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SAFETY DATA SHEET

SUPRASEC® 9631 (STI 03-0.15-S HYPERFLEX)

Version 1.1

Revision Date: 05/16/2018

SDS Number: 400001016383

Date of last issue: 02/11/2016 Date of first issue: 02/11/2016

SDS_US-PU – EN – 400001016383 1 / 27

SECTION 1. IDENTIFICATION

Product name

: SUPRASEC® 9631 (STI 03-0.15-S HYPERFLEX)

Manufacturer or supplier's details

Company name of supplier : Huntsman Polyurethanes Address : P.O. Box 4980

The Woodlands, TX 77387 United States of America (USA)

Telephone : Tech Info:(800) 257-5547 E-mail address of person responsible for the SDS

: [email protected]

Emergency telephone number : Chemtrec: (800) 424-9300 or (703) 527-3887

Recommended use of the chemical and restrictions on use

Recommended use

: Component of a Polyurethane System.

Restrictions on use

: For industrial use only.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with 29 CFR 1910.1200

Acute toxicity (Inhalation)

: Category 4

Skin irritation

: Category 2

Eye irritation

: Category 2B

Respiratory sensitisation

: Category 1

Skin sensitisation

: Category 1

Specific target organ toxicity - single exposure

: Category 3 (Respiratory system)

GHS label elements

Hazard pictograms

:

Signal word

: Danger

Hazard statements

: H315 + H320 Causes skin and eye irritation. H317 May cause an allergic skin reaction.

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H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation.

Precautionary statements

: Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. P285 In case of inadequate ventilation wear respiratory protection. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P362 Take off contaminated clothing and wash before reuse. Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: P501 Dispose of contents/container to an approved facility in accordance with local, regional, national and international regulations.

Other hazards

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture

: Mixture

Hazardous components

Chemical name CAS-No. Concentration (% w/w)

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]

39420-98-9 30 - 50

4,4'-methylenediphenyl diisocyanate 101-68-8 20 - 30

2,4'-methylenediphenyl diisocyanate 5873-54-1 10 - 20 Diphenylmethanediisocyanate 9016-87-9 5 - 10

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The specific chemical identity and/or exact percentage (concentration) of composition may be withheld as a trade secret.

SECTION 4. FIRST AID MEASURES

General advice

: Move out of dangerous area. Do not leave the victim unattended. Get medical attention immediately if symptoms occur. Show this safety data sheet to the doctor in attendance.

If inhaled

: If breathed in, move person into fresh air. Call a physician or poison control centre immediately. Keep patient warm and at rest. Keep respiratory tract clear. If breathing is difficult, give oxygen. If breathing is irregular or stopped, administer artificial respiration. If unconscious, place in recovery position and seek medical advice. Consult a physician immediately if symptoms such as shortness of breath or asthma are observed. A hyper-reactive response to even minimal concentrations of diisocyanates may develop in sensitised persons. The exposed person may need to be kept under medical surveillance for 48 hours. LC50 (rat) : ca. 490 mg/m³ (4 hours) : using experimentally produced respirable aerosol having aerodynamic diameter <5microns.

In case of skin contact

: In case of contact, immediately flush skin with soap and plenty of water. Take off contaminated clothing and shoes immediately. Wash contaminated clothing before reuse. Thoroughly clean shoes before reuse. Call a physician if irritation develops or persists. An MDI study has demonstrated that a polyglycol-based skin cleanser (such as D-TamTM, PEG-400) or corn oil may be more effective than soap and water.

In case of eye contact

: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If easy to do, remove contact lens, if worn. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

If swallowed

: Gently wipe or rinse the inside of the mouth with water. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Keep respiratory tract clear. Keep at rest. If a person vomits when lying on his back, place him in the recovery position.

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Never give anything by mouth to an unconscious person. Take victim immediately to hospital. If symptoms persist, call a physician.

Most important symptoms and effects, both acute and delayed

: Severe allergic skin reactions, bronchiospasm and anaphylactic shock This product is a respiratory irritant and potential respiratory sensitiser: repeated inhalation of vapour or aerosol at levels above the occupational exposure limit could cause respiratory sensitisation. Symptoms may include irritation to the eyes, nose, throat and lungs, possibly combined with dryness of the throat, tightness of chest and difficulty in breathing. The onset of the respiratory symptoms may be delayed for several hours after exposure. A hyper-reactive response to even minimal concentrations of MDI may develop in sensitised persons.

Protection of first-aiders

: No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If potential for exposure exists refer to Section 8 for specific personal protective equipment. First Aid responders should pay attention to self-protection and use the recommended protective clothing

Notes to physician

: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours. The first aid procedure should be established in consultation with the doctor responsible for industrial medicine.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Foam Carbon dioxide (CO2) Dry powder

Unsuitable extinguishing media

: Water may be used if no other available and then in copious quantities. Reaction between water and hot isocyanate may be vigorous.

Specific hazards during firefighting

: Do not allow run-off from fire fighting to enter drains or water courses. The pressure in sealed containers can increase under the influence of heat. Exposure to decomposition products may be a hazard to health.

Hazardous combustion : Combustion products may include: carbon monoxide, carbon

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products

dioxide, nitrogen oxides, hydrocarbons and HCN. In the event of extreme heat (>500 degrees C), aniline is suspected of being formed.

Specific extinguishing methods

: Cool containers/tanks with water spray.

Further information : Standard procedure for chemical fires.

Due to reaction with water producing CO2-gas, a hazardous build-up of pressure could result if contaminated containers are re-sealed. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Prevent fire extinguishing water from contaminating surface water or the ground water system. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Special protective equipment for firefighters

: Wear an approved positive pressure self-contained breathing apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Immediately evacuate personnel to safe areas. Use personal protective equipment. If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Only qualified personnel equipped with suitable protective equipment may intervene. For additional precautions and advice on safe handling, see section 7. Never return spills in original containers for re-use. Make sure that there is a sufficient amount of neutralizing/ absorbent material near the storage area. The danger areas must be delimited and identified using relevant warning and safety signs. Treat recovered material as described in the section "Disposal considerations". For disposal considerations see section 13.

Environmental precautions

: Do not allow uncontrolled discharge of product into the environment. Do not allow material to contaminate ground water system. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Local authorities should be advised if significant spillages cannot be contained. If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and materials for containment and cleaning up

: Clean-up methods - small spillage Contain spillage, soak up with non-combustible absorbent

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material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Clean contaminated surface thoroughly. Sweep up or vacuum up spillage and collect in suitable container for disposal. Neutralize small spillages with decontaminant. The compositions of liquid decontaminants are given in Section 16. Remove and dispose of residues. Clean-up methods - large spillage If the product is in its solid form: Spilled MDI flakes should be picked up carefully. The area should be vacuum cleaned to remove remaining dust particles completely. If the product is in its liquid form: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Leave to react for at least 30 minutes. Shovel into open-top drums for further decontamination. Wash the spillage area with water. Test atmosphere for MDI vapour. Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Technical measures

: Ensure that eyewash stations and safety showers are close to the workstation location.

Local/Total ventilation

: Use only with adequate ventilation.

Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Advice on safe handling : For personal protection see section 8. Avoid formation of aerosol. Do not breathe vapours or spray mist. Do not breathe vapours/dust. Do not swallow. Do not get in eyes or mouth or on skin. Do not get on skin or clothing. Avoid exposure - obtain special instructions before use. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Keep container closed when not in use. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.

Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-ventilated

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place.

Keep in properly labelled containers.

Observe label precautions.

Protect from moisture.

Electrical installations / working materials must comply with the

technological safety standards.

Containers which are opened must be carefully resealed and kept

upright to prevent leakage.

Materials to avoid : Acids

Amines Bases Metals water

Further information on storage stability

: Stable at normal ambient temperature and pressure.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type (Form of exposure)

Control parameters / Permissible concentration

Basis

4,4'-methylenediphenyl diisocyanate

101-68-8 TWA 0.005 ppm ACGIH

C 0.02 ppm 0.2 mg/m3

OSHA Z-1

Personal protective equipment

Respiratory protection

: Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. In emergency, non-routine and unknown exposure situations, including confined space entries, a NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA)or a full facepiece pressure demand supplied air respirator (SAR) with auxiliary self-contained air supply, should be used.

Hand protection Remarks

: The suitability for a specific workplace should be discussed with the producers of the protective gloves. Protective gloves should be worn when handling freshly made polyurethane products to avoid contact with trace residual materials which may be hazardous in contact with skin. Use chemical resistant gloves classified under Standard EN374: protective gloves against chemicals and

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microorganisms. Examples of glove materials that might provide suitable protection include: Butyl rubber, Chlorinated polyethylene, Polyethylene, Ethyl vinyl alcohol copolymers laminated (“EVAL”), Polychloroprene (Neoprene*), Nitrile/butadiene rubber (“nitrile” or “NBR”), Polyvinyl chloride (“PVC” or “vinyl”), Fluoroelastomer (Viton*). When prolonged or frequently repeated contact may occur, a glove with protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN374) is recommended. When only brief contact is expected, a glove with protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN374) is recommended. Contaminated gloves should be decontaminated and disposed of. Notice: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all requisite workplace factors such as, but not limited to : other chemicals that may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), as well as instructions/specifications provided by the glove supplier.

Eye protection

: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Chemical splash goggles. Always wear eye protection when the potential for inadvertent eye contact with the product cannot be excluded. Please follow all applicable local/national requirements when selecting protective measures for a specific workplace. Ensure that eyewash stations and safety showers are close to the workstation location.

Skin and body protection

: Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Recommended: Overall (preferably heavy cotton) or Tyvek-Pro Tech 'C' , Tyvek Pro 'F' disposable coverall.

Protective measures

: Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Ensure that eye flushing systems and safety showers are located close to the working place.

Hygiene measures

: Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after

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handling. Remove contaminated clothing and protective equipment before entering eating areas. When using do not eat, drink or smoke. Contaminated work clothing should not be allowed out of the workplace. Wash hands before breaks and immediately after handling the product. Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

: liquid

Colour

: amber

Odour

: No data is available on the product itself.

Odour Threshold


pH


Freezing point


Melting point


Boiling point


Flash point : > 250.00 °F / > 121.11 °C Method: Seta closed cup

Evaporation rate : No data is available on the product itself.

Flammability (solid, gas) : No data is available on the product itself.

Flammability (liquids) : No data is available on the product itself.

Upper explosion limit / Upper flammability limit


Lower explosion limit / Lower flammability limit


Vapour pressure : No data is available on the product itself.

Relative vapour density : No data is available on the product itself.

Relative density : 1.19 (68 °F / 20 °C)

Density : 1.19 g/cm3 (68 °F / 20 °C)

Solubility(ies) Water solubility : No data is available on the product itself.

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Solubility in other solvents : No data is available on the product itself.

Partition coefficient: n-octanol/water


Auto-ignition temperature : No data is available on the product itself.

Thermal decomposition : No data is available on the product itself.

Self-Accelerating decomposition temperature (SADT)


Viscosity


Explosive properties


Oxidizing properties


Particle size


SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions

: Reaction with water (moisture) produces CO2-gas. Exothermic reaction with materials containing active hydrogen groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the miscibility of the reaction partners is good or is supported by stirring or by the presence of solvents. MDI is insoluble with, and heavier than water and sinks to the bottom but reacts slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.

Conditions to avoid : Extremes of temperature and direct sunlight. Exposure to air or moisture over prolonged periods.

Incompatible materials : Acids Amines Bases Metals water

Hazardous decomposition products

: Combustion products may include: carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons and HCN. In the event of extreme heat (>500 degrees C), aniline is suspected of being formed.

SECTION 11. TOXICOLOGICAL INFORMATION

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Information on likely routes of exposure


Acute toxicity

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Acute oral toxicityComponents

: LD50 (Rat, male): > 10,000 mg/kg Method: OECD Test Guideline 401

4,4'-methylenediphenyl diisocyanate: Acute oral toxicityComponents


Diphenylmethanediisocyanate: Acute oral toxicityComponents


Acute inhalation toxicity - Product

: Assessment: The substance/mixture is not toxic on inhalation as defined by dangerous goods regulations.

Acute toxicity estimate: 1.48 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method

Acute dermal toxicity - Product

: Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method

Acute toxicity (other routes of administration)

: No data available

Skin corrosion/irritation

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Species: Rabbit Assessment: Irritant Method: OECD Test Guideline 404 Result: Irritating to skin. 4,4'-methylenediphenyl diisocyanate: Species: Rabbit Method: OECD Test Guideline 404 Result: Irritating to skin. 2,4'-methylenediphenyl diisocyanate: Species: Rabbit Assessment: Irritant Method: OECD Test Guideline 404

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Result: Irritating to skin. Diphenylmethanediisocyanate: Species: Rabbit Assessment: Irritating to skin. Method: OECD Test Guideline 404 Result: Skin irritation

Serious eye damage/eye irritation

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Species: Rabbit Result: Mild eye irritation Assessment: Irritant Method: No information available. Remarks: Mild eye irritation largely based on human evidence 4,4'-methylenediphenyl diisocyanate: Species: Rabbit Result: Mild eye irritation 2,4'-methylenediphenyl diisocyanate: Species: Humans Result: Irritation to eyes, reversing within 7 days Assessment: Mild eye irritant Method: OECD Test Guideline 405 Remarks: Mild eye irritation Diphenylmethanediisocyanate: Species: Rabbit Result: Irritation to eyes, reversing within 7 days Assessment: Mild eye irritant Method: OECD Test Guideline 405

Respiratory or skin sensitisation

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Exposure routes: Skin Species: Mouse Assessment: May cause sensitisation by skin contact. Result: Causes sensitisation. Exposure routes: Respiratory Tract Species: Guinea pig Assessment: May cause sensitisation by inhalation. Result: Causes sensitisation. 4,4'-methylenediphenyl diisocyanate: Exposure routes: Skin Species: Mouse Method: OECD Test Guideline 429

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Result: May cause sensitisation by skin contact. Exposure routes: Respiratory Tract Species: Guinea pig Result: May cause sensitisation by inhalation. 2,4'-methylenediphenyl diisocyanate: Exposure routes: Skin Species: Mouse Assessment: May cause sensitisation by skin contact. Result: Causes sensitisation. Exposure routes: Respiratory Tract Species: Guinea pig Assessment: May cause sensitisation by inhalation. Result: Causes sensitisation. Diphenylmethanediisocyanate: Exposure routes: Skin Species: Guinea pig Method: OECD Test Guideline 406 Result: May cause sensitisation by skin contact. Exposure routes: Respiratory Tract Species: Rat Result: May cause sensitisation by inhalation.

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Assessment: Mild eye irritation

4,4'-methylenediphenyl diisocyanate: Assessment: May cause sensitisation by inhalation and skin contact.

2,4'-methylenediphenyl diisocyanate: Assessment: Mild eye irritation

Diphenylmethanediisocyanate: Assessment: May cause an allergic skin reaction., May cause allergy or

asthma symptoms or breathing difficulties if inhaled.

Germ cell mutagenicity

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Genotoxicity in vitro : Concentration: 200 ug/plate

Metabolic activation: with and without metabolic activation Method: Directive 67/548/EEC, Annex, B.13/14 Result: negative

4,4'-methylenediphenyl diisocyanate: Genotoxicity in vitro : Concentration: 200 ug/plate

Metabolic activation: with and without metabolic activation

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Method: Directive 67/548/EEC, Annex, B.13/14 Result: negative

2,4'-methylenediphenyl diisocyanate: Genotoxicity in vitro : Metabolic activation: with and without metabolic activation

Method: OECD Test Guideline 471 Result: negative

Diphenylmethanediisocyanate: Genotoxicity in vitro : Concentration: 200 ug/plate

Metabolic activation: with and without metabolic activation Method: Directive 67/548/EEC, Annex, B.13/14 Result: negative

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Genotoxicity in vivo : Application Route: Inhalation

Exposure time: 3 Weeks Dose: 118 mg/m3 Method: OECD Test Guideline 474 Result: negative

4,4'-methylenediphenyl diisocyanate: Genotoxicity in vivo : Application Route: Inhalation


2,4'-methylenediphenyl diisocyanate: Genotoxicity in vivo : Application Route: Inhalation


Diphenylmethanediisocyanate: Genotoxicity in vivo : Application Route: Inhalation

Result: Not classified due to inconclusive data.

Application Route: Inhalation Exposure time: 3 Weeks Dose: 113 mg/m3 Method: OECD Test Guideline 474 Result: negative

Carcinogenicity

Product:

Remarks: Rats have been exposed for two years to a respirable aerosol of polymeric MDI which resulted in a chronic pulmonary irritation at high concentrations. Only at the top level (6 mg/m3), there was a significant incidence of a benign tumour of the lung (adenoma) and one malignant tumour (adenocarcinoma). There were no lung tumours at 1 mg/m3 and no effects at 0.2 mg/m3. Overall, the tumour incidence, both benign and malignant, and the number of animals with the

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tumours were not different from controls. The increased incidence of lung tumours is associated with prolonged respiratory irritation and the concurrent accumulation of yellow material in the lung, which occurred throughout the study. In the absence of prolonged exposure to high concentrations leading to chronic irritation and lung damage, it is highly unlikely that tumour formation will occur. Carcinogenicity - Assessment

: No data available

IARC No component of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity

Components:

2,4'-methylenediphenyl diisocyanate: Effects on fertility : Species: Rat, female

Application Route: Inhalation Method: OECD Test Guideline 414 Result: Animal testing did not show any effects on fertility. Species: Rat, male and female Application Route: Inhalation Method: OECD Test Guideline 414 Result: Animal testing did not show any effects on fertility.

Diphenylmethanediisocyanate: Species: Rat, male and female

Application Route: Inhalation Method: OECD Test Guideline 414 Remarks: No significant adverse effects were reported

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Effects on foetal development

: Species: Rat, male and female Application Route: Inhalation Method: OECD Test Guideline 414 Result: No teratogenic effects

4,4'-methylenediphenyl diisocyanate: Species: Rat, female

Application Route: Inhalation

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General Toxicity Maternal: No observed adverse effect level: 4 mg/m³ Method: OECD Test Guideline 414 Result: No teratogenic effects

2,4'-methylenediphenyl diisocyanate: Species: Rat, male and female

Application Route: Inhalation General Toxicity Maternal: No observed adverse effect level: 4 mg/m³ Method: OECD Test Guideline 414 Result: No teratogenic effects

Diphenylmethanediisocyanate: Species: Rat, male and female

Application Route: Inhalation General Toxicity Maternal: 4 mg/m³ Method: OECD Test Guideline 414 Result: No teratogenic effects

Reproductive toxicity - Assessment

: No data available

STOT - single exposure

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Exposure routes: inhalation (dust/mist/fume) Target Organs: Respiratory Tract Assessment: The substance or mixture is classified as specific target organ toxicant, single exposure, category 3 with respiratory tract irritation. 4,4'-methylenediphenyl diisocyanate: Exposure routes: Inhalation Target Organs: Respiratory Tract Assessment: May cause respiratory irritation. 2,4'-methylenediphenyl diisocyanate: Exposure routes: Inhalation Target Organs: Respiratory system Assessment: The substance or mixture is classified as specific target organ toxicant, single exposure, category 3 with respiratory tract irritation. Diphenylmethanediisocyanate: Exposure routes: Inhalation Target Organs: Respiratory Tract Assessment: May cause respiratory irritation.

STOT - repeated exposure

No data available

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Repeated dose toxicity

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Species: Rat, male and female NOEC: 0.2 mg/m3 Exposure time: 2 yr Number of exposures: 5 d Method: OECD Test Guideline 453 4,4'-methylenediphenyl diisocyanate: Species: Rat, male and female NOEC: 0.2 mg/m3 Exposure time: 2 yr Number of exposures: 5 d Method: OECD Test Guideline 453 2,4'-methylenediphenyl diisocyanate: Species: Rat, male and female NOEC: 0.2 mg/m3 Exposure time: 2 yr Number of exposures: 5 d Method: OECD Test Guideline 453 Diphenylmethanediisocyanate: Species: Rat, male and female NOEC: 0.2 mg/m3 Test atmosphere: dust/mist Exposure time: 2 yr Number of exposures: 5 d Method: OECD Test Guideline 453

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Repeated dose toxicity - Assessment

: Mild eye irritation

2,4'-methylenediphenyl diisocyanate: Repeated dose toxicity - Assessment

: Mild eye irritation

Aspiration toxicity

No data available

Experience with human exposure

General Information: No data available

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Inhalation: No data available

Skin contact: No data available

Eye contact: No data available

Ingestion: No data available

Toxicology, Metabolism, Distribution

No data available

Neurological effects

No data available

Further information

Ingestion: No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Toxicity to fish

: LC50 (Brachydanio rerio (zebrafish)): > 1,000 mg/l Exposure time: 96 h Test Type: static test Method: OECD Test Guideline 203

4,4'-methylenediphenyl diisocyanate: Toxicity to fish

: LC50 (Brachydanio rerio (zebrafish)): > 1,000 mg/l Exposure time: 96 h Test Type: static test Method: OECD Test Guideline 203

2,4'-methylenediphenyl diisocyanate: Toxicity to fish

: LC50 (Brachydanio rerio (zebrafish)): > 1,000 mg/l Exposure time: 96 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 203

Diphenylmethanediisocyanate: Toxicity to fish

: LC50 (Brachydanio rerio (zebrafish)): > 1,000 mg/l Exposure time: 96 h Test Type: static test Test substance: Fresh water

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Method: OECD Test Guideline 203

LC0: > 1,000 mg/l Exposure time: 96 h

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 24 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 202

4,4'-methylenediphenyl diisocyanate: Toxicity to daphnia and other aquatic invertebrates


2,4'-methylenediphenyl diisocyanate: Toxicity to daphnia and other aquatic invertebrates


Diphenylmethanediisocyanate: Toxicity to daphnia and other aquatic invertebrates


Components:

Diphenylmethanediisocyanate: Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 1,640

mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201

M-Factor (Acute aquatic toxicity)

: No data available

Toxicity to fish (Chronic toxicity)

: No data available

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): >= 10 mg/l

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aquatic invertebrates (Chronic toxicity)

Exposure time: 21 d Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 211

4,4'-methylenediphenyl diisocyanate: Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)

: NOEC (Daphnia magna (Water flea)): >= 10 mg/l Exposure time: 21 d Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 211

2,4'-methylenediphenyl diisocyanate: Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)


Diphenylmethanediisocyanate: Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)


M-Factor (Chronic aquatic toxicity)

: No data available

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Toxicity to microorganisms : EC50 (activated sludge): > 100 mg/l

Exposure time: 3 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 209

2,4'-methylenediphenyl diisocyanate: Toxicity to microorganisms : EC50 (activated sludge): > 100 mg/l


Diphenylmethanediisocyanate: Toxicity to microorganisms : EC50 (activated sludge): > 100 mg/l


Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]:

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Toxicity to soil dwelling organisms

: NOEC (Eisenia fetida (earthworms)): >= 1,000 mg/kg Exposure time: 336 h Method: OECD Test Guideline 207

4,4'-methylenediphenyl diisocyanate: Toxicity to soil dwelling organisms


2,4'-methylenediphenyl diisocyanate: Toxicity to soil dwelling organisms


Diphenylmethanediisocyanate: Toxicity to soil dwelling organisms

: EC50 (Eisenia fetida (earthworms)): > 1,000 mg/kg Exposure time: 336 h Method: OECD Test Guideline 207

Plant toxicity : No data available Sediment toxicity : No data available Toxicity to terrestrial organisms

: No data available

Ecotoxicology Assessment Acute aquatic toxicity : No data available Chronic aquatic toxicity : No data available Toxicity Data on Soil : No data available Other organisms relevant to the environment

: No data available

Persistence and degradability

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Biodegradability : Inoculum: Domestic sewage

Concentration: 30 mg/l Result: Not biodegradable Biodegradation: 0 % Exposure time: 28 d Method: Inherent Biodegradability: Modified MITI Test (II)

4,4'-methylenediphenyl diisocyanate: Biodegradability : Inoculum: Domestic sewage


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2,4'-methylenediphenyl diisocyanate: Biodegradability : Inoculum: Domestic sewage


Diphenylmethanediisocyanate: Biodegradability : Inoculum: Domestic sewage


Biochemical Oxygen Demand (BOD)

: No data available

Chemical Oxygen Demand (COD)

: No data available

BOD/COD : No data available ThOD : No data available BOD/ThOD : No data available Dissolved organic carbon (DOC)

: No data available

Physico-chemical removability

: No data available

Components:

4,4'-methylenediphenyl diisocyanate: Stability in water : Degradation half life(DT50): 20 hrs (77 °F / 25 °C)

Remarks: Fresh water

Diphenylmethanediisocyanate: Stability in water : Degradation half life(DT50): 0.8 d (77 °F / 25 °C)

Method: No information available. Remarks: Fresh water

Photodegradation : No data available Impact on Sewage Treatment

: No data available

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Bioaccumulative potential

Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Bioaccumulation : Species: Cyprinus carpio (Carp)

Bioconcentration factor (BCF): 200 Remarks: Bioaccumulation is unlikely.

4,4'-methylenediphenyl diisocyanate: Bioaccumulation : Species: Cyprinus carpio (Carp)


2,4'-methylenediphenyl diisocyanate: Bioaccumulation : Species: Cyprinus carpio (Carp)


Diphenylmethanediisocyanate: Bioaccumulation : Species: Cyprinus carpio (Carp)


Components:

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis[isocyanatobenzene]: Partition coefficient: n-octanol/water

: log Pow: 4.51 (68 °F / 20 °C) pH: 7 Method: OECD Test Guideline 117

4,4'-methylenediphenyl diisocyanate: Partition coefficient: n-octanol/water


2,4'-methylenediphenyl diisocyanate: Partition coefficient: n-octanol/water


Mobility in soil

Mobility : No data available Distribution among environmental compartments

: No data available

Stability in soil : No data available

Other adverse effects

Environmental fate and pathways

: No data available

Results of PBT and vPvB : No data available

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assessment Endocrine disrupting potential

: No data available

Adsorbed organic bound halogens (AOX)

: No data available

Hazardous to the ozone layer

Ozone-Depletion Potential

: Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological information

: No data available

Global warming potential (GWP)

: No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

International Regulations

IATA Not regulated as dangerous goods

IMDG Not regulated as dangerous goods

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable for product as supplied.

National Regulations

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DOT Classification UN/ID/NA number : NA 3082

Proper shipping name : OTHER REGULATED SUBSTANCES, LIQUID, N.O.S. (Methylene Diphenyl Diisocyanate)

Class : 9

Packing group : III

Labels : CLASS 9

ERG Code : 171

Marine pollutant : no

Special precautions for user

The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

Components CAS-No. Component RQ (lbs)

Calculated product RQ (lbs)


101-68-8 5000 19619

chlorobenzene 108-90-7 100 *

*: Calculated RQ exceeds reasonably attainable upper limit. SARA 311/312 Hazards

: Acute toxicity (any route of exposure) Skin corrosion or irritation Serious eye damage or eye irritation Respiratory or skin sensitisation Specific target organ toxicity (single or repeated exposure)

SARA 313

: The following components are subject to reporting levels established by SARA Title III, Section 313:


101-68-8 >= 20 - < 30 %

Diphenylmethanediisocyanate

9016-87-9 >= 5 - < 10 %

The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): 4,4'-methylenediphenyl

diisocyanate 101-68-8

California Prop. 65

This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

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The components of this product are reported in the following inventories:

CH INV : The formulation contains substances listed on the Swiss Inventory, On the inventory, or in compliance with the inventory

DSL : All components of this product are on the Canadian DSL AICS : On the inventory, or in compliance with the inventory NZIoC : Not in compliance with the inventory ENCS : Not in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : Not in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory TCSI : Not in compliance with the inventory TSCA : On the inventory, or in compliance with the inventory

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)

TSCA - 5(a) Significant New Use Rule List of Chemicals No substances are subject to a Significant New Use Rule. US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) No substances are subject to TSCA 12(b) export notification requirements.

SECTION 16. OTHER INFORMATION

Further information

NFPA 704: HMIS® IV:

HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. The "*" represents a chronic hazard, while the "/" represents the absence of a chronic hazard.

Liquid decontaminants (percentages by weight or volume) : Decontaminant 1 : *- sodium carbonate : 5 - 10 % *- liquid detergent : 0.2 - 2 % *- water : to make up to 100 % Decontaminant 2 : *- concentrated ammonia solution : 3 - 8 % *- liquid detergent : 0.2 - 2 % *- water : to make up to 100 %

Flammability

Hea

lth

Instab

ility

2 0

Special hazard.

FLAMMABILITY 1

PHYSICAL HAZARD

HEALTH

0

* 2 1

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Decontaminant 1 reacts slower with diisocyanates but is more environmentally friendly than decontaminant 2. Decontaminant 2 contains ammonia. Ammonia presents health hazards. (See supplier safety information.) Revision Date

: 05/16/2018

ACGIH : USA. ACGIH Threshold Limit Values (TLV) OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1

Limits for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average OSHA Z-1 / C : Ceiling

The information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.

THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.

Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined by the user and made known to handlers, processors and end users.

The trademarks above are the property of Huntsman Corporation or an affiliate thereof.

NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.

Documents

SUPRASEC® 9631 (STI 03-0.15-S HYPERFLEX) › upload › STI-03-0.15-S-HYPERFLEX-(SDS).pdf · SUPRASEC® 9631 (STI 03-0.15-S HYPERFLEX) Version 1.1 Revision Date: 05/16/2018 SDS Number: