5
e R g n i r e e n i g n E f o l a n r u o J l a n o i t a n r e t n I ) M R E J I ( t n e m e g a n a M d n A h c r a e s 9 4 3 2 : N S S I - e m u l o V , 8 5 0 2 - e u s s I , 3 0 - 6 1 0 2 y a M , 5 0 0 8 1 m o c . m r e j i . w w w t c a r t s b A s i h t n I k r o w o n a n l A g M 2 O 4 d e r a p e r p e r e w s r e d w o p o s y b g n i s u h c a o r p p a l e u f d e x i m y b s s e c o r p n o i t s u b m o c n o i t u l e t a r d y h a x e h e t a r t i n m u i s e n g a m O N ( g M 3 ) 2 H 6 . 2 ) O m u n i m u l a , e t a r d y h a n o n e t a r t i n O N ( l A ( 3 ) 3 H 9 . 2 ) O s e r u t x i m h t i w s r e z i d i x o s a H N ( a e r u f o 2 H N O C 2 ), e s o r c u s C ( 2 1 H 2 2 O 1 1 l e u F . ) n e k a t s i a e r u m o i h c i o t s s a e u f c i r t e e s o r c u s d n a l c i t r e m o i h c i o t s n o n s s e c x e s a e h T . l e u f t c e f f e e s o r c u s f o , e s a h p n o s s e c x e s a n o i t i d d a l e u f e z i s e t i l l a t s y r c . g . e ( s c i t s i r e t c a r a h c d n a e r u t c u r t s ) , y g o l o h p r o m s a e h t f o - . d e t a g i t s e v n i e r e w s r e d w o p d e t l u s e r e t i l l a t s y r c e h T y b d e n i m r e t e d e r e w s e z i s n o s m a i l l i W d n a a l u m r o f r e r e h c S g n i s u - . n o i t a u q e l l a H d e l a e v e r s t l u s e r l a t n e m i r e p x e e h T e h t t a h t s a w e t a n i m u l a m u i s e n g a m f o e s a h p e n i l l a t s y r c e r u p f o n o i t a m r o f r o f d e m r i f n o c s e r e t x i m f o s e h t c a b o w t e h t g n i r a p m o c y b s e s a c h t i w n r e t t a p D R X f o s k a e p d e n i a t b o d r a d n a t s f o s k a e p e h t D R X f o n r e t t a p c S D P C J r e b m u n d r a 1 2- 2 5 1 1 T . f o e z i s e t i l l a t s y r c e h d e s a e r c e d y l t n a c i f i n g i s s a w s r e d w o p e h t m o r f 0 8 3 o t m n 0 m n s a c u s e h t e s o r m o r f e s o r t n e t n o c , 0 0 . 0 0 5 . 0 , ( , 0 5 . 3 t w , ) % s s e c x e 4 h t i w 5 . 2 , a e r u f o s m a r g 6 a m f o s m a r g 5 . 7 d n a e t a r t i n m u i s e n g . e t a r t i n m u n i m u l a f o s m a r g s m r e T x e d n I S , n o i t s u b m o C , e s o r c u l A g M 2 O 4 , U . a e r . I I N O I T C U D O R T N l A g M ( l e n i p s e t a n i m u l a m u i s e n g a M 2 O 4 e l b u o d f o s s a l c a ) t n i o p l a i r t s u d n i e h t m o r f e c n a t r o p m i t a e r g f o s i l a i r e t a m e d i x o w e i v f o s e i t r e p o r p t n a t r o p m i r i e h t o t e u d . B h g i h s t i f o e s u a c e h g i h , t n e i c i f f e o c n o i s n a p x e l a m r e h t w o l , s s e n i r o t c a r f e r y t i l i b a t s l a c i m e h c h g i h d n a e c n a t s i s e r k c o h s l a m r e h t l A g M 2 O 4 l e e t s n i d e s u l a i r e t a m y r o t c a r f e r t n a t r o p m i n a s i ) s e l d a l l e e t s ( i r t s u d n i t n e m e c d n a s e ) s e n o z n o i t i s n a r t d n a g n i n r u b ( o s l a d n a 1 [ s r o t a r e n e g e r e c a n r u f s s a l g f o s k c i r b r e k c e h c e h t n i ]. n i d n a l n i m u l a a i s e n g a M . s n o i t a c i l p p a l a c i g o l o i b e h t n a c l e n i p S a o s l a h g i h e k i l n o i t a c i l p p a d e c n a v d a n i d e s u e b - p m e t e r u t a r e c r a - t i d i m u h , s p o l e v n e g n i s o l c n e , s r o s n e s d e r a r f n i d n a y w o d n i w t n e r a p s n a r t a i r e t a m r u o m r a d n a s e m o d , s 2 [ l . ] s e i t r e p o r p l a m r e h t d n a l a c i n a h c e m , s e i t r e p o r p l a c i s y h p e h T i g o G r e e v n a h C , t n e m e C d n a c i m a r e C f o t n e m t r a p e D e g e l l o C . A . D . P , y g o l o n h c e T G ( i g a r u b a l a K g n i r e e n i g n E f o ) a g a r a b l u , a i d n I h a h S g a r a P t n e m t r a p e D , . A . D . P , y g o l o n h c e T t n e m e C d n a c i m a r e C f o a i d n I , ) a g a r a b l u G ( i g a r u b a l a K g n i r e e n i g n E f o e g e l l o C h s e t a k n e V D . A . D . P , y g o l o n h c e T t n e m e C d n a c i m a r e C f o t n e m t r a p e D , a i d n I , ) a g a r a b l u G ( i g a r u b a l a K g n i r e e n i g n E f o e g e l l o C K . P h s e m g n a S m e C d n a c i m a r e C f o t n e m t r a p e D , , y g o l o n h c e T t n e a i d n I , ) a g a r a b l u G ( i g a r u b a l a K g n i r e e n i g n E f o e g e l l o C . A . D . P . N o a r u b a B . r D r a k i r e h S * t n e m e C d n a c i m a r e C f o t n e m t r a p e D , a i d n I , ) a g a r a b l u G ( i g a r u b a l a K g n i r e e n i g n E f o e g e l l o C . A . D . P , y g o l o n h c e T e h t f o n o i t a t n e i r o , e z i s e p a h s , e z i s e t i l l a t s y r c e h t n o d n e p e d o n a n n i e t a n i m u l a m u i s e n g a m f o s i s e h t n y S . r e d w o p r e d w o p s e i t r e p o r p e c n a m r o f r e p e h t e s a e r c n i r e h t r u f m r o f 3 , 2 [ . ] o n a N - , s r e h c r a e s e r , s t s i t n e i c s e h t g n i t c a r t t a e r a s r e d w o p d e r a p m o c s e i t r e p o r p e u q i n u r i e h t o t e u d e l p o e p l a i r t s u d n i a e r a e c a f r u s h g i h o t e u d t r a p r e t n u o c k l u b r i e h t h t i w 5 [-6 . ] a n i m u l a m u i s e n g a M s r e d w o p o n a n e t y b d e r a p e r p e r e w d i l o s d o h t e m e t a t s 7 [ ], l e g l o s 8 [ , ] o c- 9 [ n o i t a t i p i c e r p -1 1 e s r e v e r , ] m 2 1 [ d o h t e m n o i s l u m e o r c i , ] d o h t e m x e l p m o c d e z i r e m y l o p l e g , ] 3 1 [ - 4 1 [ d o h t e m n o i t s u b m o c h g i h g n i t a g a p o r p f l e s , ] t a r e p m e t e u q i n h c e t ) S H S ( s i s e h t n y s e r u , ] 5 1 [ P S S 6 1 [ g n i s s e c o r P ] , l a m r e h t o r d y h d e t s i s s a e v a w o r c i m 7 1 [ s d o h t e m r e h t o d n a n o i t s u b m o c h t i w s p u o r g l a r e v e s y b , ] g n i y r a v d n a r o s r u c e r p l a c i m e h c t n e r e f f i d g n i s u s s e c o r p e h t e k i l s r e t e m a r a p , e r u t a r e p m e t . c t e n o i t a r t n e c n o c b a d e n o i t n e m s e u q i n h c e t n o i t a r a p e r p e h T w o l s e r a e v o , o nn s u o e n e g o m o h , s r o s r u c e r p t s e i l t s o c e r i u q e r e m i t d n a y g r e n e , g n i m u s n o c e c n e i c S f o e t u t i t s n I n a i d n I f o l i t a P C . K f o r P t u b e r o l a g n a B d e l l a c d o h t e m s i s e h t n y s l e v o n a d e c u d o r t n i o w t d e r e v o c s i d s i h c i h w s i s e h t n y S n o i t s u b m o C n o i t u l o S o g a e d a c e d d n a y g r e n e o n s u o e n e g o m o h t s a f , y s a e e l p m i s s i s s e c o r p g n i m u s n o c e m i t e d i x o f o s r e d w o p o n a n e r a p e r p o t s l a i r e t a m . d e r a p e r p e r e w s r e d w o p o n a n e d i x o c i m a r e c y n a M d o h t e m S C S y b e l g n i s g n i s u l e u f ] 9 1 , 8 1 [ l e u f d e x i m d n a ] 1 2 , 0 2 [ a n i m u l a m u i s e n g a M . o n a n e t s r e d w o p o s l a e r e w e l g n i s h t i w S C S y b d e r a p e r p ] 8 1 [ s l e u f d e x i m d n a ] 2 2 [ n i . e r u t a r e t i l e h t n o e d a m n e e b e v a h s t r o p e r o n w o n l l i T o n a n f o s i s e h t n y s m u i s e n g a m n o i t u l o s y b e t a n i m u l a h t i w l e u f d e x i m e s o r c u s d n a a e r u g n i s u s s e c o r p n o i t s u b m o c a d n a y p l a h t n e f o n o i t a l u c l a c d n a e r u t a r e p m e t e m a l f c i t a b a i d s t l u s e r l a t n e m i r e p x e h t i w m e h t g n i t a l e r r o c . l A g M o n a n k r o w s i h t n I 2 O 4 y b d e r a p e r p e r e w s r e d w o p g n i s u h c a o r p p a l e u f d e x i m y b s s e c o r p n o i t s u b m o c n o i t u l o s e t a r d y h a x e h e t a r t i n m u i s e n g a m O N ( g M 3 ) 2 H 6 . 2 ) O m u n i m u l a , y h a n o n e t a r t i n e t a r d O N ( l A ( 3 ) 3 H 9 . 2 ) O h t i w s r e z i d i x o s a H N ( a e r u f o s e r u t x i m s u o i r a v 2 H N O C 2 e s o r c u s ) C ( 2 1 H 2 2 O 1 1 . ) s s e c x e s a e s o r c u s d n a l e u f c i r t e m o i h c i o t s s a n e k a t s i a e r u l e u F t r e m o i h c i o t s n o n s a n o i t i d d a l e u f e s o r c u s f o t c e f f e e h T . l e u f c i , e s a h p n o s s e c x e t s d n a e r u t c u r e z i s e t i l l a t s y r c e h t f o s a- . d e t a g i t s e v n i e r e w s r e d w o p d e t l u s e r . I I L A T N E M I R E P X E S L I A T E D . A d e s u s l a i r e t a m w a R . a x e h e t a r t i n m u i s e n g a M - e t a r d y h ( . ) O 2 H 6 . 2 ) 3 O N ( g M ( , ) s e i r o t a r o b a l l a s r e v i n U a n o N e t a r t i n m u i n i m u l A - e t a r d y h o n a N f o s i s e h t n y S n o i t u l o S y b e t a n i m u l a m u i s e n g a M h c a o r p p A l e u F d e x i M g n i s U s s e c o r P n o i t s u b m o C a e r U ( + ) e s o r c u S i g o G r e e v n a h C , h a h S g a r a P , , K . P h s e m a g n a S , D h s e t a k n e V r a k i r e h S . N o a r u b a B

Sy nthesis of Nano Magnesiu m alu m inate b y Solution Co ... · Chanveer G ogi , P arag Shah , Venkatesh D, Sangamesh P.K, B aburao N. Sherikar . Synth esis of Na n o Ma gn esi um

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Page 1: Sy nthesis of Nano Magnesiu m alu m inate b y Solution Co ... · Chanveer G ogi , P arag Shah , Venkatesh D, Sangamesh P.K, B aburao N. Sherikar . Synth esis of Na n o Ma gn esi um

eR gnireenignE fo lanruoJ lanoitanretnI )MREJI( tnemeganaM dnA hcraes 9432 : NSSI - emuloV ,8502 - eussI ,30 - 6102 yaM ,50

081 moc.mreji.www

tcartsbA — siht nI krow onan lAgM 2O4 deraperp erew sredwop

os yb gnisu hcaorppa leuf dexim yb ssecorp noitsubmoc noituletardyhaxeh etartin muisengam ON(gM 3)2 H6. 2 )O munimula ,

etardyhanon etartin ON(lA( 3)3 H9. 2 )O serutxim htiw srezidixo saHN( aeru fo 2 HNOC 2 ), esorcus C( 21 H 22 O 11 leuF .) nekat si aerumoihciots sa euf cirte esorcus dna l citremoihciotsnon ssecxe sa

ehT .leuf tceffe esorcus fo ,esahp no ssecxe sa noitidda leufezis etillatsyrc .g.e( scitsiretcarahc dna erutcurts ),ygolohprom

sa eht fo - .detagitsevni erew sredwop detluser etillatsyrc ehTyb denimreted erew sezis nosmailliW dna alumrof rerehcS gnisu

- .noitauqe llaH delaever stluser latnemirepxe ehT eht taht saw etanimula muisengam fo esahp enillatsyrc erup fo noitamrof

rof demrifnoc seretxim fo sehtcab owt eht gnirapmoc yb sesachtiw nrettap DRX fo skaep deniatbo dradnats fo skaep eht DRX

fo nrettap c SDPCJ rebmun dra 12 - 2511 T . fo ezis etillatsyrc ehdesaerced yltnacifingis saw sredwop eht morf 08 3 ot mn 0 mn sa

cus eht esor morf esor tnetnoc ,00.0 05.0 , ( ,0 5.3 tw ,)% ssecxe4 htiw 5.2 ,aeru fo smarg 6 am fo smarg 5.7 dna etartin muiseng

.etartin munimula fo smarg

smreT xednI — S ,noitsubmoC ,esorcu lAgM 2O4, U .aer

.I I NOITCUDORTN lAgM( lenips etanimula muisengaM 2O4 elbuod fo ssalc a )

tniop lairtsudni eht morf ecnatropmi taerg fo si lairetam edixo weiv fo seitreporp tnatropmi rieht ot eud . B hgih sti fo esuace

hgih ,tneiciffeoc noisnapxe lamreht wol ,ssenirotcarferytilibats lacimehc hgih dna ecnatsiser kcohs lamreht lAgM 2O4

leets ni desu lairetam yrotcarfer tnatropmi na si )seldal leets(irtsudni tnemec dna se )senoz noitisnart dna gninrub( osla dna

1[ srotareneger ecanruf ssalg fo skcirb rekcehc eht ni ] . ni dna lnimula aisengaM .snoitacilppa lacigoloib eht nac lenipS a osla

hgih ekil noitacilppa decnavda ni desu eb - pmet erutare cra - tidimuh ,spolevne gnisolcne ,srosnes derarfni dna y

wodniw tnerapsnart airetam ruomra dna semod ,s 2[ l .]

seitreporp lamreht dna lacinahcem ,seitreporp lacisyhp ehT

igoG reevnahC , tnemeC dna cimareC fo tnemtrapeD

egelloC .A.D.P,ygolonhceT G(igarubalaK gnireenignE fo )agarablu , aidnI hahS garaP tnemtrapeD , .A.D.P ,ygolonhceT tnemeC dna cimareC fo

aidnI ,)agarabluG( igarubalaK gnireenignE fo egelloC hsetakneV D .A.D.P ,ygolonhceT tnemeC dna cimareC fo tnemtrapeD ,

aidnI ,)agarabluG( igarubalaK gnireenignE fo egelloC K.P hsemgnaS meC dna cimareC fo tnemtrapeD , ,ygolonhceT tne

aidnI ,)agarabluG( igarubalaK gnireenignE fo egelloC .A.D.P .N oarubaB.rD rakirehS * tnemeC dna cimareC fo tnemtrapeD ,

aidnI ,)agarabluG( igarubalaK gnireenignE fo egelloC .A.D.P ,ygolonhceT

eht fo noitatneiro ,ezis epahs ,ezis etillatsyrc eht no dnepedonan ni etanimula muisengam fo sisehtnyS .redwop redwop

seitreporp ecnamrofrep eht esaercni rehtruf mrof 3,2[ .] onaN - ,srehcraeser ,stsitneics eht gnitcartta era sredwop

derapmoc seitreporp euqinu rieht ot eud elpoep lairtsudniaera ecafrus hgih ot eud trapretnuoc klub rieht htiw 5[ -6 .]

animula muisengaM sredwop onan et yb deraperp erew dilos dohtem etats 7[ ], leg los 8[ ,] oc - 9[noitatipicerp - 11 esrever,]

m 21[ dohtem noislume orci ,] dohtem xelpmoc deziremylopleg,]31[ - 41[ dohtem noitsubmoc hgih gnitagaporp fles ,]tarepmet euqinhcet )SHS( sisehtnys eru ,]51[ PS S

61[gnissecorP ] ,lamrehtordyh detsissa evaworcim71[ sdohtem rehto dna noitsubmoc htiw spuorg lareves yb , ]

gniyrav dna rosrucerp lacimehc tnereffid gnisu ssecorp eht ekil sretemarap ,erutarepmet .cte noitartnecnoc

ba denoitnem seuqinhcet noitaraperp ehT wols era evo , on n suoenegomoh , srosrucerp tseiltsoc eriuqer emit dna ygrene ,

gnimusnoc ecneicS fo etutitsnI naidnI fo litaP C.K forP tuberolagnaB dellac dohtem sisehtnys levon a decudortni

owt derevocsid si hcihw sisehtnyS noitsubmoC noituloSoga edaced dna ygrene on suoenegomoh tsaf ,ysae elpmis si

ssecorp gnimusnoc emit edixo fo sredwoponan eraperp otslairetam . deraperp erew sredwoponan edixo cimarec ynaM

dohtem SCS yb elgnis gnisu leuf ]91,81[ leuf dexim dna ]12,02[ animula muisengaM . onan et sredwop osla erew

elgnis htiw SCS yb deraperp ]81[ sleuf dexim dna ]22[ ni.erutaretil eht no edam neeb evah stroper on won lliT

onan fo sisehtnys muisengam noitulos yb etanimula htiw leuf dexim esorcus dna aeru gnisu ssecorp noitsubmoc

a dna yplahtne fo noitaluclac dna erutarepmet emalf citabaidstluser latnemirepxe htiw meht gnitalerroc .

lAgM onan krow siht nI 2O4 yb deraperp erew sredwop

gnisu hcaorppa leuf dexim yb ssecorp noitsubmoc noitulosetardyhaxeh etartin muisengam ON(gM 3)2 H6. 2 )O munimula ,

yhanon etartin etard ON(lA( 3)3 H9. 2 )O htiw srezidixo saHN( aeru fo serutxim suoirav 2 HNOC 2 esorcus ) C( 21 H 22 O 11 .)

ssecxe sa esorcus dna leuf cirtemoihciots sa nekat si aeru leuFtremoihciotsnon sa noitidda leuf esorcus fo tceffe ehT .leuf ci

,esahp no ssecxe ts dna erutcur ezis etillatsyrc eht fosa - .detagitsevni erew sredwop detluser

.II LATNEMIREPXE SLIATED

.A desu slairetam waR .

axeh etartin muisengaM - etardyh (.)O2H6.2)3ON( gM(,)seirotarobal lasrevinU anoN etartin muinimulA - etardyh

onaN fo sisehtnyS noituloS yb etanimula muisengaMhcaorppA leuF dexiM gnisU ssecorP noitsubmoC aerU( +

)esorcuS igoG reevnahC , hahS garaP , ,K.P hsemagnaS ,D hsetakneV rakirehS .N oarubaB

Page 2: Sy nthesis of Nano Magnesiu m alu m inate b y Solution Co ... · Chanveer G ogi , P arag Shah , Venkatesh D, Sangamesh P.K, B aburao N. Sherikar . Synth esis of Na n o Ma gn esi um

)esorcuS + aerU( hcaorppA leuF dexiM gnisU ssecorP noitsubmoC noituloS yb etanimula muisengaM onaN fo sisehtnyS

181 moc.mreji.www

)O2H9.3)3ON( lA( , lasrevinU( ,)seirotarobal aerUHN( 2 HNOC 2 ,) C( esorcuS 21 H 22 O 11 )mehclA(.) .

.B lAgM fo sisehtnyS noitsubmoC noituloS 2O4

lAgM ehT 2O4 ,etartin muisengaM gnisu yb deraperp saw ( ON(gM 3)2 H6. 2O ,) etartin muinimulA etardyhanon ( ON(lA 3)3 H9. 2O) s sa aeru dna srezidixo sa , ciot cirtemoih

dna leuf esorcus, leuf gnicuder yticimrehtoxe sa noitairaV .orcus fo leuf es eb sah elbaT ni sa dedoc dna edam ne I ehT .

erew stnatcaer tar ralom ni retaw dezinoied ni dexim dna oi ni nwohs sa ssam I elbaT desu saw retaw dezinoieD . rof

suoenegomoh esehT .level cimota ta stnatcaer fo gnixim erew snoitulos 005 ot detaeh erp ecanruf a ni tpek neht o .C

002 ot gnitaeh no tsriF 0 gnikam detaropave saw retaw eht C sesag fo noitulove ylneddus neht noitulos fo gnihtorf

t eud emalf fo tnuoma eguh htiw derrucco noitsubmoc o dna leuf neewteb noitcaer xoder ot eud gnirrucco noitcaer

ezidixo r. hc noitcaer noitsubmoc ehT dna scitsiretcara t ehdetcepxe ekil sliated noitsubmoc , deniatbo dleiy ,tcudorp

rosrucerp lacimehc fo selom dna nekat slacimehc fo tnuomabmun dna ni nwohs era nekat leuf esorcus fo selom fo re

elbaT I . noitsubmoc fo erutan ekil sliated noitsubmoc ehT ,emalf eht fo roloc, dnuos noitsubmoc ,emit noitsubmoc,

,epyt emalf II elbaT ni nwohs era fo segami laer ehT .f ecalp gnikat snoitcaer noitsubmoc fo snoitisopmoc lla ro

giF ni nwohs era esorcus . 1 erew snoitaluclac noitsubmoCrepap ot gnidrocca enod .]32[ htiw snoitcaer noitsubmoC

fo snoitisopmoc sedoc 00USAM )esorcus0.0+aeru ( & 5USAM 0 )esorcus g5.0+aeru( epyt emulov wohs

c etihw htiw noitsubmoc emalf derolo . deniatbo llA eht rednU .MES DRX yb deziretcarahc sredwop

sleuf eseht ni snoitauqe noitcaer eht snoitidnoc muirbiliuqe - lAgM fo noitaraperp rof smetsys etartin 2O4 sleuf dexim yb.woleb sa detneserper eb nac esorcus rof

ON(gM 3)2 H6. 2 ON(lA2+O 3)3. H9 2 +O HC66.6 4N2 +O

C0 21 H 22 O 31 lAgM 2O4 N6.01+ 2 OC6.6+ 2 +

H2.73 2 ..............................O ...................................... ... (1)

ON(gM 3)2 H6. 2 +O ON(lA2 3)3 H9. 2O+ HC66.6 4N2 +O

302.0 C 21 H 22 O 11 lAgM 2O4 N6.01+ 2 OC830.9+ 2 +

H34.9 2 ........................................................O ....... ...... )2(

.1 .giF segamI oc noitulos fo .0 +U fo noitsubm 5 0 fo )g(.esorcuS

C . yb sisylanA esahP X- DRX( noitcarffid yar ) X- esahp rof tuo deirrac erew seiduts noitcarffid yar

dellim eht fo ezis etillatsyrc gnitaluclac dna noitamrifnoc8D gnisu ,selpmas - ecnavdA - uC htiw enihcam rekurB -Kα

w( uC fo htgneleva -Kα 6045.1~ )λ( eht lla rof snoitaidar )ÅK etaunetta ot desu saw retlif iN .stnemerusaem β ehT .senil

gnisu detaluclac saw sredwop fo ezis etillatsyrc s'rerehcS ap eht taht edam saw noitpmussa na erehw alumrof si elcitr

42[ epahs ni lacirehps .] ehT s'rerehcS 52[ sevig alumrof ]

βθ = 3....…………………………

β ,erehw θ fo )MHWF( mumixam flah ta htdiw lluf eht si noisnemid renil eht rof sdnats L ,seerged ni skaep detcarffid dna seerged ni elgna s’ggarB ot srefer θ ,sretem ni selcitrap fo

emun a sa nwonk yllareneg ,rotcaf epahs eht si ’K lacir62[ detaulave dna tnatsnoc fo epahs no sdneped dna 39.0 sa ]

taht nees ylraelc si ti ,noisserpxe siht morF .setillatsyrc etillatsyrc fo ezis eht sa denedaorb steg maeb detcarffid

..secuder illatsyrc ehT yb detaluclac osla saw sredwop fo ezis et

llaH dna nosmailliW W( - sdnemmocer hcihw noitauqe )Hecittal dna ezis niamod eht gninibmoc no stceffe niarts orcim

tal nehw sesac eht ot srefer dohtem ehT .gninedaorb enil ecit ylsuoenatlumis era tceffe niamod eht dna noitamrofed

enil lanif eht dleiy stceffe evitcelloc rieht dna evitarepo

I elbaT euf fo tnuomA lAgM ecudorp ot noitcaer noitsubmoc eht rof desu ,rezidixo dna l 2O4 leuf dexim yb hcaorppauf aeru cirtemoihciots gniniatniam esorcuS dna le .noitidnoc leuf ssecxe sa

on.lS sedoc elpmaS ON(gM 3) 2H6. 2 )g( 0

ON(lA 3)3 H6. 2 O)g(

leuF aerU

)g(

leuFg(esorcus )

detcepxE redwop

)g(

deniatbO redwoP

)g(

fo .oN

selom

1 00USAM 65.2 5.7 4 0 24.1 63.1 00.0

2 USAM 50 65.2 5.7 4 05.0 24.1 4.1 61 .0 02

Page 3: Sy nthesis of Nano Magnesiu m alu m inate b y Solution Co ... · Chanveer G ogi , P arag Shah , Venkatesh D, Sangamesh P.K, B aburao N. Sherikar . Synth esis of Na n o Ma gn esi um

eR gnireenignE fo lanruoJ lanoitanretnI )MREJI( tnemeganaM dnA hcraes 9432 : NSSI - emuloV ,8502 - eussI ,30 - 6102 yaM ,50

281 moc.mreji.www

,)β( MHWF gninedaorb - ecittal dna )β( ezis niarg fo latot eht( noitrotsid elpmas eht htiw derapmoc nehW.) - tnedneped

latnemurtsni lamisetinifni semussa noitaler siht ,gninedaorbehT .noitubirtnoc W- sa detneserper si noitauqe H

W selcitraponan eht htiw detaicossa niarts eht si ε ereh . 8.qE X( θnis 4 neewteb enil thgiarts a stneserper - dna )sixa θsocβ

Y( - niarts eht sevig enil eht fo epols ehT .)sixa dna )ε(Y no enil siht fo )D/λk( tpecretni - ixa .)D ezis etillatsyrc sevig s

.C fo sisylana esahP lAgM 2O4 aeru yb deraperp sredwopleuf esorcus fo snoitidda ssecxe htiw leuf

.giF a 2 wohs 3 dn nrettap DRX s redwop dezisehtnys sa eht fo

rof 00USAM ( 00.0 g) USAM dna 050( .0 5 esorcus fo g htiwleuf ssecxe fo tnuoma tnereffid ylevitcepser fo noitamrof ehT .

lAgM enillatsyrc erup esahp 2O4 gnirapmoc yb demrifnoc sio skaep dradnats htiw skaep eht 12 on drac SDPCJ f - rof 2511

htob eht ehT .sesac ni egnahc htiw seirav kaep eht fo ytisnetni nO .desu leuf fo tnuoma ssecxe nosirapmoc evoba eht fo

sesahp , desaerced yllaudarg sah ytisnetni kaep taht raelc si ti htiw gnola ni esaercni gninedaorb kaep eht fo morf s 00USAM

ot 5USAM 0. esaerced ehT ezis etillatsyrc ni ni esaercni dnaaorb 5USAM rof hgih yrev si gnined 0 eb nac hcihw elpmas

morf nees ylraelc .giF 3. W elih gnizisehtnys lAgM 2O4 morf+U ot esorcus0.0+U gnisu .0 5 noitsubmoc gnirud, esorcus

yticimrehtoxe ot eud sesaerced yllaudarg ytilibaliavanu fo citabaida suht noitsubmoc etelpmoc rof selucelom negyxo fo noitamrof ot sdael siht dna sesaerced erutarepmet emalf

fo sredwop onan 6 morf gnignar ezis etillatsyrc 3 ot mn1 0 mn wol yb gniretnis fo gnitserra ot eud erutarepmet dna desaercni

sredwoponan ot maof eht tsrub devlove sesag fo selom .. T eh esaerced lAgM fo ezis etillatsyrc fo 2O4 htiw redwop

metsys noitsubmoc leuF esorcus fo tnuoma gnisaercni eb nac morf nees F erugi 2 3 dna . vni si ezis etillatsyrc ehT ylesre

ehT .tnuoma esorcus fo noitidda ssecxe eht ot lanoitroporpc morf sesaerced ezis etillatsyr 24 11 ot mn mn esaercni htiw

ezis etillatsyrc ehT .alumrof s'rerehcS yb noitidda leuf ni 5.41 ot mn 26 morf sesaerced .tolp llaH snosmailliW yb mn

saerceD ezis etillatsyrc ni e wol eht ot eud eb yam

cimrehtoxe ni esaerced ot eud detareneg erutarepmetswohs tolp llaH mailliW .erutarepmet naht rehgih seulav eht

s'rerehcS ot eud si siht alumrof noisulcxe fo gninedaorb yb demrof niarts elpmas fo si erehT . uh eg ecnereffid ni

eht fo ezis etillatsyrc sredwop leuf esorcus tuohtiw htiw.leuf esorcus

.giF 2. lAgM fo nrettap DRX 2O 4 gnisu erutxim leuf0.0+aeru( )esorcuS

.giF 3. lAgM fo nrettap DRX 2O 4 gnisu erutxim leuf

+aeru( 0.5 g )esorcuS

C NOISULCNO ehT muisengaM onan erup esahp - lenips etanimulA si

s dezisehtnys yllufsseccu emit tsrif eht rof erutarepmet wol tagnisu ssecorp noitsubmoc noitulos yb dna aeru fo erutxim

II elbaT : esorcus leuf ssecxe gniyrav rof noitcaer noitsubmoc eht fo scitsiretcarahC – ta metsys etartin cirtemoihciots aerunoc leuf lAgM eht eraperp ot noitid 2O4

ecxE fo ssorcus

es )g(

elpmaS noitsubmoCepyt dnuos/krapS sesaG roloC noitcaeR

noitsubmoCemit

0.0 lAgM 2O4 ybaerU esorcus+ emalF

oNkcarc/gnikrapS

dnuos gni

enif htiw sesaGredwop etihW maoF

noitamrof

ces12 nim6

.0 50 lAgM 2O4 yb +aeru esorcus emalF

ssol , gnikrapS dna noitulos fo

dnuos gnikcarc

sesaG eguH enif htiw

redwop yerg htorF oN

noitamrof

65 nim5 ces

...................... 4......

Page 4: Sy nthesis of Nano Magnesiu m alu m inate b y Solution Co ... · Chanveer G ogi , P arag Shah , Venkatesh D, Sangamesh P.K, B aburao N. Sherikar . Synth esis of Na n o Ma gn esi um

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taerc etillatsyrc eht gnicuder selcitrap onan fo noitamrof se.mn 11 ot mn 24 morf ezis si leuf fo erutxim fo tceffe ehT

gniyrav dna tnatsnoc aeru gnipeek esorcus+aeru gnisu deidutsp redwop no esorcus fo tnuoma eht seitrepor etillatsyrc ekil

ezis .deiduts si

R SECNEREFE

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R lairetaM morf D.hP sih deniatbo rakirehS .N oarubaB .rD hcraese lairetaM( hceT.M ,erolagnaB )cSII( ecneicS fo etutitsnI naidnI ,retneC dna cimareC ni E.B dna ,rupgarahK TII morf )gnireenignE & ecneicS ytisrevinU agrabluG(gnireenignE fo egelloC ADP morf ygolonhcet tnemeC

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rohtuA dnoceS

Page 5: Sy nthesis of Nano Magnesiu m alu m inate b y Solution Co ... · Chanveer G ogi , P arag Shah , Venkatesh D, Sangamesh P.K, B aburao N. Sherikar . Synth esis of Na n o Ma gn esi um

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481 moc.mreji.www

fo tneduts raey lanif gnireenignE fo rolehcaB si igoG reevnahC

eC dna cimareC fo tnemtraped ,ygolonhcet tnem fo egelloC ADPnireenignE agrabluG ,g – ni ezirp dr3 deniatbo eH .akatanraK .201585

tnemnorivnE dna ygrenE rof slairetaM no ecnerefnoc lanoitanretnIEEMAC, - yb dezinagro erolagnaB egelloc gnireenigne tsirhC ta dleh 5102

teicos cimarec naidnI .y

rohtuA drihT

hahS garaP si fo tnemtraped fo tneduts raey lanif gnireenignE fo rolehcaB

agrabluG ,gnireenignE fo egelloC ADP ,ygolonhcet tnemeC dna cimareC – no ecnerefnoc lanoitanretnI ni ezirp dr3 deniatbo eH .akatanraK .201585

EEMAC, tnemnorivnE dna ygrenE rof slairetaM - dleh 5102 tsirhC ta.yteicos cimarec naidnI yb dezinagro erolagnaB egelloc gnireenigne