

.4B«>6 1.13145

.62413

1.87255 .02377

.61444

.55760

.28264

.40812

.2e375

.2/447

.37647

.48775

.25555

.68757

.57477

.37313

.22048

.210U0

.46275

.4466U 1.17517

.6Ul6a

iOirr CCC i f L i

37.16 •• 1 . llH

2.55 » h . l 3

1.63 '.>\).r}

.(i'l 4.95 •

4.88 •• !>.44

8.30 • • 7,36

4.44 4.51

20.57

28. uO 11.4V lo.31

6.08 • 12.75 11.70 17.43 13.15 3.6l 7.01

23.33 •• 3.55 b.06

15.54 7.U3 «•

3.85 3.60 •

kl- - iiesponse factor rroa dai ly standard f i l e at 50.UO (t(/L

RF - Huerage Response factor froa I n i t i a l Calibration fora 01

jiUirf - i Uirrerence froa or ig ina l tvera^t or curve

CCC - Calibration Check Coapounds ( • ! SPCC - Systea Perforaance Check Coapounds ( " I

Fora V l l Page 1 of 2 1 1 1

W

o o

Ut Co

wu, , V , t i u i i i v i L a i i u i o h i u i i w i lCLI l

hjL [oapoun'lf

i.a>e Noi C a l i b r a t i o n uate-' Oo/lS/B? t o n t r a c t o r : I H I ' J S T & J M L COkiuSiuii IuMfs us-'v/

t o n i r a a t 110= rtHHriuEdtrtJ laDorator . j H i : .^0815

i r i i t r u ^ e f ' t I'v- JH I n i t i a l C a i i o r a t i o n ba te : U6 /15 ' 8 '

( l in i f iu i i Kf fo r i r i i i s .3 na>iB'.a i D i f f f o r CCC is 251

Coapound KF kt 'Ôirf CCC SrCC

inloropenzer ie .ru43'J .85406 7.55 ••

ttriwitierizene . ^ y ' ^ i l .36"y8 l i . 3 » » St' jrene . i ' / l l l .81/41 8.35 Auiene i t o t a i i .521??- .4*32^ 3.11 Broaof iuorobeniene .7o3i7 .80547 4.87 iConc '50 .00 i

Rf - Response f a c t o r f r o a d a i l u standard f i l e a t 50.00 II6/L

Rf - Auerage Response Factor f roa I n i t i a l C a l i b r a t i o n Fora VI ^

Ji'uiff - t O i f r e r e n c e f r o a o r i q i n a l aueraqe or curue o o H

CCC - Calibration Check Coapounds (•) SPCC - Svstea Perforaance Check Coapounds (••) y- '

Fora on Page 2 of 2 S 10

1 1 2

Randolph, NJ 07869 2 0 1 - ^ : ^ 4 - 0 3 3 0 7 / 1 9 / 8 9

MJ D1£P C e r t i f i e d D r i n k i n g U a t e r / U a s t e u a t e i L a b o r a t o r y I D * 14116

LIBRARY SEARCH RESULTS OF MOMTARGETED PEAKS UITH ESTIMATED CONCENTRATION OF TEiVTATiVEL Y IDEiVTIr lEO CC-iFOUNOS,

Data f i l e name.' L.3b number ; F r a c t i o n ;

>C3911 BLANK B-3ijG./Ne(i t r a l

T h i s BLANK co rre<5po nds t o t h e f o l l o u i n g l a b n u m b e r s ; 10343.^3 103'>39 I'DS^'}':' l 'D3441 103442 103443

Scan • ^ • j .mb>: r

?.329

CAS No R e t e n t i o n

T ime Compo und

Name Mo 1 c c u1 a r

U e i c i h t

2 7 . 8 4 Unk no li/n

Est imated Concentrati'jn

ug/1

10

A: Indicate-3 that the compound is an acetone based aldol-type condensation product formed by concentrating the extraction solvent (1:1 acetone/methylene chloride).

B: Indicates that the analyte uas found in the blank as well as the sample. It, further indicates possible/probable blank contamination.

Copyright ICM, I n c , 1996. All rights reserved.

^

o o

1 1 3 Ol

11.3 :> ; ; 11. e i o R.3-,.•^Jlph, N.J 0 7 8 6 9 201-r?;.1--0330 AUGUST 1, 1939

NJ DEP Certified Drinkin'j Ua t er/Ua ?;t eua t er Ljboritory ID* 14116 US EPA Contract l..aboratory

rURRfJ'?ATE FECQUERY SUMMARY A q u e 0 u •= G -i : e / N e u t r a 1

• J : l . . ... I I n'lrrb'ii'T ;ci2i:

Lab * N

BLANI-:-SLANK S BLANK SO 103433 1034 39 103 4 4': 1034 4 1 103442 103'14 3

'» .It

r.

ro e b

.—.

CO - r êvy

enzene-d5

40 4.5 36 51 48 33* 4 8 2*

30*

% R e c o % e r y 2 ~ F l u o r o b i p h e n Y l

% R y c o v e r y • T e r p h e T i y l - d l 4

• 0 u t s i d tf QC L i m i t i

70 S3 73 36 90 72 85 2 5 * 65

8 5 4 5 52 49 61 49 46 41 41

0

0

0 1 0 - I

iJC Limit Nitrobenzene-d5 2-F1u 0 r 0 b i pheny1 2 -- T e r p h e n y 1 - d 14

35-114 43-116 33-141

* Ual'.u?^; outside QC Limits. S- Spike? <;;ample S3 ~ S p i k e duplicate sample

Copyright ICM, Inc., 1987 TS

All rights reserved

PAGE * 114

W

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P:iTi,:Jn U-h , NJ 07869 NJ DEP Certified Drinking Ua t er/U 51;; t c/ua t e ::0 1-'••:M--v530 l..-jb: ratory ID* 1411.6 Ai!:;i;':;t 1 , 19S9 US EPA Contr.jct L a b c r ;vta r y

QUAL.rTY A.££.'.'RANGE DATA HATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOiJERV

3 3 ;u >fi 1 e n n in b e •:• ; B L A N K Q;.;: Bate; I-, number; 0 C 1 2 1 2

F 0 r -i.Hftp 1 e3 ; 103433 103439 103440 103441 103442 103443

C'.! il": i'-ii .ir.ri C o r e S 3 mp Added C o n e U'j/L U3/L

L /2 , 4 - T r i c h 10 r a b e a : c- n a 100 U A c e n a p h t I'l e n e 100 U ;',4-Cirii tratolêre 100 U Di-n-butylphthalate 100 U -yrerr-/ 100 U N-Ni tro ?>o-dJpro py Irimine 100 U 1 , 4-0 ichlo robenz'sne 100 U

C 0 T) C

MS ug/L

43.6 64 ,0 56,.3 65.8 75.5 49.7 36,3

X Rec

44 64 57 66 76 50 37

COTIC

MSD ug/L

36.1 60, 1 60.5 70.3 94.3 42.6 29.4

_. .

'4 Rec

3 6 * 60 61 70 94 43 29*

^

RPD

20 6 7 6

21 15 24

QC RPD

28 31 39 40 31 38 28

Limits RE^CO very

39-93 4 6-118 24-96 11-117 26-127 41-116 36-97

* U3l-.i»?-5 art? outside QC Limits

?PD; 0 out of 7 are outside QC limits, -ecovery; 2 out of 14 are outside QC limit!

C : rnment-.i;

C o p y r i g h t ICM, I n c . , 1 9 8 7 , A l l r i g h t s r e s e r v e d , TS

PAGE * 1 1 5 o o

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1^0

1^0

-30

20

18

90 108 1S8 208 250 300 350 400

365 493

GC/hS PERFORMANCE STANDARD

m/z Ion Abundance

Criteria

Decafluorotriphenylphospine (DFTPP1

\ Relative Abundance Base Appropriate Peak Peak Status

51 70-60X of mass 198 . 57.83 57.83 68 Less than 2% of mass 69 0.00 0.00 69 (reference only) 62.94 62.94 70 Less than 2% of mass 69 .31 .49 127 40-60X of mass 198 43.17 43.17 197 Less than IX of mass 198 0.00 0.00 198 Base peak, lOOX relative abundance 100.00 100.00 199 5-9X of mass 198 7.19 7.19 275 10-30X of mass 198 20.09 20.09 365 Greater than IS of masa 198 1.79 1.79 441 0-lOOS of mass 443 4.90 27.35 442 Greater than 40S of mass 198 89.15 89.15 443 17-23X of mass 442 17.91 20.09

Injection Date: 07/'12/89 Injection Time: 15:09

Data File: Scan:

>C3871 564

Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok

A n a l y s t ' s S i g n a t u r e 7U*Ctuur r ) i O t . l 2 . H ^

S a m p l e Numbers /0 -»^3 /^ IO^* tS^ / 6 \ i l ^ r , i6i>fi% /6î/i/0. /&3>V^

/o^9¥l, /d>>vVi T T e

50

o o

ril« >C3871 197.7-198.7 *«u.INST 59793,0FTPP859 30M SPH-H tA^ COLUHN EIP

100 200 380 408 508 680 708 888 . I i • I i i • • I . • • . I • i , , I , • • • I , 1 , • • I • • • • 1 1 1 • • 1 • . , • I . • I , , ,

69896-

r;608(>-

52080-

48000'

44000-

40000-

36080-

32000-

zseoo-

24000-

20000-

16000-

12080-

8000-

4080^

>C3871 564

INST 59703,DFTPP050 30M SPn-5 CAP COLUMN NRM ENH

F i l e : >C3871 Scan *: 564 R e t n . t i m e : 1 4 . 5 3

m/z I n t m/z In t m/z I n t m/ z In t . m/z I n t .

3 7 . 0 0 3 8 . 0 0 3 9 . 0 0 4 0 . 0 0 4 1 . 0 0 4 3 . 9 0 4 5 . 0 0 4 7 . 7 0 4 8 . 3 0 5 0 . 0 0 5 1 . 0 0 5 2 . 1 0 5 2 . 7 0 5 5 . 0 0 5 6 . 0 0 5 7 . 0 0 5 8 . 0 0 5 8 . 8 0 6 1 . 0 0

. 2 5 7

. 9 7 8 5 . 8 4 8

. 5 7 3

. 2 7 4

. 9 3 4 . 0 5 8 . 0 2 9 . 0 3 9

1 4 . 1 8 7 5 7 . 8 3 2

3 . 0 0 2 . 2 1 9 . 3 5 9

1 .842 4 . 2 9 0

. 2 4 3

. 0 5 7

. 9 7 4

9 9 . 0 0 1 0 0 . 0 0 1 0 1 . 0 0 1 0 1 . 9 0 1 0 3 . 0 0 1 0 4 . 1 0 1 0 5 . 1 0 1 0 7 . 0 0 1 0 8 . 0 0 1 1 0 . 0 0 1 1 1 . 0 0 1 1 2 . 1 0 1 1 3 . 3 0 1 1 4 . 0 0 1 1 6 . 1 0 1 1 7 . 0 0 1 1 8 . 1 0 1 1 8 . 9 0 1 1 9 . 3 0

2 . 7 8 6 . 2 5 7

1.550 . 0 2 7 . 7 0 1

1 .054 .986

1 2 . 2 5 1 1 .914

3 2 . 7 6 1 4 . 1 6 2

.520

.032

. 0 2 3

.872 7 . 3 9 6

. 476

. 1 7 4

. 0 2 1

1 5 6 . 1 0 1 5 7 . 1 0 1 5 8 . 0 0 1 5 9 . 1 0 1 6 0 . 0 0 1 6 1 . 1 0 1 6 2 . 1 0 1 6 4 . 1 0 1 6 4 . 3 0 1 6 5 . 1 0 1 6 6 . 1 0 1 6 7 . 1 0 1 6 8 . 1 0 1 6 9 . 1 0 1 7 0 . 0 0 1 1 7 1 . 0 0 1 7 2 . 0 0 1 7 3 . 1 0 1 7 4 . 1 0

1 . 6 1 1 . 4 9 3 . 3 9 7 . 1 9 7 . 6 6 0

1 .063 . 2 8 3 . 2 3 9 . 0 4 4 . 7 4 7 . 5 6 0

3 . 7 6 5 2 . 2 4 2

. 3 8 4 1 7l26

. 1 4 5

. 4 0 7

. 4 5 6

. 8 4 0

2 0 9 . 5 0 2 1 0 . 1 0 2 1 1 . 1 0 2 1 1 . 7 0 2 1 5 . 1 0 2 1 7 . 1 0 2 1 8 . 0 0 2 2 1 . 1 0 2 2 4 . 1 0 2 2 5 . 1 0 2 2 7 . 1 0 2 2 8 . 1 0 2 2 9 . 1 0 2 3 0 . 1 0 2 3 1 . 1 0 2 3 1 . 9 0 2 3 4 . 1 0 2 3 5 . 1 0 2 3 6 . 1 0

. 1 2 0 . 3 1 3 . 7 6 5 . 3 1 2 . 2 3 1

3 . 9 6 0 . 4 5 0

6 . 7 9 6 9 . 0 2 9 2 . 4 9 8 3 . 5 1 4

. 5 5 4

. 8 3 4

. 036

. 3 8 6

. 0 1 6 - . 1 8 1 . 2 0 6 . 0 4 1

2 9 0 . 3 0 2 9 3 . 2 0 2 9 6 . 1 0 2 9 7 . 2 0 3 0 2 . 1 0 3 0 3 . 2 0 3 0 4 . 1 0 3 0 8 . 0 0 3 1 3 . 0 0 3 1 4 . 1 0 3 1 5 . 2 0 3 1 6 . 2 0 3 1 7 . 3 0 3 2 1 . 2 0 3 2 2 . 1 0 3 2 3 . 2 0 3 2 6 . 9 0 3 3 3 . 0 0 3 3 4 . 2 0

. 0 1 3

. 3 2 4 3 . 8 1 2

. 4 9 7

. 0 1 7

.539 . 0 7 4 . 0 2 7 . 0 7 5 . 2 2 7 . 4 7 9 .399 . 0 2 1 . 0 9 8 . 0 2 3

1 .646 .'273 . 1 6 3 . 922

W ^

o o M

(Jl

_ 1 "*sl

o-» . i u 65.00 66.90 69.00 70.00 71.00 73.10 74,00 75.00 77. 10 78.0 0 79.00 80.00 81.00 82.00 83.00 84.00 84.90 86.00 87.10 87.70 88.70 89.00 91.00 92.10 93.00 94.00 94.60 95.10 96.10 96.80 98.00

. i . ^ J

1.246 .041

62.942 .307 .019 .094

4.401 6.652

48.596 3.690 3.461 2.727 3.519 .948 .957 .216 .709 .838 .445 .041 .017 .019

1.097 .805

4.196 .254 .011 .120 .218 .152

3.460

L i . . . . 1 U

123.00 124.10 124.90 127.10 128.00 129.00 130.00 131.10 132.40 133.30 134.00 135.00 136.00 137.00 137.70 140.00 141.00 142.10 143.10 144.40 146.10 147.10 148.10 149.00 149.80 151.10 151.70 152.00 153.10 153.90 155.00

. ^ ^ T

1.291 .705 .553

43.173 3.558 16.935 1.314 .247 .071 .091 .608

1.447 .641 .791 .267 .169

2.037 .775 .461 .140 .418 .995

2.013 .543 .111 .240 .195 .193 .602 .468

1.226

i/ /' . u u 177.80 179.00 180.10 181.10 182.10 182.30 182.60 182.80 184.10 185.10 186.10 187.10 188.10 189.10 190.10 191.10 192.00 193.10 194.30 196.10 198.10 199.10 200.00 201.60 203.10 204.10 205.10 206.10 207.10 208.10 208.90

. O V 7

.064 2.602 1.946 .890 .130 .030 .019 .020 .233

1.333 10.686 3.139 .344 .594 .123 .216 .728 .811 .216

2.919 100.000 7.190 .428 .548 .539

2.273 4.242 17.231 2.814 .531 .175

'*z 244. 245 246, 247 249, 250. 251, 252. 252, 253. 253. 255. 256. 257, 258. 259, 261. 264, 265. 271. 272. 273. 274. 275. 276. 277. 278. 279. 282. 285.

. i. u

. 10

.10 ,10 .10 .10 .00 ,10 .00 ,30 ,10 ,30 ,10 .10 ,10 .10 ,90 10 ,00 10 ,60 00 ,10 10 10 20 10 10 10 00 20

8 1 1

38 5

1

1 3, 20 2, 1

. '*OU

.309

. 160

.277

.269

.278

.017

.062

.077

.019

.209

.245

.020

.721

.408

.700

.082

.027

.009

.753

.020

. 046

.233

.770

.088

.894

.169

.280

.015

.013

.229

^'41

346. 352 353, 354 355, 365 366, 370 371, 372 373, 374 383, 390 391, 395. 401, 402, 403. 404, 421. 422, 423. 424. 438. 439, 441. 442. 443. 444.

. i . <j

,00 .10 ,20 .20 ,10 .10 ,10 .30 ,10 .10 ,20 .00 ,10 .10 ,30 ,10 ,20 ,20 ,20 .20 ,20 ,20 20 ,20 ,30 ,00 30 ,20 20 ,20

• w •

.298

.543

.468

.519

.019 1.789 .102 .016 .061 .960 .220 .011 .250 .155 .084 .012 .093 .337 .656 .155 .548 .444

4.654 1.016 .022 .021

4.898 89.151 17.910 1.495

w

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1 1 8 (J l OJ 00

L c ^ '

Initial Calibration Oata HSL Coapounds

Case No:

Contractor: INDUSTRIAL CORROSION

Contract No: mNAGOCNT

Instruaent ID: 3C

Calibration Date: 07/06/89

/ O S H 3 ?

lo'hHHO

niniaua RF for SPCC is .0$ naxiaua k RSO for CCC is 30)1

Laboratory 10:

Coapound

>C3e54 RF

20.00

>C385J RF

90.00

>C3852 RF

80.00

>C3851 RF

120.00

>C38$0 RF

160.00 RRT RF »RSD CCC SPCC

N-Nitrosodiaethylaaine 2-Fluorophenol Aniline Phenol-d6 Phenol 2-Chlorophenol bis(2-Chloroethyl)ether 1,3-DichIorobenzene 1,4-Dichlorobenzene 1,2-Oichlorobenzene Benzyl alcohol bis(2-Chloroisopropyl)ether 2-nethylph«nol Hexachloroethane M-Nitroso-di-fl-propylaaine 4-nethylphenol Nitrob«flzene-d5 Nitrobenzene Isophorone 2-Nitrophenol 2,4-Oiaethylphenol bis(2-Chlaroethoxy)aethene 2,4-Dichlorophenol Benzoic K i d 1,2,4-Tr ichlorobenzene Naphthalene 4-Chloro«niline Hexachlorobutadiene 4-Chloro-3-aethylphenol 2-NethyInaphthalene

.79987 .96997 .97203 .99960 1.17343 .379 .98298

.98336 1.32136 1.33657 1.39724 1.62589 .722 1.33288

.92531 1.24341 1.22592 1.24635 1.40250 .935 1.20870 2.00349 1.78269 1.61809 1.59145 1.87600 .953 1.77435 1.84050 2.06840 1.89481 1.86314 1.91274 .956 1.91592 1.51940 1.63142 1.51108 1.46665 1.53100 .963 1.53191 1.87170 1.88644 1.64643 1.56134 1.67470 .952 1.72812 1.59232 1.66188 1.50534 1.43908 1.48365 .991 1.53645 1.69028 1.78353 1.54586 1.46850 1.49771 1.004 1.59638 1.62889 1.67201 1.46391 1.37817 1.39882 1.848 1.50836 .84969 1.01849 .97295 .97955 1.08571 1.052 .98128

3.16368 3.33398 3.15043 3.07185 3.14473 1.887 3.17293 1.38670 1.50106 1.38347 1.33251 1.43B59 ,1.893 1.48687 .70836 .74082 .60698 .57185 .61547 1.124 .64854

1.33575 1.46482 1.27018 1.20334 1.32924 1.124 1.32049 1.32936 1.50302 1.47350 1.46127 1.53838 1.130 1.45949 .43714 .47530 .45292 .44636 .476«7 .869 .45768 .16856 .19927 .19281 .19295 .21215 .802 .85590 .92236 .83346 .80274 .13483 .921 .21962 .25789 .24933 .24278 .25849 .933 .35489 .39168 .36919 .35868 .387B6 .958 .56554 .68425 .56639 .54813 .57970 .969 .29578 .34315 .34236 .32226 .31444 .985 .15391 .25948 .27799 .18167 .31667 1.083 .37052 .38442 .34348 .32797 .31458 .995 1.18918 1.24198 .97514 .83391 .78519 1.804 1.80585 .42992 .43762 .41685 .41534 .44883 1.823 .42787 .18222 .19026 .17258 .16252 .13941 1.846 .16948 .35785 .41658 .39045 .37125 .38589 1.126 .38424 .83115 .83767 .03260 .03115 .03353 1.155 .03322

.19314

.70970

.24546

.37244

.57288

.32358

.22193

.34818

13.493 17.285 14.377 9.793 4.681 3.964 8.337 5.838 8.479 8.909 8.778 3.853 4.484

11.151 7.381 5.312 3.853 8.199

45.765 6.427 4.489 3.640 6.17B

40.686 8.345

20.421 2.771

11.643 5.747 8.081

RF - Response Factor (Subscript is aeount in IC/?L)

RRT - Average Relative Retention Tiae (RT Std/RT Istd)

RF - Average Response Factor

VSO - Percent Relative Standard Deviation

CCC - Calibration Check Coapounds (•) SPCC - Systea Perforaance Check Coapowds (**)

Fora UI Page 1 of 3 1 '' 9

^.

o o

(Jl UJ vo

Initial Calibration Data HSL Coapounds

Case No:

Contractor: INDUSTRIAL CORROSION

Contract No: W*««Ef€NT

Instruaent 10: 3C


niniaua RF for SPCC is .05 naxiaua « RSO for CCC is 30X

Laboratory

Coapound

Hexach1orocyc1open t ad i ene 2,4,6-Tr ichlorophenoI 2,4,5-Trichlorophenol 2-Fluorobiphenyl 2-Chloronaphthalene 2-Nitroaniline Acenaphthylene Oiaethylphthalate 2,6-Oinitrotoluene 3-Nitroaniline

, Acenaphthene 2,4-0initrt)phenol Oibenzofuran 4-Nitrophenol

1 2,4-Oinitrotoluene Fluorene 4-Chlorophenyl-phenylether Oiethylphthalate 4-NitroanJline

4,6-0initro-2-aethyIphenol K-Nitr«sodiphenylaaine (1) ftzobenzene 4-6roaophenyl-phenylether Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Oi-n-butylphthalate Fluoranthene

ID: >C3854 >C3853 >C3852 >C3851 RF RF RF RF

20.00 50.00 80.00 120.00

.07414 .09817 .11940 .36555 .39319 .39303 .38729 .38765 .43316 .44315 .42616 .91979 .95848 .89558 .88037

>C3850 RF

160.00

.13414

.35213

.37145

.78665 1.18201 1.21362 1.16617 1.12947 1.00830 .41880 .47447 .51592 .52373 .50412

1.77904 1.85408 1.58971 1.39433 1.22532 1.39276 1.47592 1.36412 1.29154 .33482 .36548 .39296 .36487 .35693 .40908 .40446 .40675

1.20733 1.20204 1.12704 1.06749 .09656 .18903 .25430 .26959

.80867

.32307

.39389

.99548

.28307 1.72466 1.77658 1.60088 1.45475 1.27898 .11113 .14008 .15562 .16044 .49244 .53563 .53283 .52344

.14859

.50709 1.32996 1.36362 1.14661 1.88689 1.87408 .67611 .70267 .59569 .54931 1.39336 1.46653 1.28143 1.19209 .38161 .45282 .46907 .48289 .12806 .13486 .11238 .10844 .15235 .18892 .19937 .88668 .56535 .59155 .53869 .48323 .92737 .92524 .93661 .84481 .22978 .22718 .20541 .19306 .27036 .26253 .21758 .20910 .15980 .184D .16795 .16847

1.17389 1.18875 .99648 .88786 1.13483 1.16005 .97861 .85507 1.55982 1.60325 1.17914 1.03041 1.40294 1.40827 1.20086 1.08205

RF -. Response Factor (Subscript is aaount in U6/1L)

1 RRT - Average Relative i

RF - Average Response i

detention Tiae (RT Std/RT Istd)

"actor

) ffiSO - Percent Relative Standard Deviation

.47822

.13044

.03818

.11798

.01876

.39515

.74433

.18561

.21769

.17486

.82642

.71961

.84427

.92866

RRT RF

.886 .10647

.899 .37824

.905 .41232

.909 .88817

.919 1.13991

.940 .48741

.978 1.56850

.975 1.26660

.980 .35624 1.000 .39422 1.005 1.11988 1.013 .21851 1.029 1.56717 1.036 .14317 1.036 .51829 1.078 1.20023 1.082 .60040 1.078 1.09277 1.089 .36491 .922 .12017 .904 .11320 .910 .51479 .913 .87567 .951 .20821 .966 .23545 .989 .17104

1.003 1.01468 1.009 .96963 1.085 1.24338 1.145 1.20456

«RSO CCC SPCC

24.535 " 4.887 • 7.529 7.202 6.980 8.756 16.700 20.872 7.773 5.489 8.070 • 35.301 •• 12.979 13.611 »• 3.521 11.421 15.299 50.155 51.182 8.919

82.602 15.158 • 9.390 9.525 12.164 5.298 • 16.157 19.243 26.626 17.215 •

CCC - Calibration Check Coapounds (*) SPCC - Systea Perforaance Check Coapounds (**)

Fora UI Page 2 of 3 12 0

!

o o

Ul

L<i.b

Con

Case No:

tinuing Calibration Check HSL Coapounds

Calibri

Contractor: INDUSTRIAL CORROSION Tiae: :

Contract No: MANAGEMENT

Instruaent ID: 3C

niniaua RF for SPCC is

Coapound

N-Nitrosodiaethylaaine

2-Fluorophenol Ani l ine Phenol-d6 Phenol

2-Chlorophenol bis(2-Chloroethyl)ether

1,3-Oichlorobenzene 1,4-Oichlorobenzene 1,2-Oichlorobenzene Benzyl alcohol bis(2-Chloroisopropyl)ether

2-l1ethylphenol Hexachloroethane K-Nitroso-di-n-propylaaine 4-flethyIphenoI Nitrobanzene-d5 Nitrobenzene

2-Nitrophenol

2,4-DiM thy Iphenol

bis(2-Chloroethoxy)Bethane 2,4-Oichloropheno1 Benzoic acid 1,2,4-Tr ichlorobenzene Naphthalene

4-Chloroanil ine Hexachlorobutadiene 4-Chloro-3-aethylphenol

2-nethyInaphthaiene Hexachlorocyclopentadiene

2,4,6-Trichlorophenol

Laboral

I n i t i a l

.05 naxiai

^ RF

.98298 1.07713 1.33288 1.46853

1.20870 1.05901 1.77435 2.09731 1.91592 2.10775

1.53191 1.62313 1.72812 1.98553 1.53645 1.67947

1.59638 1.74128 1.50836 1.70110

.98128 .90205 3.17293 3.92289 1.40687 1.50940 .64854 .78328

1.32049 1.47048 1.45949 1.45846

.«768 .49597

.19314 .17693

.70970 .92727

.24546 .23714

.37244 .37652

.57280 .60595

.32358 .29288 .22193 .17167

.34818 .35212 1.00505 1.23434

.42787 .28894

.16940 .17731

.38424 .33225

.03322 .03710

.10647 .11242

.37824 .34626

RF - Response Factor froa dai ly standard f i !

I t ion Da

15:36

tory ID:

1 Cal ibr,

ja % Dif

W i f f 1

9.58 10.18 12.38 18.20

10.01 5.95

14.90 9.31 9.08

12.78 8.87

23.64

7.29 20.78 11.35

.07 8.37 8.39

30.66 3.39

1.09 5.79

9.49 22.64

1.13

22.81 32.47 4.67

13.53 11.67

5.59

8.46

le at '

te : 07/12/89

>C3872

i t ion Date: 07/06/89

f for CCC is 25»

CCCSWX

f

•

ff«

t

•

t

t

t l

•

50.00 UG/lt

RF - Average Response Factor froa I n i t i a l Cal ibrat ion Fora UI

ttiff - X Difference froa or ig inal average or i

CCC - Cal ibrat ion Check Coi

curve

opouids (•) SPCC - Sy stea Perforaance Check Co

?0

o o

(Jl

Fora UII Page 1 of 3 - ? 2

Continuing Calibration Check HSL Coapounds

Case No: Calibration Date: 07/12/89

Contractor: INDUSTRIAL CORROSION Tiae:

Contract No: fWNAGEf€NT

Instruaent ID: 3C

niniaua RF for SPCC is

Coapound

2,4,5-Tr ichlorophenoI 2-Fluorobiphenyl 2-ChIoronaphthalene 2-NitroaniIine Acenaphthylene Oiaethylphthalate 2,6-Oinitrotoluene 3-Nitroaniline Acenaphthene 2,4-OinitrophenoI Oibenzofuran 4-Nitrophenol 2,4-Oinitrotoluene Fluorene 4-Chtorophenyl-phenylether Oiethylphthalate 4-Hitroaniline 2,4,6-Tr ibroaopheno1 4,6-0initro-2-aethyIphenol N-Nitrosodiphenylaaine (1) Azobenzen« 4-6roBophenyl-phenyIether Hexachlorobenzene Pentachlorophanol Phenanthrene Anthracene Oi-n-butylphthalate Fluoranthene Benzidine Pyrene Terphenyl-dl4 Butylbenzylphthalate

15:36

Laboratory 10: >C?8.''2

Initial Calibration Date: 07/06.^9

.05 naxiaua % Diff for U X is 25%

RF RF

.41232 .34302

.88817 1.02201 1.13991 1.23999 .48741 .38677 1.56850 1.83989 1.26660 1.28964 .35624 .30427 .39422 .16319 1.11988 1.22850 .21851 .07712 1.56717 1.57306 .14317 .08535 .51829 .34026

1.20023 1.18013 .60040 .58118

1.09277 1.14924 .36491 .07885 .12017 .16711 .11320 .15439 .51479 .56692 .87567 1.25955 .20821 .27814 .23545 .33348 .17104 .14971 1.01468 1.21454 .96963 1.15888 1.24338 1.44964 1.28456 l.mOI .00801 .00581

1.43285 2.00195 .96534 1,18151 .90207 .89082

\Diff CCC SPCC

16.81 15.07 8.78

20.65 17.30 1.82 14.59 58.60 9.70 •

64.71 " .38

52.30 •• 34.35 1.67 3.21 5.17 . 78.39 39.86 36.39 9.55 • 43.84 29.74 41.64 12.47 • 19.70 19.52 16.59 7.77 • 27.48 39.72 22.39 1.25

RF - Response Factor froa daily standard f i l e at 50.00 UG/ll

RF - Average Response Factor froa In i t ia l Calibration Fora Ut

ttiff - X Difference froa original average or curve

CCC - Calibration Check Coapounds (*) SPCC - Systea Perforaance Check CoqMxmds (••)

Fora UII Page 2 of 3 1 2 3

w

o o

(Jl •Co

Continuing Calibration Check HSL Coapounds

Case No:

Contractor: IWXJSTRIAL CORROSION

Contract No: MAW^nENT

Instruaent ID: 3C


Tiae: 15:36

Laboratory ID: >C3872

Initial Calibration Date: 07/06/89

niniaua RF for SPCC is .05 naxiaua % Diff for CCC is 25«

Coapound

Senzo(a)anthracene 3,3'-OichIorobenzidine Chrysene bis(2-Ethylhexyl)phthaIate Oi-n-octylphthalate Benzo(b)fluoranthene 8enzo(k)fluoranthene Benzo(a)pyrene Indenod,2,3-cd )pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene

RF RF

1.32516 1.29184 .43549 .25511

1.16247 1.26203 1.19107 1.21479 2.46779 2.83390 1.96578 1.60351 1.47693 1.60351 1.47733 1.51778

.88323 1.19545

.90015 1.08384

.83663 1.21859

»Dif f CCC SPCC

2.51 41.42

8.56 1.99

14.84 • 18.43 8.57 2.74 •

35.35 20.41 45.65

RF - Response Factor froa daily standard file at 50.00 UG/HL

RF - Average Response Factor froa Initial Calibration Fora UI

ttiff - I Difference froa original average or curve

CCC - Calibration Check Coapounds (*) SPCC - Systea Perforaance Check Coapounds (**)

Fora UII Page 3 of 3

1 24

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•i . l 'J2 P .y . i t c - LO R;.. li(J:; Ip l - i , N-.i O?'*?,!

2 0 1 - 2 3 4 - 0 2 3 0 A u M U - t 1 , 1 9 S 9

NJ CEP CI-:-,- t. i f i e d D r i n k ;in<3 Ua t t r / U r i r t €=ua t e r L i b c r n i - y y I D * I ' V l l i y (J S E P A C o n t r ;3, : t L 31) o i- ;3 t. o T- y •

QUALITY ASSURANCE DATA - SPIKE rECQ'-'EiR lE'S

F o f • i . ; i i i l i : . - l . ; ;S i

.L03-13S 1 0 3 - 4 3 9 103-44'0 103-44.1 1 0 3 - 4 4 2 1 0 3 4 , 1 3

M a t r i x t y p e : WATER

P a r a m e t e r L a b

N u m b e r R e ^ i u l t

P.v,tr-o l e u m H y d r o c a r b o TI BLK S P U

Amount AcJded mg/ 1

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C ( . ' p y r i 9 h t I C M , I n c . , 1 9 8 7 . A l l r i g h t s r e s e r v e d ,

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DATE SPLD

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SAMPUNQ POINT « SAMPUNG METHOD DESCRIPTION SAMPLE MATERIAL ANALYSIS REMARKS

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Abba/e, Oanial

Baron, Nary

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Blank, Robert

Cariati, Edwina

Cowell, Kristin

Crotty, Michael

Eberly, Daniel

Gbebreyesus, Habteab

Harvey, Sarab

Heller, Sbaron

Hof. Philip

Holt, Sodica

Jercsynski, Hallna

Kadakla, Geeta

Koleno, Panla

Kusterer, Jeanat

Luo, Snyl

Mancuso, Thoaas

Martines, Jose

McElbenny, Colleea

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Norscb, Cathie

Norton, Kiaberly

Peters, Catherine

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Rel, Anabela

Riccio, Mark

Richardson, Susan

Ridings, Audrey

Rlngwelski, Ewa

Roberts, S. David

Santana, Illnaiaada

Sarsoay, Keaneth

Strojnowska, Isabtlli

Thorp, Carla

Wachal, Best!

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Selengut, Jeffrey

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NAME

Maedel, Lynne

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Otey, Margo vt)a\QO O ^ g J U

INITIALS

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m NJ DEP Certified Drinking Water/Wastewater Laboratory ID# U116


DATE RECEIPT/REFRIGERATION ?>\\^W*=\

DATE SAMPLED aWSN*^*^

LAB # Q ^ / ^

GC/MS:

Ex t r ac t i ons : Acids

Base/Neutrals 3 > \ n \ ^ * ^

Analys i s : Vo la t i l e s a»V^\HS

Acids

Base/Neutrals ? , \ ^ \ \ ^ * ^

GC: Extractions:

Pesticide/PCB Analysis:

Pesticide/PCB

Volatiles


Extractions: f ^ \ n H ^

Analysis: ^V^^NÔt

PRESERVATIVE j I r t j i , A . , i ^ r / h / ^ ^ ^ . ^


(Signature) 25253^sigw3L-


(Signature)

ATOMIC ABSORPTION:

Metals:

Mercury:

GENERAL ANALYTICAL:

Cyanide:

Phenol:

OTHER ANALYSIS:

V>Vl ?>\N?SW 1 3

Section Supervisor ~^. -Review & Approval: *U«<Jt^<£^

(Signature) "*"


(Signature)

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(Signature)

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NJ DEP C e r t i f i e d Dr inking Water /Wastewater L a b o r a t o r y IDl 14116


DATE RECEIPT/REFRIGERATION ^^\c^\^C\

DATE SAMPLED ?>\\fe.N\<H .

GC/MS:

Extractions: Acids

Base/Neutrals 3|v^\^<\

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Acids

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Pesticide/PCB

Volatiles


Extractions:

Analysis:

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ATOMIC ABSORPTION;

Metals:

Mercury;

GENERAL ANALYTICAL:

Cyanide:

Phenol:

OTHER ANALYSIS:

LAB # 99ivî

PRESERVATIVE l i r t ^ i l o y ^ O l i ^ H ^ H,<7\^

Section Supervisor Review & Approval: 2te&


(Signature)


(Signature) '^^


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1 4 Final Approval : ' ' ^ ^ r y n \Jf*'


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E NJ DEP Certified Drinking Water/Wastewater Laboratory ID# IA116


DATE RECEIPT/REFRIGERATION ?v\\S\*^*^ LAB # ^ Q i 3 ^ 0

DATE SAMPLED

GC/MS:

Extractions: Acids

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Extractions: Pesticide/PCB


Volatiles


Extractions: ?N\nNflL<H

Analysis:

ATOMIC ABSORPTION:

Metals:

Mercury:

GENERAL ANALYTICAL:

Cyanide:

Phenol:

OTHER ANALYSIS:

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Final Approval: (

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(Signature)

(Signature)

(Signature)

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7 f? .lty Assurance Coordinj

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DATE RECEIPT/REFRIGERATION >>\\'r>\9>^

DATE SAMPLED ?^\\«h\'^^

GC/MS:

GC: Extractions:

Pestlcide/PCB Analysis:

Pesticide/PCB

Volatiles

GENERAL ANALYTICAL:

LAB # qsi53>

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Extractions: Acids

Base/Neutrals

Analysis: Volatiles

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ATOMIC ABSORPTION:

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(Signature)

- g în*l Approval: (Â/TVnO i l O ^

(Quality Assurance Coor

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u Jj NJ DEP Certified Drinking Water/Wastewater Laboratory ID# 14116


DATE RECEIPT/REFRIGERATION I^Nyg^VRq

DATE SAMPLED •?k\\c->\\.<=K

GC/MS:

Extractions: Acids

Base/Neutrals ?^\r)\^°\

Analysis: Volatiles

Acids ?>^^'!^q

Base/Neutrals "?.^?>>\%t^

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Pesticide/PCB

Volatiles


Extractions:

Analysis:

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ATOMIC ABSORPTION;

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GENERAL ANALYTICAL:

Cyanide:

Phenol:

OTHER ANALYSIS:

LAB # ^ ^ \ ? S ^

PRESERVATIVE I. UX^ i D C ^ i v f A ^y\^^


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Section Supervisor Review & Approval: eAn^tA

(Signature)

1 7



Final Approval: ( /

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(Signature)

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m NJ DEP Certified Drinking Water/Wastewater Laboratory IDl 14116


DATE RECEIPT/REFRIGERATION \\<;\<Kgi

DATE SAMPLED :^\\S\7k9

LAB # Q^<\\?iS

GC/MS:

Extractions: Acids

Base/Neutrals ?>\n\<r<^

Analysis:

Volatiles ^bvN^"'

Acids

Base/Neutrals '3>\'X\\' g)

GC: Extractions:

Pesticlde/PCB Analysis:

Pesticide/PCB

Volatiles


PRESERVATIVE U , ^ t . o AQ JULt-a _ H iXsLi


(SignatiAre)


(Signature)

Extractions: _

Analysis:

ATWaC ABSORPTION:

Metals:

Mercury:

GENERAL ANALYTICAL:

Cyanide:

Phenol:

OTHER ANALYSIS:

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Final Approval: (

(Signature)

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(Signature)

..J/h/naU«-' w Quality Assurance Coordinator

% r NJ DEP C e r t i f i e d Dr ink ing Water/Wastewater Labora to ry IDl 14116


DATE RECEIPT/REFRIGERATION 3 \ S S V & S

DATE SAMPLED ? ) ^ ^ S \ ^ ^

GC/MS:

E x t r a c t i o n s : Acids

Base/Neutrals

Ana lys i s : Vo la t i l e s ;^V^^\^°|

Acids

Base/Neutrals

GC: Extractions:

Pestlcide/PCB Analysis:

Pesticide/PCB

Volatiles


Extractions:

Analysis:

ATOMIC ABSORPTION:

Metals:

Mercury:

GENERAL ANALYTICAL:

Cyanide:

Phenol:

OTHER ANALYSIS:

LAB I 9S^^\o PRESERVATIVE






V w r t ^ i o ^ f ^ . t > f p ^

(Signature)

(Signature)

(Signature) »

(Signature)

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Final Approval

(Signature)

1 9 Quality Assurance Coordinator

i i . u u j i n m i - v ^ u n n u J i U . - l n n N f l O t f l t N T , I N C .

n S 2 Route 10 NJ DEP Certified Drinking Water/ Randolph, NJ 07869 Wastewater Laboratory l O t U l U 201-584-0330 USEPA Contract Laboratory


-Lab Nuabers: Q Q \ ? f V C^Q\>vi>.

Volatile Organics: Anaiyied j^ Not Analyzed

All tunes were run in required frequency. YesJ^ No

All tunc a/t ratios aet criteria. YesJ( No

All initial and/or continuing calibrations were run in required frequency. YesJ|[ No

All calibration SPCCs and CCCs act criteria. Yes A No

Surrogate recoveries act QC criteria. Yes ^ No

All aethod blanks aet contaaination criteria. Yes No

Ail saaples were analyzed within the required holding tiaes. Yes X No


Coaaents:

Seal-volatlIc Organics: Analyzed X Not Analyzed

All tuoes were run in required frequency. Yes X No.

All tune a/x ratios aet criteria. Yes y No

All initial and/or continuing calibrations were run in required frequency. Yes •^ No

All calibration SPCCs and CCCs aet criteria. Yes V No

Surrogate recoveries aet QC criteria. Yesji|![__ No

All aetbod blanks act contaaination criteria. Yes X No 15

All saaples were extracted and analyzed within the required holding tiaes. Yes JC No ^

o Other nonconforaances.

^ _ _ _ Ul

— — ^ Coaaents:

xo-

115.2 Route 10 Randolph, NJ 07869 201-S84-0330

NJ DEP Certified Drinking Water/ Wastewater Laboratory IDai*116 USEPA Contract Laboratory


Lab Nuabors : _ 9 9 - L 3 Q : L 9 ^ i 3 k

Pesticides/PCBs: Analyzed. Not Analyzed

All aetbod blanks set contaaination criteria. Yes No

All saaples were extracted and analyzed within the required holding tiaes. Yes No.


Coaaents:

Metals: Analyzed. Not Analyzed_iL

All aethod blanks aet contaaination criteria. Yes. No

All saaples were analyzed within the required holding tiaes. Yes No


Coaaents:

Petroleua Hydrocarbons: Analyzed. Not Analyzed.

All saaples were analysed within the required holding tiaes. Yes t . No


Coaaen ts : 50

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•y.y^-y~jmii 113^ Koucc iQ NJ OEP C e r t i f i e d D r i n k i n g W a t e r / i ? t i S ^ R a n d o l p h , NJ 07369 W a s t e w a l o r L a b o r a t o r y I D t l 4 l l 6 v|? 2 0 1 - 5 8 4 - 0 3 3 0 USEPA C o n t r a c t L a b o r a t o r y **


âb N u a b c r s : _ ^ V 2 Q z a ^ a 2 i A ^

General Cheaistry: Analyzed X Not Analyzed

All saaples were analyzed within the required holding tiaes. Yes )C No


Coaaents;

Genera 1:

All saaples were properly preserved in the field. Yes y No.

Coaaents:.

A d d i t i o n a l C o a a e n t s ;

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furggafcjgg (CC/HS?

MATRIX: Water

METHOD REFERENCE: Code of Federal Regulations 40, Part 136, Appendix A, Method 624.

METHOD SUMMARY: Heliua Is bubbled through a S al water saaple contained in specially designed purging chaaber for 11 Bla. at aabient teaperature. The purgeables are transferred froa the aqueous to the vapor phase and passed through a 3 coaponeat trap (OV-1, Tenax and silica gel) where they are absorbed. After purging is coaplete, the trap is heated and backflushed with heliua to desorb the purgeables onto a gss chroaato-graphic coluan. The chroaatograph is teaperature prograaaed (3 ain. at 4S degrees C, then raap to 220 degrees C at 8 degrees/ain.; final hold 12ala.) to separate the purgeables which are thea detected with the aass spectroaeter. The aass spectroaeter dtjta systea (RTE-6) identifies target coapouads thatlaeflt the criteria of reteatloa tiae (-•SO sec), relative abundance of characteristic aasses (-*20X), and' aazlaisation of characteristic aasses wlthla 1 scan of each other. Other coapouads detected can be searched by the data systea ia its EPA/NIH library of 42000« coapoaads.

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HATRIX: Hater

HETHOO REFSSEMCE: Code of Federal Regulations 'Ô, Part 136, Appeodis A, Hethod 62S.

METHOD SUHMSY: A Deasured voluQe of saeple, approziaately 1 litsr, is serially estractsd v;ith setbylene chloride at a pH greater than 11 and again at pH less than 3 asiag a ssparatory funnel. The oethylene chloride estract is drisd, concentrated to a voluEie of 1.0 al and analysed by CC/HS. The gas chroaatograph t ith 30 n . SPB-S capillary coluan, is prograaaed at 30 degrees C (1 Qia.) to 60 degrees C at 30 degrees C/@ia., then to 300 degrees C at & degrees C/iin, uith a final bold of 24 Qia. The Q S S S spectroaeter data systeQ (BTE-6) identifies target coapouads that oest the criteria of retention tioe (-«30 s e c ) , relative abundance of 3 characteristic Basses (-*20S,of u standard spectra), aad QasiQisation of , i. characteristic Basses uithin 1 scan of each'ôthspT ; Other conpounds detected can b® searched ^y, tbe'da^ta systeo ia its BPA/t4!H library of 42000« coopouads.-Quantitative analysis is perforaed osiag intersai standard tecbaigues trith a single characteristic n/s.

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HATRIX: Water

METHOD REFERENCE: U.S. EPA Methods for cheaical Analysis of âter and Hastes, 1983 Spectrophotooetric Infrared Hethod 418.1

NETHOO SUnnASY: The saaple bottle is oarbed at the uater aeniscus for later detoraination of voluae. The saaple is poured in a 2000 Ql separatory funnel. The saople bottl@ is rins tilth 30 ol of fluorocarbon-113 uhich is thea addsd to the saople in the separatory funnel.- The faasQl is shaben for 10 ainutes and the solvoat lays? filtered through a funnel containing solveat-ooistenod fliter "-paper into a 100 ol voluaetric flasCi. The saople is estracted tuice oors uith 30 ol of fresh solvent cpobia ing all extracts ia the voluaetric flasb. ¥h@ extract diluted to 100 ol. 3 g. of silica gel is added andr stirred for S ainutes. Quaatitatioa is perforaed esisg aa infrared spectrophotoaeter. Appropriate dilutioao are aade if tha estract eoaceatratioa is greater thaa 4Qg/100ol.

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MATRIX: Water

« ™ D REFERENCE: Standard Method, u t h Editiun. Methud 423

MKTHOO .-JaNMARY: Following st.,nd.>rdiza11on of the pH aeter, the

dry " L l c / a ^ r ; " " ' ' ' ' ^ ' " ^ ' ^ ^ " « ' - ="><! blottod dry Saaples are brought to rooa teaperature, the c c redo IS le.orêd in the solution, and wh „ equilibriua i= established, the pH is read

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1.28S55 2,28295 Z. iK^t 2.957.3 l.iK1385

!.27Sn M 5 ) 3 : \ . W M 1.0*083 .95^70

7.06632 2.5728E 3.35138 ISXJH 2.fl^S9

1.20850 .80287 .e?-:5J .71731 .59789

5.18335 S.33C59 t6JIH31.8M)8 1.26896

1.J216S 3.85865 3.5i513 3.158S3 3.0G178

3.95K6 3.69333 5.2S»72 3.31612 3.80803

).37231 1.78238 1.615811.S3129 1.1)111

5.88669 1.192821.39?^ 1.892S3 h i i m

5.11295 1.21571 l . ^ ' ' l 3.9K91 3.2913S

1.60916 3,65590 3.17957 3.38115 3.06361

.863« .31158 .SrW .03978 .01021

.98691 .96851 .85733 .86569 .78110

,98301 .916Si .35755 .36916 .77730 ,69511 ,55821 ,53398 .SHIS .50728

.92868 .77785 ,71231 .77218 .72395

,11762 .38193 .iSi97 .27178 .5121

.87261 .81308 .77»7: .78610 .TT/t t

,56721 .15162 .12521 .1IW3 .37329

,68689 ,53699 ,5!S1* .53118 .52111

.36761 ,28929 ,::»!? .28185 .262%

1,26221 1.M281 l.«7211.06921 I,a2$j7

.13928 . W 5 7 .11713 .12M8 .18638

.19878 .15281 . ! « » : . ! « » .13317

.61187 .1380 ,13^7 .17102 .11536

. S e S .3K99 .7.611 , i 3 e 6 ,30631

. m a .28286 .2663 .2nS6 ,21326 : . % m .19871 .1^553 .11651 ,3713

W l 8?

,220 1.91813 .327 .57575

.105 2.89736

.523 1.09768

.725 3.67811

,888 .88133

.867 1.92751

.972 3,58291

1.079 3.15721

l . m 1.66265

1.1831.29826 1.250 1,39011

1.211 3.57851

.515 .01522

.727 .98115

.711 . m i l

.7SS .56788

.761 .78710

.827 .38569

.836 ,fl)12S

.862 .15281

.881 .55988

.891 .2961?

.S89».'1113

.89: .12713

. m .15569

1.882 .17983

. m .3K39

.901 ,31157

.y i2 ,«251

IliSS

8.431

5.156

8.691

51.951

52.138

29.589

9.318 11.711

18.SS

13.652

12.318

16.552

17.281 28.118

8.815

3.687

12.968 9.871

9.136

5.572

15.135

12.373 13.911

8.325

3.686

16.211

15.68t

31.256 23.116

55.591

CCt Sri::

8f - ixs^m:fkiJar . i ixbiaif i if aneont in p;?-

i r - Averaj! i t l i i i v t it\aii<m I im (Vl Stii '?! Uii)

tf - Dvtrage h ^ s a i factar

UtSS - 7«rc«r.t JtldtiM 5iatard 8a<.natia)

CCC - Calibration Cktck Ca«Nn6s (») SPK - Syi tw Perfornance Chtci; Canpooids <» )

f m n H Tage 1 8f 2

9 6

I o

y * O l

h i t i a l 'Cahlif3:.i» D-a'a HSl Catpcvr.^

CaxD::

Coniracta-: "fSI I.-iC.

ContriKt DP:

I s s t rwwt 18: 2

r - , ' ; K r i t i . , IV..,. r.I.Tfi.«q

'.'•--bi Z -y, 'y ' '1 .

•-z.yryii

ryytf?.

r . v n t m Sr fw SPCC i s .30 !!ar.n.jn I i!S8 for CCC i s JS2

Laboratory 10: >85«3 >85579 )K980 )8S981 >853S2 ff if Rf Rf 8f _ _

CwjHJWiiJ 20.08 58.88 100.38 158.88 286.!KJ MT 8f : K 2 CCC S?:C

1 . ! .2 .2 - I« t rach ior» lhan« .68501 .11633 .12707 .13881 .12663 .987 .18177 22.551 loiuene-dS 1.613351.£0887 1.37875 5,31155 1.13583 .956 5.11287 12,375 Io l«M .91238 ,86122 ,77877 .77213 .69528 .962 .85181 51.9:3 •

'ChlsrofcaszKW 5.15153 !.18851 1.31523 .53321 .31861 l.»11.31813 11.SK *» CthvlfceniHt 2,35211 2,11695 2,18565 1,93621 1.75319 1.889 2.K889 11.569 » Styrant 1.39587 1.28139 1,13031 1,10616 1,81708 1,263 1.17676 11.159 lotal Xylenes 2.28372 1.98831 1.88219 1.75618 1.56503 1.J15 1.871S5 i;.»7S Br-awfliBrobfc-erie 1.11122 .95726 .90573 .81681 .79681 1.1S3 .52157 13.163 Scroleis . . . . . . . . feryljRitrile . . . . . . . . iHhthlc-ratecaw - - -9«p-3lcl>l5ri)benia)*s . . . . . . . .

(Csnc*28C. (t8K<88, 8.S

j ^

•"ays', -• -- .,..,

-my^y- ' •• yy?'-•^X'lzy'. 'fi - ^T... ' -

W - !««sn»-racti)ri<Stii)Kriptisaneasi inppb)

• ':y -yi \ _ ->. ;

m - 3v«rase Relat ive Retffltim h n t iV. St<S/R? I s td )

Rf - !!vera;e Respsise f ae t t r

1858 - Pe r : s i t Relat ive Stacdvd e » i a t i s s

CCC - Caiicrat ioa Chetk Conpeiadi (•) 5KC - Syiien Ferforaance Check

farn.VI h g t 2 ol 2 9 7

{ « ;

CauKs:

Coritnottr: ICR I-.c.

btf.'tL, O b i nw.

T _ . l . , ^ „ . Tn. Vt

Cahintisfi fete: 33.-'2!/«9

Tir*: 16:18

.li.-.jiwRf forSPCCis.}! inXlnun « i/tn i5r L*. i J 4j«

Cjn^sund

C,M3rsn«t!',3i» Srononetiwie Vinyl CMsriiie CMcTGetl-A-te Itethylaw CMwiiie 8ceia» Carbcr, Oisuifiiie l,1-0ichloroether,e l . l -Dic.ysTMt' iafa Toial-1,2-03cMorsei'iem CMwofom Lr-Oiehla-oetJane

1 . :-3;r i t lcrMiiaf ie-d1 2 - ia ia imt l.l.l-Tnchlsraeti'ans Carbor, TetratUsrliie Uinyl Dcitate SroiwiicbloraiitthaAe 1,2-Bichlcr8|»'tpa>')e Trai»-1,3-8icfcIorapr3peia Ir:cj)li)r»th«M SisronscMcraKthaH

l.l.Z-InchisrsetlaM 8in»J»

tii-1,3-8j:hlori>pr:(inc 2-Chli>r9«it)ylvi»yletl»r Sronsfsn

1-fl»ti)vl-2-F»tffl«t- ,

Z-SaxanoBe • • • V - . ' ' " • '

Ie t ra th l i r« t t^ i f ; t -«?^- -I j .2 .2-T8i i ; i^^ ia»k; ' \ o l m H S . . ^ . ^ f y C y ,

Rf Rf

!,95313 2,28861 . r f t f t 1.18532

2,39726 2.35985 5.S9768 1.21S)5 3.67815 2.S1238 .»)138 .32319

1.92751 1.71899 3.58291 1.81369 3.157:^ 2.6316:

1.66:^ 1.51985 1.29826 1.85181 1.5%}1 5.85886 3.57851 1.52218 .31523 .81851 .58115 5.31823 .88887 1.31776 .567n .53817 .78718 .52111 . ^ 9 .28881 .«I125 .85(37 .15281 .19055

.55508 .62669 .2«17 .3817?.

l . n i C 1.12992

.irm .««

.15569 .19671 ,17!S .57155 iSSBi .12857

. • J « 7 " . i C 1 9

: y m .51321 :i'^1«?7 .f7396

f.i lST 1.17360

:D-.ff cccspcc

IS.88 ** 26.18 1,21 •

13.13 23.51 2.28 1.23

12.19 • 6.37 «

8,59 13.39 » 23,66 26.11 7.25

12,55 15,51 3.95

17.37 .81 •

6.53 3.33

12.11 2.85 1.3?

8.7E

22.51 19.71 *•

16.21

8.58 i : . i :

2.23 « 1.26

(Co«->50,08)

«'. .' 4 "•

(C(mc<'53.80)

Rf - Response factor frtn oaily standard file at 58.1)8 ppb

Rf - Rveraje Re^KKse factsr frtn Liitial Cdliaratlsn f im ill

Shff - ! ihffs-ence frait onjiaiS K t r ^ ^ or carve

CCC - Calitratis-. Check Cai^tsndi <>! SKI - Systen Pa-fsmanct Qtacii Caôwds ( « )

fom lai taj! U f 2

98

I O i o

o

I

VV,.^...S,*,ll^ VU..1WI . ] , . < , ' , (.,,ffCll

KSi. Cunpu'.T.-ii

Cass He: Caiiisrat-.on 5at j : •32.'25.''85

Cwt r j c ta - : IC!IJnc. I i w : ! i :18

C;,-,t,-sc'. Its: CatoratDry ID: >Btti5

Ir.5t7ijia.-,t IS: 28 I n i t i a l CaiitratiiW Sate: 32/20/85

!5:r,iri»i « for SPCC is , 2 I1a««« I Siff for CCC js 25)1

Conpsui-id Rf Rf lO l f f CCCSPCC

Toluer,8 ,35185 .75151 2.33 • a i j r s b e r u H a 5.01813 1.82313 1.50 » Ct.".vlta.i:tr* 2.06385 2.23328 15,53 » Styrene 1.17676 1.25651 6.81 Total Xylenes !.87555 2,17561 55.75

B r a w f l u c r s i w j e M .52157 5.01837 53.36 <Corf--53.B0)

Iteroleia - - - <Cone»5SB.80>

Bc -v l cn i t r i l e - - - (Consul 008. OO.i ii-3ic''.lorsbei«er<e . . . <C5nt'508,aO) c«p-3icMerofcenjsne3 - - - (Cone-100. W )

Rf - Res CRse factsr f r a i da l ly standard f i l e at 58,33 ppb

y - ^ z : ^ z m

ry-.i

i Rf - Rverafe Respcnse factar fron I n i t i a l Cali i iration f o m 81 o I o

SStff - I Siffs-encs f ron s r i s ina ! average or n r v e

CCC - Calibration Check Conftounds («) SPC£ * Systen Perfomance Check Caôunds (*•>

f o r n V I I Pase 2 o f 2

99

0^ i l »

^ • i inds Iph . MJ 0 7-369 -.>l-3.= -1-;-33'D / A / 8 9 ''

NJ DCP Certified Drinking U a t e r / U a s t e u a ^ ^ Labor 3lor-y I D * .14114 "' ^

l.JBRARir SEARCH RESULTS OF NONTARGETED PEAKS UITH ESrr,'Â7£.P CCi.'^CEWTÂriClN OF TENTATIVELY IDENTIFIES COMPOUNDS,

• ' yy

a t a f i l e ncime: >iC3137

T a c t i o n ; B a s e / N e u t r a l

,-130 T h j i BLANK c o r r e s p o n d s to t h e f o l l o u i n g l a b nu:r>bers:

>913i 99132 99133 99134 99135

* » ; •

Scan \'iiirber CAS No

ftetentio n Time

Compound Name

MolecuIar Ueisht

Est imated Co ncentra t io n

ug/1

None Found

Indic:at5s that the compound is an acetone based aldol-type condensation produc fsrxijd by CO ncentrat iJ!3 t, e extraction- solvent (li 1 aceto ne/inethylene._chip ridt Indicates that th© analyte was found in the blank as uell as t_hei.,same;ie..jvllt farthfjr indicates possible/probsble blank contamination. 1-ft s^.yy

'Wf ' -'s^tf.-y.y

• cpyright ICH, I n c , 1986. All rights reserved.

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Sample Numbers *Wl3C,«Wft/^ t t . 7 ^ <>^/33, T/^«f/y/aX"^ f/-^V^^T/^^^

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5T/5 7

103

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F i l e ; > C ? 1 3 ' ? S c a n * : 441 P a t n . t i m e : 1 3 . 8 7

m/z In t . m y z I r . t m*'z I n t . m-'z I r . t . r » / r i n t -

39.3 0 5 0. Ou 93 .IJO 92.00 54.20 56.00 57.00 62.0 J 63.no 6 5 . 6 9 . 7 4 . 7 9 . 7 6 . 7 7 .

7a.

1 0 0 0 OiJ f lO 1 0 110

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3 . 6 4 2 l J . 8 3 1 ) 4 3 . 8 3 9

2 . 8 8 8 . 3 9 4 .

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7.400 3.08 4

611 002 970

2.970 3.642 1 . 2 1 4

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Case No:

C o n t r a c t o r : iNCOSTRJflL C.-^CSiOH

Cantracf Nc: tWW^rtMT

Initrunent IP: 3C

Catibration Date: O'/tJ-'S?

- ' I C

ainiBUB Rf far £KX is .CS r^-visu* X RSO for CCC IS JfiS

Labor.itory 10:

Coepound

N-NttrosodiMV,yl«aine 2-Flucropher.ot A r . i l iM Pherjol-<14 PhenoS 2-Chtoraph9nol bis(2-Chloroethyl)ether 1,3-Oichlorobenzene 1,4-Ojchlorobenierie 1,2-Cichlorobenzene Benzyl alcohol bis(2-Chloroisopropyl)ether 2-nethylpheflol Hexecti loroethane H-ri J t roso-d 1 -n-propy! am i ne 4-netttylphenol Nitrobenzene-dS Nl trobenzene Isophorone 2 - N i t r o ^ n o l 2,4-0iaethylph8nol bis(2-CMoroethQiry)Mth9ne 2,4-UicMorophenoi Benzoic t c i d 1,2,4-Trichloroben?sne

Naphthalene 4-Chloroan:l ine H»xacM orobut a l 1 ene

4-0»loro-J-«thylphenol 2-nethy lMphthalena/v>V . ;v;;

i >C2?S1 >C79/7 >C?V78 » Rf Rf

23.011 50.eo ao.oo

.S(27«8 .82.-71 .ir.'43»

>C2'*?9 Rf

12fl.ua

.8249?

>i:29t!u Rf

160.UII

.80271 1.J2177 1,J695-' l . J : m 1.32446 1.296'!4

1.^6018 1.5(1729 1.44S9J 1.6961? l . t59?i ' 1.83294 1.8909i 1.79fc78 l..'3'J28 1.54766 1.80298 1.72846 1.56526 l . ' f l l95 1.36259 1.53922 1.49044 1.JW05 1.2?':3U i.Odais 1.40963 1.50729 1.57114 1.69617 1.65972 1.74243 1.67885 1.57846 1.52^46 1.45715

1.75606 1.66232 1.54,->97 1.498W 1.39660

1.77J51 1.65583 1.55352 1.52718 1.43514 1.00459 .98251 .96540 1.31905 ,94866 2.16153 1.90669 2.03822 2.13517 2.07877 1.32792 1.27792 1.17713 1.173«8 1.1!.^38

.75317 .76576 .70374 .68154

1.28681 1.23895 1.12310 1.24428 1.44819 1.39038 1.27758 .44066 .43192 .43176

.23763 .22535 .21581

.88513 .84852 .&i844

.26484 .25470 .25488

.36133 .372-rt .56r/4

.52442 .49394 .48879

.59*63 .36541 .'6247

.25610 .29420 .2e926

.43U8 .41105 .594V4

1.1SH72 1.07678 l . t U t i .50.^6 .47647 .464!-:< .24288 .22614 .21412 .42.MI .48AA8 .!yp>»

•^<i7»29 .73349 .68109

'''--'.'.-; -,' -'' 9f ' Reapnnse Fac^tirJlSi|i icnpt^ri> aaount tn Usvn.)

,63883 ,75198

1.23180 1.14459 .43457

.20264

.iM7'/8

.26371

.*85W

.48957

.35y?6

.32^59

.:8886

.91357

.4.'124

.•M}i f

.^97/6

.64765

RRT - A-.-erage Pelat iyefPl t ln t ion: T i ie (KT SXtAll Istd)

.41110

.19537

.802*-5 ,24360 .36531 .45847

.54366

.30794

.?6?"2

.91692

.426-44

.18771

.5 5 7 !

.63540

W l «tF

.316 ,821"»2

.674 1.32668

.943 1.57446

.951 1.75973

.954 1.59219

.9'<5 1.32634

.VJ2 1.56879

.99y 1.59567 1.0115 1,57239 1.054 1.58901) l.'J64 .938>4

l . l «5 2.S5768 1.707 1.207:5

l.l.'*5 .70861 1.149 i . r m 3

1.152 1.29H49 .864 ,43031)

.821 ,21488

.922 .H4480

.952 .25617

.958 .37008

.975 .4894C

.984 ,36583

1.015 ,29462 .994 .;"»9«7

1.005 1.03443 l.BJfl . i«9:6 1.047 ,21487 1,13« .39788

1.147 ,69756

% Pb.) Cl t

1.5)5 1.997

6.551

7.507 11.-^s? •

14.297 7.58n

7.191 8.921 •

8.162 2.54^

4.998 a.Btr

7.359 19.4i')» 9.387 2,596

8.195 5.47t

3.3*3 * 2.26? 4.876 4.9»2 ^ 8.756

5.!«2 l8.9i!!J 4,19V

9.816 • 4.5*1 •

18.459

SPir

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tfSO - Percent Kel«ti</e Star^rd £'<uiaticn

CCC - Calibration Clecit Csipnwids (*^ SMI - S<jst«a Ptrfiirrance Check Caa aun.1s ('*)

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In i t ia l Calibration Ota HS. fonpouncs

CaM No:

Contractor: !t«(J£TRl«. C'lRRiBlUi

•.:antract fte: n f t ' * ! ^ N f

Instruaent 10: 3C

CalibreMon aue: 0.'/24/8''

r * •

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i Laboratory 11): >L29S1 >U'2977 >L7* '8 >C297«» >C,;98I! M

Coixpound

Heyachlorocyclopentadiene ' 2,4,6-Tr icMorophenol

2,4,5-Trichlaropher.ol 2-Fluorobiphenyl

' 2-Chloronaphthalene 2-Ni t roani l in« Acenaphthylene

Oiaethylphthalate 2,6-UinitrotDluene 3-NitroaniItne flcenaphthar«

2,4-Oinitrophenol Oibenzofuran

J 4-Nitrophano: [j 2,4-0ini t rotaluen«

4-'iIhlorophenyl-pnfnylat.^«r

1 ^ Oiethylphthalate B 4-Ni t roani l ine ^ ^ 2,4,6-Tr Ibroaopheno I

4,6--Oinitro-2-nethy:phenil N-Nitrosedip»enytaistne (1)

ftzobenrene 4-8roaaphenyl-phenu|ether

Heiaehlornbenzerie Pentachlorophenol (^^nanthrene

Anthracene Ui-n-tuitylpNthalate

Fluoranthar^ . ^ <.:;><>

Bf Rf Rf Rf Rf 20.00 50,08 30.!!8 IV!!. 80 160. nO

.15515 .26712 .26B11 .2«9tt2 .26592

.48628 .46500 .45027 .4505? .41194

.53425 .50907 .«9V)4 ,-6944 .4 l l ' '4

1.35178 .98795 ,93390 .91785 .84059 1.37465 1.2V562 1.2!!l39 \ . \ n - f i I.f59'i8

.46985 .46651 .46159 .45785 .44693 2.84761 1.96555 l.84«fl9 l . ; 5 f i : i 1.57406

1.78122 1.68931 1.63505 1.57271 1.47^64 .42506 .45265 .42078 .419^3 .39106 .44,'96 .41882 .37850 .57576 .55813

1.36454 1.21510 1.0V863 1.85267 .96365

.24028 .29318 .51583 .33215 .31666 1.94848 1.80862 1,70686 1.68228 1.5549/

.26038 .27848 .25793 .24682 .23488

.62785 .62717 .60912 .6!?:04 .56452

1.56736 1.47987 1.37734 1.33574 1.22128 .73687 .67676 .63541 .422al .5,''443

1.84226 1.68144 1,55475 1.58474 1.41W8 .46561 .47286 .46884 .44573 .572'.8 .15264 ,14113 ,15893 ,14563 .14203 ,21644 .23499 .25517 .21567 .17528 .6399a ,59158 ,51250 .4=843 ,40290

1.52716 .97584 .9!y81 .24518 .73438 .25426 .23596 .23265 .23735 .23829 .29946 .28536 .2*778 .-JaiV) .2/^619 .20.'45 .21601 .205IW .21537 .21526

1.36911 1.23'>51 1.18/60 l . lV j ^ v 1,15'2S7 l.)?88« 1.29824 1.20223 1.1*722 l . l ? r . 2 1.9S9S2 V.W95 1,64559 l . ^ l t f t } l .J^87l

,4.«288J41§56854 1.43553 1.46530 1,31467

m yf

.878 .24866

.893 .45243

.897 .43341

.906 .946-25 ,915 l.r.U19

.942 .46030

.977 1.8J7IW

.980 1.62979 ,9(J8 .4177*

1.006 .39584 l.e:i6 1.15892

1.021 .29962 1.050 \ .?Ain i 1.041 .25554 1.845 .ia65!'

1.882 1.3'»632 1.387 ,64878 I.W9 1.6C841 I . I M .445fiS .919 .14437 .907 .21511 .939 .52CK4 .911 .9«BC?

,950 .23918 .964 ,28175

,988 .21198 1.503 1.227*4 1.839 1.22194

1,693 1,66)66

1.150 1.46.?37

% s^v CiC spcr;

21.5y7 »• 5.957 • 9.{:J6

8.3:7 9.725 1.936

10.!599

7.158 5.784 9.257

1J.6<7 *

12.005 • •> 8.467 < 6.4P9 ' • *

4.220 9.535 9.439

10,326 9,44Ji

3.723 11.171

18.418 • 12.7^2 3.969 4 . l e ;

2.314 t 6.974

4.38^ 14.168 7,542 •

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CCC - Calibration Ciecii Ccapoimds (») SHIl - Stiatea Perforaance Check Coapouni s t**)

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Case No:

Contractor: iNftJSfPIflL C-WJSICM

Contract Mo! : ' = M w i T t N f •: .

Instrunent 10: 3i:

Calibration Date: O.V'^4/8''

fliniiiwia Rf for ;SHCt: IS ,C'"' r,Ji'i\M» % SSD f.ir DC IS 3li!J

L^tjoratory

Coopounrt

>C29M1

2fl.3!l

>C2V77

Rf

50 . Oil

>C2979 RF

80.110

>C^ '9 ;N

Rf 120.RB

>C':v8!i Rf

160.^0 K«T ( f % m.\ DT !-Hcr

Benzidine .01476 .31390 .31294 .ni2fcy .01219 l.2'i4 .1)1330 7.7:6 P-yrena 1.88059 1.80207 1.73638 1.75o73 1.,'3474 ,825 1.78218 3.445 Terphar.yl-dl4 1.15827 1.12!!a5 1. ! !B418 1.0!?2!4 I.u5-'y2 .986 1.II9631 3.60-.' Butylbenrylpnthaiata 1.08237 1.08598 1.81138 1.00417 .98357 .960 1.03349 4.i.?4 Benzoia)anthr»ceae 1.66415 1.602116 1.577.'a 1.57^54 1.566^4 .999 1.59.'11 2.48'' 3,3*-0ichl3robenzidir.8 .59137 .578:'8 .56856 .53200 .43391 1,082 .55ia7 7.892 Chrysene 1.494^3 1.46H08 l . }9 i43 1.344l'# 1.-/65'9 1.083 l.?9314 6.67« bist2-Ethylhe-<y:)phth3late 1.58515 1.55B83 1.42499 1.38'-"23 1.32'»91 1.019 1.45482 7.452 Di-n-octylphthalate 5.1B!I51 5.17650 2.88556 2."0712 2,92119 .949 2.99774 4.399

eanrolb)fluoranthene 1.8935? 1.78683 1.95763 2.55256 2.72881 .9*3 2.18228 19.4.')5 tonzotklflucranthene 1.76410 1.74471 1.54735 1.15436 ?.,^ft81 .965 l..->8626 ^2.305 eenzotalpyrene 1.62880 1.60020 1.58646 1.637711.61194 .995 1.61382 1.299 lrdenotl,2,3-cdlpyrene 1.33910 1.35156 1.24442 ,65750 1.4165" 1.144 1.19783 26.649

Oir4nz(a,h)anthracene 1.25105 1,27507 1.28243 1.21613 1.16120 1,151 1.22118 3.609 benzo(g,h,i)perylene 1.28V05 1.5eSrt2 1.16428 l.r,'»l69 l.:i542*i 1.1«7 1.18746 8.954

T

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Rf Responi'a Farter,, (Suhwript.tVÔBnunt in %.Tt.)

Ai-eraoe Relattve'ReteiitionTiae^ ( K >»td.1?r Isti!)

C'.-eraga Respcnse factor

Percent Stel.it!'* Staniarj Ueviatis.-\

Cal'.brafion Check l>.af,««il« (•) SW - S-^ten Perfor»snce O'-eck C-^coads (•*)

fora ')[ Pv n 3 r-f ) 1 0 fl

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Continuing Catibratior. D-'ecii K>L Compounds

Caê tio:

Ccntracto.-: ItOlSTRIW. Cl»*iBia)

Contract Nn: R«l«iEfl£NT

Instrusant IC: 3C

CahbraMon C«l«: 0?'5;/^9

Tiae: l ' i : lA

Laboratory IC: >C51'6

I n i t i a l Cal i t raf ior , Cste: 05.'24,'8"?

riiniBUffl Rf for S W is .05

Coapaunrt Rf

RaxiHua !t Oiff for C X is 25S

RF ttiff O X SPCC

N-Nitrosodiaethylaaine 2-fluorophenol

A r i l i ne PhenoI-d6 P^.enol 2-Chlorophenol bis(2-Chloroethyl)ether

1,3-Oichlorobenzene 1,4-Oichtorobenzene 1,2-Dichlorobenzene Benzyl alcohol bi9(2-ChloroisRpropyl lether 2-nethylphenol Hexechloroethane N-Nitroso-di-n-propylaaine

Nitrobenzene-d5 Nitrobenzene Isophorone 2-Nitrophenol

2,4-Oiaathylphenol bis(2-Chloroathoxylaethane 2,4-Oichlorophenol

Benzoic acid 1,2,4-Trichlorobenzene

Naphthalene 4-Chloroanil ine

He«achIorobutadiene 4-Chloro-3-aethylph«nol

2-nethylnaphthalene . ' ; i i j ^ . ; ' Hexach lorocyc lopentaditimii l^.;

.82192 .25718 1.52668 1.52CS6 1.57446 1.43095 1.75975 l.,-^165 1.59219 1.67239

1.J2634 1.42514 1.56879 ,90234

1.59567 1,67829 1.57239 1,66613 1.589'JO 1.67508

.98804 ,81081 2.85768 1.55674 1.2072* 1,17955 ,78861 .76704

1.12903 1.09019 1.29849 1.26635

,43000 .42157 .21480 .23717

.84480 .81550

.2561? .23391

.37808 .35868

.48948 .47615

.36503 .34606

.29462 .13827

.39907 .48116 1.93440 1.12134

.46916 .36988

.21487 .22491

.39789 .3M92

yw7i f^7Am •«v24e66ft.l2M0

2,4,6-Tr ich lorophenoi^ | i ;^#- ;5^452/WS-- i^^

- . • y 7 f i ; ^ y z ^ ^ ' y y ; ^ i } y » . . yy$MM'i^- '< i^-y^ ' -^ -••- • -

RF - itesponse Factorjfr«M'.•tallyiitanCard f i l

68.71 .46

5.94 .46

5.84 •

7.45 42.48 5,18 5.96 • 5.42

18.02 24,34

2.29 8.25 3.44 • *

2.-48 1,96

19.42 3.47 8.69 •

3.98 2.71 5.19 •

53.97

.52 8.41

21.18 4.67 «

7.99 •

6.58 49.9'/ • * 2.99 •

le at 59.30 U6.

RF - A^'erage Response Factor froa Initial Caliwration Fora V!

Oiff • X Oiffer5nr.e frca anginal average or curve

CCC - Calibration Check Diapowds (*i SPCC - S^«tea Perforaance Oieck Coopnunds (**)

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Continuing Calibration Dêck HS. Coapounds

'Ja-ie tio:

Contractor: DOJSTPIAL CIKFOSION

Contract Ho: .rnNAttftNT

InjtfuMnl ID: iC

Calibration Cate: O.VJl.'Oy

Tiee: 10:16

Laboratory IC: )Cn?6

I n i t i a l Cj!:br-iHo.r Date: 0'/24/8V

"' z/'f'yy.

tliniiTJia Rf fcr SPCC is .05

Ca-apound Kf

ItiYiaua S Oiff for ClX is 2f*

Rf iCiff CCC s p a

2,4,5-Trichiorophenol 2-FluorobiphV7! 2-C')lor3naphtha!er.e 2-»iJro8r,ilir.e Acanaphthylere Oiaethylphthalate 2,6-Oinitretoluene 3-Nitroaniline Acenaphthene 2,4-Oinitrophenol Oibenzofuran 4-Nitrophenol 2,4-Oinitrotoluene Fluorene 4-Chlorophenyl-pnenylether Oiethylphthalate 4-Nitrcanitine 2,4,6-TribroacphensI 4,6-0initro-2-«ethyIphenol M-Nitroaodiphenylaair.e (!) Azobenzene 4-8roaophenyl-phenylether HexachIorcbenzene Pentachlorop^«nol Phena-tthrene Anthracene Di-n-butylpMhalats Fluoranthene &nzidine Pyrene Te.'phanyl -dl4 fiuty!ben:ylphthalate :f4f'y •'

zy%: -''

.48341 .44834 3.12

.94625 .96025 1.4« 1.22419 1.27927 4.50

.46850 .57583 ?9.52 1.83709 1.91707 4.35 1.62979 1.54171 5.4u

.4177/ .36681 12.20 .39584 .54539 12.74

1.13892 1,22521 7,58 ,29962 .14150 52.77

1.74024 1.68427 3.22 .25554 .26722 4.5? .68658 .52473 15.4y

1.39652 1,40823 ,8S .64878 .65098 .34

1.61941 1,66265 3.89 .44505 .30954 58.49 .1440? .15661 5.18 .21511 .19158 10.94 .52894 .5775! 18.84 .90007 1.00157 11.28 .2!810 .23206 2.54 .28173 .28834 .49 .21198 .20272 4.37

1.22/64 1.27889 3.46 1.K194 1.24944 2,25 1.64366 1.83621 18.37 1.4e.'571.52124 5.67

.91339 .91919 14.22 vj l.?K!19 1.64944 7.67 'Siif?*)! Ii8«93 9.51

•^l-:»?i^:;i;?W75 4.81

RF - Response Factortf ro r daily: stMdard file et '-'9.!)3 iG/nL

Rf - A-Jersga Response factor froa Initial Calibfetion Frra VI

"SOiff - % Difference froa original av-erage or curve

CCC - Calibratiai Cieck CAcptwnds (*) SK£, - Syateo Parforaancs D'-ack Ciapnunds (**)

fo-^ UII Page 2 of 5 1 1 0

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Continuing Caiibrati j. ' i Ciiect: ({9. Cospounfls

Case t:o:

Contractor: iMOlTilRIAL CUTPObilCN

Cnntract Nn: r p m s O t l T

Instrunent ID: 3C

Calibration Date: 0-/31/8':'

Tiae: 1-J:14

Laboratory IC: >C51.'6

I n i t i a l C i l i t r a t i o r , O.-ite: fl5/24/SV

tliniBua RF f,-r SPCC is .C5 RaxiHja % Oif f fc? OX is T-A

Coapeunri

BenzoleJanthracane 3,5'-Oichlorab«nzid;ne

Chrysene bis(2-EthyIhexyl)phthalate Oi-n-or.tylphthalate Ger.zolblflucranthens 8enzo(k)fluoranthene

8e,tzo(a)pyrene Indenoll,2,5-cd)pyrene Oibenz(a,h)anthracene 8enzo(g,h,i)psry!ene

Rf Rf

1.59713 1.55532 .55087 .31025

1.39514 1.41879

1.45482 1.45l-.'8 2.99774 2.73424

2.18228 1.84721 1.78626 1.84720

1.41502 1.57436 1.19783 1.61383 1.22118 1.44544 1.18746 l.6'284S

!B)iff i x i : SP-X

2.74 4?.6H 1.84 .25

8.79 » 15.55 3.41 2.48 •

34.73 18.36 37.13

:'^*SfS^3

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•» ' - . , f

Rf - Sespcnse Factor" froB d u l y s tvdard f : ! e at 5!:.03 LN'TS

Sf - A-.'erag!> kespnnsa Factar froa I n i t i a l CalitraMa.". F-.ra 'Jl

VQiff - % Difference f rca o r : g i m l a«.-Kreê nr curt-e

CCC - Cal ibrat ion Check Coapounds (*) SPCC - Syatea Perforaance O-iack C-apounda (>•)

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