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Synthesis, Structural Determination, and Physicochemical Property Studies of Novel Coordination Polymers Incorporating Kinked and Hydrogen-Bonding Capable Bifunctional Organodiimines. Robert L. LaDuca Lyman Briggs College, Michigan State University, East Lansing, MI 48825. - PowerPoint PPT Presentation
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Synthesis, Structural Determination, and Physicochemical Property Studies of NovelCoordination Polymers Incorporating Kinked and
Hydrogen-Bonding Capable Bifunctional Organodiimines
Robert L. LaDuca Lyman Briggs College, Michigan State University, East Lansing, MI 48825
Hydrogen-bonding capable dipyridyl tethering ligands have afforded divalent metal dicarboxylate coordination polymers with novel topologies
N
N
H
N
4,4'-dipyridylaminedpa
{[Cu2(phthalate)2(dpa)]•H2O}n
homochiral septuple [Cu2O2(dpa)]n 6-fold helices with weak ferromagnetic coupling
{[Cd(phthalate)(dpa)(H2O)]•4H2O}n3-fold interpenetration of regular (12,3) self-penetrated sublattices,
connection through phthalate affords 4-connected chiral self-penetrated yyz net (7482 topology)